Sure Shot 80+ Challenges-ALL Three

#Challenge-1
Given below are two statements:

Statement I: Fluorine has most negative electron gain enthalpy in its
group.
Statement II: Oxygen has least negative electron gain enthalpy in its
group.
In the light of the above statements, choose the most appropriate
from the options given below.
A Both Statement I and Statement II are true
B Statement I is true but Statement II is false
C Both Statement I and Statement II are false
D Statement I is false but Statement II is true

Statement – I: Along the period, the chemical reactivity of the
element gradually increases from group 1 to group 18.
Statement – II: The nature of oxides formed by group 1 element is
basic while that of group 17 elements is acidic.
In the the light above statements, choose the most appropriate from
the questions given below :
A Both statement I and Statement II are true.
B Statement I is true but Statement II is False.
C Statement I is false but Statement II is true.
D Both Statement I and Statement II is false.

Statement (I) : The NH2 group in Aniline is ortho and para directing
and a powerful activating group.
Statement (II) : Aniline does not undergo Friedel- Crafts reaction
(alkylation and acylation).
answer from the options given below :
A Both Statement I and Statement II are correct
B Both Statement I and Statement II are incorrect
C Statement I is incorrect but Statement II is correct
D Statement I is correct but Statement II is incorrect

Given below are two statements :
Statement (I) : p-nitrophenol is more acidic than m-nitrophenol
and o-nitrophenol.
Statement (II) : Ethanol will give immediate turbidity with Lucas
reagent.
In the light of the above statements, choose the correct answer
from the options given below :
A Statement I is true but Statement II is false
B Both Statement I and Statement II are true

Statement (I) : Aminobenzene and aniline are same organic
compounds.
Statement (II) : Aminobenzene and aniline are different organic
compounds.
In the light of the above statements, choose the most
appropriate answer from the options given below:
B Statement I is correct but Statement II is incorrect
D Both Statement I and Statement II are incorrect

Given below are two statements : one is labelled as
Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Haloalkanes react with KCN to form alkyl
cyanides as a main product while with AgCN form isocyanide
as the main product.
Reason (R) : KCN and AgCN both are highly ionic compounds.
In the light of the above statement, choose the most
appropriate answer from the options given below :
A (A) is correct but (R) is not correct
B Both (A) and (R) are correct but (R) is not the correct
explanation of (A)
C (A) is not correct but (R) is correct
D Both (A) and (R) are correct and (R) is the correct explanation of (A)
Choose the correct statements about the hydrides of group 15 elements.
A. The stability of the hydrides decreases in the order NH3 > PH3 > AsH3 > SbH3 > BiH3
B. The reducing ability of the hydrides increases in the order NH3 < PH3 < AsH3 < SbH3 < BiH3
C. Among the hydrides, NH3 is strong reducing agent while BiH3 is mild reducing agent.
D. The basicity of the hydrides increases in the order NH3 < PH3 < AsH3 < SbH3 < BiH3
Choose the most appropriate from the option given below :
A B and C only B C and D only
C A and B only D A and D only

Statement I: S8 solid undergoes disproportionation reaction
under alkaline conditions to form S2- and S2O32-
Statement II: ClO4- can undergo disproportionation reaction
under acidic condition.
A Statement I is correct but statement II is incorrect.
B Statement I is incorrect but statement II is correct
C Both statement I and statement II are incorrect
D Both statement I and statement II are correct

Statement I: Aniline reacts with con. H2SO4 followed by heating at 453-473
K gives p-aminobenzene sulphonic acid, which gives blood red colour in
the 'Lassaigne's test'.
Statement II: In Friedel - Craft's alkylation and acylation reactions, aniline
forms salt with the AlCl3 catalyst. Due to this, nitrogen of aniline aquires a
positive charge and acts as deactivating group. In the light of the above
statements, choose the correct answer from the options given below :
A Statement I is false but statement II is true
B Both statement I and statement II are false
C Statement I is true but statement II is false
D Both statement I and statement II are true

Statement-I: Since fluorine is more electronegative than nitrogen, the net
dipole moment of NF3 is greater than NH3.
Statement-II: In NH3, the orbital dipole due to lone pair and the dipole moment
of NH bonds are in opposite direction, but in NF3 the orbital dipole due to lone
pair and dipole moments of N-F bonds are in same direction.
In the light of the above statements. Choose the most appropriate from the
options given below.
A Statement I is true but Statement II is false.
B Both Statement I and Statement II are false.
C Both statement I and Statement II is are true.
D Statement I is false but Statement II is are true.

