MOCK TEST (JEE ADVANCED)

PHYSICS, CHEMISTRY & MATHEMATICS

PAPER - 2 DATE: 07.05.2024

Time Allotted: 3 Hours Maximum Marks: 180

JEE ADVANCED – MOCK TEST

 Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
 Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .

INSTRUCTIONS

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & Section-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) Section-A (01 – 10) contains 10 multiple choice questions which have one or more than one
correct answer. Each question carries +3 marks for correct answer. There is no negative
marking.

(ii) Section-C (01 – 10) contains 10 Numerical based questions with answers as numerical value
from 0 to 9 and each question carries +3 marks for correct answer. There is no negative
marking.

Name of the Candidate

Enrolment No.
 Useful Data

PHYSICS
Acceleration due to gravity g = 10 m/s2

Planck constant h = 6.6 1034 J-s

Charge of electron e = 1.6  1019 C

Mass of electron me = 9.1  1031 kg

Permittivity of free space 0 = 8.85  1012 C2/N-m2

Density of water water = 103 kg/m3

Atmospheric pressure Pa = 105 N/m2

Gas constant R = 8.314 J K1 mol1

CHEMISTRY

Gas Constant R = 8.314 J K1 mol1

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
23
Avogadro's Number Na = 6.023  10
34
Planck’s constant h = 6.625  10 Js
= 6.625  10–27 ergs
1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66  10–27 kg
–19
1 eV = 1.6  10 J

Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
Physics PART – I
SECTION – A
Straight Objective Type
This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out of which only ONE OR MORE THAN ONE is/are correct.

1. Four point charges +q, +q, – q, and – q are placed respectively at corners A, B, C and D of a
square. Then
(A) the potential at the centre O of the square is zero
(B) the electric field at the centre O of the square is zero
(C) If E is the mid-point of side BC, the work done in carrying an electron from O to E is zero
(D) If F is the mid-point of side CD, the work done is carrying an electron from O to F is zero

B
2. In the circuit show in figure, if the galvanometer resistance is 6 ,
C1 = 10 F C2 = 20 F
then in the steady state
(A) no current flows through the galvanometer A C
G = 6
(B) the current through R2 is 4A
(C) the charge on C1 is 80 C. R1 = 16 R1 = 8

(D) the charge on C2 is 80 C D

12V

3. A thin rod AB of length l carries a current I1. It is placed in the P

magnetic field of a long wire PQ carrying a current I2 as shown in A l1 B

figure l2
 II  l  a
(A) The force experienced by the rod is F  0 1 2 loge  1  l
4  2a 
0I1I2 l Q

(B) The force experienced by the rod is F  loge  1  
4  a 
(C) The rod experiences no torque
(D) The rod experiences a force as well as a torque.

Space for rough work

 y
4. A fly crawls with constant speed v along the radial ê
spoke of a wheel which is rotating with constant angular
speed . Initially the fly starts from centre of the wheel
along x-axis. Then (where r  v  ) v êr
(A) The actual velocity of the fly in fixed frame is 
 Fixed frame
v  veˆ r  reˆ 
(B) The actual velocity of the fly in fixed frame is

v  veˆ r  reˆ 
 v.
(C) The position of fly at any instant r  eˆ r

 vt
(D) The position of fly at any instant r  eˆ r


5. A cubical region of side a has its centre at the origin. It encloses three fixed point charges, -q at
(0, -a/4, 0) + 3q at (0, 0, 0) and -q at (0 + a/4, 0) Choose the correct options(s)
z
a

-q
-q y
3q
3q
x
(A) The net electric flux crossing the plane x = +a/2 is equal to the net electric flux crossing the
plane x =-a/2
(B) The net electric flux crossing the plane y = +a/2 is more than the net electric flux crossing the
plane y =- a/2
(C) The net electric flux crossing the entire region is q/0
(D) The net electric flux crossing the plane z = +a/2 is equal to the net electric flux crossing the
plane x = +a/2

6. Let the energy, magnitude of linear momentum and angular frequency of an electron in hydrogen
atom be E,P and  respectively. If n be the corresponding quantum number, then
(A) E/W varies as n (B) E P/W is independent of n
(C) P W varies as n1/2 (D) E P W is independent of n.

