Nbs Circular 461

SELECTED VALUES
of
PROPERTIES OF HYDROCARBONS
CIRCULAR OF THE NATIONAL BUREAU OF STANDARDS C461
Prepared as Part of the work of the

American Petroleum Institute Research Project 44
by
Frederick D. Rossini, Kenneth S. Pitzer
William J. Taylor, Joan P. Ebert, John E. Kilpatrick
Charles W. Beckett, Mary G. Williams, and Helene G. Werner
Issued November 1947
U. S. DEPARTMENT OF COMMERCE NATIONAL BUREAU OF STANDARDS
W. Averell Harriman, Secretary E. U. Condon, Director
UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON, D. C.
For sale by the Superintendent of Documents, United States Government Printing Office, Washington 25, D. C. Price $2.75 (Buckram)
National Bureau of Standards
JAN 3 01948
U14L.1
PREFACE
One of the bulwarks of any technical or scientific research program

is the collection and critical appraisal of the pertinent information
already available. One type of such information that is required by
all laboratories in industry and science comprises selected values of
the fundamental physical constants and of the properties of the
chemical substances. Many advantages result from having such
fundamental work performed systematically and consistently in a
cooperative program by a full-time staff of experts, rather than
incidentally and sporadically by workers in different laboratories.
In addition to the obvious advantage of producing a complete, accu¬
rate, and self-consistent set of values of constants and properties,
such a cooperative program results in a considerable saving in
over-all cost and manpower.
Since its founding in 1901, the National Bureau of Standards
has been the principal agency of the Federal Government for funda¬
mental research in physics, chemistry, and engineering. The Re¬
search Associate Plan of the National Bureau of Standards makes
it possible for an industry to join with the National Bureau of
Standai’ds in the prosecution of a fundamental research program
of mutual benefit and in the public interest. Research investigations
in the petroleum, rubber, and chemical industries depend heavily
upon fundamental data on the physical and thermodynamic prop¬
erties of hydrocarbons. In 1941 the National Bureau of Standards,
through Lyman J. Briggs, then Director, and G. E. F. Lundell,
Chief of the Division of Chemistry, proposed to the American
Petroleum Institute, through J. Bennett Hill, then Chairman of the
Institute’s Advisory Committee on Fundamental Research on the
Composition and Properties of Petroleum, that the two organiza¬
tions establish a cooperative program on the compilation of tables of
selected values of properties of hydrocarbons. The proposal was
approved, and the new undertaking was begun in 1942, as the
American Petroleum Institute Research Project 44. In the several
years of its operation, the Project has had the wholehearted support
of the American Petroleum Institute, represented by David V.
Stroop, Assistant to the President (and coordinator of the research
programs), and William J. Sweeney, Chairman of the Institute’s
Advisory Committee on Fundamental Research on the Composition
and Properties of Hydrocarbons.
iii
IV
To advise the Project in its policy and program of work, the

Institute is represented by the following Advisory Committee:
Wayne E. Kuhn, The Texas Co., chairman.
Otto Beeck, Shell Development Co.
Gustav Egloff, Universal Oil Products Co.
Stewart S. Kurtz, Jr., Sun Oil Co.
From its beginning, the Project has had the benefit of the advice,
guidance, and enthusiastic support of this Advisory Committee.
Direction of the project was placed under Frederick D. Rossini,
Chief of the Section on Thermochemistry and Hydrocarbons at the
National Bureau of Standards. Kenneth S. Pitzer, Professor of
Chemistry at the University of California, joined the project, first
as a consultant, and then as associate director. The research and
clerical staff of the project has increased from two persons in 1942
to eight persons as of May 31, 1947. These include five research
investigators, William J. Taylor, John E. Kilpatrick, Joan P. Ebert,
Mary G. Williams, and Helene G. Werner, and two clerical assist¬
ants, at the National Bureau of Standards, and one research investi¬
gator, Charles W. Beckett, at the University of California. Provi¬
sion has been made by the American Petroleum Institute for the
addition of two more research investigators to the staff beginning
July 1, 1947, one each at the National Bureau of Standards and the
University of California.
The following investigators on the regular scientific staff of the
National Bureau of Standards have collaborated in various investi¬
gations of the API Research Project 44 and are serving as consult¬
ants to the Project: Carl S. Cragoe, Edward J. Prosen, and Donald
D. Wagman.
With regard to the physical and thermodynamic properties of hy¬
drocarbons, and closely related compounds, the aims of the Project
are as follows: (1) To examine all the pertinent original data in
the literature and all available unpublished data and appraise them
critically, (2) to correlate values of given properties with tempera¬
ture, pressure, molecular structure, etc., as appropriate, (3) to
make original calculations of thertnodynamic and physical prop¬
erties, as necessary, (4) to select and tabulate “best” values of the
properties, (5) to prepare the selected values in a convenient, usable
form for prompt distribution to the American Petroleum Insti¬
tute, the National Bureau of Standards, and to United States Gov¬
ernment, university, and industrial laboratories, (6) to prepare the
original calculations, analyses, and correlations in a form suitable
for publication, and (7) to keep the tables of selected values of the
properties up to date by revision at appropriate intervals.
The properties being investigated or to be investigated, include
the following: Boiling point, and pressure coefficient of the boiling
point; refractive index; density and specific gravity; freezing point;
molecular volume; molecular and specific refraction; specific disper¬
sion; refractivity intercept; viscosity; critical constants; P-V-T
relations; vapor pressures; heat and entropy of vaporization; heat
of combustion; heat content; free energy function; entropy; heat
capacity; heat of formation; free energy of formation; equilibrium
V
constant of formation; heat and entropy of fusion; cryoscopic

constants; and heat of transition.
In addition to the compilation of critically selected values of the
physical and thermodynamic properties, the American Petroleum
Institute Research Project 44 has also performed the service of
collecting (from cooperating laboratories in the industry, university
and government laboratories) and distributing, on standard forms,
infrared and ultraviolet spectograms of hydrocarbons and related
compounds. Procedures for the collection and distribution of Raman
and mass spectral data are in process of formulation. Information
concerning these spectographic data may be obtained by writing
the National Bureau of Standards.
The manner in which the work of the Project is performed is
indicated in the chart at the end of this preface.
Since the beginning of the work, the tables of numerical constants
and properties prepared by the Project have been, and will con¬
tinue to be, issued in loose-leaf form, monthly as compiled. The
distribution of the tables is in accordance with the following plan:
(1) Copies of tables and spectograms are supplied to all United
States Government laboratories having a proper need for them, at no
cost, on application to the National Bureau of Standards, (2) one
set of the tables and spectograms is supplied gratis to each depart¬
ment of chemistry, physics, and engineering, in universities and
colleges, with the compliments of the American Petroleum Insti¬
tute and the National Bureau of Standards, on application to the
National Bureau of Standards, (3) up to 10 copies each of the tables
and spectrograms are supplied gratis to each of the supporters of the
research fund of the American Petroleum Institute, on application
to the Institute, (4) additional sets of the existing tables and
spectograms, as well as new tables and spectograms as issued, may
be obtained by individual research workers, and by laboratories in
industry, research institutions, and universities, from the American
Petroleum Institute, attention of D. V. Stroop, 50 West Fiftieth
Street, New York, N. Y., at a cost of 3 cents a sheet for the tables
of properties and 5 cents a sheet for the spectral data.
The present volume is a complete collection of all the numerical
tables issued by the American Petroleum Institute Research Project
44 as of May 31, 1947. The plan of issuing new tables in loose-leaf
form, monthly as compiled, will in no way be affected by the prepa¬
ration of this bound volume. It is planned to have a second volume
of this work published at the end of the second 5-year period.
The staff of the Project will greatly appreciate receiving com¬
ments regarding any errors that have escaped attention, as well as
suggestions for improving the work and its presentation.
These tables are being extended to cover additional properties and
additional compounds as rapidly as the resources will permit.
Edward U. Condon, Director.

AMERICAN PETROLEUM INSTITUTE RESEARCH PROJECT 44
TABLES OP SELECTED VALUES OP

LOCATION OF DATA
CHEMICAL ABSTRACTS PRIOR COMPILATIONS, PRIVATE
AND OTHER REFERENCE WORKS,
ABSTRACT JOURNALS AND REVIEWS COMMUNICATIONS
COLLECTION OF THE ORIGINAL DATA FROM
PUBLISHED SCIENTIFIC LITERATURE UNPUBLISHED REPORTS
SYSTEMATIC FILING OF DATA ON

PHYSICAL THERMODYNAMIC SPECTROSCOPIC
AND OTtCR
PROPERTIES PROPERTIES MOLECULAR PROPERTIES
I
ANALYSIS, CORRELATION, AND CALCULATION
DIRECT GRAPHICAL CORRELATION STATISTICAL CALCULATION
ANALYSIS AND OF DATA THERMODYNAMIC PROPERTIES
AND ANALYTICAL WITH FROM
EVALUATION CORRELATION MOLECULAR SPECTROSCOPIC
OF DATA OF DATA STRUCTURE .MOLECULAR DATA
EXTENSION OF THE
AVAILABLE EXPERIMENTAL DATA BY THEORETICAL CALCULATIONS
INVOLVING THE APPLICATION OF
CHEMICAL THERMODYNAMICS, STATISTICAL MECHANICS, AND QUANTUM MECHANICS
TO THEORIES OF THE GASEOUS, LIQUID, AND SOLID STATES
_AND OF MOLECULAR STRUCTURE AND SPECTRA _ _
PUBLICATION
OF
Alkylcycloprntane* and Cyclohexane* sod the In¬ REPORTS

crement per CHi Croup (or Several Homologous
Senes of Hydrocarbons' OF
INVESTIGATIONS
COMPILATION
AND
PERIODIC REVISION
OF A
COMPLETE
AND
SELF-CONSISTENT SET
OF
. TABLES of SELECTED VALUES

OF
PHYSICAL
AND
THERMODYNAMIC
PROPERTIES
Vll
CONTENTS
PREFACE iii
I. INTRODUCTION . 1
Fundamental constants and conversion factors. 1
Temperature scale. 1
Internal consistency. 1
Sources of data. 1
Methods of calculation. 2
Uncertainties. 2
Explanation of numbers in titles of tables. 2
Explanation of letters in titles of tables. 2
Summary of tables as of May 31, 1947. 4
II. TABLES OF FUNDAMENTAL CONSTANTS, CONVERSION FACTORS, USEFUL
EQUATIONS, AND MOLECULAR WEIGHTS.7
a (part 1). Values of fundamental constants. 8
a (part 2). Values of fundamental constants. 9
a (part 3). Values of fundamental constants.10
(3 (part 1). Conversion factors for units of length.11
(3 (part 2). Conversion factors for units of length.11
(3 (part 3). Conversion factors for units of area.11
(3 (part 4). Conversion factors for units of volume.12
(3 (part 5). Conversion factors for units of mass,..13
(3 (part 6). Conversion factors for units of density.13
(3 (part 7). Conversion factors for units of pressure.14
(3 (part 8). Conversion factors for units of energy.15
(3 (part 9). Conversion factors for units of molecular energy.16
(3 (part 10). Conversion factors for units of specific energy.17
(3 (part 11). Conversion factors for units of specific energy per degree.17
7 (part 1). Useful equations with numerical constants.18
8 (index to parts). Molecular weights.19

8 (part 1). Molecular weights, C0H0 to C10H22. 20
8 (part 2). Molecular weights, Ci0H0 to C20H22.21
8 (part 3). Molecular weights, C10H22 to C20H42.22
8 (part 4). Molecular weights, C2oH0 to C30H22.23
8 (part 5). Molecular weights, C20H22 to C30H42. 24


8 (part 13). Molecular weights, C40H42 to C5oH62.32
8 (part 14). Molecular weights, C40H62 to C6oH82.33
8 (part 15). Molecular weights, C4oH82 to CsoHm.34
III. TABLES OF SELECTED VALUES OF PROPERTIES.35
Explanation of arrangement of tables.35
Systematic classification of table numbers by classes of compounds.36
Index of letters identifying tables arranged alphabetically by names of properties. 36
Tables of selected values of properties.
la Paraffins, Ci to C5. 37
2a (part 1) Paraffins, C6. 38
2a (part 2) Paraffins, C7. 39
3a Paraffins, C8. 40
4a (part 1) Boiling point, at 760 mm Paraffins, C9. 41
4a (part 2) Hg, in °C. Paraffins, C9. 42
5a iit/dp, at 760 mm Hg in Alkylbenzenes, C6 to C9. 43
6a °C/mmHg. Alkylcyclopentanes, C6 to C7 44
7a Refractive index, at 20° and Alkylcyclohexanes, C6 to C8. 45
8a (part 1) 25°C, 7iD- Monoolefins, C2 to C6. 46
8a (part 2) Density, at 20° and 25°C, Monoolefins, C6. 47
9a (part 1) in g/ml. Monoolefins, C7. 48
9a (part 2) Freezing point, in air at 1 Monoolefins, C7. 49
10a (part 1) atm, in °C. Monoolefins, C8. 50
10a (part 2) Monoolefins, C8. 51
11a (part 1) Diolefins, C3 to Cs. 55
1 la (part 2) Diolefins, C8. 56
12a Acetylenes, C2 to C6. 57
13a Styrenes, C8 and C9. 58
14a Alkylbenzenes, C10. 59
15a Alkylcyclopentanes, C8. 60
Vlll
la-E Paraffins, Ci to C6. 61

2a-E (part 1) Paraffins, C6. 62
3a-E Paraffins, C8. 64
5a-E 'Boiling point, at 29.921 Alkylbenzenes, C8 to C9. 67
6a-E in. Hg, in °F. Alkylcyclopentanes, Cs to C7. 68
7a-E dt/dp, at 29.921 in. Hg, Alkylcyclohexanes, C6 to. C8. 69
8a-E (part 1) in. °F/in. Hg. Monoolefins, C2 to C6. 70
8a-E (part 2) Refractive index, at 68° Monoolefins, C6. 71
9a-E (part 1) and 77°F, nr>. Monoolefins, C7. 72
9a-E (part 2) Density, at 60°, 68°, and Monoolefins, C7. 73
lOa-E (part 1) 77°, in lb/ft* and lb/ Monoolefins, C8. 74
lOa-E (part 2) gal. Monoolefins, C8. 75
lOa-E (part 3) Specific gravity, (60°F/ Monoolefins, C8. 76
lOa-E (part 4) 60°F). Monoolefins, C8. 77
lOa-E (part 5) Freezing point, in air at 1 Monoolefins, C8. 78
lla-E (part 1) atm, in °F. Diolefins, C3 to C6. 79
lla-E (part 2) Diolefins, C8. 80
12a-E Acetylene^ C2 to Cj,. 81
13a-E Styrenes, C8 and C9. 82
14a-E Alkylbenzenes, C10. 83
15a-E Alkylcyclopentanes, C8. 84
It. Paraffins, Ci to C6. 85
2b (part 1) Paraffins, C8. 86
3b Paraffins, C8. 88
4b (part 2) Molecular volume, at 20° Paraffins, C9. 90
5b and 25° C, in ml/mole. Alkylbenzenes, C6 to C9. 91
6b Molecular refraction, at 20° Alkylcyclopentanes, C6 to C7. 92
7b and 25°C, in ml/mole. Alkylcyclohexanes, Ce to C8. 93
8b (part 1) Specific refraction, at 20° Monoolefins, C2 to C6. 94
8b (part 2) and 25°C, in ml/g. Monoolefins, C6.,. 95
9b (part 1) [\ Refractivity intercept, at 20°
9b (part 2) and 25°C. ' Monoolefins, C7. 97
10b (part 1) Specific dispersion, at 20° Monoolefins, C8. 98
10b (part 2) and 25°C, in ml/g. Monoolefins, C8. 99
10b (part 3) Monoolefins, C8.100
lib (part 1) Diolefins, C3 to Ce.103
1 lb (part 2) Diolefins, C8.104
12b Acetylenes, C2 to C5.105
13b Styrenes, C8 and C9.106
14b Alkylbenzenes, C10. 107
15b Alkylcyclopentanes, C8.108
20c (part 1) 1 (Viscosity (absolute), forf Normal paraffins, Ci to C8.109
20c (part 2) (l the normal liquid range, 1 Normal paraffins, C6 to C10.110
20c (part 3) [| at given temperatures I Normal paraffins, Cn to Ci6.Ill
20c (part 4) I I in °C, in centipoises. I Normal paraffins, C16 to C2o- . ■ ... .112
20c-E (part 1)| | Kinematic viscosity, fori Normal paraffins, Ci to C6.113
20e-E (part 2) II the normal liquid range, I Normal paraffins, C8 to Cio- . ■ .114
20c-E (part 3) 11 at given temperatures! ' Normal paraffins, Cn to Cu.115
20c-E (part 4)11 in °F, in centistokes. I Normal paraffins, Ci6 to C20.116
20c-K (part 1)| | Kinematic viscosity, for j [Normal paraffins, Ci to C6.117
20c-K (part 2) II the normal liquid range, I i Normal paraffins, C6 to Cio.118
20c-K (part 3) 11 at given temperatures I Normal paraffins, C11 to Cu. . . ... .119
20c-K (part 4) J[ in °C, in centistokes.J Normal paraffins Ci6 to C20.120
lk Paraffins, Ci to C8.121
2k (part 1) Paraffins, C6.122
3k (part 2) (Vapor pressures and boiling1 Paraffins, C8.125
5k (part 1) ••! points, at 10 to 1,500 mm [■ • Alkylbenzenes, C6 to C8.126
5k (part 2) 1 Hg, in °C. J Alkylbenzenes, C9.127
6k (part 1) Alkylcyclopentanes, C6 to C7.128
7k (part 1) Alkylcyclohexanes, C6 to C8.129
7k (part 2) Alkylcyclohexanes, C8.130
8k (part 1) Monoolefins, C2 to C4.131
lm [Heats of vaporization, AHv, Paraffins, Ci to C5.132
2m at 25°C and normal boil¬ Paraffins, C6 and C7.133
3m ing point, in kcal/mole, Paraffins, C8.134
4m I cal/g, and Btu/lb. Paraffins, C9.135
5m I Entropy of vaporization, ASv, Alkylbenzenes, C8 to C9.136
6m at normal boiling point, Alkylcyclopentanes, C6 to C7.137
7m in cal/deg mole. Alkylcyclohexanes, Ce to C8.138
8m (part 1) Monoolefins, C2 to C4.139
ix
On (H2, C, CO.140
In Paraffins, C; to C6.141
2n Paraffins, C6 and C7.142
3n Paraffins, C8.143
5n Alkylbenzene^ C6 to C9.144
8n (part 1) Monoolefins, C2 to C6.145
8n (part 2) Heat of combustion,1 Monoolefins, Ce.146
9n (part 1) &Hc°, at 25° C, [ I Monoolefins, C7.147
9n (part 2) liquid and gas, in 1 1 Monoolefins, C7.148
12n kcal/mole, cal/g, and Acetylenes, C2 to C8.149
20n and Btu/lb. J Normal paraffins, Ci to C2o.150
21n Normal alkylbenzenes, Ca to C22.151
22n Normal alkylcyclopentanes, C5 to C2i. . . 152
23n Normal alkylcyclohexanes, C6 to C22.. . .153
24n Normal monoolefins (1-alkcnes), C2toC2o. 154
25n Normal acetylenes (1-alkynes), C2toC2o. 155
Op Heat of formation, r02,H2,H20, N2,C,C0,C02.156

lp AHf°, at 25°C, liquid Paraffins, Ci to C5.157
2p and gas, in kcal/ Paraffins, C6 and C7.158
3p mole. Paraffins, C8.159
5p Entropy, S°, at 25°C, Alkylbenzenes, C6 to C9.160
8p (part 1) I liquid and gas, in Monoolefins, C2 to C8.161
8p (part 2) cal/deg mole. Monoolefins, C6.162
12p Free energy of forma¬ Acetylenes, C2 to C6.163
20p tion, AFf°, at 25°C, Normal paraffins, Ci to C2o.164
21p liquid and gas, in Normal alkylbenzenes, C6 to C22.165
24p kcal/mole. Normal monoolefins (1-alkenes), C2to C29. 166
25p Normal acetylenes (1-alkynes), C2 to C20.167
Standard heat of vaporization,
lq AHv°, at 25°C, in kcal/mole. 5
Paraffins, Ci to C .168
2q Standard entropy of vaporization, 6
Paraffins, C and C .169 7
3q •j ASv°, at 25°C, in cal/deg mole. { Paraffins, C8.170
5q Standard free energy of vaporiza¬ Alkylbenzenes, C6 to C9.171
7q tion, AFv°, at 25°C, in kcal/ Alkylcyclohexanes, C6 to C8.172
mole.
OOr 0, H, N, C.173
Or 02, H2, OH, H20, N2, NO, C, CO, C02.... 174
lr Paraffins, Ci to C6.175
2r (nart 1) Paraffins, C«.176
2r v irt 2) Paraffins, C7.177
3r Paraffins, C8.178
5r Alkylbenzenes, C6 to C9..179
7r {Heat content func-) Alkylcyclohexanes, Ce to C8.180
8r (part 1) ■
tion,{H° — H °)/T, ( Monoolefins, C2 to C4.181
8r (part 2) to 1,500°K, in cal/ f Monoolefins, C6.182
8r (part 3) deg mole. ) Monoolefins, C6.183
12r Acetylenes, C2 to C5.184
20r Normal paraffins, Ci to C20.185
21r Normal alkylbenzenes, C* to C22.186
22r Normal alkylcyclopentanes, C5 to C2i.187
23r Normal alkylcyclohexanes, C6 to C22.188
24r Normal monoolefins (1-alkenes), C2 to C20.189
25r Normal acetylenes (1-alkynes), C2 to C20. . 190
00s f 10,H,N,C.191
0s 02,H2,0H,H20,N2,N0,C,C0,C02.192
Is Paraffins, Ci to C5.193
2s (part 1) Paraffins, C8.194
2s (part 2) Paraffins, C7.195
3s Paraffins, C8.196
5s Alkylbenzenes, C& to C9.197
7s (Free-energy function,1 Alkylcyclohexanes, C$ to C8.1<)8
8s (part 1) (F° —Ho°)/T, to II Monoolefins, C2 to C4.199
8s (part 2) 1,500°K, in cal/1 j Monoolefins, C5.200
8s (part 3) deg mole. J Monoolefins, C6.201
12s Acetylenes, C2 to C5.202
20s Normal paraffins, Ci to C2o.203
21s Normal alkylbenzenes, C6 to C22.204
22s Normal alkylcyclopentanes, C6 to C2i.205
23s Normal alkylcyclohexanes, C6 to C22.206
24s Normal monoolefins (1-alkenes), C2 to C20 207
25s j (Normal acetylenes (1-alkynes), C2 to C20. .208
oot fO,H,N,C.209
ot 02,H2,0H,H20, N2iN0,C,C0,C02.210
It Paraffins, Ci to C6.211
2t (part 1) Paraffins, C6.212
2t (part 2) Paraffins, C7.213
3t Paraffins, C8.214
5t Alkylbenzenes, C6 to C9.215
7t (Entropy, S°, to) Alky Icy clohexanes, C8 to Cs.216
8t (part 1) ( 1,500°K, in cal/H Monoolefins, C2 to C4.217
8t (part 2) ( deg mole. J Monoolefins, C6.218
8t (part 3) Monoolefins, C6.219
12t Acetylenes, C2 to Cs.220
20t Normal paraffins, Ci to C20.221
21t Normal alkylbenzenes, Co to C22 .222
22t Normal alkylcyclopentanes, C6 to C2i . . . .223
23t Normal alkylcyclohexanes, Co to C22 .224
24t Normal monoolefins (1-alkenes) C2 to C2o 225
25t Normal acetylenes (1-alkynes) C2 to C20.. .226
OOu ) fO,H,N,C.227
Ou 02,H2,0H,H20,N2,N0,C,C0,C02.228
lu Paraffins, Ci to C6.229
2u (part 1) Paraffins, Co...230
2u (part 2) Paraffins, C7.231
3u Paraffins, C8.232
5u Alkylbenzenes, Co to C9.233
7u fHeat content, H° —} Alkylcyclohexanes, C6 to C8.234
8u (part 1). •{ H°, to 1,500°K, U Monoolefins, C2 to C4.235
8u (part 2) [ in cal/mole. j Monoolefins, C5.236
8u (part 3) Monoolefins, C6.237
12u Acetylenes, C2 to Co.238
20u Normal paraffins, C4 to C20.239
21u Normal alkylbenzenes, C6 to C22.240
22u Normal alkylcyclopentanes, C6 to C24.241
23u Normal alkylcyclohexanes, C6 to C22.242
24u Normal monoolefins (1-alkenes), C2 to C20 243
25u Normal acetylenes (1-alkynes), C2 to C20. .244
Ou-E 02,H2,0H, H20,N2,N0,C,C0,C02.245

lu-E Paraffins, Ci to C5.246
2u-E (part 1) Paraffins, C6.247
3u-E (part 2) Paraffins, Cs.250
5u-E (part 1) Alkylbenzenes, C8 to C8.251
5u-E (part 2) Alkylbenzenes, C9.252
8u-E (part 1) Monoolefins, C2 to C4.253
8u-E (part 2) Heat content, Monoolefins, C5.254
8u-E (part 3; page 1) H°-H°, Monoolefins, Ci.255
8u-E (part 3; page 2) to 2,200°- Monoolefins, Cs.256
12u-E F, in Btu/ Acetylenes, C2 to C5.257
20u-E (part 1) lb. Normal paraffins, Ci to Cio.258
20u-E (part 2) Normal paraffins, Cn to C20.259
2lu-E (part 1) Normal alkylbenzenes, C6 to Cn.260
21u-E (part 2) Normal alkylbenzenes, C]4 to C22 . 261
24u-E (part 1) Normal monoolefins (1-alkenes), C2 to Cn 262
24u-E (part 2) Normal monoolefins (1-alkenes), C]2 to C29 263
25u-E (part 1) Normal acetylenes (1-alkynes), C2 to Cn 264
25u-E (part 2) Normal acetylenes (1-alkynes), Ci2to C?o.265
Ou-G [02,H2,0H,H20,N2,N0,C,C0,C02.266
lu-G Paraffins, C4 to C5.267
2u-G (part 1) Paraffins, Ci.268
2u-G (part 2) Paraffins, C7.269
3u-G Paraffins, C8.270
5u-G (Heat content, H° — ) Alkylbenzenes, C6 to C9.271
8u-G (part 1) ( H°, to 1,200°C, )j Monoolefins, C2 to C4.272
8u-G (part 2) ’ [ in cal/g. J | Monoolefins, C5.273
8u-G (part 3) Monoolefins, Ci. 274
12u-G Acetylenes, C2 to C5.275
20u-G Normal paraffins, Ci to C20.276
2 lu-G Normal alkylbenzenes, C6 to C22 .277
24u-G Normal monoolefins (1-alkenes), C2 to C2o.278
25u-G Normal acetylenes (1-alkynes), C2 to C2o. .279
XI
OOv ] (0,H,X,C.280
Ov | |02,H2,0H,H20,N2,N0,C,C0,C02.281
1v I Paraffins, Ci to C6.282
2v (part 1) | Paraffins, C6.283
2v (part 2) | Paraffins, C7.284
3v Paraffins, Cg.285
5v Alkylbenzenes, Cg to C9.286
7v [Heat capacity,} Alkylcyelohexanes, C6 to Cg.287
8v (part 1) | C°, to l,500°kA Monoolcfins, C2 to C4.288
8v (part 2) ({ in cal/deg mole.j Monoolcfins, C5.289
8v (part 3) Monoolefins, C6.290
12v Acetylenes, C2 to C5.291
20v Normal paraffins, Ci to C20.292
21 v Normal alkylbenzenes, C6 to C22 .293
22 v Normal alkyleyelopentanes, C5 to C2i . . . .294
23v Normal alkylcyelohexanes, C6 to C22 .295
24 v Normal monoolefins (1-alkenes), C2 to C20.296
25v Normal acetylenes (1-alkynes), C2 to C2o. .297
Ov-E f02,H2,0H,H20, N2,N0,C,C0,C02.298
1 v-E Paraffins, Ci to C5.299
2v-E (part 1) Paraffins, Cg.300
2v-E (part 2) Paraffins, C7.301
3v-E Paraffins, C8.302
5v-E (part 1) Alkylbenzenes, C6 to Cs.303
ov-E (part 2) Alkylbenzenes, C9.304
Sv-E (part 1) fHeat capa-] Monoolcfins, C2 to C4.305
Sv-E (part 2) I dty, C,°, | Monoolefins, C5.306
8v-E (part 3, page 1) l; to 2,200 Monoolefins, Cg.307
8v-E (part 3, page 2) h °F, in f Monoolefins, C6.308
12 v-E I Btu/lb°F.| Acetylenes, C2 to C5.309
20v-E (part 1) Normal paraffins, Ci to C10.310
20v-E (part 2) Normal paraffins, Cu to C20.311
21v-E (part 1) Normal alkylbenzenes, Cg to Cu.312
21 v-E (part 2) Normal alkylbenzenes, Cu to C22.313
24v-E (part 1) Normal monoolefins (1-alkenes), C2 to Cu 314
24v-E (part 2) Normal moonolefins (1-alkenes), C[2to C2o 315
25v-E (part 1) Normal acetylenes (1-alkynes), C2 to Cn 316
25v-E (part 2) Normal acetylenes (1-alkynes), Ci2 to C20.317
Ov-G (02,H»,0H,H20,N2,N0,C,C0,C02.318
lv-G Paraffins, Ci to C5. . .319
2v-G (part 1) Paraffins, Cg.320
2v-G (part 2) Paraffins, C7.321
3v-G Paraffins, Cg.322
5v-G fHeat capacity,} Alkylbenzenes, C6 to C9.323
8v-G (part 1) \C,°, to 1,200°C,) I Monoolefins, C2 to C4.324
8v-G (part 2) (in cal/g °C. J Monoolefins, C5.325
8v-G (part 3) Monoolefins, Cg.326
12v-G Acetylenes, C2 to C5.327
20v-G Normal paraffins, Ci to C2o.328
21v-G Normal alkylbenzenes, Cg to C22 .329
24v-G Normal monoolefins (1-alkenes), C2 to C20 330
25v-G Normal acetylenes (1-alkynes), C2 to C2o. .331
OOw i'0,H,N,C.332
0\v 0,,H2,0H,H20,N2,N0,C,C0,C02.333
l\v Paraffins, Ci to C5.334
2\v (part 1) Paraffins, C6.335
2\v (part 2) Paraffins, C7.336
3\v Paraffins, C8.337
5w Alkylbenzenes, Cg to C9.338
7w (Heat of formation,1 Alkylcyelohexanes, Cg to Cg.339
8\v (part 1) I- to 1,500°K,V Monoolefins, C2 to C4.340
8\v (part 2) | [ in kcal/mole. J) Monoolefins, C5.341
8\v (part 3) Monoolefins, Cg.342
12\v Acetylenes, C2 to C5.343
20 \v Normal paraffins, Ci to C20.344
21 w Normal alkylbenzenes, Cg to C22 .345
22w Normal alkyleyelopentanes, C5 to C24 . . . .346
23w ! Normal alkylcyelohexanes, Cg to C22 .347
24\v ] Normal monoolefins (1-alkenes), C2 to C2o .348
25w [Normal acetylenes (1-alkynes), C2 to C2n. .349
XU
OOx f(),H,N,C.350
Ox 02,H2,0H,H20,N2,N0,C,C0,C02.351
lx Paraffins, Ci to C8.352
2x (part 1) Paraffins, C6.353
2x (part 2) Paraffins, C7.354
3x Paraffins, C8.355
5x fFree energy of forma-) Alkylbenzenes, C6 to C9.356
7x tion, AFf°, t o | Alkylcyclohexanes, C6 to C8.357
8x (part 1) ( 1,500°K, in kcal/ H Monoolefins, C2 to C4.358
8x (part 2) { mole. J Monoolefins, C6.359
8x (part 3) Monoolefins, C6.360
12x Acetylenes, C2 to C5.361
20x Normal paraffins, Ci to C20.362
21x Normal alkylbenzenes, C6 to C22 . 363
22x Normal alkylcyclopentanes, C6 to C2l . . . .364
23x Normal alkylcyclohexanes, C8 to C22 . 365
24x Normal monoolefins (1-alkenes), C2 to C2o366
25x Normal acetylenes (1-alkynes), C2 to C20. .367
OOy fO,H,N,C.368
0y 02,H2,0H,H20,N2,N0,C,C0,C02.369
iy Paraffins, Ci to C5.370
2y (part 1) Paraffins, C6.371
2y (part 2) Paraffins, C7.372
3y Paraffins, C8.373
5y Alkylbenzenes, C6 to C9.374
7y fLogarithm of equili-1 Alkylcyclohexanes, C6 to C8.375
8y (part 1) J brium constant o/U Monoolefins, C2 to C4.376
8y (part 2) ) formation, toil Monoolefins, Cs.377
8y (part 3) ( 1,500°K, logioA/.j Monoolefins, C6.378
12y Acetylenes, C2 to C5.379
20y Normal paraffins, Ci to C2o.380
21y Normal alkylbenzenes, C8 to C22 . 381
22y Normal alkylcyclopentanes, C5 to C2i . . . .382
23y Normal alkylcyclohexanes, C6 to C22 .383
24 y Normal monoolefins (1-alkenes), C2 to C2o 384
25y Normal acetylenes (1-alkynes), C2 to C20. .385
lz Heat of fusion, AHm°, in kcal/ (Paraffins, Ci to Cs.j .386
2z (part 1) mole. Paraffins, C6. .387
2z (part 2) Entropy of fusion, ASm°, in Paraffins, C7. .388
3z cal/deg mole. Paraffins, C8. .389
5z Freezing points, in air at 1 I Alkylbenzenes, C8 to C9 . . .390
6z atm, in °C and °K. | Alkylcyclopentanes, C5 to C .391
7z Cryoscopic constants. J Alkylcyclohexanes, C6 to C8 .392
8z (part 1) ] Monoolefins, C2 to C4. .393
8z (part 2) (Monoolefins, C5. .394
IV. SPECIFIC REFERENCES FOR TABLES OF PROPERTIES.395

la, la-E, and lb.396
2a (part 1), 2a-E (part 1), and 2b (part 1).397
3a, 3a-E, and 3b.399
5a, 5a-E, and 5b.402
6a, 6a-E, and 6b.404
7a, 7a-E, and 7b.405
10a (part 1), lOa-E (part 1), and 10b (part 1).410
11a (part 1), lla-E (part 1), and lib (part 1).415
11a (part 2), I la-E (part 2), and 1 lb (part 2).416
12a, 12a-E, and 12b.417
13a, 13a E, and 13b.418
14a, 14a-E, and 14b.419
15a, 15a- E, and 15b.421
20c, 20c-E, and 20c-K.422
lk.423
2k (part 1).423
2k (part 2).424
3k.424
5k.425
Xlll
6k.425
7k.426
8k.426
lm.427
2m.427
3m.428
4m.429
5m.430
6m.430
7m...431
8m.431
n.432
Op.433
lp.434
2p.435
3p.436
5p.437
8p (part 1).438
8p (part 2).439
12p.440
20p.441
21 p.442
24 p.443
25p.444
q.445
OOr, 00s, OOt, OOu, OOv, OOw, OOx, and OOy.446
Or, Os, Ot, Ou, Ou-E, Ou-G, Ov, Ov-E, Ov-G, Ow, Ox, and Oy.447
lr, Is, It, lu, lu-E, lu-G, lv, lv-E, lv-G, lw, lx, and ly.448
2r, 2s, 2t, 2u, 2u-E, 2u-G, 2v, 2v-E, 2v-G, 2w, 2x, and 2y (parts 1).449
3r, 3s, 3t, 3u, 3u-E, 3u-G, 3v, 3v-E, 3v-G, 3w, 3x, and 3y.451
7r, 7s, 7t, 7u, 7v, 7w, 7x, and 7y.453
22r, 22s, 22t, 22u, 22v, 22w, 22x, and 22y.460
23r, 23s, 23t, 23u, 23v, 23w, 23x, and 23y.461
lz.464
2z (part 1).465
2z (part 2).466
3z.467
5z.468
6z. 469
7z.470
8z (part 1).471
8z (part 2).472
V. GENERAL LIST OF REFERENCES.473

VI. PUBLICATIONS OF THE AMERICAN PETROLEUM INSTITUTE RESEARCH
PROJECT 44 .483
SELECTED VALUES OF
By
Frederick D. Rossini, Kenneth S. Pitzer,
William J. Taylor, Joan P. Ebert, John E. Kilpatrick,
Charles W. Beckett, Mary G. Williams, and Helene G. Werner
I. INTRODUCTION
Fundamental Constants and Conversion Factors Internal Consistency
The values selected for the fundamental and The tables of the API Research Project 44 are
derived constants required in the preparation of internally consistent in the sense that all the
the tables of selected values of properties of known physical and thermodynamic relations
hydrocarbons issued by the American Petro¬ existing between the properties in the several
leum Institute Research Project 44 are in all tables are satisfied by the tabulated values of
cases those given in table a (parts 1, 2, and 3). these properties. Thus, the values in the a-E
The original sources upon which this set of self- and b tables are based on the appropriate values
consistent values of the constants is based are in the a tables, and the boiling and freezing
listed in the footnote to table « (part 3). The points in the a tables are, insofar as possible,
conversion factors in table (3 (parts 1 to 11) and consistent with the corresponding values in the
the numerical constants in table 7 are calculated k and z tables, respectively. The thermodynamic
directly from the values of the fundamental relations that exist between the properties in
constants given in table a (parts 1, 2, and 3). the k, m, n, p, q, r, s, t, u, u-E, u-G, v, v-E, v-G,
In the few cases in which a special constant or w, x, y, and z tables are satisfied by the tabu¬
conversion factor not included in table « (parts lated values, and they therefore form an inter¬
1, 2, and 3) or table /3 (parts 1 to 11) has been nally consistent set of tables of the thermody¬
required in the preparation of a table, the value namic properties.
selected is indicated in a footnote to the appro¬
Sources of Data
priate table. Values of molecular weights are
given in table 8. The-sources of data are given specifically for
Temperature Scale each property of each compound, as appropriate,
in section IV on Specific References for Tables
In these tables temperatures given in degrees of Properties. Section IV gives the names of the
centigrade (°C) which are based on experi¬ author or authors of a given publication, to¬
mental measurements, as for example, boiling gether with a numeral superscript on the last
points and freezing points, are referred to the author’s name, indicating the number of the
International Centigrade Temperature Scale publication for that particular author or group
(see Burgess1 and Mueller1 in section V). As of authors. From this, the complete reference
appropriate, these temperatures have been con¬ to the publication in the literature is obtained
verted to degrees Kelvin (°K) by the relation from the General List of References in section
(°K) — (°C) +273.160, and to degrees Fahren¬ V, in which the names are arranged alpha¬
heit (°F) by the relation (°F) =1.8(°C) +32. betically, with the publications of each author
The differences between temperatures on the or group of authors listed in numerical order.
international and thermodynamic scales are Initials of authors are not given unless two or
discussed by E. F. Mueller in the reference more authors or groups of authors have identi¬
cited. cal surnames.
Temperatures given in degrees Kelvin (°K) The specific references in section IV apply
in the tables of thermodynamic functions (tables as of the date indicated. In general, the specific
designated by the letters r, s, t, u, v, w, x, and y) references are intended to include all sig¬
are on the Kelvin thermodynamic temperature nificant work published since 1936, but only
scale. These temperatures have been converted the more important work published prior to
to degrees centigrade (°C), in the u-G and v-G that time. At the beginning of the work of the
tables, by the relation (°C) = (°K)-273.160, Project, original publications were located prin¬
and to degrees Fahrenheit (°F), in the u-E and cipally through searches of Chemical Abstracts,
v-E tables, by the relation (°F) =1.8(°K)— Annalen der Chemie, the bibliographies given
459.688. in the existing compilations of Egloff1-2-3-'4,
1
2
Doss1, Francis1, Ward and Kurtz1, International Explanation of Letters in Titles of Tables
Critical Tables1- and Landolt-Bornstein-Roth1.
The bibliographies of Egloff represent searches The letters in the titles of the tables of properties
of Beilstein’s Handbuch der Organischen represent the following properties:
Chemie, Chemisches Zentralblatt, and British Letter Properties
Chemical Abstracts. Credit for the considerable a. .... . .Values of fundamental constants.
amount of as yet unpublished data that has been (3.Conversion factors.
made available to the Project is given in the ap¬ 7 .Useful equations with numerical constants.
propriate places in section IV on specific ref¬ 8 .Molecular weights.

a.Boiling point (°C), dt/dp (°C/mm Hg), refractive
erences. index, density (g/ml), and freezing point (°C).
a-E.Boiling point (°F), dt/dp (°F/in. Ilg), refractive
index, density (lb/ft3 and lb/gal), specific gravity
Methods of Calculation (60° F/60° F), and freezing point (°F).
b.Molecular volume (ml/mole), molecular refraction
The methods of calculation have been, or will (ml/mole), specific refraction (ml/g), refractivity
intercept, and specific dispersion (ml/g).
be, described in comprehensive reports of in¬ c.Viscosity (absolute) (centipoises), at temperatures
vestigations published as part of the work of the in °C.
API Research Project 44. References to such c-E.Kinematic viscosity (centistokes), at temperatures
in °F.
reports as have been published are given in the
c-K.Kinematic viscosity (centistokes), at temperatures
appropriate places in section IV. Information in °C.
concerning unpublished work of this nature may k.Vapor pressures (mm Hg) and boiling points (°C)
be obtained by writing the National Bureau of at 10 to 1,500 mm Hg.
m.Heat of vaporization (kcal/mole, cal/g, Btu/lb) and
Standards. A list of the publications of the API
entropy of vaporization (cal/deg mole), at 25°C
Research Project 44 is given in section VI of and the normal boiling point.
this volume. n.Heat of combustion (kcal/mole, cal/g, and Btu/lb),
at 25°C.
p.Heat of formation (kcal/mole), entropy (cal/deg
mole), and free energy of formation (kcal/mole),
Explanation of Numbers in Titles of Tables at 25° C.
q.Standard heat of vaporization (kcal/mole), entropy
The numbers in the titles of the tables of proper¬ of vaporization (cal/deg mole), and free energy of
ties represent the following groups of compounds: formation (kcal/mole), at 25° C.
r.Heat-content function, (H° — H0°)/T, (cal/deg
Number Compounds mole) at 0° to 1,500°K.
s.Free-energy function, (F° — H°)/T, (cal/deg mole)
00 O, H, N, C.
at 0° to 1,500°K.
0 02,H2,0H, H20, N2,NO,C, CO, C02.
t.Entropy, S°, (cal/deg mole) at 0° to 1,500°K.
1 Paraffins, Ci to C5
u.Heat content, //° — H° (cal/mole), at0° to 1,500° K.
2 Paraffins, C6 and C7.
u-E.Heat content, H° — H0°, (Btu/lb), at —459.69° to
3 Paraffins, C8.
2,200° F.
4 Paraffins, C9.
u-G.Heat content, — (cal/g), at —273.16° to
5 Alkylbenzenes, C6 to C9.
1 200° C
6 Alkylcyclopentanes, C6 to C7.
v.Heat capacity, Cp°, (cal/deg mole), at0°to 1,500° K.
7 Alkylcyclohexanes, C6 to C8.
v-E.Heat capacity, Cv°, (Btu/lb °F), at —459.69° to
8 Monoolefins, C2 to C6.
2,200° F.
9 Monoolefins, C7.
v-G.Heat capacity, C,°, (cal/g °C), at —273.16° to
10 Monoolefins, C8.
1,200° C.
11 Diolefins, C3 to Cs.
w.Heat of formation, AHf°, (kcal/mole), at 0° to
12 Acetylenes^ C2 to C5.
1,500° K.
13 Styrenes, C8 and C9.
x.Free energy of formation, AFf°, (kcal/mole), at 0°
14 Alkylbenzenes, C10.
to 1,500° K.
15 Alkylcyclopentanes, Cg.
y.Logarithm of equilibrium constant of formation,
20 Normal paraffins, Ci to C2o.
logioK/, at 0° to 1,500° K.
21 Normal alkylbenzenes, C6 to C22.
z.Heat of fusion (kcal/mole), entropy of fusion (cal/
22 Normal alkylcyclopentanes, C5 to C2i.
deg mole), freezing points (°C and °K), and cryo-
23 Normal alkylcyclohexanes, Ce to C22.
scopic constants (deg-1).
24 Normal monoolefins (1-Alkcnes), C2 to C2o.
25 Normal acetylenes (1-Alkynes), C2 to C2o.
Uncertainties
Frequently, one page will not accommodate all It is not feasible to give estimated uncertain¬
the values of a given group of properties for the ties for each of the individual numerical values
entire lot of compounds coming under one num¬ of the physical and thermodynamic properties.
ber. In such cases, the given lot of compounds However, an indication of the magnitude of the
will be subdivided, as table 10 (part 1), table estimated uncertainties is given in the accom¬
10 (part 2), etc. panying table.
3
M ACi N ITU OK OF THE ESTIMATED UNCERTAINTIES
WHEN VALUE IS WRITTEN TO—
Property Units 1 0.1 0 01 0.001 0.0001 0.00001
Uncertainty is estimated to be—
Boiling point. )
y (len C. > i
f 0.2 0.03
to
0 005
to
Freezing point. J (
t0
1.0 0.15 0.020
Refractive index. ftl) ] f 0.003 0.0002 0.00005

l > 0.02
Density.7. K/ml 1 ( 0.020 0.0020 0.00015
Viscosity (absolute). Centipoise | >0.1 j

f 0.02
to
0.002
to
0.0010
to
.
Kinematic viscosity. Centistoke ( 0.20 0.020 0.0030
Heat content function1. 1 0.10 0.005

> 0.75
Entropy1. 0.75 0.050
Heat capacity1.
J l
Heat of formation. f 0.15 0.015

> 1.0
Free energy of formation. ( 1.00 0.200
f 0.04 0.010
> 0.2
1 0.20 0.040
f 0.04 0 004 0.0010

> 0.2
( 0.20 0.040 0.0040
1 The values at 298.10° and 300° K. are frequently given to one more decimal place than are the corresponding values at higher temperatures.
In these cases the estimated uncertainty is indicated by the number of decimal places retained at the next higher temperature.
745211 0 - 47 -2
4
Summary of Tables
A summary of the tables of numerical values prepared as of May 31,1947, is given in the follow¬
ing table:
Summary of Tables as of May 31, 1947
!S
J bj
^
No. 00 0 i 2 3 4 5 7 8 9 10 11 12 13 14 15 17 18 in 20 24
|
|
|
<5
o
d
o X
Normal acetylenes (1-alkynes)

01
c
Alkylcyclopentanes, Cs to C7
o' 6
Normal alkylcyclopentanes
O CJ
| Normal alkylcyclohexanes
o 0
0
0
z 6
Normal alkylbenzenes
Properties CJ
Alkylcyclohexanes, C#
0 CJ
o CJ Cj
z 6 O 6 01 c
6 o>
O
O O c
s
c 8 <a01
m
o' o
T3
C
CJ c
cl O
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c
Cj e3 V c
01 c
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a S3 c3
<2 X
01 O
o3 <2 C
Ol
c
01 0)
€
03
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c
<v
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JD c c C Cj u
c a
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0 03
S3 x X X 0i a
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o co to c 0 CJ c CO* c 0
c c O) — c ID 01 c
CL.
C
£ £ £
c
X
X
O 0 O
O
O
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0>
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j
Letter Number in block indicates number of pages
Boiling point in °C at 760 mm

Hg; dt/dp in °C/mm Hg;
refractive index, np, and
density in g/ml, at 20° and
25°C; freezing point in °C
a l 2 i 2 1 1 1 2 2 5 2 1 1 1 1 24
Boiling point in °F at 29.921
in. Hg; dt/dp in °F/in. Hg;
refractive index, np, at 68°
and 77°F; density, in lb/fts,
lb/gal at 60°, 68°, and77°F;
specific gravity (60°F/60°-
F); freezing point, in °F at
a-E l 2 i 2 1 1 2 2 5 2 1 1 1 24
Molecular volume and refrac¬
tion in ml/mole; specific re¬
fraction and dispersion in
ml/g; refractivity intercept;
all at 20° and 25°C. b l 2 i 2 1 1 1 2 2 5 2 1 1 1 1 24
Viscosity (absolute) in centi-
poise at given temperatures
c 4 4
Kinematic viscosity in centi-
stokes at given tempera-
c-E 4 4
Kinematic viscosity in centi-

stokes at given tempera-
c-K 4 4
i
Pressure-volume-temperature
j
Vapor pressures and boiling
points in °C; at 10 to 1,500
k l 2 2 2 1 2 1 1 1
Vapor pressure and boiling
k-E
Heat of vaporization, A//r,

at 25°C and boiling point in
kcal/mole, cal/g, and Btu/
lb. Entropy of vaporiza¬
tion, ASv, at boiling point
m 1 1 i 1 1 1 1 1 s
Heat of combustion,A//c°, at
25°C, for liquid and gas, in
kcal/mole, cal/g, and Btu/
lb n 1 1 1 i 1 2 •> 1 1 1 1 1 1 1 16
1
5
No. 00 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
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and C9
d co a c
CD o a; 2 £ ca 03
d C CD d o C 03 c S co c £
o' d
S3 C d
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m o S3 o 03 £ >> "o £
O X C X d d d to C c X E 0 O ">»
C c 03 >> >> >> c
z 6 d d d 03 a -C
C d CD
a -C d a XI Jd £ 0 03
V EC C C d 03 V
o to" to C/3 c o tfl cn ID
"o co" 0 a 03 03 S3 £ S3
o CO "o (D CD <2 c C
<D
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£ £ £ o o o O <D 0
o o3 03 a3 03 o >> e5 O O O O O
o o' 6 Ph Ph Oh Ph < < s s s < < < < Ph < < z £ £ £ H
1 >etter Number in block ndicates numbe of pages
Heat of formation, AHf°, and

free energy of formation,
AFf°, in kcal/mole; En-
topy, S°, in cal/deg mole, all
for liquid and gas, at 25°C. . l l i i 1 2 i 1 1 1 1 12
Standard heat of vaporization,
AHv°, and free energy of
vaporization, AFv° in kcal/
mole, at 25°Cj standard en¬
tropy of vaporization, ASv°,
in cal/deg mole, at 25°C.. . q l i l l 1 5
Heat-content function, (H° —
Ho°)/T, to l,500°K,in cal/

1 i l 2 1 l i 3 1 1 1 1 1 1 1 18
Free-energy function, (F° —
IIo°)/T, to 1,500°K, in cal/ -

8 i 1 l 2 l i i 3 1 1 1 1 1 1 1 18
Entropy, S°, to 1,500°K, in
t l i l 2 l l i 3 i 1 1 1 1 1 1 18
Heat content, H° — Ho°, to
U 1 i 1 2 l l i 3 i 1 1 1 1 1 1 18
Heat content, 11°— IIo°, to
2,200°F, in Btu/lb. u-E i 1 2 2 2 4 i 2 2 2 2 21
Heat content, 11° —11°o, to
u-G l l 2 1 1 3 i 1 1 1 1 14
Heat capacity, Cp°, to 1,500°-

l i l 2 i 1 i 3 i 1 1 1 1 1 1 18
v-E 1 l 2 1 2 4 i 2 2 2 2 20
v-G i l 2 i i 3 i 1 1 1 1 14
Heat of formation, A///°, to
w l i 1 2 i 1 i 3 i 1 1 1 1 1 1 18
Free energy of formation, A-
Ff°, to 1,500°K, in kcal/
X l i l 2 i 1 i 3 i 1 1 1 1 1 1 18
Logarithm- of equilibrium
constant of formation, logio
Kf, to 1,500°K. l i 1 2 i 1 i 3 1 1 1 1 1 1 1 18
Heat of fusion, AIIm°, in
kcal/mole; entropy of fu¬
sion, ASm°, in cal/deg mole;
cryoscopic constants (A,B)
freezing point in °C and °K
1 2 i i 1 2 9
Total 8 14 21 38 23 7 24 6 16 52 8 15 6 17 3 3 3 28 16 9 9 16 16 358
Values of fundamental con-

a 3
p 7
Useful equations with nu-
y 1
8 16
II. TABLES OF FUNDAMENTAL CONSTANTS, CONVERSION FACTORS, USEFUL
EQUATIONS, AND MOLECULAR WEIGHTS
7
8 SELECTED VALUES OF PROPERTIES OF HYDROCARBONS
National Bureau of Standards Washington, D, C.
TABLE a (Part 1) - VALUES OF CONSTANTSa
December 31, 1944; revised March 31, 1945
1 sec = 1.00273791 sidereal second sec = mean solar second
g0 = 980.665 cm/sec2 , Definition; gQ = standard gravity
1 liter = 1000.028 * 0.004 cm3
1 atm = 1,013,250. dynes/cm2 Definition; atm = standard atmosphere
1 mm Hg = (1/760) atm 1
mm Hg = standard millimeter mercury
= 1333.2237 dynes/cm2 J
1 lnt. ohm = 1.000494 ± 0.000015 abs.ohm b lnt. = International; abs. = absolute
1 lnt. amp = 0.999838 ± 0.000025 abs.amp b amp - ampere
1 lnt. coul - 0.999838 + 0.000025 abs.coul b coul = coulomb

b
1 lnt. volt = 1.000332 ± 0.000029 abs.volt
b
1 lnt. watt = 1.000170 t 0.000052 abs.watt
b
1 lnt.Joule = 1.000170 ± 0.000052 abs.Joule
1 cal = 4.1833 lnt.Joule Definition; cal = thermochemical calorie
= 4.18401 ± 0.00020 abs.Joule
= 41.2930 ± 0.0020 cm3atm
= 0.0412918 ± 0.0000020 liter atm
T0oc = 273.160 t 0.010°K Absolute temperature of the Ice-point, 0°C
(PV) 0°C = (RTW = 2271,16 * 0,04 abs*Joule/mole I

= 22414.6 ± 0.4 cm3atm/mole >PV product for ideal gas at 0°C
= 22.4140 + 0.0004 liter atm/mole J

>
R = 8.31439 + 0.00034 abs.Joule/deg mole
= 8.31298 + 0.00054 lnt.Joule/deg mole
= 1.98718 + 0.00013 cal/deg mole ►R = gas constant per mole
= 82.0567 t 0.0034 cm3 atm/deg mole
= 0.0820544 + 0.0000034 liter atm/deg mole >
In 10 = 2.302585 In = natural logarithm (base e)
R In 10 = 19.14459 + 0.00078 abs.Joule/deg mole
- 19.14134 -t 0.00124 lnt. Joule/deg mole
= 4.57566 t 0.00030 cal/deg mole
N = (6.02283 ± 0.0022) x 1023 /mole N = Avogadro number
k = (R/N)= (1.38048 + 0.00050) x 10-16 erg/deg k = Boltzmann constant
a See footnote to Table a (Part 3).
b The International electrical units used In these tables are those In terms of which certification of stand¬
ard cells, standard resistances, etc., Is made by the National Bureau of Standards.
SELECTED VALUES OF PROPERTIES OF HYDROCARBONS 9
National Bureau of Standards Washington, D. C.
TABLE a (Part 2) - VALUES OF CONSTANTS3,
_P7
h = (6.6242 * 0.0044) x 10 erg sec h - Planck constant
c » (2.99776 t 0.00008) x 1010 cm/sec c = Velocity of light
(h2/8TT2k) = (4.0258 + 0.0037) x 10-39 g cm2 deg Constant In rotational partition function
of gases
(h/drr8c) = (2.7986 ± 0.0018) x 10-39 g cm Constant relating wave number and moment
of Inertia
Z ~ Nhc - 11.9600 t 0.0036 abs. Joule cm/mole
• Z = Constant relating wave number
« 11.9580 * 0.0036 lnt. joule cm/mole and energy per mole
=2.85850 * 0.0009 cal cm/mole
(Z/R) = (hc/k) = c2 = 1.43847 * 0.0QC45 cm deg Second radiation constant
y= 96501.2 ± 10.0 lnt. coul/g-equlv or

lnt. joule/lnt.volt g-equlv
- 96485.6 * 10.0 abs. coul/g-equlv, or
abs. Joule/abs.volt g-equlv T= Faraday constant
«= 23068.2 ± 2.4 cal/lnt.volt g-equlv
= 23060.6 ± 2.5 cal/abs.volt g-equlv
(T/R) = 11608.50 ± 1.40 deg/lnt.volt
= 11604.65 ± 1.30 deg/abs.volt
(7/RlnlO) = 5041.51 ± 0.62 deg/lnt.volt
= 5039.84 + 0.67 deg/abs.volt
e = (1.60200 * 0.00060) x 10-19 abs.coul
= (1.60200 t 0.00060) x 10"20 abs.e.m.u. e = Electronic charge
= (4.80240 t 0.00180) x 10-10 abs.e.s.u.
1 lnt.electron-volt/molecule = 96501.2 ± 10. lnt. Joule/BTole

= 23068.2 t 2.4 cal/mole
1 abs.electron-volt/molecule = 96485.6 ± 10. abs. Joule/mole
= 23060.6 ±2.5 cal/mole
1 lnt.electron-volt = (1.60253 * 0.00060) x 10-12 erg
1 abs.electron-volt = (1.60200 * 0.00060) x 10-12 erg
he = (1.23915 * 0.00032) x 10-4 lnt.electron-volt cm Constant relating wave number and energy
per molecule
= (1.23956 * 0.00032) x 10-4 abs.electron-volt cm
k = (8.61438 * 0.00100) x 10-5 lnt.electron-volt/deg
Boltzmann constant
= (8.61723 * 0.00100) x 10“5 abs.electron-volt/deg
See footnote to Table « (Part 3).