Statement – I: High concentration of strong nucleophilic reagent with
secondary alkyl halides which do not have bulky substituents will
follow SN2 mechanism.
Statement – II: A secondary alkyl halide when treated with a large
excess of ethanol follows SN1 mechanism.
In the the light of the above statements, choose the most appropriate
from the questions given below :
B Statement I is false but Statement II is true.
C Both statement I and Statement II are false.
D Both statement I and Statement II are true.

Given below are two statements: One is labelled as Assertion A
and the other is labelled as Reason R.
Assertion A : H2Te is more acidic than H2S.
Reason R: Bond dissociation enthalpy of H2Te is lower than H2S.
In the light of the above statements. Choose the most
appropriate from the options given below.
Both A and R are true but R is NOT the correct

A
explanation of A.
Both A and R are true and R is the correct

B
explanation of A.
C A is false but R is true.
D A is true but R is false.

Choose the correct statements from the following
A. All group 16 elements form oxides of general formula EO2 and
EO3 where E = S, Se, Te and Po. Both the types of oxides are
acidic in nature.
B. TeO2 is an oxidising agent while SO2 is reducing in nature.
C. The reducing property decreases from H2S to H2Te down the
group.
D. The ozone molecule contains five lone pairs of electrons.
Choose the correct answer from the options given below:
A A and D only B B and C only
C C and D only D A and B only

Given below are two statements: one is labelled as Assertion
(A) and the other is labelled as Reason (R).
Assertion (A) : PH3 has lower boiling point than NH3.
Reason (R) : In liquid state NH3 molecules are associated
through van der waal’s forces, but PH3 molecules are
associated through hydrogen bonding.
A Both (A) and (R) are correct and (R) is not the
correct explanation of (A)
B (A) is not correct but (R) is correct
Both (A) and (R) are correct but (R) is the

C
D (A) is correct but (R) is not correct

Statement (I) : Potassium hydrogen phthalate is a primary
standard for standardisation of sodium hydroxide solution.
Statement (II) : In this titration phenolphthalein can be used as
indicator.

Challenge-#1
Part-2
Statement (I) : Angular quantum number determines the three
dimensional shape of the orbital.
Statement (II) : The principal quantum number determines the
orientation and energy of the orbital.
A Statement I is false but Statement II is true
C Statement I is true but Statement II is false
D Both Statement I and Statement II are false

Statement (I) : PH3 can act as a ligand in the formation of
coordination compound with transition elements.
Statement (II) :Single N–N bond is stronger than the single P–P
bond.

Statement (I) : Ionisation enthalpy of molecular oxygen is very
close to that of xenon.
Statement (II) :Only type of interactions between particles of
noble gases are due to weak dispersion forces.

Statement (I) : Order of a reaction is experimentally determined
quantity.
Statement (II) :The order of a reaction is always equal to the sum
of the stoichiometric coefficients of reactants in the balanced
chemical equation for a reaction

Statement (I) : Conductivity of solution depends upon size of ions.
Statement (II) : Conductivity of solution increases with temperature.
C Both Statement I and Statement II are incorrect
D Statement I is incorrect but Statement II is correct

Statement (I) : Molarity of a solution in liquid state changes with
temperature.
Statement (II) : The volume of a solution changes with change in
temperature.

Statement (I) : Aqueous solution of ammonium carbonate is basic.
Statement (II) : Acidic/basic nature of salt solution of a salt of weak
acid and weak base depends on Ka and Kb value of acid and the
base forming it.

Statement (I) : The 4f and 5f - series of elements are placed
separately in the Periodic table to preserve the principle of
classification.
Statement (II) :S-block elements can be found in pure form in
nature. In the light of the above statements, choose the most

Given below are two statements : one is labelled as Assertion (A)
and the other is labelled as Reason (R).
Assertion (A) : Melting point of Boron (2453 K) is unusually high in
group 13 elements.
Reason (R) : Solid Boron has very strong crystalline lattice.
appropriate answer from the options given below ;
Both (A) and (R) are correct but (R) Is not the correct
A
explanation of (A)
Both (A) and (R) are correct and (R) is the correct
B
explanation of (A)
C (A) is true but (R) is false
D (A) is false but (R) is true

Statement (I) : Copper sulphate can be stored in zinc vessel.
Statement (II) : Zinc is less reactive than copper.