Space for rough work

7. A nitrogen nucleus 14N7 absorbs a neutron and can be transformed to lithium nucleus 6Li3 under
suitable condition, after emitting
(A) 4 proton and 3 neutrons
(B) 5 proton and 1 beta particle
(C) 2 alpha particles, 1 neutron and 2 gama photons
(D) 4 protons and 4 neutrons

8. At 0oC a black body placed in 0oC surrounding then it emits

(A) all wavelengths of radiation (B) only visible light
(C) only micro wave radiation (D) no radiation

9. A 100 W bulb B1, and two 60 W bulbs B2 and B3, are connected to a B1 B2
250 V source, as shown in figure. Now W 1, W 2 and W 3 are the output
powers of the bulbs B1, B2 and B3, respectively. Then
(A) W1  W2  W3 (B) W1  W2  W3
(C) W1  W2  W3 (D) W1  W2  W3 B3

250V

10. A block of mass m is placed on a prims of mass M. The inclined

m
surface is smooth and inclination with horizontal is . The
horizontal surface is sufficiently rough to prevent slipping of prism.
The body of mass m is coming down the inclined face then
M
(A) Acceleration of body along the inclined surface is g sin 
1 
(B) Frictional force is mgsin 2
2
mg
(C) Maximum frictional force is
2
(D) Friction force will be maximum when   450

Space for rough work

 SECTION – C
(One Integer Value Correct Type)
This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive).

1. Water flows vertically down ward out of a round nozzle of radius r0 with a
speed u0. Which is not quite large for some distance below nozzle the flow
in water laminar stream over this distance the stream radius ry as a
1/  u0 r0 y
function of the distance of belong the nozzle is ry  r0 1  y  .
Value of    is take value of u20 / g  1 .

2. A 60 cm metal rod M1 is joined to another 100 cm metal rod M2 to form an L shaped single piece
This piece is hung on a ply at the joint. The two rods are observed to be equality inclined to the
vertical. The two rods are equally thick. If the ratio of density M1 to that of M2 is  , then value of
18
is
25

3. A black surface at constant high temperature TH is parallel

to another black plane surface at a constant lower
temperature TL (enclose vacuum in between). A heat shield
consisting of two thin black plates is placed between the TH TL
warm and the cold surfaces and parallel to these. After
J
some time steady state is achieved. The value of   0
J
is (Jo is initial heat current and J is final current)

Space for rough work

4. The velocity filter of a mass spectrometer uses a uniform E = 100 v/m and a magnetic field
B1  2 102 T below filter at the uniform magnetic filed of induction 8 102 used to deflect the
beam above filter. Both the beams are +e charged having mass numbers 20 and 22 pass through
the filter and make a 180o turn in the deflecting filed. If the distance between the points S1 & S2 is
d, then find the approximate (integer) value of 2d?
1amu
(Value of  108 SI unit ) (Note: spectrometer does not changes speed of ions)
e

S1 S2
d

5. A quarter cylinder of radius R and refractive index 1.5 is placed

on a table as shown in figure. For what value of 3m, a ray
from P will emerge parallel to table? Assume small aperture.

P R
mR

6. A material with uniform restively  is formed in the w w

shape of a wedge as shown. The resistance of wedge

across length L is R  ln  ' . Then find the value of
L y2
 y1
 L L L
  ' .  y  ,y 2  ,W  
6 
 3 6 6

Space for rough work

7. A uniformly thick plate in the shape of an arrowhead has dimension
as shown. The centre of mass lies at a distance x cm from O. The
value of x is 6 cm
O

6 cm
3 cm

8. A long flexible inextensible rope of uniform mass density  v

is being pulled on a rough floor with horizontal force F in F
such a way that the lower part is at rest and upper part
moves with constant speed v as shown, the magnitude of F
will be (in N) .    1 kg / m,v  2m / s 

9. Consider an infinite ladder net work as shown R1 R1

in figure A voltage is applied between points A C
A
and B. If the voltage is hawed after each
section, find the ratio R2/R1. …….. 
R2 R2

B
D

10. Value of electric field at centre of charged hemisphere is ……… N/C if it has uniform charged
density   8 o c / m2 at surface.

Space for rough work

Chemistry PART – II
SECTION – A
Straight Objective Type
This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out of which only ONE OR MORE THAN ONE is/are correct.

1. A system is changed from an initial state to a final state by a manner such that if the same
change from the initial state to the final state were made by a different path, which of the following
statements are correct for H system?
(A) remain the same
(B) will depend upon the type of path
(C) Heat exchanged q will be same if the path is isobaric
(D) Heat exchanged q will be different if the path is not isobaric

2. Which of the following are correct regarding the products of the given reaction?

Products

(A) only X and Z are formed (B) Y > Z (amount)

(C) X > Y (amount) (D) Y > X (amount)

Space for rough work

3. Which of the following pairs of nitrates give the same gaseous products on thermal
decomposition?
(A) KNO3 and Pb(NO3)2 (B) KNO3 and NaNO3
(C) Pb(NO3)2 and Cu(NO3)2 (D) NaNO3 and Ca(NO3)2

