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Njeets FT 6-Jee Adv p2
Njeets FT 6-Jee Adv p2
Important Instructions:
1. The question paper has three parts: Physics, Chemistry and Mathematics. Each part has three sections.
2. Carefully read the instructions given at the beginning of each section.
3. Part A (i) contains 08 multiple choice questions with one or more than one correct option.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
4. Part A (ii) contains 2 “Paragraph” type questions. Each paragraph describes an experiment, a situation or
a problem. Two multiple choice questions will be asked based on this paragraph. One or more than one
option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and −1 in all other cases.
5. There is no Section B.
6. Part C contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9
(both inclusive).
Marking scheme: +4 for correct answer and 0 in all other case
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Section – 1: PHYSICS
Part A – (i): (ONE OR MORE THAN OPTION CORRECT TYPE)
This section contains 08 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE THAN ONE is correct.
1. One mole of a gas is subjected to two processes AB and BC, one after the other as shown in
the figure. BC is represented by PV = constant. We can conclude that (where T = temperature,
W = work done by gas, V = volume and U = internal energy).
(a) TA = TB = TC (b) VA < VB, PB < PC (c) WAB > WBC (d) TA < TB
2. A particle is projected at t = 0 such that its velocity varies with times as V = (15 − 6t ) i + ( 20 − 8t ) j. Pick up the
correct statement(s).
(a) Total acceleration of the particle is 10 m/s2 at all times
(b) Path of the particle is parabolic
(c) Path of the particle straight line
(d)Minimum kinetic energy of the particle during the motion is non-zero
4. The coefficient of friction between the block and plank is and its value is such that block becomes
stationary with respect to plank before it reaches the other end. Then
m V0
M
(a) the work done by friction on the block is negative (b) the work done by friction on the plank is positive
(c) the net work done by friction is negative (d) net work done by the friction is zero
6. A meter scale lying horizontally on a frictionless table is struck by a ball as shown in the diagram. Which of
the following quantities is conserved for the ball-scale system-
Centre
r
7. A point object is moving with a velocity, v 0 = 2i$- 3j$ + 4k $ ; in front of a moving plane mirror whose
8. Inside conductor there is a cavity and a charge q is placed inside the cavity. Let E1 be the field due to
charge q at P. E2 be the field at P due to induced charge on the inner surface of cavity. E3 be the field at
P due the induced charge on the outer surface of conductor then
q
Cavity
(a) E1 + E2 + E3 = 0 (b) E1 + E2 = 0
(c) E1 + E3 = 0 (d) E3 = 0
Space For Rough Work
A disc of mass M and radius of curvature R is lying on a frictionless ground. A small ball of mass M moving on the
ground with a velocity V strikes the disc and collides with it. The coefficient of restitution being e .
9. Velocity of approach for the system (ball + disc) along line of impact is
(a) V (b) V sin
(c) V cos (d) zero
1. Two conducting objects one with charge of +Q and another with –Q are kept on x-axis at x = −3 m and
4
x = +4 m respectively. The electric field on the x-axis is given by 3Q x 2 + . What is the capacitance C
3
x
of this configuration of objects? Capacitance of this system is given by F . Find value of x.
119
2. In the circuit shown, r = 4, C = 2 F . Charge ( in C ) on the capacitor connected between 8 & 9 in
the steady state condition is ( x 3) C . Find value of x.
2
r r
C
5 6
C
r r r
r
1 9
r 3
r r r
7 8
I r
r
4
4
K
24V
3. Third overtone of a closed organ pipe of length 7 cm is in unison with fourth harmonic of an open organ
pipe. Find the length of open organ pipe, in cm.
4. Two spheres of volume 500 cc each but of relative densities 0.8 and 1.2 are
Relative density = 0.8
connected by the string and the combination is immersed in a liquid in
vertical position as in figure. Find the tension in the string (in Newton).
(g = 10 m/s2)
Relative density = 1.2
6. Two swimmers start a race. One who reaches the point C first on the
other bank wins the race. A makes his stroke in a direction of 37o to the
river flow with velocity 5 km/hr relative to water. B makes his strokes in
a direction 127o to the river flow with same relative velocity. River is
flowing with speed of 2 km/hr and is 100m wide. If tA and tB be the time
taken by A and B to reach the point C if the speeds of A and B on the
ground are 8 km/hr and 6km/hr respectively, find the value of
(tA − tB)/5.
