eni MX 5114

additive package
technology report

April 2016
 CONTENTS

1. eni MX 5114 TECHNICAL DATA SHEET

2. API SL-CF PERFORMANCE

2.1 Formulations & Compositions
2.2 Formulation Data
2.3 Text Matrix
2.4 API SL/CF Engine Tests

3. API SL - JASO MA2 - MB PERFORMANCE

3.1 Formulations & Compositions
3.2 Formulation Data
3.3 JASO MA & MA2 Engine Tests

4. INFRARED SPECTRUM

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eni MX 5114

eni MX 5114 is a new additives package designed for advanced cost-efficient engine
oil technologies for cars and 4-stroke motorcycles.

APPLICATIONS AND PROPERTIES

eni MX 5114 additives package is suitable for blending high level performance car and 4-stroke
motorcycles engine lubricants when formulated with the appropriate base stocks and Viscosity
Modifier.
eni MX 5114 meets JASO MA-2.
Grade SAE formulations covered: 10W-30, 10W-40, 15W-40, 15W-50, 20W-50. Grades from
15W-40 are fully obtained with Group I base stock.

TREAT RATE
6,5 %

PERFORMANCE CLAIMS

Specifications Performance

API SL/CF

JASO MA-2

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TECHNICAL DATA

Method Unit Values

min max
Physical properties
Appearance - clear liquid
3
Density @ 15°C ASTM D 4052 kg/m 995
2
Viscosity @ 100°C ASTM D 445 mm /sec 147 226
Flash Point ASTM D 93 °C 100
Chemical properties
TBN ASTM D 2896 mg KOH/g 85 115
Calcium ASTM D 4951 %m 2.22 3.14
Magnesium ASTM D 4951 %m 0.13 0.19
Zinc ASTM D 4951 %m 1.24 1.75
Phosphorus ASTM D 4951 %m 1.15 1.57
Nitrogen ASTM D 5291 %m 0.72 1.09

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2. API SL/CF PERFORMANCE
2.1 FORMULATIONS COMPOSITION
API performance level SL/CF SL/CF SL/CF SL/CF SL/CF
SAE Grade 10W-30 10W-40 15W-40 15W-50 20W-50
GP I - SN150S 75.80% 73.30% 56.50% 55.70% 5.30%
GP I - SN500 - - 28.00% 25.00% 79.00%
GPIII - ETRO 4 8.00% 8.00% - - -
Eni MX 5114 6.50% 6.50% 6.50% 6.50% 6.50%
VII –Eni MX 4106 9.50% 12.00% 8.80% 12.60% 9.00%
PPD – Eni MX 4333 0.20% 0.20% 0.20% 0.20% 0.20%

• Eni MX 5114 can be considered as composed by part packages Eni Tripletech TM Eni MX 5612 A, Eni MX
5612 B and Eni MX 5612 C respectively at 0.50% 4.87% and 1.13% treat rates.

2.2 FORMULATIONS DATA

BASE STOCKS INSPECTION

Base stock ETRO 4 SN 150 SN 500

Base stock Type, ATIEL Group III Group I Group I

Viscosity Index (ASTM D 2270) 130 101 92

KV @ 100°C, cSt (ASTM D 445) 4.24 5.21 11.49
KV @ 40°C, cSt (ASTM D 445) 19.10 30.32 108.30
CCS viscosity @ -35°C (ASTM D 5293) 2635 - -
CCS viscosity@ -20°C (ASTM D 5293) - 2200 3230
CCS viscosity @ -10°C (ASTM D 5293) - - 4000
Flash Point, °C (ASTM D 92) 232 240 270
Pour Point, °C (ASTM D 97) -12 -9 -6
Noack @ 250°C, %wt (CEC-L-40-T-87) 8.2 12.0 3.0
Sulfur, %wt < 0.01 0.78 1.22

