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1 s2.0 S0196890406001981 Main
1 s2.0 S0196890406001981 Main
www.elsevier.com/locate/enconman
Received 6 November 2005; received in revised form 27 May 2006; accepted 15 June 2006
Available online 17 August 2006
Abstract
A theoretical model is developed to simulate the heat and mass transfer processes in a cross flow dehumidifier/regenerator using liquid
desiccant. The model depends on NTU as input parameter, and NTU can be correlated based on the corresponding experimental data.
The model is able to predict the air and desiccant parameters inside the dehumidifier/regenerator, as well as the outlet parameters, with
known inlet parameters. The calculated results are compared with the experimental findings. For the total 284 groups of dehumidifica-
tion experimental data with different module sizes, the average absolute discrepancies for enthalpy effectiveness and moisture effective-
ness are 7.9% and 8.5%, respectively. For the 82 groups of regeneration experimental results, the average discrepancies for enthalpy and
moisture effectiveness are 5.8% and 6.9%, respectively. The distributions of desiccant outlet temperatures are measured during both the
dehumidification and regeneration processes, and the temperatures predicted by the theoretical model agree well with the experimental
results.
2006 Elsevier Ltd. All rights reserved.
Keywords: Liquid desiccant; Cross flow; Heat and mass transfer; Model; Experiment
0196-8904/$ - see front matter 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.enconman.2006.06.002
X.H. Liu et al. / Energy Conversion and Management 48 (2007) 546–554 547
Nomenclature
counter flow and cross flow dehumidifiers, respectively, ator. The model is validated by a large number of
while no attempt was made for adiabatic cross flow dehu- dehumidification and regeneration experimental data,
midifiers. In complicated models [15–20], the velocity field including device overall effectiveness and desiccant outlet
within the dehumidifier is first gained by solving the com- temperature distributions. The model can express the tem-
bined continuity and momentum equations, and then, the perature and concentration field distributions inside the
temperature and concentration fields are obtained by solv- dehumidifier/regenerator, which can be used in the optimi-
ing the energy and mass balance equations. zation of the devices.
Complicated models consume much time and require
large computational memory, hence, the simplified model 2. Theoretical model
is adopted in the present study. The objective of this paper
is to establish a model for the heat and mass transfer pro- The schematic of the adiabatic cross flow module (serves
cesses inside the adiabatic cross flow dehumidifier/regener- as dehumidifier or regenerator) is shown in Fig. 1. The
Table 1
Previous work on heat and mass transfer models in dehumidifier
Dehumidifier Simplified model Complicated model
Counter flow configuration Adiabatic Factor and Grossman [6]a Grossman [15]
Gandhidasan et al. [7]a Ali et al. [16]
Stevens et al. [8]a
Sadasivam and Balakrishnan [9]a
Khan [10]
Potnis and Lenz [11]a
Oberg and Goswami [4]a
Chung and Wu [12]a
Internally cooled Jain et al. [13]a –
Cross flow configuration Adiabatic – Ali et al. [17]
Dai and Zhang [18]a
Internally cooled Khan [14]a Zografos & Petroff [19]
Park et al. [20]a
a
Predicted values by the model were compared with experimental results.
548 X.H. Liu et al. / Energy Conversion and Management 48 (2007) 546–554
With known NTU value and air and desiccant inlet tributions of air and desiccant parameters over the entire
parameters of mesh (i, j), solving Eqs. (11)–(15) can give computational domain.
the air and desiccant outlet parameters of this mesh, which However, the NTU value is difficult to obtain by pure
are equal to the air inlet parameters of mesh (i + 1, j) and theoretical analysis. Experimental data have to be used
desiccant inlet parameters of mesh (i, j + 1), respectively. for determining the NTU value.
The concrete procedures are as follows.