7. The system is initially at rest if a particle of mass m strike the block with velocity 12 m/sec, and then sticks
to it find the speed of system just after the collision:
m
•
m
m
8. A convex lens of focal length 9 cm is placed 10 cm before Screen
Section – 1: CHEMISTRY
Part A – (i): (ONE OR MORE THAN OPTION CORRECT TYPE)
This section contains 08 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE THAN ONE is correct.
1. The potential (EMF) of a cell consisting of an anode of silver in 0.10 M − AgNO3 solution and a cathode
of Pt immersed in a solution of 1.6 M − Cr2O72− , 0.4 M − Cr 3+ and 0.1M − H +
A2 ( g ) → 2 A ( g ) ; K1 ( / h )=e
− +5
−1 RT
20000( / J )
B3 ( g ) → 3B ( g ) ; K 2 ( / h −1 ) = e
− +10
RT
Where K1 and K2 are the rate constants with respect to disappearance of A2 and B3 , respectively. One
mole, each of A2 ( g ) and B3 ( g ) , is taken in a 100 litre. evacuated flask and at some temperature at
which they start decomposing at the same rate. The incorrect information regarding the reactions is:
1200
(a) The temperature at which the reactions are performed is K
8.314
PA2
(b) At any instant, will be constant and equal to 1.0, where PA2 and PB3 are the partial pressures
PB
2
of gases at that time.
(c) At some instant, the total pressure of all gases in the flask may be less than 0.2 atm
PA
(d) At any instant, will be constant and equal to 1.0, where PA and PB are the partial pressure of
B
P
gases at that time.
3. The correct information regarding a solid element (atomic radius=r) having ABCABC.... type packing
(FCC unit cell edge length =a) is:
3a
(a) The distance between nearest octahedral and tetrahedral void is
4
a
(b) The distance between two nearest octahedral void is
2
3a
(c) The distance between two nearest tetrahedral void is
2
2
(d) The distance between successive A and B layers is 2r.
3
4.
C6H5
Pyridine
H C OH + SOCl 2 A + HCl + SO2
H3C
( + ) - -Phenyl ethanol (optically pure)
Which of the following statement(s) are true regarding the above reaction.
(a) Product ‘A’ has opposite configuration to alcohol
(b) Product ‘A’ has same configuration as alcohol
(c) Product ‘A’ is leavo rotatory
(d) Product ‘A’ is dextro rotatory
O
CH3
6. H2N O
⎯⎯⎯⎯→
1. NaOH , Br2
2. H + ,
product
H3C CH3
The main product is.
(a) O (b) H
N
HO O
O
OH
(c) O (d) O
NH H2N O
OH
O
+
H3O/Hg2+
7. CH3 A (major)
O2N
The compound ‘A’ cannot be
(a) (b) O
CH3
CH3
O
NO2
NO2
(c) (d) O
CH3
CH3
O2N O
O2N
A volume of 100 ml of 0.1M − H3 PO4 solution is titrated with 0.5 M − NaOH solution till the second
equivalence point. Then 10 ml of 0.5 M − HCl solution is mixed in the resulting solution. The dissociation
−13
constants of H 3 PO4 are 10−3 ,10−8 and 10 .
The solubility product of base A ( OH ) 2 is 4.0 10 . Its solubility in the final solution is:
−30
10.
−10 −16
(a) 10 M (b) 4.0 10 M
−18 −22
(c) 4.0 10 M (d) 4.0 10 M
Space For Rough Work
A water soluble salt ‘A’ on strong heating gives a reddish brown coloured gas and a colourless gas leaving a grey
residue. On addition of dilute HCl to an aqueous solution of A, a white precipitate ‘B’ is formed. ‘B’ is insoluble in
both cold & hot water. The precipitate ‘B’ when treated with NH4OH forms a black residue ‘C’. ‘C’ is soluble in
aquaregia and forms a compound ‘D’ with evolution of N2. When KI is added drop wise to a solution of ‘D’ a red
precipitate ‘E’ is formed which is soluble in excess KI due to the formation of a soluble compound ‘F’
2+
1. A Solution of 0.2g of a compound containing Cu and C2O42− ions on titration with 0.02 M − KMnO4
in the presence of H 2 SO4 consumes 22.6 ml of the oxidant. The resultant solution is neutralized
with Na2CO3 , acidified with dilute acetic acid and treated with KI. The liberated iodine requires 11.3 ml
2+
of 0.05M − Na2 S2O3 for complete reduction. If the molar ratio of Cu to C2O42− in the compound is
1: x, the value of x is?