TABLE a (Part 3) - VALUES OF CONSTANTS3

1 I.T. cal = (1/860) = 0.00116279 lnt.watt-hr Definition of I.T. cal;

I.T. = International steam tables
= 4.18605 lnt.Joule
= 4.18676 abs.Joule
= 1.000657 cal cal = thermochemical calorie
1 I.T. cal/g =1.8 BTU/lb Definition of BTU;
BTU = I.T. British Thermal Unit
1 BTU = 251.996 I.T. cal
= 0.293018 lnt.watt-hr
= 1054.366 lnt.Joule
= 1055.045 abs.Joule
= 252.161 cal cal = thermochemical calorie
1 horsepower = 550 ft-lb(wt)/sec Definition of horsepower (mechanical);
lb(wt) = weight of 1 lb at standard gravity
= 745.575 lnt.watt
1 In. = (1/0.3937) = 2.54000508 cm Definition of In.; In. = U.S. Inch
1 ft = 30.4800610 cm ft = U.S. foot (1 ft = 12 in.)
1 lb = 453.5924277 g Definition; lb = avoirdupois pound
1 gal = 231 cu In. Definition; gal = U.S. gallon
= 0.133680555 cu ft
= 3785.43449 cm3
= 3.785329 liter
3 For details, reference Is made to the following reports:

Baxter, Guichard, Honlgschmld, and Whytlaw-Gray1.
Birge1
Birge2
Burgessl
Cragoe3
Curtis1
Mueller and Rossinil
National Bureau of Standards2
Peffer and Mulligan1
Wagman, Kilpatrick, Taylor, Pitzer and Rossini1
National Bur.au of Standard. Amarican P.trolmun In.titute He.earch Project 44 Wuhington, D. C.
TABLE £ (Part 1) - CONVERSION FACTORS3
UNITS OF LENCTH
January 31, 1945
CO
S
/K
a
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o
8
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C^
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1 centimeter (cm) = 108
1
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rH
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1 Angstrom unit (A) =
To convert the ramerical value of a property expressed In one of the units In the left-hand column of the table to the numerical value of the same property expressed
11
In one of the units In the top row of the table, multiply the former value by the factor In the block common to both units.
cd
To convert the numerical value of a property expressed in one of the units in the left-hand column of the table to the
SELECTED VALDES OF PROPERTIES OF HYDROCARBONS
*
*
aJ
To convert the numerical value of a property expressed In one of the units In the left-hand column of the table to the numerical value of the same property ex-
13
ft
cd
To convert the numerical value of a property expressed In one of the units In the left-hand column of the table to the numerical value
§
CQ
£
xn
a
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pressed In one of the units In the top row of the table, multiply the former value by the factor In the block common to both units.
15
16
00 lO
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to the numerical value of the same

to C
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CM
oo io 05 lO
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CQ O
CO «-H
to
2
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To convert the numerical value of a property expressed In one of the units In the left-hand column of the table to the numerical value of the same property ex'
17
TABLE r (Bart 1’) - USEFUL EQUATIONS WITH NUMERICAL CONSTANTS
FOR CALCULATING THE THERMODYNAMIC FUNCTIONS FOR
TRANSLATION (OF ALL MOLECULES) AND ROTATION (OF RIGID MOLECULES)

»
January 31, 1945
Definitions and Units: The equations In this table may be used to calculate the translational and
rotational contributions (In cal/deg mole) to the heat content function, (H°- Hq°)/T,
the free energy function, (F°- H0°)/T, and the entropy, S°, the translational heat capa¬
city at constant pressure, Cp°, and the rotational heat capacity, C°; all for a gas in
the thermodynamic standard gaseous state of unit fugaclty (1 atmosphere), at the given
absolute temperature T(ln °K). M Is the molecular weight (g/mole). I (g-cm2) la the
value of the two equal moments of Inertia of a linear molecule about axes perpendicular
to the axis of the molecule; and 1^, I2, and I3 (g-cm2) are the three principal moments
of Inertia of a nonlinear molecule. The symmetry number, « (a dimensionless Integer),

Is the number of ways the molecule may be superimposed upon Itself by rotation of^the
entire molecule»a log - common logarithm (to the base 10).
TRANSLATION
(of all molecules)
(H°- Hq°)/T = Cp° = 4.9680
(F°— Ho°)/T = - 6.8635 log M + 7.2820 - 11.4391 log T
S° = 6.8635 log M - 2.3141 + 11.4391 log T
ROTATION
(of rigid molecules)
I. Diatomic or linear polyatomic molecules
(H°- Hq°)/T = C° = 1.9872
(a) g (symmetry number) = 1:
(F°- H0°)/T = - 4J5757 log(I X 1039) + 2.7676 - 4.5757 log T
S° = 4.5757 log(I x 1039) - 0.7804 + 4.5757 log T

«
(b) a (symmetry number) = 2:
(F°- Hq°)/T = - 4.5757 log(I X 1039) + 4.1450 - 4.5757 log T
S° = 4.5757 log(I X 1039) - 2.1578 + 4.5757 log T
II. Nonlinear polyatomic molecules
(H°- h0°)/t = C° = 2.9808
(F°- Hq°)/T = - 2.2878 log^ I2 I3 X 10117) + 4.5757 log * + 3.0140 - 6.8635 log T
S° = 2.2878 logU-L I2 I3 X 10117) - 4.5757 log - 0.0332 + 6.8635 log T
a For further details, reference may be made to Tolman* or Mayer and Mayer*.
o 19
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20

National Bureau of Standards Washington. D. C
The values of molecular weights In this table are based on the atomic weights. c= 12.010, H= 1.0080, as given In the Thirteenth Report of the Committee on Atomic
Weights of the International Union of Chemistry, Baxter, Gulchard, and Whytlaw-Grayl.
21
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SELECTED VALUES OF PROPERTIES OF HYDROCARBONS
23
24
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22 382.476 394.486
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23 383.484 395.494 407.504
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443.534 455.544
LO
O
tO
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467.554 491.574
24 384.492 396.502 408.512
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420.522
CO
432.532
Cl
444.542
LO
456.552
Q
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468.5C2 492.582
25 385.500 397.510 409.520 433.540
CO
CO
421.530
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LG
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LO
445.550
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457.560 - 469.570 493.590

26 386.508 398.518 410.520
CO
CD
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422.530 434.548 446.558

LO
Q
CO
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458.568 470.578 494.596

27 387.516 399.526 411.536
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423.546
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to
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459.576 471.586 495.606

28 388.524 400.534 412.544
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460.584 472.594 496.614

29 389.532 401.542 413.552 425.562
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437.572 449.582
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461.592
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473.602
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497.622
30 390.540
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414.560 426.570
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450.590 462.600 474.G10 498.630

31 391.548 403.558
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427.570 439.588
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463.600 475.618 499.638

32 392.556 404.566 416.576
CC
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428.586
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440.596
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464.616 476.626 500.646

33 393.564 405.574 417.584
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429.594 441.604
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453.614
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465.624 477.634 501.654

34 394.572 406.582
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35 395.580 407.590
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419.600 431.610
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443.620 455.630 467.640 479.650 503.670

36 396.588 408.598
C.
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420.608 432.610
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444.628 456.638
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468.648 480.658 504.678

37 397.596 409.606
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421.616
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433.626
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445.636 457.646 469.656 431.666 505.686

38 398.604 410.614
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434.634 446.644
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458.654
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470.664 482.674 506.694

39 399.612 411.622 423.632
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c.
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435.642 447.652
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459.662
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471.672 483.682 507.702

40 400.620 412.630 424.640
c,
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440.660 460.670 472.680 434.690 508.710

41 401.628 413.638 425.648
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449.660 4C1.678 473.688 435.698 509.716

42 402.636 414.646
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462.606 474.696 486.706 510.726

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TABLE S (Part 12) - MOLECULAR WEIGHTS
Range: C4Q to C5Q; to
December 31, 1946
No. of number of C atoms

H
s*
1—1
3
5
$
atoms
CO
CO
Cj
8
502.576 514.586 526.596

C]
C2
{-
22 538.606 550.616
CO
562.626 574.636 586.646 598.656 610.666

23 503.584 515.594 527.604 539.614 551.624
r#
563.634
CO
CO
575.644 587.654 599.664 611.674

504.592 516.602 528.612 540.622 552.632
rj<
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24 564.642 576.652
Cj
588.662 600.672 612.682

25 505.600 517.610 529.620 541.630
CO
O
553.640 565.650 577.660 589.670 601.680 613.690

506.608 518.618 530.628 542.638
CO
26 554.648
O
566.658 578.668 590.678 602.688 614.69G

#
507.616 519.626 531.636 543.646
0~
555.656
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27 567.666 579.676 591.686 603.696 615.706

28 508.624 520.634 532.644 544.654 556.664
C2
568.674
CO
580.684 592.694 604.704 616.714

29 509.632 521.642 533.652 545.662 557.672
CD
CO
569.682 581.692 593.702 605.712 617.722

30 510.640 522.650 534.660 546.670
^
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558.680 570.690 582.700 594.710 606.720 618.730

31 511.648 523.658 535.668 547.678
rH
559.688 571.698 583.708 595.718 607.728 619.738

32 512.656 524.666
01
536.676 548.586
lO
560.696 572.706 584.716 596.726 608.736 620.746

33 513.664 525.674 537.684
CO
549.694 561.704
CO
573.714 585.724 597.734 609.744 621.754

34 514.672 526.682
C-
538.692 550.702 562.712 574.722 586.732 598.742 610.752 622.762

35 515.680 527.690
CO
539.700 551.710 563.720 575.730 587.740 599.750 611.760 623.770

36 516.688 528.698
CO
540.708 552.718 564.728 576.738 588.748 600.758 612.768 624.77S

37 517.696 529.706
CT.
541.716 553.726 565.736 577.746 589.756 601.766 613.776 625.786

38 518.704 530.714
O
542.724 554.734 566.744 578.754 590.764 602.774 614.784 626.794

39 519.712
rH
531.722 543.732 555.742 567.752 579.762 591.772 603.782 615.792 627.802

40
02
520.720 532.730 544.740 556.750 568.760 580.770 592.780 604.790 616.800 628.810
41
C2
521.728 533.738 545.748 557.758 569.768 581.778 593.788 605.798 6]f. 808 629.818
42
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31
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TABLE i (Part 14) - MOLECULAR WEIGHTS
Range: C^ to C^; Hffi to
December 31, 1946
No. of Number of C atcms

H
9
atoms 40 41 43 44 OS
o
45 46 47 48
-
62 542.896 554.906 566.916 578.926 590.936 602.946 614.956 626.966 638.976 650.986 .662.996
63 543.904 555.914 567.924 579.934 591.944 603.954 615.964 627.974 639.984 651.994 664.004
64 544.912 556.922 568.932 580.942 592.952 604.962 616.972 628.982 640.992 653.002 665.012
65 545.920 557.930 569.940 581.950 593.960 605.970 617.980 629.990 642.000 654.010 666.020
66 546.928 558.938 570.948 582.958 594.968 606.978 618.988 630.998 643.008 655.018 667.028
67 547.936 559.946 571.956 583.966 595.976 607.986 619.996 632.006 644.016 656.026 668.036
68 548.944 560.954 572.964 584.974 596.984 608.994 621.004 633.014 645.024 657.034 669.044
69 549.952 561.962 573.972 585.982 597.992 610.002 622.012 634.022 646.032 658.042 670.052
70 550.960 562.970 574.980 586.990 599.000 611.010 623.020 635.030 647.040 659.050 671.060
71 551.968 563.978 575.988 587.998 600.008 612.018 624.028 636.038 648.048 660.058 672.068
72 552.976 564.986 576.996 589.006 601.016 613.026 625.036 637.046 649.056 661.066 673.076
73 553.984 565.994 578.004 590.014 602.024 614.034 626.044 638.054 650.064 662.074 674.084
74 554.992 567.002 579.012 591.022 603.032 615.042 627.052 639.062 651.072 663.082 675.092
75 556.000 568.010 580.020 592.030 604.040 616.050 628.060 640.070 652.080 664.090 676.100
76 557.008 569.018 581.028 593.038 605.048 617.058 629.068 641.078 653.088 665.098 677.108
77 558.016 570.026 582.036 594.046 606.056 618.066 630.076 642.086 654.096 666.106 673.116
78 559.024 571.034 583.044 595.054 607.064 619.074 631.084 643.094 655.104 667.114 679.124
79 560.032 572.042 584.052 596.062 608.072 620.082 632.092 644.102 656.112 668.122 680.132
80 561.040 573.050 585.060 597.070 609.080 621.090 633.100 645.110 657.120 669.130 681.140
81 562.048 574.058 586.068 598.078 610.088 622.098 634.108 646.118 658.128 670.138 682.148
82 563.056 575.066 507.076 599.086 611.096 623.106 635.116 647.126 659.136 671.146 683.156
33
III. TABLES OF SELECTED VALUES OF PROPERTIES
Explanation of Arrangement of Tables
The tables of selected values of properties in this section are identified by

a number, which indicates the class of compounds included in the given
table, followed by a letter, which indicates the property or properties which
are tabulated in the given table (in some cases there is a second letter, which
indicates a variation in properties or units). Tables bearing the same letter
are grouped together, and these groups are arranged in alphabetical order
by the identifying letters. The tables within each group are arranged in
numerical order. In order to facilitate the location of individual tables there
are given below : (1) A systematic classification of table numbers by classes
of compounds; and (2) an index of letters identifying tables arranged
alphabetically by names of properties.
745211 0-47-4
35
36
Systematic Classification Of Table Numbers Formation, free energy of, for liquid and gas at 25° C,
By Classes Of Compounds in kcal/mole. p
Free energy of, for gas, to 1,500° K, in kcal/mole. . x
Class of Compounds number Heat of, for liquid and gas, at 25° C, in kcal/mole.. p
I. Xonlmlrocnrbon compounds Heat of, for gas, to 1,500° I\, in kcal/mole. w
Elements Logarithm of equilibrium constant of, for gas, to
O, 11, X, C (monatomic gas). 00 1,500° K... y
02, 11., X:, C (graphite). 0 Free-energy function, for gas, to 1,500° K, in cal/deg
Compounds mole. s
on, ii .o, xo, co, cos. o Free energy of formation, for liquid and gas, at 25° C,
II. 11yd rocarhons in kcal/mole. p
Paraffins (alkanes) For gas, to 1,500° K, in kcal/mole. x
Xormal paraffins, Ci to C2o. 20 Free energy of vaporization, standard, at 25° C, in
Paraffins, C, to C6. 1 kcal/mole. q
Paraffins, C6 to Ct. 2 Freezing point, at 1 atm, in ° C. a
Paraffins, C„. 3 At 1 atm, in °F. a-E
Paraffins, C». 4 At 1 atm, in °C and °K. z
Alkyl cycloparaffins (cycloalkanes) Fusion, entropy of, in cal/deg mole. z
Alkyl cyclopcntanes Heat of, in kcal/mole. z
X'ormal alkyl cyclopentancs, Cj to Temperature of, in °C. z, a
C21. 22 Temperature of, in °F. a-E
Alkvl cyclopcntanes, C6 to C7. 6 Temperature of, in °K. z
Alkyl cyclopcntanes, Cs. 15 Heat capacity, for gas, to 1,500° K, in cal/deg mole. . v
Alkyl cyclohexanes For gas, to 2,200° F, in Btu/lb ° F. v-E
Xormal alkvl eyclohexanes, C6 to C22 23 For gas, to 1,200° C, in cal/g ° C. v-G
Alkyl eyclohexanes, C6 to Cs. 7 Heat content function, for gas, to 1,500° K, in cal/deg
Olefins mole. r
Monoolefins (alkenes) Heat content, for gas, to 1,500° K, in cal/mole. u
Xormal monoolefins (1-alkenes), C2 For gas, to 2,200° F, in Btu/lb. u-E
to C20. 24 For gas, to 1,200° C, in cal/g.. u-G
Monoolefins, C2 to Cs. 8 Heat of combustion, for liquid and gas, at 25° C, in
Monoolefins, C7. 9 kcal/mole, cal/g, and Btu/lb.. n
Monoolefins, Cs. 10 Heat of formation, for liquid and gas, at 25° C, in
Diolefins (alkadienes) kcal/mole. p
Diolefins, C3 to Cs. 11 For gas, to 1,500° K, in kcal/mole. w
Acetylenes (alkyncs) Heat of fusion, in kcal/mole. z
Xormal acetylenes (1-alkynes), C2 to C2o- . 25 Heat of vaporization, at 25° C and boiling point in
Acetylenes, Cj to C6. 12 kcal/mole, cal/g, and Btu/lb. m
Aromatics (mononuclear) Standard, at 25° C, in kcal/mole. q
Alkyl benzenes Kinematic viscosity, at °F, in centistokes. c-E
Xormal alkyl benzenes, C6 to C22.. . 21 At °C, in centistokes. c-K
Alkvl benzenes, C6 to C9. 5 Logarithm of equilibrium constant of formation, for
Alkyl benzenes, C10. 14 gas, to 1,500° K... y
Alkenyl benzenes Molecular refraction, at 20" and 25° C, in ml/mole. . . b
Styrenes, C8 and C9. 13 Molecular volume, at 20° and 25° C, in ml/mole. b
Pressure coefficient of boiling point, at 1 atm, in ° C/
Index Of Letters Identifying Tables Arranged mm Hg. a
Alphabetically By Names Of Properties At 1 atm, in ° F/in. Hg. a-E
Property Letter Refraction, molecular, at 20° and 25° C, in ml/mole. . b
Specific, at 20° and 25° C, in ml/g. b
Roiling point, at 1 atm, in °C. a Refractive index, at 20° and 25° C. a
At 1 atm, in °F. a-E At 68° and 77° F. . a-E
At 10 to 1,500 mm Hg, in °C. k Refractivity intercept, at 20° and 25° C.. . b
Pressure coefficient of, at 1 atm, in °C/mm Hg. ... a Specific dispersion, at 20° and 25° C, in ml/g. b
Pressure coefficient of, at 1 atm, in °F/in. Hg. a-E Specific gravity, 60° F/60° F. a-E
Combustion, heat of, for liquid and gas, at 25° C, in Specific refraction, at 20° and 25° C, in ml/g. b
kcal/mole, cal/g and Btu/lb. n Vaporization, entropy of, at boiling point in cal/deg
Constants, eryoscopic, in deg . z mole. m
Cryoscopie constants, in deg _1. z Entropy of, standard, at 25° C, in cal/deg mole.... q
Density, at 20° and 25° C, in g/ml. a Free energy of, standard, at 25° C, in kcal/mole. . . q
At 60°, 08°, and 77°F, in lb/ft3 and lb/gal. a-E Heat of, at 25° C and boiling point in kcal/mole,
Equilibrium constant of formation, logarithm of, for
gas, to 1,500° K. y cal/g, and Btu/lb. m
Entropy, for liquid and gas, at 25° C, in cal/deg mole, p Heat of, standard, at 25° C, in cal/deg mole. q
For gas, to 1,500° K, in cal/deg mole. t Vapor pressures, at 10 to 1,500 mm Hg, in mm Hg.. . k
Entropy of fusion, in cal/deg mole. z Viscosity, absolute, at °C, in centipoises. c
Entropy of vaporization, at boiling point, in cal/deg Viscosity, kinematic, at °F, in centistokes. c-E
mole. m At ° C, in centistokes. c-K
Standard, at 25° C, in cal/deg mole. q Volume, molecular, at 20° and 25° C, in ml/mole. b
cd
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41
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This Isomer, formerly labeled "trans", has the following properties: boiling point at 1 atm., 120.09°C; refractive Index, nD at 25°C, 1.4206;
density at 25°C, 0.7620 g/ml.
This Isomer, formerly labeled "els", "has the following properties: boiling point at 1 atm., 124.45°C; refractive Index, nD at 25°C, 1.4284;
density, at 25°C, 0.7006 g/ml.
45
46
For air-saturated hydrocarbon In the liquid state at one atmosphere, unless otherwise Indicated. 13 See footnote b of Table la.
At saturation pressure. d For air-saturated hydrocarbon at one atmosphere, unless otherwise Indicated. e Triple point.
nD = 1*3675 at 15°C. g Density = 0.6325 g/ml at 15°C.
:ompleteness, all isomers are listed. However, when the data are Inadequate, approximate values are given
nixtures of the ois and trans forms, as Indicated by the brafces.
For air-saturated hydrocarbon In the liquid state at one atmosphere. b see footnote b of Table la.
For air-saturated hydrocarbon at one atmosphere. d see footnote d of Table 9a (Part 1).
49
a For air-saturated hydrocarbon In the liquid state at one atmosphere. bSee footnote b of Table la.
c For air-saturated hydrocarbon at one atmosphere.
745211 0 - 47 -5
For air-saturated hydrocarbon In the liquid state at one atmosphere. D See footnote b of Table la
For air-saturated hydrocarbon at one atmosphere. d See footnote d of Table 9a (Part 1).
For air-saturated hydrocarbon In the liquid state at one atmosphere. D See footnote b of Table la
For air-saturated hydrocarbon at one atmosphere. ^ See footnote d of Table 9a (Part 1).
C0 O
For air-saturated hydrocarbon In the liquid state at one atmosphere. “ See footnote b of Table la
Eh
u
u
a
o
m
- 3
%
UO
^
s s
t
CO
CO
^
rH
05
§
Oj
05
CO
CO
CD
03
CO
lO
CD
§
CO
D"
CO
03
CO
02
05
7
CO
^
CD
rH
CO
CO
CO
to
CD
CO
W
00
UD
C
CO
CO
CO
CQ
CD
to
CD
02
CO
CD
CO
^
rH
O
o
CO
CO
CD
CO
CO
02
rH
CQ
CD
02
ii n s ^
o
CO
CO
^
For air-saturated hydrocarbon In the liquid state at one atmosphere, unless otherwise Indicated. D See footnote b of Table la
55
?or air-saturated hydrocarbon in the liquid state ' t one atmosphere. ^ See footnote b of Table la.
58
For air-saturated hydrocarbon In the liquid state at one atmosphere, D See footnote b of Table la.
For air-saturated hydrocarbon at one atmosphere. d See footnote d of Table 9a (Part 1)
cd
o
cd
c*.
o
•-saturated hydrocarbon at one atmosphere
59
61
62
i
u
o
ra
§
-—--- Washington D. C.
TABLE 2a-E (Part 2) - PARAFFINS, C?
BOILING POINT, dt/dp, REFRACTIVE INDEX, DENSITY, AND FREEZING POINT
June 30, 1945
Bolling Specific Freezing
•O
O
d.
X
<d
%-t
P
>
cd
O
®
C
•o
Q)
X
Density*)
xy 1 xy
■PI Q.
Point Gravity*5^ Point0
03
CT)
C\2
CVJ
cn
In air,
o
O
o
Formula
O
o
O
o
CO
Ex,
C'-
o
CO
U.
CO
o
Cx,
CO
CD
C*e
f:
Cx,
8
U.
CO
CD
D-
Compound
rH Cd
fee
r-l CCJ
C
th
c
o> X
«H
S £
bO
sr§
ob'|ofc'
1 atm
o
\
a
C
Cx,
O
lb/cu ft
Cx,
lb/gal
X
Q
*0 T-«
CD C
X
bO •
Cx, bC
O
n- Heptane. 209.17 2.048 1.38764 1.38517 42.913 42.680 42.417 5.7367
CD
5.7055
rH
5.6703 0.68808 -131.07
c
2- Methylhexane. 194.09 2.025 1.38490 1.38230 42.605 42.366 42.097 5.6954 5.6635 5.6275 .68314 -180.89
3- " . 197.51 2.039 1.38865 1.38615 43.12 42.89 42.62 5.764 5.733 5.698 .6914
3-Ethylpentane. 200.24 2.048 1.39340 1.39085 43.830 43.585 43.310 5.8592 5.8265 5.7897 .70277 -181.47
'
2.2- Dlmethylpentane . 174.57 2.007 1.38217 1.37956 42.305 42.067 41.798 5.6554 5.6235 5.5876 .67833 -190.82
*
2.3- " . 193.62 2.048 1.39200 1.38950 43.629 43.394 43.130 5.8323 5.8009 5.7656 .69955
■
2.4- " . 176.92 1.998 1.38150 1.37888 42.243 42.001 41.727 5.6471 5.6147 5.5781 .67734 -182.61
=
3.3- " . 186.93 2.062 1.39090 1.38842 43.506 43.277 43.018 5.8160 5.7852 5.7507 .69759 -210.03
=
2.2.3- Trlmethylbutane. 177.57 2.048 1.38946 1.38686 43.310 43.076 42.812 5.7897 5.7584 5.7231 .69445 -12.93
X
bO
i
cd
r—I
E-
£3
<D
cd
w
For air-saturated hydrocarbon at one atmosphere. See Table 2z (Part 2) for the freezing points of the metastable'crystalline forms.
63
64
See footnote <3 of Table la-E. 0 For air-saturated hydrocarbon at one atmosphere
65
CO CO 05 02
O) Ol 05 O)
tDlOlDlDCOCOlDCOlOlDlD
CO ^ CD
02 ID CO
lOlDCOCOCOCOlDCOlDlDlDCOCOCOCO
5 3
CD LO CD COCOlDCOCDCOlDCOCOCO
CO
CD 05
ID 02
^ CD $ £8 0~ CO
3 3 3 3 3 3
02<-HC0CDlDlD0505 ^ W CO ^ 11)
5 ^ j ^ 3 j j j 3 3 3 3 3
05 CD 05 CD
0 For air-saturated hydrocarbon at one atmosphere

CO CO CD 00 00 CO 00 ID
05 O 02 00 CO CO
S 5 3 § 5 S 9 9
CD^^^0)O5^'O5'^!'<'^'tO5'd*<
CV20002020202020202020JW020102
02 02 02 02 02 02 02 02 02 02 02 02 02 02 02
00 05 CO CO
S £
C0020202020202020202 02 02020202
See footnote d of Table la-E.
A 3
A 4* O2O2O2O2O2C0C0C0
66
cs
m
O
W
V
<
See footnote d of Table la-E. e For air-saturated hydrocarbon at one atmosphere

67
CO to CO
<0 CO CO CO CO 0> 00
CO CO CD CO CO CO CD CO CO CO CO
CO CO lO
O CD CO CO
IQ CO O
N N CD
N N CO b a
See Table 5z for the freezing points of the metastable crystalline forms
CO CO CD
s s CO CO ^
^ to CO CO CO cf tO CO Ifl
LO LO LO lO lO LO
O) CD O)
-d* ^ ^ CO CO CO to d* CO CO lO ^
LO LO LO LO LO lO LO LO LO LO lO LO LO
CD 02 CM
0> O) lO
LO LO lO LO LO LO LO
™ §
1: LO ^ ^ d'd'iOd'd'iQiOd'
CO O) O) CO
ho •
<D C
s s s s CM
CO
lO
CO
O
M1
CO
to
T3 th CM CM CM CM CM CM CM CM
lO CO CO O) rH
lO CO CM
CO CD Oi CO CO
CM CM CM CM to S iS 3 8
53
%
745211 0 - 47 -6
68
hH
E-*
>H
x
CO
H
6
§
§ 8
CO
,H
- 3
I
•»
Q &
°
CO
D.
Bolling Freezing
&
•Q
O
Q
£
©
CD
i-t
cc
*-i
2
4-9
5
©
£
•§
H
©
O
£
p| CX
£
C5
© ^cd
Point Point0
O
In air,
c
o
o
o
o
o
c^
CO
Et,
co
CO
k
o
CO
&L,
CO
GO
CO
CO
S
*«
Compound Formula
O
rH ©
rH oJ
CO CO
I i o o
Cn
1 atm
05 £
a X
03 *h
CD C
CT> X
03 -rH
03 bO
03 bO
o
o
£*.
Cx.
£
lb/cu ft lb/gal
T) -rH
O
9 a
* if
'
6.2204 0.75048 -136.84
o
Cyclopentane . 120.67 1.829 1.40645 1.40363 46.805 46.532 46.224 6.2569 6.1792
“to
rH
O
0.75354 -224.40
o
Methylcyclopentane . 161.26 1.952 1.40970 1.40700 46.996 46.735 46.442 6.2825 6.2476 6.2083
“to
CVJ
rH
0.77103 -217.18
o
Ethylcyclopentane. 218.23 2.103 1.41975 1.41726 48.087 47.848 47.580 6.4282 6.3963 6.3604
rH
“t- *
1,1-Dlmethylcyclopentane . 190.11 2.057 1.41357 1.41092 47.353 47.100 46.814 6.3301 6.2962 6.2581 .75927 -93.51
*
cls-l,2-Dlmethylcyclopentane . 211.15 2.103 1.42221 L.41965 48.484 48.232 47.948 6,4813 6.4476 6.4096 .77741 -64.93
■
197.37 2.035 1.41199 1.40939 47.164 46.910 46.624 6.3048 6.2703 6.2326 .75624 -179.63
trans-1,2- " .
*
cis-1,3- " . 197.4 2.06 1.4111 1.4085 47.00 46.74 46.46 6.282 6.249 6.211 .7535
■
195.39 2.062 1.40891 1.40629 46.747 46.495 46.211 6.2491 6.2154 6.1775 .74955 -208.62
trans-1,3- " .
a l atm = 29.921 In. Hg. b For air-saturated hydrocarbon 1n the liquid state at one atmosphere. c See footnote o of Table la-E.
d See footnote d of Table la-E. 0 For air-saturated hydrocarbon at one atmosphere.

EjM
CO
a
H
u
a
>
<
j
§
co
O
U,
a,
a
Oi
w
ee
o
u
CO
O
U.
a
><
Q
DC
o
o
««:
s
O
2
CO
Bolling dt
CO
©
O
D.
Freezing
Q
©
C
CO
Refractive Indexb»c
i?
•a
Point dp
O
J-,
©
>
V+ 4->
Point®
CT>
CM
o
Cj
o
o
o
o
o
In air,
o
o
co
CD
Cx,
O'
0-
Cx,
co
1
o
Cx.
CO
Cx,
00
c^
C*h
co
o
C*H
c*.
Compound
CO
00
p
Cx,
rH Cd
«H (0
o o
CM -vH
05 C
O' K
C
a k
CM bo
CM bO
co CO
c*. Cx,
o o
1 atm
o
Cx,
C
C
o
ft
Cx,
lb/cu lb/gal
Q
Q
d *h
© C
^ £
o
Cyclohexane. 177.33 2.003 1.42623 1.42354 48.861 48.602 48.311 6.5317
“to
rH
CM
6.4972 6.4583 0.78344 +43.80
o
Methylcyclohexane.. . . 213.68 2.135 1.42312 1.42058 48.271 48.030 47.760 6.4529 6.4207 6.3846
^
0.77398 -195.88
rH
o
Ethylcyclohexane . ..... 269.21 2.272 1.43304 1.43073 49.410 49.187
CD
48.936
rH
6.6052
“to
6.5754 6.5418 0.79225 -108.54
*
1,1-Dlmethylcyclohexane. 247.18 2.249 1.42895 1.42657 48.983 48.751 48.491 6.6481 6.5171 6.4823 .78540 -28.37
‘
cls-l,2-Dlmethylcyclohexane. 265.51 2.281 1.43596 1.43360 49.933 49.708 49.456 6.6751 6.6451 6.6113 .80064 -58.00
■
trans-1,2- * . 254.15 2.263 1.42695 1.42470 48.666 48.444 48.193 6.5057 6.4760 6.4425 .78032 -126.72
‘
cls-1,3-f ’ . 248.16 2.231 1.42294 48.047
1.42063 47.821 47.567 6.4229 6.3927 6.3587 .77039 -104.01
*
trans-l,3-g * . 256.01 2.245 1.43085 1.42843 49.219 48.987 48.727 6.5796 6.5487 6.5139 .78919 -130.18
*
cls-1,4- ” . 255.78 2.249 1.42966 1.42731 49.101 48.871 48.612 6.5639 6.5331 6.4984 .78730 -125.36
*
trans-1,4- * . 246.83 2.240 1.42090 1.41853 47.836 47.603 47.341 6.3948 6.3637 6.3286 .76702 -34.46
1 atm = 29.921 In. Hg. b For air-saturated hydrocarbon In the liquid state at one atmosphere. c See footnote c of Table la-E.
See footnote d of Table la-E. ® For air-saturated hydrocarbon at one atmosphere. f Formerly labeled "trans"; see footnote d of Table 7a
Formerly labeled "els"; see footnote e of Table 7a.
69
70
Cm
CO
O
o
0.
I
Q
CO
1
■P
i
rH
&
-
6-
s
O
hh
£
a
Bolling JD
Freezing
Q
©
C
03
H
&
Refractive Indexb,c
•rH jo
o •q
W U
© >
CX cd
•o| "O
£
Point r
■p| o.
Point
O)
03
oi
03
Compound Formula In air,
o
o
o
C"
00
£
CO
£*
ft,
CO
o
C*.
<o
CO
£
£
CO
CD
rH Cd
o o
•H cd
60°F
co| CO
o o
TH
a
1 atm
h
C
cd X
o> X
03 bO
03 bo
deg F/
o
C
C*<
£
lb/cu ft lb/gal
In. Hg
1
Ethene (Ethylene). -154.68 1.024 -272.478
T*
^^3
©
©
N
03
rH
-301.458
lO
CO
03
Propene (Propylene) . -53.86 1.321 32.08® 31.54® 4.350® 4.289® 0.5218®
CO
©
©
**
CD
C'
rH
CD
-301.638
to
OOO
1- Butene. 20.73 1.541 37.15® , 36.76® 5.011® 4.966® 0.6011®
CO
e
©
©
rH
in
CO
CD
to
03
cls-2-Butene. 38.70 1.577 38.79® 38.42® 5.229® 5.185® .6272® -218.04
B
©
©
CD
CD
co
CQ
N
trans-2- " . 33.58 1.577 37.72® 37.36® 5.085® 5.042® .6100® -157.99
c
©
©
CD
O
O-
^rHOrf*
CO
2- Methylpropene (Isobutene) . 19.58 1.536 37.09® 36.70® 5.004s 4.958® .6002® -220.63
IO
o-
n
Q
O
0
CO
Q
1- Pentene . 85.95 1.74 1.3714 1.3683 40.02 39.70 5.387 5.349 0.6461 -265.40
rH
O
c
^
IO
CO
-240.47
rH
03
cis-2-Pentene . 98.8 1.74 1.3830 1.3798 40.9 40.6 5.51 5.47 .661
c
IO
<D
W
r-
0
lO
trans-2- " .•. 97.45 1.74 1.3793 1.3761 40.46 40.15 5.447 5.409 .6533 -220.42
c
IO
CD
CO
-215.61
O
CD
2- Methyl-l-butene . 87.98 1.74 1.3778 1.3746 40.60 40.27 5.467 5.428 .6557
c
^
in
-271.30
CD
3- " -1- " . 68.11 1.69 1.364^* 39.15 5.273 5.234 .6325
s
ID
^
CD
co
^^^^co^
rH
CO
2- " -2- " . 101.34 1.74 1.3874 1.3842 41.35 41.01 5.566 5.527 .6676 -208.80
1 atm = 29.921 In. Hg. b For air-saturated hydrocarbon In the liquid state at one atmosphere, unless otherwise Indicated. c See footnote c of Table la-]
See footnote d of Table la-E. e At saturation pressure. f For air-saturated hydrocarbon at one atmosphere, unless otherwise Indicated.
Triple point. h nD = 1.3671 at 60°F.

n Petroleum Institute Research Project 44
71
72
1 atm = 29.921 In. Hg. 0 For air-saturated hydrocarbon In the liquid state at one atmosphere. c See footnote c of Table la-1
See footnote d of Table la-E. 8 For air-saturated hydrocarbon at one atmosphere.
For completeness, all Isomers are listed. However, when the data are Inadequate, approximate values are given for mixtures of the els and
trans forms, as Indicated by the braces.
TABLE 9a-E (Part 2) - MONOOLEFINS, C?

June 30, 1945

CO
©
£
Bolling Freezing
&
o
>
cc
©
£
cd
O
©
£
•a
m
X
£
(Q
4-3
S
o V
*•* &
©
£ 5u
*-f
•a | -a
&
Point®
■P I o.
Point
©Q
O)
In air,
02
02
a
Compound^ Formula
©
©
1
u.
CD
CO
o
CO
CO
tx.
CD
<§*
g-
Ci-.
rH ©
60°F
rH Cd
68 °F
g|S
C
o> X
-i
i
1 atm
W)
bO
\
bO
£
C
Q
Q
lb/cu ft lb/gal
•© T-l
© C
*
O
2- Ethyl-l-pentene . 2.01 1.405 1.402 44.4 44.2 43.9 5.94 5.91 5.88 0.712
rH
3- " -1- " . 2.01 1.398 1.395 43.9 43.6 43.4 5.86 5.83 5.80 .703
2.3- Dlmethyl-l-pentene. 2.01 1.403 1.400 44.5 44.3 44.1 5.96 5.93 5.89 .714
2.4- " -1- " . 2.01 1.397 1.394 43.5 43.3 43.1 5.82 5.79 5.76 .698
3.3- " -1- " . 2.01 1.399 1.396 43.7 43.4 43.2 5.84 5.81 5.78 .700
3.4- " -1- " . 2.01 1.399 1.396 44.0 43.8 43.5 5.88 5.85 5.82 .705
.6871 -213.9
O
4.4- " -1- " . 2.01 1.3918 1.3892 42.85 42.62 42.36 5.728 5.697 5.662
5.99 .726
03r-HfHrHi-HrHrH03
3-Ethyl-2-pentene .... . 2.01 1.4143 1.4117 45.3 45.1 44.8 6.06 6.03
2.3- Dlmethyl-2-pentene. 2.01 1.421 1.418 45.7 45.4 45.2 6.11 6.08 6.04 .732 -102.
3^ seseBecce
5.804 5.768 .7000
02rH
OCDOOO'CÔ'COOOCD
rHi0l0C0r-HG00JC0C*-O
5.836
CO
2.4- " -2- " . 2.01 1.403 1.400 43.65 43.42 43.15
r
cIs-3,4-Dlmethy1-2-pentene.
.717
Oi
5.95 5.92
rH
CO
2.01 1.407 1.404 44.7 44.5 44.3 5.98
e
trans-3,4- ” -2- " .
c
cl3-4,4- " -2- n .
5.74 5.71 .692
CO
i-H
05
2.01 1.399 1.396 43.2 42.9 42.7 5.77
c
trans-4,4- " -2- ” .
e
5.97 5.93 .719
03
3-Methyl-2-ethyl-l-butene . 2.01 1.410 1.407 44.9 44.6 44.4 6.00
c
5.046 .7097 -168.5
c-
5.883
rHr-H
03
r-H
2,3,3-Trlmethyl-l-butene. 2.06 1.4029 1.4000 44.26 44.01 43.73 5.913
1 atm = 29.921 In. Hg. b For air-saturated hydrocarbon In the liquid state at one atmosphere. See footnote c of Table la-1
See footnote d of Table la-E. 6 For air-saturated hydrocarbon at one atmosphere. f See footnote f of Table 9a-E (Part 1).
73
74
See footnote d of Table la-E. e For air-saturated hydrocarbon at one atmosphere

1 atm = 29.921 In. Hg. b For air-saturated hydrocarbon In the liquid state at one atmosphere. 0 See footnote c of Table la-1
See footnote d of Table la-E. 9 For air-saturated hydrocarbon at one atmosphere. f See footnote f of Table 9a-E (Part 1).
75
76
National Bureau of Standards______ Washington, D. C.
a 1 atm = 29.921 ln.Hg. b For air-saturated hydrocarbon In the liquid state at one atmosphere. c see footnote c of Table la-1
d See footnote d of Table la-E. « For air-saturated hydrocarbon at one atmosphere. f See footnote f of Table 9a-E (Part 1).
78
S-$, CQCnCO^^ÔrHCQcntOCQCO 02 C*» lO CO to w

NNtONWNtO^NHCOW^ 02 rf 02 CO
o-C'-o~o-cs-cv-cs'0-r'~Kc'-C'~o o- 0- t> o- t> o-
•<D £d
cx
CO o
u
O02l0C0CDC0C002l0C0l0C-C0
OOOOOOOrHOCnOOJrH
COCOCOlOCOCOCOCOcOlOCOiflCO
O) CO LO CO CO
c See footnote c of Table la-I

CO CO CO CO CO CO CO CO 1/5 CO
f See footnote f of Table 9a-E (Part 1).

CO O)
CO 5*
§ 8 03 O
CO co co CO CO CO CO CO lO co CO
8 CO CO CO CO co o> 00 02
3 4
03 co in o> co co co lO CO lO o>
b For air-saturated hydrocarbon In the liquid state at one atmosphere.

5iOO>1hOoSi002CÔOCîH^ CO S 02 ^ COO-
§ «j> § §
9 For air-saturated hydrocarbon at one atmosphere.