4. KO2 finds use in oxygen cylinders used for space and submarines. The fact(s) related to such
use of KO2 is/are:
(A) it produces O2 (B) It produces O3
(C) It absorbs CO2 (D) It absorbs both CO and CO2

5. Which of the following are correct?

(A)
1.O 3

2 . Zn,H 2 O
 OHC–CH2CH2CH2–CHO

H H
(B) O
C6H5C–OOH
CH2Cl2 H H
H H
O
(C)
KMnO 4

cold dilute solution

 H H
H H
OH OH
(D) O O
KMnO 4

– 
OH ,heat –O—CCH CH CH C—O–
2 2 2
H H

6. Which of the following statements are correct about stability of chelates–

(A) As the number of rings in complex increases, stability of chelate also increases
(B) A chelate having five membered ring is more stable if it contains double bonds.
(C) A chelate having six membered ring is more stable than if it does not contain double bonds.
(D) Chelating ligands are at least bidentate ligands.

7. Which of the following is/are extracted by electrolytic reduction?

(A) Cu (B) Al
(C) Mg (D) Ag

Space for rough work

8. Choose the incorrect statement:
(A) Salicylic acid (o–Hydroxybenzoic acid) is much stronger acid than its m-,p-isomers and
benzoic acid itself.
(B) Acidity of salicylic acid is due to steric inhibition of resonance, as – OH group forces – COOH
out of the plane of ring
(C) The orbitals which are in the same plane take part in resonance
(D) All the resonating structures have real existence

9. Rotation around the bond (between the underlined atoms) is restricted in:
(A) C2H4 (B) H2O2
(C) C2H2 (D) C2H6

10. Select the coloured compound(s):

(A) K 2Cr2O7 (B) CuSO4 .5H2O
(C)  V  H 2 O 6  Cl 3 (D)  Cu  NH 3  4  SO 4

SECTION – C
(One Integer Value Correct Type)
This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive).

1. Find the total number of species having planar shape.

I3 , XeF4 ,SF4 , C 2 F4 , H 2O 2 , BrF5 ,SO3 , NOCl, ClF3 , F2CO, XeF5

2. How many moles of Grignard reagent are consumed in given compound?

O OEt
C Cl O
EtO C H

SH
HO O

Space for rough work

3. How many monochloro compounds including stereoisomers will give propene on treatment with
Mg/ether followed by H2O ?

4. Find the sum of optically active isomers of both  Pt  gly 2 Cl 2  and  Co  en  2 Cl 2  .

5. A polyhydric alcohol is acylated by using ethanoyl chloride in presence of alkali. It was observed
that molecular mass of alcohol is increased to 237% on acylation. If the molecular mass of
polyhydric alcohol is 92, then the number of –OH groups present in polyhydric alcohol are____

6. For the synthesis of ammonia at 300 K :

N2(g) + 3H2 (g) 
 2NH3(g)
Calculate the value of  G° in Kcal and give your answer in magnitude by using the following data:
N2 H2 NH3
°
 H f (Kcal/mole) 0 0 -10
 S° (Cal/K-mole) 40 30 45

7. Calculate the change in pressure (in atm) when 2 mole of NO and 16 g O2 in a 6.25 litre originally
at 27°C react to produce the maximum quantity of NO2 possible according to the equation.
1
2NO(g) + O2(g)  2NO2(g) (Take R = ltr. Atm/mol K)
12
8. Electrons in a sample of H  atoms make transitions from state n = x, to some lower excited state.
The emission spectrum from the sample is found to contain only the lines belonging to a particular
series. If one of the photons had an energy of 0.6375 eV. Then find the value of x.
3
[Take 0.6375 eV = × 0.85eV]
4
9. If the atomic number of the inert gas is XY in which the total number of d-electrons is equal to the
difference in the number of total p- and s- electrons. Find |X-Y|.

10. For the reaction 3A  g   2B  g   2C  g  , starting with pure A, pressure after 9 min was 387.5
mm of Hg and after a long time was 400mm of Hg. Calculate half life of A in min.

Space for rough work

Mathematics PART – III
SECTION – A
Straight Objective Type
This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out of which only ONE OR MORE THAN ONE is/are correct.