−8
2. The average life time for then n = 3 excited state of a hydrogen-like atom is 4.8 10 s and that for the
n = 2 state is 1.28 10−7 s . Ratio of the average number of revolutions made in the n = 3 state to the
average number of revolutions made in the n = 2 state before any transitions can take place from these
states in 1: x . The value of x is…..
3. The total number of isomers (structural as well as stereo) possible for dichlorocyclopentane are ____
⎯⎯⎯⎯⎯
CHCl3 / KOH
H O+
→ A ⎯⎯⎯⎯⎯
(H3CCO)2 O
H3CCOONa,
→ B
4. 3
(Major Pr oduct)
5. Which statement shows the correct stability order of the complexes [Fe(H 2O)6 ]3+ , [Fe(NH3 ) 6 ]3+ ,
[Fe(en)3 ]3+ & [FeCl6 ]3− .
I. [Fe(H 2O)6 ]3+ II. [Fe(NH3 ) 6 ]3+
III. [Fe(en)3 ]3+ IV. [FeCl6 ]3−
(1) I < IV < II < III
(2) I < IV < III < II
(3) IV < I < II < III
(4) IV < I < III < II
OH
6. HIO4
⎯⎯⎯ → A + B
CH2OH
Total number of lone pairs present in products A and B is……
a + sin x − 1
t
2. If f ( x ) = lim ; x ( 0, 6 ) , then:
a + sin x + 1
t → t
x
3. If f ( x ) = t −1dt, where 0 x 2, then:
0
4. If z lies on the circle centred at origin. If area of the triangle whose vertices are z , wz and z + wz,
where w is the cube root of unity, is 4 3 sq. units. Then radius of the circle is:
(a) 1 (b) 2
(c) 3 (d) 4
5. Consider a circle with its centre lying on the focus of the parabola y 2 = 2 px such that it touches the
directrix of the parabola, then a point of intersection of the circle and the parabola is:
p p
(a) , p (b) ,−p
2 2
−p −p
(c) , p (d) ,−p
2 2
x2 y 2
6. If the tangent at the point ( a sec , b tan ) to the hyperbola − = 1 meets the transverse axis at
a 2 b2
T, then the distance of T from a focus of the hyperbola is:
(a) a ( e − cos ) (b) b ( e + cos )
K .6K + 2 K +1.3K 1
1. If the sum of the series 3 .2
K =1
K 2 K +1
= , then S is equal to…………………?
( K + 1) .K S
2. Two non-negative integers are chosen at random from the set of non-negative integers with replacement.
p
If the probability that the sum of their squares is divisible by 10 is , then q − 5 p = ………………?
q
3. Tangents are drawn to the incircle of ABC which are parallel to its sides. If x, y, z are the length of the
tangents intercepted between the sides of triangle and a, b, c that of sides BC , CA and AB
2x 2 y 2z
respectively, then + + = ……………?
a b c
n
Ck cos kx.cos ( n + k ) x + sin ( n − k ) x.sin ( 2n − k ) x = ( 2n − k ) cos nx ……..?
k =1
5. If a circle S ( x, y ) = 0 touches at the point ( 2,3) of the line x + y = 5 and S (1, 2 ) = 0 , then radius of
1
such circle is units, then k is equal to………….?
k
6. The equation of the largest circle with centre (1, 0 ) that can be inscribed in the ellipse x2 + 4 y 2 = 16 is
p
( x − 1) + y2 =
2
(where p and q are coprime), then p − q is…………..?
q
7. ( )(
Non-zero vectors a , b , c satisfy a.b = 0 , b − a . b + c = 0 and 2 b + c = b − a . If a = b + 4c , )
then the maximum possible value of is……………….?
dy (x 2
− 1)( y 2 − 1)
8. The curve passing through the point (1,1) satisfies the differential equation + = 0.
dx xy
If the curve passes through ( 2, k ) then the value of k is (where . represents greatest integer
function)……………?
Space For Rough Work
1. A
2. CD
3. ABD
4. A
5. AB
3SO2 + O3 → 3SO3
3SnCl2 + 6HCl + O3 → 3SnCl4 + 3H2O
6. B
NaOH, Br2 serve as reagents for two important reactions. Hofmann bromamide as well Bromoform test.