CO CO CO 02
OOOOOlOOlOOOlOOO O lO
r-Hi-HrHrHi—IrHi—lrHr-H<HrH«Hr-H i—I r—I
NWNNWNNNNNNWN 02 02
CO
Si 85
CO
a §
02 02 See footnote d of Table la-E.
1 atm = 29.921 In. Hg.
4 4
* ^
02 02 02 CO CO CO
National Bui.au of Standard. _ Washington, D. C.
TABLE lla-E (Part 1) - DIOLEFINS, Cg to C5
June 30, 1945
Bolling dt Specific Freezing
O
£
E-t
>
OS
Vd
©
O
4-5
©
»—f
C
X3
©
K
©
Density13
Point dp Gravltyb>d Point1
o
Cc.
CO
o
&
l
OJ
CM
In air,
O
o
O
O
o
c!
O
O
Compound
CO
CO
Du
CO
Ex,
r-
C"
Ex,
GO
Du
Ex.
co
Du
Ex,
CO
§
t
o
CO
o
i—1 ©
rH ©
CO
o
Ex.
CM -rH
O) 2G
05 C
G> X
C
1 atm
CM bO
CM hO
O
O
deg F/
Du
Ex,
' lb/cu ft lb/gal
cQ
ln.Hg
o
X
Propadlene (Allene). -30.1 1.37 -213.
^
CO
o
X
1.2- Butadlene. 50.5 1.60 41.0® 40.7® 40.3® 5.49® 5.44® 5.39® 0.658® -213.3
^
co
=
1.3- " . 24.06 1.55 39.12® 38.77® 38.39® 5.229® 5.183® 5.131® .6272® -164.05
o
X
1.2- Pentadlene . 112.8 1.83 1.421 1.418 43.5 43.2 42.9 5.81 5.77 5.73 0.697
co
lO
«
cls-l,3-Pentadlene (cls-Plperylene). . 111.6 1.83 1.4359 1.4326 43.38 43.11 42.79 5.799 5.762 5.721 .6956
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trans-1,3- " (trans- " ). . 108.1 1.78 1.4299 1.4266 42.50 42.23 41.91 5.681 5.645 5.603 .6815
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2.3- ” . 104. 1.78 1.39 1.39 41. 41. 41. 5.5 5.5 5.5 .66
e
3-Methyl-l,2-butadlene . 104. 1.78 1.410 1.407 42.7 42.5 42.1 5.71 5.67 5.63 .685
e
2- ’ -1,3- " (Isoprene). . . 93.34 1.74 1.4216 1.4180 42.79 42.50 42.18 5.720 5.681 5.638 .6861 -230.8
79
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TABLE 12a-E - ACETYLENES, C£ to C5
June 30, 1946

S
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Ethyne (Acetylene). -119.f 0.82 -114.
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1- Butyne (Ethylacetylene) . 47.7 1.65 41.g 41.g 41.g 5.4g 5.4g 0.65® -194.4
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745211 0 - 47 -7
84
TABLE 15a-E - ALKYL CYCLOPENTANES, Cg
February 28, 1947
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absolute values of the specific dispersion, 10^(nr-np)/d, given above are believed to be uncertain by not more than 6 units. The differences between
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For air-saturated hydrocarbon In the liquid state at one atmosphere. See footnote a of Table lb. h See footnote b of Table 8b (Part 1)
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For completeness, all isomers are listed. However, when the data are Inadequate, approximate values are given for mixtures of the els
cd
For air-saturated hydrocarbon In the liquid state at one atmosphere. See footnote a of Table lb. b See footnote b of Table 8b (Part 1)
o
See footnote c of Table 9b (Part 1).
97
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For air-saturated hydrocarbon In the liquid state at one atmosphere. See footnote a of Table lb* D See footnote b of Table 8b (Part. 1)
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For air-saturated hydrocarbon In the liquid state at one atmosphere. See footnote a of Table lb.
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107
108
For air-saturated hydrocarbon In the liquid state at one atmosphere. See footnote a of Table lb.
TABLE 20c (Part 1) - NORMAL PARAFFINS, C1 to C&
VISCOSITY (ABSOLUTE)
FOR THE NORMAL LIQUID RANGE, AT ATMOSPHERIC PRESSURE3
March 31, 1P47
Tempera¬ Methane Ethane Propane n-Butane n-Pentane Tempera¬

Methane Ethane Propane n-Butane n-Pentane
ture ture
°C Viscosity (absolute) In centlpolses*3 °C Viscosity (absolute) In centlpolses*3
-200 -50 0.228 0.355 0.484

-195 -45 .216 .335 .457
-190 13.8C -40 .20Sd .315 .432
-185 0.226c 8.78 -35 .298 .408
-180 .188 5.96 -30 .282 .385
-175 .161 0.985 4.26 -25 .267 .364
-170 .142 .805 3.18 -20 .253 .345
-165 .127 .673 2.46 -15 .241 .327
-160 .115" .574 1.96 -10 .229 .309
-155 .500 1.60 -5 .219 .292
-150 .442 1.34 0 .210d .2766
-145 .396 1.14 +5 .2625
-140 .359 0.984 10 .2496

-135 .328 .861 15 .2374
-130 .301 .762 20 .2259

-125 .278 .681 25 .2152
-120 .257 .614 30 .2052
-115 .238 .558 35 .1958
-110 .222 .510 40 . 1868d
-105 .207 .469
-100 .195 .433
-95 .183 .402
-90 .172 .374 0.63
-86 .162d .350 .58
-80 .327 .536
-75 .307 .497
-70 .288 .462 0.62
-65 .272 .431 .58
-60 .256 .403 .54
-55 .242 .378 .51
-50 .228 .355 .484
Unless otherwise Indicated.

b The values of absolute viscosity In this table are referred to a value of 1.005 centlpolses for water at 20°C.
This Is the value used In the certification of standard viscosity samples by the National Bureau of Standards,
and corresponds to the value for the kinematic viscosity of water at 20°C (68°F) recommended In ASTM Method
D-445.
c Extrapolated value for the undercooled liquid below the normal melting point.
d For the liquid above the normal boiling point, at saturation pressure.
no SELECTED VALUES OF PROPERTIES OF HYDROCARBONS
TABLE 20c (Part 2) - NORMAL PARAFFINS, C. to C,.

o 1U
March 31, 1947
Tempera¬ Tempera¬
n-Hexane n-Heptane n-Octane n-Nonane n-Decane n-Hexane n-Heptane n-Octane n-Nonane n-Decane
ture ture
°C Viscosity (absolute) In centipolsesb °C Viscosity (absolute) In centlpolsesb
+50 0.2295 0.3017 0.3888 0.4926 0.6148
55 .2191 .2873 .3691 .4657 .5788
60 .2096 .2740 .3509 .4412 .5462
65 .2007 .2618 .'3342 .4188 .5165
70 .1923d .2503 .3185 .3978 .4890
75 .2397 .3042 .3788 .4641
-70 0.87 1.22 80 .2296 .2906 .3609 .4409
-65 .82 1.15 85 .2202 .2780 .3444 .4195
-60 .77 1.08 1.53C 90 .2113 .2662 .3288 .3996
-55 .72 1.02 1.44 2.04C 95 .2030 .2552 .3145 .3813
-50 .684 0.966 1.37 1.93 100 .1949d .2446 .3007 .3638
-45 .646 .914 1.29 1.83 105 .235 .288 .348
-40 .611 .865 1.22 1.73 110 .225 .276 .333
-35 .578 .817 1.15 1.63 115 .216 .264 .318
-30 .545 .770 1.086 1.529 2.15c 120 .208 .254 .304
-25 .515 .725 1.020 1.430 2.00 125 .200 .243 .292
-20 .486 .682 0.955 1.332 1.852 130 • 192d .234 .280
-15 .459 .641 .892 1.235 1.704 135 .224 .268
-10 .432 .600 .828 1.138 1.556 140 .215 .257
-5 .406 .560 .768 1.047 1.417 145 .207 .247
0 .3827 .5251 .7142 0.9638 1.291 150 .199 .237
+5 .3616 .4928 .6651 .8896 1.180 155 .191d .228
10 .3423 .4638 .6213 .8238 1.081 160 .219
15 .3243 .4370 .5816 .7649 0.9956 165 .210
20 .3077 .4127 .5458 .7129 .9204 170 .202
25 .2923 .3903 .5136 .6665 .8543 175 ,194d
30 .2781 .3701 .4845 .6253 .7964
35 .2648 .3512 .4578 .5878 .7444
40 .2522 .3335 .4329 .5532 .6968
45 .2405 .3171 .4102 .5218 .6540
50 .2295 .3017 .3888 .4926 .6148
a Unless otherwise Indicated. b See footnote b of Table 20c (Part 1)
National Bureau of Standards Washington D. C.
TABLE 20c (Part 3) - NORMAL PARAFFINS, C to C15
March 31, 1947
n- n- n- n- n- n- n- n- n- n-
Tempera¬ Tetra- Penta- Tempera¬ Tetra- Penta-
ture Undecane Dodecane Tridecane ture Undecane Dodecane Trldecane
decane decane decane decane
°C Viscosity (absolute) In centlpoisesb °C Viscosity (absolute) in centlpolsesb
+100 0.4338 0.5110 0.5955 0.6877 0.7874
105 .414 .486 .566 .652 .745
110 .395 .463 .538 .619 .706
115 .377 .442 .512 .588 .669
-30 3.02c 120 .360 .422 .488 .559 .636
-25 2.80 125 .345 .403 .465 .532 .605
-20 2.57 130 .330 .385 .444 .508 .576
-15 2.34 135 .316 .368 .424 .484 .549
-10 2.12 2.87C 3.36C 140 .303 .352 .405 .462 .523
-5 1.90 2.55 3.39 145 .290 .337 .388 .442 .500
0 1.717 2.268 2.975 150 .278 .323 .372 .423 .478
+5 1.551 2.023 2.621 3.372c 4.309c 155 .267 .310 .356 .405 .457
10 1.407 1.816 2.324 2.952 3.724 160 .256 .297 .341 .388 .437
15 1.283 1.639 2.074 2.605 3.248 165 .247 .286 .327 .372 .419
20 1.176 1.488 1.865 2.319 2.862 170 .237 .274 .314 .356 .401
25 1.082 1.358 1.689 2.081 2.544 175 .228 .263 .301 .342 .384
30 1.002 1.248 1.540 1.382 2.283 180 .219 .253 .289 .328 .369
35 0.9311 1.152 1.411 1.713 2.063 185 .211 .243 .278 .315 .355
40 .8668 1.066 1.298 1.566 1.873 190 .203 .234 .268 .303 .341
45 .8095 0.9902 1.199 1.437 1.710 195 .195 .226 .258 .292 .328
50 .7570 .9215 1.110 1.324 1.567 200 .188d .217 .248 .281 .316
55 .7096 .8598 1.030 1.224 1.442
60 .6668 .8046 0.9605 1.136 1.331
65 .6284 .7551 .8980 1.058 1.235
70 .5928 .7099 .8410 0.9870 1.149
75 .5608 .6694 .7905 .9247 1.073
80 .5311 .6320 .7440 .8676 1.003
85 .5039 .5978 .7020 .8162 0.9412
90 .4786 .5665 .6633 .7693 .8849
95 .4556 .5379 .6284 .7271 .8345
100 .4338 .5110 .5955 .6877 .7874
Unless otherwise Indicated,
b See footnote b of Table 20c (Part 1).
TABLE 20c (Part 4) - NORMAL PARAFFINS, C16 to C2Q
FOR THE NORMAL LIQUID RANGE,AT ATMOSPHERIC PRESSURE3
March 31* 1947
n- n- n- n- n- n- n- n- n-
Tempera¬ Tempera¬ n-
Hexa- Hepta- Octa- Nona- Hexa- Hepta- Octa- Nona-
ture Elcosane ture Elcosane
decane decane decane decane decane decane decane decane
°C Viscosity (absolute) in centlpoisesb °C Viscosity (absolute) in centlpolses*3
+100 0.8952 1.011 1.134 1.267 1.408
105 .846 0.953 1.068 1.190 1.320
110 .800 .900 1.007 1.120 1.240
115 .757 .850 0.950 1.055 1.166
120 .718 .805 .898 0.997 1.101
125 .682 .764 .851 .943 1.040
130 .649 .726 .808 .894 0.985
135 .617 .690 .766 .848 .933
140 .588 .656 .729 .805 .885
145 .561 .626 .694 .766 .841
150 .536 .597 .662 .730 .801
155 .512 .570 .632 .696 .764
160 .490 .545 .603 .664 .728
+15 4.022c 165 .469 .521 .577 .635' .695
20 3.505 4.265C 170 .449 .499 .551 .606 .664
25 3.087 3.720 4.456C 175 .430 .477 .527 .580 .634
30 2.748 3.284 3.899 4.603c 180 .412 .458 .505 .555 .607
35 2.464 2.923 3.445 4.037 4.704C 185 .396 .439 .485 .533 .582
40 2.223 2.620 3.068 3.572 4.134 190 .380 .422 .465 .511 .558
45 2.018 2.364 2.754 3.187 3.667 195 .366 .405 .447 .491 .536
50 1.840 2.144 2.484 2.860 3.275 200 .352 .390 .430 .472 .515
55 1.685 1.954 2.253 2.581 2.943
60 1.550 1.790 2.055 2.345 2.663
65 1.432 1.647 1.885 2.143 2.424
70 1.326 . 1.522 1.734 1.964 2.215
75 1.234 1.411 1.603 1.811 2.036
80 1.152 1.312 1.487 1.675 1.878
85 1.077 1.225 1.384 1.555 1.739
90 1.010 1.146 1.291 1.447 1.615
95 0.9506 1.076 1.210 1.354 1.507
100 .8952 1.011 1.134 1.267 1.408
Unless otherwise Indicated.
b See footnote b of Table 20c (Part 1).
TABLE 20c-E (Part 1) - NORMAL PARAFFINS, Cx to C5
KINEMATIC VISCOSITY
FOR THE NORMAL LIQUID RANGE, AT ATMOSPHERIC PRESSURE3,
May 31, 1947
Tempera¬ n-Butane n-Pentane Tempera¬

Methane Ethane Propane Methane Ethane Propane n-Butane n-Pentane
ture ture
°F Kinematic viscosity In centlstokesb °F Kinematic viscosity In centlstokes^
-100 0.487 0.720
-90 .460 .670 0.85
-80 .435 .626 .80
-70 .412 .586 .75
-60 .391 .551 .71
-50 .372 .520 .668
-40 •355d .491 .632
-30 .465 .598
-310 18.8° -20 .441 .566
-300 0.485c 11.5 -10 .419 .536
-290 .405 7.62 0 .399 .508
-280 .349 1.42 5.36 +10 .382 .482
-270 .311 1.16 3.96 20 .366 .456
-260 .282 0.967 3.05 30 .353 .433
-250 .258d .830 2.43 32 .350d .428
-240 .728 1.99 40 .412
-230 .650 1.68 50 .392
-220 .588 1.435 60 .374
-210 .538 1.247 .68 .361
-200 .496 1.099 ' 70 .357
-190 .458 0.982 77 .346
-180 .426 .885 80 .342
-170 .397 .806 90 .327
-160 .372 .739 100 .313d
-150 .351 .682
-140 .332 .633
-130 .314 .590 0.91
-120 .298d .552 .84
-110 .518 .78
-100 .487 .720
3 Unless otherwise Indicated.
b The values of kinematic viscosity In this table are referred to a value of 1.005 centlpolses for the viscosity
(absolute) of water at 20° C. This Is the value used In the certification of standard viscosity samples by the
National Bureau of Standards, and corresponds to the value for the kinematic viscosity of water at 20° C (68° F)
recommended In ASTM Method D-445.
d ror the liquid above the normal boiling point, at saturation pressure.
TABLE.20C-E (Part 2) - NORMAL PARAFFINS, Cg to C10
KINEMATIC VISCOSITY
FOR THE NORMAL LIQUID RANGE, AT ATMOSPHERIC PRESSUREa
my 31, 1947
Tempera¬ Tempera¬
n-Hexane n-Heptane n-Octane n-Nonane n-Decane ture n-Hexane n--Heptane n-Octane n-Nonane n-Decane
ture
°F Kinematic viscosity In centistokesb °F Kinematic viscosity In centlstokes^
+100 0.401 0.511 0.645 0.807 1.001
110 .383 .486 .611 .761 0.937
120 .367 .463 .580 .718 .880
130 .351 .442 .551 .679 .828
140 .337 .422 .524 .643 .781
150 .324 .405 .500 .611 .739
160 • 3l2d .388 .478 .581 .700
-90 1.15 1.57 170 .373 .457 .554 .665
-80 1.08 1.48 2.05° 180 .359 .438 .529 .632
-70 1.02 1.40 1.93 2.68° 190 .345 .420 .506 .603
-60 0.959 1.32 1.82 2.54 200 .333 .404 .485 .576
-50 .906 1.25 1.72 2.40 210 .321d .388 .465 .550
-40 .858 1.18 1.63 2.27 220 .374 .446 .527
-30 . .811 1.11 1.54 2.14 2.96° 230 .360 .429 .505
-20 .766 1.05 1.44 2.00 2.77 240 .347 .412 .484
-10 .723 0.988 1.35 1.86 2.57 250 .334 .396 .464
0 .683 .928 1.266 1.728 2.36 260 .323d .381 .446
+10 .644 .869 1,176 1.592 2.15 270 .367 .429
20 .606 .812 1.089 1.460 1.952 280 .354 .412
30 .572 .759 1.009 1.338 1.768 290 .341 .397
32 .565 .750 0.994 1.315 1.734 300 .329 .382
40 .540 .712 .937 1.230 1.607 310 .318d .369
50 .512 .670 .874 1.136 1.466 320 .355
60 .486 .632 .818 1.052 1.346 330 .343
68 .467 .604 .777 0.993 1.261 340 .331
70 .462 .597 .767 .979 1.241 350 .319d
77 .446 .574 .735 .934 1.176
80 .440 .566 .722 .915 1.150
90 .420 .537 .682 .859 1.072
100 .401 .511 .645 .807 1.001
Unless otherwise Indicated. ^ See footnote b of Table 20c-E {Part 1).
TABLE 20c-E (Part 3) - NORMAL PARAFFINS, Cn to C
KINEMATIC VISCOSITY
May 31, 1947
n- n- n- n-
Tempera¬ n- n- n- Tetra- Penta- Tempera¬ n- n- n- Tetra- Penta-
ture Undecane Dodecane Trldecane decane decane ture Undecane Dodecane Trldecane decane decane
°F Kinematic viscosity In centlstokes*3 °F Kinematic viscosity in centlstokesb
+200 0.676 0.788 0.910 1.042 1 .187
210 .645 749 .862 0.986 1 .119
220 .616 .713 .819 .934 1 .058
230 .588 .680 .780 .887 1 .003
-20 3.84C 240 .563 .649 .742 .843 0 .951
-10 3.53 250 .539 .620 .708 .803 .904
0 3.22 260 .517 .594 .677 .766 861
+10 2.91 3.92c 270 .496 .569 .647 .731 .821
20 2.60 3.45 4.57C 280 .476 .545 .619 .698 .783
30 2.33 3.05 3.97 290 .457 .523 .593 .668 748
32 2.28 2.97 3.86 300 .440 .502 .569 .640 716
40 2.09 2.70 3.46 4 .43° 5.63° 310 .424 .483 .547 .614 .686
50 1.032 2.40 3.04 3 .84 4.80 320 .408 .464 .525 .590 658
60 1.709 2.155 2.697 3 .357 4.148 330 .393 .447 .505 .567 632
68 1.588 1.987 2.465 3 .040 3.724 340 .379 .431 .486 .544 606
70 1.560 1.948 2.412 2 .969 3.628 350 .366 .415 .468 .523 582
77 1.469 1.822 2.243 2 .740 3.324 360 .353 .400 .451 .504 561
80 1.433 1.773 2.177 2 .651 3.208 370 .341 .386 .435 .486 540
90 1.325 1.626 1.980 2 .391 2.868 380 .330 .373 .420 .469 521
100 1.229 1.498 1.809 2 .170 2.583 390 .319d .361 .406 .453 503
110 1.145 1.385 1.663 1 .979 2.340 400 .349 .393 .436 486
120 1.068 1.286 1.534 1 814 2.133
130 1.000 1,196 1.419 1 670 1.954
140 0.938 1.118 1.319 1 546 1.796
150 .884 1.047 1.232 1 436 1.662
160 .834 0.984 1.152 1 338 1.544
170 .789 .928 1.082 1 252 1.438
ieo .748 .877 1.019 1 174 1.344
190 .711 .830 0.962 1 105 1.261
200 .676 .788 .910 1 042 1.187
a Unless otherwise Indicated. b See footnote b of Table 20c-E (Part 1).
745211 0 - 47 -9
TABLE 20C-E (Part 4) - NORMAL PARAFFINS, C16 to C20
KINEMATIC VISCOSITY
FOR THE NORMAL LIQUID RANGE, AT ATMOSPHERIC PRESS>!REa
my 31, 1947
n- n- n- n- n- n- n- n- n-
Tempera¬ Tempera¬ n-
Hexa- Hepta- Octa- Nona- Hexa- Hepta- Octa- Nona-
ture Elcosane ture Elcosane
decane decane decane decane decane decane decane decane
°F Kinematic viscosity In centlstokes*3 °F Kinematic viscosity In centlstokesb
+200 1.342 1.510 1.688 1.879 2.082
210 1.263 1.417 1.580 1.755 1.941
220 1.191 1.333 1.483 1.645 1.815
230 1.126 1.257 1.396 1.546 1.702
240 1.065 1.188 1.317 1.456 1.600
250 1.011 1.126 1.246 1.374 1.508
260 0.962 1.069 1.182 1.300 1.425
270 .915 1.016 1.122 1.232 1.349
280 .872 0.966 1.065 1.170 1.279
290 .832 .921 1.014 1.113 1.215
300 .796 .880 0.968 1.060 1.157
310 .762 .841 .925 1.013 1.103
320 .729 .805 .884 0.966 1.053
+60 5.10° 330 .700 .772 .847 .925 1.006
68 4.53 340 .671 .740 .811 .885 0.963
70 4.41 5.32c 350 .644 .709 .777 ,848 .922
77 4.01 4.80 360 .620 .682 .747 .814 .885
80 3.86 4.61 5.47c 6.46C 370 .597 .656 .718 .783 .850
90 3.42 4.05 4.76 5.58 6.50° 380 .575 .632 .692 .753 .817
100 3.05 3.59 4.19 4.87 5.62 390 .555 .610 .667 .726 .787
110 2.748 3.21 3.72 4.29 4.92 400 .536 .589 .642 .701 .758
120 2.489 2.886 3.33 3.82 4.36
130 2.267 2.614 3.00 3.42 3.88
140 2.077 2.383 2.720 3.09 3.49
150 1.912 2.183 2.484 2.808 3.16
160 1.766 2.012 2.277 2.564 2.875
170 1.641 1.862 2.100 2.358 2.634
180 1.530 1.730 1.946 2.177 2.425
190 1.430 1.613 1.808 2.017 2.241
200 1.342 1.510 1.688 1.879 2.082
a Unless otherwise Indicated. b See footnote b of Table 20c-E (Part 1).
0 Extrapolated value for the undercooled liquid below the normal melting point.
TABLE 20C-K (Part 1) - NORMAL PARAFFINS, ^ to C5
KINEMATIC VISCOSITY
FOR THE NORMAL LIQUID RAMIE, AT ATMOSPHERIC PRESSURE3
March 31, 1947
Tempera¬ Tempera¬
Methane Ethane Propane n-Butane n-Pentane ture Methane Ethane Propane n-Butane n-Pentane
ture
°C Kinematic viscosity In centlstokesb °C Kinematic viscosity In centlstokesb
-200 -50 0.387 0.545 0.698
-195 -45 .370 .517 .664
-190 18.8° -40 .355d .491 .632
-185 0.495° 12.1 -35 .468 .601
-180 .418 8.24 -30 .446 .572
-175 .364 1.52 5.93 -25 .426 ..545
-170 .325 1.25 4.45 -20 .407 .519
-165 .295 1.05 3.46 -15 .390 .495
-160 .272d 0.907 2.78 -10 .375 .471
-155 .796 2.28 -5 .362 .449
-150 .711 1.92 0 • 350d .4284
-145 .643 1.65 +5 .4096
-140 .588 1.435 10 .3924
-135 .542 1.264 15 .3762
-130 .504 1.126 20 .3607
-125 .469 1.015 25 .3464
-120 .438 0.922 30 .3330
-115 .411 .844 35 .3203
-110 .387 .778 40 .3081d
-105 .365 .721
-100 .348 .671
-95 .330 .628
-90 .314 .590 .91
-85 .299d .555 .85
-80 .524 .79
-75 .496 .736
-70 .470 .689 0.87
-65 .447 .647 .82
-60 .425 .609 .78
-55 .406 .576 .74
-50 .387 .545 .698
a Unless otherwise Indicated.

b The values of kinematic viscosity In this table are referred to a value of 1.005 centlpolses for the ’viscosity
(absolute) of water at 20°C. This Is the value used In the certification of standard viscosity samples by the
National Bureau of Standards, and corresponds to the value for the kinematic viscosity of water at 20°C (68°F)
recommended In ASTI1 Method D-445.
c Extrapolated 'value for the undercooled liquid below the normal melting point.
d For the liquid above the normal belling pclnt, at saturation pressure.
TABLE 20C-K (Part 2) - NORMAL PARAFFINS, Cg to C10
KINEMATIC VISCOSITY
MARCH 31, 1947
Tempera¬ Tempera¬
n-Hexane n-Heptane n-Octane n-Nonane n-Decane n-Hexane n-Heptane n-Octane n-Nonane n-Decane
ture ture
°C Kinematic viscosity In cent 1st okesb °C Kinematic viscosity In centistokesb
+50 0„3635 0.4589 0.5735 0.7096 0.8693
55 .3497 .4400 .5479 .6748 .8229
60 .3370 .4225 .5242 .6431 .7808

* .3252
65 .4065 .5024 .6141 .7426
70 .3141d .3914 .4819 .5868 .7071
75 .3775 .4633 .5622 .6750
-70 1.18 1.61 80 .3643 .4456 .5390 .6450
-65 1.11 1.53 85 .3519 .4291 .5175 .6173
-60 1.05 1.45 2.00° 90 .3402 .4137 .4972 .5916
-55 0.998 1.37 1.90 2.64° 95 .3293 .3994 .4787 .5679
-50 0.948 1.30 1.80 2.51 100 •3186d .3854 .4606 .5452
-45 .901 1.24 1.71 2.39 105 .372 .444 .524
-40 .858 1.18 1.63 2.27 110 .360 .429 .505
-35 .816 1.12 1.55 2.15 115 .348 .413 .486
-30 .774 1.062 1.464 2.026 2.81° 120 .337 .399 .468
-25 .736 1.006 1.381 1.904 2.63 125 .326 .386 .451
-20 .699 0.952 1.301 1.782 2.441 130 • 316d .373 .436
-15 .664 .899 1.221 1.660 2.256 135 .360 .420
-10 .629 .846 1.140 1.538 2.070 140 .348 .406
-5 .596 .795 1.064 1.422 1.895 145 .337 .392
0 .5649 .7495 .9939 1.315 1.734 150 .327 .379
+5 .5373 .7076 .9307 1.220 1.592 155 .317d .367
10 .5120 .6700 .8742 1.136 1.466 160 .355
15 .4885 .6353 .8230 1.060 1.357 165 .344
20 .4666 .6037 .7768 0.9933 1.261 170 .333
.4464 .5745 .7352 .9336 1.176 175 ,323d

25
30 .4277 .5483 .6976 .8807 1.102
35 .4102 .5236 .6631 .8326 1.036
40 .3936 .5005 .6309 .7879 0.9747
45 .3781 .4791 .6014 .7474 .9197
50 .3635 .4589 .5735 .7096 .8693
b See footnote b of Table 20c-K (Part 1).

TABLE 20C-K (Part 3) - NORMAL PARAFFINS, Cn to C15
KINEMATIC VISCOSITY
FOR.THE NORMAL LIQUID RANGE , AT ATMOSPHERIC PRESSURE3
March 31 , 1947
n- n- n- n-
Tempera¬ n- n- n- Tempera¬ n- n- n- Penta-
Tetra- Penta- Tetra-
ture Undecane Dodecane Trldecane ture Undecane Dodecane Tridecane decane
decane decane decane
°C Kinematic viscosity In centistokesb °C Kinematic viscosity In cent 1st okesb
+100 0.6386 0.7412 0.8533 0.975 1.106
105 .613 .710 .815 .929 1.052
110 .588 .680 .780 .887 1.003
115 .565 .652 .746 .847 0.956
-30 3.90c 120 .544 .626 .715 .810 .913
-25 3.63 125 .523 .601 .686 .776 .873
-20 3.34 130 .504 .579 .659 .745 .836
-15 3.06 135 .486 .557 .633 .714 .801
-10 2.78 3.72° 4.97C 140 .468 • 536 .608 .686 .768
-5 2.51 3.33 4.38 145 .452 .517 .586 .660 .738
0 2.276 2.973 3.863 150 .437 .498 .565 .635 .710
*5 2.065 2.664 3.418 4.362° 5.535° 155 .422 .481 .544 .612 ' .683
10 1.882 2.402 3.045 3.835 4.803 160 .408 .464 .525 .590 .658
15 1.725 2.178 2.729 3.400 4.207 165 .395 .449 .507 .569 .634
20 1.588 1.987 2.465 3.040 3.724 170 .382 .434 .490 .549 .611
25 1.469 1.822 2.243 2.740 3.324 175 .370 .419 .473 .530 .589
30 1.367 1.682 2.055 2.489 2.996 180 .358 .406 .457 .512 .569
35 1.276 1.560 1.891 2.276 2.720 185 .347 .393 .443 .495 .550
40 1.194 1.451 1.748 2.090 2.481 190 .336 .381 .429 .479 .532
45 1.121 1.354 1.623 1.927 2.275 195 .327 .370 .416 .464 .516
50 1.054 1.267 1.510 1.784 2.095 200 .317d .359 .403 .450 .500
55 0.9933 1.188 1.408 1.657 1.937
60 .9384 lj 118 1.319 1.546 1.796
65 .8891 1.054 1.240 1.447 1.675
70 .8432 0.9964 1.167 1.356 1.566
75 .8022 .9444 1.103 1.277 1.469
_ 80 .7640 .8966 1.043 1.204 1.380
85 .7290 .8527 0.9896 1.139 1.302
90 .6963 .8125 .9401 1.079 1.230
95 .6668 .7759 .8954 1.025 1.166
100 .6386 .7412 .8533 0.975 1.106
13 See footnote b of Table 20c-K (Part 1).

° Extrapolated value for the unaercooled liquid below the nornB.1 melting point.
TABLE 20c-K (Part 4) - NORMAL PARAFFINS, C16 to Cg)
KINEMATIC VISCOSITY
MarcH 31, 1947
n- n- n- n- n- n- n- n-
Tempera¬ n- Tempera¬ Octa- Nona- n-
Hexa- Hepta- Octa- Nona- Hexa- Hepta-
ture Eicosane ture decane decane Elcosane
decane decane decane decane decane decane
°C Kinematic viscosity In centlstokesb °C Kinematic viscosity in centistokesb
+100 1.248 1.399 1.559 1.731 1.914
105 1.184 1.326 1.476 1.634 1.803
110 1.126 1.258 1.398 1.546 1.702
115 1.071 1.195 1.325 1.463 1.608
120 1.022 1.138 1.260 1.390 1.526
125 0.976 1.085 1.200 1.321 1.449
130 .934 1.037 1.146 1.259 1.379
135 .893 0.990 . 1.093 1.200 1.313
140 .856 .948 1.044 1.146 1.253
145 .821 .909 1.000 1.097 1.197
150 .789 .872 0.959 1.050 1.146
155 .758 .838 .921 1.008 1.098
160 .729 .805 .884 0.966 1.053
+15 5.177° 165 .703 .775 .851 .929 1.011
20 4.531 5.481° 170 .677 .746 .818 .893 0.971
25 4.008 4.801 5.721c 175 .652 .718 .787 .859 .934
30 3.583 4.257 5.027 5 906C 180 .630 .693 .759 .827, .899
35 3.227 3.805 4.461 5 202 6.035° 185 .608 .669 .733 .798 .867
40 2.924 3.425 3.990 4 622 5.325 190 .588 .646 .707 .770 .836
45 2.666 3.104 3.597 4 141 4.743 195 .569 .625 .684 .744 .808
50 2.442 2.828 3.258 3 732 4.254 200 .551 .606 .662 .721 .781
55 2.247 2.589 2.968 3 383 3.840 >
60 2.077 2.383 2.720 3 087 3.489
65 1.928 2.202 2.506 2 834 3.190
70 1.793 2.045 2.316 2 609 2.928
75 1.677 1.905 2.151 2 417 2.703
80 1.573 1.780 2.005 2 246 2.505
85 1.478 1.670 1.875 2 .095 2.330
90 1.393 1.570 1.757 1 .958 2.174
95 1.318 1.481 1.655 1 .841 2.039
100 1.248 1.399 1.559 1 .731 1.914
a Unless otherwise Indicated,
k See footnote b of Table 20c-K (Part 1).

c Extrapolated value for the undercooled liquid below the normal melting point
National Bureau of Standards Washinoton, D. C.
TABLE lk - PARAFFINS, Cx to C&
VAPOR PRESSURES AND BOILING POINTS, AT 10 to 1500 mm Hg
June 30, 1944
2-Methyl- 2-Methyl- 2,2-Dlmethyl-
Pressure Methane Ethane Propane n-Butane propane n-Pentane butane propane
(Isobutane) (Isopentane) (Neopentane)
mm Hg Temperature In °C
10 -195.51 -142.88 -108.51 -77.76 -86.42 -50.1 -57.0

20 -191.77 -136.69 -100.91 -68.93 -77.93 -40.2 -47.3
30 -189.41 o -132.74 -96.07 -63.30 -72.52 -33.93 -41.15
40 -187.66 o
CO -129.78 -92.44 -59.08 -68.45 -29.22 -36.52
50 -136.25 -127.39 -89.51 -55.66 -65.16 -25.41 -32.77
60 -185.06 -125.36 -87.02 -52.77 -62.37 -22.18 -29.60
80 -183.12 a -122.03 -82.94 -48.02 -57.79 -16.89 -24.39
100 -181.45 -119.33 -79.63 -44.17 -54.07 -12.59 -20.16
150 -178.09 -114.12 -73.26 -36.76 -46.91 -4.33 -12.02
200 -175.55 -110.19 -68.43 -31.16 -41.49 +1.92 -5.86
250 -173.47 -106.98 -64.51 -26.59 -37.06 7.01 -0.84 b
300 -171.69 -104.25 -61.17 -22.71 -33.30 11.34 +3.42 -13.85
400 -168.76 -99.74 -55.65 -16.29 -27.07 18.49 10.48 -7.11
500 -166.35 -96.05 -51.14 -11.04 -21.98 24.337 16.25 -1.59
600 -164.29 -92.90 -47.29 -6.57 -17.63 29.319 21.176 +3.11
700 -162.48 -90.14 -43.92 -2.65 -13.81 33.685 25.492 7.24
710 -162.31 -89.88 -43.60 -2.28 -13.46 34.094 25.896 7.63
720 -162.14 -89.63 -43.29 -1.92 -13.10 34.499 26.296 8.01
730 -‘161.98 -89.37 -42.98 -1.56 -12.75 34.899 26.692 8.39
740 -161.81 -89.12 -42.67 -1.20 -12.41 35.295 27.083 8.77
750 -161.65 -88.88 -42.37 -0.85 -12.06 35.687 27.471 9.14
760 -161.49 -88.63 -42.07 -0.50 -11.73 36.074 27.854 9.50
770 -161.33 -88.39 -41.77 -0.16 -11.39 36.458 28.234 9.87
780 -161.17 -88.15 -41.48 +0.19 -11.06 36.838 28.609 10.23
790 -161.02 -87.91 -41.19 0.52 -10.73 37.214 28.981 10.58
800 -160.86 -87.67 -40.90 0.86 -10.40 37.587 29.352 10.94
900 -159.39 -85.44 -38.17 4.04 -7.31 41.12 32.85 14.29
1000 -158.04 -83.38 -35.66 6.95 -4.47 44.37 36.06 17.36
1200 -155.6 -79.71 -31.2 12.2 +0.6 50.17 41.80 22.9
1500 -152.5 -75.00 -25.4 18.9 7.1 57.6 49.2 29.9
Above values calculated from the constants below and the Antoine equation:
log10 p = A - B/(C+t) ; t = B/(A-log10 P) - C

(P in mm Hg ; t in °C)
Constants of the Antoine equation

A 6.61184 6.80266 6.82973 6.83029 6.74808 6.85221 6.80380 6.73812
7.69540(solid)
B 389.93 656.40 813.20 945.90 882.80. 1064.63 1027.25 950.84
532.20(solid)
c 266.00 256.00 248.00 240.00 240.00 232.000 234.000 237.00
275.00(solid)
a At the triple point, - 182.48 °C, the pressure Is 87.7 Iran Hg.
b At the triple point, - 16.6 °C, the pressure Is 265.4 mm Hg.
TABLE 2k (Part 1) - PARAFFINS, Cg

VAPOR PRESSURES AND BOILING POINTS, AT 10 TO 1500 mm Hg
March 31, 1944
n- 2-Methyl- 3-Methyl- 2,2-Dlmethyl- 2,3-Dlmethyl-

Pressure
Hexane pentane pentane butane butane
10 -25.0 -32.1 -30.1 -41.5 -34.9
20 -14.3 -21.6 -19.4 -31.1 -24.3
30 - 7.4 -14.8 -12.6 -24.5 -17.5
40 - 2.3 - 9.8 - 7.5 -19.5 -12.5
50 + 1.85 - 5.7 - 3.4 -15.5 - 8.4
60 5.36 - 2.2 + 0.13 -12.1 - 4.9
80 11.13 + 3.46 5.87 - 6.5 + 0.82
100 15.81 8.06 10.53 - 2.0 5.45
150 24.809 10\92 19.49 + 6.79 14.36
200 31.611 23.626 26.261 13.41 21.099
250 37.148 29.086 31.778 18.81 26.590
300 41.854 33.727 36.467 23.405 31.259
400 49.633 41.402 44.222 31.009 38.984
500 55.988 47.675 50.559 37.230 45.299
600 61..402 53.022 55.960 42.538 50.685
700 66.147 57.709 60.694 47.194 55.406
710 66.591 58.148 61.137 47.630 55.848
720 67.030 58.582 61.576 48.062 56.285
730 67.465 59.012 62.010 48.489 56.718
740 67.895 59.437 62.439 48.911 57.147
750 68.321 59.858 62.864 49.329 57.571
760 68.742 60.274 63.284 49.743 57.990
770 69.159 60.686 63.700 50.153 58.405
780 69.572 61.094 64.112 50.558 58.816
790 69.981 61.498 64.520 50.960 59.223
800 70.385 61.897 64.924 51.357 59.626
900 74.23 65.70 68.76 55.14 63.45
1000 77.75 69.18 72.28 58.60 66.97
1200 84.05 75.41 78.57 64.80 73.24
1500 92.1 83.4 86.6 72.8 81.3
log1QP = A - B/(C+t) t = B/(A~l0g1()P) - C

(P In mm Hg; t In °C)
6.87773 6.83907 6.84884 6.75480 6.80980

A
B 1171.530 1135.410 1152.368 1081.176 1127.187
224.366 226.572 227.129 229.343 228.900

C
TABLE 2k (Part 2) PARAFFINS, C7
May 31, 1944
2,2- 2,3- 2,4- 3,3- 2,2,3-

n- 2-Methyl- 3-Methyl- 3-Ethyl-
pressure Dlmethyl- Dimethyl- Dlmethyl- Dlmethyl- Trlmethyl-
Heptane hexane hexane pentane
pentane pentane pentane pentane butane
10 -2.1 -9.1 -7.8 -6.8 -18.7 -10.3 -17.1 -14.4 -18.8
20 +9.49 +2.3 +3.6 +4.71 -7.5 +1.1 -5.9 -2.9 -7.5
30 16.84 9.5 10.9 12.03 -0.4 8.5 +1.2 +4.40 -0.2
40 22.351 14.9 16.4 17.52 +4.99 13.9 6.5 9.89 +5.22
50 26.807 19.3 20.8 21.960 9.31 18.4 10.8 14.33 9.63
60 30.573 23.0 24.5 25.714 12.97 22.1 14.5 18.08 13.35
80 36.758 29.1 30.6 31.880 18.98 28.3 20.5 24.253 19.47
100 41.773 34.1 35.6 36.882 23.860 33.3 25.4 29.260 24.443
150 51.411 43.60 45.19 46.497 33.244 42.88 34.73 38.893 34.004
200 58.696 50.79 52.42 53.768 40.346 50.12 41.81 46.184 41.242
250 64.625 56.65 58.32 59.688 46.131 56.03 47.57 52.123 47". 140
300 69.663 61.62 63.32 64.719 51.049 61.06 52.48 57.172 52.154
400 77.988 69.85 71.60 73.036 59.187 69.37 60.58 65.524 60.452
500 84.787 76.57 78.37 79.830 65.839 76.16 67.21 72.352 67.236
600 90.579 82.29 84.13 85.620 71.511 81.94 72.85 78.174 73.021
700 95.653 87.31 89.19 90.692 76.483 87.02 77.80 83.278 78.094
710 96.128 87.78 89.66 91.168 76.949 87.49 78.27 83.756 78.570
720 96.598 88.24 90.13 91.637 77.410 87.96 78.72 84.228 79.039
730 97.063 88.70 90.59 92.102 77.866 88.42 79.18 84.696 79.505
740 97.523 89.15 91.05 92.563 78.317 88.88 79.63 85.159 79.965
750 97.978 89.60 91.50 93.018 78.763 89.34 80.07 85.617 80.420
760 98.428 90.05 91.95 93.468 79.205 89.79 80.51 86.071 80.871
770 98.874 90.49 92.39 93.914 79.642 90.24 80.95 86.520 81.317
780 99.315 90.93 92.83 94.355 80.075 90.68 81.38 86.964 81.758
790 99.752 91.36 93.27 94.793 80.504 91.11 81.80 87.404 82.196
800 100.185 91.79 93.70 95.225 80.928 91.55 82.22 87.839 82.629
900 104.29 95.85 97.79 99.334 84.96 95.65 86.23 91.98 86.74
1000 108.06 99.57 101.55 103.102 88.66 99.42 89.91 95.77 90.52
1200 114.79 106.2 108.3 109.84 95.27 106.2 96.5 102.56 97.27
1500 123.41 114.8 116.9 118.47 103.8 114.8 104.9 111.3 105-.93
Above values calculated from the constants below and the Antoine equation
log1QP - A - B/(C + t) ; t . B/(A-

logiop) - c
(P In mm Hg ; t in °c)
A 6.90319 6.88017 6.86216 6.87306 6.81506 6.85785 6.84773 6.81810 6.79968

E 1268.586 1240. 1238. 1249.825 1190.298 1240. 1204. 1223.543 1204.997
C 216.954 220. 219. 219.595 223.343 222. 223. 224.687^ 226.615

Washington, D. C.
TABLE 3k (Part 1) - PARAFFINS,

o
April 30, 1944
2,2- 2,3- 2,4- 2,5-

n- 2-Methyl- 3-Methyl- 4-Methyl- 3-Ethyl-
Pressure Dlmethyl- Dlmethyl- Dlmethyl-
Octan© Dlmethyl-
heptane heptane heptane hexane
hexane hexane hexane hexane
mm Hg Temperature In yC
10 19.2 12.3 13.3 12.4 12.8 3.1 9.9 5.2 5.3

20 31.5 24.4 25.4 24.5 25.0 15.0 22.1 17.2 17.2
30 39.28 32.16 33.15 32.23 32.68 22.54 29.78 24.77 24.74
40 45.13 37.93 38.94 38.00 38.48 28.21 35*56 30.47 30.42
50 49.849 42.607 43.627 42.671 43.162 32.798 40.242 35.087 35.020
60 53.840 46.556 47.586 46.616 47.123 36.678 44.198 ^8*985 38.906
80 60.393 53.041 54.088 53.096 53.628 43.052 50.696 45.391 45.291
100 65.706 56.298 59.359 58.349 58.903 48.224 55.967 50*586 50.470
150 75.914 68.399 69.491 68.447 69.043 58.171 66.100 60.578 60.429 1
200 83.628 76.034 77.150 76.080 76.709 65.697 73.764 68.136 67.961
250 89.905 82.247 83.384 82.293 82.949 71 826 80.003 74.290 74.094
300 95.237 87.524 88.680 87.571 88.251 77.037 85.306 79.521 79.306
400 104.048 96.245 97.434 96.295 97.015 85.654 94.072 88.171 87.925
500 111.240 103.366 104.583 103.418 104.173 92.697 101.233 95.239 94.967
600 117.367 109.431 110.673 109.488 110.271 98.701 107.336 101.263 100.969
700 122.732 114.743 116.009 114.804 115.614 103.963 112.684 106.543 106.228
710 123.235 115.241 116.508 115.302 116.114 104.456 113.185 107.037 106.721
720 123.732 115.733 117.002 115.794 116.609 104.944 113.680 107.526 107.208
730 124.223 116.219 117.491 116.282 117.099 105.426 114.170 108.010 107.690
740 124.710 116.701 117.975 116.764 117.583 105.903 114.655 108.489 108.167
750 125.191 117.178 118.454 117.241 118.062 106.375 115.135 108.963 108.639
760 125.667 117.649 118.927 117.712 118.537 106.843 115.610 109.432 109.106
770 126.139 118.116 119.396 118.180 119.006 107.305 116.080 109.896 109.568
780 126.605 118.577 119.860 118.642 119.471 107.763 116.545 110.355 ]10.026
790 127.067 119.035 120.320 119.100 119.931 108.217 117.006 110.810 110.479
800 127.525 119.488 120.774 119.553 120.387 108.666 117.462 111.260 110.927
900 131.87 123.79 125.09 123.86 124.71 112.93 121.79 115.54 115.19
1000 135.85 127.73 129.05 127.80 128.68 116.84 125.77 119.46 119.10
1200 142.96 134.77 136.13 134.86 135.77 123.84 132.87 126.47 126.08
1500 152.1 143.8 145.2 143.9 144.9 132.8 142.0 135.5 135.0
log1QP = A - B/(C + t) ; t = B/(A-log10P) - C
(P In mm Hg ; t In °C)
A 6.92374 6.91733 6.89942 6.90061 6.89095 6.83712 6.87000 6.85302 6.85980
B 1355.126 1337.468 1331.530 1327.661 1327.884 1273.594 1315.503 1287.876 1287.274
C 209.517 213.693 212.414 212.568 212.595 215.072 214.157 214.790 214.412

American, ratrolaom Institute Research Project 44
RTsHcmal Bataan ci Stawdanli Washington, D. C
TABLE 3k (Part 2) - PARAFFINS, Cg

April 30, 1944
3,3- 3,4- 2-Methyl- 3-Methyl- 2,2,3- 2,2,4- 2,3,3- 2,3,4- 2,2,3,3-

Pressure Dimethyl- Dimethyl- 3-ethyl- 3-ethyl- Trlmethyl- Trlmethyl- Trlmethyl- Trlmethyl- Tetramethyl-
hexane hexane pentane pentane pentane pe ntane pentane pentane butane
10 6.1 11.3 9.5 9.9 3.9 -4.3 6.9 7.1 13.5

20 18.2 23.5 21.7 22.3 16.0 +7.5 19.2 19.3 24.6
30 25.93 31.32 29.41 30.26 23.69 15.05 27.10 27.06 31.6
40 31.72 37.14 35.22 36.19 29.48 20.69 33.00 32.88 36.8
50 36.410 41.858 39.918 40.984 34.167 25.267 37.773 37.585 40.95
60 40.372 45.843 43.891 45.039 38.130 29.139 41.808 41.565 44.47
80 46.882 52.388 50.420 51.702 44.641 35.502 48.438 48.103 50.21
100 52.162 57.695 55.715 57.105 49.925 40.665 53.817 53.406 54.83 ~
150 62.316 67.899 65.896 67.495 60.088 50.598 64.162 63.605 63.65 ^
200 69.998 75.614 73.596 75.353 67.779 58.115 71.988 71.320 70.24 “
250 76.253 81.895 79.866 81.750 74.043 64.237 78.361 77.602 75.56
300 81.570 87.232 85.194 87.187 79.369 69.443 83.778 82.941 80.25
400 90.362 96.056 94.004 96.176 88.178 78.055 92.738 91.770 87.43
500 97.546 103.263 101.202 103.519 95.379 85.094 100.059 98.984 93.40
600 103.669 109.404 107.336 109.778 101.518 91.096 106.300 105.133 98.45 a
700 109.035 114.784 112.712 115.262 106.899 96.357 111.770 110.522 103.35
710 109.538 115.288 113.215 115.776 107.404 96.850 112.283 111.027 103.86
720 110.035 115.787 113.713 116.283 107.902 97.338 112.789 111.526 104.35
730 110.527 116.280 114.206 116.786 108.395 97.820 113.291 112.019 104.85
740 111.014 116.768 114.693 117.283 108.884 98.297 113.787 112.508 105.34
750 111.495 117.251 115.176 117.775 109.367 98.770 114.278 112.992 105.82
760 111.972 117.728 115.653 118.262 109.844 99.237 114.763 113.470 106.30
770 112.444 118.201 116.126 118.744 110.318 99.700 115.244 113.944 106.77
780 112.910 118.669 116.593 119.221 110.786 100.157 115.720 114.413 107.24
790 113.373 119.133 117.057 119.694 111.250 100.611 116.192 114.877 107.70
800 113.831 119.591 117.515 120.162 111.709 101.060 116.658 115.337 108.16
900 118.18 123.95 121.87 124.60 116.07 105.33 121.09 119.70 112.52
1000 122.17 127.95 125.86 128.68 120.07 109.24 125.16 123.71 116.51
1200 129.30 135.09 133.00 135.96 127.23 116.23 132.42 130.86 123.7
1500 138.4 144.2 142.2 145.3 136.4 125.21 141.7 140.0 132.8
log10P = A - B/(C+t) ; t = B/(A-log10P) - C
(P In ran Hg ; t In °C)
A 6.85118 6.87982 6.86354 6.86727 6.82542 6.81984 6.84349 6.85392 6.87665
t 7.78882(solld)
8 1307.882 1330.035 1318.120 1347.209 1294.875 1262.490 1328.046 1315.084 1327.8
1625.7(solld)
C 217.439 214.863 215.306 219.684 218.420 221.271 220.375 217.526 226.
226.(solid)
a At the triple point , 100.58°C, the pressure Is 647.0 mm Hg.

National Bureau ol Standard,_ Waahington, D. C.
TABLE 5k (Part 1) - ALKYL BENZENES, to C„

D 8
June 30, 1944
Methyl- 1,2-Dlmethyl- 1,3-Dlmethyl- 1,4-Dlmethyl-

Ethyl-
Pressure Benzene benzene benzene benzene
benzene benzene
(Toluene) (o-Xylene) (m-Xylene) (p-Xylene)
10 -11.5 « 6.37 25.90 32.11 28.26 27.30

20
-2*6 t 18.39 38.62 45.11 41.09 40.14
30 + 3.01 a 26.04 46.71 53.36 49,24 48.30
40 7.57 31.77 52.77 59.55 55.35 54.42
50 11.82 36.399 57.668 64.547 60.281 59.356
60 15.41 40.313 61.808 68.769 64.448 63.529
80 21.305 46.737 68.604 75.697 71.287 70.378
100 26.085 51.944 74.112 81.309 76.826 75.926
150 35.272 61.944 84.692 92.083 87.460 86.579
200 42.217 69.499 92.684 100.217 95.488 94.623
250 47.870 75.645 99.185 106.831 102.015 101.163
300 52.672 80.864 104.706 112.444 107.554 106.716
400 60.611 89.485 113.826 121.712 116.701 115.885
500 67.093 96.520 121.268 129.272 124.161 123.364
600 72.616 102.511 127.606 135.706 130.510 129.730
700 77.454 107.757 133.155 141.338 (136.067 135.303
710 77.908 108.248 133.674 141.865 136.587 135.825
720 78.356 108.733 134.188 142.386 137.101 136.341
730 78.799 109.214 134.696 142.902 137.610 136.851
740 79.238 109.689 135.199 143.412 138.113 137.356
750 79.672 110.160 135.697 143.917 138.612 137.856
760 80.101 110.625 136.189 144.416 139.104 138.350
770 80.526 111.086 136.677 144.911 139.592 138.839
780 80.947 111.542 137.159 145.400 140.075 139.323
790 81.364 111.994 137.637 145.885 140.553 139.803
800 81.776 112.440 138.109 146.364 141.026 140.278
900 85.694 116.68 142.60 150.92 145.52 144.78
1000 89.286 120.57 146.71 155.09 149.63 148.91
1200 95.705 127.52 154.06 162.54 156.98 156.29
1500 103.93 136.42 163.48 172.07 166.39 165.73
log1QP - A - B/(C + t) ; t - B/(A-log10P) - C
A 6.89745 6.95334 6.95366 7.00289 7.00659 6.99099

9.0963 (solid)
B 1206.350 1343.943 1421.914 1477.519 1460.498 1453.840
1882.0 (solid)
C 220.237 219.377 212.931 214.024 214.889 215.367
244.0 (solid)
'
a At the triple point, 5.53°C, the pressure Is 35.8 ram Hg.