Statement (I) : The rate of a reaction decreases with passage of
time as the concentration of reactants decreases.
Statement (II) :The rate of a reaction is same at any time during
the reaction.

Statement (I) : P4 molecule in white phosphorus have angular
strain therefore white phosphorus is very reactive.
Statement (II) :PCl5 is ionic in solid state in which cation is
tetrahedral and anion is octahedral.

Statement (I) : HI cannot be prepared by the reaction of KI with
concentrated H2SO4
Statement (II) : HI has lowest H–X bond strength among halogen
acids.

Statement (I) : Actinoids form relatively less stable complexes
as compared to lanthanoids.
Statement (II) : Actinoids can utilise their 5f orbitals along with
6d orbitals in bonding but lanthanoids do not use their 4f orbital
for bonding.

Statement (I) : Boron has a smaller first ionisation enthalpy than
beryllium.
Statement (II) : The penetration of a 2s electron to the nucleus is
more than the 2p electron hence 2p electron is more shielded by
the inner core of electrons than the 2s electrons.

Challenge-#2
Set-1
The correct match between items I and II is
D
The distillation technique most suited for separating glycerol from
spent lye in the soap industry is
A fractional distillation
B steam distillation
C distillation under reduced pressure
D simple distillation
In chromatography, which of the following statements is INCORRECT for
Rf ?
A The value of Rf cannot be more than one.
B Higher Rf value means higher adsorption.
C Rf value is dependent on the mobile phase.
D Rf value depends on the type of chromatography.

Ethylamine and diethylamine cannot be differentiated by :
A Hinsberg test
B carbylamine test
C Iodoform test
D both (a) and (b)

Lassaigne's test is used for detection of :
A Nitrogen and Sulphur only
B Nitrogen, Sulphur and Phosphorus Only
C Phosphorous and halogens only
D Nitrogen, Sulphur, phosphorous and halogens

Which one of the following techniques is not used to
spot components of a mixture separated on thin layer
chromatographic plate?
A I2 (Solid)
B U.V. Light
C Visualisation agent as a component of mobile phase
D Spraying of an appropriate reagent

Which among the following purification methods is based on the
principle of “Solubility” in two different solvents?
A Column Chromatography
B Sublimation
C Distillation
D Differential Extraction
In Kjeldahl’s method for estimation of nitrogen,
CuSO4 acts as :
A Reducing agent
B Catalytic agent
C Hydrolysis agent
D Oxidising agent
On a thin layer chromatographic plate, an organic
compound moved by 3.5 cm, while the solvent
moved by 5 cm. The retardation factor of the
organic compound is _____ × 10-1
Which one of the following tests used for the identification of
functional groups in organic compounds does not use copper
reagent?
A Seliwanoff’s test
B Barfoed's test
C Benedict's test
D Biuret test for peptide bond

Match List-I with List-II
List-I Test/Reagents/ Observation(s) List-II Species detected
(a) Lassaigne's Test (i) Carbon
(b) Cu(II) oxide (ii) Sulphur
(c) Silver nitrate (iii) N, S, P, and halogen
(d) The sodium fusion extract gives black (iv) Halogen Specifically
precipitate with acetic acid and lead acetate
The correct match is:
A (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
B (a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
C (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
D (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

0.400 g of an organic compound (X) gave 0.376 g of
AgBr in Carius method for estimation of bromine % of
bromine in the compound (X) is__________.
(Given: Molar mass AgBr = 188 g mol-1 , Br = 80g mol-1 )
A (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
B (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
C (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
D (A)-(III), (B)-(IV), (C)-(I), (D)-(II)