 1   1   x  
1. If 2f  x  xf    2f  2 sin   x     4cos2    x cos , x  R  0 , then which of the
 x    
4   
 2  x
following statement(s) is/are true?
 1
(A) f 2  f    1 (B) f 2  f 1  0
 2 
 1  1
(C) f 2  f 1  f   (D) f 1 f   f 2  1
 2   2 

2. Let ABC be a non obtuse triangle such that AB > AC & B  45o . Let O and I denote the
circumcenter and incentre of ABC respectively. Suppose that 2OI  AB  AC, then the
possible values of sin BAC is/are
4 2 2
(A) 1/ 2 (B)
2
4 2 2
(C) (D) 1/2
2

x y z
3.    1 intersects the coordinate axis at points A, B and C resp. If PQR has midpoints A,
a b c
B, & C then
(A) centroid of ABC & PQR coincide
(B) foot of normal to ABC from O is circumcentre of PQR
(C) area PQR  2 a2 b2  b2c 2  c 2a2
(D) incentres of ABC and PQR coincide

Space for rough work

4. x  y  a, y  z  b, x. b  , x . y  1& y.z  1 then
a b 1 
(A) y  (B) x  y  a  y 
 y 2  
1  1 
(C) z  y  b  y  (D) x  y  a  y 
y 2    2  

1
1
 C7 x200 1 x dx is equal to
7
5. If the value of the definite integral 207
where k  N , then k is
0
k
divisible by
(A) 13 (B) 16
(C) 9 (D) 52

6. A function f : R  R satisfies the equation f  x  y  f  x  f  y  x, y  R & is continuous through

n

out the domain. If I1  I2  I3  I4  I5  450 where In  n f  x dx , then

0

(A) f  x  4x (B) f  x  2x
(C) f ' 0  4 (D) f ' 0  2

7.   
A a ,B b ,C c are position vector of vertices of ABC such that

a.b  a.c  a.a  b.c. Also b  c  a  b  2 a  c . Inradius of triangle is 1 unit, then which of
the following statement is/are correct?
(A) sin2 B  sin2 C  1 where B = ABC & C = ACB
(B) Diameter of circumcircle of ABC is 5 units
(C) Area of ABC is 6 sq. units
Area of ABC
(D) 2
semi perimeter of ABC

Space for rough work

8. The curves y  ax 3  4x a  0 & xy  1 touch each other at points P and Q, where P is in first
quadrant. A triangle is formed by drawing a tangent to y  ax 3  4x at point Q and coordinate
axes. Then which of the following is/are correct?
(A) The value of a is – 4
(B) The area of the triangle formed is 2
(C) The value of a is – 2
(D) The area of the triangle formed is 1

 
1
 1  1 x   
2 a  b
 
If the value of definite integral  cot  cot  dx     ,
1
9.
 2 
 1 x  1  x 2 
x
  c 
1
 
where a, b, c,  N in their lowest form then
(A) a = 1 (B) b = 2
(C) a = 2 (D) b = 1

0   a b 
Let A    &  A  I  50A    then
50
10.
0 0   c d
   
(A) a + d =2 (B) a + b = 1
(C) b + c = 0 (D) a+ d = 1

SECTION – C
(One Integer Value Correct Type)
This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive).

tan1 tan2 tan1024  

1.   .......   tan   tan, then    .........,
 1000 
 G.I.F .
cos 2 cos 4 cos 2048

2. A triangle ABC has positive integer sides, A  2B and C  90o , then the minimum length of
the perimeter of ABC is 70 + K then K is equal to

Space for rough work

 7  7C 14 
    C  Cr  is  k  . Then k is
k r 14 k 1
3. The value of
k 0
14
Ck r k
k


1
sin1 x 2 n
4. If the value of x dx is  where n  N , then the value of is
0
2
 x 1 n 27

5. The sum of the following n term series for   30o

 n  1
n

cos2   cos2  cos 2  cos3  cos3  .....  cosn  cos n is n  1sin   , then k is
  k 
6 

6. A tourist takes a trip through a city in stages each stage consist of three segments of length 100
meters separated by right turns of 60o. Between the last segment of one stage and first segment
o
of the next stage, the tourist makes a left turn of 60 . The distance the tourist will be from his
initial position after 2017 stages is 100 k. Then k is

7. Let A n n  N be a matrix of order 2n  12n  1 such that aij  0 i  j &

th th
aij  n  i  1 2n i  j , where aij denotes the element of i row & j column of An. Let Tn =
2

 102 
  Tn 
 n1 
1  (sum of all the element of An). Then the value of   , where. represents the G.I.F,
n

520200 
 
 
is

8. The minimum area bounded by the function y  f  x and y  kx  9, k  R , where f satisfies

the relation f  x  y   2f x   xf  y   y f  x x,y  R & f ' 0  0 is 9 A, value of A is

9. Let f  x be a differentiable function such that f '  x is symmetrical about the line 2x = 5 and f(1) =
3

2, f(4) = 6 then  f  x dx is equal to

2

10. If the radius of circumcircle of the TPQ where PQ is the chord of contact corresponding to point
T with respect to circle x 2  y 2  2x  4y  11  0 is b units. Then the minimum distance of T from
director circle of the given circle is 12  4 x , then k is equal to