American Petroleum Inatitute Reaearch Project 44
National Bureau of Standarda Waahington, D. C.
TABLE 5k (Part 2) - ALKYL BENZENES,

C9
VAPOR PRESSURES AM) BOILING POINTS, AT 10 to 1500 mm Hg
June 30, 1944
1- Methyl- 1-Methyl- 1-Methyl- 1,2,3- 1,2,4- 1,3,5-

n-Propyl- Isopropyl¬
Pressure 2- ethyl- 3-ethyl- 4-ethyl- Trlmethyl- Trlmethyl- Trlmethyl-
benzene benzene
benzene benzene benzene benzene benzene benzene
ran Hg Temperature In °C
10 43.44 38.33 47.6 44.7 44.9 55.9 50.7 47.4

20 56.79 51.46 61.2 58.2 58.5 69.9 64.5 61.0
30 65.28 59.81 69.9 66.8 67.1 78.8 73.2 69.7
40 71.64 66.08 76.4 73.3 73.6 85.4 79.8 76.1

50 76.783 71.140 81.6 78.5 78.8 90.8 85.1 81.4
60 81.129 75.419 86.0 82.9 83.2 95.3 89.5 85.8
80 88.263 82.444 93.3 90.1 90.5 102.8 96.9 93.0
100 94.045 88.139 99.2 95.9 96.3 108^.8 102.3 98.9
150 105.152 99.080 110.4 107.1 107.6 120.3 114.2 110.1
200 113.542 107.348 119.0 115.5 116.1 129.0 122.7 118.6
250 120.367 114.075 125.9 122.4 123.0 136.1 129.7 125.5
300 126.163 119.789 131.7 128.2 128.8 142.1 135.6 131.4
400 135.738 129.231 141.4 137.8 138.4 152.0 145.4 141.0
500 143.552 136.938 149.3 145.6 146.3 160.0' 153.3 148.9
600 150.206 143.502 156.1 152.3 153.0 166.9 160.1 155.6
700 156.032 149.251 161.93 158.12 158.85 172.88 166.02 161.49
710 156.578 149.789 162.49 158.66 159.40 173.44 166.57 162.04
720 157.117 150.322 163.03 159.20 159.94 173.99 167.12 162.59
730 157.651 150.848 163.57 159.73 160.48 174.54 167.66 163.12
740 158.179 151.369 164.10 160.26 161.01 175.08 168.20 163.65
750 158.701 151.885 164.63 160.78 161.53 175.62 168.73 164.18
760 159.218 152.395 165.15 161.30 162.05 176.15 169.25 164.70
770 159.730 152.900 165.67 161.81 162.56 176.68 169.77 165.21
780 160.236 153.400 166.18 162.32 163.07 177.20 170.28 165.72
790 160.738 153.895 166.68 162.82 163.57 177.71 170.79 166.23
800 161.234 154.385 167.18 163.31 164.07 178.22 171.29 166.73
900 165.95 159.04 171.9 168.0 168.8 183.1 176.1 171.5
1000 170.27 163.30 176.3 172.3 173.1 187,5 180.4 175.8
1200 177.99 170.92 184.1 180.0 180.9 195.4 188.3 183.6
1500 187.87 180.69 194.0 189.9 190.7 205.5 198.2 193.5
log10P - A - B/(C + t) ; t = B/(A-log10P) - C
A 6.95175 6.92926 7.03460 7.05428 7.06730 7.10175 7.07938 7.04089
B 1491.548 1455.811 1566.60 1566.30 1582.70 1646.80 1609.10 1567.10
C 207.171 207.202 212.00 214.00 216.00 214.00 214.00 212.00

TABLE 6k (Part 1) - ALKYL CYCLOPENTANES, Cg to C?
August 31, 1944
Methyl- Ethyl-
Pressure Cyclopentane
cyclopentane cyclopentane
10 -40.4 -23.7 -0.1
20 -30.1 -12.8 +11.7

30 -23.6 -5.8 19.3
40 -18.6 -0.6 25.0
50 -14.7 +3,64 29.6
60 -11.3 7.22 33.4
80 -5.8 13.10 39.8
100 -1.3 17.86 45.0
150 +7.28 27.027 54.9
200 13.78 33.958 62.4
250 19.08 39.601 68.5
300 23.574 44.397 73.7
400 31.007 52.327 82.3
500 37.079 58.806 89.4
600 42.252 64.328 95.3
700 46.785 69.166 100.58
710 47.209 69.620 101.07
720 47.629 70.068 101.56
730 48.044 70.511 102.04
740 48.455 70.950 102.51
750 48.862 71.384 102.98
760 49.264 71.814 103.45
770 49.663 72.239 103.91
780 50.057 72.660 104.37
790 50.447 73.077 104.82
800 50.834 73.490 105.27
900 54.50 77.41 109.5
1000 57.87 81.00 113.4
1200 63.88 87.43 120.4
1500 71.6 95.7 129.3
Above values calculated from the constants below and the Antoine equation
log1QP = A - B/(C +' t) ; t - B/(A-log10P) - C
A 6.88673 6.86280 6.86472
B 1124.162 1186.059 1286.60
C 231.361 226.042 219.50

American Patrolaum Institute Rssaarch Project 44
National Bureau of Standard!__ Washington D C
TABLE 7k (Part 1) - ALKYL CYCLOHEXANES, Cg to Cg

August 31, 1944; March 31, 1947
1,1-
Methyl- Ethyl- Dlmethyl-
Pressure Cyclohexane cyclohexane cyclohexane cyclohexane
10 -3.2 20.6 10.1

20 +8.7 33.4 22.6
30 a 16.30 41.50 30.55
40 6.69 21.99 47.58 36.53
50 11.01 26.592 52.503 41.361
60 14.67 30.485 56.665 45.449
80 20.672 36.882 63.501 52.169
100 25.543 42.072 69.044 57.622
150 34.912 52.057 79.704 68.115
200 42.000 59.612 87.766 76.058
250 47.772 65'. 766 94.329 82.530
300 52.678 70.998 99.907 88.033
400 60.792 79.652 109.128 97.138
500 67.422 86.725 116.661 104.582
600 73.074 92.756 123.081 110.930
700 78.028 98.042 128.706 116.496
710 78.492 98.537 129.233 117.018
720 78.950 99.027 129.754 117.533
730 79.405 99.511 130.270 118.044
740 79.854 99.990 130.780 118.549
750 80.299 100.465 131.284 119.048
760 80.738 100.934 131.784 • 119.543
770 81.174 101.400 132.278 120.032
780 81.604 101.859 132.767 120.516
790 82.032 102.315 133.253 120.997
800 82.454 102.766 133.732 121.472
900 86.47 107.05 138.29 125.98
1000 90.15 110.98 142.47 130.12
1200 96.73 118.01 149.94 137.53
1500 105.2 127.0 159.5 147.0
logiop - A - B/(C + t) ; t = B/(A-log1()P) - C

A 6.84498 6.82689 6.87041 6.80225

B 1203.526 1272.864 1384.036 1323.861
C 222.863 221.630 215.128 218.053
At the triple point, 6.56 °C, the pressure Is 39.7 mm Hg.

^National Bureau of Standards Washington, D, C.
TABLE 7k (part 2) - ALKYL CYCLOHEXANES, Cg

August 31, 1944; March 31, 1947 (Corrected)
cis-1,2- trans-1,2- ClS-1,3- trans-1,3- CiS-1,4- trans-1,4-

Pressure Dimethyl- Dimethyl- Dimethyl- Dimethyl- Dimethyl- Dimethyl-
cyclohexane cyclohexane cyclohexane3 cyclohexane13 cyclohexane cyclohexane
10 18.4 13.0 11.2 14.9 14.5 10.1

20 31.1 25.6 23.6 27.4 27.1 22.6
30 39.25 33.66 31.57 35.42 35.10 30.54
40 45.34 39.70 37.53 41.41 41.10 36.51
50 50.266 44.580 42.347 46.258 45.958 41.341
60 54.430 48.711 46.421 50.355 50.063 45.425
80 61.273 55.498 53.116 57.087 56.810 52.136
100 66.824 61.005 58.547 62.549 62.233 57.581
150 77.500 71.596 68.992 73.054 72.810 68.057
200 85.577 79.609 76.895 81.002 80.775 75.985
250 92.155 86.136 83.330 87.474 87.262 82.442
300 97.746 91.683 88.800 92.976 92.776 87.932
400 106.993 100.859 97.847 102.077 101.897 97.014
500 114.550 108.357 105.240 109.513 109.350 104.437
600 120.992 114.750 111.542 115.853 115.704 110.766
700 126.638 120.353 117.056 121.410 121.274 116.315
710 127.167 120.878 117.583 121.931 121.795 116.835
720 127.690 121.396 118.094 122.445 122.311 117.349
730 128.208 121.910 118.601 122.954 122.822 117.857
740 128.720 122.419 119.102 123.459 123.327 118.360
750 129.227 122.921 119.598 123.957 123.827 118.859
760 129.728 123.419 120.088 124.450 124.321 119.351
770 130.224 123.912 120.574 124.939 124.811 119.839
780 130.715 124.399 121.054 125.422 125.295 120.321
790 131.202 124.882 121.530 125.901 125.776 120.800
800 131.683 125.360* 122.001 126.375 126.250 121.273
900 136.26 129.90 126.48 130.88 130.77 125.77
1000 140.46 134.07 130.59 135.01 134.91 129.90
1200 147.96 141.51 137.92 142.40 142.31 137.28
1500 157.6 151.1 147.3 151.9 151.8 146.7
Above values calculated from the constants below and the antolne equation:
iog P - A - B/(C ♦ t) ; t - B/(*-log1()P) - C

(P In ran Hg ; t In °C)
Constants of the antolne equation
A 6.84154 6.83722 6.84293 6.83866 6.83699 6.82180
B 1369.525 1356.100 1340.658 1345.859 1347.794 1332.613
c 216.040 219.342 218.281 £15.596 216.360 218.791
3 Formerly labeled "trans"; see footnote d of Table 7a.

b Formerly labeled ?cls"; see footnote e of Table 7a.
National Bureau of Standard* Washington D. C
TABLE 8k (Part 1) - MONOOLEFINS, Cg to C4

July 31, 1944; revised March 31, 1945
2-Methyl-
Pressure Ethene Propene 1- cls-2- trans-2- propene
(Ethylene) (Propylene) Butene Butene Butene (Isobutene)
mm Hg Temperature in 3C
10 -153.22 -112.11 -cJl.50 -73.42 -76.31 -81.95

20 -147.59 -104.75 -72.89 -64.58 -67.46 -73.37
30 -144.00 -100.06 -67.41 -58.94 -61.82 -67.90
40 -141.31 -96.55 -63.29 -54.72 -57.60 -63.79
50 -139.13 -93.70 -59.96 -51.305 -54.18 -60.472
60 -137.28 -91.29 -57.15 -48.416 -51.29 -57.664
80 -134.24 -87.33 -52.52 -43.672 -46.54 -53.051
100 -131.78 -84.12 -48.77 -39.824 -42.69 -49.309
150 -127.03 -77.95 -41.56 -32.426 -35.29 -42.111
200 -123.44 -73.27 -36.10 -26.831 -29.69 -36.666
250 -120.51 -69.46 -31.65 -22.276 -25.13 -32.231
300 -118.01 -66.23 -27.87 -18.405 -21.26 -28.462
400 -113.88 -60.87 -21.62 -12.005 -14.85 -22.227
500 -110.51 -56.50 -16.52 -6.776 -9.62 -17.133
600 -107.62 -52.76 -12.16 -2.321 -5.16 -12.789
700 -105.09 -49.49 -8.35 +1.584 -1.26 -8.983
710 -104.86 -49.18 -7.99 1.950 -0.89 -8.626
720 -104.62 -48.88 -7.64 2.311 -0.53 -8.274
730 -104.39 -48.58 -7.29 2.669 -0.17 -7 .*925
740 -104.16 -48.28 -6.94 3.023 +0.18 -7.580
750 -103.93 -47.99 -6.60 3.374 0.53 -7.238
760 -103.71 -47.70 -6.26 3.720 0.88 -6.900
770 -103.49 -47.41 -5.93 4.063 1.22 -6.565
780 -103.27 -47.13 -5.59 4.403 1.56 -6.334
790 -103.05 -46.85 -5.26 4.740 1.90 -5.906
800 -102.83 -46.57 -4.94 5.072 2.23 -5.581
900 -100.78 -43.91 -1.85 8.235 5.40 -2.497
1000 -98.90 -41.48 +0.99 11.135 8.30 +0.333
1200 -95.53 -37.13 6.06 16.319 13.49 5.391
1500 -91.20 -31.55 12.56 22.97 20.14 11.88
log10P » A - B/(C + t) ; t - B/(A-log10P) - C

(P In mm Hg ; t in °C)
A 6.74756 6.81960 6.84290 6.86926 6.86952 6.84134

B 585-00 785.00 926.10 960.10 960.80 923.20
C 255.00 247.00 240.00 237.000 240.00 240.000
745211 0-47-10
TABLE 1m - PARAFFINS, Cx TO C5
HEAT AND ENTROPY OF VAPORIZATION, AT 25°C AND THE NORMAL BOILING POINT
March 31, 1944; May 31, 1947
Entropy of
Normal
Vaporization,
a
Boiling Heat of Vaporization aHv, at saturation pressure aSv,
Point at satn.press.a
Compound Formula
At Normal
At 1 atm. At 25°C At Normal Bolling Point Boiling Point
°C kcal/mole cal/g BTU/lb kcal/mole cal/g BTU/lb cal/deg mole
Methane . ch4 -161.4S - - 1.955 121.87 219.22 17.51
Ethane. - 88.63 3.517 116.97 210.41 19.06

C2H6
Propane . - 42.07 3.605 81.76 147.07 4.487 101.76 183.05 19.42

%%
n-Butane. - 0.50 5.035 86.63 155.83 5.352 92.09 165.64 19.63

C4H10
2-Methylpropane (Isobutane) . . " - 11.73 4.570 78.63 141.44 5.089 87.56 157.50 19.47
n-Pentane .. 36.074 6.316 87.54 157.48 6.160 85.38 153.59 19.92

C5H12
2-Methylbutane (Isopentane) . . " 27.854 5.878 81.47 146.56 5.842 80.97 145.66 19.41
2,2-DlmethyIpropane(Neopentane) " 9.50 5.205 72.15 129.78 5.438 75.37 135.59 19.24
a For the process, CmHn (1iq.) « CmHn (gas), at saturation pressure at the indicated temperature.
National Bureau of Standards___Washington, D. C.
TABLE 2m - PARAFFINS, Cg AND C?

March 31, 1944; May 31, 1947
Entropy of
Normal
Vaporization,
Bolling Heat of Vaporization, aHv at saturation pressurea aSv,
a
Point at satn.press.
Compound Formula At Normal
At 1 atm. At 25°C At Normal Bolling Point Bolling Point
°c kcal/mole cal/g BTO/lb kcal/mole cal/g Biu/ib cal/deg mole
n-Hexane. 68.742 7.540 87.50 157.40 6.896 80.03 143.96 20.17

C6H14
2-Methylpentane . " 60.274 7.138 82.83 149.00 6.643 77.09 138.67 19.92
3- " . " 63.284 7.235 83.96 151.03 6.711 77.88 140.09 19.95
2,2-Dlme thylbutane. " 49.743 6.617 76.79 138.13 6.287 72.96 131.24 19.47
2,3- " . " 57.990 6.960 80.77 145.29 6.519 75.65 136.08 19.68
n-Heptane . C7H16 98.428 8.735 87.18 156.82 7.575 75.60 135.99 20.38
2-Methylhexane. " 90.05 8.318 83.02 149.33 7.329 73.14 131.56 20.18
3- " . " 91.95 8.385 83.68 150.53 7.350 73.43 132.09 20.15
3-Ethylpentane. " 93.468 8.419 84.02 151.14 7.398 73.83 132.81 20.18
2,2-Dlmethylpentane . " 79.205 7.751 77.36 139.15 6.969 69.55 125.11 19.78
2,3- " . " 89.79 8.184 81.68 146.92 7.262 72.48 130.38 20.01
2,4- " . " 80.51 7.860 78.44 141.11 7.050 70.36 126.56 19.93
3,3- " . " 86.071 7.892 78.76 141.68 7.085 70.71 127.19 19.72
2,2,3-Trlmethylbutane . " 80.871 7.657 76.42 137.46 6.918 69.04 124.19 19.54
a For the process, CmHn (1lq.) - CmHp (gas), at saturation pressure at the Indicated temperature.
National Bureau of Standards Washington. D. C.
TABLE 3m - PARAFFINS, Cg
March 31, 1944
Normal Entropy of
Vaporization,
Bolling Heat of Vaporization, aHv, at saturation pressurea aSv,
a
Point at satn.press.
Compound Formula
At 1 atm. At 25°C At Normal Bolling Point At Normal
Bolling Point
°c kcal/mole cal/g BTU/lb kcal/mole cal/g BTU/lb cal/deg mole
n-Octane. 125.66 9.915 86.80 156.14 8.360 73.19 131.65 20.96

C8H18
2-Methylheptane .... " 117.64 9.483 83.02 149.34 8.03 70.3 126.5 20.55
3- ” .... " 118.92 9.520 83.35 149.92 8.14 71.3 128.2 20.76
4- ” .... " 117.71 9.482 83.01 149.32 8.100 70.91 127.56 20.72
3-Ethylhexane . " 118. S3 9.475 82.95 149.21 8.19 71.7 129.0 20.91
2,2-Dlmethylhexane. . . 106.84 8.912 78.02 140.35 7.73 67.7 121.7 20.34
2,3- ” ... » 115.60 9.271 81.17 146.00 8.02 70.2 126.3 20.63
2,4- " ... " 109.43 9.026 79.02 142.14 7.82 68.5 123.2 20.44
2,5- n ... " 109.10 9.048 79.21 142.49 7.84 68.6 123.5 20.51
3,3— n ... " 111.97 8.971 78.54 141.28 7.82 68.5 123.2 20.30
3,4- " ... " 117.72 9.315 81.55 146.69 8.02 70.2 126.3 20.52
2-Methyl-3-ethylpentane " 115.65 9.207 80.60 144.99 7.96 69.7 125.4 20.47
3- " -3- ” 118.26 9.080 79.49 142.99 7.91 69.3 124.6 20.21
2,2,3-Trlmethylpentane. " 109.84 8.823 77.24 138.95 7.69 67.3 121.1 20.08
2,2,4- 99.24 8.396 73.50 132.22 7.410 64.87 116.69 19.90
2,3,3- " " 114.76 8.895 77.87 140.08 7.78 68.1 122.5 20.06
2,3,4- « 113.47 9.012 78.90 141.92 7.810. 68.37 122.99 20.20
2,2,3,3-Tetramethylbutane 106.30 10.24b 89.6b 161.3b 7.56 66.2 119.1 19.92
a For the process, C^f^ (llq.) = CujHjj (gas), at saturation pressure at the Indicated temperature,unless otherwise Indicated.
b Heat of sublimation, for the process, Cj^ (solid) = (gas), at saturation pressure at the Indicated temperature.
National Bureau of Standards_ Washington, D. C.
TABLE 4m - PARAFFINS, Cg
March 31, 1945
Normal Entropy at
Bolling Heat of Vaporization, aHv, at saturation pressure5 Vaporization,
Point aSv,
Compound Formula at satn.press.3
At 1 atm. At 25°C At Normal Bolling Point At Normal
Bolling Point
n-Nonane . . 150.80 11.099 86.54 155.67 9.030 70.41 126.65 21„30

C9H20
2-Methyloctane . " 143.26 10.67 83.2 149.7 8.76 68.3 122.9 21.03
3- " 144.18 10.69 83.4 149.9 8.79 68.5 123.3 21.06
4- " " 142.48 10.69 83.4 149.9 8.75 68.2 122.7 21.06
3-Ethylheptane . ” 143. 10.71 83.5 150.2 8.78 68.5 123.1 21.10
4- " " 142. 10.71 83.5 150.2 8.76 68.3 122.9 21.10
2,2-Dlmethylheptane. " 130.5 10.10 78.8 141.7 8.31 64.8 116.6 20.58
2,3- " 140.7 10.46 81.6 146.7 8.63 67.3 121.0 20.84
2,4- " 133. 10.25 79.9 143.8 8.45 65.9 118.5 20.80
2,5- " 136. 10.25 79.9 143.8 8.51 66.4 119.3 20.80
2,6- " 135.21 10.24 79.8 143.6 8.49 66.2 119.1 20.80
3,3- " " 137.3 10.19 79.5 142.9 8.44 65.8 118.4 20.55
3,4- ” 143. 10.48 81.7 147.0 8.69 67.8 121.9 20.87
3,5- " 136. 10.27 80.1 144.0 8.52 66.4 119.5 20.83
4,4- " " 138. 10.19 79.5 142.9 8.45 65.9 118.5 20.55
2-Methyl-3-ethylhexane . . . " 139. 10.48 81.7 147.0 8.60 67.1 120.6 20.87
2- " -4- " . " 136. 10.27 80.1 144.0 8.52 66.4 119.5 20.83
3- " -3- " . " 143. 10.28 80.2 144.2 8.54 66.6 119.8 20.53
3- " -4- " . " 143. 10.50 81.9 147.3 8.70 67.8 122.0 20.90
2,3,3-Trlmethylhexane. " 134. 10.02 78.1 140.5 8.31 64.8 116.6 20.40
2,2,4- " . " 126.54 9.69 75.6 135.9 8.13 63.4 114.0 20.34
2,2,5- " . " 124.09 9.601 74.86 134.66 8.07 62.9 113.2 20.31
2,3,3- " . " 138. 10.09 78.7 141.5 8.36 65.2 117.3 20.34
2,3,4- " . " 140. 10.26 80.0 143.9 8.53 66.5 119.6 20.64
2,3,5- n . " 131.37 9.900 77.19 138.86 8.32 64.9 116.7 20.57
2,4,4- " . " 131. 9.76 76.1 136.9 8.20 63.9 115.0 20.29
3,3,4- n " 139. 10.11 78.8 141.8 8.40 65.5 117.8 20.37
3,3-Dlethylpentane . " 146.5 10.36 80.8 145.3 8.60 67.1 120.6 20.50
2,2-Dlmethyl -3-eth.vlpentane. " 133.83 10.04 78.3 140.8 8.32 64.9 116.7 20.43
2,3- -3- " . " 142. 10.17 79.3 142.6 8.44 65.8 118.4 20.32
2,4- -3- " . " 136.73 10.26 80.0 143.9 8.46 66.0 118.7 20.64
2,2,3,3-Tetramethylpentane . " 140.23 9.80 76.4 137.4 8.43 65.7 118.2 20.38
2,2,3,4- " " 133.01 9.80 76.4 137.4 8.19 63.9 114.9 20.17
2,2,4,4- " ..... " 122.28 9.11 71.0 127.8 7.85 61.2 110.1 19.86
2,3,3,4- " . " 141.54 9.98 77.8 140.0 8.35 65.1 117.1 20.13
ôr the process, Cn^n(llq.) = CmHn(gas), at saturation pressure at the indicated temperature.
National Bureau of Standards _ ____Washington, D. C.
TABLE 5m - ALKYL BENZENES, CQ TO Cg

June 30, 1944; revised rforch 31, 1945
Normal Entropy of
Vaporization,
Boiling Heat of'Vaporization, aHv at saturation pressure3
Point aSv,
Compound Formula at satn.press.3
At Normal
At 1 atm. At 25°C At Normal Boiling Point
Boiling Point
Benzene . c6h6 80.10 8.090 103.57 186.31 7.353 94.14 169.34 20.81
Methylbenzene (Toluene) . C7hb 110.62 9.080 98.55 177.28 8.00 86.8 156.2 20.85
Ethylbenzene. 136.19 10.097 95.11 171.09 8.60 81.0 145.7 21.01

C8H10
1,2-Dimethylbenzene (o-Xylene). . . . " 144.42 10.381 97.79 175.90 8.80 82.9 149.1 21.07
1,3- " (m- " ). . . . « 139.10 10.195 96.03 172.75 8.70 82.0 147.4 21.10
n
1,4- " (P- " )• . . . 138.35 10.128 95.40 171.61 8.62 81.2 146.1 20.95
n-Propylbenzene . 159.22 11.049 91.93 165.37 9.14 76.0 136.8 21.14

CSH12
Isopropylbenzene (Cumene) . " 152.40 10.789 89.77 161.48 8.97 74.6 134.3 21.08
1-Methyl-2-ethylbenzene . " 165.15 11.40 94.9 170.7 9.29 77.3 139.0 21.2
1- " -3- " . " 161.30 11.21 93.3 167.8 9.21 76.6 137.8 21.2
fl
1- " -4- " . 162.05 11.14 92.7 166.7 9.18 76.4 137.4 21.1
1,2,3-Trlmethylbenzene (Hemlmellitene) n 176.15 11.725 97.56 175.49 9.57 79.6 143.2 21.3
1,2,4- " (Pseudocumene) n 169.25 11.457 95.33 171.48 9.38 78.0 140.4 21.2
1,3,5- " (Mesitylene) . " 164.70 11.346 94.40 169.82 9.33 77.6 139.6 21.3
a For the process, CmHn(liq.) = Cj^fgas), at saturation pressure at the indicated temperature.
National Bureau of Standards_____Washington. D. C.
TABLE 6m - ALKYL CYCLOPENTANES, C& to C?
HEAT AND ENTROPY OF VAPORIZATION. AT 25°C AND THE NORMAL BOILING POINT
March 31, 1945
Normal Entropy of
Boiling Heat of Vaporization, aHv, at saturation pressure3 Vaporization,
aSv,
Compound Formula Point
at satn.press.3
At 1 atm. At 25° C At Normal Bolling Point At Normal

Bolling Point
°C kcal/mole cal/g BTU/1P kcal/mole cal/g BTU/lb cal/deg mole
Cyclopentane. 49.26 6.81 97.1 174.7 6.53 93.1 167.5 20.26

C5H10
Methylcyclopentane-.. 71.81 7.560 89.83 161.59 7.00 83.2 149.6 20.30

C6H12
Ethylcyclopentane . 103.45 8.70 88.6 159.4 7.69 78.3 140.9 20.42

C7H14
1,1-Dimethylcyclopentane. " 87.5 8.10 82.5 148.4 7.32 74.6 134.1 20.3
cls-1,2-Dlmethylcyclopentane. " 99.3 8.48 86.4 155.4 7.56 77.0 138.5 20.3
trans-1,2- " . " 91.9 8.24 83.9 151.0 7.41 75.5 135.8 20.3
cis-1,3- " . "

n
trans-1,3- " . 90.8 8.21 83.6 150.4 7.39 75.3 135.4 20.3
3 For the process, CjjHjj (Uq.)- CmHn (gas), at saturation pressure at the Indicated temperature.
TABLE 7m - ALKYL CYCLOHEXANES, Cc to C0

b o
March 31, 1945; March 31, 1947
Entropy of
Normal Vaporization,
Bolling Heat of Vaporization, aHv, at saturation pressure3 aSv,
Point
at satn. pressure3
C ompound Formula
At Normal
Cyclohexane . 80.74 7.895 93.81 168.75 7.19 85.4 153.7 20.30

C6H12
Methylcyclohexane . 100.94 8.451 86.07 154.83 7.58 77.2 138.9. 20.26

C7H14
Ethylcyclohexane. 131.79 9.673 86.21 155.07 8.29 73.9 132.9 20.47

C8H16
1,1-Dlmethylcyclohexane . " 119.54 9.043 80.59 144.97 7.88 70.2 126.3 20.06
II
cls-l,2-Dlmethylcyclohexane . 129.73 9.492 84.59 152.17 8.18 72.9 131.1 20.29
II
trans-1,2- " . 123.42 9.167 81.70 146.96 7.98 71.1 127.9 20.13
It
cls-l,3-b ,r . 120.09 9.136 81.42 146.46 7.96 70.9 127.6 20.25
II
trans-l,3-c " . 124.45 9.368 83.49 150.18 8.09 72.1 129.7 20.35
II
cls-1,4- " . 124.32 9.328 83.13 149.54 8.07 71.9 129.4 20.30
II
trans-1,4- " . 119.35 9.052 80.67 145.11 7.90 70.4 126.6 20.12
For the process, C^Hf, (Uq.) = CmHn (gas), at saturation pressure at the Indicated temperature.
Formerly labeled "trans"; see footnote d of Table 7a. c Formerly labeled "els"; see footnote e of Table 7a.
National Bureau of Standards___ Washington, D. C.
TABLE 8m (Part 1) - MONOOLEFINS, C2 to C4
HEAT AMD ENTROPY OF VAPORIZATION, AT 25°C AND THE NORMAL BOILING POINT
March 31, 1945
Normal Entropy of
Vaporization,
Bolling
Heat of Vaporization, aHv at saturation pressure3 ASV,
Point at satn.press.3
Compound Formula
At Normal
Ethene (Ethylene) . c2h4 -103.71 - - - 3.237 115.39 207.56 19.10
Propene (Propylene) . -47.70 - - - 4.402 104.62 118.19 19.52

C3H6
1-Butene. C4H8 -6.25 4.87 86.8 156.1 5.238 93.36 167.93 19.62
cis-2-Butene. " 3.72 5.30 94.5 169.9 5.580 99.46 178.91 20.15
trans-2- " . " 0.88 5.15 91.8 165.1 5.439 96.94 174.37 19.85
2-Methylpropene (Isobutene) . " -6.90 4.92 87.7 157.7 5.286 94.22 169.48 19.85
For the process, CmHn (liq.) = CjjHj, (gas), at saturation pressure at the Indicated temperature
American P«trol«um Institute Research Profact 44
National Buraau of Standards__ Washington, D, C.
TABLE On - H_, C , CO
&
HEATS OF COMBUSTION, AT 25°C a
April 30, 1945; May 31, 1945
Heat of Combustion, - aHc°,
Compound Formula State Reaction at 25°C and constant pressure*3
kcal/mole cal/g BTU/lb
Hydrogen.. gas Hg(gas) + i Og(gas) = Hg0 (llq.c) 63.3174 33887.6 60957.7

H2
Hydrogen.. gas Hg(gas) + i Og(gas) r Hg0 (gas) 57.7979 28669.6 61571.4

K2
Carbon. . . C solid, C(solld, graphite) + Og(gas)= COg(gas) 94.0518 7831.1 14086.8

graphite
Carbon monoxide . CO gas CO(gas) + ± Og(gas) s COg(gas) 67.6361 2414.7 4343.6
a The values In this table are given to more significant figures than are warranted by the absolute accuracy of the
Individual values. In order to retain the significance of certain differences.
^ ~aHc° represents the heat evolved In the combustion of the given compound In the state Indicated, in gaseous oxygen
to form the products Indicated, at 25°C and constant pressure, with all the reactants and products in their appro¬
priate standard reference states.
c llq. = liquid.
SELECTED VALUES OF PROPERTIES OF HYDROCARBONS 14]
National Bureau of Standards Washington, D. G.
TABLE In - PARAFFINS, Cx TO C5
March 31, 1944; April 30, 1945
neat of Combustion, -4Hc°#

o
at 25 C and constant pressure, t formc:
Compound Formula State13
HgO (liq.) and Ctig (gas) HgO (gas) and C02 (gas)
kcal/mole cal/g BTU/lb kcal/mole cal/g BTU/lb
Methane . gas 212.798 13265.1 23861. 191.759 11953.6 21502.

CH4
Ethane . gas 372.820 12399.2 22304. 341.261 11349.6 20416.

C2H6
Propane . , gas 530.605 12033.5 21646. 488.527 11079.2 19929.

C3»8
" . llq.d 526.782 11946.8 21490. 484.704 10992.5 19774.
n-Butane. gas 687.982 11837.3 21293. 635.384 10932.3 19665.

C4H10
tl n
llq.d 682.844 11748.9 21134. 630.246 10843.9 19506.
2-Methylpropane (Isobutane) . . . " gas 686.342 11809.1 21242. 633.744 10904.1 19614.
ft " llq.d 681.625 11727.9 21096. 629.027 10822.9 19468.
n-Pentane. gas 845.16 11714.6 21072. 782.04 10839.7 19499.

C5H12
" . " iiq* 838.80 11626.4 20914. 775.68 10751.6 19340.
2-Methylbutane (Isopentane) . . . " gas 843.24 11688.0 21025. 780.12 10813.1 19&1.
n " 11Q- 837.31 11605.6 20877. 774.19 10730.9 19303-
2,2-DImethylpropane (Neopentane). " gas 840.49 11649.8 20956. 777.37 10775.0 19382.
■ n llq.d 835.18 11576.2 20824. 772.06 10701.4 19250-
a The values In this table are given to mo're significant figures than are warranted- by the absolute accuracy of the Indi¬
vidual values In order to retain the significance of the small differences between the liquid and gaseous states and,
to a lesser extent, between Isomers.
b liq. = liquid.
c -aHc° represents the heat evolved In the combustion of the given hydrocarbon, In the state Indicated, In gaseous oxygen
to form gaseous carbon dioxide aril gaseous or liquid water, as Indicated, at 25°C and constant pressure, with all the
reactants and products In their appropriate standard reference states, unless otherwise Indicated.
d At saturation pressure.
TABLE 2n - PARAFFINS, C6 AND C?

March 31, 1944; April 30, 1945
Heat of Combustion, -aHc° >

at 25°C and constant pressure. to formc:
HgO (llq.) and CO,, (gas) HgO (gas) and C02 (gas)
gas 1002.57 11634.5 20928. 928.93 10780.0 19391.

C6H14
". " llq. 995.01 11546.8 20771. 921.37 10692.2 19233.
2-Methylpentane . II gas 1000.87 11614.8 20893. 927.23 10760.2 19356.

It « llq. 993.71 11531.7 20743. 920.07 10677.1 19206.
3-Metbylpentane . n gas 20906. 10767.6 19369.

1001.51 11622.2 927.87
" . * llq- 994.25 11538.0 20755. 920.61 10683.4 19218.
2,2-Dlmethylbutane. " gas 998.17 11583.5 20837. 924.53 10728.9 19299.

n 10651.7
" . llq. 991.52 11506.3 20698. 917.88 19161.
2,3-Dlmethylbutane. " gas 1000.04 11605.2 20876. 926.40 10750.6 19338.
" . " llq. 993.05 11524.0 20730. 919.41 10669.5 19192.
n-Heptane . c7h16 gas 1160.01 11577.2 20825. 1075.85 10737.2 19314.
" . . " llq. 1151.27 11489.9 20668. 1067.11 10650.0 19157.
2-Methylhexane. " gas 1158.30 11560.1 20795. 1074.14 10720.2 19284.

II It
llq. 1149.97 11477.0 20645. 1065.81 10637.0 19134.
3-Methylhexane. " gas 1158.94 11566.5 20806. 1074.78 10726.6 19295.

It 10642.8 19145.
" llq. 1150.55 11482.8 20655. 1066.39
3-Ethylpentane. " gas 1159.56 11572.7 20817. 1075.40 10732.7 19306.

II
" . llq. 1151.13 11488.6 20666. 1066.97 10648.6 19155.
2,2-Dlmethylpentane . " gas 1155.61 11533.3 20746. 1071.45 10693.3 19235.
» . " llq. 1147.85 11455.8 20607. 1063.69 10615.9 19096.

n
2,3-Dlmethylpentane ....... gas 1157.28 11549.9 20776. 1073.12 10710.0 19265.
" . " llq. 1149.09 11468.2 20629. 1064.93 10628.3 19118.

it 19253.
2,4-Dlmethylpentane .. gas 1156.60 11543.1 20764. 1072.44 10703.2
n 1148.73 11464.6 20623. 1064.57 10624.7 19112.
11 . llq.
3,3-Dimethylpentane . « gas 1156.73 11544.4 20766. 1072.57 10704.5 19255.

tl " llq. 1148.83 11465.6 20625. 1064.67 10625.7 19114
n 11536.6 20752. 1071.78 10696.6 19241.
2,2,3-Trlmethylbutane . gas 1155.94
" . n llq. 1148.27 11460.0 20614. 1064.11 10620.1 19104.
a See footnote a of Table In. b llq. = liquid. 0 See footnote c of Table In.
SELECTED VALUES OF PROP (RTIES OF HYDROCARBONS 143
TABLE 3n - PaRAFFINS, Cq
HEATS OF COMBUSTION, AT 25°C 3
March 31, 1944; April 30, 1945
Heat of Combustion, -aHc°,

0 f*
at 25 C and constant pressure, to form :
Compound Formula Stateb
H20 (llq.) and C0;2 (gas) HgO (gas) and CCg (gas)
kcal/mole cal/g BTU/lb kcal/mole cal/g ETU/lb
n-Octane. ....... gas 1317.45 11533.9 20747. 1222.77 10705.0 19256.

C8H18
" . " llq. 1307.53 11447.1 20591. 1212.85 10618.2 19100.
2-Methylheptane .... II gas 11519.1 20721. 1221.08 10690.2 19230.

1315.76
" .... II llq. 1306.28 11436". 1 20572. 1211.60 10607.2 19080.
3-Methylheptane .... II gas 1316.44 11525.1 20732. 1221.76 10696.2 19240.
" .... II llq. 1306.92 11441.7 20582. 1212.24 10612.8 19091.

4-Methylheptane .... II gas 1316.57 11526.2 20734. 19243.
1221.89 10697.3
II llq. 1307.09 11443.2 20584. 1212.41 10614.3 19093.
3-Ethylhexane . II gas 1316.87 11528.8 20738. 1222.19 10699.9 19247.
n . II llq. 1307.39 1212.71 10616.9
11445.8 20589. 19098.
2,2-Dimethylhexane. . . II gas' 1313.56 11499.9 20686. 1218.88 10671.0 19195.
" . . . llq. 1304.64 11421.8 20546. 1209.96 10592.9 19055.
2,3-Dlmethylhexane. . . " gas 1316.13 11522.4 20727. 1221.45 10693.5 19236.
" . . . llq. 1306.86 11441.2 20581. 1212.18 10612.3 19090.
" . . . llq. 1305.80 11431.9 20564. 1211.12 10603.0 19073.
It " llq. 1305.00 11424.9 20551. 1210.32 10596.0 19060.
3,3-Dlmethylhexane. . . gas 1314.65 11509.4 20703. 1219.97 10680.5 19212.
" ... " llq. 1305.68 11430.9 20562. 1211.00 10602.0 19071.
3,4-Dlmethylhexane. . . II gas 1316.36 11524.4 20730. 1221.68 10695.5 19239.
" ... II llq. 1307.04 11442.8 20583. 1212.36 10613.9 19092.
2-Methyl-3-ethylpentane II gas 1316.79 20737. 1222.11
11528.1 10699.2 19246.
" II llq. 1307.58 11447.5 20592. 1212.90 10618.6 19101.
3-Me thy1-3-e thylpentane 11 gas 1315.88 11520.2 20723. 1221.20 10691.3 19232.
" II llq. 1306.80 11440.7 20580. 1212.12 10611.8 19089.
2,2,3-Trlmethylpentane. II gas 1314.66 20703.
11509.5 1219.98 10680.6 19212.
" II llq. 1305.83 11432.2 20564. 1211.15 10603.3 19073.
2,2,4-Trlme thylpentane. It gas 1313.69 11501.0 20688. 10672.1
1219.01 19197.
" II llq. 1305.29 11427.5 20556. 1210.61 10598.6 19065.
2,3,3-Trlmethylpentane. " gas 1315.54 11517.2 20717. 1220.86 10688.3 19226.
" " llq. 1306.64 11439.3 20577. 1211.96 10610.4 19086.
2,3,4-Trlmethylpentane. " gas 1315.29 11515.0 20713. 1220.61 10686.1 19222.
" " llq. 1306.28 11436.1 20572. 1211.60 10607.2 19080.
2,2,3,3-Tetramethylbutane " gas 1313.27 11497.3 20682. 1218.59 10668.4 19191.
" " solid 1303.03 11407.7 20520. 1208.35 10578.8 19029.
See footnote a of Table In. b llq. = liquid; solid = crystalline solid. 0 See footnote c of Table In.
National Bureau of Standards Washinoton, 1). C.
TABLE 5n - ALKYL BENZENES, Cg to Cg

HEATS OF COMBUSTION, AT 25°C
March 31, 1945

at 25°C and constant pressure, to form*3:
Compound Formula Statea
HgO (llq.) and C02 (gas) HgO (gas) and C02 (gas)
Benzene . c6H6 gas 789.08 10102.4 18172. 757.52 9698.4 17446.

" . ° llq. 780.98 9998.7 17986. 749.42 9594.7 17259.
Methylbenzene (Toluene) . gas 943.58 10241.4 18422. 901.50 9784.7 17601.

c7H8
" . " llq. 934.50 10142.8 18245. 892.42 9686.1 17424.
Ethylbenzene. C8H10 gas 1101.13 10372.4 18658. 1048.53 9876.9 17767.

■ ■ llq. 1091.03 10277.2 18487. 1038.43 9781.7 17596.
1,2-Dlmethylbenzene (o-Xylene). " gas 1098.54 10348.0 18614. 1045.94 9852.5 17723.
• . " llq. 1088.16 10250.2 18438. 1035.56 9754.7 17547.
1,3-Dlmethylbenzene (m-Xylene). * gas 1098.12 10344.0 18607. 1045.52 9848.5 17716.
" ...... ■ llq. 1087.92 10247.9 18434. 1035.32 9752.4 17543.
1,4-Dlmethylbenzene (p-Xylene). " gas 1098.29 10345.6 18610. 1045.69 9850.1 17719.
" . * llq. 1088.16 10250.2 18438. 1035.56 9754.7 17547.
n-Propylbenzene . c9h12 gas 1258.24 10469.1 18832. 1195.12 9943.9 17887.

- . " llq. 1247.19 10377.2 18667. 1184.07 9852.0 17722.
Isopropylbenzene (Cumene) . n gas 1257.31 10461.4 18818. 1194.19 9936.2 17873.

ft 18657. 1183.40 17712.
’ . llq. 1246.52 10371.6 9846.4
1-Methyl-2-ethylbenzene . n gas 1256.66 10456.0 18808. 1193.54 9930.8 17864.
" . a 1245.26 10361.1 18638. 1182.14 9835.9 17693.

llq.
1-Methyl-3-ethylbenzene . " gas 1255.92 10449.8 18797. 1192.80 9924.6 17853.
■ . n llq. 1244.71 10356.5 18630. 1181.59 9831.3 17685.
1-Methyl-4-ethylbenzene . ■ gas 1255.59 10447.1 18792. 1192.47 9921.9 17848.

■ ■ llq. 1244.45 10354.4 18626. 1181.33 9829.2 17681.
a gas 1254.08 10434.5 18770. 1190.96 9909.3 17826.
1,2,3-Trlmethylbenzene (Hemlmellltene). .
■ . . ■ llq. 1242.36 10337.0 18594. 1179.24 9811.8 17650.
1,2,4-Trlmethylbenzene (Pseudocumene) . . ■ gas 1253.04 10425.8 18754. 1189.92 9900.7 17809.
" . . ■ llq. 1241.58 10330.5 18583. 1178.46 9805.3 17638.

n gas 1252.53 10421.6 18747. 1189.41 9896.4 17802.
1,3,5-Trlmethylbenzene (Mesltylene) . . .
■ ■ llq. 1241.19 10327.2 18577. 1178.07 9802.1 17632.
a llq. = liquid
b See footnote c of Table In.

National Bureau of Standards___ Washington. D. C.
TABLE 9n (Part 1) - MONOOLEFINS, Cg to Cg
HEAT OF COMBUSTION, AT 25°C
October 31, 1945
at 25°C and constant pressure, to form5':

H20 (llq-) and CO2 (gas) H20 (gas) and COg (gas)
Ethene (Ethylene). gas 337.234 12021.7 21625. 316.195 11271.7 20276.

C2H4
Propene (Propylene). C3H6 gas 491.987 11692.3 21032. 460.428 10942.3 19683.
1-Butene . C4H8 gas 649.757 11581.3 20833. 607.679 10831.3 19484.
■ . " llq.
cls-2-Butene . " gas 648.115 11552.0 20780. 606.037 10802.0 19431.
■ . " llq.
trans-2-Butene . gas 647.072 11533.4 20747. 604.994 10783.4 19397.
* . " llq.
2-Methylpropene (Isobutene). gas 646.134 11516.7 20716. 604.056 10766.7 19367.
" . " llq.
1-Pentene. C5H1O gas 806.85 11505.1 20696. 754.25 10755.1 19346.
" . llq.
cls-2-Pentene. gas 805.34 11483.5 20657. 752.74 10733.5 19308.
" . ■ llq.
trans-2- Pentene . " gas. 804.26 11468.1 20629. 751.66 10718.1 19280.
* . " llq.
2-Methyl-1-butene. " gas. 803.17 11452.6 20601. 750.57 10702.6 19252.
" . " llq.
3-Methyl-1-butene. " gas 804.93 11477.7 20646. 752.33 10727.7 19297.
” . " llq.
2-Methyl-2-butene. ” ' gas 801.68 11431.3 205&3. 749.08 10681.3 19214.
■ llq.
3 llq. - liquid
b
See footnote c of Table In.
TABLE 8n (Part 2) - MONOOLEFINS . c6

HEAT OF COMBUSTION, AT 25° C
October 31, 1045
at 25°C and constant pressure, to formb:

HgO (llq.) and COg (gas) HgO (gas) and C0£ (gas)
kcal/mole cal/g BTU/lb kcal/mole cal/g BTU/1L
1-Hexene. °6h12 gas 964.26 11458.0 20611. 901.14 10708.0 19262.
" . " llq.
cls-2-Hexene. gas 962.66 11439.0 20577. 899.54 10689.0 19228.

" . " llq.
trans-2-Hexene. " gas 961.66 11427.1 20555. 898.54 10677.1 19206.
" . " llq.
cls-3-Hexene. " gas 062.66 11439.0 20577. 899.54 10689.0 19228.
" . " llq.
trans-3-Hexene. " gas 061.66 11427.1 20555. 898.54 10677.1 19206.
" . " llq.
2-Hethyl-l-pentene. " gas 960.66 11415.2 20534. 897.54 10665.2 19185.
" . " llq.
3-Hethyl-l-pentene. " gas 963.20 11445.4 20588. 900.08 10695.4 19239.
" . | llq.
4-Methyl-l-pentene. gas 962.56 11437.8 20575. 899.44 10687.8 19225.
" . " llq.
2-Methyl-2-pentene. " gas 959.26 11398.6 20504. 896.14 10648.6 19155.
" . n llq.
ols (?)-3-Methyl-2-pentene. " gas 959.QO 11406.2 20518. 896.78 10656.2 19169.
" . " llq.
trans (?)-3-Methyl 2-pentene. gas 959.90 11406.2 20518. 896.78 10656.2 19169.
" . " llq.
cls(?)-4-Methyl-2-pentene . " gas 960.96 11418.8 20540. 897.84 10668.8 19191.
" . " llq.
trans (?)-4-Methyl-2-pentene. gas 959.96 11406.9 20519. 896.84 10656.9 19170.
" . " llq.
2-Ethyl-1-butene. ", gas 961.30 11422.8 20548. 898.18 10672.8 19198.
" . " llq.
2,3-Dlmethyl-l-butene . " gas 959.44 11400.7 20508. 896.32 10650.7 19159.
11 . " llq.
3-3-Dimethyl-l-butene . " gas 959.97 11407.0 20519. 896.85 10657.0 19170.
" . " llq.
2,3-Dlmethyl-2-butene . " gas 958.31 11387.3 20484. 895.19 10637.3 19135.
" . llq.
a llq. r liquid

TABLE 9n (Part 1) - MONOOLEFINS, C7
October 31, 1945
Heat of Combustion, -&Hcc
at 25°C and constant pressure. to form*3:

Compound
Formula State3
HgO (llq.) and COg(gas) HgO (gas) and C0£ (gas)
1-Heptene. gas 1121.69 11424.6 20551. 1048.05 10674.6 19202.

C7H14
" . " liq.
cls-2-Heptene. " gas 1120.09 11408.3 20522. 1046.45 10658.3 19172.
' . " llq.
trans-2-Heptene. " gas 1119.09 11393.1 20503. 1045.45 10648.1 19154.
' . llq.
cls-3-Heptene. " gas 1120.09 11408.3 20522. 1046.45 10658.3 19172.
" . " llq.
trans-3-Keptene. " gas 1119.09 11398.1 20503. 1045.45 10648.1 19154.
" . " llq.
2-Methyl-1-hexene. gas 1118.08 11387.8 20485. 1044.44 10637.8 19136.
" " llq.
3-Methyl-l-hexene. " gas 1120.62 11413.7 20531. 1046.98 10663.7 19182.
■ . llq.
4-Methyl-l-hexene. " gas 1120.62 11413.7 20531. 1046.98 10663.7 19182.
" . " llq.
5-Methyl-1-hexene. " gas 1119.98 11407.2 20520. 1046.34 10657.2 19170.
" . " llq.
2-Methy1-2-hexene. " gas 1116.68 11373.6 20459. 1043.04 10623.6 19110.
" " llq.
c ls-3-Methyl-2-hexene. " gas 1117.32 11380.1 20471. 1043.68 10630.1 19122.
“ . . " llq.
trans-3-Methyl-2-hexene. gas 1117.32 11380.1 20471. 1043.68 10630.1 19122.
■ " llq.
cl8-4-Methyl-2-hexene. " gas 1119.02 11397.4 20502. ln45.38 10647.4 19153.
" . " llq.
trans-4-Methyl-2-hexene. " gas 1118.02 11387.2 20484. 1044.38 10637.2 19134.
" " llq.
cls-5-Methyl-2-hexene. " gas 1118.38 11390.9 20490. 1044.74 10640.9 19141.
" " llq.
trans-5-Methy1-2-hexene. " gas 1117.38 11380.7' 20472. 1043.74 10630.7 19123.
" " llq.
cls-2-Methyl-3-hexene. " gas 1118.39 113°0.9 20490. 1044.74 10640.9 19141.
" " llq.
trans-2-Methyl-3-hexene. " gas 1117.38 11380.-7 20472. 1043.74 10630.7 19123.
" * llq.
c1s-3-Methyl-3-hexe ne. " gas 1117.32 11380.1 20471. 1043.68 10630.1 19122.
" " llq.
trans-3-Methyl-3-hexene. . . . . n gas 1117.32 11390.1 20471. 1043.68 10630.1 19122.
" " llq.
a llq. = liquid.
15 See footnote c of Table In.
745211 0 - 47 - 11
National Bureau of Standards,___Washington, D. C.
TABLE 9n (Part 2) - MONOOLEFINS, C7
HEAT OF COMBUSTION AT 25°C
October 31, 1945
Heat of Combustion, -aHc°
at 25°C and constant pressure, to form*3:

Compound
Formula State3
HQ (ilq.) and (X) (gas) Hg0 (gas) and C0g (gas)
d 2
keal/ffiol© cal/g BTU/lb kcal/mole cal/g BTU/lb
2-Ethyl-l-pentene . . . . gas 1118.72 11394.3 20496. 1045.08 10644.4 19147.

Via
“ . X
• • • llq.
3-Ethyl-l-pentene . . . . . " gag 1121.24 11420.0 20542. 1047.60 10670.0 19193.