The technique used for purification of steam volatile water
immiscible substance is :
A Fractional distillation
B Fractional distillation under reduced pressure
C Distillation
D Steam distillation
Match the following :
Test / Method Reagent
(i) Lucas Test (a)C6H5SO2Cl/aq. KOH
(ii) Dumas method (b) HNO3/ AgNO3
(iii) Kjeldahl’s method (c) CuO/CO2
(iv) Hinsberg test (d) Conc. HCl and ZnCl2
(e) H2SO4
A (i) - (b), (ii) - (d), (iii) - (e), (iv) - (a)
B (i) - (d), (ii) - (c), (iii) - (e), (iv) - (a)
C (i) - (b), (ii) - (a), (iii) - (c), (iv) - (d)
D (i) - (d), (ii) - (c), (iii) - (b), (iv) - (e)

Challenge-#2
Set-2
Statement I : A mixture of chloroform and aniline can be
separated by simple distillation.
Statement II : When separating aniline from a mixture of aniline
and water by steam distillation aniline boils below its boiling
point.
A Both statement I and statement II are false
B Both statement I and statement II are true
D Statement I is false but statement II is true

Match List I with List II
LIST I (Technique) LIST II (Application)
A. Distillation I. Separation of glycerol from
spent-lye
B. Fractional distillation II. Aniline - Water mixture
C. Steam distillation III. Separation of crude oil fractions
D. Distillation under reduced IV. Chloroform-Aniline
pressure
Choose the correct answer from the options given below :
A A-IV, B-I, C-II, D-III B A-IV, B-III, C-II. D-I
C A-I. B-II, C-IV, D-III D A-II, B-III. C-I, D-IV

Acetaldehyde and benzaldehyde can be
differentiated by :
A Fehling test
B Iodoform test
C Tollen’s reagent
D both (a) and (b)

‘Adsorption’ principle is used for which of the following
purification method?
A Extraction B Chromatography
C Distillation D Sublimation
The formula of the purple colour formed in Lassaigne's test for
sulphur using sodium nitroprusside is
A NaFe[Fe(CN)6]
B Na[Cr(NH3)2(NCS)4]
C Na2[Fe(CN)5(NO)]
D Na4[Fe(CN5)(NOS)]
p-nitrophenol and o-nitrophenol are separated by
A Crystallisation
B Fractional crystallisation
C Distillation
Using the provided information in the following paper
chromatogram :
The calculated Rf value of A ______ × 10–1
Paper chromatography for compounds A and B

Phenolic group can be identified by a positive :
A Phthalein dye test
B Lucas test
C Tollen’s test
D Carbylamine test
In Dumas method for the estimation of N2. the sample
is heated with copper oxide and the gas evolved is
passed over:
A Ni
B Pd
C Copper gauze
D Copper oxide
A, B and C are three biomolecules. The results of the tests performed on them are
given below
Molisch's Test Barfoed Test Biuret Test
A Positive Negative Negative
B Positive Positive Negative
C Negative Negative Positive
A, B and C are respectively
A A = Lactose, B = Fructose, C = Alanine
B A = Lactose, B = Glucose, C = Alanine
C A = Glucose, B = Fructose, C = Albumin
D A = Lactose, B = Glucose, C = Albumin

Chromatographic technique/s based on the
principle of differential adsorption is/are
A. Column chromatography
B. Thin layer chromatography
C. Paper chromatography
Choose the most appropriate answer from the options given below:
A B only B A only
C A & B only D C only

In a Dumas experiment, 0.5 g of an organic compound on
heating with copper oxide liberated 112 mL of N2 at STP. The
percentage of nitrogen (by weight) in the compound is:
A 70
B 35
C 14
D 28
Statement I : Retardation factor (Rf ) can be measured in
meter/centimeter.
Statement II : Rf value of a compound remains constant in all
solvents.
Choose the most appropriate answer from the options given
below :

The fragrance of flowers is due to the presence of some steam
volatile organic compounds called essential oils. These are
generally insoluble in water at room temperature but are
miscible with water vapour in vapour phase. A suitable
method for the extraction of these oils from the flowers is -
A crystallisation B distillation under reduced pressure
C distillation D steam distillation

Glycerol boils at 290o C with slight decomposition, impure glycerine can
be purified by:
A Steam distillation
B Simple distillation
C Vacuum distillation
D Extraction with a solvent