Space for rough work

 MOCK TEST (JEE ADVANCED)
PHYSICS, CHEMISTRY & MATHEMATICS

PAPER - 2 DATE: 07.05.2024

ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. A, C A, C, D A, B, C

2. A, C, D B, D A, C

3. B, D B, C A, B, C

4. A, C A, C A, B, C

5. A, C, D A, B, C, D A, B, C, D

6. A, B A, D A, C

7. C B, C A, B, C

8. A B, D A, B

9. D A, C C, D

10. A, B, D A, B, C, D A, B, C

1. 6 7 2

2. 2 6 7

3. 3 4 6

4. 5 8 4

5. 4 3 2

6. 8 8 2

7. 1 2 2

8. 4 8 8

9. 2 3 4

10. 2 3 2
Physics PART – I
SECTION – A

1. A, C
Refer to figure. potential at O is
1 q q q q
V0     0
40  r r r r 
+q +q
A B

r
r

r r

D C
-q F -q
2
a
Refer to fig. again (AE)2  a2   
2
5a2 5a 5a a a
 , giving AE  . Similarly DE  and BE  ,CE  . Potential at E is
4 2 2 2 2
1  q q q q 
VE     0
40  AE BE DE CE 
Work done in carrying a charge – e from O to E is
W  e(VE  V0 )
  e(0  0)  0
Potential at F is
1  q q q q 
VF    
40  AF BF DF CF 


Now, AF  BF  5 a / 2 and CF = DF = a/2

Putting these values, we get
q  1 
VF    1
0 a  5 
Work done is carrying a charge – e from O to F is
W  e  VF  V0   eVF
qe  1 
 1 
0a  5
Hence the correct choice is (a) and (c).

2. A, C, D
In the steady state, no current flows through the branch ABC containing the capacitors. Thus all
the current flows through ADC. So choice (a) is correct. Current through R1 = current through R2
= I = 12/24 = 0.5 A. Now p.d. across A and C = 12 V. Therefore Q  V1C1  V2C2 . Thus
 V1 C2
 =2. Also V1  V2  12 . Therefore, V1 = 8 V and V2 = 4V. Thus
V2 C1
Q  C1V1  10F  8V  80C  charge on C2. Thus the correct choices are (a), (c) and (d)

3. B, D
Consider a small element of length dx of the rod at a distance x from wire PQ as shown in figure.
The magnetic field use to wire PQ at the element is
P
x
l1

a
A B
dx
l2
l
Q
0I1I2 dx
dF  BI1 dx 
2x
 Total force experienced by the rod is
F  dF 
x (a  l)
0I1I2 dx

22 
x a
x
 II al
 0 1 2 loge  
2  a 
Now, the magnetic field B is not uniform; it decreases as we go from and A to end B of the rod.
Hence the rod will also experience a torque. Thus the correct choices are (b) and (d).

4. A, C
   v
v  veˆ r  reˆ  , t  , r  eˆ
 

5. A, C, D
Using Gauss theorem.

6. A, B
1 1 1
a,b as E  2
,P  & W  3
n n n

7. C
17 6 4 1
N7  Li3 + 2 2He + 0n + 2 

8. A
From black body radiation concept.

9. D
The resistances of bulbs B1, B2 and B3 respectively are
 V 2 (250)2
R1    625
W1 100
(250)2
R2   1042  R3
60
Voltage across B3 is V3 = 250 V
VR1
Voltage across B1 is V1 
(R1  R2 )
250  625
  93.7V
(625  1042)
Voltage across B2 is V2  250  93.7  156.3V
V12 (93.7)2
W1    14W
R1 625
(156.3)2
Power output W2   23W
1042
(250)2
W3   60W
1042
Hence W1  W2  W3 , which is choice (D)

10. A, B, D
F1 N

a0

F
a0  gsin 
F  Nsin , N  mgcos 
1
 F  mgsin2
2

SECTION – C

1. 6
A 1V1  A 2 V2
 r 
2

Vy   0  u0
 ry 
ro
By Bernoulli’s theorem
p 1 2 p 1
 Vy  gh1   u02  gh2
 2  2 y
1/4
 2gy 
 ry  r0 1  2 
1/4 h2
 r0 1  2y 
 u0  ry
   6
2. 2
A  0 A
m2 g 2 sin 45  m1g1 sin 45
o o
........... (1)
m1  1 1, m2  2  2 45o 45o 1
2
From (1),
1 12  2 22
2 m2g m1g
1  5  25
   
2 3 9
18
x 2
25

3. 3
In steady state heat flow will be same across each sheet.
Now J   TH4  T14  A
J J
J   T14  T24  A TH TL
J
J   T24  TL4  A
Now 3J   TH4  TL4   Jo
Jo T1 T2
3
J