3. Dehumidification experimental data for validation
(a) Calculate air outlet enthalpy ha,i+1,j using Eq. (14)
and humidity ratio xa,i+1,j using Eq. (15). The schematic of the experimental setup [21] is shown in
(b) Calculate air outlet temperature Ta,i+1,j using air Fig. 3. The module is the core device in the experiment,
physical property, since air outlet enthalpy and which can serve as either dehumidifier or regenerator. A
humidity ratio are known. lithium bromide (LiBr) aqueous solution was used as the
(c) Calculate desiccant outlet mass flow rate m_ s;i;jþ1 and desiccant in the system. The Celdek structured packing
concentration ni,j+1 using Eqs. (12) and (13), was used in the module with a specific surface area of
respectively. 396 m2/m3 and flute height of 7 mm. The packing was
(d) Calculate the desiccant outlet enthalpy hs,i,j+1 using made of corrugated cellulose paper sheets with different
Eq. (11). flute angles, one steep (45) and one flat (45) that had been
(e) Calculate the desiccant outlet temperature Ts,i,j+1 bonded together. The measurement devices and corre-
using desiccant physical property, since desiccant sponding accuracies were shown in Table 2. The tempera-
enthalpy and concentration are already known. tures were measured using Pt RTD (resistance
temperature detectors), and the temperature readings were
Repeat the above procedures on the meshes in the fol- scanned and recorded by the data acquisition system (Agi-
lowing order: (1) calculate the outlet parameters of air lent 13970 A). The air humidity ratio was derived by the
and desiccant for mesh (1, 1), since air and desiccant inlet measured dry-bulb and wet-bulb temperatures, and the
parameters are all known; then calculate the outlet desiccant concentration was derived by the measured desic-
parameters for mesh (2, 1), since the air inlet parameters cant temperature and density.
for mesh (2, 1) are equal to the air outlet parameters of For the dehumidification experiment, two different sizes
(1, 1); and then the outlet parameters for mesh (3, 1), of modules (recorded as module A and B) were used. The
(4, 1) until mesh (M, 1); (2) for meshes (1, 2) to (M, 2), height (H), thickness (L) and width (W) of the packed
the outlet parameters can be gained similarly to those modules were 550 · 400 · 350 mm3 and 550 · 300 ·
for (1, 1) to (M, 1), since the desiccant inlet parameters 350 mm3 for module A and module B, respectively. The
are equal to the desiccant outlet parameters of (1, 1) to air and desiccant inlet parameters are shown in Table 3.
(M, 1) and (3) such processes are performed on meshes Totally 284 experimental runs (201 groups for module A,
(1, 3) to (M, 3), meshes (1, 4) to (M, 4), until meshes and 83 groups for module B) were conducted for the two
(1, N) to (M, N). Thus, the above model can give the dis- modules.
Packed module
Cooling coil Humidifier T Standard nozzle
Heater A Fan
H T T H T P
Sampling fan C Sampling fan
Rotor flowmeter
Solution
T
Heater B Valve
Cooling water
Flowmeter
T Temperature sensor
H Wet-bulb temperature Heat exchanger
sensor T
T
C Density sensor
C
P Pressure sensor Solution
Solution tank B Valve Solution pump tank A
Table 2
Specification of the different measuring devices
Parameters Devices Accuracy Operational range
Air flow rate Standard flow nozzles plus inclined differential manometer 1% 0–1600 m3/h
Air dry-bulb temperature Pt RTD 0.2 C 0–100 C
Air wet-bulb temperature Pt RTD 0.2 C 0–100 C
Solution flow rate Glass rotor flowmeter 2% 0–2500 l/h
Solution temperatures Pt RTD 0.2 C 0–100 C
Solution densities Specific gravity hydrometer 1 kg/m3 1300–1700 kg/m3
Table 3
Air and desiccant inlet parameters during the dehumidification experiment
Module Fa (kg/m2 s) Ta (C) xa (kg/kg) Fs (kg/m2 s) Ts (C) n (%)
A 1.58–2.43 24.7–33.9 0.010–0.021 2.12–4.55 20.1–29.5 42.6–54.8
B 1.74–2.50 25.4–35.4 0.0095–0.018 2.04–5.35 19.7–27.2 42.2–54.1
The mass transfer coefficient can be expressed by the Sh tively. Error analysis based on the accuracies of direct mea-
number. The form of the Sh correlation provided by Chung surements indicated that the uncertainties of the enthalpy
and Wu [12] is adopted with the constants newly fitted by and moisture effectivenesses were both within ±8%.
nonlinear regression of the present experimental data.