Challenge-#3
All ammonium salts liberate ammonia gas when :
A Heated with water
B Heated with caustic soda
C Heated with H2SO4
D
Heated with NaNO2
Element not showing variable oxidation state is :
A Bromine
B Iodine
C Chlorine
D Fluorine
The chromyl chloride test is meant for which of the following ion?
A Cl– ions
B Both Cl– and Br– ions
C I– ions
D
Cl– and CrO42– ions
Metal (M) shows crimson red colour in flame test and its halide is
deliquescent then metal (M) could be :
A Li
B Mg
C Ca
D
Ba
Hot conc. H2SO4 acts as moderately strong oxidising agent. It
oxidises both metals and non-metals. Which of the following
element is oxidised by conc. H2SO4 into two gaseous products?
A Cu
B S
C C
D Zn
In the wet tests for detection of various cations by
precipitation, Ba2+ cations are detected by obtaining
precipitate of
A Ba(ox) : Barium oxalate B BaCO3
C Ba(OAc)2 D BaSO4
Two inorganic compounds A and B were heated in a dry test tube.
A evolved a colourless gas which turned lead acetate paper black
and B evolved a gas which turned lime water milky. The anions A
and B respectively are :
A SO32-, CO32-
B S2-, CO32-
C PO43-, HSO3–
D
S2-, NO3–
A white precipitate was formed when BaCl2 was added to
water extract of an inorganic salt. Further, a gas ‘X’ with
characteristic odour was released when the formed white
precipitate was dissolved in dilute HCl. The anion present
in the inorganic salt is
A I– B SO32-
C S2- D NO2–
The total number of acidic oxides from the
following list is
NO, N2O, B2O3, N2O5, CO, SO3, P4O10
A 3
B 4
C 5
D 6
Find the total number of acidic radical which produce volatile
product with dil HCl :
(i) SO42- (ii) l- (iii) NO2– (iv) NO3–
(v) SO32– (vi) HCO3–
The ratio of sigma and 𝜋 bonds present in
pyrophosphoric acid is___________.
During the qualitative analysis of salt with cation y2+, addition of
a reagent (X) to alkaline solution of the salt gives a bright red
precipitate. The reagent (X) and the cation (y2+) present
respectively are :
A Dimethylglyoxime and Ni2+
B Dimethylglyoxime and Co2+
C Nessler’s reagent and Hg2+
D Nessler’s reagent and Ni2+

One mole of P4 reacts with 8 moles of SOCl2 to give 4
moles of A, x mole of SO2 and 2 moles of B. A, B and x
respectively are.
A PCl3,S2Cl2 and 4
B PCl3, S2Cl2 and 2
C POCl3, S2Cl2 and 2
D POCl3, S2Cl2 and 4

Affinity for hydrogen decreases in the group from fluorine to iodine.
Which of the halogen acids should have highest bond dissociation
enthalpy?
A HF
B HCl
C HBr
D HI
Wrong statement about Boron is
(a) It is found as Na2B4O7.10H2O and not as Na2B4O7. 4H2O
(b) Its Abundance in Earth’s crust is 10-3 %
(c) It has highest melting point in its group.
(d) It has highest boiling point in its group.
A a and b
B a,b and c
C b and c
D All of these
Solutions
#Challenge-1
group.
group.

group.
group.

Solution:
Statement-1 is false because chlorine has most

negative electron gain enthalpy in its group.


Solution:
Chemical reactivity of elements decreases along the period

therefore statement – I is false.
Group – 1 elements form basic nature oxides while group – 17
elements form acidic oxides therefore statement – II is true.


Solution:
The NH2 group in Aniline is ortho and para

directing and a powerful activating group as NH2 has
strong +M effect.
Aniline does not undergo Friedel-Crafts reaction
(alkylation and acylation) as Aniline will form complex
with AlCl3 which will deactivate the benzene ring.
and o-nitrophenol.
reagent.

and o-nitrophenol.
reagent.

Solution:
compounds.
compounds.

compounds.
compounds.

Solution:
Aniline is also known as amino benzene.

explanation of (A)
explanation of (A)
Solution:


Solution:


Solution:


Solution:


Solution:


Solution:

A
explanation of A.

B
explanation of A.


A
explanation of A.

B
explanation of A.

Solution:
Due to lower Bond dissociation enthalpy of H2Te it ionizes to give H+

more easily than H2S.
acidic in nature.
group.

acidic in nature.
group.