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FORMULATIONS CHARACTERISTIC

API performance level SL/CF SL/CF SL/CF SL/CF SL/CF

SAE Grade 10W-30 10W-40 15W-40 15W-50 20W-50
Sulphated ash, wt% (calculated) 0.8 0.8 0.8 0.8 0.8
Elemental Content, wt%:
- Calcium (ASTM D 4951) 0.195 0.195 0.195 0.195 0.195
- Zinc (ASTM D 4951) 0.096 0.096 0.096 0.096 0.096
- Phosphorus (ASTM D 4951) 0.087 0.087 0.087 0.087 0.087
- Magnesium (ASTM D 4951) 0.010 0.010 0.010 0.010 0.010
- Molibdenum 0.006 0.006 0.006 0.006 0.006
- Nitrogen (ASTM D 3228) 0.048 0.048 0.048 0.048 0.048
TBN, mgKOH/g (ASTM D 2896) 6.4 6.4 6.4 6.4 6.4
Density at 15°C, kg/l (ASTM D 4052) 0.876 0.878 0.884 0.884 0.893
Visc. @150°C, cP at 106 s-1 (ASTM D 4741) 3.55 3.94 4.04 4.57 5.01
Viscosity at 100°C, cSt (ASTM D 445) 11.84 13.54 14.1 17.47 19.96
Viscosity at 40°C, cSt (ASTM D 445) 75.9 87.6 106.5 133.5 184.5
Viscosity Index (ASTM D 2270) 151 157 135 144 125
6550 6850 6850 6950 9100
CCS Viscosity, cP (ASTM D 5293) @-25°C @-25°C @-20°C @-20°C @-15°C
56100 67100 38000 46400 26100
Pumping visc., cP (ASTM D 4684) @-30°C @-30°C @-25°C @-25°C @-20°C
Flash point, °C (ASTM D 92 / ASTM D93) 220/210 214/208 232/217 222/212 230/218
Shear Stability (CEC-L-14-A-78):
- Viscosity at 100°C after 30 cycles, cSt 10.67 11.95 12.25 14.83 17.14
- Viscosity loss, % -11 -13.5 -13.5 -15 -14.5
NOACK, g/100g (CEC L-40-93) 13.9 13.3 11.1 12.0 7.1
Gelation Index (ASTM D5133) - <6 - - -
Foam tendency (ASTM D 892) Seq. I/ II / III - 10/20/10 - - -

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2.3 TEST MATRIX
API perform. level - - - SL/CF SL/CF SL/CF SL/CF SL/CF
Supporting formulation Matrix Core

Test Oil Code DC1AB216 DC2AB31 EC1AB89 - DC1AB214 - - -

SAE Grade 10W-40 10W-40 15W-40 10W-30 10W-40 15W-40 15W-50 20W-50
API SL/CF Tests:
- BRT - X* - RA RA RA RA RA
- EOFT X^ - - RA RA RA RA RA
- EOWTT X^ - - RA RA RA RA RA
- H&M X^ - - RA RA RA RA RA
- Sequence VG 1 - X* - RA RA RA RA RA
- Sequence IIIF - - - RA X RA RA RA
- Sequence IVA - - - RA X RA RA RA
- Sequence VIII - - - RA X RA RA RA
- Cat 1MPC - - X° RA RA RA RA RA

Notes:

X = Test passed according to the mentioned specification.

RA = test waived per Read Across Engine Testing

Some of the original tests of API SL performance level are now obsolete and no more available.
Other current tests are used in order to demonstrate the performance level:
1 Run in place of Sequence VE

Read Across Details:

* BRT and Seq. VG passed with the supporting formulation DC2AB31 10W-40 containing the same
core technology but higher detergent treat rate (TBN= 8), in comparison with DC1AB214.

^ Lab tests passed with the supporting formulation DC1AB216 10W-40 containing the same core
technology but higher antioxidant booster in comparison with DC1AB214.

° Cat 1MPC test passed with the supporting formulation EC1AB89 15W-40 containing the same
detergent technology and lower amounts of dispersant and antioxidant in comparison with DC1AB214.

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2.4 API SL/CF ENGINE TESTS

SEQUENCE IVA – ASTM D6891

Oil Code DC1AB214 SL
SAE Grade 10W-40 LIMITS
ACC Code DC1AB214-PO 2013/67
Laboratory Intertek
Test n° 01B-13-0533

Cam wear avg., µm 29.91 120 max

PASS/FAIL: SL PASS PASS
PASS/FAIL: SM PASS
PASS/FAIL: SN PASS

SEQUENCE VG– ASTM D6593

Oil Code DC2AB31 SL

SAE Grade 10W-40 LIMITS
ACC code EU-DC2AB31-A-1-VG-01-EG-VG04
Laboratory Intertek
Test n° VG04-20-0253

