CHEMISTRY

Chapters : Std 12 : Chemistry Date : 12/06/22

Total Marks : 40 Practice paper halo Time : 01 hour

//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [30]
1. The two optical isomers given below are namely ?
(A) Enantiomers CH3 CH3
(B) Diastereomers H Cl H Cl
(C) Position isomers Cl H H Cl
(D) Meso compound CH2CH3 CH2CH3

2. Which of the following is most reactive towards nucleophilic substitution reaction ?

(A) CH2 = CH – Cl (B) C6H5Cl
(C) CH3CH = CHCl (D) ClCH2 – CH = CH2
3. Which of the following Fisher projection formula is identical to D-glyceraldehyde ?

CH2OH CHO CHO

CH2OH
CH 2OH
(A) HO CHO (B) HO (C) H OH (D) H CH 2OH
H H OH
CHO
4. 3-Phenylpropene on reaction with HBr gives (as a major product)
(A) C6H5CH2CH(Br)CH3 (B) C6H5CH(Br)CH2CH3
(C) C6H5CH2CH2CH2Br (D) C6H5CH(Br)CH = CH2
5. Which of the following compounds has the highest boiling point ?
(A) CH3CH2CH2Cl (B) CH3CH2CH2CH2Cl (C) CH3CH(CH3)CH2Cl (D) (CH3) C Cl
6. The major product formed in the following reaction is....
CH3CH(Cl)CH2 – CH2OH¾¾¾¾¾ aq. KOH
®
(A) CH3CH = CHCH2OH (B) CH2 = CH – CH2CH2OH
(C) CH3 – CH – CH 2 (D) CH 3 – CH – CH 2 CH 2OH
|
O CH2 OH
7. 3-methylbut-1-ene on reaction with HBr gives (as major product) ?
(A) (CH3)2 CHCH2CH2Br (B) (CH3)2 CBrCH2 CH3
(C) (CH3)2 CHCH Br CH3 (D) (CH3)3 CCH2 Br
8. A : Chloral reacts with phenyl chloride to form DDT.
R : It is an electrophilic substitution reaction.
(A) Both assertion and reason are correct, reason is correct explanation of the assertion.
(B) Both assertion and reason are true but reason is not a correct explanation of the assertion.
(C) The assertion is true but reason is false.
(D) Both assertion and reason are false.
9. A compound is formed by substitution of two chlorine for two hydrogens in propane. The number
of possible isomeric compounds is....
(A) 4 (B) 3 (C) 5 (D) 2
10. Which of the following compound possess antiseptic properties ?
(A) Dichloro methane (B) Triflouro methane
(C) Tri Iodo methane (D) Tetrachloro methane
11. In presence of which compound, benzene reacts with I2 to give iodo benzene ?
(A) HNO3 (B) HI (C) SO2 (D) H2O
12. In the following reactions, the final product B is....
KCN H+/H2O
CH3Cl ¾¾¾¾ ® A ¾¾¾¾¾ ® B
(A) CH 3COOH (B) H COOH (C) CH3NH2 (D) CH3COCH3
13. When you heat chloroform with silver powder ....... is formed.
(A) ethene (B) ethyne (C) methane (D) ethane
14. ......... is obtained when 1-chloro butane reacts with alcoholic potash ?
(A) 1-butanol (B) 2-butene (C) 1-butene (D) 2-butanol
15. Which of the following reaction is true for preparation of methyl flouride ?
(A) CH4 + HF ¾® (B) CH3OH + HF ¾® (C) CH4 + F2 ¾® (D) CH3Br + AgF ¾®
16. Chlorobenzene reacts with sodium metal in presence of dry ether to prepare diphenyl the name of
the reaction is...
(A) Fittig reaction (B) Wurtz-Fittig reaction
(C) Sandmeyer reaction (D) Gattermann reaction
17. Which of the following compound doesn’t hydrolyse by SN1 mechanism ?
(A) CH2 = CHCH2Cl (B) C6H5Cl (C) C6H5CH2Cl (D) C6H5CH(CH3) Cl
18. Which of the following is a nucleophilic substitution reaction ?
(A) HNO3 (B) HI (C) SO2 (D) H2O
19. Which of the following shows optical isomerism ?

H H CH3 CH3
| | | |
(A) HO - C - CO2 H (B) H3 C – C – CO 2H (C) H3 C – C – CO2 H (D) H3 C – C – CO2 H
| | | |
H OH H Cl
20. The (R) – (S) – enantiomers of an optically active compound differ in...
(A) their reactivitiy with achiral reagents.
(B) their optical rotation of plane polarized light.
(C) their melting points.
(D) their solubility in achiral reagents.
21. Isopropyl chloride undergoes hydrolysis by...
(A) SN1 mechanism (B) SN2 mechanism
(C) SN1 and SN2 mechanisms (D) Neither SN1 nor SN2 mechanism
22. When primary amine reacts with chloroform in ethanolic KOH, then product is ..........
(A) an isocyanide. (B) an aldehyde. (C) an cyanide. (D) an alcohol.
23. Which of the following is least reactive in a nucleophilic substitution reaction ?
(A) (CH3)3 C – Cl (B) CH2 = CHCl (C) CH3CH2Cl (D) CH2 = CHCH2Cl
24. Which represents nucleophilic aromatic substitution reaction ?
(A) Reaction of benzene with Cl2 in sunlight
(B) Benzyl bromide hydrolysis
(C) Reaction of NaOH with dinitro fluoro benzene
(D) Sulphonstion of benzene
25. Which of the following compounds is not chiral ?
(A) 1-chloropentane (B) 2-chloropentane
(C) 1-chloro 2-methylpentane (D) 3-chloro-2-methylpentane
26. For the following : (a) I– (b) Cl– (c) Br–the increasing order of nucleophilicity would be...
(A) Br– < Cl– < I– (B) I– < Br– < Cl– (C) Cl– < Br– < I– (D) I– < Cl– < Br–
27. Which of the following is correct order of decreasing SN2 reactivity ?
(A) R2CHX > R3CX > RCH2X (B) RCH2X > R3CX > R3CX
(C) RCH2X > R2CHX > R3CX (D) R3CX > R2CHX > RCH2X (X = halogen)
28. CH 3 – CHCl – CH 2 – CH 3 has a chiral centre. Which one of the following represents its
R-configuration ?
C2H5 CH 3 C2H5 C2H5
| | | |
(A) H – C – CH3 (B) H – C – Cl (C) Cl – C – CH3 (D) H3C – C – Cl
| | | |
Cl C 2 H5 H H
NH2
NaNO 2 HBF4
29. In the chemical reaction, A B the compounds A’ and ‘B’ respectively are...
HCl 278K
(A) Nitrobenzene and chlorobenzene
(B) Nitrobenzene and fluorobenzene
(C) Phenol and Benzene
(D) Benzene diazonium chloride and fluoro-benzene
30. Which of the following is a nucleophilic substitution reaction ?
H+
(A) CH3 – CH = CH2 + H2O¾¾¾ ® CH 3 – CH – CH 3
|
OH

(B) R – CHO + R' – MgX ® R – CH – R'

|
OH

(C) R – CH 2 – CH – CH 2Br + NH3 ® CH 3 – CH2 – CH – CH2 NH2

| |
CH3 CH3

(D) CH3CHO + HCN ® CH 3 – CH – CN

|
OH