4. 5
Speed of ions
E
V  1  5000 m s1
B1
m v m v 
S1S2  2 r2  r1   2  2  1 
 qB qB 
2  5000 amu
 22  20
B e
104
  2 108
8 102
1
d  102 m  2.5mm
4

5. 4
For plane surface.
n1 n n2  n1
 2 
mR v R1
n1  1,n2  1.5 1 R1    v  1.5mR
For curve surface
n1 n n  n1 P R
 2  2 mR
1.5mR  R  R
n2  1,n1  1.5
4
m ,3m  4
3
6. 8
dx y y
dR     1 dx
wy x r Lr
y1
dx   L  r  L  r
L
y
R    In y2
0 wy wy1 r 
y2 L y 36 L
Now r = L R= In 1  In2 x r
y1  y 2 w  y1  y 2  y 2 L

7. 1
A1 x1  A 2 x 2
x cm 
A1  A 2
1
A1   6  9  27cm2
2
1
A 2   6  3  9cm2
2
X1  0, X 2  2
27  0  9 2
Xcm   1cm
27  9

8. 4
dm
Fv  v 2
dt
4N

9. 2
VAB  X
R2 x
R1  x
R2  x
VAB  2Vcd
 VAC  VCD
R2 x
 R1 
R2  x
Now 2R x  x
R1R2 R
R1   2 2
R2  2R1 R1

10. 2

Ec   2N / C
4 o
Chemistry PART – II
SECTION – A

1. A, C, D
H is a state function so it is independent of path.

2. B, D
The yield of product will depend on stability of the carbocation. Carbocation corresponding to (y)
is more stable than (z) as well as (x).

3. B, C
KNO3 
 KNO 2  O2
NaNO3 
 NaNO2  O2
Cu NO3 2 
 CuO  NO2
Pb(NO3 )2 
 PbO  NO2

4. A, C
Fact.

5. A, B, C, D
(A) bond cleavage takes place as a result of reductive ozonolysis.
(B) epoxidation
(C) syn addition
(D) oxidative cleavages in basic medium

6. A, D
Fact.

7. B, C
Highly electropositive metal are extracted by electrolytic reduction.

8. B, D
Fact.

9. A, C
Rotation is restricted about   bond .

10. A, B, C, D
Fact.

SECTION – C

1. 7
I3 , XeF4 ,C2F4
SO3 ,NOCl,ClF3
F2 CO,

2. 6
 O O
C OEt 2 moles, C H 1 mole

OH 1 mole, SH 1 mole,
Epoxide – 1 mole so total 6 moles.

3. 4

Cl, , Cl (E & Z)
Cl

4. 8
Pt gly  Cl  and Co en Cl  have 6 & 2 optically active isomers respectively.
 2 2   2 2 

5. 3
O

ROH + CH3COCl R O C CH3

In the above reaction molecule wt. of product is increased by 42 units.

So if n, - OH groups were present in the compound then increase in molecule wt. will be 42 n
increase in mass of compound  218  92  126
42n  126  n  3

6. 8
HR0  2 H0f NH3   3 H0f H2   H0f H2   20Kcal
SR0  2 S0f NH3   3 S0f H2   S0f N2 
 2  45  3  30  40  40 cal  0.04 Kcal
G0  H0  TS0  8 K cal

7. 2
2NO  O2 
 2NO2
2 0.5 0
2 1 0 1
ni  2.5, nf  2
n  0.5
nRT 0.5  0.0821 300
P   2
v 6.25

8. 8
3
E   0.85eV
4
 1 1 1
0.85 1   13.6  2  2 
 4 
4 n 
n8
9. 3
S  e  8
P  e  18
Pe  Se  10
de  10
At.No  36
63  3

10. 3
3A  g   2B  g   2C  g 
t=0 3P 0 0
t=9 3P–3P1 2P1 2P1
t=  0 2P 2P
Total pressure after long time = 4P = 400  P = 100
Pressure after 9 minutes = 3P + P1 = 387.5  P1 = 87.5
Pressure of A becomes one-eighth in 9 minutes. That means 3t1/2 = 9  t1/2 = 3
Mathematics PART – III
SECTION – A
1. A, B, C
Replace x by 2, we get
 1
2f 2  2f    2f 1  4 ...........i
 2 
 1
 f 2  f    2  f 1
 2 
Replace x by 1, f 1  1 ....ii
1  1  1 5
Replace x by ,2f    f 2  2  ......iii
2  2 2  2
 1 
Solving (i) & (iii) f    0,f 2  1
 2 