Average engine sludge, merit 9.13 7.8 min

Rocker arm cover sludge, merit 9.56 8.0 min
Average piston skirt varnish, merit 8.46 7.5 min
Average engine varnish, merit 9.28 8.9 min
Oil screen clogging, % 1 20.0 max
Hot stuck compression rings 0 None
Cold stuck rings 0 Rate and Report
Oil screen debris, % 1 Rate and Report
Oil ring clogging, % 0 Rate and Report
PASS/FAIL: SL PASS PASS
PASS/FAIL: SM PASS
PASS/FAIL: SN PASS

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SEQUENCE IIIF – ASTM D1491

Oil Code DC1AB214 SL

SAE Grade 10W-40 LIMITS
ACC Code EU-DC1AB214-A-1-IIIF-01-EG-GM04
Laboratory Intertek
Test n° 04-08-1358

Viscosity increase @80h, % 86.9 275 max

AVG piston skirt varnish, merit 9.16 9.0 min
Weighed piston deposit, merit 3.64 4.0 min
Cam+lifter wear Avg, micron 2.1 20 max
Hot stuck rings none none
Oil consumption, l 4.16 5.2 max
PASS/FAIL: SL PASS (*) PASS
(*) except for WPD

SEQUENCE VIII - ASTM D6709

Oil Code DC1AB214 SL

SAE Grade 10W-40 LIMITS
ACC Code EU-DC1AB214-A-1-VIII-01-EG-L1
Laboratory Intertek
Test n° 1-252-16-119

Bearing weight loss, mg 10.9 26.4

PASS/FAIL: SL PASS PASS

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CAT 1M-PC
Oil Code EC1AB89 CF LIMITS
SAE Grade 15W-40
Laboratory Intertek
Test n° 59-185

Top Groove Fill, %wt 68 70 max

Weighted Total Demerit 143.8 240 max
Piston Ring Sticking None None
Ring Side Clearance Loss, max, mm 0.013 0.013
Piston Ring Scuffing, % 0 0
Piston Liner Scuffing, % 0 0
PASS/FAIL: CF PASS PASS

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3. API SL; JASO MA2; MB PERFORMANCE
3.1 FORMULATIONS COMPOSITION
API level SL* SL* SL* SL* SL* SL* SL* SL*
JASO level MA MA, MA2 MA MB MA MA MA, MA2 MA
SAE Grade 5W-40 5W-40 10W-30 10W-30 10W-30 10W-40 10W-40 15W-50
GP I - SN150S - - 79.60% 79.30% 79.40% 70.50% - 58.10%
GP I - SN500 - - - - - - - 21.00%
GP II – NR 150 - - - - - - 51.20% -
GP II – NR 400 - - - - - - 20.00% -
GPIII - ETRO 4 18.30% 5.80% - - - 10.00% 10.00% -
GPIII – ETRO 6 57.50% 74.00% 5.00% 5.00% 5.00% - - -
GPIV – PAO 4 5.00 % 5.00% - - - - - -
eni MX 5114 6.50% 6.50% 6.50% 6.50% 6.50% 6.50% 6.50% 6.50%
VII - eni MX 4106 12.50% - 8.60% 8.60% 8.60% 12.70% 12.00% 14.10%
VII – SV261 - 8.50% - - - - - -
PPD - eni MX 4333 0.20% 0.20% 0.10% 0.10% 0.10% 0.30% 0.30% 0.30%
Booster 1 ^ - - - 0.50% - - - -
Booster 2 ^ - - 0.20% - - - - -
Booster 3 ^ - - - - 0.40% - - -

* eni MX 5114 treat rate is the same as API SL performance level.

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3.2 FORMULATIONS DATA
BASE STOCKS INSPECTION

Base stock PAO 4 ETRO 4 ETRO 6

Base stock Type, ATIEL Group IV Group III Group III

Viscosity Index (ASTM D 2270) 126 130 130

KV @ 100°C, cSt (ASTM D 445) 4.1 4.26 6.10
KV @ 40°C, cSt (ASTM D 445) 19.0 - -
CCS viscosity @ -35°C (ASTM D 5293) 1424 2585 8150
CCS viscosity @ -30°C (ASTM D 5293) 910 1392 4340
CCS viscosity @ -25°C (ASTM D 5293) - 809 2430
Flash Point, °C (ASTM D 92) 220 220 230
Pour Point, °C (ASTM D 97) -66 -18 -18
Noack @ 250°C, %wt (CEC-L-40-T-87) <14.0 14.5 6.5
Sulfur, %wt <0.01 <0.01 <0.01