“ ...... • llq.
2,3-Dlmethyl-l-pentene. . . . • • • " gas 1117.06 11377.4 20466. 1043.42 10627.4 19117.
" .... • • " llq.
2,4-Dlmethyl-l-pentene. . . . . • . gas 1116.38 11370.5 20454. 1042.74 10620.5 19104.
" .... . . " llq.
3,3-Dimethyl-l-pentene. . . . . . . gas 1110.41 11391.2 20491. 1044.77 10641.2 19142.
" .... • • . . " llq.
3,4-Dlmethyl-l-pentene. . . . • . . . " gas 1118.96 11396.3 20501. 1045.32 10646.8 19152.
" .... • • . . ■ llq.
4,4-Dlmethyl-l-pentene. . . . . . . " gas 1117.29 11379.8 20470. 1043.65 10629.8 19121.
" .... . . " llq.
3-Ethyl-2-pentene . . . " gas 1117.94 11386.4 20482. 1044.30 10636.4 19133.
" ...... • • . " llq.

n 20437. 10611.2 19088.
2,3-Dlmethyl-2-pentene. . . . . . gas 1115.46 11361.1 1041.82
' . . . . . . . . ■ llq.
2,4~Dlmethyl-2-pentene. . . . . . ” gas 1114.98 11356.3 20428. 1041.34 10606.3 19079.
* .... . . llq.
cls-3,4-Dlmethyl-2-pentene. . . . . n gas 1115.66 11363.2 20440. 1042.02 10613.2 19091.
• . . . . " llq.
trans-3,4-Dlmethyl-2-pentene. . . " gas 1115.66 11363.2 20440. 1042.02 10613.2 19091.
" . . . " llq.
cla-4,4-Dlir.ethy l-2-per:ter,e. . " gas 1115.69 11363.5 20441. 1042.05 10613.5 19092.
.
" . .. * llq.
trans-4,4-Dlmethyl-2-pentene. . . . " gas 1114.69 11353.3 20422. 1041.05 10603.3 19073. |
" . . . " llq.

w 20466. 1043.42 10627.4 19117.
3-Methyl-2-ethyl-l-butene . . . . . gas 1117.06 11377.4
" . . llq.
" gas 1115.72 11363.8 20441. 1042.08 10613.8 19092. :

2,3,3-Trlmethyl-l-butene. . .
L:a llq. = liquid

•
" llq.
1
TABLE 12n - ACETYLENES, C2 to C5
March 31, 1946
at 25°C and constant pressure, to form13:

H20 (llq.) and COg (gas) HgO (gas) and CO2 (gas)
Ethyne (Acetylene) . c2h2 gas 310.615 11930.2 21460. 300.096 11526.2 20734.
m " llq.
Propyne (Methylacetylene). . . c3h4 gas. 463.109 11559.8 20794. 442.070 11034.6 19849.
" ... " llq.
1-Butyne (Ethylacetylene). . . c4h6 gas 620.86 11478.7 20648. 589.302 10895.2 19599.
ft
" llq.
2-Butyne (Dlmethylacetylene) . " gas 616.533 11398.7 20504. 584.974 10815.2 19455.
ft
" llq.
1-Pentyne. C5H8 gas 778.03 11422.5 20547. 735.95 10804.7 19436.

n
" . llq.
2-Pentyne. " gas 774.33 11368.2 20449. 732.25 10750.4 19338.

ft
" llq.
3-Methyl-1-butyne. ” gas 776.13 11394.6 20497. 734.05 10776.8 19386.

H " llq.
a llq. = liquid b See footnote c of Table In.

National Bureau ot Standards Washington, D. C.
TABLE 20n - NORMAL PARAFFINS, C]_ to Cgo
HFAT OF COMBUSTION, AT 25°C
December 31, 1945
Compound Formula
HgO (llq.) and COg (gas) HgO (gas) and C02 (gas)
Methane . ch4 gas 212.798 13265.1 23861. 191.759 11953.6 21502.
" . . . . " llq.
Ethane . gas 372.820 12399.2 22304. 341.261 11349.6 20416.

C2h6
" . ■» llq.
Propane . C3H8 gas 530.605 12033.5 21646. 488.527 11079.2 19929.
" . " llq.c 526.782 11946.8 21490. 484.704 10992.5 19774.
n-Butane . C4H10 gas 687.982 11837.3 21293. 635.384 10932.3 19665.

" . " llq.° 682.844 11748.9 21134. 630.246 10843.9 19506.
n-Pentane .... . c5h12 gas 845.16 11714.6 21072. 782.04 10839.7 19499.
" . " llq. 838.80 llb26.4 20914. 775.68 10751.5 19340.
n-Hexane . c6h14 gas 1002.57 11634.5 20928. 928.93 10780.0 19391.

" . " llq. 995.01 11546.8 20771. 921.37 10692.2 19233.
n-Heptane . gas 1160.01 11577.2 20825. 1075.85 10737.2 19314.

C7H16
" . " llq. 1151.27 11489.9 20668. 1067.11 10650.0 19157.
n-Octane . gas 1317.45 11533.9 20747. 1222.77 10705.0 19256.

C8H18
" . " llq. 1307.53 11447.1 20591. 1212.85 10618.2 19100.
n-Nonane . c9h20 gas 1474.yo 11500.2 20687. 1369.70 10680.0 19211.
" . " llq. 1463.80 11413.6 20531. 1358.60 10593.4 19056.
n-Decane . gas 1632.34 11473.0 20638. 1516.63 10659.7 19175.

C10H22
" . 11 llq. 1620.06 11386.7 20483. 1504.35 10573.4 19020.
n-Undecane. C11H24 gas 1789.78 11450.8 20598. 1663.55 10643.2 19145.
" . " llq. 1776.32 11364.7 20443. 1650.09 10557.0 18990.
n-Dodecane. gas 1947.23 11432.2 20564. 1810.48 10629.4 19120.

C12H26
" . " llq. 1932.59 11346.3 20410. 1795.84 10543.4 18966.
n-Trldecane . gas 2104.67 11416.5 20536. 1957.40 10617.6 19099.

C13H28
" . " llq. 2088.85 11330.6 20382. 1941.58 10531.8 18945.
n-Tetradecane . gas 2262.11 11402.9 20512. 2104.32 10607.5 19081.

C14H30
11 . " llq. 2245.11 11317.2 20358. 2087.32 10521.8 18927.
n-Pentadecane . gas 2419.55 11391.2 20491. 2251.24 10598.7 19065.

C15H32
" . " llq. 2401.37 11305.6 20337. 2233.06 10513.2 18911.
n-Hexadecane. gas 2577.00 11380.9 20472. 2398.17 10591.1 19052.

C16H34
" . " llq. 2557.64 11295.4 20318. 2378.81 10505.6 18898.
n-Heptadecane . C17h36 gas 2734.44 11371.8 20456. 2545.09 10584.3 19039.
" . " llq. 2713.90 11286.4 20302. 2524.55 10498.9 18886.
n-Octadecane. gas 2891.88 11363.7 20441. 2692.01 10578.3 19028.

C18H38
" . " llq. 2870.16 11278.4 20288. 2670.29 10493.0 18875.
n-Nonadecane. gas 3049.33 11356.5 20428. 2838.94 10572.9 19019.

C19H40
" . llq. 3026.43 11271.2 20275. 2816.04 10487.7 18865.
n-Elcosane. c20H42 gas 3206.77 11350.0 20416. 2985.86 10568.1 19010.
" . llq. 3182.69 11264.7 20263. 2961.78 10482.8 18857.

_
a llq.- liquid b See footnote c of Table In. 0 At saturation pressure.
TABLE 21n - NORMAL ALKYL BENZENES, Cg to CZ2
December 31, 1945
Compound Formula St)atea

H2O (llq.) and COg (gas) HgO (gas) and C02 (gas)
Benzene . c6h6 gas 739.08 10102.4 18172. 757.52 9698.4 17446.

n
llq. 780.98 9998.7 17986. 749.42 9594.7 17259.
Methylbenzene (Toluene). . . . c7h8 gas 943.58 10241.4 18422. 901.50 9784.7 17601.
n " llq. 934.50 10142.8 18245. 892.42 9686.1 17424.
Ethylbenzene . . . . C8H10
gas 1101.13 10372.4 18658. 1048.53 9876.9 17767.
It
" llq. 1091.03 10277.2 18487. 1038.43 9781.7 17596.
n-Propylbenzene. gas 1258.24 10469.1 18832. 1195.12 9943.9 17887.

C9H12
It
llq. 1247.19 10377.2 18667. 1184.07 9852.0 17722.
n-Butylbenzene . gas 1415.44 10546.3 18971. 1341.80
C10H14 9997.6 17984.
" . " llq. 1403.46 10457.0 18810. 1329.82 9908.4 17823.
n-Amylbenzene. C11H16 gas 1572.88 10610.5 19086. 1488.72 10042.8 18065.

" . " llq.
n-Hexylbenzene . gas 1730.33 10663.7 19182. 1635.65 10080.2 18132.

C12H18
" ... " llq.
n-Heptylbenzene. gas 1887.77 10708.3 19262. 1782.58

C13H20 10111.6 18189.
" ... " llq.
n-Octylbenzene . gas 2045.21 10746.4 19331. 1929.50 10138.4 18237.

C14H22
n
llq.
n-Nonylbenzene . c15h24 gas 2202.66 10779.3 19390. 2076.43 10161.5 18279.

11
llq.
n-Decylbenzene . c16h26 gas 2360.10 10807.9 19441. 2223.35 10181.7 18315.

n
" llq.
n-Undecylbenzene . gas 2517.54 10833.1 19487. 2370.27

C17H28 10199.4 18347.
" ... " llq.
n-Dodecylbenzene . gas 2674.98 10855.4 19527. 2517.19 10215.0
C18H3G 18375.
" .T t llq.
n-Trldecylbenzene. gas 2832.43 10875.3 19563. 2664.12 10229.1

C19H32 18400.
" . . " llq.
n-Tetradecylbenzene. gas 2989.87 10893.2 19595. 2811.04 10241.6 18423.

C20H34
" llq.
n-Pentadecylbenzene. gas 3147.31 10909.3 19624. 2957.96

C21H36 10253.0 18443.
. llq.
n-Hexadecylbenzene . c22h38 gas 3304.76 10924.0 19650. 3104.89 10263.3 18462.

n
" llq.
llq. r liquid b
See footnote c of Table In
TABLE 22n - NORMAL ALKYL CYCLOPENTANES , C5 to C2i
March 31, 1946
at 25°C and constant pressure, to formb;
Compound Formula State

H2O (llq.) and COg (gas) HgO (gas) and COg (gas)
Cyclopentane . gas 793.39 11313.1 20350. 740.79 10563.1 19001.

C5H10
• *B 786.54 11215.5 20175. 733.94 10465.4 18825.
llq.
Methylcyclopentane . gas 948.72 11273.4 20279. 885.60 10523.3 18930.

C6H12
a a 941.14 11183.3 20117. 878.02 10433.2 18768.
llq.
Ethylcyclopentane. gas 1106.21 11266.9 20267. 1032.57 10516.9 18918.

C7H14
. If 1097.50 11178.2 20108. 1023.86 10428.2 18758.
" llq.
n-Propylcyclopentane . gas 1263.56 11260.9 20256. 1179.40 10510.8 18907.

C8h16
ff " llq. 1253.74 11173.4 20099. 1169.58 10423.3 18750.
n-Butylcyclopentane. gas 1421.10 11257.7 20250. 1326.42 10507.6 18901.

C9h18
■ II llq. 1410.10 11170.5 20094. 1315.42 10420.5 18745.
n-Pentylcyclopentane . gas 1578.54 11254.4 20245. 1473.34 10504.4 18895.

C 1(^20
a a
llq.
n-Hexylcyclopentane. gas 1735.99 11251.8 20240. 1620.28 10501.8 18891.

C11H22
S m
llq.
n-Heptylcyclopentane . gas 1893.43 11249.5 20236. 1767.20 10499.6 18887.

c12h24
B a llq.
n-Octylcyclopentane. gas 2050.87 11247.6 20232. 1914.12 10497.6 18883.

C13H26
a a llq.
n-Nonylcyclopentane. gas 2208.32 11246.0 20230. 2061.05 10496.1 18880.

C14H28
» a
r—1
O'
n-Decylcyclopentane. gas 2365.76 11244.6 20227. 2207.97 10494.6 18878.

C15H30
a Si
llq.
n-Undecylcyclopentane. gas 2523.20 11243.4 20225. 2354.89 10493.4 18876.

c16h32
a a
llq.
n-Dodecylcyclopentane. gas 2680.65 11242.4 20223. 2501.82 10492.4 18874.

C17H34
a a
• • • • llq.
n-Tridecylcyclopentane . . . . gas 2838.09 11241.4 20221. 2648.74 10491.4 18872.

C18H36
a a llq.
n-Tetradecylcyclopentane . . . gas 2995.53 11240.5 20220. 2795.66 10490.5 18870.

C19H38
a a
llq.
n-Pentadecylcyclopentane . . . gas 3152.97 11239.7 20218. 2942.58 10489.7 18869.

c20h40
a a
llq.
n-Hexadecylcyclopentane. . . . gas 3310.42 11239.1 20217. 3089.51 10489.1 18868.

C21H42
a a
llq. V
llq. - liquid t> See footnote c of Table In

National Bureau of Standards Washington D C.
TABLE 23n - NORMAL ALKYL CYCLOHEXANES, C6 t0 c22
March 31, 1946
Compound Formula State3-

H20 (llq.) and C02 (gas) Hg0 (gas) and COg (gas)
Cyclohexane. gas 944.79 11226.7 20195. 881.67 10476.7 18846.

c6h12
m a
llq. 936.88 11132.7 20026. 873.76 10382.7 18676.
Methylcyclohexane. c7h14 gas 1099.59 11199.5 20146. 1025.95 10449.5 18797.
• If
11113.3 19991. 18642.
llq. 1091.13 1017.49 10363.3
Ethylcyclohexane . c8h16 gas 1257.90 11210.4 20166. 1173.74 10460.4 18816.

N If
llq. 1248.23 11124.3 20011. 1164.07 10374.3 18661.
n-Propylcyclohexane. gas 1415.12 11210.3 20165. 1320.44 10460.3 18816.

îs
it if
llq. 1404.34 11124.9 20012. 1309.66 10374.9 18663.
n-Butylcyclohexane . gas 1572.74 11213.0 20170. 1467.54 10463.0 18821.

C 10%)
If n
llq. 1560.78 11127.8 20017. 1455.58 10377.8 18668.
n-Pentylcyclohexane. gas 1730.18 11214.1 20172. 1614.47 10464.1 18823.

C11h22
S n
llq.
n-Hexylcyclohexane ...... gas 1887.63 11215.1 20174. 1761.40 10465.1 18825.

C12H24
a If
llq.
n-Heptylcyclohexane. gas 2045.07 11215.8 20175. 1908.32 10465.8 18826.

C13H26
a It
llq.
n-Octylcyclohexane . gas 2202.51 11216.5 20176. 2055.24 10466.5 18827.

C14H28
■ n
llq.
n-Nonylcyclohexane . Cl^TO gas 2359.96 11217.1 20178. 2202.17 10467.1 18828.
If
" llq.
n-Decylcyclohexane . gas 2517.40 11217.6 20178. 2349.09 10467.6 18829.

C16H32
a If
llq.
n-Undecylcyclohexane . gas 2674.84 11218.0 20179. 2496.01 10468.0 18830.

C17H34
n If
llq.
n-Dodecylcyclohexane . gas 2832.28 11218.4 20180. 2642.93 10468.4 18831.

C18H36
■ If
llq.
n-Trldecylcyclohexane. gas 2989.73 11218.8 20181. 2789.86 10468.8 18831.

C19h38
• S
llq.
n-Tetradecylcyclohexane. . . . gas 3147.17 11219.1 20181. 2936.78 10469.1 18832.

C20H48
■ If
llq.
n-Pentadecylcyclohexane. . . . gas 3304.61 11219.3 20182. 3083.70 10469.3 18832.

C21h42
It If
llq.
n-Hexadecylcyclohexane . . . . gas 3462.06 11219.6 20182. 3230.63 10469.6 18833.

c22h44
« It
llq.
llq. s liquid b See footnote c of Table In

TABLE 24n - NORMAL MONOOLEFINS (1-ALKENES), C2 to C2Q
December 31, 1945
at 25°C and constant pressure, to form13:

H20 (llq.) and C02 (gas) HgO (gas) and COg (gas)
kca1/mole cal/g BTU/lb kcal/mole cal/g BTU/lb
Bthene (Ethylene). c2h4 gas 337.234 12021.7 21625. 316.195 11271.7 20276.
" . 11 llq.
Propene (Propylene) . c3h6 gas 491.987 11692.3 21032. 460.428 10942.3 19683.
" . " llq.
1-Butene . C4H8 gas 649.757 11581.3 20833. 607.679 10831.3 19484.
" . " llq.
1-Pentene. gas 806.85 11505.1 20696. 754.25 10755.1 19346.

C5H10
" . " llq.
1-Hexene . gas 964.26 11458.0 20611. 901.14 10708.0 19262.

C6H12
" . " llq.
1-Heptene. gas 1121.69 11424.6 20551. 1048.05 10674.6 19202.

C7H14
" . " llq.
1-Octene . gas 1279.13 11399.6 20506. 1194.97 10649.6 19157.

C8H16
" . " llq.
1-Nonene . c9h1B gas 1436.58 11380.3 20471. 1341.90 10630.3 19122.
" . " llq.
1-Decene . c10h20 gas 1594.02 11364.8 20443. 1488.82 10614.7 19094.
" . " llq.
1-Undecene . gas 1751.46 11352.0 20420. 1635.75 10602.1 19071.

C11H22
" . " llq.
1-Dodecene . . . . gas 1908.91 11341.5 20401. 1782.68 10591.5 19052.

C12H24
" . . * . . . . llq.
1-Trldecene. . .. gas 2066.35 11332.5 20385. 1929.60 10582.5 19036.

C13H26
" . " llq.
i-Tetradecene. gas 2223.79 11324.8 20371. 2076.52 10574.9 18022.

C14H28
" . " llq.
]-Feritaaecene. gas 2381.23 11318.2 20359. 2223.44 10568.2 19010.

C15H30
" . " llq.
1-Kexaaocene . gas 2538.68 11312.4 20349. 2370.37 10562.4 19000.

C16H32
" . " llq.
l-H'-i.tadecene. gas 2696.13 11307.3 20340. 2517.30 10557.3 18991.

C17H34
M . 1 llq.
1-Cctadecene . gas 2853.57 11302.7 20332. 2664.22 10552.7 18882.

C18H36
" _ . " llq.
l-Nontdeoene. gas 3011.01 11298.6 20324. 2811.14 10548.6 18975.

c1Sh38
" . " llq.
gas 3168.45 11294.9 20318. 2958.06 10544.9 16968.

C20H40
" llq.
c llq. = liquid. b See footnote c of Table In.

TABLE 25n - NORMAL ACETYLENES (1-ALKYNES), C2 to C2o
March 31, 1946

H20 (llq.) and COg (gas) H20 (gas) and C02 (gas)
Ethyne (Acetylene) . CgHg gas 310.615 11930.2 21460. 300.096 11526.2 20734.
" . " llq.
Propyne (Methylacetylene). . . C3H4 gas 463.109 11559.8 20794. 442.070 11034.6 19849.
" ... " llq.
1-Butyne (Ethylacetylene). . . c4h6 gas 620.86 11478.7 20648. 589.30 10895.2 19599.
" ... " llq.
1-Pentyne. gas 778.03 11422.5 20547. 735.95 10804.7 19436.

C5H8
" . " llq.
1-Hexyne . C6H10 gas 935.45 11388.5 20486. 882.85 10748.1 19334.
" . " llq.
1-Heptyne. C7H12 gas 1092.89 11364.6 20443. 1029.77 10708.2 19262.
■ . " llq.
1-Octyne . gas 1250.34 11346.9 20411. 1176.70 10678.6 19209.

C8H14
" . " llq.
1-Nonyne . c9Hi6 gas 1407.78 11333.1 20386. 1323.62 10655.6 19168.
" . " llq.
1-Decyne . gas 1565.22 11322.2 20366. 1470.54 10637.3 19134.

C10H18
" . " llq.
1-Undecyne . gas 1722.67 11313.3 20350. 1617.48 10622.4 19108.

C11H20
" . " llq.
1-Dodecyne . gas 1880.11 11305.8 20337, 1764.40 10610.0 19086.

C12H22
" . " llq.
1-Trldecyne. gas 2037.55 11299.5 20326. 1911.32 10599.5 19066.

C13H24
" . " llq.
1-Tetradecyne. gas 2194.99 11294.1 20316. 2058.24 10590.5 19050.

C14H26
" . " llq.
1-Pentadecyne. gas 2352.44 11289.5 20308. 2205.17 10582.8 19036.

c15h28
" " llq.
1-Hexadecyne . gas 2509.88 11285.4 20300. 2352.09 10575.9 19024.

C16h30
" . llq.
1-Heptadecyne. gas 2667.32 11281.8 20294. 2499.01 10570.0 19013.

C17H32
" . " llq.
1-Octadecyne . gas 2824.77 11278.7 20288. 2645.94 10564.7 19004.

C18H34
" . " llq.
1-Nonadecyne . gas 2982.21 11275.8 20283. 2792.86 10559.9 18995.

C19H36
" ... " llq.
1-Elcosyne . gas 3139.55 11273.3 20279. 2939.78 10555.6 18988.

C20H38
" n
llq.
llq. = liquid b See footnote c of Table In

TABLE Op - 02, Hg, HgO, Ng, C, CO, COg
HEAT OF FORMATION, ENTROPY, AND FREE ENERGY OF FORMATION, AT 25°C a
April 30, 1945
Heat of Free Energy of
Formation c Entropy*3 Formation c
Compound Formula Stateb aHf° S° AFf°
At 25°C At 25°C At 25°C
kcal/mole cal/deg mole kcal/mole
Oxygen . gas 0 49.003 0

°2
Hydrogen . gas 0 31.211 0

H2
Water. h2o gas -57.7979 45.106 -54.6351

* If
llq. -68.3174 16.716 -56.6899
Nitrogen . gas 0 45.767 0

N2
Carbon .. C solid, 0 1.3609 0

graphite
Carbon monoxide. CO gas -26.4157 47.300 ^ -32.8077
Carbon dioxide . gas -94.0518 51.061 -94.2598

C02
a The values In this table are given to more significant figures than are warranted by the ab¬
solute accuracy of the Individual values. In order to retain the significance of certain
differences.
b llq. = liquid.
c 4Hf° and AFf° represent the Increments In heat content and free energy, respectively, for
the reaction of forming the given compound from the elements, with all the reactants and
products In their appropriate standard reference states.
d g° represents the entropy (exclusive of nuclear spin) of the given compound in Its appro¬
priate standard reference state.

TABLE lp - PARAFFINS, C TO C5
April 30, 1944; April 30, 1945

—--—--- —

Entropy”1
Formation0 Formation0
S°
AHf° AFf°

At 25°C At 25°C At 25°C
kcal/mo le cal/deg mole kcal/mo le
Methane. ch4 gas -17.839 44.50 -12.140
Ethane . gas -20.236 54.85 -7.86C

C2H6
Propane. gas -24.820 64.51 -5.614

°3H8
11 It
llq.e -28.643
n-Butane . C H gas -29.812 74.10 -3.754

4 10
II
liq.e -34.950
11
2-MethyIpropane (Isobutane). gas -31.452 70.42 -4.296
liq.e -36.169
n-Pentane. gas -35.00 83.27 -1.96

. C5H12
11 11
liq. -41.36 62.79 -2.21
2-Methylbutane (Isopentane). " gas -36.92 81.98 -3.50

" . It
liq. -42.85 62.38 -3.59
11
2,2-Dlmethylpropane (Neopentane) .... gas -39.67 73.23 -3.64
It n
liq.e -44.98
The values in this table are given to more significant figures than are warranted by the absolute accu¬
racy of the individual values in order to retain the significance of the small differences between the
liquid and gaseous states and, to a lesser extent, between Isomers.
b liq. = liquid.
c AHf° and AFf° represent the increments in heat content and free energy, respectively, for the reaction of
forming the given hydrocarbon in the state indicated from the elements carbon (crystalline graphite) and
hydrogen (gaseous), with all the reactants and products in their appropriate standard reference states,
unless otherwise indicated.
^ S° represents the entropy (exclusive of nuclear spin) of the given hydrocarbon in its appropriate standard
reference state.
e At saturation pressure.
National Bureau of Standards_' _ Washington, D. C.
TABLF. 2p - PARAFFINS, CQ AND C?

April 30, 1944; April 30, 1945; November 30, 1946

Entropy11
AHf° S°
AFf°
Compound Formula State*3
At 25°C At 25°C At 25°C
kca1/mole cal/deg mole kcal/mole
n-Hexane . C6H14 gas -39.96 92.45 +0.05

" . " liq. -47.52 70.34e -0.91
2-Methylpentane. .... . " gas -41.66 90.65 -1.11
" . liq. -48.82 69.21 -1.88
3-Methylpentane. gas -41.02 90.77 -0.51
" . " liq. -48.28 69.22 -1.34
2,2-Dimethylbutane . " gas -44.35 85.72 -2.33
" . II liq. 65.18

-51.00 -2.86
2,3-Dlmethylbutane . " gas -42.49 87.33 -0.95
" . " liq. -49.48 66.27 -1.66
n-Heptane. gas -44.89 101.64 +2.09

C7H16
" .. " liq. -53.63 77.92 +0.42
2-Methylhexane . gas -46.60 99.64 +0.98
" . " liq. -54.93 76.58 -0.47
3-Methylhexane . . . " gas -45.96 101.37 +1.10
" . " liq. -54.35 78.23 -0.39
3-Ethylpentane . n gas -45.34 98.47 +2.59
" . " liq. -53.77 75.33 +1.06
2,2-Dlmethylpentane. " gas -49.29 93.60 +0.09
" ........... " liq. -57.05 71.50 -1.08
2,3-Dlmethy lpentane.. " gas -47.62 98.96 +0.16
" .. . . " liq. -55.81 76.27 -1.27
2,4-Dlmethylpentane.‘. . . " gas -48.30 94.80 +0.72
" . " liq. -56.17 72.47 -0.49
3,3-Dimethylpentane. n gas -48.17 95.53 +0.63
" . " liq. -56.07 73.44 -0.69
2,2,3-Trlmethylbutane. " gas -48.96 92.46 +0.76
" . ii
liq. -56.63 70.73 -0.43
a See footnote a of Table lp. ^ liq. r liquid. 0 See footnote c of Table lp.
d See footnote d of Table lp.

e A more accurate value for the entropy of n-hexane (liquid) at 25°C, namely, 70.76 +0.14 cal/deg mole, has
Recently become available (Douslln and Huffman'*’). However, the value 70.34 cal/deg mole is retained in
order to preserve, in the framework of the tables, the consistency of the Increment per CHg group, and its
temperature coefficient, for the entropy and related thermodynamic properties. It is planned to make the
change when more accurate data become available on the normal paraffins above hexane.
ÊLECTED VALUES OF PROPERTIES OF HYDROCARBONS 159
TABLE 3p - PARAFFINS, Cg
HEAT OF FORMATION, ENTROPY, AND FREE ENERGY OF FORMATION AT 25°C a

.
April 30, 1944; April 30, 1945

Entropy11
aHf° S° aFf°

At 25°C At 25°C At 25°C
kca1/mole cal/deg mole kcal/mole
n-Octane. gas -49. 82 110.82 4.14

C8H18
". " llq. -59. 74 85.50 1.77
2-Methylheptane . " gas -51. 50 108.81 3.06
B . llq. -60. 98 84.16 0.92
3-Methylheptane . gas -50. 82 110.32 3.29
" . " llq. -60. 34 85.66 1.12
4-Methylheptane . gas -50. 69 108.35 4.00
" . llq. -60. 17 83.72 1.86
3-Ethylhexane . gas -50 40 109.51 3.95
" . " llq. -59 88 84.95 1.80
2,2-Dlmetbylhexane. " gas -53 71 103.06 2.56

It
" llq. -62 63 79.33 0.72
2,3-Dlmethylhexane. " gas -51 13 106.11 4.23
" . " llq. -60. 40 81.92 2.17
2,4-Dlmethylhexane. " gas -52 44 106.51 2.80
" . " llq. -61 47 82.82 0.89
2,5-Dimethylhexane. " gas -53 21 104.93 2.50

" . " llq. -62 26 80.96 0.59
3,3-Dimethylhexane. " gas -52 61 104.70 3.17
" . llq. -61 58 81.12 1.23

3,4-Dlmethylhexane. gas -50 91 104.38 4.97
" . llq. -60 23 80.20 2.86
2-Methyl-3-ethylpentane . " gas -50 48 105.43 5.08
" . " llq. -59 69 81.41 3.03
3-Methyl-3-ethylpentane . " gas -51 38 103.48 4.76
" . " llq. -60 46 79.97 2.69
2,2,3-Tr lmet bylpentane. " gas -52 61 101.62 4.09

" . n llq. -61 44 78.30 2.22
2,2,4-Trlmethylpentane. gas -53 .57 101.62 3.13

" . llq. -61 .97 78.87 1.51

" . llq. 79.93 2.54
-60 .63
" . ■ llq. -60 .98 79.39 2.34
2,2,3,3-Tetramethylbutane . " gas -53 .99 94.34 4.88

" . ° solid -64 .23 67.17 2.74
h p
See footnote a of Table lp. llq = liquid; solid = crystalline solid. See footnote o of Table lp.
See footnote d of Table lp.

National Bureau oi Standards Washington, D. C.
TABLE 5p - ALKYL BENZENES, C6 To Cg
HEAT OF FORMATION, ENTROPY, AND FREE ENERGY OF FORMATION, AT 25°Ca
November 30, 1945

Entropy*3
S°
AHf° AFf°

At 25°C At 25°C At 25°C
Benzene. gas 19.820 64.34 30.989

C6H6
n 41.30 29.756
" . liq. 11.718
Methylbenzene (Toluene). c7h8 gas 11.950 76.42 29.228
" . n liq. 2.867 52.48 27.282
Ethylbenzene . gas 7.120 86.15 31.208

C8H10
N H
liq. -2.977 60.99 28.614
1,2-Dimethylbenzene (o-Xylene) . " gas 4.540 84.31 29.177

" . " liq. -5.841 58.91 26.370
1,3-Dimethylbenzene (m-Xylene). " gas 4.120 85.49 28.405

•
" liq. -6.075 60.27 25.730
n
1,4-Dlmethylbenzene (p-Xylene) . gas 4.290 84.23 28.952
" " liq. -5.838 59.12 26.310
n-Propylbenzene. gas 1.870 95.74 32.810

C9H12
" . " liq. -9.178 69.44 29.600
Isopropylbenzene (Cumene). " gas 0.940 92.87 32.738
" •. " liq. -9.848 66.87 29.708
1-Methyl-2-ethylbenzene. ■ " gas 0.290 95.42 31.323

tl
" liq. -11.110 68.42 27.973
H
1-Methyl-3-ethylbenzene. gas -0.460 96.60 30.217
n
" liq. -11.670 69.90 26.977
l-Methvl-4-ethylbenzene. " gas -0.780 95.34 30.281
" . " liq. -11.920 68.84 27.041

11
1,2,3-Trlmethylbenzene (Hemlmellltene) . gas -2.290 93.50 29.319
n
" liq. -14.013 66.40 25.679
1,2,4-Trimethylbenzene (Pseudocumene). . " gas -3.330 94.73 27.912
" . . " liq. -14.785 67.93 24.462
1,3,5-Trlmethylbenzene (Mesitylene). . . " gas -3.840 92.15 28.172

It
" ... liq. -15.184 65.35 24.832
a See footnote a of Table lp. b liq. = liquid. c See footnote c of Table lp.

TABLE 8p (Part 1) - MONOOLEFINS, C2 to C5
HEAT OF FORMATION, ENTROPY, AND FREE ENERGY OF FORMATION, AT 25°C

November 30, 1945; May 31, 1S47

Entropy11
S°
AHf° AFf°
At 25°C At 25°C At 25°C
Ethene (Ethylene). c2h4 gas 12.496 52.45 16.282

" . " llq.
Propene (Propylene). gas 4.879 63.80 14.990

C3H6
H . U
llq.
l'-Butene. C4H8 gas 0.280 73.48 17.217

" . " llq. *
n -1.362 71.90
cis-2-Butene . gas 16.046
n n
llq.
trans-2-Butene . n gas -2.405 70.86 15.315

n n
llq.
2-Methyl-2-propene (Isobutene) . n gas -3.343 70.17 14.582

n n
llq.
l-Pentene. c5hio gas -5.000 83.08 18.787

" . n
llq.
cis-2-Pentene. n -6.710 82.76 17.173

gas
n n
llq.
trans-2-Pentene. it gas -7.590 81.81 16.575

n it llq.
2-Methyl-l-butene. n gas -8.680 81.73 15.509

" . it llq.
it -6.920 79.70 17.874
3-Methyl-l-butene. gas
" . n
llq.
it 80.90 14.267
2-Methyl-2-butene. gas -10.170
n ti
llq.
a See footnote a of Table lp. b llq. = liquid. c See footnote c of Table lp.

TABLE 8p (Part 2) - MONOOLEFINS, C6
HEAT OF FORMATION, ENTROPY, AND FREE ENERGY OF FORMATION, AT 25°C
November 30, 1945

Entropyd
S°
aHf° AFf°
At 25°C At 25°C At 25°C
1-Hexene . gas -9.96 92.25 20.80

C6H12
" . » llq.
cls-2-Hexene . gas -11.56 92.35 19.18
" .. " llq.
trans-2-Hexene. " gas -12.56 91.40 18.46
" . " llq.
cls-3-Hexene . " gas -11.56 90.73 19.66
" . " llq.
trans-3-Hexene.. gas -12.55 90.04 18.86
" . " llq.
2-Methyl-l-pqntene . . -. gas -13.56 91.32 17.48
" . " llq.
3-Methvl-l-pentene . n gas -11.02 90.45 20.28
" . " llq.
4-Meth.yl-l-pentene. " gas -11 .65 89.58 19.90
" . llq.
2-ilethyl-2-pentene. " gas -14.96 90.45 16.34
" . " llq.
els (?)-3-i-lethyl-2-pentene. " gas -14.32 90.45 16.93
" . " llq.
trans (?)-3-Methyl-2-oentene .;.... " gas -14.32 91.26 16.74
" . " llq.
els (?)-4-Hethyl-2-pentene . " gas -13 .26 89.23 18.40
" . llq.
trans(?)-4-Methvl-2-pentene. " &s -14.26 88.02 17.77
" . " Ho.
2-Ethvl-l-butene . " gas -12.92 90.01 18.51
" . " llq.
2,3-Dlmethyl-l-butene. " gas -14.78 87.39 17.43
" . " llq.
3,3-Dlmethyl-l-butene. " gas -14.25 83.79 19.04
" . " llq.
2,3-D lmethy 1-2-butene. " gas -15.91 86.57 16.52
" . " llq.
a See footnote a of Table lp. b llq. = lleuld. c See footnote c of Table lp.
^ See footnote d of Table lp.

National Bureau of Standards Washington, D. C
TABLE 12p - ACETYLENES, Cg to C5
HEAT OE FORMATION, ENTROPY, AND FREE ENERGY OF FORMATION, AT 25°Ca
June 30, 1946

Entropyd
S°
AHf° ^Ff 0
At 25°C At 25°C At 25°C
Ethyne (Acetylene). gas 54.194 47.997 50.000

C2H2
II liq.
Propyne (Methylacetylene) . gas 44.319 59.30 46.313

C3H4
" . " liq.
1-Butyne (Ethylacetylene) . C H gas 39.70 69.51 48.52

4 6
" . t! liq.
2-Butyne (Dlmethylacetylene). II gas 35.374 67.71 44.725

n n liq.-
l-Pentyne . gas 34..50 79.10 50.17

C5H8
n n liq.
2-Pentyne . n gas 30.80 79.30 46.41

•1 n liq.
3-Methyl-1-butyne. n gas 32.60 76.23 49.12

a fi liq.
a See footnote a of Table lp. b llq.=llquld c See footnote c of Table lp. d See footnote d of Table lp.
745211 0-47-12
American Petroleum Institute Reseerah Project 44
Nations! Bureau of Standards • Washington, D. C.
TABLE 20p - NORMAL PARAFFINS, to
HEAT OF FORMATION, ENTROPY, AND FREE ENEROY OF FORMATION, AT 25°Ca
June 30, 1946

Entropy3
S°
eHf° AFf 0
Compound Formula 3tateb
At 25°C At 25°C At 25°C
Methane . gas -17.889 44.50 -12.140

CH4
" . " llq.
Ethane. gas -20.236 54.85 -7.860

C2H6
". * iia-
Propane . . , . c3H8 gas -24.820 64.51 -5.614

n b llq.
n-Butane. C4H10 gas -29.812 74.10 -3.754

n • llq.
n-Pentane . C5H12 gas -35.00 83.27 -1.96
" . N llq.
n-Hexane. ceHi4 gas -39.96 92.45 ♦0.05

n 11 llq.
n-Heptane . C7H16 gas -44.89 101.64 2.09
" . " llq.
n-Octane. c8H18 gas -49.82 110.82 4.14
" .. s llq.
n-Nonane. c9h20 gas -54.74 120.00 6.18

1) llq.
"
n-Decane. c10H22 gas -59.67 129.19 8.23
" . n llq.
n-Undecane. c11h24 gas -65.60 138.37 10.28
" . b llq.
n-Dodecane.. c12h26 gas -69.52 147.55 12.33
" . R llq.
n-Trldecane . C13H28 gas -74.45 156.74 14.37
" . " llq.
n-Tetradecane . c14H30 gas -79.38 165.92 16.42
" . R llq.
n-Pentadecane . cl#32 gas -84.31 175.10 18.47

■ " llq.
n-Hexadecane. . . . . .. gas -89.23 184.28 20.52
* . * .. * llq.
n-Heptadecane .. gas -94.15 193.47 22.56
" . " llq.
n-Octadecane. gas -99.08 202.65 24.61

C18H38
" . " solid
a-Nonadecane. gas -104.00 211.83 26.66
C19H40
* . " solid
n-Elcoeane. gas -108.93 221.02 28.71
C20H42
" . " solid
a See footnote a of Table lp. b llq.-liquid c See footnote c of Table lp. 3 See footnote d or Table lp.
TABLE 21p - NORMAL ALKYL BENZENES, C6 to Cgg
June 30, 1946

Entropyd
s°
*Hf° aFf°
At 25°C At 25°C At 25°C
Benzene . gas 19.820 64.34 30.989

C6«6
II «
liq.
Methyl benzene (Toluene). gas 11.950 76.42 29.228

C7«8
" . R
liq.
Ethylbenzene. gas 7.120 86.15 31.208

C8H10
n fl liq.
n-Propylbenzene . gas 1.870 95.74 32.810

C9K12
" . n
liq.
n-Butylbenzene. c10h14 gas -3.30 104.91 34.62

II
" liq.
n-Amylbenzene . gas -8.23 114.09 36.67

C11H16
n " liq.
n-Hexylbenzene. gas -13.15 123.28 38.72

°i2Hi8
" . n
liq.
n-Heptylbenzene . gas -18.08 132.46 40.76

^ô
" . n liq.
n-Oc tylbenzene. C14h22 gas -23.00 141.64 42.81
* . n
liq.
n-Nonylbenzene. gas -27.93 150.82 44.86

C15H24
n • liq.
n-Decylbenzene. gas -32.86 160.01 46.91

C16H26
" . n liq.
n-Undecylbenzene. gas -37.78 169.19 48.96

C17H28
It n liq.
n-Dodecylbenzene. gas 42.71 178.37 51.00

c18h30
n ■y liq.
n-Trldecylbenzene . gas -47.63 187.56 53.05

C19H32
11 R liq.
n-Tetradecylbenzene . gas -52.56 196.74 55.10

C20H34
" . n liq.
n-Pentadecylbenzene . gas -57.49 205.92 57.15

C21H36
« fl liq.
n-Hexadeoylbenzene. gas -62.41 215.11 59.20

C22H38
n fl liq.
a See footnote a of Table lp. b liq.=llquld c See footnote c of Table lp. d See footnote d of Table lp.
TABLE 24p - NORMAL MONOOLEFINS (1-ALKENES),Cg to C2Q
June 30, 1946

c Entropyd
Formation Formation0
S°
AHf° aFf°
Compound Formula State*5
At 25°C At 25°C At 25°C
Ethene (Ethylene) . c2h4 gas 12.496 52.45 16.282
* . " llq.
Propene (Propylene) . gas 4.879 63.80 14.990

C3H6
n " llq.
1-Butene. c4Ha gas 0.280 73.48 17.217
" . " llq.
1-Pentene. gas -S.000 83.08 18.787

C5H10
" . " llq.
1-Hexene. gas -9.96 92.25 20.80

C6H12
" . " llq.
1-Heptene . gas -14.89 101.43 22.84

C7H14
" . llq.
1-Octene. gas -19.82 110.61 24.89

C8H16
H
■ . llq.
1-Nonene. gas -24.74 119.80 26.94

C9H18
" . " llq.
1-Decene. gas -29.67 128.98 28.99

C10H20
n llq.
"
l-Undecene. gas -34.60 138.16 31.03

C11H22
m " llq.
l-Dodecene. gas -39.52 147.34 33.08

C12H24
" . " llq.
1 Trldecene . gas -44.45 156.53 35.13

C13H26
" . " llq.
1-Tetradecene . gas -49.38 165.71 37.18

°14H28
" . " llq.
1-Pentadecene . gas -54.31 174.89 39.23

C15H30
n »l llq.
l-Hexadecene. gas -59.23 184.08 41.27

C16H32
" . " llq.
1-Heptadecene . gas -64.15 193.26 43.32

C17H34
" . " llq.
1-Octadecene. gas -69.08 202.44 45.37

C18H36
" . " llq.
1-Nonadecene. gas -74.00 211.63 47.42

C19H38
- . " llq.
1-Elcosene. gas -78.93 220.81 49.47

C20H40
" . solid
a See footnote a of Table lp. bllq.=llquld c See footnote c of Table lp. d See footnote d of Table lp.
TABLE 25p - NORMAL ACETYLENES (1-ALKYNES), C2 to C20
June 30, 1946

Entropy11
Formatlonc Formatlonc
S°
aHf° aFf°
Compound Formula State15 Q 0
At 25 C At 25 C At 25 C
Ethyne (Acetylene). gas 54.194 47.997 50.000
« . " llq.
Propyne (Methylacetylene). c3h4 gas 44.319 59.30 46.313

■
■ . llq.
1-Butyne (Ethylacetylene) . gas 39.70 69.51 48.52

C4H6
* . llq.
1-Pentyne . gas 34.50 79.10 50.17

C5H8
■ " llq.
1-Hexyne. gas 29.55 88.27 52.19

C6H10
It
■ . llq.
1-Heptyne. gas 24.62 97.45 54.24

C7«12
■ . * llq.
1-Octyne. gas 19.7b 106.63 56.29

C8H14
• * llq.
1-Nonyne. gas 14.77 115.82 58.34

C9H16
• * llq.
1-Decyne. C10H18 gas 9.85 125.00 60.39
■ . " llq.
1-Undecyne. c11h20 gas 4.92 134.13 62.43
■ . ■ llq.
1-Dodecyne. c12h22 gas -0.01 143.36 64.48
* . * llq.
1-Trldecyne .
c13h24 gas -4. 93 152.55 66.53
* . * llq.
1-Tetradecyne . gas -9.86 161.73 68.58

C14H26
" . * llq.
1-Pentadecyne . gas -14.78 170.91 70.63
* . * llq.
1-Hexadecyne. gas -19.71 180.10 72.67

C16H30
* . * llq.
1-Heptadecyne . gas -24.64 189.28 74.72

C17H32
B . ■
llq.
l-Octadecyne. gas -29.56 198.46 76.77

C18H34
* . • solid
1-Nonadecyne. gas -34.49 207.65 78.82

C19H36
" . * solid
l-Elcosyne. gas -39.41 216.83 80.87

C20H38
* . " solid
be d
See footnote a of Table lp. llq.=llquld See footnote c of Table lp. See footnote d of lable lp.
Natiohal Bureau of Standards Washington. D. C.
TABLE lq - PARAFFINS, C, To C_.

1 o
STANDARD HEAT, ENTROPY, AND FREE ENERGY OF VAPORIZATION, AT 25°C
May 31, 1944
Standard Standard Standard

Heat of Entropy of Free Energy of
Vaporization3, Vaporization3 Vaporization3
Compound Formula aHv° aSv° aFv°
At 25°C At 25°C At 25°C
Methane. - - -
CH4
Ethane . C2H6
Propane. 3.823 b
C3H8
n-Butane . 5.138b
C4H10
2-Methylpropane (Isobutane). II 4.717b
n-Pentane. C5H12 6.357 20.48 0.252

2-Methylbutane (Isopentane). " 5.934 19.60 0.090
2,2-Dlmethylpropane (Neopentane). " 5.311b
a aHv°, aSv°, and aFv° represent the increments in heat content, entropy, and free energy, respectively, for
the process (liq.)= CmHn (gas), with the liquid and gas in their appropriate standard reference states,
unless otherwise indicated. For the heat of vaporization at saturation pressure see Table lm.
b Liquid at saturation pressure.

TABLE 2q - PARAFFINS, Cg AND

May 31, 1944

Vaporization3 Vaporizatlona Vaporization3
aHv° ASV° aFv°
Compound Formula
At 25°C At 25°C At 25°C
n-Hexane . 7.555 22.11 0.963

C6«14
It
2-Me thylpentane. 7.160 21.44 0.767
3- " . n 7.255 21.55 0.830

it
2,2-Dlmethylbutane . 6.651 20.54 0.527
2,3- " . n 6.985 21.06 0.706
n-Heptane. 8.739 23.72 1.666

C7H16
ft
2-Methylhexane . 8.325 23.06 1.448
tl
3- " . 8.391 23.14 1.491
ft
3-Ethyl pentane. 8.425 23.14 1.525
It
2,2-Dimethylpentane. 7.764 22.10 1.174
2,3- " . * 8.191 22.69 1.426
2,4- " . n 7.872 22.33 1.214

it
3,3- " . 7.901 22.09 1.316
tt
2,2,3-Trime thylbutane. 7.669 21.73 1.190
3 See footnote a of Table lq. For the heat of vaporization at saturation pressure see Table 2m.
TABLE 3q - PARAF’FINS, CQ
Nay 31, 1944

Vaporization Vaporization3 Vaporization3
_ 0 _ 0
aHv° aSv aFv
Compound Formula
At 25°C At 25°C At 25°C
n-Octane . 9.915 25.32 2.365

C8h18
It
2-Methylheptane. 9.484 24.65 2.135
3- " . II
9.521 24.66 2.167
4- " . II
9.483 24.63 2.138
II
3-Ethylhexane. 9.476 24.56 2.152
2,2-Dlmethylhexane . II
8.915 23.73 1.839
2,3- " II
9.272 24.19 2.060
2,4- " ... " 9.029 23.89 1.907
2,5- " . It
9.051 23.97 1.905
3,3- " " 8.973 23.58 1.942
3,4- " . " 9.316 24.18 2.107
2-Nethyl-3-ethylpentane. " 9.209 24.02 2.048
3- " -3- " It
9.081 23.51 2.071
2,2,3-Trlmethylpentane . 11
8.826 23.32 1.874
2,2,4- " . It
8.402 22.75 1.620
2,3,3- " . II
8.897 23.21 1.976
2,3,4- " . " 9.014 23.60 1.976
2,2,3,3-Tetramethylbutane. " 10.24b 27.17b 2.139b
a See footnote a of Table lq. For the heat of vaporization at saturation pressure see Table 3m.
b For the process of sublimation, CmHn (solid) = (gas), with the solid and gas in their appropriate
standard reference states.