2. A, C
B 
sinB 
1
2
, tan   
 2   2 1 
2 sin A  cos A 
& sinC  sin 135o  A  
2
c  ab B
r tan  
2  2 

R  
2  1 sin A  sin C  sinB

OI  R  2Rr
2


OI2  R 2 1 2sin A  2sinC  2 sinB  2 1  .............ii

& 2OI  AB  AC
OI2  C  2 sin A  sinC  sinB  
2  1 ...........iii
From i & ii,we obtain


2 sinC  sinB  1 2 sin A  sinC  sinB
2
 2  1
 1 2 sinC  sinB  sin A  sinC  sinB 2  1
2

 1 2sin C  2 2 sinC  1  2 sin A  sinC 2  1  2  2 

2

 sin A  cos A   2sin A  cos A   2 2  2 sin A  2  2 sin A  cos A 

 2  2 

 1 2sin A cos A   2  2 sin A  2 cosB  2 2  2 

  2 sin A  1 2 cos A  2  1  0

1 1 2 4 22
 sin A  & cos A   sin A 
2 2 2
3. A, B, C
AC  PR & 2AC  PR
So, ABPC is a parallelogram comparing the coordinates of Q
midpoints of diagonal, we get
P a,b,c  Q a,b,c  & R a,b,c  . C A
Also AD & AP are medians of ABC and PQR
respectively.
So, centroids are coinciding. The perpendicular bisector of P R
B
PR is also perpendicular to AC.
 the circumcenter of PQR is orthocentre of ABC
area PQR  4area ABC

OAB  OBC  OAC

2 2 2
4
Where OAB is the area of projection of ABC on the plane
XOZ etc.
4. A, B, C
x  y b  a b
  x. b.y   y . b x  a  b

 .y   y . b.x  a  b  x.b  

y.b  y.y  z  0

a b
y

 
 x y  y  a y

  x.y .y   y.y  x  a  y

 x.y  1
2
 y  y x  a y
1  y  a  y
x  
y2
y  z y  b  y
 y z  z. y .y  b  y
2
 y2 z  y  b y
1 
z y  b  y 
y2  

5. A, B, C, D
x 200 1 x  dx
1 7

I  207
C7
0
II I
 201  11
7 x
C7 1 x  ,   7 1 x .x 201dx

6
 207
 
201 0 207 0

1
7
1 x x 201dx
201 0
6
207 C7
 Similarly by applying integration by part 6 times we get
1
7.6.5.4.3.2.1
201.202.203......207 0
I 207 C7 . x 207 dx

207! 7! 1
 . ..............
7!200! 201!202.203 207....208
1 1
 
208 k

6. A, C
f  x  kx
1 2

1. kxdx  2 kxdx

0 0
3 4 5

3  kxdx  4  kxdx  5. kxdx

0 0 0

k3
 1  23  33  43  53 
2 
k 56
2

  
2  3 
225K

2
225K
given  450
2
k 4

7. A, B, C
  
a. b  a  c b  a  0  C
AC. AB  0
a
Also a  c  2b  i & b2  c 2  a2 b
b2  a  c a  c   2b a  c 
A c B
 b  2 a  c   ii
From i & ii we get
a b c
  
5 4 3
6 2
 Inradius = 1   1   1
6
 a  5,b  4,c  3

8. A, B
At the point of contact of two functions their value are equal and their derivatives are equal.
 f  x   gx  & f ' x   g' x 
1 1
ax 3  4x  & 3ax 2  4  
x x2
1
 x2 
2
 a  4
 1   1 
 P  , 2  & Q  , 2 
 2   2 
Area of triangle formed by any tangent to rectangular hyperbola xy  c 2 with coordinate axis
equal to 2c 2
 Area  2

9. C, D
1
 1  1
1  x
 cot   cot dx
 2 
1  1 x  1  x 2 
x

 
1
   
 
 cot1 
1 x
  cot 1    dx
 1 x  
 1  x 2  
2 x
1
 
 
 
1  1
1
x x  dx
2I   cot 1
cot    cot1
2   
1 x  1  x  1  x 
x 2x
2

 
1

1
1
2I    cot1 dx
1 1 x 2
1

2I    tan1 1 x 2 dx
1

Integrating by parts

1  x 
I   x tan1 1 x 2    
1
x

2   dx
2 0 0
1  1 x  1 x 2 
1
 x 2 dx
2 0 2  x 2  1 x 2
I put x = sin, dx = cos d