Base stock NR 150 NR 400 SN 150 SN 500

Base stock Type, ATIEL Group I Group I Group I Group I

Viscosity Index (ASTM D 2270) 105 105 105 95

KV @ 100°C, cSt (ASTM D 445) 5.3 8.0 5.25 11.0
KV @ 40°C, cSt (ASTM D 445) 30.0 58 30.5 95.0
CCS viscosity @ -25°C (ASTM D 5293) 3850 - -
CCS viscosity@ -20°C (ASTM D 5293) 2150 6500 2200 3230
CCS viscosity @ -15°C (ASTM D 5293) - 3300 - -
CCS viscosity @ -10°C (ASTM D 5293) - - - 4000
Flash Point, °C (ASTM D 92) 215 240 210 240
Pour Point, °C (ASTM D 97) -9 -9 -9 -9
Noack @ 250°C, %wt (CEC-L-40-T-87) <13.0 <10 12.0 3.0
Sulfur, %wt <0.1 <0.2 0.8 1.22

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FORMULATIONS CHARACTERISTIC
API performance level SL* SL* SL* SL* SL* SL* SL* SL*
JASO performance level MA MA, MA2 MA MB MA MA MA,MA2 MA
SAE Grade 5W-40 5W-40 10W-30 10W-30 10W-30 10W-40 10W-40 15W-50
Sulphated Ash, wt% calc. 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8
Elemental Content, wt%:
Calcium (ASTM D 4951) 0.195 0.195 0.195 0.195 0.195 0.195 0.195 0.195
Zinc (ASTM D 4951) 0.096 0.096 0.096 0.096 0.096 0.096 0.096 0.096
Phosphorus (ASTM D 4951) 0.087 0.087 0.087 0.087 0.087 0.087 0.087 0.087
Magnesium (ASTM D 4951) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
Molybdenum (ASTM D 4951) 0.006 0.006 0.020 0.020 0.006 0.006 0.006 0.006
Nitrogen (ASTM D 3228) 0.048 0.048 0.048 0.048 0.048 0.048 0.048 0.048
TBN, mgKOH/g (ASTM D 2896) 6.4 6.4 6.4 6.4 6.4 6.4 6.4 6.4
Density @ 15°C, kg/l 0.855 0.854 0.878 0.853 0.879 0.856 0.867 0.866
(ASTM D 4052)
Visc. @150°C, cP @ 106 s-1 - - - - - - - -
(ASTM D 4741)
Viscosity at 100°C, cSt 14.53 13.78 11.25 11.21 11.60 14.65 14.86 19.39
(ASTM D 445)
Viscosity at 40°C, cSt 91.6 85.1 74.4 73.0 76.3 96.9 99.4 141.5
(ASTM D 445)
Viscosity Index (ASTM D 2270) 166 164 142 145 141 155 156 149
CCS Viscosity, cP 6300 6300 6250 6150 6300 6700 6400 6750
(ASTM D 5293) -30°C -30°C -25°C -25°C -25°C -25°C -25°C -20°C
Flash point, °C 227 232 234 235 233 223 220 233
(ASTM D 92 / ASTM D93) 205 205 216 219 221 205 207 210
Shear Stability (CEC-L-14-A-78):
Viscosity @ 100°C 12,94 13.22 10.20 10.05 10.33 12.60 12.92 16.42
after 30 cycles, cSt
Viscosity loss, % -11,2 -3.0 -9.3 -10.4 -10.9 -14.0 -13.0 -15.3
Evap. Loss (NOACK), g/100g - - - - - - - -
(CEC L-40-93)
Pour Point (ASTM D 97) -33 -36 -21 -21 -21 -30 -24 -24
Foaming tendency - - - - - - - -
(ASTM D 892)Seq. I / II / III

* eni MX 5114 treat rate is the same as API SL performance level.