Solution:

C


C

Solution:
Unlike NH3, PH3 molecules are not associated

through hydrogen bonding in liquid state. That is
why the boiling point of PH3 is lower than NH3.
indicator.

indicator.

Solution:
Statement (I) : Potassium hydrogen phthalate is a primary standard for

standardisation of sodium hydroxide solution as it is economical and its
concentration does not changes with time.
Phenolphthalein can acts as indicator in acid base titration as it shows
colour in pH range 8.3 to 10.1
Challenge-#1
Part-2


Solution:
bond.

bond.

Solution:


Solution:
quantity.

quantity.

Solution:


Solution:
temperature.
temperature.

temperature.
temperature.

Solution:
base forming it.

base forming it.

Solution:
Aqueous solution of (NH4)2CO3 is Basic

pH of salt of weak acid and weak base depends on Ka and Kb
value of acid and the base forming it
classification.

classification.

Solution:
s-block elements are highly reactive and found in combined state.

group 13 elements.
A
explanation of (A)
B
explanation of (A)

group 13 elements.
A
explanation of (A)
B
explanation of (A)

Solution:
Solid Boron has very strong crystalline lattice so its melting point
unusually high in group 13 elements


Solution:
the reaction.

the reaction.

Solution:


Solution:
concentrated H2SO4
acids.

concentrated H2SO4
acids.

Solution:
for bonding.

for bonding.

Solution:
beryllium.

beryllium.

Solution:
Challenge-#2
Set-1
D
D
Solution:
Solution:

spent lye in the soap industry is distillation under reduced pressure.
This method allows for the separation of components at lower
temperatures, minimizing thermal degradation and preserving the
purity of glycerol.
Rf ?

Rf ?

Solution:
The Rf value is a measure of how far a compound travels in the

chromatography medium relative to the solvent front. A higher Rf
value actually indicates lower adsorption to the stationary phase,
allowing the compound to travel further with the mobile phase.
A Hinsberg test
B carbylamine test
C Iodoform test
D both (a) and (b)

A Hinsberg test
B carbylamine test
C Iodoform test
D both (a) and (b)

Solution:
Et — NH2 → -ve iodoform

Et — NH — Et → -ve iodoform


Solution:
Lassaigne's test is used for detection of all

element N, S, P, X.
A I2 (Solid)
B U.V. Light

A I2 (Solid)
B U.V. Light

Solution:
The function of mobile phase is to carry the components present on

TLC.
B Sublimation
C Distillation
B Sublimation
C Distillation
Solution:
Different Extraction
Different layers are formed which can be separated
in funnel.
CuSO4 acts as :
A Reducing agent
B Catalytic agent
C Hydrolysis agent
D Oxidising agent
CuSO4 acts as :
A Reducing agent
B Catalytic agent
C Hydrolysis agent
D Oxidising agent
Solution:
Kjeldahl’s method is used for estimation of Nitrogen

where CuSO4 acts as a catalyst.
Ans. 07
Solution:
reagent?
B Barfoed's test
C Benedict's test

reagent?
B Barfoed's test
C Benedict's test

Solution:
Seliwanoff’s test → Resorcinol dissolved in conc HCI.

All other test use copper based reagent.
A (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
B (a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
C (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
D (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

A (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
B (a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
C (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
D (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

Solution:
Ans: 40
Solution:
A (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
B (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
C (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
D (A)-(III), (B)-(IV), (C)-(I), (D)-(II)

A (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
B (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
C (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
D (A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Solution:
C Distillation
C Distillation
Solution:
Steam distillation is used for those liquids which

are insoluble in water, containing non-volatile
impurities and are steam volatile.
(e) H2SO4
A (i) - (b), (ii) - (d), (iii) - (e), (iv) - (a)
B (i) - (d), (ii) - (c), (iii) - (e), (iv) - (a)
C (i) - (b), (ii) - (a), (iii) - (c), (iv) - (d)
D (i) - (d), (ii) - (c), (iii) - (b), (iv) - (e)

(e) H2SO4
A (i) - (b), (ii) - (d), (iii) - (e), (iv) - (a)
B (i) - (d), (ii) - (c), (iii) - (e), (iv) - (a)
C (i) - (b), (ii) - (a), (iii) - (c), (iv) - (d)
D (i) - (d), (ii) - (c), (iii) - (b), (iv) - (e)

Solution:
Lucas Test - Conc. HCl/ZnCl2

Dumas method - CuO/CO2
Kjeldahl’s method - H2SO4
Hinsberg test - C6H5SO2Cl/aq. KOH
Challenge-#2
Set-2
point.

point.