 /2
 sin2 
2 0 2  sin2 
 d

 /2
 sin2   2  2
2 0 2  sin2 
 d

 /2 / 2
 d
 
2 0
d   
2  sin2 
0
 /2
2 sec 2 d
  
4 0
2 tan2   2  tan2 
 
2 dk
   2 tan   k 
4 0
k 2

2 1  1 k 
  .  tan 
4 2  2  0
2 2
 
4 2 2
 1  2 
 2  
 4 

10. A, B, C
0  
A 
0 0 
 
 0   0  
A2    
0 0  0 0 
  
0 0 
 
0 0 
 
 A3  0
 A  I  A 3  3A 2  3A  I
3

 A  I  50A  I
50

 1 0
 A  I  50A   
50


0 1

SECTION – C

1. 2
tan  tan  1 tan2 
  tan2  tan 
cos 2 1 tan2 
 tan2  tan1   tan 4  tan2  ...............  tan 2048  tan1024
 tan 2048  tan1

2. 7
sin A  sin2B  sin A  2sinB cosB
Also, sinC = sin3B = 3 sinB  4 sin3B
 a  2bcosB,c  b 3  4 sin2 B  b 4cos2 B  1
hence a2  b b  c 
A triangle of smallest perimeter means gcda,b,c   1 .
In fact gcd b,c   1 since any common factor of b, c would be a factor of a as well.
2
 A perfect square a is being expressed as the product of two relatively prime integers b and c,
it must be the case that both b & b + c are perfect squares. Thus for some integer m & n with
gcd  m, n   1 we have
 b  m2 & b  c  n2 ,a  mn
n a
2cosB  
m b
 C  90o  O  B  30o
n
& 3  2cosB   2
m
The smallest value of (m, n) that satisfies the above mentioned conditions are 4 and 7.
3. 6
7 7C 14
r 14 
  14
k 0
k
k 14  k 
r K

k r  k r 14  r 
 7 14  7
   7 Ck  14K C7k    7 Ck 214k

k 0  r k  k 0
 1
7 k

 214  7 Ck    67  76
k 0
 2 

4. 4
1
sin1 x
I  dx .....i
0
x2  x  1
sin1 1 x
1

 dx
1 x  1 x  1
2
0
1
cos1 x
 dx ..............ii
0
x2  x  1
Addingi & ii
1
 1
2I  
2 0 x  x 1
2
dx

 1  1  2x  1
1

2I  . tan  
2  3    3 
   0
 2 
2
2I 
3 3
2
I
108
n  108
5. 2
z  cos  cos   isin 
n
z  z n1
 zk 
k 1 1 z
n

 cos  cosk  isink

k 1
k

cos  cos   isin   cosn1  cos n  1   isin n  1  


sin2   icos  sin 
 icos  cos   isin   cosn 1  cos n  1   isin n  1 

sin  cos   isin 
 cosn1  cosn  isinn
 i cot   
 sin  
sinn cosn1   cosn1  cosn 
  icot   
sin   sin  
n
sinn cosn1 
 cos  cos k 
k

k 1 sin 
For = 30o
n1
n  3 
 2 sin  
6  2 
6. 2
In one stage the tourist traverses the complex number
2
x  100  100z  100z  100  100 3i
 
where z  cos  isin
3 3
In 2017 stages, the tourist traverses the complex number
W  x  xz  xz 2  .....  xz 2016
1 z 2017 
 x   
 1 z 
 xz
W  xz  200
7. 2
aij  0i  j
aij  n  1  ii  j
2

 sum of all the elements of An

2n1
  n  1  i
2

i1
 
 2n  1n  1  2n  1 n
2

 2n3  3n2  3n  1
 n3  n  1
3

Tn  1 n3  n  1 
n 3

 
n1
 1 n3  1 n  1
n 3

 Vn  Vn1
102 102
  Tn    Vn  Vn1   V102  V0  102
3

n1 n1

 102 
  Tn 
 n1 
 2
 520200 
 
 
8. 8
f x  h  f  x  0
f '  x   lim
x  h
2f  x  xf h  h f  x  2f  x  xf 0  0 f  x
 lim
x  h
As f (0) = 0
 f h  f 0 
 lim x    f  x 
h 0 
 h  0 
f '  x   f x 
f '  x
 dx   dx  2 f  x  x  C
f  x
x2
f  x 
4
when   0, area is minimum
9
Required min area = 2 2 ydy
0

 72 sq. unit

9. 4
5  5 
f '   x   f '  x 
 2   2 
5
Replacing x by x
2
f '  x   f ' 5  x   F x   F 5  x   C
 C  f  x   f 5  x 
C8
3 3

I   f x  dx   f 5  x dx
2 2
3

 2I   f  x   f 5  x  dx
2
3

  8dx  I  4
2

10. 2
 x  1   y  2  32
2 2

P
 x  1   y  2  16
2 2

S O

TS  OT  SO  12  4 2