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3.3 JASO MA & MA2 ENGINE TESTS

JASO CFT (Clutch Friction Test – T 903 : 2011)

Oil Code 15NB041LA MA1 MA2

SAE Grade 5W-40 LIMITS LIMITS
Laboratory SWRI
Test n° J8-11-1186

DFI (Dynamic Friction Characteristics Index) 1.80 ≥ 1.30 and < 1.85 ≥ 1.85 and < 2.50
SFI (Static Friction Characteristics Index) 2.14 ≥ 1.25 and < 1.70 ≥ 1.70 and < 2.50
STI (Stop Time Index) 1.86 ≥ 1.45 and < 1.85 ≥ 1.85 and < 2.50
JASO Performance Level MA

Oil Code 15NB078LA MA1 MA2

SAE Grade 5W-40 LIMITS LIMITS
Laboratory SWRI
Test n° J8-25-1200

DFI (Dynamic Friction Characteristics Index) 1.90 ≥ 1.30 and < 1.85 ≥ 1.85 and < 2.50
SFI (Static Friction Characteristics Index) 2.36 ≥ 1.25 and < 1.70 ≥ 1.70 and < 2.50
STI (Stop Time Index) 1.95 ≥ 1.45 and < 1.85 ≥ 1.85 and < 2.50
JASO Performance Level MA, MA2

Oil Code 15NB039LA MA1 MA2

SAE Grade 10W-30 LIMITS LIMITS
Laboratory SWRI
Test n° J16-16-589

DFI (Dynamic Friction Characteristics Index) 1.46 ≥ 1.30 and < 1.85 ≥ 1.85 and < 2.50
SFI (Static Friction Characteristics Index) 1.80 ≥ 1.25 and < 1.70 ≥ 1.70 and < 2.50
STI (Stop Time Index) 1.58 ≥ 1.45 and < 1.85 ≥ 1.85 and < 2.50
JASO Performance Level MA

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Oil Code 15NB040LA MA MB
SAE Grade 10W-30 LIMITS LIMITS
Laboratory SWRI
Test n° J8-2-1177

DFI (Dynamic Friction Characteristics Index) 1.59 ≥ 1.30 and < 2.50 ≥ 0.50 and < 1.30
SFI (Static Friction Characteristics Index) 0.91 ≥ 1.25 and < 2.50 ≥ 0.50 and < 1.25
STI (Stop Time Index) 1.67 ≥ 1.45 and < 2.50 ≥ 0.50 and < 1.45
JASO Performance Level MB

Oil Code 15GB028LA MA1 MA2

SAE Grade 10W-30 LIMITS LIMITS
Laboratory SWRI
Test n° J8-40-1215

DFI (Dynamic Friction Characteristics Index) 1.83 ≥ 1.30 and < 1.85 ≥ 1.85 and < 2.50
SFI (Static Friction Characteristics Index) 1.74 ≥ 1.25 and < 1.70 ≥ 1.70 and < 2.50
STI (Stop Time Index) 1.89 ≥ 1.45 and < 1.85 ≥ 1.85 and < 2.50
JASO Performance Level MA

Oil Code 15NB056LA MA1 MA2

SAE Grade 10W-40 LIMITS LIMITS
Laboratory SWRI
Test n° J16-33-606

DFI (Dynamic Friction Characteristics Index) 1.77 ≥ 1.30 and < 1.85 ≥ 1.85 and < 2.50
SFI (Static Friction Characteristics Index) 2.38 ≥ 1.25 and < 1.70 ≥ 1.70 and < 2.50
STI (Stop Time Index) 1.82 ≥ 1.45 and < 1.85 ≥ 1.85 and < 2.50
JASO Performance Level MA

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Oil Code 15NB075LA MA1 MA2
SAE Grade 10W-40 LIMITS LIMITS
Laboratory SWRI
Test n° J8-18-1193

DFI (Dynamic Friction Characteristics Index) 1.90 ≥ 1.30 and < 1.85 ≥ 1.85 and < 2.50
SFI (Static Friction Characteristics Index) 2.18 ≥ 1.25 and < 1.70 ≥ 1.70 and < 2.50
STI (Stop Time Index) 1.93 ≥ 1.45 and < 1.85 ≥ 1.85 and < 2.50
JASO Performance Level MA, MA2

Oil Code 15NB055LA MA1 MA2

SAE Grade 15W-50 LIMITS LIMITS
Laboratory SWRI
Test n° J16-32-605

DFI (Dynamic Friction Characteristics Index) 1.74 ≥ 1.30 and < 1.85 ≥ 1.85 and < 2.50
SFI (Static Friction Characteristics Index) 2.38 ≥ 1.25 and < 1.70 ≥ 1.70 and < 2.50
STI (Stop Time Index) 1.82 ≥ 1.45 and < 1.85 ≥ 1.85 and < 2.50
JASO Performance Level MA

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4. INFRARED SPECTRA

Eni MX 5114

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