SUBJECT : CHEMISTRY

TOPIC : CLASSIFICATION OF ELEMENTS &

S1
PERIODICITY IN PROPERTIES JEE
©2022-23 ALL RIGHT RESERVED

SECTION - I

1) An element of atomic mass 40 has 2,8,8,

7) Which of the following is the correct is
and 2 as electronic configuration. Which
the correct order of gradually decreasing
one of the following statements
basic nature of the oxides?
regarding this element is not correct?
(a)AI2O3, MgO,CI2O7,SO3
(a) It forms a basic oxide
(b)CI2O7,SO3,AI2O3, MgO
(b) It belongs to IIA group
(c)MgO, AI2O3,SO3, CI2O7
(c) It belongs to IV period
(d)SO3,CI2O7,MgO, AI2O3
(d) It forms an acidic oxide
8) Which of the ions are isoelectronic?
2) How many ionization energies can
(a) Be2+,Mg2+,AI3+
carbon have?
(b) AI3+,Ca2+,Sr2+
(a)1 (b)2
(c) Ca2+,K+,S2-
(c)6 (d)4
(d) K+,Na+,Li+
3) Ionic radii are
9) The enthalpy of sublimation of aluminum
(a) inversely proportional to effective
is 330kJ/mol. Its first, second, and third
nuclear charges.
ionization ethalpies are 580, 1820, and
(b) Directly proportional to square of
2740 kJ respectively. How much heat
effective nuclear charge
has to be supplied (in kJ)respectively.
(c)Directly proportional to effective
How much heat has to be supplied(in kJ)
nuclear charges
to convert 13.5 g of aluminum into AI3+
(d)inversely proportional to square of
ions and electrons at 298 K?
effective nuclear charge.
(a)5470 (b)3764
4) Electronic configuration of chalcogens in
(c)4105 (d)2735
their outermost orbit is
10) Which one of the following ions has the
(a)s2p3 (b)s2p5
highest value of ionic radius?
(c)s2p4 (d)s2p6
(a) B3+ (b)O2-
5) In which of the following species energy
(c)S2- (d)F-
is released when electron is added?
11) Which one of the following elements has
(a)F- (b)O
the maximum electron affinity?
(c)O- (d)Na
(a)F (b)Br
6) In the periodic table, going down in
(c)CI (d) I
fluorine group
12) Which of the following factors may be
(a) ionization potential will increase
regarded as the main cause of
(b) electronegativity will increase
lanthanide contraction?
(c) reactivity will increase
(d) ionic radius will increase
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 (a) Greater shielding of 5d- electrons by 17) The amount of energy released when
4f- electrons 1012 atoms of CI vapour are converted to
(b)Poorer shielding of 5d-electrons
electrons by 4f
4f- CI-ions, according to the equation:
electrons CI(g) + e- CI-(g) is 58 x 10-10 J.
(c) Poor shielding of one of 4f
4f-electrons calculate the ∆eg. H of CI atom in kJ mol-1
by another in the subshell and eV atom-1
(d) Effective shielding on one of 4f-
4f (a)-0.036 eV atom-1
electrons by another in the subshell (b)-3.48 eV atom-1
13) In the periodic table, the element with (c)-0.038 eV atom-1
atomic number 16 will be placed in the (d)-0.361eV atom -1
group. 18) The size of the following species
(a) Sixth increases in the order
(b) Fourth (a) AI < Mg < F- < Na+
(c) Fifth (b) F- < AI < Na+ > Mg2+
(d)Third (c) Mg2+ < Na+ < F- < AI
14) Which one of the following combination (d) Na+ < AI < F- < Mg2+
represents a metallic element? 19) Which element having the following
(a) 2,8,7 (b)2,8,2 electronic configurations has minimum
(c)2,8,4 (d)2,8,8 ionization potential?
15) The correct order of the size is: (a) 1s1 (b) 1s2,2s22p6
(a) Ca2+ > K+ > Ar > CI- > S2- (c) 1s2,2s22p2 (d) 1s2,2s22p63s1
(b) K+ > Ca+ > CI- > Ar > S2- 20) Colord salts are formed by
2- - + 2+
(c) S > CI > Ar > K > Ca (a) Transition metals
2- - 2+ +
(d) S > Ar > CI > Ca > K (b) Lanthanides
16) Ionic character of a bond (H--X) varies (c) Actinides
with the difference in electroneg
electronegativity (d) Alkali metals
values as shown below.
SECTION - II

21) The atomic number of the element

present in the second period and group
16 is ________
22) For bromine the IE/EA ratio=10/3,
50% ionic character of HX is when EN Electronegativity of bromine is 2.8 on
difference is Muliken’s scale, its EA in kJ/mol will be
(a) 1.4 (b) 1.7 ____________
(c) 1.6 (d) 1.5
23) Find the total number of cations for
which I.P. of cation is lower than
corresponding atom.
K+,O+,Ne+,P+,Be+,Na2+,Fe+,Sn2+
24) Write the total number of elements (upto
atomic number =10), which have positive
electron gain enthalpy (EGE1)
25) The ∆egH0 of Br is 3.4 eV. The energy
_______ in kcal is released when 1.6 g
or Br (g) is completely converted to Br ⊖
(g) ions. (1 eV = 23.06 kcal mol-1)
26) ∆fH° of hypothetical MX is -250 kJ mol-1
and for MX2 is -600 kJ mol-1. The
enthalpy of disproportionation of MX is
-100x kJ mol-1. Find the value of x.
27) Find out the sum of all the digits of
atomic number of the element “Uuq”. (if
your answer is greater than 9 then add
all the digits. For example, Ans. 12 then
fill 1 + 2 = 3, Ans. 123 then fill 1 + 2 + 3 =
6 and Ans. 20 then fill 2 + 0 = 2
28) How many elements are possible for 1st
period of periodic table if azimuthal
quantum number can have integral
values from 0,1,2,… (n + 1)?
29) The number of CI atoms ionized in the
process CI CI+ + e by the energy
liberated for the process CI + e CI- for
one Avogadro number of atoms is
x x 1023. Given IE = 13.0 eV and
Eg = 3.60 eV. The value of x is
30) From the given compounds if X number
of compound are acidic in water.
CaO,SO2,SO3,Fe2O3,CI2O7;CO2,Na2O
Find the value of X

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