O
NH2
O O
H2N ⎯NaOH
⎯⎯ ⎯→
, Br2 +CHBr3
O–
H+
H
NH2 N
O ⎯−⎯⎯→ O
H 2O
OH
7. ABD
8. CD
CuSO4 + 2KCN ⎯⎯
→ Cu(CN)2 + K2SO4
Cu(CN)2 + CN ⎯⎯
-
→ CuCN + (CN)2 cyanogen
CuCN + 3KCN ⎯⎯→ K3[Cu(CN)4]
9. D
10. C
11. B
12. B
[Integer Questions]
1. [2]
2. [9]
3. [7]
Cl Cl
Cl Cl
Cl Cl
Cl Cl Cl
Cl
Cl Cl
Cl
Cl
5. [3]
6. [4]
O + HCHO
7. [9]
3 + 2 + 1.5 + 2.5
8. [2]
3Cu + 8HNO3 → 3Cu ( NO3 )2 + 2 NO + 4 H 2O
1. C
Putting x = f ( y ) = 0
We get f ( 0 ) = 1
Again, putting x = f ( y ) =
2
We get f ( ) = 1 −
2
2. ABCD
Given function is discontinuous when a + sin x = 1
If a = 1, then sin x = 0 or x = 1, 2,3, 4,5
If a = 3, then sin x = −2, not possible
If a = 0.5, then sin x = 0.5, x has 6 value
1 3 5 7 9 11
If a = 0, then sin x = 1 or x = , , , , ,
2 2 2 2 2 2
3. ABD
x2
x − ,0 x 1
f ( x) = 2 2
x − x + 1 ,1 x 2
2
1 − x , 0 x 1
f '( x) =
x − 1 ,1 x 2
f ( x ) is continous as well as differentiable at x=1
Also, f ( x ) = cos x has one real root
2
( z + wz ) C
A( z)
( wz ) B
O
`
2
AOB =
3
OAB ABC
Area of ABC = Area of OAB
1 2
z wz sin =4 3
2 3
z =4
5. AB
Radius of the circle = distance between focus and directrix
= semi latus vertex
=P
Equation of circle is
2
P
x− + y = P
2 2
2
Solving with y 2 + 2 Px
P 3P
We get, x = , x = −
2 2
Hence y = P
6. AC
Equation of tangent at ( a sec , b tan ) is
x y
sec − tan = 1
a b
Which meets the transverse axis at ( a cos , 0 )
Distance = ae − a cos & ae + a cos
7. D
On solving:
2
= cos2 B cos2 C − cos2 A − sin 2 B sin 2 C + 2cos A sin B sin C
a
= cos A ( −2sin B sin C ) + 2cos A sin B sin C = 0
a2
8. ABCD
4 1 8
P1 = , P2 = , P3 =
29 2 29 29
Paragraph Questions (09-10)
/2
f ( x) − sin x cos tf (t )dt = sin x
0
( A + 1)
A=
2
2
f ( x) = sin x
2−
2
Now, sin x = 2
2−
1 3
[Integer Type]
1. [2]
k +2
1 2 1
k =1 2
k +1
= k +1
−
k ( k + 1) k =1 2 k k + 1
1 1 1
lim − k +1 =
k → 2
2 ( k + 1) 2
2. [5]
The digits in the units place of x2 as well as y2 can be from 0,1, 4,5, 6,9
18 9
P(E) = =
100 50
3. [2]
A
x
D E
F I
O z
y
B C
G H
x AE AD
= =
sin A sin B sin C
FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7042202900/8800309344
FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448
4. [2]
n −1
n
Ck cos kx.cos ( n + k ) x + sin ( n − k ) x.sin ( 2n − k ) x = ( 2n − k ) cos nx − − − − − (1)
k =1
n −1 n
Ck
LHS = cos ( n + 2k ) k − cos ( 3n − 2k ) x + 2 cos n x
k =1 2
n −1
= n Ck 4sin x cos nx sin ( n − 2k ) x + 2 cos nx
k =1
n −1 n −1
= n Ck cos nx cos 2kx − cos ( 2 ( n − k ) x ) + n Ck cos nx
k =1 k =1
n −1
= n Ck cos nx
k =1
= cos nx ( 2n − 2)
5. [2]
Family of circle, ( x − 2) + ( y − 3) + ( x + y − 5) = 0
2 2
Since, S (1, 2 ) = 0
Circle is x2 + y 2 − 3x − 5 y + 8 = 0
1
Radius =
2
6. [8]
On solving
11
( x −1) + y2 =
2
7. [5]
FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9650037427/7042202900/8800309344
FIITJEE Ltd, 1st Floor, Hotel Building, Wegmans Business Park, KP-III, Surajpur Kasna Rd, Greater Noida-201308 Ph: 9599596524 / 9871113448
y 2 −1 = − x2 − 1 + sec−1 x + c