The final correlation becomes:
0:396 1:913
0:333 Fs n 80
Sh ¼ 0:0011 Re1:363
a Sca 1
Fa 100 +20%
0%
ð16Þ
60
Predicted values /%
model.
-20%
Table 4
Air and desiccant inlet and outlet parameters in dehumidification experiment for Figs. 5 and 8
Fa (kg/m2 s) Ta (C) xa (kg/kg) Fs (kg/m2 s) Ts (C) n (%)
Inlet parameters 1.97 31.7 0.013 3.08 22.9 45.7
Outlet parameters by experiment – 26.9 0.0099 – 27.8 45.7
Outlet parameters by simulation – 27.6 0.010 – 27.5 45.6
Table 5
Air and desiccant inlet parameters during the regeneration experiment
Module Fa (kg/m2 s) Ta (C) xa (kg/kg) Fs (kg/m2 s) Ts (C) n (%)
A 1.37–2.19 28.6–38.8 0.012–0.022 2.47–4.48 47.5–62.7 38.4–54.0
552 X.H. Liu et al. / Energy Conversion and Management 48 (2007) 546–554
80 50
+20%
0% 48
60
Predicted values /%
-20%
46
Ts,out /°C
40
44
20 Predicted values
42
Experimental results
0 40
0 20 40 60 80 0 0.1 0.2 0.3 0.4
Experimental results /%
z /m
Table 6
Air and desiccant inlet and outlet parameters in regeneration experiment for Fig. 7
Fa (kg/m2 s) Ta (C) xa (kg/kg) Fs (kg/m2 s) Ts (C) n (%)
Inlet parameters 1.41 35.4 0.021 2.77 57.3 47.1
Outlet parameters by experiment – 46.6 0.031 – 46.1 47.6
Outlet parameters by simulation – 46.2 0.031 – 46.3 47.4
X.H. Liu et al. / Energy Conversion and Management 48 (2007) 546–554 553
Fig. 8. Temperature and concentration distributions in the dehumidifier with inlet parameters shown in Table 4: (a) air temperature; (b) air humidity ratio;
(c) desiccant temperature and (d) desiccant concentration (H = 0.55 m, L = 0.40 m).
In the case corresponding to Fig. 8, the maximum the corresponding experimental findings. In the present
temperature and humidity ratio differences of air in the analysis, NTU is correlated from the dimensionless correla-
transverse direction of the air flow are as high as tion provided by Chung and Wu with the constants newly
2.7 C and 1.5 g/kg, while the maximum temperature fitted by nonlinear regression of the present experimental
and concentration differences of desiccant in the trans- data.
verse direction of the desiccant flow are as high as Good agreement is shown between the calculated results
2.9 C and 0.1%. Other cases have similar situations, with the experimental findings. For the total 284 groups of
including the regeneration processes. That suggests the dehumidification experimental data, the average absolute
differences of air temperature and humidity ratio in the discrepancies for enthalpy effectiveness and moisture effec-
transverse direction of the air flow can not be neglected. tiveness are 7.9% and 8.5%, respectively. For the 82 groups
The desiccant temperature difference in the transverse of regeneration experimental results, the average discrepan-
direction of the desiccant flow can not be neglected cies for enthalpy and moisture effectiveness are 5.8% and
either, while the desiccant concentration difference in 6.9%, respectively. The predicted distributions of the desic-
the transverse direction of the desiccant flow can be rea- cant outlet temperatures by the theoretical model agree
sonably neglected. well with both the dehumidification and regeneration
experimental results.
6. Conclusion Based on the analysis of air and desiccant temperature
and concentration fields, the desiccant concentration differ-
A two dimensional theoretical model for the cross flow ence in the transverse direction of the desiccant flow can be
dehumidifier/regenerator is established in this paper, where reasonably neglected, while the differences of air tempera-
Le and NTU should be taken as input values. Le is ture, air humidity ratio and desiccant temperature in their
assumed to be one, while NTU should be determined by flow transverse directions can not be neglected.
554 X.H. Liu et al. / Energy Conversion and Management 48 (2007) 546–554
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