«
National Bureau of Standards Washinoton D. C.
TABLE 5q - ALKYL BENZENES, Cg to Cg

July 31, 1944; revised March 31, 1945
Vaporization3 Vaporization3 Vaporization3

Compound Formula
aHv° aSv° aFv°
. At 25°C At 25°C At 25°C
kcal/mole cal/deg mole kca1/mole
Benzene. 8.102 23.04 1.233

C6H6
Methylbenzene (Toluene). 9.083 23.94 1.946
C7H8
Ethylbenzene . 10.097 25.16 2.594
C8H10
1,2-Dimethylbenzene (o-Xylene) . If 25.40 2.807
10.381
1,3- " (m- " ). If 10.195 25.22 2.675

It 10.128 25.11 2.642
1,4- " (P- " ) .
n-Propylbenzene. 11.048 26.3 3.21

C9H12
II 10.788 26.0 3.03
Isopropylbenzene (Cumene).
l-Methyl-2-ethylbenzene. If 11.40 27.0 3.35
1- " -3- " . II 11.21 26.7 3.24

It 11.14 26.5 3.24
1- " -4- " .
1,2,3-Trimethylbenzene (Hemimellitene) . II 11.723 27.1 3.64
1,2,4- " (Pseudocumene). . II 11.455 26.8 3.45
1,3,5- " (Mesitylene). . . " 11.344 26.8 3.34
a See footnote a of Table lq. For the heat of vaporization at saturation pressure see Table 5m.
National Bureau of Standards 9 Washington, D. C.
TABLE 7q - ALKYL CYCLOHEXANES, Ce to CQ

o o
March 31, 1947

Vaporization3 Vaporization3 Vaporization3
aHv° £Sv° AFV°
Compound Formula
At 25°C At 25°C At 25°C
Cyclohexane .
C6H12 7.908 22.43 1.219
Methylcyclohexane . . . C7H14 8.458 22.80 1.659
Ethylcyclohexane. C8H16 9.674 24.32 2.423

n
1,1-Dimethylcyclohexane . 9.046 23.35 2.083
St
cls-1,2-Dimethylcyclohexane . . . 9.493 23.95 2.351
St
trans-1,2- " ... . 9.169 23.45 2.176
cis-l,3~b " . . 9.139 23.56 2.114
ts
tra'ns-l,3-c " . 9.370 23.93 2.235
SI
cis-1,4- " . 9.330 23.84 2.223
St
trans-1,4- " . 9.055 23.39 2.082
3 See footnote a of Table Iq. For the heat of vaporization at saturation pressure see Table 7m.
b Formerly labeled "trans"; see footnote d of Table 7a. c Formerly labeled "els"; see footnote e of Table 7a.
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305
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o co o CO CO CM CO ID CM 00 00 00
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347
See footnote a of Table lw. G See footnote b of Table lw. c See footnote c of Table lw,
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17.500 29.228 29.335 35.390 41.811 48.477 55.306 62.236 69.255 76.320 83.40 90.50 97.61 104.71 111.81
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11.096 29.177 29.329 37.883 46.852 56.103 65.548 75.110 84.777 94.494 104.23 113.99 123.76 133.50 143.24
10.926 28.405 28.554 37.008 45.906 55.099 64.492 74.006 83.630 93.307 103.00 112.72 122.45 132.15 141.85
11.064 28.952 29.104 37.688 46.724 56.060 65.604 75.275 85.058 94.897 104.76 114.64 124.54 134.40 144.27
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8.092 31.323 31.514 42.26 53.48 65.02 76.78 88.65 100.64 112.67 124.7 136.8 148.9 160.9 173.0
7.593 30.217 30.406 41.05 52.20 63.68 75.38 87.20 99.14 111.14 123.2 135.2 147.2 159.2 171.2
7.241 30.281 30.472 41.25 52.54 64.16 76.02 88.00 100.10 112.26 124.4 136.6 148.8 161.0 173.2
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163.03 175.51
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357
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359
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363
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375
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,
infinite -11.7618 -11.7677 -12.1469 -12.5576 -12.9169 -13.2274 -13.4923 -13.7200 -13.9126 -14.0749 -14.2166 -14.3389 -14.4417 -14.5321
=
Infinite -11.2255 -11.2362 -11.7896 -12.2824 -12.6874 -13.0268 -13.3081 -13.5498 -13.7526 -13.9226 -14.0688 -14.1938 -14.2979 -14.3901
=
Infinite -10.6888 -10.7038 -11.4244 -12.0112 -12.4763 HL2.8533 -13.1649 -13.4245 -13.6424 -13.8249 -13.9805 -14.1141 -14.2257 -14.3232
With regard to estimated uncertainties for the above compounds, see footnote c on Tables Rr, 8s, and Bt
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381
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ci
IV. SPECIFIC REFERENCES FOR TABLES OF PROPERTIES
SPECIFIC REFERENCES
FOR TABLES la, la-E, and lb
(Applicable as of the date of Issue of the numerical table)
May 31, 1947
REFERENCES FOR
Compound
Bolling Refractive Freezing Refractive
Polht Index Density
Point Dispersion
Methane . 12,13,15,16,17,
18,19
Ethane. 13,20,21
Propane . 2,8 23,26,27

27
n-Butane. 1,2,8 5,30,31
2-Methylpropane . 1,3,28,32,33, 1,2,8 28,31,36

34,35
n-Pentane . 6,9,34,37,38, 6,7,9,40,42, 2,6,7,8,9,44, 9,14,37,30,44, 7,9,46

39,40,41,42, 43,44,45,46, 45,46,48,50 46,47,49,55
43,44,45,46, 47,51,55
47
2-Methylbutane. 6,9,34,40,41, 6,7,9,40,42, 2,6,9,44,50 6,9,40,49,52, 7,9

42,44,52,53 44,51,55 53,54,55
2,2-Dlmethylpropane . 1,4 1 1,4,6,45
REFERENCES
1. Benollel1 28. Coffin and Maass1

2. Cragoe1 29. Coffin and Maass2
3. Cragoe2 30. Huffman, Parks, and Barmore1
4. Aston and Messerly1 31. Glasgow and Rossln'1
p
5. Aston and Messerly 32. Hiickel and Rossmann1
6. Howard, Mears, Fookson, Pomerantz, and Brooks1 33. Peters and Lohmar1
7. Garrett1 34. Lamb and Roper1
8. Natural Gasoline Association of America1 35. Aston, Kennedy, and Schumann1
9. Wlbaut, Hoog, Langedljk, Overhoff, Smlttenberg, 36. Parks, Shomate, Kennedy, and Crawford1
Bennlnga, Bouman, van Dijk, Gaade, Geldof, 37. Messerly and Kennedy1
Hackmann, Jonker, Paap, and Zulderweg1 38. Timmermans and Hennaut-Roland2
10. Frank and Cluslus1 39. Wojclechowskl1
11. Keyes, Taylor, and Smith1 40. Smlttenberg, Hoog, and Henkes1
12. Henning and Stock1 41. Willingham, Taylor, Plgnocco, and Rossini1
13. Cluslus and Welgand1 42. McArdle and Robertson1
14. Parks and Huffman1 43. Griswold, van Berg, and Kasch1
15. Parks and Huffman2 44. American Petroleum Institute Research Project 451
16. Cluslus1 45. Birch, Fldler, and Lowry1
17. Eucken and Karwot1 46. Sheperd, Henne, and Mldgley1
18. Wlebe and Brevoort1 47. Malr1
19. Freeth and Verschoyle1 48. Quayle, Day, and Brown1
2D. Witt and Kemp1 49. Glasgow, Murphy, Willingham, and Rossini1
21. Wlebe, Hubbard, and Brevoort1 50. Gelst and Cannon1
22. Loomis and Walters1 51. Wlbaut and Langedljk1
23. Hartlck and Edse1 52. Guthrie and Huffman1
24. Dana, Jenkins, Burdick, and Timm1 53..Schumann, Aston, and Sagenkahn1
25. Francis and Robbins1 54. Timmermans and Martin1
26. Hlcks-Bruun and Bruun1 55. Fcrzlatl, Glasgow, Willingham, and Rossini1
27. Kemp and Egan
SPECIFIC REFERENCES
FOR TABLES 2a (Part 1), 2a-E (Part 1), and 2b (Part 1)
May 31, 1947
REFERENCES FOR
Compound
Density
Point Index Point Dispersion
n-Hexane . 3,6,7,8,10,11, 1,5,6,7,8,10,11, 1,5,6,7,8,11, 1,2,7,10,11,13, 5,7,11,21

12,13,14,15, 13,15,16,17, 15,18 20
16,17 19
2-Methylpentane. 3,4,6,7,8,9,12, 1,4,6,7,8,9,13, 1,4,6,7,8,9,15 1,2,4,9 7,21

15,16,17 15,16,17,19
3-Methylpentane. 3,4,6,7,8,9,11, 1,4,6,7,8,9,13, 1,4,6,7,8,9,18 7,21

12,17 17,19
2,2-Dlmethylbutane . ^ ... . 3,4,6,7,8,12,13, 1,4,6,7,8,13, 1,4,6,7,8,22, 1,2,4,7,13,22, 7,21

16,17,22,23, 16,17,19,22 23,24,27 23,24,25
24,25,27 23,24,26,27
2,3-Dlmethylbutane . 3,6,7,8,9,12,13, 1,6,7,8,9,13, 1,6,7,8,9,15, 1,2,7,9,13,22 7,21

14,15,16,17, 15,16,17,19, 22,28
22 22,28
1*
REFERENCES
1. Forzlatl, Glasgow, Willingham, and Rossini1 15. Lemons and Felslng1 11

2. Glasgow, Murphy, Willingham, and Rossini1 16. McArdle and Robertson1
3. Willingham, Taylor, Plgnocco, and Rossini1 17. Griswold, van Berg, and Kasch1
4. Howard, Mears, Fookson, Ponerantz, and Brooks1 18. Quayle, Day, and Brown1
5. Garrett1 19. Wibaut and Langedljk1
6. Birch, FIdler, and Lowry1 20. Huffman, Parks, and Barmore1
7. Wibaut, Hoog, Langedljk, Overhoff, Smlttenberg, 21. Forzlatl and Rossini1
p
Bennlnga, Bouman, van DIJk, Gaade, Geldof, 22. Brooks, Howard, and Crafton
Hackmann, Jonker, Paap, and Zulderweg1 23. Hicks-Bruun, Bruun, and Faulconer1
p
8. Cramer and Mulligan1 24. van Risseghem
9. Bruun, Hicks-Bruun, and Faulconer1 25. Timmermans1
10. Malr1 26. van Grosse1
11. Shepard, Henne, and Mldgley1 27. Liberman, Lukina, Solovova, and Kazanskil1
12. Wojclechowski3 28. Bazhulin, Bokshteln, Liberman, Lukina, Margolls,
13. Smlttenberg, Hoog, and Henkes1 Solovova, and Kazanskil1
14. Lamb and Roper1
SPECIFIC REFERENCES
May 31, 1947
- REFERENCES FOR
Compound ,
Boiling Refractive Freezing Refractive
Density
n-Heptane. 1,5,6,7,8,9,10, 1,5,6,7,11,12, 1,2,5,6,7,8,10, 5,11,18,27,28,

11,12,13,14, 11,12,13,15, 13,15,18,19, 11,12,13 29
15,16,17 16,18 20,21
2-Methylhexane . ... 5,6,7,8,9 5,6,7 5,7,8,22 5,28
3-Methylhexane . . 6,7,9,14 6,7,9 6,7 28
3-Ethylpentane . 6,7,9,13,14 6,7,9,13 6,7,13 13,22 28
2,2-Dlmethylpentane. 3,5,6,7,8,9,14, 1,5,6,7,8,9,16 1,5,6,7 5,7,8,22 5,28,29

16
2,3-Dlmethylpentane. 4,5,6,7,8,9,14, 4,5,6,7,8,9,16, 4,5,6,7,23,24 5,28

16,23,24 23,24
2,4-Dlmethylpentane. 4,5,6,7,8,9,16, 4,5,6,7,8,9,16, 4,5,6,7,24 4,5,7,8,22 5,28

24 24
3,3-Dlmethylpentane. 3,5,7,8,9,25,26 1,5,7,8,9,25,26 1,5,7,25,26 5,7,8,22,26 5,28,29
2,2,3-Trimethylbutane. 5,6,7,8,9,13, 5,6,7,8,9,13, 5,6,7,13,18,24 2,5,6,7,8,13 5,18,28

14,16,24 16,18,24
REFERENCES
Forzlatl, Glasgow, Willingham, and Rossini 17. Smith, E.R.1

1
Glasgow, Murphy, Willingham, and Rossini1 18. Garrett
Willingham, Taylor, Plgnocco, and Rossini1 19. Reno and Katz1
Howard, Mears, Fookson, Pomerantz, and Brooks1 20. Quayle, Day, and Brown1
Wibaut, Hoog, Langedljk, Overhoff, Smittenberg, 21. Gelst and Cannon1
Benninga, Bouman, van Dijk, Oaade, Geldof, 22. Streiff, Murphy, Sedlak, Willingham, and Rossini1
Hackmann, Jonker, Paap, and Zuiderweg1 23. Cline1
6. Birch, Fldler, and Lowry1 24. Bazhulin, Bokshteln, Liberman, Lukina, Margolis,
7. Edgar and Callngaert1 Solovova, and Kazanskii1
8 . Smittenberg, Hoog, and Henkes1 25. Liberman, Lukina, Solovova, and Kazanskii1
1
9. Davies and Gilbert1 26. American Petroleum Institute Research Project 45
10. Malr1 27. Grosse and Wackher1
11. Shepard, Henne, and Mldgley1 28. Smyth and Stoops1
12. Brooks1 29. Forzlatl and Rossini1
2
13. Brooks, Howard, and Crafton
14. Wojciechowskl3
15. Butler1
16. McArdle and Robertson1
SPECIFIC REFERENCES
FOR TABLES 3a, 3a-E, and 3b
May 31, 1947
REFERENCES FOR
Compound
Density
n-Octane . 3,7,8,10,11,12, 1,6,7,8,10,11, 1,5,6,7,8,11,13, 1,2,7,8,10,11, 6,8,11,32,33

13,14 13,14 15 13
2-Methylheptane. 1,6,7 1,5,7,15 1,2 6,32,33
3-Methylheptane. 1,6,7 1,5,6,8,15 1.2 6,8,32,33
4-Methylheptane. 1,6,16,17 1,5,6,15,16,17 1,2,16,17 6,32,33
3-Ethylhexane. 3 1 1,5,15 32,33
2,2-Dlmethylhexane . 1,18 1,5,18 1.2 32,33
2,3-Dlmethylhexane . 1,8,9,17,19 1,5,8,9,17,19 8,32,33
2,4-Dimethylhexane . 1,7 1.5,7 32,33
2,5-Dlmethylhexane . 1,7,8,20 1,7,8,20 1,2 8,32,33
3,3-Dlmethylhexane . 3 1 1.5 1,2 32,33
3,4-Dlmethylhexane . 1,7,8,9 1,5,7,8,9 8,32,33
2-Methyl-3-ethylpentane. . . . 3,4,9 1,4,6,9 1,4,5,6,9 1,2,4 6,32,33
3-Methyl-3-ethylpentane. . . . 3,8,18 1,6,8,18 1,5,6,8,18 1,2,8,17 6,8,32,33
2,2,3-Trlmethylpentane .... 1,7,8,9,22 1,5,7,8,22 1,2,22 8,32,33
2,2,4-Trlmethylpentane .... 3,7,8,12,14,21, 1,6,7,8,14,21, 21 9 1,7,8,21,23,26 6,8,25,30,31,

23,24 23,25 23,25 32,33
2,3,3-Trlmethylpentane .... 3,4,7,19 1,4,7,19 1,4,5,7,19 1,2,17 32,33
2,3,4-Trlmethylpentane .... 3,7,9,23 1,6,7,9,23 1,5,7,9,23 1,2,23,29 6,32,33
2,2,3,3-Tetramethylbutane. . . 27,28 28 28 9,28 32,33
REFERENCES
1. Forzlatl, Glasgow, Willingham, and Rossini1 16. Butler1 11

2. Strelff, Murphy, Sedlak, Willingham, and Rossini1 17. American Petroleum Institute Research Project 451
3. Willingham, Taylor, Plgnocco, and Rossini1 18. Liberman, Lukina, Solovova, and Kazanskll1
4. Howard, Mears, Fooksons, Pomerantz, and Brooks1 19. Cline1 '
5. Gelst and Cannon1 20. Turk1
6. Garrett1 21. Brooks1
7. Birch, Fldler, and Lowry1 22. Brooks, Howard, and Crafton1
p
8. Wlbaut, Hcog, Langedljk, Overhoff, Smlttenberg, 23. Brooks, Howard, and Crafton
Eennlnga, Bouman, van DIJk, Gaade, Geldof, 24. Smith, E.R.1
Hackmann, Jonker, Paap, and Zulderweg1 25. Tilton1
9. Bazhulln, Bokshteln, Liberman, Lukina, Margolls, 26. Glasgow, Murphy, Willingham, and Rossini1
Solovova, and Kazanskll1 27. Henry1
10. Malr1 28. Callngaert, Soroos, Hnlzda, and Shapiro1
11. Shepard, Henne, and Mldgley1 29. Pltzer and Scott1
12. Wojclechowskl3 30. Grosse and Wackher1
13. Schmidt, Schoeller, and Eberleln1 31. Smyth and Stoops1
14. McArdle and Robertson1 32. Forzlatl and Rossini1
15. Quayle, Day, and Brown1 33. American Petroleum Institute Research Project 441
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
Point Index Density Point Dispersion
n-Nonane . 9,10,11,12,13, 9,10,11,12,15, 9,10,11,12,13, 9,10,11,12,15, 10,12,28,29

14,16,17,26 16,17 15 17,18
2-Methyloctane . 3,5,19 3,5,19 3,5 29
3-Methyloctane . 1.3 1.3 3 29

4-Methyloctane . 3 3 3 3 29
3-Ethylheptane . 5,19 5,19 5 29

4-Kthylheptane . 1,2,20,21 1,2,20,21 29
2,2-Dlmethylheptane. 6 6 6 29
2,3-Dlmethylheptane. 4,5,22 4,5,22 5 29

2,4-Dimethylheptane. 7,8 7,8,23 29
2,5-Dimethylheptane. 7,8 7,8,23 29
2,6-Dimethylheptane. 21,24 21,24 21,24 24 29

3,3-Dlmethylheptane. 6,25 6,25 29
3,4-Dimethylheptane. 1,2,27 1,2,27 29

3,5-Dimethylheptane. 1,2 1,2 29
4,4-Dlmethylheptane. 1,2 1.2 29
REFERENCES
1. Taylor, Pignocco, and Rossini1 15. Forziatl, Glasgow, Willingham, and Rossini1
2. Francis1 16. McArdle and Robertson1
3. White and Glasgow1 17. Smlttenberg, Hoog, and Henkes1
4. White and Glasgow2 18. Parks and Huffman2
5. Whitmore and Southgate1 19. Whitmore and Orem1
6. Marker and Oakwood1 20. Oberreit1
7. Tuot1 21. Butler1
8. Clarke and Biggs 22. Cline1
9. Mair1 23. Richards and Shipley1
10. Shepard, Henne, and Mldgley1 24. White, Rose, Callngaert, and Soroos1
11. Birch, Fldler, and Lowry1 25. No Her1
12. Wlbaut, Hoog, Langedijk, Overhoff, Smlttenberg, 26. Wojciechcwskl3
Bennlnga, Bouman, van DIJk, Gaade, Geldof, 27. Henne and Chanan1
Hackmann, Jonker, Paap, and Zulderweg1 28. Forziatl and Rossini1
13. Quayle, Day, and Brown1 29. American Petroleum Institute Research Froject 441
14. Willingham, Taylor, Pignocco, and Rossini1
SPECIFIC REFERENCES
•
FOR TABLES 4a(Part 2), 4a-E(Part 2), and 4b(Part 2)
(Applicable as of the date of issue of the numerical table)
May 31, 1947
REFERENCES FOR
Compound
Bolling Refractive Density Freezing Refractive
2-Methyl-3-ethylhexane .... 1,2,7 1,2,7 1,2,7 20
2-Methyl-4-ethylhexane .... 1,2 !,2 1,2 20

3-Methyl-3-ethylhexane .... 1,2 1,2 1,2 20
3-Methyl-4-ethylhexane .... 1,2 1,2 1,2 20
2,2,3-Trlme thylhexane. 1,2,6,7 1,2,6,7 1,2,6,7 20
2,2,4-Trlmethylhexane. 3,4,5 3,4,5,19 3,4,5 3,4 20
2,2,5-Trime thylhexane. 3,4,8,9,10 3,4,8,9,10,11 3,4,8,9,10 3,4,11 20
2,3,3-Trimethylhexane. 1,2,12 1,2,12 1,2,12 20
2,3,4-Trimethylhexane. 1,2 1,2 1,2 20

S
CD
2,3,5-Trimethylhexane. 4,8,12,19 4,8,12 4 20
2,4,4-Trlmethylhexane. 1,2,7,13 1,2,7,11,13 1,2,7,13 20
3,3,4-Trlmethylhexane. 1,2,7 1,2,7 1,2,7 20

3,3-Diethylpentane. 14,21 14,21 14,21 14,21 20
2,2-Dimethyl-3-ethylpentane. . 4 4 4 4 20
2,3-Dimethyl-3-ethylpentane. . 1,2 1,2 1,2 20
2,4-Dlmethyl-3-ethylpentane. . 4,7 4,7 4,7 20
2,2,3,3-Tetramethylpentane . . 4 4 4 4 20
2,2,3,4-Tetramethylpentane . . 4 4 4 4 20
2,2,4,4-Tetramethylpentane . . 15,16,17 15,17 15,17 11,15,17 20
2,3,3,4-Tetramethylpentane . . 4,18 4,18 4,18 4 20
REFERENCES
1. Taylor, Plgnocco, and Rossini1 12. Cline1

2. Francis1 13. Levina and Kagan1
3. Brooks, Cleaton, and Carter1 14. Morgan, Carter, and Duck1
4. Howard, Mears, Fookson, Pomerantz, and Brooks1 15. Howard1
5. Moersch1 16. Smith, E.R.2 3 4 5 6 7 8 9 10 11
6. Schlesman1 17. Whitmore and Southgate1
7. Whitmore and others1 18. Enyeart1
8. Turk1 19. American Petroleum Institute Research Project G1
9. Birch, Fldler, and Lowry1 20. American Petroleum Institute Research Project 441
10. Noller1 21. Horton1
11. Strelff, Murphy, Cahill, Flanagan, Sedlak,
Willingham,and Rossini1
SPECIFIC REFERENCES
FOR TABLES 5a? 5a-E, and 5-b
May 31, 1947
REFERENCES FOR
Compound
Benzene. 3,4,7,9,10,11, 1,4,6,7,9,10, 1,4,5,9,10,19, 2,4,7,9,10,14, 6,43,56,59

12,13,14,15, 14,16,17,18, 20,60 60
16,17,19,60 19,60
Methylbenzene. 3,4,7,9,13,17, 1,4,7,9,17,18, 1,4,5,9,20,22, 2,4,7,9,23,60 34,43,56,57,59
21,6C 57,60 57,60
Ethylbenzene . 3,4,9,17,21,25, 1,4,6,9,17,18, 1,4,5,9,20,25, 2,4,9,25,26,55, 6,43,56,58,59
26,60 25,26,59,60 26,59,60 60
1,2-Dimethylbenzene. 3,4,21,24,26, 1,4,6,24,26,28, 1,4,5,20,24,26, 2,4,24,26,30, 6,43,56,58,59
27,28,29,30, 29,30,31,59, 29,30,59,60 32,60
31,60 60
1,3-Dimethylbenzene. 3,4,21,24,26, 1,4,6,18,24,26, 1,4,5,20,24,26, 2,4,24,26,32, 6,43,56,58,59
27,28,31,33 28,31,33,59 33,59 33
1,4—Dlmethylbenzene. 3,4,21,24,26, 1,4,6,18,24,26, 1,4,5,20,24,26, 2,4,24,26,28, 6,24,43,56,57,
27,28,31,34, 28,31,34,35, 28,34,35,59, 32,34,35,36, 58,59
35,60 59,60 60 60
n-Propylbenzene. 3,4,17,33,37, 1,4,6,17,18,33, 1,4,5,20,33,37, 2,4,33,38,39, 6,43,58,59
60 37,39,59,60 39,59,60 60
Isopropylbenzene . 3,4,7,17,21,37, 1,4,6,7,17,18, 1,4,5,37,39,41, 2,7,39,41,42, 6,43,58,59
40,41,42,60 37,39,41,42, 42,59,60 60
59,60
1-Methy1-2-ethylbenzene. . . . 4,8,38,43,44 4,8,18,38,39, 4,8,39,43,45, 4,38,39 43,59
43,44,45,59 59
l-Methy1-3-ethylbenzene. . . . 4,8,38,43,44 4,8,18,38,39, 4,8,39,43,59 4,8,38,39 18,43,59
43,59
1-i'ethy 1-4-ethylbenzene. . . . 4,8,43,44,46 4,8,18,35,38, 4,8,35,39,43, 4,35,38,39 18,43,51,59
39,43,44,46, 46,59
59
1,2,3-Trlmethylbenzene . . . . 4,8,31,43,47 4,31,38,39,43, 4,39,43,47,59 2,4,38,39,47 43,47,59
47,59
1,2,4-Trimethylbenzene . . . . 4,8,31,43,47, 4,8,18,31,38, 4,8,39,43,47, 4,8,38,39,47, 43,51,58,59
48,49,50 38,43,47,48, 51,59 48,52
49,51,59
1,3,5-Trimethylbenzene . . . . 4,8,21,31,43, 4,8,18,31,38, 4,8,39,43,47, 4,8,38,39,47 43,51,58,59
47,50,53,54 39,43,47,51, 51,53,54,59
59
Amuicin Petroleum Institute Retouch Project 44
National Bureau of Standard! Waehington, D. C.
SPECIFIC REFERFjNCES
FOR TABLES 5a, 5a-E, and 5b - (Continued)
May 31, 1947
REFERENCES
1. Forzlatl, Glasgow, Willingham, and Rossini'*’ 32. Pitzer and Scott2

2. Glasgow, Murphy, Willingham, and Rossini1 33. Timmermans and Hennaut-Roland1
3. Willingham, Taylor, Plgnocco, and Rossini1 34. Timmermans and Martin2
4. Birch, Fldler, and Lowry1 35. Schmidt and Schoeller1
5. Gelst and Cannon1 36. Stuckey and Saylor1
6. Garrett1 37. McKenna and Sowa1
7. Smlttenberg, Hoog, and Henkes1 38. Strelff, Murphy, Sedlak, Willingham, and Rosslni1
8. American Petroleum Institute Research Project 451 39. Hischler and Faulconer1
9. Timmermans and Martin1 40. Kobe, Okabe, Ramsted, and Huemmer1
10. Wojclechowski2 41. White and Rose3
11. Swletoslowski and Usakiewicj1 42. Trojan1
12. Smith, E.R.1 43. von Auwers2
13. Zmaczynskl1 44. Turner and Leslie1
14. Kistlakowsky, Ruhoff, Smith, and Vaughan3 45. Blaise and Montagne1
15. Scat chard, Wood, and Mochel1 46. Le Fevre, Le Fevre, and Robertson1
16. Griswold, van Berg, and Kasch1 47. Malr and Schlcktanz1
17. Smith and Pennekamp1 48. Smith and Lund1
18. von Auwers and Kolllgs1 49. Smith and Cass1
19. Griswold and Ludwig1 50. Richards and Barry1
20. Massart1 51. von Auwers and Muller1
21. de la Mare and Robertson1 52. Huffman, Parks, and Barmore1
22. Bur lew1 53. Richards and Shipley2
23. Malr, Glasgow, and Rossini1 54. Tistchenko1
24. White and Rose1 55. Guthrie, Spltzer, and Huffman1
25. White and Rose2 56. Grosse and Wackher1
26. Hammond and McArdle1 57. Tilton1
27. Wojciechowski3 58. Cotton and Mouton1
28. Chapas1 59. Forzlatl and Rossini1
29. Chavanne, Katzenstein, and Pahlavouni1 60. Gibbons, Thompson, Reynolds, Wright, Chanan,
30. Miller1 Lambert!, Hipsher, and Karablnos1
31. Smith and Pennekamp2
745211 0 - 47 - 27
SPECIFIC REFERENCES
FOR TABLES 6a, 6a-E, and’6b
May 31, 1947
REFERENCES FOR
Compound
Cyclopentane . 2,5,10,11,12, 1,2,3,5,11,15, 1,2,3,4,5,11, 2,5,10,14,15 3,5,32,37

13,34,35 35,36 34,35
Methylcyclopentane . 2,5,9,11,13, 1,2,3,5,11,12, 1,2,3,4,5,9,11, 5,9,14 3,5,31,32,37
16,17,34,40 15,16,17,18, 16,17,18,34,
36,40 40
Ethylcyclopentane. 2,9,11,16,19, 2,3,9,11,16, 2,3,4,9,11,16, 9,14,21,23,24 3,9,31,32
20,22,23,32, 18,19,20,22, 18,22,23,32,
34,38,39,40 23,24,32,38, 34,38,39,40
39,40
1,1-Dlmethylcyclopentane . . . 2,24,25,26,27, 2,24,25,26,27, 2,25,26,27,32 2,24,25,26 24,32,33
28,32,44 28,32,44
cls-l,2-Dimethylcyclopentane . 2,6,8,32,41,44 2,6,8,24,32,44 2,6,8,32,41 6,8,24,41 6,8,32,33
trans-l,2-Dimethlcyclopentane. 2,6,8,24,29,32, 2,6,8,24,29, 2,6,8,£9,32 6,8,24,29,41, 6,8,32,33
41,44 32,41,44 42
cls-l,3-Dlmethylcyclopentane . 23,33,43 23,33,43 23,33,43 33
trans-l,3-Dlmethylcyclopentane 7,11,19,24, 7,11,24,29, 7,11,29,30, 7,24,29 7,32,33

29,30,32 32 32
REFERENCES
Forzlatl, Glasgow, Willingham, and Rossini 23. American Petroleum Institute Research Project 451
Birch, Fldler, and Lowry1 24. Strelff, Murphy, Cahill, Flanagan, Sedlak,
Garrett1 Willingham, and Rossini1
2
Gelst and Cannon1 25. Bruun and Hicks-Bruun
Wlbaut, Hoog, Langedljk, Overhoff, Smlttenberg, 26. Chavanne, Miller and Comet1
Bennlnga, Bouman, van Dijk, Gaade, Geldof, 27. Klshner3
Hackmann, Jonker, Paap, and Zulderweg1 28. Henshall1
6. Chlurdoglu1 29. Glasgow1
7, Chavanne1 30. Chavanne and Miller1
8, Chavanne2 31. Grosse and Wackher1
9, Chavanne and Becker1 32. Forzlatl and Rossini1
10. Aston, Fink, and Schumann1 33. American Petroleum Institute Research Project 44"
.
11 Evans
2
34. Kay1
.
12 Griswold, van Berg, and Kasch1 35. Vogel1
13. Willingham, Taylor, Flgnocco, and Rossini1 36. Wlbaut and Langedljk1
14. Glasgow, Murphy, Willingham, and Rossini1 37. Douslln and Huffman1
15. Smlttenberg, Hcog, and Henkes1 38. Zelinsky, Kasar.sky, and Plate1
16. Crane1 39. Pines ar.d Ipatieff1
17. Griswold and Ludv/lg1 40. Crane, Boord, and Henn.e1
18. Mcore, Renqulst, and Farks1 41. Chlurdoglu2
19. Turner and Lesslle1 42. Huffraan, Parks, and Barraore1
,
20 McArdle and Robertson1 43. Strelff, Murphy, Cahill, Soule, Sedlak,
.
21 Timmermans
2
Willingham, and Rossini1
22. Greenlee1 44. 'Whitmore ar.d others'1'
National Bureau of Standards _Washington D. C.
SPECIFIC REFEREllCES
FOR TABLES 7a, 7a-E and 7b
(Applicable as of tne date of issue of tne numerical table)
May 31, 1947
REFERENCES FOR
Compound
Boiling Refractive Density Freezing Refractive
Cyclohexane. 3,4,6,9,11,12, 1,4,5,6,9,10, 1,4,5,6,7,9, 2,4,6,9,10,14, 5,6,26,28

13 12,13,14,15 14,15,16 17,29
Methylcyclonexane. 3,4,6,9,13,18, 1,4,5,6,9,10, 1,4,5,6,7,9, 2,4,6,32 5,6,19,26,28
30 13,14,18,19, 14,16,19,30
31
Ethylcyclohexane . 3,4,9,13,20,21 1,4,5,9,13,21 1,4,5,7,9 2,20,21,33 5,28
1,1-Dimethylcyclohexane. . . . 8,21,22,23,24, 8,21,22,23,24, 8,22,23,25,28 8,21,23,25,33 8
25,28 25,28
cis-l,2-Dimethylcyclohexane. . 3,8,21,25 1,5,8,21 1,5,7,8 8,21,33 5,8,27,28
trans-l,2-Dlmethylcyclohexane. 3,8,21 1,5,8,21 /,8 8,21,33 5,8,27,28
cis-l,3-Dimethylcyclohexane. . 3,4,8,34 1,4,8,34 1,4,7,8,34 8,33,35 8,28
trans-1,3-Dimethylcyclohexarie. 3,8,34 1,8,34 1,7,8,34 8,33,35 8,28
cls-l,4-Dimethylcyclohexane. . 3,8 1,5,8,21 1,5,7,8 8,21,33 5,8,28
traris-1,4-Dime thylcyclohexane. 3,8 1,5,8,21 1,5,7,8 8,21 5,8,28
REFERENCES
1. Forzlati, Glasgow, Willingham, and Rossini1 19. Tilton1 11

2. Glasgow, Murphy, Willingham, and Rossini1 20. Timmermans2
3. Willingham, Taylor, Pignocco, and Rossini1 21. Streiff, Murphy, Cahill, Flanagan, Sedlak,
4. Birch, Fidler, and Lowry1 Willingham and Rossini1
5. Garrett1 22. Zelinsky, Packindcrff, and Khokhlova1
6. Wibaut, Hoog, Langedijk, Overhoff, Smittenberg, 23. Chavanne, Miller, and Cornet1
Bennlnga, Bouman, van Dljk, Gaade, Geldof, 24. Turner and Lesslie1
Hackmann, Jonker, Paap, and Zuiderweg1 25. American Petroleum Institute Research Project 451
7. Geist and Cannon1 26. Grosse and Wackher1
8. Miller5 27. Miller2
9. Evans2 28. Forziatl and Rossini1
10. Smittenberg, Hoog, and Henkes1 29. Aston, Szasz, and Fink1
11. Scat chard, Wood, and Mochel1 30. Kay1
12. Griswold, van Berg, and Kascn1 31. Calingaert1
13. Smith and Pennekarnp1 32. Douslln and Huffman1
14. Moore, Renquist, and Parks1 33. Huffran and others1
15. Waterman and Leendertse1 34. Mousseron and Granger1
16. Massart1 35. Streiff, Murphy', Cahill, Soule, Sedlak, Willingham,
17. Ruehrwein and Huffman1 and Rossini1
18. McArdle and Robertson1
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
Ethene . 4,10,11,12,49 10,11

Propene. 3,4,13,14,15, 1 13,16
49
1-Butene . 2,3,4,17,18,49 1,2 18
cls-2-Butene . 2,3,4,19,49,51 1,2 3,20,31,51
trans-2-Butene . 2,3,4,19,21,49 1,2 3,20,21,31
2-Methylpropene. 2,3,4,22,49 1,2 3,20,22,31,52
1-Pentene. 9,24,28 8,24,28 9,54 50
26,27,28
cls-2-Pentene. 5,6,7,8,28,29, 5,6,7,9,28,29, 5,6,7,8,29,30 5,7,9 30,50
30,32 30
trans-2-Pentene. 5,6,7,8,9,28, 5,6,7,9,28,30, 6,7,8,28,30,34, 5,7,9,28 50
30,33,34,35 33,34,35 35
2-Methyl-l-butene. 8,9,36,37,38, 9,36,37,38,39, 8,37,53 9,28,53 50
39,53 53
3-Methy1-1-butene. 6,7,8,9,23, 6,7,40,41,42, 6,7,8,41,43 9,31 43,50
40,41,42,43, 43
48
2-Methy1-2-butene. 4,6,7,8,9,28, 6,7,9,28,36, 6,7,8,28,47 ' 7,9,28,31,36, 50
36,38,39,43, 38,39,43,44, 43
44,45,46,47 45,46,47
REFERENCES
1. Cragoe1 28. American Petroleum Institute Research Project 451 11

2. Benoliel1 j 29. Sherrill and Launspach1
3. Klstlakowsky, Ruhoff, Smith, and Vaughan 30. Sherrill and Mat lack1
4. Lamb and Roper1 31. Glasgow and Rosslnl1
5. Lucas and Prater1 32. Gredy1
6. Carr and Walter1 33. Lauer and Stodola1
7. Norris and Reuter1 34. Sherrill, Baldwin, and Haas1
8. Ewell and Hardy1 35. Sherrill, Otto, and Pickett1
9. Strelff, Murphy, Sedlak, Willingham, and Rossini1^ 36. Klstlakowsky, Ruhoff, Smith, and Vaughan^
10. Klstlakowsky, Romeyn, Ruhoff, Smith, and Vaughan 37. Sherrill and Walter1
11. Egan and Kemp1 38. Church, Whitmore, and McGrew1
12. Henning and Stock1 39. Whitmore, Rowland, Wrenn, and Kilmer1
13. Powell and Glauque1 40. Dolllver, Gresham, Klstlakowsky, and Vaughan1
14. Crawford, Klstlakowsky, Rice, Wells, and Wilson1 41. Whitmore, Popkln, Bernstein, and Wilkins1
15. Ashdown, Harris, and ArnBtrong1 42. Gredy2
16. Huffman, Parks, and Barmore1 43. Leendertse, Tulleners, and Waterman1
17. Lucas and Dillon1 44. Whitmore and Mosher1
18. Aston, Fink, Bestul, Pace, and Szasz1 45. Whitmore and Stahly1
19. Young, Dillon, and Lucas1 46. Michael and Weiner1
20. Todd and Parks1 47. Thompson and Sherrill1
21. Guttman and Pltzer1 48. Smith, E.A.1
22. Coffin and Maass3 49. Cragoe2
23. Whitmore and Simpson1 50. American Petroleum Institute Research Project 441
24. Sherrill, Mayer, and Walter1 51. Scott, Ferguson, and Brlckwedde1
25. Stewart, Dod, and Stenmark1 52. Rands, Scott, and Brlckwedde1
26. Mulllken, Wakeman, and Gerry1 53. Slabey1
27. Pykstra, Lewis, and Boord1 54. American Petroleum Institute Research Project 61
N
SPECIFIC REFERENCES
FOR TABLES 8a (Part 2), 8a-E (Part 2), and 8b (Part 2}
(Applicable as of the date of Issue of the numerical value)
May 31, 1947
REFERENCES FOR
Compound
1-Hexene . 2,4,5,9,10,14, 2,4,9,10,14,21 2,4,5,9,10,14, 4,5,14,21 4,9,14,21,47

20,21,22,23 21,22
cls-2-Hexene . 2,4,14,24,25 2,4,14,25 2,4,14,25 4,14,26 2,4,14,47
trans-2-Hexene . 2,4,14,17 2,4,14,17 4,14,17 2,4,14,47
cls-3-Hetene.. . . . 2,3,6,18,19,27 2,3,6,18,19,27 2,3,6,18,19,27 3,26 4,18,47
trans-3-Hexene . 2,3,6,18,27 2,3,6,18,27 3 4,18,47
2-Methyl-l-pentene . 1,2,10 1,2,10 1,2,10 47
3-Methyl-l-pentene . . . 2,28,29 2,28,29 2,28,29 47
4-Methyl-l-pentene . 2,16,17,22 2,16 2,16,22 2,16,47
2-Methyl-2-pentene . 2,13,15,17,30, 2,13,15,30,31, 2,13,15,30,31, 13,30 2,15,47

31,32 32 32
cls(?)-‘3-Metnyl-2-pentene. . . . 2,7,12,19,33, 2,7,33,34,35 2,7,34,35 7 2,47

34,35
trans(?)-3-Methyl-2-pentene... . 2,7,12,19,33, 2,7,33,34,35 2,7,34,35 7 2,47

34,35
cls(?)-4-Methyl-2-pentene. . . . 2,5,11,17,19, 2,23,30 2,23,30 47

23,30
trans(?)-4-Methyl-2-pentene. . . 2,5,19 2 2 47
2-Ethyl-l-butene . 1,2,9,10,35, 1,2,9,10,35, 1,2,9,10,35, 9,47

36 36 36
2,3-Dlmethyl-l-butene. 1,2,7,8,37,38, 1,2,7,8,37,38, 1,2,7,8,38 7,38 47

39 39
3,3-Dlmethyl-l-butene. 8,38,39,40,41, 8,38,39,40,41, 8,38,41,43 8,44,46 47

42,43,46 42,43,46
2,3-Dlmethyl-2-butene. 6,7,8,30,37, 6,7,8,30,37, 7,8,30,38 7,8,30,37,38, 38,47

38,39 38,39 45
REFERENCES
1. Schmitt and BoordJ 25. Gredy1

2. Schmitt and Boord2 26. Henne and Greenlee1
3. Campbell and Eby1 27. Gibson1
4. Campbell and Eby2 28. Whitmore and Carney1
5. van Rlsseghem, Gredy, and Plaux1 29. Taylor, Plgnocco, and Rossini1
6. Carr and Waite.'1 30. American Petroleum Institute Research Project 451
7. Howard, Mears, Fookson, Pomerantz, and Brooks1 31. Rudel1
8. Brooks, Howard, and Crafton2 32. Nasarov1
9. van Pelt and Wlbaut1 33. Whitmore and Mosher1
10. Whitmore, Fenske, Quiggle, Bernstein, Carney, 34. Homey1
Lawroskl, Popkln, Wagner, Wheeler, and Whitaker1 35. Hull1
11. van Rlsseghem2 36. Colonge1
12. van Rlsseghem4 37. Klstiakowsky, Ruhoff, Smith, and Vaughan2
13. van Rlsseghem5 38. Schurman and Boord1
14. van Rlsseghem6 39. Laughlln, Nash, and Whitmore1
15. van Rlsseghem7 40. Dolllver, Gresham, Klstiakowsky, and Vaughan1
16. van Rlsseghem8 41. Fomin and Sochanskl1
17. van Rlsseghem10 42. Birch, Fidler, and Lowry1
18. van Rlsseghem11 43. Wlbaut and Gltsels2
19. van Rlsseghem12 44. Kennedy, Shomate, and Parks1
20. Wlnsteln and Lucas1 45. Parks, Todd, and Shomate1
21. Waterman and De Kok1 46. Strelff, Murphy, Cahill, Soule, Sedlak, Willingham,
22. Dykstra, Lewis, and Boord1 and Rossini1
23. Mulllken, Wakeman, and Gerry1 47. American Petroleum Institute Research Project 441
24. Stewart, Dod, and Stenmark1
SPECIFIC REFERENCES
FOR TABLES 9a(Part 1), 9a-E(Part 1), and 9b(Part 1)
May 31, 1947
REFERENCES FOR
Compound
Density
1-Heptene. 2,3,7,8,10,11, 2,3,7,6,10,11, 2,7,8,11,13, 7,8,10,16 7,8,13

12,13,14,15,17 13,14,15 14,15
cls-2-Heptene. 1,2,3,4 1,2,3,4 1,2,4 27
trans-2-Heptene. 1,2,3,4 1,2,3,4 1,2,4 27
cls-3-Heptene.
ll,2,5,6,o,18, 1,2,5,6,9,18, 1,2,5,6,9,18, 27
trans-3-Heptene.
I 19 19 19
2-Me thy1-1-hexene. 1,2 1,2 1,2 27
3-Hethy1-1-hexene. 1,2 1,2 1,2 27
4-Iiethy 1-1-hexene. 1.2 1.2 1,2 27
5-Methy1-1-hexene. 2,17,20,21 1,2,17,21 2,17,20,21 27
2-Methy1-2-hexene. 2,5,22,23 2,5,23 2,5,23 27
cis-3-Me thy1-2-hexene. 1,2,24,25 1,2,24,25 1,2,25 27
trans-3-Methyl-2-hexene. . . . 1,2,24,25 1,2,24,25 1,2,25 27
cis-4-Methyl-2-hexene. 1.2 1,2 1,2 27
trans-4-Methyl-2-hexene. . . . 1,2 1,2 1,2 27
cls-5-Methyl-2-hexene. 1,2,5 1,2,5 1,2,5 27
trans-5-Methy 1-2-hexene. . . . 1,2,5 1,2,5 1,2,5 27
cis-2-Methyl-3-hexene. ....
}l,2 1,2 1.2 27
trans-2-Methy1-3-hexene. . . .
cls-3-Methy1-3-hexene.
Jl,22,26 1 1 27
trans-3-Methyl-3-hexene. . . .
REFERENCES
1. Taylor, Plgnocco, and Rossini1 15. Appleby, Dobratz, and Kapranos1

2. Soday and Boord1 16. Parks, Todd, and Shonate1
3. Stewart, Dod, and Stenrtark1 17. Mulliken, Wakeman, and Gerry1
4. Gredy1 18. Komarewsky and Kritchevsky1
5. Tuot2 19. Mathus and Glbon1
6. Carr and Walter1 20. Dykstra, Lewis, and Boord1
7. Campbell and Eby2 21. American Petroleum Institute Research Project 451
8. Waterman and De Kok2 22. Edgar, Callngaert, and Marker1
9. Prevost and Daujat1 23. Rudel1
10. Klstlakowsky, Ruhoff, Smith, and Vaughan2 24. Horney1
11. Sherrill, Mayer, and Walter1 25. Nasarov1
12. Lamb and Roper1 26. Favorski and Zalusky-Klbardine1
13. van Pelt and Wibaut1 27. American Petroleum Institute Research Project 441
14. Campbell and Young1
SPECIFIC REFERENCES
FOR TABLES 9a(Part 2), 9a-E(Part 2), and 9b (Part 2)
May 31, 1947
REFERENCES FOR
Compound
2-Ethyl-l-nentene. 1,2 1,2 1,2 23
3-Ethyl-l-pentene. 1,7 1,7 1,7 23
2,3-Dimethyl-l-pentene .... 1,2 1,2 1,2 23
2,4-Dlmethyl-l-pentene .... 1,2 1,2 1,2 23
3,3-Dimethyl-l-peritene .... 1,3,8 1,3,8 1,3,8 23
3,4-Dimethyl-l-pentene .... 1 1 1 23
4,4-Dimetnyl-l-pentene .... 6,9,10,11 6,9,10,11 6,9,11 6,10 23
3-Ethyl-2-pentene. 2,4,12,13,14 2,4,12,14 2,4,12 2,23
2,3-Dime thy1-2-pentene .... 4,5,13,15 4,5,15 4,5,15 5 23
2,4-Dimethyl-2-penterie .... 13,14,16,17, 16,17,18,19 16,17,18,19 17,18,23

18,19
cis-3,4-Dimethyl-2-pentene . . 1 23
1,2,4 1,2,4 1,2,4
trans-3,4-Dimethy1-2-pentene . J 23
cis-4,4-Dimethyl-2-pentene . . 23
1,3 1,3 1,3
trans-4,4-Dimethyl-2-peritene . 23
3-Methyl-2-ethyl-l-buterie. . . 1,2 1,2 1,2 23

2,3,3-Trimethyl-l-butene . . . 5,6,20,21,22 5,6,20,21,22 6,20,21,22 6,20,21 21,23
REFERENCES
1. Taylor, Pignocco, and Rossini1 13. Edgar, Calingaert, and Marker1

2. Soday and Boord1 14. Birch, Fidler, and Lowry1
3. Schurman and Bcord1 15. Pariselle and Simon1
4. Nasarov1 16. Deux1
5. Cline^ 17. De Graef1
6. American Petroleum Institute Research Project 451 18. van Pelt and Wibaut1
7. Prevost and Daujat1 19. Wibaut, van Pelt, Santllhano, and Beuskens1
8. Rudel1 20. Brooks, Howard, and Crafton2 3 4 5 6 7 8 9 10 11 12
9. Mulliken, Wakeman, and Gerry*- 21. Chavanne and Lejeune1
10. Dolliver, Gresham, Kistlakowsky, and Vaughan1 22. Meshcheryakov1
11. VJhitmore and Homeyer1 23. American Fetroleum Institute Research Project 441
12. Carr and Walter1
SPECIFIC REFERENCES
FOR TABLES 10a (Part 1), lOa-E (Part 1), and 10b (Part 1)
May 31, 1947
REFERENCES FOR
Compound
l-Octene . 2,3,6,7,8,9,11, 2,3,6,7,8,9,11, 2,3,6,7,8,9,11, 2, 6,7,9 6,13,14,26

12,13,14 12,13,14 12,13,14
cis-2-0ctene . 2,3,4,6,7,8,11, 2,3,4,6,7,8,11, 2,3,4,6,7,8,11, 2,6,7 6,26
15 15 15
trans-2-0ctene . 2,3,4,6,7,8,9, 2,3,4,6,7,8,9, 2,3,4,6,7,8,9, 2,6,7,9 6,26
11 11 11
cis-3-0ctene . 2,5,8,16,17 2,5,8,16,17 2,5,8,16,17 6,16,26
trans-3-0ctene ........ 2,5,8,9,16,17, 2,5,8,9,16,17, 2,5,8,9,16,17, 2,5,18,25 6,16,26
18,25 18,25 18,25
cis-4-0ctene . 2,5,8,19,20 2,5,8,19,20 2,5,8,19,20 2,5,19,20 6,26
trans-4-0ctene . 2,4,5,8,9,18, 2,4,5,8,9,18, 2,4,5,8,9,18, 2,5,9,18,20, 6,26

20,25 20,25 20,25 25
2-Methyl-l-heptene . 7,8,10,21 7,8,10,21 7,8,10 7,10 26
3-Methyl-l-heptene . 1,4 1,4 1,4 26
4-Methyl-l-heptene . 1,3 1,3 1,3 26
5-Methyl-l-heptene , . 1,3 1,3 1,3 26
6-Methyl-l-heptene . 3,7,10,22 3,7,10,22 3,7,10,22 26
2-Methyl-2-heptene . 17,21,23,24 17,21,23,24 17,23,24 26
REFERENCES
1. Taylor, Pignocco, and Rossini1 14. Waterman and Te Nuyl1

2. Henne and Greenlee1 15. Gredy1
3. Dietrich1 16. Wlbaut and Gitsels1
4. Gibson1 17. Tuot2
5. Campbell and Eby1 18. Campbell and McDermott1
6. Campbell and Eby2 19. Campbell and Young1
7. Henne, Chanan, and Turk1 20. Young, Jasaitls, and Levanas1
8. Mavity1 21. Birch, Fldler, and Lowry1
9. Cleveland1 22. Brooks and Humphrey1
10. Cleveland2 23. Rudel1
11. Whitmore and Herndon1 24. Hull1
12. Meshcheryakov1 25. American Petroleum Institute Research Project 451
13. van Pelt and Wibaut1 26. American Petroleum Institute Research Project 441
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
Density
cls-3-Methyl-2-heptene .
| 1,2,3,4 1,2,3,4 1,2,4 14
trans-3-Methyl-2-heptene
} 1,5,6,7,9 1,5,6,7,9 1,5,6,7 14
cis-5-Methyl-2-heptene .
1 1 14
cls-6^lethyl-2-heptene .
| 1,5,13 1,5,13 1,5,13 14
| 1,8 1,8 1,8 14
j 1,10,11 1,10,11 1,10,11 14
trans-3-Llethyl-3-heptene
cis-4-Methyl-3-heptene .
1 1 14
trans-4-Methyl-3-heptene l1
1,8 1,8 14
trans-5-llethyl-3-heptene
cls-6^lethyl-3-heptene .
| 1,8,12 1,8,12 1,8,12 14
t ran s-6-Methy1-3-hept ene
REFERENCES
1. Taylor, Plgnocco, Rossini1 8. Mavlty1

2. Tuot3 9. Komarewsky and Krltchensky1
3. Horney1 10. Reid1
4. Hull1 11. Mescheryakov1
5. Dietrich1 12. Tuot2
6. Henne, Chanan, and Turk1 13. American Petroleum Institute Research Project 451
7. Mulllken, Wakeman, and Gerry1 14. American Petroleum Institute Research Project 441
Ametican Petroleum Institute Research Project 44
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
2—'thy 1-1-hexene. 1,2,3 1,2,3 1,2,3 3,16,17

3-1'thyl-l-hexene. 1,2 1,2 1,2 17
4-Ethyl-1-hexene . 1 1 1 17
2,3-Dimethyl-l-hexene. 1,4,5,15 1,4,5,15 1,4,5,15 17
2,4-Dimethyl-l-hexene. 1,4 1,4 1,4 17
3,3-Dimethyl-l-hexene. 1,5,5 1,5,6 1,5,6 17

cis-3-Ethy1-2-hexene ..... 1 1,8 1,8 17
\ 1,8
trans-3-Ethyl-2~hexene .... 1
cis-4-Ethyl-2-hexene .....
!,7 1,7 1,7 17
trans-4-Ethyl-2-hexene .... J
2,3-Dimethyl-2-hexene. 1,5,9,10,11,12 1,5,9,10,11,12 1,5,9,11,12 9 17
2,4-Dimethyl-2-hexene. 1,5,10,13 1,5,10 1,5,10 17
2,5-Dimethy1-2-hexene. .... 1,6,0,14 1,6,8,14 1,6,8,14 17
1. Taylor, Flgnocco, and Rossini1 10. Homey1

2. Mavity1 11. Nasarcv1
3. van Pelt and Wibaut1 12. Henne and Hatuszak1
4. Kuykendall1 13. Birch, Fidler, and Lowry1
5. Reid1 14. Tuot2
6. Rudel1 15. American Petroleum Institute Research Project 451
7. Dietrich1 16. Grosse and Wackher1
8. Hull1 17. American Petroleum Institute Research Project 441
9. Cline1
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
Density
Point 4ndex Point Dispersion
cis-3,4-Dimethy1-2-hexene. .
1.2 1,2 1,2
trans-3,4-Dimethy1-2-hexene.
cis-3,5-Dimethyl-2-hexene. .
1,2,3,4 1,2,3,4 1,3,4
trans-3,5-Dimethyl-2-hexene.
cis-4,4-Dlmethy1-2-hexene. .
1.5 1.5 1.5
1.6 1.6 1.6
cis-5,5-Dlmethyl-2-hexene. .
3-Ethy1-3-hexene . 1 1 1
cis-2,2-Dimethyl-3-hexene. . 1,5,7 1,5,7 1,5,7
trans-2,2-DImethyl-3-hexene.
cis-2,3-Dimethy1-3-hexene. .
trans-2,4-Dlmethyl-3-hexene.
cis-2,5-DImethyl-3-hexene. .
1,8 , ,
1 8 1,8
REFERENCES
1. Taylor, Pignocco, and Rossini1 6. Dietrich1