Solution:
spent-lye
pressure

spent-lye
pressure

Solution:
A. Distillation IV. Chloroform-Aniline

B. Fractional distillation III. Separation of crude oil fractions
C. Steam distillation II. Aniline - Water mixture
D. Distillation under reduced I. Separation of glycerol from spent-lye
pressure
differentiated by :
A Fehling test
B Iodoform test
D both (a) and (b)

differentiated by :
A Fehling test
B Iodoform test
D both (a) and (b)

Solution:
Solution:
Principle used in chromatography is adsorption.

A NaFe[Fe(CN)6]
C Na2[Fe(CN)5(NO)]
D Na4[Fe(CN5)(NOS)]
A NaFe[Fe(CN)6]
C Na2[Fe(CN)5(NO)]
D Na4[Fe(CN5)(NOS)]
Solution:
S2- + [Fe(CN)5NO]2- → [Fe(CN)5(NOS)]4-
Purple
A Crystallisation
C Distillation
A Crystallisation
C Distillation
Solution:
p-Nitrophenol and o-nitrophenol can be separated by steam

distillation. This method works because p-nitrophenol has a lower
boiling point when steam is present, which helps in separating it
from o-nitrophenol more easily.
Using the provided information in the following paper
chromatogram :
The calculated Rf value of A ______ × 10–1
Paper chromatography for compounds A and B

Solution:
B Lucas test
C Tollen’s test
D Carbylamine test
B Lucas test
C Tollen’s test
D Carbylamine test
Solution:
Carbylamine Test-Identification of primary amines

Lucas Test - Differentiation between 1°, 2° and 3° alcohols
Tollen's Test - Identification of Aldehydes
Phthalein Dye Test - Identification of phenols
passed over:
A Ni
B Pd
C Copper gauze
D Copper oxide
passed over:
A Ni
B Pd
C Copper gauze
D Copper oxide
Solution:
given below

given below

Solution:
- All carbohydrates give, Molisch’s test

- Barfoed test is specific for monosaccharide
- Biuret test is used for detecting the presence of peptide bonds
A B only B A only

A B only B A only

Solution:
Column chromatography and Thin Layer Chromatography (TLC) are

based on the principle of differential adsorption, where substances
separate by their varying adsorption rates to a stationary phase. While
Paper chromatography involves separation through differential
partitioning rather than adsorption.
A 70
B 35
C 14
D 28
A 70
B 35
C 14
D 28
Solution:
meter/centimeter.
solvents.
below :

meter/centimeter.
solvents.
below :

Solution:
Retardation factor (Rf ) is the ratio of distance moved by the

substance from the base line to the distance moved by the solvent
from the baseline. So, it is dimensionless.
The distance moved by the substance is due to adsorption of the
substance on the stationary phase. It does not depend on the
nature of solvent. But the distance moved by the solvent will
change with the nature of solvent.
Therefore, Rf will vary with the change in solvent.
So, both the statements are false.


Solution:
Steam distillation technique is applied to separate

substances which are steam volatile and are
immiscible with water.
be purified by:

be purified by:

Solution:
Impure glycerol can be purified using vacuum distillation, where it's

heated under reduced pressure to prevent decomposition. This
process lowers the boiling point of glycerol, allowing it to be collected
in a pure form while leaving impurities behind.
Challenge-#3
A Heated with water
C Heated with H2SO4
D
Heated with NaNO2
A Heated with water
C Heated with H2SO4
D
Heated with NaNO2
Solution:
A Bromine
B Iodine
C Chlorine
D Fluorine
A Bromine
B Iodine
C Chlorine
D Fluorine
Solution:
Fluorine does not show variable oxidation state.

A Cl– ions
C I– ions
D
A Cl– ions
C I– ions
D
Solution:
Chromyl chloride test is applied for the detection of Cl– ion.

A Li
B Mg
C Ca
D
Ba
A Li
B Mg
C Ca
D
Ba
Solution:
A Cu
B S
C C
D Zn
A Cu
B S
C C
D Zn
Solution:
precipitate of
C Ba(OAc)2 D BaSO4
precipitate of
C Ba(OAc)2 D BaSO4
Solution:
Ba2+ belongs to Vth Group and hence they are precipitated with CO32- to give
ppt of BaCO3. In Wet tests for cations, (NH4)2CO3 is used as a group reagent
for fifth group cations (Ba2+, Ca2+, Sr2+)
Ba2+ + (NH4)2 CO3 → BaCO3 + NH4⊕
A SO32-, CO32-
B S2-, CO32-
C PO43-, HSO3–
D
S2-, NO3–
A SO32-, CO32-
B S2-, CO32-
C PO43-, HSO3–
D
S2-, NO3–
Solution:
S2- produce H2S gas on heating, which turns lead acetate paper black. CO32-
produces CO2 gas on heating, which turn lime water milky.
SO32- also produce SO2 gas on heating, which turn lime water milky.
A I– B SO32-
C S2- D NO2–
A I– B SO32-
C S2- D NO2–
Solution:
following list is
A 3
B 4
C 5
D 6
following list is
A 3
B 4
C 5
D 6
Solution:
NO, N2O, CO – neutral oxides

B2O3, N2O5, SO3, P4O10 – acidic oxides
Ans. 3
Solution:
(iii, v, vi)
NO2–, SO32–, HCO3–

Ans. 6
Solution:
respectively are :

respectively are :

Solution:
respectively are.
A PCl3,S2Cl2 and 4
B PCl3, S2Cl2 and 2

respectively are.
A PCl3,S2Cl2 and 4
B PCl3, S2Cl2 and 2

Solution:
enthalpy?
A HF
B HCl
C HBr
D HI
enthalpy?
A HF
B HCl
C HBr
D HI
Solution:
A a and b
B a,b and c
C b and c
D All of these
A a and b
B a,b and c
C b and c
D All of these

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#Challenge-1

Given below are two statements:

A Both Statement I and Statement II are true

B Statement I is true but Statement II is false

C Both Statement I and Statement II are false

D Statement I is false but Statement II is true

A Both statement I and Statement II are true.

B Statement I is true but Statement II is False.

C Statement I is false but Statement II is true.

D Both Statement I and Statement II is false.

A Both Statement I and Statement II are correct

B Both Statement I and Statement II are incorrect

C Statement I is incorrect but Statement II is correct

D Statement I is correct but Statement II is incorrect

A Statement I is true but Statement II is false

B Both Statement I and Statement II are true

C Both Statement I and Statement II are false

D Statement I is false but Statement II is true

A Both Statement I and Statement II are correct

B Statement I is correct but Statement II is incorrect

C Statement I is incorrect but Statement II is correct

D Both Statement I and Statement II are incorrect

A (A) is correct but (R) is not correct

C (A) is not correct but (R) is correct

A B and C only B C and D only

C A and B only D A and D only

A Statement I is correct but statement II is incorrect.

B Statement I is incorrect but statement II is correct

C Both statement I and statement II are incorrect

D Both statement I and statement II are correct

A Statement I is false but statement II is true

B Both statement I and statement II are false

C Statement I is true but statement II is false

D Both statement I and statement II are true

A Statement I is true but Statement II is false.

B Both Statement I and Statement II are false.

C Both statement I and Statement II is are true.

D Statement I is false but Statement II is are true.

A Statement I is true but Statement II is false.

B Statement I is false but Statement II is true.

C Both statement I and Statement II are false.

D Both statement I and Statement II are true.

Both A and R are true but R is NOT the correct

Both A and R are true and R is the correct

C A is false but R is true.

D A is true but R is false.

A A and D only B B and C only

C C and D only D A and B only

Both (A) and (R) are correct but (R) is the

D (A) is correct but (R) is not correct

A Both Statement I and Statement II are correct

B Statement I is correct but Statement II is incorrect

C Statement I is incorrect but Statement II is correct

D Both Statement I and Statement II are incorrect

A Statement I is false but Statement II is true

B Both Statement I and Statement II are true

C Statement I is true but Statement II is false

D Both Statement I and Statement II are false

A Statement I is false but Statement II is true