2. Homey1 7. Henne and Matuszak1
3. Hull1 8. Eeid1
4. Tuot1 9. American Petroleum Institute Research Project 441
5. Schurman and Boord1
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
Density
2-n-Propyl-l-pentene ..... 1,2 1,2 1,2 22
2-Isopropyl-l-pentene. 1,2 1,2 1,2 22
3—Methyl-2-ethyl-l-pentene . . 1,2 1,2 1,2 22
4-I«:ethyl-2-ethyl-l-pentene . . 1,2,3 1,2,3 1,2,3 22
2-Methy 1-3-ethyl--1-pentene . . 1,2 1,2 1,2 22
3-Kethyl-3-ethyl-l-pentene . . 1,4 1,4 1,4 22
4~Methyl-3-ethyl-l-Jpentene . . 1 1 1 22
2,3,3-Trlmethyl-l-petnene. . . 1,2,5,7,10 1,2,5,7,10 1,2,5,7,10 10 22
2,3,4-Trimethyl-l-pentene. . . 1,2 1,2 1,2 22
2,4,4-Trlmsthyl-l-pentene. . . 8,9,11,12,13 8,9,11,12,13 8,9 8,9,14 22
2-Methyl-3-ethyl-2-pentene . . 1,4,17 1,4,17 1,4,17 22
cls-4-Methyl-3-ethyl-2-pentene
1
trans-4-Methyl-3-ethyl-2- > 1,4 1,4 1,4 22
pefitene.
2,3,4-Trimethyl-2-pentene. . . 6,9,18 6,9,18 9,18 22
2,4,4-Trlmethyl-2-pentene. . . 8,9,11,13,19, 8,9,11,13,19, 8,9,19,20 8,9,14 20,22

20 20.
cls-3,4,4-Trimethyl-2-pentene.
]
trans-3,4,4-TrImethyl-2- i 5,7,9,19 5,7,9,19 7,9,19 22
pentene.
3-Methy1-2-1sopropyl-l-but ene. 1,2,6,18 1,2,6,18 1,2,18 22
3,3-Dlmethyl-2-ethy1-1-butene. 1,21 1 1 22
_
REFERENCES
1. Taylor, Pienocco, and Rossini1 12. Whitmore and Houk1 2 3 4 5 * 7 8 9 10 11

2. Kuykendall 13. Whitmore, Rowland, Wrenn, and Kilmer1
3. mvity1 14. Parks, Todd, and Shomate1
4. Reid1 15. Rudel1
5. Whitmore and Laughlln1 16. Dietrich1
P 17. Nasarov1
6 * Whitmore and Laughlln^
3
7. Whitmore and laughlln 18. Wiest1
8. Tongberg,Pickens, Fenske, and Whitmore1 19. Homey1
9. Howard, Mears, Fookson, Pomerantz and Brooks1 20. van Pelt and WIbaut1
10. Cline1 21. Clarke and Jones1
11. Dolllver, Gresham, Klstlakowsky, and Vaughan1 22. American Petroleum Institute Research Project 441
SPECIFIC REFERENCES
FOR TABLES 11a (Fart 1), lla-E (Part 1), and lib (Part 1)
May 31, 1947
REFERENCES FOR
Compound
Propadiene . 1,2,3,4 1,4
1,2-Butadlene. 5 5,33 6
1,3-Butadiene. 7,10,12,18 1,6,10,13
1,2-Pentadiene.. . . 14,33 14,33 14,33 14
cls-l,3-Fentadlene . 8,9,15,16,17, 8,9,15,16,19, 8,9,16,19,20 9,33

19 20
trans-l,3-Fentadiene . 8,9,15,16 8,9,15,16,20 8,9,16,20 15 9,33
1,4-Pentadlene . 1,2,21,22,23 21,22 21,22,23 1,24
2,3-Pentadlene . 33 33 33
3-!.'ethyl-l,2-butadlene . . . . 25 25,33 25,33 25
2-Methyl-l,3-butadlene . . . . 9,26,27,28,29 9,26,29,30,31 9,26,29,31 6,26,29 9,26,29,31
REFERENCES
1. Klstlakowsky, Ruhoff, Smith, and Vaughan3 18. Buck1 11

2. Lamb and Roper1 19. Harries and Duvel1
3. Livingston and Helslg1 20. Ward1
4. Lespleau amd Chavanne1 21. Shoemaker and Boord1
5. Hurd and Melnert1 22. Kogerman1
6. Glasgow and Rossini1 23. Dykstra, Lewis, and Boord1
7. Benollel1 24. Parks, Todd, and Shomate1
8. Craig1 25. von Auwers1
9. Farmer and Warren1 26. Beckhedahl, Wood, and Wojclechowskl1
10. Meyers, Scott, Brlckwedde, and Rands1 27. Whitby and Crozler1
11. Prevost3 28. Helslg1
12. Cragoe1 29. Enklaar1
13. Garner, Adams, and Stuchell1 30. Glazebrook1
14. Bouls1 31. Forzlatl and Rossini1
15. Dolllver, Gresham, Klstlakowsky, and Vaughan1 32. von Auwers and Westerman1
16. Prevost1 33. American Petroleum Institute Research Froject 441
17. Mulllken, Wakeman, and Gerry1
SPECIFIC REFERENCES
FOR TABLES 11a (Part 2), lla-E (Part 2), and lib (Part 2)
May 31, 1947
REFERENCES FOR
Compound
Density Dispersion
Point Index Point
1,2-Hexadlene. ] 1 1 1
cis-l,3-Hexadiene.
' 2,3,4 2,3,4 2,3,4 2,26
trans-1,3-Hexadlene.
c1s-1,4-Kexadlene.
' 4,5 4,5 4,5
trans-1,4-Kexad1ene.
1,5-Hexadiene. 6,7,8,9,10 7,9 7,9,10 6,7
2,3-Hexadlene. 11 11 11 11
cis,cis-2,4-Hexadiene.
3,4,12,13,14, 3,4,12,13,14, 3,4,12,13,14, 13,14,26
cls,trans-2-4-Kexadlene. . . . 15,16,17
15,16,17 15,16,17
trans,trans-2,4-Hexadlene. . .
3-'.'ethyl-l,2-pentadlene. . . . 26 26 26
4-’Iethyl-l,2-pentadiene. . . . 1 1 1 1
cls-2-’.'sthyl-l,3-pentadiene. .
• 2,12,13,14 2,12,13,14 2,12,13,14 2,13,14,26
trans-2-l'ethyl-l, 3-pentadlene.
cis-3-i.'ethyl-l,3-pentadiene. .
> 12,13,18 12,13,18 12,13 13,26
trans-3-Methyl-l, 3-pentadlene.
4-Methy 1-1,3-pentadlene. . . . 12,13,19,20 12,13,19,20 12,13,19,20 13,26
2-Methyl-l,4-pentadlene. . . . 19 19,26 19,26
3-Methyl-l,4-pentadiene. . . . 26 26 26
2-’.'ethyl-2,3-pentadlene. . . . 26 26 26
2-Ethyl-l,3-butadlene. 21,26 26 26 26
2,3-Dimethyl-l,3-butadiene . . 8,12,13,14, 12,13,14,22,25 12,13,14,25 14,22 13,14,26

22,23,24,25
REFERENCES
1. Bouls1 14. Enklaar1

2. van Keersbllck1 15. Prevost1
3. Henne and Turk1 16. van Pelt and Wibaut1
2
4. Prevost 17. Henne and Chanan1
5. Shoemaker and Boord1 18. Fisher and Chittenden1
6. Klstlakowsky, Ruhoff, Smith, and Vaughan3 19. Wlest1
7. Cortese1 20. Bachman and Goebel1
8. WInsteIn and Lucas1 21. Parlselle and Simon1
9. Henne, Chanan, and Turk1 22. Dolllver, Gresham, Klstlakowsky and Vaughan1
10. Ilerllng1 23. Allen and Bell1
g 24. Birch, Fldler and Lowry1
11. van Rlsseghem
12. Whitby and Gallay1 25. Lebedev1
13. Farmer and Warren1 26. American Petroleum Institute Research Project 441
National Bureau of Standards ____ _Washington. D. C.
SPECIFIC REFERENCES
Kay 31, 1947
REFERENCES FOR
Compound
Density Point Dispersion
Point Index
Ethyne . 1,3 1,4
Propyne. 1,5,7,8,9,10,
11,12 1,5,6,8
1-Butyne ..... . 1,11,12,13,14, 1,15 1,6,14,15

15
2-Butyne . 2,5,6,10,16,17 16 2,16 2,6,16,18
1-Pentyne. 2,11,19,20,21, 11,19,22 2,11,19,20,22 2,20,22

23
2-Pentyne.. 6,22,23,24 6,22,23,24 6,22,23,24 6,23 23
3-Methyl-l-butyne. 26 26 26
REFERENCES
1. Morehouse and Maassl 14. Picon1

2 . Morehouse and Maass2 15. Dupont1
3. Burrell and Robertson1 16. Helslg and Davis1
4. mass and Russell1 17. Wisllcenus1
5. Conn, Kistlakowsky, and Smith1 18. Yost, Osborne, and Gari
6. American Petroleum Institute Research Project 451 19. Bouls1
7. Meinert and Hurd1 20. Picon2
8 . Lespleau and Chavanne1 21. Bourgel1
9. Helsig and Hurd1 22. Greenlee1
10. Helslg1 23. van Risseghem1
11. Krleger and Wenzke1 24. Sherrill and Launspaclr
12 . Lamb and Roper1 25. Gredy2
13. Hurd and Me Inert1
National Bureau of Standards_Washington, D. C.
SPECIFIC REFERENCES
(Applicable as of the date of Issue of the numerical table}
May 31, 1947
REFERENCES FOR
Compound
Styrene. 1,2,3,5,6 1,2,3,5,7 6,8,9 2,17
a-Methylstyrene. 2,10,11,12,13 2,11,12,13 2,11,12,13 13 2
els- /3-Methylstyrene. 1
2,14,15,16 2,14,16 2,14,16 2
trans-/3-Methylstyrene.
J
REFERENCES
1. Patnode and Scheiber1 10. Harries1

2. von Auwers and Eisenlohr1 11. Tiffeneau1
3. Shorygin and Shoryglna1 12. Klages1
4. Garner, Adams, and Stuchell1 13. Drelsbach1
5. Goldfinger, Josefowltz, and Mark1 14. Campbell and O’Connor1
6. Smoker and Burchfield1 15. Tlffeneau2 3 4 5 6 7 8 9
7. Cragoe and Peffer1 16. Levina1
8. Glasgow and Rossini1 17. Forziatl and Rossini1
9. Guttman, Westrum, and Pltzer1
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound Boiling Refractive Freezing Refractive
Density
n-Butylbenzene . 1,2,3.4,5,8,10, 2,3,4,11,12,13 1,2,3,6,7 50

11,12
Isobutylbenzene. 1,2,3,4,5,8,14, 1,2,4,5,8,10,11 2,4,11,14,15,51 1,2,6,51 50

15,51 14,16,51
sec-Butylbenzene . IV 918, 1,2,4,5,10,11, 2,4,11,17,51 1,2,6,18,51 50

19,51 17,19,51
tert-Butylbenzene. 2,3,4,5,8,17,19, 1,2,4,5,8,10,11, 2,4,11,17,20, 1,2,6,22,51 50

20,21,22,23,24, 16,17,19,20,24, 21,22,24,25,51
25,26,51 25,51
l-Methyl-2-propylbenzene . . 9 27,28 9,28 9,50
l-Methyl-3-propylbenzene . . 9 27 9 9,27,50
l-Methyl-4-propylbenzene . . 3,29 3,27,29 3,9,29 3,29 9,27,50
l-Methyl-2-isppropylbenzene. 2,9,30 2,9,30 2,9,30 2 9,50
1-Methy1-3-Isopropylbenzene. 2,8,9,31,32 2,8,9,31,32 2,9,31,32 2 9,50
l-Methyl-4-lsppropylbenzene. 2,3,7,9,19.26. 2,9,14,19,26,27, 2,9,14,26,32, 2,7,32,51 9,50

32,33,34,35,36, 32,33,34,36,38, 33,34,36,51
37,38,51 39,51
1,2-Dlethylbenzene . 2,3,40,52,54 2,3,40,52 2,3,40,52 2,52 50
1,3-D1ethylbenzene . 2,3,41,42,53,54 2,3,4,41,42,53 2,3,41,42,53 2,3,53 50
1,4-Dlethylbenzene . 2,3,52,54 2,3,52 2,3,52 2,3 9,50
1,2-Dlmethy1-3-ethylbenzene. 2,3,4 2,3,4 2,3,4 2,3 50
1,2-Dimethy1-4-ethylbenzene. 2,4,43 2,4 2,4,43 2 50
1,3-Dinethy 1-2-ethylbenzene. 2,4 2,4,44 2,4 2 50
l,3-Dimethyl-4-ethylbenzene. 2,4 2,4,44 2,4 2 50
1,3-Dlmethyl-5-ethylbenzene. 2,4 2,4 2,4 2 50
1,4-Dlmethy1-2-ethylbenzene. 2,4 2,4,44 2,4 2 50
1,2,3,4-Tetramethylbenzene . 45,46 38,44,46,47 46 7,46,48 9,50
1,2,3,5-Tetramethylbenzene . 3,45,54 3,38,47 3 3,7.47,48 50
1,2,4,5-Tetramethylbenzene . 45 50 50 38,48,49 50
745211 0 - 47 - 28
SPECIFIC REFERENCES
FOR TABLES 14a, 14a-E, and 14b (Continued)
May 31, 1947
REFERENCES
1. Strelff, Murphy, Cahill, Flanagan, Sedlak, 28. Kuhn and Deutsch1
Willingham, and Rossini1 29. Schmidt and Schoeller1
2. Birch, Fldler, and Lowry1 30. Desseigne1

2
3. American Petroleum Institute Research Project 451 31. Lacourt
4. Forziatl and Rossini1 32. Richter and Wolff2
5. Smith and Pennekamp1 33. Welsh and Hennlon1
6. Glasgow, Murphy, Willingham, and Rossini1 34. Lacourt1
7. Huffman, Parks, and Barmore1 35. McVlcker, Marsh, and Stewart1
8. Turner and Lesslie1 36. Le Fevre, Le Fevre, and Robertson1
9, von Auwers2 37. Kobe, Okabe, Ramstad, and Huemmer1
10, Calingaert1 38. Smith and Pennekamp2
11. Hennlon and Auspos1 39. Schorgerl
12. Schmidt, Hopp, and Schoeller1 40. Fries and Bestlan1
13. Massart1 41. Copenhaven and Reid1
14. Perkins1 42. Ipatieff, Pines, and Komarewsky1
15. Zelinsky ana Gawerdowskaja1 43. Kruber1
16. Urry and Kharasch1 44. Smith and Kiess1
17. McKenna and Sowa1 45. MacDougall and Smith1
18. Timmermans2 46. Malr and Strelff1
19. Simon and Harti 47. Smith and Cass2
20. Grosse and Ipatieff1 48. Smith and MacDougall1
21. Richards and Shipley2 49. Fuson and McKusick1
22. Huffman, Parks, and Daniels1 50. American Petroleum Institute Research Project 441
23. de la Mare and Robertson1 51. Buess, Karabinos, Kunz, and Gibbons1
24. Smith, R.A.1 52. Karabinos, Seri Jan, and Gibbons1
25. Huston, Fox, and Binder1 53. Gibbons, Thompson, Reynolds, Wright, Chanan,
26. Hennlon and Kurtz1 Lambert 1, Hlpsher, and Karabinos1
27. von Auwers and Kolligs1 54. American Petroleum Institute Research Project 61
SPECIFIC REFERENCES
FOR TABLES 15a, 15a-E, and 15-b
May 31, 1947
REFERENCES FOR
Compound
Density Point Dispersion
Point Index
n-Propylcyclopentane . 1,3,4,5,6,8,11, 3,4,5,6,8,11, 1,3,4,6,16 1

11,12,15 12,13,15 12,13,14,15
Isopropylcyclopentane. 1,4,5,6,8,10,17 1,3,5,6,8,13,17 3,5,6,8,13,14, 1,3,4,6 13

17
l-Methyl-l-ethylcyclopentane.. 2,24 2,7,24 2 7 2
cls-l-L'ethyl-2-
ethylcyclopentane. 2,9,24 7,9,24 2,9 7,9 2,9
trans-l-I :ethyl-2-
ethylcyclopentane. 7,9,24 7,9,24 2,9 9
cls-l-Liethyl-3-
ethylcyclopentane. 2,18,19,24 7,18,24 2,18
trans-l-Methyl-3-
ethylcyclopentane. 7,24 7,24 2 7
1,1,2-Trlmethylcyclopentane. . 1,2,5,19,20,24 1,2,5,19,20,24 2,5,20 1,5
1,1,3-Trlmethylcyclopentane. . 1,2,4,5,21,22 1,2,4,5,21,22 2,4,5,21,22 1
els,els,cls-
1,2,3-Trimethylcyclopentane. 7,19,24 7,19,24 2,19 7
cls,cls,trans-
1,2,3-Trlmethylcyclopentane. 7,24 7,24 2 7
cls,trans,cls-
1,2,3-Trlmethylcyclopentane. 2,24 7,24 2 7
els,els,cls-
1,2,4—Trlmethylcyclopentane. 23 23 23
cls,cls,trans-
1,2,4-Tr lmethyleyelopentane. 1,2,24 1,2,24 O 1
els,trans,CIS-
1, 2,4-Trlmethyl cyclopentane. 1,2,24 1,2,24 2 1
1. Strelff, Murphy, Cahill, Flanagan, Sedlak, 12. Zelinsky, Kasansky, and Flate1
Willingham and Rossini1 13. Garrett1
2. Forzlatl and Rossini1 14. Geist and Cannon1
3. Forzlatl, Glasgav, Willingham, and Rcsslnl1 15. Turova-Follak and Polyakova1
4. American Petroleum Institute Research Project 451 16. Timmermans2 3 4 5 6 7 8 9 10 11
5. Birch, Fldler, and Lowry1 17. Kazansky and Tatevosyan1
6. Crane, Boord and Kenne1 18. Zelinsky1
7. Strelff, Murphy, Cahill, Soule, Sedlak, Willingham 19. Turner and Lesslle1
and Rossini1 20. Crossley and Renouf1
8. Pines arid Ipatieff1 21. McKinley, Stevens, and Baldwin1
9. Chlurdoglu2 22. Zelinsky and Uspensky1
10. Willingham, Taylor, 1 Ignccco, and F.osslr.l1 23. American F^troleum Institute Research Project 441
11. Chavanne and Becker1 24. Whitmore and others1
SPECIFIC REFERENCES
FOR TABLES 20c, 20C-E, and 20c-K
May 31, 1947
REFERENCES FOR REFERENCES FOR

Compound Compound
Viscosity Viscosity
Methane. n-Undecane. 1,4,15,17

Ethane . n-Dodecane. 1,4,17,21,22
Propane. 1,6,7,9 n-Trldecane . 1,15,21
n-Butane . 1,9 n-Tetradecane . 1,21,23
n-Pentane. n-Pentadecane . 1,21
n-Hexane . 1,2,3,4,12,13,19,20 n-Hexadecane. 1,21,22,23
n-Heptane. 1,2,3,4,5,12,16,18 n-Heptadecane . 1,15,21,24
n-Octane . . 1,2,3,4,13,14,15 n-Octadecane. 1,21,23,25
n-Nonane . n-Nonadecane. 1
n-Decane . n-Elcosane. 1,21
REFERENCES
1. American Petroleum Institute Research Project 441 14. Madge1 11

2. Gelst and Cannon1 15. Schmidt, Schoeller, and Eberleln1
3. Thorpe and Rodger1 16. Smyth and Stoops1
4. Shepard, Henne, and Mldgley1 17. Bingham and Fornwalt1
2
5. Timmermans and Hennaut-Roland 18. Lewis1
6. Gerf and Galkov1 19. Andrade and Rotherham1
7. Galkov and Gerf1 20. Drapler1
8. Gerf and Galkov2 21. American Petroleum Institute Research Project 421
9. Llpkin, Davison, and Kurtz1 22. Evans1
10. Bresler and Landerman1 23. Engler-Hofer1
11. Rudenko and Shubnlkov1 24. Karrer and Ferrl1
1
12. Khalilov2 25. Dover and Hensley
rz
13. Timmermans and Martin
National Bureau of Standards Washington, D f!
SPECIFIC REFERENCES
FOR TABLE lk
May 31 1947

Compound Compound
Vapor Pressures Vapor Pressures
and Bolling Points and Boiling Points
Methane . 1,2,3 2-Methylpropane . 1,8
Ethane... 1,4 n-Pentane . 9,12
Propane. 1,5 2-Methylbutane. 9,10
n-Butane. 1,7 2,2-Dlmethylpropane . 6,11
REFERENCES
2
1. Cragoe2 7. Aston and Messerly
2. Freeth and Verschoyle1 8. Aston, Kennedy, and Schumann1
3. Cluslus and Weigand1 9. Willingham, Taylor, Pignocco, and
4, Loomis and Walters1 10. Schumann, Aston, and Sagenkahn1
5. Kemp and Egan1 11. Benoliel1
6. Aston and Messerly1 12. Messerly and Kennedy1
SPECIFIC REFERENCES
FOR TABLE 2k (Part 1)
May 31, 1947
Compound Vapor Pressures Compound Vapor Pressures

and Bolling Points and Boiling Points
n-Hexane. 1 2,2-Dlmethylbutane. 1
2-Methylpentane. 1 2,3-Dlmethylbutane. 1
3-Methylpentane . 1
REFERENCES

National Bureau of Standards_ Waihington, D. C.
SPECIFIC REFERENCES
my 31, 1947

Compound Compound
and Boiling Points and Bolling Points
n-Heptane . 1,2,6 2,3-Dimethylpentane. 3,6
2-ITethyIhexane. 3,4,6 2,4-Dlmethylpentane . 3,4,6
3-Methylhexane. 3,4,6 3,3-Dlmethylpentane . 1,6
3-Ethylpentane. 3,5,6 2,2,3-Trimethylbutane. 3,5,6
2,2-Dlmethylpentane . 1,6
REFERENCES
1. Willingham, Taylor, Pignocco, and Rossini1 4. 'Callngaert and Thomson1

2. Smith, E.R.1 5. ' Smith, E.R.2
3. American Petroleum Institute Research Project 441 6. Callngaert1
SPECIFIC REFERENCES
FOR TABLE 3k
my 31, 1947

Compound Compound
n-Octane. 1 3,3-Dimethylhexane. 1
2-Methylheptane . 1 3,4-Dlmethy lhexane. 1
3-Methylheptane. 1 2-Methyl-3-ethylpentane . 1
4-Methylheptane . 1 3-Methyl-3-ethylpentane . 1
3-Ethylhexane. 1 2,2,3-Trlmethylpentane. 1
2,2-Dimethylhexane. 1 2,2,4-Trlmethylpentane. 1,2
2,3-Dlmethylhexane. 1 2,3,3-Trimethylpentane. 1
2,4-Dimethylhexane. 1 2,3,4-Trlmethylpentane. 1
2,5-Dimethylhexane. 1 2,2,3,3-Tetramethylbutane .... 3
REFERENCES

2. Smith, E.R.1
3. Callngaert, Soroos, Hnlzda, and Shapiro1
SPECIFIC REFERENCES
FOR TABLE 5k
May 31, 1947

Compound Compound
and Bolling Points and Bolling Points
Benzene . 1,2,3,4,5,6,7,8,9, Isopropylbenzene. 1,13

10
l-Methyl-2-ethylbenzene . 14
Methylbenzene . 1,2,3
1-Methy1-3-ethylbenzene . 14
Ethylbenzene. 1,5,11
1-Methy1-4-ethylbenzene . 14
1,2-Dlmethylbenzene . 1, , b, 12
1,2,3-Trimethylbenzene. 14,15
1,3-Dlmethylbenzene. 1,2,12
1,2,4-Trlmethylbenzene. 14,16
1,4-Dlmethylbenzene . 1,2,12
1,3,5-Trlmethylbenzene. 12,14
n-Propylbenzene . 1
REFERENCES
1. Willingham, Taylor, Plgnocco, and Rossini1 9. Flock, Glnnlngs, and Holton1

2. Pltzer and Scott1 10. Osborne and Winnings1
3. Thomson1 11. Guttman, Westrum, and Pltzer1
4. Smith, E.R.2 12. Kassel4
5. Stuckey and Saylor 13. Kobe, Okabe, Kanstad, and Huemmer1
6. Stull1 14. American Petroleum Institute Research Project 44
7. International Critical Tables 15. Smith and Splllane1
8. Huffman, Parks, and Daniels1 16. Smith and Lund1
SPECIFIC REFERENCES
FOR TABLE 6k
May 31 1947

Compound Compound
and Bolling Foints and Bolling Foints
1-
Cyclopentane. 1,2 Ethylcyclopentane . 4
MethyIcyclopentane. 1,3
REFERENCES
1. Willingham, Taylor, Plgnocco, and Rossini1 ' 3. Schmitt1

2. Aston, Fink, and Schumann1 4. American Petroleum Institute Research Project 44.
SPECIFIC REFERENCES
FOR TABLE 7k
Nay 31, 1947

Compound Vapor Pressures Compound Vapor Pressures
and Boiling Points and Boiling Points
Cyclohexane . 1,2,3,4 trans-l,2-Dimethylcyclohexane . . 1
Hethylcyclohexane . 1,6 cls-l,3-Dimethylcyclohexane . . . 1
Ethylcyclohexane. 1 trans-|l,3-Dlmethylcyclohexane . . 1
1,1-Dlmethylcyclohexane . 5,7 cis-l,4-Dlmethylcyclohexane . . . 1
cis-l,2-Dlmethylcyclohexane . . . 1 trans-l,4-Dlmethylcyclohexane . . 1
REFERENCES
1. Willingham, Taylor, Plgnocco, and Rossini1 5. American Petroleum Institute Research Project 44L
2. Scatchard, Wood, and Nochel1 6. Stuckey and Saylor1
1
3. Aston, Szasz, and Fink 7. Forziatl and Rossini1
1
4. International Critical Tables
SPECIFIC REFERENCES
Nay 31, 1947

Compound Compound
Ethene. 1,2,3 cls-2-Butene. 1,5,7
Propene . 1,4,5 trans-2-Butene. 1,5,7,8
1-Butene. 1,5,6 2-Nethylpropene . 1,5
REFERENCES
1. Cragoe2 5. Lamb and Roper1

2. Egan and Kemp1 6. Benollel
3. Henning and Stock1 7. Klstiakowsky, Ruhoff, Smith, and Vaughan1
4. Powell and Glauque1 8. Guttman and Pltzer1
SPECIFIC REFERENCES
FOR TABLE lm
May 31, 1947

Compound Compound
Heat of Vaporization Heat of Vaporization
Methane. 1,2 2-Methylpropane. 6,13,14
Ethane . 3 n-Pentane. 7,8,9,10,13
Propane. 4,13,14 2-Meth.vlbutane. 11,13
n-Butane . 5,13,14 2,2-Dlmethylpropane. . . . 12,13
REFERENCES
1. Frank and Clusius 8. Messerly and Kennedy1

2. Osborne and others 9. Pltzer5
3. Witt and Kemp'*' 10. Sage, Evans, and Lacey1
4. Kemp and Egan1 11. Schumann, Aston, and Sagenkahn1
2
5. Aston,and Messerly 12. Aston and Messerly1
6. Aston, Kennedy, and Schumann1 13. American Petroleum Institute Research Project 441
7. Osborne and Glnnings1 14. Dana, Jenkins, Burdick, and Timm1
SPECIFIC REFERENCES
FOR TABLE 2m
my 31, 1947

Compound Compound
n-Hexane . 1,2,3,4,9 3-Methylhexane . 9
2-Methylpentane. 1,3,5,9 3-Ethylpentane . 1,9
3-Methylpentane. 1,5,9 2,2-Dimethylpentane. . . . 1,9
2,2-Dimethylbutane .... 1,2,6,7,9 2,3-Dimet hylpentane. . . . 1,9
2,3-Dlmethylbutane .... 1,3,5,9 2,4-Dlmethylpentane. . . . 1,9
n-Heptane. 1,8,9,10 3,3-Dlmethylpentane. . . . 1,9
2-Methylhexane . 9 2,2,3-Trlmethylbutane. . . 1,9,10
REFERENCES
1. Osborne and Glnnings1 6. Pltzer

2. Waddlngton and Douslln1 7. Kilpatrick and Pltzer1
3. Lemons and Felsing1 8. Pltzer4
4. Mathews1 9. American Petroleum Institute Research Project 44
5. Huffman and others1 10. Waddlngton, Todd,and Huffman1
SPECIFIC REFERENCES
FOR TABLE 3m
Fay 31, 1947
REFERENCES FOR references' FOR

Compound Compound
n-Gctane . 1,5 3,3-Dlmethylhexane .... 1,5
2-Methylheptane. 1,5 3,4-Dlmethylhexane .... 1,5
Z-Methylheptane. , . . . . 1,5 2-Methyl-3-ethylpentane. . 1,5
4-Methylheptane. 1,2,5 3-Methyl-3-ethylpentane. . 1,5
3-Ethylhexane. 1,5 2,2,3-Trlmethylpentane . . 1,5
2,2-L)lmethyIhexane .... 1,5 2,2,4-Trlmethylpentane . . 1,3,5
2,3-Dlmethylhexane .... 1,5 2,3,3-Trlmethylpentane . . 1,5
2,4-Dlmethylhexane . . . . 1,5 2,3,4-Trlmethylpentane . . 1,4,5
2,S-Dlmetlxylhexane . . . . 1,5 2,2,3,3-Tetranethylbutane. 5
REFERENCES
1
1. Osborne and Glnnlngs 4. Pltzer and Scott1
2. Mathews 5. Ape rican Petroleum Institute Research Project 441
3. PI tzer4
National bureau of Standards Washington, D. C.
3FECIFIC REFERENCES
1
FOR TABLE 4m
Hay 31, 1947

Compound Compound
n-Nonane.. 1,2 3-Hethyl-4-ethylhexane. . . 2
2-Methyloctane . 2 2,2,3-Trlmethylhexano . . . 2
3-Methyloctane . 2 2,2,4-Trlmethylhexane . . . 2
4-Hethyloctane . 2 2,2,5-Trlmethylhexane . . . 1,2
3-Ethylheptane. 2 2,3,3-Trlmethylhexane . . . 2
4-Ethylheptane . 2 2,3,4-Trlmethylhexane . . . 2
2,2-Bimethyiheptane. . . . 2 2,3,5-Trlmethylhexane . . . 1,2
2,3-Dlmethylheptane. . . . 2 2,4,4-Trimethylhexane . . . 2
2,4-Dimethylheptane. . . . 2 3,3,4-Trimethylhexane . . . 2
2,5-Dlmethylheptane. . . . 2 3,3-Diethylpencane. 2
2,6-Dlmethylheptane. . . . 2 2,2-Dlmethyl-3-ethylpentane 2
3,3-Dimethylheptane. . . . 2 2,3-Dimethyl-3-ethylpentane 2
3,4-Dlmethylheptane. . . . 2,4-Dimethyl-3-ethylpentane 2
2
3,5-Dlmethylheptane. . . . 2 2,2,3,3-Tetramethylpentane. 2
4,4-Dlmethylheptane. . . . 2 2,2,3,4-Tet ramet hy Ip ent ane. 2
2-Hethyl-3-ethylhexane . . 2 2,2,4,4-Tetramet hylp ent ane. 2
2-Nethyl-4-ethylhexane . . 2 2,3,3,4-Tet r aniet hy lpe nt an e. 2
3-Hethyl-2-ethylhexane . . 2
REFERENCES
1. Osborne and Glnnings1

2. American Petroleum Institute Research Project 44
SPECIFIC REFERENCES
FOR TABLE 5m
May 31, 1947

Compound Compound
Benzene . 1,2,3,4,5,8 Isopropylbenzene. 1,8
Methylbenzene . 1,4,5,8 1-Methy1-2-ethylbenzene .... 8
Ethylbenzene. 1,4,6,8 1-Methy1-3-ethylbenzene .... 8
1,2-Dlmethylbenzene . 1,4,7,8 1-Methy1-4-ethylbenzene .... 8
1,3-Dimethylbenzene . 1,4,7,8 1,2,3-Trimethylbenzene. 1,8
1,4-Dlmethylbenzene . 1,4,7,8 1,2,4-Trlmethylbenzene. 1,8
n-Propylbenzene . 1,8 1,3,5-Trlmethylbenzene. 1,8
REFERENCES
1. Osborne and Glnnlngs1 5. Kolossovsky and Theodorowltsch1

2. Waddlngton and Douslin1 6. Scott and Brlckwedde1
3. Flock, Glnnlngs, and Holton1 7. Pitzer and Scott2
4. Mathews1 8. American Petroleum Institute Research Project 441
SPECIFIC REFERENCES
FOR TABLE 6m
my 31, 1947

Compound Compound
Cyclopentane. 1.2.3.5 cls-l,2-Dlmethylcyclopentane. . 5
Methylcyclopentane. 4.5 trans-l,2-Dlmethylcyclopentane. 5
Ethylcyclopentane . 5 cls-l,3-Dlmethylcyclopentane. .
1,1-Dlmethylcyclopentane. . . 5 trans-l,3-Dlmethylcyclopentane. 5
REFERENCES
1. Aston, Fink, and Schumann1 4. Osborne and Glnnlngs1

2. Spltzer and Pitzer1 5. American Petroleum Institute Research Project 441
3. Huffman and others1
SPECIFIC REFERENCES
FOR TABLE 7m
my 31, 1947

Compound Compound
Cyclohexane. 1,2,3,4,5 trans-1,2-Dlmet hylcyclohexane. 1,5
Methylcyclohexane. 1,2,4,5 cis-l,3-Dimethylcyclohexane. • 1,5
Ethylcyclohexane . 1,5 trans-1,3-Dlmet hylcyclohexane. 1,5
1,1-Dlmethylcyclohexane. . . . 5 cls-l,4-Dlmethylcyclohexane. . 1,5
c1s-1,2-Dlmethylcyclohexane. . 1,5 trans-l,4-Dlmethylcyclohexane. 1,5
REFERENCES
1. Osborne and GInnings1 4. Mathews1

2. Spltzer and PItzer 5. American Petroleum Institute Research Project 44
3. Aston, Szasz, and Fink
SPECIFIC REFERENCES
FOR TABLE 8m (Part 1)
May 31, 1947

Compound Compound
Ethene . 1 cls-2-Butene . 4,7
Propane. 2 trans-2-Butene . 5,7
1-Butene . 3,7 2-Methylpropene. 6,7
REFERENCES
1. Egan and Kemp1 5. Guttman and PItzer1

2. Powell and Glauque1 6. Rands,■ Scott, and Brlckwedde1
_ _ w
3. Aston, Fink, Bestul, Pace, and Szasz 7. American Petroleum Institute Research Project
4. Scott, Ferguson, and Brlckwedde1
SPECIFIC REFERENCES
FOR THE "n" TABLES
May 31, 1947
The values of the heats of combustion, -aHc°, at 25°C, In the n tables are calculated from the
selected values of the standard heats of formation, AHf°, at 25°C, for the hydrocarbons and for
carbon dioxide (C0g) and water (HgO), as given In the p tables. The specific references for the p
tables are given In the appropriate place In tills section. The specific references for those n tables
for which trie corresponding p tables have not yet been Issued are as follows: Table 9n, Prosen and
Rossini13; Tables 22n and 23n, Prosen, Johnson, and Rossini^.
SELECTED VALUES OF PROPERTIES QF HYDROCARBONS 433
SPECIFIC REFERENCES
FOR TABLE Op
May 31, 1947
REFERENCES FOR
Compound Formula
Heat of Entropy Free Energy
Formation of Formation
At 25°C
Oxygen. °2 3 1 2
Hydrogen. 3 1 2
Water. H20 3,6 1,6 2,6

Nitrogen. n2 3 1 2
Carbon (graphite) . c 3,4,5 1 2
Carbon Monoxide . CO 3,6 1,6 2,6

Carbon dioxide. co2 3,4,5,6 1,6 2,6
REFERENCES
1. See references given for the "t" table.

2. See references given for the "x" table.
3. Wagman, Kilpatrick, Taylor, Pltzer, and Rossini
4. Prosen, Jessup, and Rossini1
5. Prosen and Rossini1''
6. National Bureau of Standards1-
SPECIFIC REFERENCES
FOR TABLE lp
Nay 31, 1947
REFERENCES FOR
Compound Heat of Entropy Free Energy of

Formation Formation
At 25°C
Nethane. 3,4,5,6,15 1 2
Ethane . 3,4,5,6,15 1 2
Propane. 3,4,5,6,15 1 2
n-Butane . 3,4,5,6,15 1 2
2-He thylpropane. 3,4,5,6,9,10,11,12 1 2
n-Pentane. 3,4,5,6,8,15 1 2
2-Methylbutane . 3,4,5,6,7,13,14 1 2
2,2-Dlme thylpropane. 3,4,5,6,7,9,10,11,12 1 2
REFERENCES
1. See references p-lven for the "t" table.

3. Rossini4
4. Rossini8
5. Rossini18
6. Rossini81
7. Knowlton and Rossini1 11
4
8. Prosen and Rossini
9. Thomsen1
10. Thomsen2
11. Thomsen
12. Thomsen4
13. Roth and Macheleldt1
14. Roth and PahIke1
15. Prosen and Rossini8
SPECIFIC REFERENCES
FOR TABLE 2p
May 31, 1947
REFERENCES FOR
Compound Heat of Entropy Free Energy of

Formation Formation
At 25°C
n-Hexane. 3,5,6,10,11,13 1 2
2-Methylpentane . 3 1 2
3-Methylpentane .'. 3 1 2
2,2-Dlme thylbutane. 3 1 2
2,3-Dlmethylbutane. 3,4,12 1 2
n-Heptane . 4,5,6,7,8,9,13 1 2
2-Me thylhexane. 4,7,8 1 2
3-Methylhexane. 4,7,8 1 2
3-Ethylpentane. 4,7,8 1 2
2,2-Dlmethylpentane . 4,7,8 1 2
2,3-Dlmethylpentane . 4,7,8 1 2
2,4-Dimenthylpentane. 4,7,8 1 2
3,3-Dimethylpentane . 4,7,8 1 2
2,2,3-Trimethylbutane . 4,7,8 1 2
REFERENCES
2. see references given for the "x" table.
6. Jessup1
7. Jessup4
8. Davies and Gilbert1
9. Louguinine1
10. Stohmann, Kleber, and Langbeln3
11. Zubow1
12. Thomsen4
13. Prosen and Rossini®
745211 0 - 47 - 29
SPECIFIC REFERENCES
FOR TABLE 3p
May 31, 1947
REFERENCES FOR
Compound Keat of Entropy Free Energy of

Formation Formation
At 25°C
n-Octane. 3,4,5,6,7,8,9 1 2
2-Methylheptane.. 5,7 1 2
3-Methylheptane . . 5 1 2
4-Methylheptane . 5 1 2
3-Ethylhexane . ..... 5,7 1 2

2,2-Dimethylhexane. 5 1 2
2,3-Dimethylhexane. ....... . 5 1 2
2,4-Dlme thylhexane. 5 1 2
2,5-Dlmethylhexane. ... . 5,7 1 2
3,3-Dlme thylhexane. 5 1 2
3,4-Dimethylhexane. . . . . 5,7 1 2
2-Methyl-3-ethylpentane . 5 1 2
3-Me thyl-3-e thylpentane. 5 1 2
2,2,3-Trlmethylpentane. 5 1 2
2,2,4-Trlmethylpentane. 5,8 1 2
2,3,3-Trlmethylpentane. 5 1 2
2,3,4-Trime thylpentane. 5 1 2
2,2,3,3-Tetramethylbutane . . . 5,8 1 2
REFERENCES
2. see references given for the "x" table.
3. Jessup1
4. Prosen and Rossini4 5 6
5. Prosen and Rossini7 8 9
6. Zubow1
7. Richards and Jesse1 3
8. Jessup4
9. Banse and Parks1
SPECIFIC REFERENCES
FOR TABLE 5p
May 31, 1947
REFERENCES FOR
Compound Heat of Free Energy of

Entropy
Formation Formation
At 25°C
Benzene. 3,4,6,7,8,9,10,11,12,13, 1 2
14,15,16
Methylbenzene. 3,4,12,13,14,17,18,19 1 2
Ethylbenzene . 3,4,13,20,21,22 1 2
1,2-DlmethyIbe nzene. 3,4,13,17 1 2
1,3-Dlme thylbenzene. 3,4,11,12,17 1 2
1,4-Dlme thylbenzene. 3,4,11,17 1 2
n-Propylbenzene. 3,4,5,13,23,24 1 2
Isopropylbenzene . , . 3,5,13,23,24 1 2
1-Methyl-2-ethylbenzene. 3,5 i 2
l-Methyl-3-ethylbenzene. 3,5 l 2
1-Me thyl-4-ethylbenzene. 3,5 l 2
1,2,3-Trlmethylbenzene . 3,5 l 2
1,2,4-Trlmethylbenzene . 3,5,13 i 2
1,3,5-Trlmethylbenzene . 3,5,13,17 l 2
REFERENCES

3. Prosen, Johnson, and Rossini1 11
4. Prosen, Gllmont, and Rossini1
5. Johnson, Prosen, and Rossini1
6. Berthelot1
7. Stohmann, Rodatz, and Herzberg1
9. Richards, Henderson, and Frevert1
10. Richards, Henderson, and Frevert2
11. Richards and Jesse1
12. Roth and von Auwers1
13. Richards and Barry1
14. Richards and Davis2
15. Berthelot3
16. Thomsen4
17. Stohmann, Rodatz, and Herzberg2
18. Schmldlln1
19. Richards and Davis1
20. Jesse1
21. Moureu and Andre'1
22. von Auwers and Kolllgs2
23. Oenvresse1
SPECIFIC REFERENCES
FOR TABLE 8p (Part 1)
May 31, 1947
REFERENCES for
Heat of Entropy Free Energy of

Conpound Formation Formation
At 25°C
Ethene... 3,4,8,9,11,13,15 1 2
Propene. 3,5,8,9,11,13 1 2
1-Butene . 3,5 1 2
cls-2-Butene ..... . 3,5 1 2

trans-2-Butene... 3,5 1 2
2-Methylpropene... 3,5,10,11,12,13 1 2
1-Pentene. 3 1 2
cls-2-Pentene. . 3 1 2
trans-2-Pentene. 3 1 2
2-Msthyl-l-butene.. . . . . 3,6 1 2
3-Methy1-1-butene. 3,7 1 2
2-Methyl-2-but ene. 3,6,10,11,12,13,14 1 2
REFERENCES
1. See references riven for the "t" table.

3. Prosen and Rossini^
4. Klstlakowsky, Romeyn, Ruhoff, Smith, and Vaughan1 11
5. Klstlakowsky, Ruhoff, Smith, and Vaurhan1
6. Klstlakowsky, Ruhof?, Smith, and Vaughan2
7. Dolllver, Gresham, Klstlakowsky, and Vaughan1
8. Berthelot and Matlgnon1
9. Rossini and Knowlton1
10. Thomsen1
11. Thomsen2
12. Thomsen3
13. Thomsen4
14. Zubow1
15. Mlxter1
SPECIFIC REFERENCES
FOR TABLE 8p (Part 2)
Nay 31, 1947
REFERENCES FOR

Compound Formation Formation
At 25°C
1-Hexene . . 3 1 2
cls-2-Hexene . 3 1 2
trans-2-Hexene . 3 1 2
cls-3-Hexene . 3 1 2
trans-3-Hexene . 3 1 2
2-Nethyl-l-pentene . 3 1 2
3-Nethyl-l-pentene. 3 1 2
4-Nethyl-l-pentene... 3 1 2
2-Methyl-2-pentene . 3 1 2
cls-3-Methyl-2-pentene . 3 1 2
trans-3-Nethyl-2-pentene . 3 1 2
cls-4-Methyl-2-pentene . 3 1 2
trans-4-Nethyl-2-pentene . 3 1 2
2-Ethyl-l-butene . 3 1 2
2,3-Dlmethyl-l-butene. 3,4 1 2
3,3-Dlmethy1-1-butene. 3,4 1 2
2,3-Dlmethy1-2-butene. 3,4 1 2
REFERENCES

4. Klstlakov/sky, Ruhoff, Smith, and Vaughan1 2 3 4
SPECIFIC REFERENCES
FOR TABLE 12p
May 31, 1947
REFERENCES FOR

At 25°C
Ethyne . 3,4,5,6,7,8,9,10,11 1 2
Propyne. 3,11 1 2
1-Butyne. 3,11 1 2
2-Butyne . 3,11 1 2
1-Pentyne. 3,11 1 2
2-Pentyne. 3,11 1 2
3-Methyl-l-butyne. 3,11 1 2
REFERENCES

4. Berthelot1 2
5. Thomsen1
6. Thomsen2
7. Thomsen3
8. Thomsen4 5 6 7 8 9 10 11
9. Berthelot and Matlgnon1
10. Mlxter2
11. Wagman, Kilpatrick, Pltzer, and Rossini1
SPECIFIC REFERENCES
FOR TABLE 20p
Nay 31, 1947
REFERENCES FOR

At 25°C
Methane. 3,4,5,6,8 1 2
Ethane . 3,4,5,6,8 1 2
Propane. 3,4,5,6,8 1 2
n-Butane . 3,4,5,0,8 1 2
n-Pentane. 3,4,5,6,7,8 1 2
n-Hexane . 7,8,9,10,11,12 1 2
n-Heptane. 7,8,9,15,14,15 1 2
n-Octane . 7,8,9,12,13,16,17,18 1 2
n-Nonane . 7,8,9 1 2
n-Decane . 7,8,9 1 2
n-Undecane . 8,9 1 2
n-Dodecane . .7,8,9 1 2
n-Trldecane. 8 1 2
n-Tetradecane. 8 1 2
n-Pentadecane. 8 1 2
n-Hexadecane . 7,8,19 1 2
n-Heptadecane. 8 1 2
n-Octadecane . 8 1 2
n-Nonadecane . 8 1 2
n-Eicosane . 8 1 2
REFERENCES

3. Rossini4
4. Rossini8
5. Rossini18
6. Rossini21
9. Jessup1 11
12. Zubow1
13. Jessup4
14 . Davies and Gilbert1
15. Louguinlne1
17. Richards and Jesse1
18. Banse and Parks1
19. Richardson and Parks'^
National Bureau of Standards_Washington, D. C.
SPECIFIC REFERENCES
FOR TABLE 21p
Nay 31, 1947
REFERENCES FOR

Compound Format Ion Formation
At 25°C
Benzene. 3,4 1 2
Hethylbenzene. 3,4 1 2
Ethylbenzene . 3,4 1 2
n-Pr opylbenzene. 3,4 1 2
n-Butylbenzene . 3 1 2
n-Amylbenzene.'. 3 1 2
n-Hexylbenzene . 3 1 2
n-Heptylbenzene. 3 ■J 2
n-Octylbenzene . 3 1 2
n-Nonylbenzene . . . 3 1 2
n-Decylbenzene . .... . 3 1 2
n-Undecylbenzene . 3 1 2
n-Dodecylbenzene . 3 1 2
n-Trldecylbenzene.. . 3 ■ 1 2
n-Tetradecylbenzene... 3 1 2
n-Pentadecylbenzene. 3 1 2
n-Hexadecylbenzene . . 3 1 2
REFERENCES

3. Prosen, Johnson, and RosslnlJ
4. For additional references, see references for Table 5p.
American Petroleum Institute Research Project 44 •
SPECIFIC REFERENCES
FOR TABLE 24p
Nay 31, 1947
REFERENCES FOR

Compound Formation Entropy Formation
At 25°C
Ethene. 3,4 1 2
Propene. 3,4 1 2
1-Butene., . . . . 3,4 1 2
1-Pentene. 3 1 2
1-Hexene . 3 1 2
1-Kept ene. 3,5 1 2
1-Octene. 3 1 2
1-Nonene . 3 1 2
1-Decene . 3 1 2
1-Undecene . 3 1 2
1-Dodecene . 3 1 2
1-Trldecene. 3 1 2
1-Tetradecene. 3 1 2
1-Pentadecene. 3 1 2
1-Hexadecene . 3 1 2
1-Heptadecene. 3 1 2
1-Octadecene . 3 1 2
1-Nonadecene . 3 1 2
1-Elcosene.... 3 1 2
REFERENCES
1. See references given for the " t" table.

2. See references given for the " x" table.
4. For additional references, see references for Table 8p (Part 1).
5. Klstiakowsky, Ruhoff, Smith, and Vaughan1 2 3 4 5
SPECIFIC REFERENCES
FOR TABLE 25p
May 31, 1947
REFERENCES FOR

Compound Formation Entropy Formation
At 25°C
Ethyne. 3 1 2
Propyne. 3 1 2
1-Butyne . 3 1 2
1-Pentyne. 3 1 2
1-Hexyne . 3 1 2
1-Heptyne. 3,4 1 2
1-Octyne . 3 1 2
1-Nonyne . 3 1 2
1-Decyne . 3 1 2
1-Undecyne.. 3 1 2
1-Dodecyne . 3 1 2
1-Trldecyne. 3 1 2
1-Tetradecyne. 3 1 2
1-Pentadecyne. 3 1 2
1-Hexadecyne . 3 1 2
1-Heptadecyne. 3 1 2
1-Octadecyne . . 3 1 2
1-Nonadecyne .. 3 1 2
l-Elcosyne . 3 1 2
REFERENCES
1. See references given for the »»t*’ table.

2. See references given for the " x" table.
3. Prosen and Rossini-1 2 3 4 5-0
4. Moureau and Andre1
5. For additional references, see references for Table 12p.
SPECIFIC REFERENCES
FOR THE "q" TABLES
(Applicable as to the date of Issue of the numerical table)
May 31, 1947
The values of the standard heat of vaporization, aHv°, standard entropy of vaporization, aSv°,
and standard free energy of vaporization, aFv°, all at 25°C, given In the q tables are calculated from
the values of the heats of vaporization, aHv, at saturation pressure and 25°C, given In the corres¬
ponding m tables, the values of the vapor pressures'at 25°C derived from the corresponding 1c tables,
and unpublished calculations of the American Petroleum Institute Research Project 44 1. The
specific references for the k and m tables are given In the appropriate places In this section.
446
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National Bureau of Standards1
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SPECIFIC REFERENCES
FOR TABLE lz
May 31, 1947
REFERENCES FOR
Compound
Freezing Point Heat of Fusion Cryoscopic Constants
Methane. 1,16,20 1 15
Ethane . 2,3,16 2,3 15
Propane. 4,20 4 15
n-Butane . 5,6,17 5,6 15
2-Methylpropane. 7,8,17 7,8 15
n-Pentane. 9,10,18,20 9,10 15
2-Methylbutane . 11,12,13,18,19,20 11,12,13 15
2,2-Dime thylpropane. 14,19,20 14 15
REFERENCES
1. Clusius1 12. Guthrie and Huffman1

2. Witt and Kemp1 13. Parks, Huffman, and Thomas1
3. Wlebe, Hubbard, and Brevoort1 14. Aston and Messerly1
4. Kemp and Egan1 15. American Petroleum Institute Research Project 441
2
5. Aston and Messerly 16. Clusius and Weigand1
6. Huffman, Parks, and Barmore1 17. Glasgow and Rossini1
7. Parks, Shomate, Kennedy, and Crawford1 18. Glasgow, Murphy, Willingham, and Rossini1
8. Aston, Kennedy, and Schumann1 19. Howard, Mears, Fookson, Pomerantz, and Brooks1
9. Messerly and Kennedy1 20. For additional references, see references to
10. Parks and Huffman1 Table la.
11. Schumann, Aston, and Sagenkahn1
SPECIFIC REFERENCES
FOR TABLE 2z (Part 1)
May 31, 1947
REFERENCES FOR
Compound
Freezing Point Heat of Fusion Cryoscoplc Constants
n-Hexane . 1,2,3,4,6,9 1,2,3,4 8

2-Me thylpentane. 1,4,6,7 1,4 8
3-Methylpentane.
2,2-Dlmethylbutane . 1,4,5,6,7,9 1,4,5 8
2,3-Dlmethylbutane . 1,6,9 1 8
REFERENCES
1. Douslln and Huffman** 6. Glasgow, Murphy, Willingham, and Rossini1 2 3 4 5

2. Huffman, Parks, and Barnore1 7. Howard, Mears, Fookson, Pomerantz, and Brooks1
3. Parks, Huffman, and Thomas-*- 8. American Petroleum Institute Research Project 441
4. Stull1 9. For additional references, see references to
5. Kilpatrick and Pltzer1 Table 2a (Fart 1).
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
n-Heptane. 1,2,4,6,7,9 1,2 8

2-Methylnexane. 1,5,7,9 1 8
3 Methylhexane .
3-Ethylpentane . 3,5,6 3 8
2,2-Dime thylpentarie. 3,5,7,9 3 8
2,3 Dime thylpentane.

2,4-Dimethylpentane. 3,5,7,9 3 8
3,3-Dime thylpentane. 3,5,7,9 3 8
2,2,3-Trimethylbutane. 3,4,6,7,9 3 8
REFERENCES
p
1. Farks, Huffman, and Thomas1 6. Brooks, Howard, and Craft on
2. Pltzer4 5 7. Edgar and Calingaert1 2 3
3. Huffman, Farks, and Thomas1 8. American Petroleum Institute Research Project 441
4. Glasgow, Murphy, Willingham, and Rossini1 9. For additional reference, see references to
5. Streiff, Murphy, Sedlak, Willingham, and Rossini1 Table 2a (Part 2).
SPECIFIC REFERENCES
FOR TABLE 3z
May 31, 1947
REFERENCES FOR
Compound
n-Octane . 1,2,3,8 1,2 7
2-Methylheptane. 3 7 3
3-Methylheptane. 3 7 3
4-Methylheptane. 3,8 7 3
3-Ethylhexane.
2,2-Dimethylhexane . 3 7 3
2,3-Dimethylhexane .
2,5-Dimethylhexane . 3 7 3
3,3 Dimeth.vlhexane. 3 7 7
2-Methyl-3-ethylpentane. 3,8 7 3
3-Methyl-3-ethylpentane. 3,8 7 3
2,2,3-Trlmethylpentane. 3,8 7 3
2,2,4-Trimethylpentane . 1,4,8,9 1 7
2,3,3-Trimethylpentane . 3 7 3
2,3,4-Trimethylpentane . 3,5,9 5 7
2,2,3,3-Tetramethylbutane. . . . 6,10 6 7
REFERENCES
1. Parks, Huffman, and Thomas1 7. American Fetroleum Institute Research Project 44''-
2. Huffman, Parks, and Barmore1 3 8. For additional references, see references to
3. Strelff, Murphy, Sedlak, Willingham, and Rosslni1 Table 3a.
p
4. Pltzer4 5 6 9. Brooks, Howard, and Craft on
5. Pltzer and Scott-'- 10. Calingaert, Soroos, Hnlzda, and Shaplro1
6. Parks and Huffman^
745211 0 - 47 - 31
SPECIFIC REFERENCES
for table 5z'
May 31, 1947
REFERENCES FOR
Compound
Benzene. 1,2,3,12,13 1,2,3 11

Methylbenzene. 2,3,4,12,13 2,3,4 11
Ethylbenzene . 1,5,6,12,13 1,5,6 11
1,2-Dimethylbenzene. . . . 1,7,12,13 1.7 11
1,3-Dimethylbenzene. . . . 1,7,12,13 1,7 11
1,4-Dimethylbenzene. . . . 1,7,12,13 1,7 11
n-Propylbenzene.. 8,13 8
Isopropylbenzene . 12,13 11
1-Methy1-2-ethylbenzene. . 8,13 8
I-Methyl-3-ethylbenzene. . 8,13 8
1-Methy1-4-ethylbenzene. . 8,13 8
1,2,3-Trimethylbenzene . . 8,9,13 9 8
1,2,4-Trlmethylbenzene . . 8,9,10,13 9,10 8
1,3,5-Trimethylbenzene . . 8,9,13 9 11
REFERENCES
Huffman, Parks, and Daniels1 8 Streiff, Murphy, Sedlak, Willingham, and Rossini1
Stull1 9 Rossini12
Ziegler and Andrews1 10 Huffman, Parks, and Barmore1
Kelley1 11 American Petroleum Institute Research Project 441
Guthrie, Spitzer, and Huffman1 12 Glasgow, Murphy, Willingham, and Rossini1
Scott and Brickwedde1 13 For additional references, see references to
Fitzer and Scott2 Table 5a.
SPECIFIC REFERENCES
FOR TABLE 6z
May 31, 1947
REFERENCES FOR
Compound
Cyclopentane . 1,2,3,5,9 1,2,3 8

Mathylcyclopentane . 3,4,5,9 3,4 8
Ethylcyclopentane. 5,6,7,9 6 7
1,1-Dimethylcyclopentane .... 7,9 7
cis-l,2-Dimethylcyclopentane . . 7,9 7
trans-1,2-Dimethylcyclopentane . 4,7,9 4 8
cis-1,3-Dimethylcyclopentane . .
trans-1,3~Dimethylcyclopentane . 7,9 7
REFERENCES
1. -Jacobs and Parks1 7. Strelff, Murphy, Cahill, Flanagan, Sedlak,

2. Aston, Fink, and Schunann1 Willingham, and Rossini1
3. Douslin and Huffman1 8. American Petroleum Institute Research Project 441
4. Huffman, Parks, and Barmore1 9. For additional references, see references to
5. Glasgow, Murphy, Willingham, and Rossini1 Table 6a.
745211 0 - 47 - 32
SPECIFIC REFERENCES
FOR TABLE 7z
May 31, 1947
REFERENCES FOR
Compound
Cyclohexane. 1,2,3,4,8,12 1,2,3,4 11

Methylcyclohexane. 5,6,8 5,6 11
Ethylcyclohexane . 7,8,9 7 9
1,1-Dime thylcyclohexane. 7,9,12 7 9
cls-l,2-Dimethylcyclohexane. . . 7,9,12 7 9
trans-l,2-Dimethylcyclohexane. . 7,9,12 7 9
cls-l,3-Dlmethylcyclohexane. . . 7,10,12 7 10
trans-l,3-Dimethylcyclohexane. . 7,10,12 7 10
cis-l,4-Dlmethylcyclohexane. • • 7,9,12 7 9
trans-l,4-Dlmethylcyclohexane- • 7,9,12 7 9
REFERENCES
1. Parks, Huffman, and Thomas1 8 Glasgow, Murphy, Willingham, and Rossini1 2 3 4 5 6 7

2. Ziegler and Andrews1 9 Streiff, Murphy, Cahill, Flanagan, Sedlak,
3. Aston, Szasz, and Flnk1 Willingham, and Rossini1
4. Ruehrweln and Huffman1 10 Streiff, Murphy, Cahill, Soule, Sedlak,
5. Parks and Huffman1 Willingham and Rossini1
6. Douslln and Huffman1 11 American Petroleum Institute Research Project 441
7. Huffman and others1 12 For additional references, see references to
Table 7a.
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
Freezing Point Heat or Fusion Cryoscoplc Constants
Ethene . 1,2 1,2 1C

Propene.. 3,4 3,4 10
1-Butene . 5 5 10
cis-2-Butene . 6,7,11 6,7 10
trans-2-Butene. 6,8,11 6,8 10
2-Methylpropene. 6,9,11 6,9 10
REFERENCES
1. Egan and Kemp1 7. Scott, Ferguson, and Brickwedde1 2 3 4 5 6

2. Eucken and Hauck1 8. Guttman and Pltzer1
3. Huffman, Parks, and Barmore1 9. Rands, Scott, and Brickwedde1
4. Powell and Glauque1 10. American Fetroleum Institute Research Project 441
5. Aston, Fink, Bestul, Pace, and Szasz1 11. For additional references, see references to
6. Todd and Parks1 Table 8a (Part 1).
SPECIFIC REFERENCES
May 31, 1947
REFERENCES FOR
Compound
1-Pentene. 1,2 1 2
cis-2-Pentene. 1,2,5 1 2
trans-2-Pentene. 1,2,5 1 2
2-Methy1-1-butene. 1,2,5 1 2
3-Methyl-l-butene. 1,2,5 1 2
2-Methyl-2-butene. 1,2,3,5 1,3 4
REFERENCES
1. Todd, Oliver, and Huffman1

2. Streiff, Murphy, Sedlak, Willingham, and Rossini1
3. Parks and Huffman1
4. American Petroleum Institute Research Project 441
5. For additional references, see references to Table 8a (Part 1).
V. GENERAL LIST OF REFERENCES
A Baxter, Guichard, and Whytlaw-Gray:

Ahlberg, Blanchard, and Lundberg: 1. J. Am. Chem. Soc. 69, 731 (1947).
1. J. Chem. Phys. 5, 539 (1937). Bazhulin, Bokshtein, Liberman, Lukina, Margolis, Solo-
Allen and Bell: vova, and Kazanskii:
1. Organic Synthesis 22, 39 (1942). 1. Bull. acad. sci. U. R. S. S. 198 No. 3 (1943).
American Petroleum Institute Research Project 6, Beckett, Pitzer and Spitzer:
National Bureau of Standards, Washington, 1. J. Am. Chem. Soc. 69, 000 (1947).
D. C., F. D. Rossini: Bekhedahl, Wood, and Wojciechowski:
1. Unpublished data. 1. J. Research Natl. Bur. Standards 17, 883 (1936).
American Petroleum Institute Research Project 42, Bennewitz and Rossner:
1. Z. physik. Chem. B39, 126 (1938).
Pennsylvania State College, State College, Penn¬
sylvania, F. C. Whitmore: Benoliel:
1. Unpublished data. 1. Thesis, Pennsylvania State College (1941).
American Petroleum Institute Research Project 44, Na¬ Berger:
tional Bureau of Standards, Washington, D. C., 1. Rec. trav. chem. 57,1029 (1938).
F. D. Rossini: Berthelot:
1. Unpublished calculations and correlations. 1. Ann. chim. phys. 13, 1 (1878).
American Petroleum Institute Research Project 45, Ohio 2. Ann. chim. phys. 23, 176 (1881).
State University, Columbus, Ohio, C. E. Boord: 3. Ann. chim. phys. 23, 193 (1881).
1. Unpublished data. Berthelot and Matignon:
Andrade and Rotherham: 1. Ann. chim. phys. 30, 547 (1893).
1. Proc. Phys. Soc. (London) 48, 261 (1936). Bettendorff and Wullner:
Appleby, Dobratz, and Kapranos: 1. Ann. Physik 133, 293 (1868).
1. J. Am. Chem. Soc. 66, 1938 (1944). Bichowsky and Rossini:
Arbuzov and Zelinski: 1. “The Thermochemistry of Chemical Substances,”
1. Compt. rend. acad. sci. U. R. S. S. 30, 721 (1941). Reinhold Publishing Corporation, New York,
Ashdown, Harris, and Armstrong: N. Y (1936).
1. J. Am. Chem. Soc. 58, 850 (1936). Bingham and Fomwalt:
Aston, Fink, Bestul, Pace, and Szasz: 1. J. Rheology 1, 372 (1930).
1. J. Am. Chem. Soc. 68, 52 (1946). Birch, Fidler, and Lowry:
Aston, Fink, and Schumann: 1. Unpublished data, Anglo Iranian Oil Co., Ltd., Sun-
1. J. Am. Chem. Soc. 65, 341 (1943). bury, England.
Aston, Kennedy, and Schumann: Birge:
1. J. Am. Chem. Soc. 62, 2059 (1940). 1. Rev. Modern Phys. 1, 1 (1929).
Aston and Messerly: 2. Rev. Modem Phys. 13, 233 (1941).
1. J. Am. Chem. Soc. 58, 2354 (1936). Blaise and Montagne:
2. J. Am. Chem. Soc. 62, 1917 (1940). 1. Compt. rend. 181, 122 (1925).
Aston, Szasz, and Fink: Bouis:
1. J. Am. Chem. Soc. 65, 1135, 2481 (1943). 1. Ann. Chim. 9, 402 (1928).
Aston, Szasz, Woolley, and Brickwedde: Bourgel:
1. J. Chem. Phys. 14, 67 (1946). 1. Compt. rend. 176, 751 (1923).
von Auwers: Bresler and Landerman:
1. Ber. 51, 1126 (1918). 1. J. Exptl. Theoret. Phys. (U.S.S.R.) 10, 250 (1940).
2. Ann. 419, 92 (1919). Brockway and Cross:
von Auwers and Eisenlohr: 1. J. Am. Chem. Soc. 58, 2407 (1936).
1. J. prakt. chem. 82, 65 (1910). Brooks:
von Auwers and Kolligs: 1. J. Research Natl. Bur. Standards 21, 847 (1938).
1. Ber. 55, 21 (1922). Brooks, Cleaton, and Carter:
2. Ber. 55, 3872 (1922). 1. J. Research Natl. Bur. Standards 19, 319 (1937).
von Auwers and Muller: Brooks, Howard, and Crafton:
1. Ber. 44, 1606 (1911). 1. J. Research Natl. Bur. Standards 23, 637 (1939).
von Auwers, Roth, and Eisenlohr: 2. J, Research Natl. Bur. Standards 24, 33 (1940).
1. Liebigs Ann. Chem. 373, 267 (1910). Brooks, Howard, and others:
2. Liebigs Ann. Chem. 385, 102 (1911). 1. Unpublished data, Section on Automotive Power
von Auwers and Westerman: Plants, National Bureau of Standards, Washing¬
1. Ber. 54, 2993 (1921). ton D. C.
Brooks and Humphrey:
1. J. Am. Chem. Soc. 40, 822 (1918).
B Bruun and Faulconer:
Bachman and Goebel: 1. Ind. Eng. Chem. Anal. Ed. 9, 192 (1937).
1. J. Am. Chem. Soc. 64, 787 (1942). Bruun and Hicks-Bruun:
Badger: 1. J. Research Natl. Bur. Standards 5, 933 (1930).
1. J. Chem. Phys. 2, 128 (1934). 2. J. Research Natl. Bur. Standards 10, 465 (1933),
2. J. Chem. Phys. 3, 710 (1935). Bruun, Hicks-Bruun, and Faulconer:
Badger and Bauer: 1. J. Am. Chem. Soc. 59, 2355 (1937).
1. J. Chem. Phys. 5, 599 (1937). Buck:
Badger and Woo: 1. Unpublished data. Shell Development Co., Emery¬
1. J. Am. Chem. Soc. 54, 3523 (1932). ville, Calif.
Banse and Parks: Buess, Karabinos, Kunz, and Gibbons:
1. J. Am. Chem. Soc. 55, 3223 (1933). 1. Technical Note No. 1021, National Advisory Com¬
Barbandy: mittee for Aeronautics, Aircraft Engine Research
1. Bull. soc. chim. 39, 371 (1926). Laboratory, Cleveland, Ohio.
Baxter, Guichard, Honigschmid, and Whytlaw-Gray: Burcik, Eyster, and Yost:
1. J. Am. Chem. Soc. 63, 845 (1941). 1. J. Chem. Phys. 9, 118 (1941).
473
474
Burgess: Copenhaver and Reid:

1. J. Research Natl. Bur. Standards 1, 635 (1928). 1. J. Am. Chem. Soc. 49, 3157 (1927).
Burlew: Cortese *
1. J. Am. Chern. Soc. 62, 690 (1940). 1. J. Am. Chem. Soc. 51, 2266 (1929).
Burrell and Robertson: Cotton and Mouton:
1. J. Am. Chem. Soc. 37, 2482 (1915). 1. Ann. chim. phys. 28, 209 (1913).
Butler: Cragoe:
1. Thesis, Ohio State University (1941). 1. National Bureau of Standards Letter Circular LC-
736 (1943).
2. Unpublished data, National Bureau of Standards,
c Washington, D. C.
Calingaert: 3. J. Research Natl. Bur. Standards 26, 495 (1941).
1. Unpublished data, Ethyl Corporation, Detroit, Mich. Cragoe and Peffer:
Calingaert and Thomson: 1. Unpublished data, National Bureau of Standards,
1. Unpublished data, Ethyl Corporation, Detroit, Mich. Washington, D. C.
Calingaert, Soroos, Hnizda, and Shapiro: Craig:
1. J. Am. Chem. Soc. 66, 1389 (1944). 1. J. Am. Chem. Soc. 65,1006 (1943).
Campbell and Eby: Cramer and Glasebrook:
1. J. Am. Chem. Soc. 63, 216 (1941). 1. J. Am. Chem. Soc. 61, 230 (1939).
2. J. Am. Chem. Soc. 63, 2683 (1941). Cramer and Mulligan:
Campbell and McDermott: 1. J. Am. Chem. Soc. 58, 373 (1936).
1. J. Am. Chem. Soc. 67, 282 (1945).
Campbell and O’Connor: 1. Thesis, Ohio State University (1941).
1. J. Am. Chem. Soc. 61, 2897 (1939). Crane, Boord, and Henne:
Campbell and Young: 1. J. Am. Chem. Soc. 67,1237 (1945).
1. J. Am. Chem. Soc. 65, 965 (1943). Crawford:
Carr and Walter: 1. J. Chem. Phys. 7, 555 (1939).
1. J. Chem. Phys. 4, 756 (1936). 2. J. Chem. Phys. 8, 526 (1940).
Chapas: Crawford, Kistiakowsky, Rice, Wells, and Wilson:
1. Thesis, Paris (1932). 1. J. Am. Chem. Soc. 61, 2980 (1939).
Chavanne: Crittenden:
1. Bull. soc. chim. Belg. 35, 283 (1926). 1. Unpublished data, National Bureau of Standards,
2. Bull. soc. chim. Belg. 39, 402 (1930). Washington, D. C.
Chavanne and Becker: Crossley and Renouf:
1. Bull. soc. chim. Belg. 36, 591 (1927). 1. J. Chem. Soc. 89, 26 (1906).
Chavanne, Katzenstein, and Pahlavouni: Curtis:
1. Bull. soc. chim. Belg. 41, 209 (1932). 1. J. Research Natl. Bur. Standards 33, 235 (1944).
Chavanne and Lejeune: Curtis, Moon, and Sparks:
Chavanne and Miller:
1. Bull. soc. chim. Belg. 39, 287 (1930).
Chavanne, Miller, and Cornet:
1. Bull. soc. chim. Belg. 40, 673 (1931). D
Chavanne and van Risseghem: Dailey and Felsing:
1. Bull. soc. chim. Belg. 31, 87 (1922). 1. J. Am. Chem. Soc. 65, 42 (1943).
Chiurdoglu: 2. J. Am. Chem. Soc. 65, 44 (1943).
1. Bull. soc. chim. Belg. 47, 363 (1938). Dana, Jenkins, Burdick, and Timm:
2. Bull. soc. chim. Belg. 53, 45 (1944). 1. Refrig. Eng. 12,387 (1926).
Church, Whitmore, and McGrew: Davies and Gilbert:
1. J. Am. Chem. Soc. 56,182 (1934). 1. J, Am. Chem. Soc. 63, 2730 (1941).
Clark and Biggs: Davis and Johnston:
2. J. Am. Chem. Soc. 34,60 (1912). Deanesly and Carleton:
Clark and Jones: 1. J. Phys. Chem. 45,1104 (1941).
1. J. Am. Chem. Soc. 34,171 (1912). 2. J. Research Natl. Bur. Standards 21, 375 (1938).
Clayton and Giauque: 3. J.Wash. Acad. Sci. 29,313 (1939).
1. J. Am. Chem. Soc. 55, 5071 (1933). Desseigne i
Cleveland: 1. Compt. rend. 200, 466 11935).
1. J. Chem. Phys. 11,1 (1943). Deux:
2. J. Chem. Phys. 11, 227 (1943). 1. Compt. rend. 208, 523 (1939).
Cleveland and Murray: 2. Compt. rend. 208, 528 (1939).
1. J. Chem. Phys. 10,174 (1942). Dewey and Harper:
Cline: 1. J. Research Natl. Bur. Standards 21, 457 (1938).
1. Thesis, Ohio State University (1940). Dietrich:
Clusius: 1. Thesis, Ohio State University (1933).
1. Z. physik. Chem. B3, 41 (1929). Dolliver, Gresham, Kistiakowsky, and Vaughan:
Clusius and Weigand: 1. J. Am. Chem. Soc. 59, 831 (1937).
1. Z. physik. Chem. B46,1 (1940). Dornte and Smyth:
Coe and Godfrey: 1. J. Am. Chem. Soc. 52, 3546 (1930).
1. J. Applied Phys. 15, 625 (1944). Doss:
Coffin and Maass: 1. “Physical Constants of the Principal Hydrocar¬
1. J. Am. Chem. Soc. 50,1427 (1928). bons,” 3d and 4th Editions, The Texas Co., New
2. J. Am. Chem. Soc. 50, 1433 (1928). York, N. Y.
3. Trans. Roy. Soc. Can. 21, 33 (1928). Douslin and Huffman:
Colonge: 1. J. Am. Chem. Soc. 68,173 (1946).
1. Bull. soc. chim. 9, 730 (1942). 2. J. Am. Chem. Soc. 68,1704 (1946).
Conn, Kistiakowsky, and Smith: Dover and Hensley:
1. J. Am. Chem. Soc. 61,1868 (1939). 1. Ind. Eng. Chem. 27, 337 (1935).
475
Drapier: Fiock. Ginnings, and Holton:

1. Bull. acad. sci. Belg., 630 (1911). 1. J. Research Natl. Bur. Standards 6, 881 (1931).
Dreisbach: Fisher and Chittenden:
1. Unpublished data, Dow Chemical Co., Midland, 1. Ind. Eng. Chem. 22, 869 (1930).
Mich. Fomin and Sochanski:
Dupont: 1. Ber. 46, 244 (1913).
1. Compt. rend. 118,1522 (1909). Forziati, Glasgow, Willingham, and Rossini:
Dwyer and Oldenberg: 1. J. Research Natl. Bur. Standards 36, 129 (1946).
1. J. Chem. Phys. 12, 351 (1944). Forziati, Mair, and Rossini:
Dykstra, Lewis, and Boord: 1. J. Research Natl. Bur. Standards 35, 513 (1945).
1. J. Am. Chem. Soc. 52, 3398 (1930). Forziati and Rossini:
1. Unpublished data, American Petroleum Institute
E Research Project 6, National Bureau of Stand¬
ards, Washington, D. C.
Ebersole: Francis:
1. Technical Note No. 1020, National Advisory Com¬ 1. Ind. Eng. Chem. 35, 442 (1943).
mittee for Aeronautics, Washington, D. C. Francis and Robbins:
Eckman and Rossini: 1. J. Am. Chem. Soc. 55, 4339 (1933).
1. J. Research Natl. Bur. Standards 3, 597 (1929). Frank and Clusius:
Edgar and Calingaert: 1. Z. physik. Chem. B36, 291 (1937).
1. J. Am. Chem. Soc. 51,1540 (1929). 2. Z. physik. Chem. B42, 395 (1939).
Edgar, Calingaert, and Marker: Frank-Kamenetzky and Markovich:
1. J. Am. Chem. Soc. 51,1483 (1929). 1. Acta Physicochim. U.R.S.S. 17, 308 (1942).
Egan and Kemp: Freeth and Verschoyle:
1. J. Am. Chem. Soc. 59,1264 (1937). 1. Proc. Roy. Soc. (London) A130, 453 (1931).
Egloff: Frey and Huppke:
1. “Physical Constants of Hydrocarbons,” Vol. I, 1. Ind. Eng. Chem. 25, 54 (1933).
“Paraffins, Olefins, Acetylenes, and Other Ali¬ Fries and Bestian:
phatic Hydrocarbons,” Reinhold Publishing Cor¬ 1. Ber. 69B, 715 (1936).
poration, New York, N. Y. (1939). von Fuchs and Anderson:
2. “Physical Constants of Hydrocarbons,” Vol. II, 1. Ind. Eng. Chem. 29, 319 (1937).
“Cyclanes, Cyclenes, Cyclynes, and Other Ali- Fuson and McKusick:
cyclic Hydrocarbons,” Reinhold Publishing Cor¬ 1. J. Am. Chem. Soc. 65, 62 (1943).
poration, New York, N. Y. (1940).
3. “Physical Constants of Hydrocarbons,” Vol. Ill,
“Mononuclear Aromatic Hydrocarbons,” Rein¬ G
hold Publishing Corporation, New York, N. Y.
(1946). Galkov and Gerf:
4. “Physical Constants of Hydrocarbons,” Vol. IV, 1. J. Tech. Phys. (U.S.S.R.) 11, 613 (1941).
“Polynuclear Aromatic Hydrocarbons,” Rein¬ Galloway and Barker:
hold Publishing Corporation, New York, N. Y. 1. J. Chem. Phys. 10, 88 (1942).
(1947). Gamer, Adams, and Stuchell:
Engler-Hofer: 1. Petroleum Refiner 21, 321 (1942).
1. Das Erdol 1, 53 (Berlin, 1913). Garrett:
Enklaar: 1. Unpublished data, Ohio State University, Colum¬
1. Rec. trav. chim. 36, 215 (1916). bus, Ohio.
2. Rec. trav. chim. 36, 247 (1916). Geist:
Enyeart: 1. Thesis, Pennsylvania State College (1942).
1. Pennsylvania State College, Abs. Doc. Diss. 5, 201 Geist and Cannon:
(1942). 1. Ind. Eng. Chem. Anal. Ed. 18, 611 (1946).
Eucken and Fried:
1. Physik 29, 41 (1924). 1. Bull. soc. chim. 9, 219 (1893).
Eucken and Hauck: Gerf and Galkov:
1. Z. physik. Chem. 134,161 (1928). 1. J. Tech. Phys. (U.S.S.R.) 10, 725 (1940).
Eucken and Karwot: 2. J. Tech. Phys. (U.S.S.R.) 11, 801 (1941).
1. Z. physik. Chem. 112, 467 (1924). Giauque:
Eucken and Liide: 1. J. Am. Chem. Soc. 52, 4816 (1930).
1. Z. physik. Chem. B5, 413 (1929). Giauque and Ashley:
Eucken and Sarstedt: 1. Phys. Rev. 43, 81 (1933).
1. Z. physik. Chem. B50, 143 (1941). Giauque and Clayton:
Eucken and Weigert: 1. J. Am. Chem. Soc. 55, 4875 (1933).
1. Z. Physik. Chem. B5, 265 (1933). Giauque and Egan:
Evans: 1. J. Chem. Phys. 5, 45 (1937).
1. J. Inst. Petroleum Tech. 24, 38 (1938). Gibbons, Thompson, Reynolds, Wright, Chanan, Lam-
2. J. Inst. Petroleum Tech. 24, 321 (1938). berti, Hipsher, and Karabinos:
Ewell and Hardy: 1. J. Am. Chem. Soc. 68,1130 (1946).
1. J. Am. Chem. Soc. 63, 3460 (1941). Gibson:
Evkman: 1. Thesis, Ohio State University (1938).
1. Chem. Zentr. II, 1205 (1907). Glasebrook and Lovell:
2. Recherches Refractometriques (1919). 1. J. Am. Chem. Soc. 61,1717 (1939).
Glasgow:
1. J. Research Natl. Bur. Standards 24, 509 (1940).
F Glasgow and Rossini:
Farmer and Warren: 1. Unpublished data, National Bureau of Standards,
1. J. Chem. Soc. 3221 (1931). Washington, D. C.
Favorski and Zalusky-Kibardine: Glasgow, Murphy, Willingham, and Rossini:
1. Bull. soc. chim. 37, 1227 (1925). 1. J. Research Nat. Bur. Standards 37, 141 (1946).
Fenske, Quiggle, and Tongberg: Glasgow, Streiff, and Rossini:
1. Ind. Eng. Chem. 24, 408 (1932). 1. J. Research Natl. Bur. Standards 35, 355 (1945).
476
Glazebrook: Herington:
1. Unpublished data, Hercules Powder Co., Wilming¬ 1. Faraday Soc. Trans. 40, 481 (1944).
ton, Del. Herzberg:
Glenn: 1. “Infrared and Raman Spectra of Polyatomic Mol¬
1. Thesis, Pennsylvania State College (1941). ecules,” D. Van Nostrand Co., New York, N. Y.
Goldfinger, Josefowitz, and Mark: (1945).
1. J. Am. Chem. Soc. 65, 1432 (1943). Herzberg, Patat, and Verleger:
Gordon: 1. J. Phys. Chem. 41, 123 (1937).
1. J. Chem. Phys. 1, 308 (1933). Heuse:
2. J. Chem. Phys. 2, 65 (1934). 1. Ann. Phys. 59, 86 (1919).
3. J. Chem. Phys. 2, 549 (1934). Hicks-Bruun and Bruun:
4. J. Chem. Phys. 6, 219 (1938). 1. J. Am. Chem. Soc. 58, 810 (1936).
Gordon and Barnes: Hicks-Bruun, Bruun, and Faulconer:
1. J. Phys. Chem. 36, 1143 (1932). 1. J. Am. Chem. Soc. 61, 3100 (1939).
2. J. Chem. Phys. 1, 297 (1933). Hischler and Faulconer:
de Graef: 1. J. Am. Chem. Soc. 68, 210 (1946).
1. Bull. soc. chim. Belg. 40, 315 (1931). Horney:
Gredy: 1. Thesis, Ohio State University (1937).
1. Bull. soc. chim. 2, 1029 (1935). Horton:
2. Bull. soc. chim. 2,1951 (1935). 1. J. Am. Chem. Soc. 69, 182 (1947).
Greenlee i Howard:
1. Thesis, Ohio State University (1942). 1. J. Research Natl. Bur. Standards 24, 677 (1940).
Griswold and Ludwig: Howard, Mears, Fookson, Pomerantz, and Brooks:
1. Ind. Eng. Chem. 35, 117 (1943). 1. J. Research Natl. Bur. Standards 38, 365 (1947).
Griswold, van Berg, and Kasch: Hiickel and Rossmann:
1. Ind. Eng. Chem. 35, 854 (1943). 1. J. prakt. chem. 136, 30 (1933).
Grosse and Ipatieff: Huffman and others:
1. J. Am. Chem. Soc. 57, 2415 (1935). 1. Unpublished data, U. S. Bureau of Mines, Bartles¬
Grosse and Wackher: ville, Okla.
1. Ind. Eng. Chem. Anal. Ed. 11, 614 (1939). Huffman, Parks, and Barmore:
Guthrie and Huffman: 1. J. Am. Chem. Soc. 53, 3876 (1931).
1. J. Am. Chem. Soc. 65, 1139 (1943). Huffman, Parks, and Daniels:
Guthrie, Spitzer, and Huffman: 1. J. Am. Chem. Soc. 52, 1547 (1930).
1. J. Am. Chem. Soc. 66, 2120 (1944). Huffman, Parks, and Thomas:
Guttman: 1. J. Am. Chem. Soc. 52, 3241 (1930).
1. Thesis, University of California (1943). Hull:
Guttman and Pitzer: 1. Thesis, Ohio State University (1935).
1. J. Am. Chem. Soc. 67, 324 (1945). Hurd and Meinert:
Guttman, Westrum, and Pitzer: 1. J. Am. Chem. Soc. 53, 289 (1931).
1. J. Am. Chem. Soc. 65, 1246 (1943). Huston, Fox, and Binder:
1. J. Org. Chem. 3, 251 (1938).
I
H International Critical Tables:
Hammond and McArdle: 1. Ill, 208, 262, 263.
1. Ind. Eng. Chem. 35, 809 (1943). 2. V, 10.
Harries: Ipatieff, Pines, and Komarewsky:
1. Ann. 390, 265 (1912). 1. Ind. Eng. Chem. 28, 222 (1936).
Harries and Duvel:
1. Ber. 410, 54 (1915). I
Hartick and Edse: Jacobs and Parks:
1. Z. physik. Chem. A182, 220 (1938). 1. J. Am. Chem. Soc. 56,1513 (1934).
Heisig:
1. J. Am. Chem. Soc. 53, 3245 (1931). 1. j. Am. Chem. Soc. 34,1337 (1912).
Heisig and Davis: Jessup:
1. J. Am. Chem. Soc. 57, 339 (1935). 1. J. Research Natl. Bur. Standards, 18, 115 (1937).
Heisig and Hurd: 2. J. Research Natl. Bur. Standards, 21, 475 (1938).
1. J. Am. Chem. Soc. 55, 3485 (1933). 3. J. Research Natl. Bur. Standards, 29, 247 (1942).
Henne and Chanan: 4. Unpublished data, National Bureau of Standards,
1. J. Am. Chem. Soc. 66, 395 (1944). Washington, D. C.
Henne, Chanan, and Turk: Jessup and Green:
1. J. Am. Chem. Soc. 63, 3474 (1941). 1. J. Research Natl. Bur. Standards 13, 469 (1934).
Henne and Greenlee: Johnson, Prosen, and Rossini:
Henne and Matuszak: 2. J. Research Natl. Bur. Standards 36, 463 (1946).
Henne and Turk: 4. J. Research Natl. Bur. Standards 39, 000 (1947).
1. J. Am. Chem. Soc. 64, 826 (1942). Johnston and Chapman:
Henning and Stock: 1. J. Am. Chem. Soc. 55,153 (1933).
1. Z. Physik 4, 226 (1921). Johnston and Davis:
Hennion and Auspos: 1. J. Am. Chem. Soc. 56, 271, (1934).
1. J. Am. Chem. Soc. 65,1603 (1943). Johnston and Dawson:
Hennion and Kurtz: 1. J. Am. Chem. Soc. 55, 2744 (1933).
1. J. Am. Chem. Soc. 65,1001 (1943). Johnston, Dawson, and Walker:
Henry: 1. Phys. Rev. 43, 473 (1933).
1. Compt. rend. 142,1075 (1906). Johnston and Walker:
Henshall: 1. J. Am. Chem. Soc. 55, 172 (1933).
1. J. Soc. Chem. Ind. 62,127 (1943). 2. J. Am. Chem. Soc. 57, 682 (1935).
477
E Krapiwin:
1. Bull. soc. naturalistes, Moscow 22, 134 (1918).
Ivarabinos, Serijan, and Gibbons:
Krieger and Wenzke:
1. J. Am. Chem. Soc. 68, 2107 (1946).
1. J. Am. Chem. Soc. 60, 2115 (1938).
Karrer and Ferri: Kruber:
1. Helv. Chim. Acta 17, 358 (1934). 1. Ber. 57, 1008 (1924).
Ivasscl * Kuhn and Deutsch:
1. J. Chem. Phys. 1, 576 (1933). 1. Ber. 65, 43 (1932).
2. J. Am. Chem. Soc. 55, 1351 (1933). Kuykendall:
3. J. Am. Chem. Soc. 56, 1838 (1934). 1. Thesis, Ohio State University (1935).
4. J. Am. Chem. Soc. 58, 670 (1936).
Kay: L
1. Unpublished data, Standard Oil Co. (Indiana), Lacourt:
Whiting, Ind. 1. Bull. soc. chim. Belg. 38, 1 (1929).
Kazanskii and Tatevosyan: 2. Bull. soc. chim. Belg. 39, 132 (1930).
1. J. Gen. Chem. (U.S.S.R.) 9, 2248 (1939). Lamb and Roper:
van Keersbilck: 1. J. Am. Chem. Soc. 62, 806 (1940).
1. Bull. soc. chim. Belg. 38, 205 (1929). Lamberti, Reynolds, and Chanan:
Keffler: 1. Technical Note No. 1163, National Advisory Com¬
1. J. Am. Chem. Soc. 56, 1259 (1934). mittee for Aeronautics, Washington, D. C.
Kelley: Landolt-Bornstein-Roth:
1. J. Am. Chem. Soc. 51, 2738 (1929). 1. “Physikalisch-Chemische Tabellen”, 4th ed., Ber¬
Kemp and Egan: lin (1923).
1. J. Am. Chem. Soc. 60, 1521 (1938). Landrieu, Baylocq, and Johnson:
Kennedy, Shomate, and Parks: 1. Bull. soc. chim. 45, 36 (1929).
r 1. J. Am. Chem. Soc. 60, 1507 (1938). Lauer and Stadola:
Keyes, Taylor, and Smith: 1. J. Am. Chem. Soc. 56, 1215 (1934).
1. J. Math. Phys. 1, 211 (1922). Laughlin, Nash, and Whitmore:
Khalilov: 1. J. Am. Chem. Soc. 56,1395 (1934).
1. J. Tech. Phys. (U.S.S.R.) 8, 1249 (1938). Leendertse, Tulleners, and Waterman:
2. J. Exptl. Theoret. Phys. (U.S.S.R.) 9, 335 (1939). 1. Rec. trav. chim. 52, 515 (1933).
Kilpatrick and Pitzer: Le Fevre, Le Fevre, and Robertson:
1. J. Am. Chem. Soc. 68, 1066 (1946). 1. J. Chem. Soc. 480 (1935).
2. J. Research Natl. Bur. Standards 37, 163 (1946).’ Lemons and Felsing:
Kilpatrick, Prosen, Pitzer, and Rossini: 1. J. Am. Chem. Soc. 65, 46 (1943).
1. J. Research Natl. Bur. Standards 36, 559 (1946). Lemoult:
Kilpatrick, Spitzer, and Pitzer: 1. Compt. rend. 152, 1402 (1911).
1. J. Am. Chem. Soc. 69, (1947). Lespieau and Chavanne:
Kishner: 1. Compt. rend. 140, 1035 (1905).
1. J. Soc. Chim. St. Petersburg 37, 514 (1905). Levina:
2. J. Soc. Chim. St. Petersburg 40, 995 (1908). 1. J. Gen. Chem. (U.S.S.R.) 9, 2287 (1939).
3. Chem. Zentr. 2, 2132 (1913). Levina and Kagan:
1. J. Gen. Chem. (U.S.S.R.) 11, 523 (1941).
Kistiakowsky:
Lewis:
1. J. Am. Chem. Soc. 58, 766 (1936).
1. J. Am. Chem. Soc. 47, 626 (1925).
Kistiakowsky, Lacher, and Ransom: Lewis and von Elbe:
1. J. Chem. Phys. 8, 970 (1940). 1. J. Am. Chem. Soc. 57, 2737 (1935).
Kistiakowsky and Nickle: 2. J. Chem. Phys. 3, 63 (1935).
1. J. Chem. Phys. 10, 78 (1942). Lewis and Randall:
2. J. Chem. Phys. 10, 146 (1942). 1. “Thermodynamics and the Free Energy of Chem¬
Kistiakowsky and Rice: ical Substances ” McGraw-Hill Book Co., Inc.,
1. J. Chem. Phys. 8, 610 (1940). New York, N. Y. (1923).
2. J. Chem. Phys. 8, 618 (1940). Libby:
Kistiakowsky, Romeyn, Ruhoff, Smith, and Vaughan: 1. J. Chem. Phys. 11, 101 (1943).
1. J. Am. Chem. Soc. 57, 65 (1935). Liberman, Lukina, Solovova, and Kazanskii:
Kistiakowsky, Ruhoff, Smith, and Vaughan: 1. Compt. rend. acad. sci. U.R.S.S. 40, 70 (1943).
1. J. Am. Chem. Soc. 57, 876 (1935). Lipkin, Davison, and Kurtz:
2. J. Am. Chem. Soc, 58, 137 (1936). 1. Ind. Eng. Chem. 34, 976 (1942).
3. J. Am. Chem. Soc. 58, 146 (1936). Livingston and Heisig:
Klages: 1. J. Am. Chem. Soc. 52, 2409 (1930).
1. Ber. 35 (1902). Loomis and Walters:
Knowlton and Rossini: 1. J. Am. Chem. Soc. 48, 2051 (1926).
1. J. Research Natl. Bur. Standards 22, 415 (1939). Louguinine:
Kobe, Okabe, Ramstad, and Huemmer: 1. Compt. rend. 93, 274 (1881).
1. J. Am. Chem. Soc. 63, 3251 (1941). Lowry and Allsopp:
1. Proc. Roy. Soc. A113, 26 (1931).
Ivogerman:
Lucas and Dillon:
1. J. Am. Chem. Soc. 52, 5060 (1930).
1 J. Am. Chem. Soc. 50, 1460 (1928).
Kohlrausch and Koppl: Lucas, Dillon, and Young:
1. Z. physik. Chem. B26, 209 (1934). 1. J. Am. Chem. Soc. 52, 1949 (1930).
Kohlrausch and Stockmair: Lucas and Prater:
_ 1. Z. physik. Chem. B29, 296 (1935). 1. J. Am. Chem. Soc. 59, 1682 (1937).
Kolossovsky and Theodorowitsch: Luschinsky:
1. Bull. soc. chim. 2, 692 (1935). 1. Z. physik. Chem. A182, 384 (1938).
Komarewsky and Kritchevsky:
1. J. Am. Chem. Soc. 65, 547 (1943). M
Korschung: MacDougall and Smith:
1. Naturwissenschaften 31, 384 (1943). 1. J. Am. Chem. Soc. 52; 1998 (1930).
478
McArdle and Robertson: Mixter:

1. Ind. Eng. Chem., Anal. Ed. 15, 484 (1943). 1. Am. J. Sci. 12, 347 (1901).
McKenna and Sowa: 2. Am. J. Sci. 22,13 (1906) .
1. J. Am. Chem Soc. 59, 470 (1937). Mizusima, Morino, and Huzisino:
McKinley, Stevens, and Baldwin: 1. J. Chem. Soc. Japan 62, 587 (1941).
1. J. Am. Chem. Soc. 67, 1455 (1945). Moersch:
McVicker, Marsh, and Stewart: 1. Pennsylvania State College, Abs. Doc. Diss. 5, 301
1. J. Chem. Soc. 125, 1743 (1924). (1942).
Maass and Russell: Moldavskii and Nizovkina:
1. J. Am. Chem. Soc. 40,1561 (1918). 1. J. Gen. Chem. (U.S.S.R.) 9, 1652 (1939).
Maass and Wright: 2. J. Gen. Chem. (U.S.S.R.) 10,1183 (1940).
1. J. Am. Chem. Soc. 43, 1098 (1921). Montgomery:
Madge: 1. Unpublished data, Gulf Research & Development
1. J. Phys. Chem. 34, 1599 (1930). Co., Pittsburgh, Pa.
Madorsky and Wood: Montgomery, McAteer, and Franke:
1. Unpublished data, National Bureau of Standards, 1. J. Am. Chem. Soc. 59, 1768 (1937).
Washington, D. C. 2. Paper presented before the Division of Petroleum
Maess and von Muffling: Chemistry, American Chemical Society, Balti¬
1. Angew. Chem. 50, 759 (1937). more, Md., April 1939.
Magnus: Montgomery, McAteer, and Horne:
1. Ann. Physik 48, 983 (1915). 1. Unpublished data, Gulf Research & Development
2. Ann. Physik 70, 303 (1923). Co., Pittsburgh, Pa.
Magnus and Hodler: Montgomery and de Vries:
1. Ann. Physik 80, 808 (1926). 1. J. Am. Chem. Soc. 64, 2375 (1942).
Mair: Moore, Renquist, and Parks:
Mair, Glasgow, and Rossini: Morehouse and Maass:
1. J. Research Natl. Bur. Standards 26, 591 (1941). 1. Can. J. Research 5, 306 (1931).
2. J. Research Natl. Bur. Standards 27, 39 (1941). 2. Can. J. Research 11, 637 (1934).
Mair and Schicktanz: Morgan, Carter, and Duck:
1. J. Research Natl. Bur. Standards 11, 665 (1933). 1. J. Chem. Soc. 127, 1252 (1925).
Mair and Streiff: Moureau and Andre:
1. J. Research Natl. Bur. Standards 27, 343 (1941). 1. Ann. chim. 1, 113 (1914).
Mair and White: Mousseron and Granger:
1. J. Research Natl. Bur. Standards 15, 51, (1935). 1. Bull. soc. chim. Belg. 5, 1618 (1938).
Marker and Oakwood: Mueller:
1. J. Am. Chem. Soc. 60, 2598 (1938). 1. “Temperature, its Measurement and Control in
MessefI * Science and Industry”, p. 162-179, Reinhold Pub¬
1. Bull. soc. chim. Belg. 45, 76 (1936). lishing Corp., New York, N. Y. (1941).
de la Mare: Mueller and Rossini:
1. J. Chem. Soc. 279 (1943). 1. Am. J. Physics 12, 1 (1944).
Martin: Mueller and Stimson:
Mathews: Mulliken, Wakeman, and Gerry:
Mathus and Gibon:
1. Bull. soc. chim. Belg. 34, 303 (1925). N
Mavity:
Nasarov:
1. Thesis, Ohio State University (1931).
1. Ber. 70B, 606 (1937).
Mayer and Mayer: National Bureau of Standards:
1. “Statistical Mechanics,” John Wiley & Sons, New 1. Selected Values of Chemical Thermodynamic Prop¬
York, N. Y. (1940). erties. Unpublished.
Mecke and Ziegler: 2. Miscellaneous Publication M121, “Units of weight
1. Z. Physik 101, 405 (1936). and measure; definitions and tables of equiva¬
Meinert and Hurd: lents.”
1. J. Am. Chem. Soc. 52, 4544 (1930). Technical Committee, Natural Gasoline Association of
Merling: AmencE *
1. Ann. 264, 310 (1891). 1. Ind. Eng. Chem. 34, 1240 (1942).
Meshcheryakov: Nemst:
1. Bull. acad. sci. U.R.S.S., No. 1 (1941). 1. Ann. Physik 36, 395 (1911).
Messerly and Kennedy: Nernst and Lindemann:
1. J. Am. Chem. Soc. 62, 2988 (1940). 1. Z. Elektrochem. 17, 817 (1911).
Meyers, Scott, Brickwedde, and Rands: Noller:
Washington, D. C. Norris and Reuter:
Michael and Weiner: 1. J. Am. Chem. Soc. 49, 2624 (1927).
1. J. Org. Chem. 4, 531 (1939).
Midgley and Henne: o
1. J. Am. Chem. Soc. 51, 1215 (1929). Oberreit:
Millar: 1. Ber. 29, 1998 (1896).
1. J. Am. Chem. Soc. 45, 874 (1923). Oliver, Todd, and Huffman:
Miller: 1. J. Am. Chem. Soc. 69, 000 (1947).
1. Bull. soc. chim. Belg. 41, 217 (1932). Osborne, Garner, and Yost:
2. Bull. soc. chim. Belg. 42, 238 (1933). 1. J. Am. Chem. Soc. 63, 3492 (1941).
3. Bull. soc. chim. Belg. 44, 513 (1935). Osborne and Ginnings:
Miller and Piaux: 1. Unpublished data, National Bureau of Standards,
1. Compt. rend. 197, 412 (1933). Washington, D. C.
479
Osborne and others: Prosen and Rossini:

Washington, D. C. 2. J. Research Natl. Bur. Standards 27, 289 (1941).
Osborne, Stimson, and Ginnings: 3. J. Research Natl. Bur. Standards 27, 519 (1941).
1. J. Research Natl. Bur. Standards 23, 197 (1939). 4. J. Research Natl. Bur. Standards 33, 255 (1944).
P 8. J. Research Natl. Bur. Standards 34, 263 (1945).
Pariselle and Simon: 9. J. Research Natl. Bur. Standards 36, 209 (1946).
1. Conipt. rend. 173, 80 (1921). 10. Unpublished data, National Bureau of Standards,
Parks and Huffman: Washington, D. C.
1. J. Am. Chem. Soc. 52, 4381 (1930).
2. Ind. Eng. Chem. 23, 1138 (1931). Q
Parks, Huffman, and Thomas: Quayle, Day, and Brown:
Parks, Shomate, Kennedy, and Crawford:
1. J. Chem. Phys. 5,'359 (1937).
Parks, Todd, and Shomate:
R
1. J. Am. Chem. Soc. 58, 2505 (1930). Rands, Scott, and Brickwedde:
Parr: 1. Unpublished data, National Bureau of Standards
1. Ind. Eng. Chem. 4, 740 (1912). Washington, D. C.
Patnode and Scheiber: Reid:
Paul and Normaut: Reno and Katz:
1. Compt. rend. 210, 089 (1943). 1. Ind. Eng. Chem. 35, 1091 (1943).
Pauling, Springall, and Palmer: Richards and Barry:
Peffer and Mulligan: Richards and Davis:
1. National Bureau of Standards Circular C434, 1. J. Am. Chem. Soc. 39, 341 (1917).
“Testing of glass volumetric apparatus”, 2. J. Am. Chem. Soc. 42, 1599 (1920).
van Pelt and Wibaut: Richards, Henderson, and Frevert:
1. Rec. trav. chim. 60, 55 (1941). 1. Proc. Am. Acad. 42, 573 (1907).
Perkins: 2. Z. physik. Chem. 59, 532 (1907).
1. J. Chem. Soc. 77, 273 (1900). Richards and Jesse:
Peters and Lohmar: 1. J. Am. Chem. Soc. 32, 268 (1910).
1. Beiheft, Z. Ver. deut. Chem. No. 2, Angew, chem. Richards and Shipley:
50, 40 (1937). 1. J. Am. Chem. Soc. 38, 996 (1916).
Picon: 2. J. Am. Chem. Soc. 41, 2002 (1919).
1. Compt. rend. 158, 1184 (1914). Richardson and Parks:
2. Compt. rend. 158, 1340 (1914). 1. J. Am. Chem. Soc. 61, 3543 (1939).
Pines and Ipatieff: Richter and Wolff:
1. J. Am. Chem. Soc. 61, 1070 (1939). 1. Ber. 63B, 1714 (1930).
Pitzer: 2. Ber. 63B, 1721 (1930).
1. J. Chem. Phys. 6, 08 (1938). Riechemeier, Seuftleben, and Pastorff:
2. J. Chem. Phvs. 8, 711 (1940). 1. Ann. Physick 19, 202 (1934).
3. Chem. Rev. 27, 39 (1940). van Risseghem:
5. J. Am. Chem. Soc. 63, 2413 (1941). 2. Bull. soc. chim. Belg. 30, 8 (1921).
0. J. Chem. Phys. 12, 310 (1944). 3. Bull. soc. chim. Belg. 31, 65 (1922).
7. Ind. Eng. Chem. 36, 829 (1944). 4. Bull. soc. chim. Belg. 31, 213 (1922).
Titzer and Gwinn: 6. Bull. Soc. chim. Belg. 35, 328 (1926).
Pitzer and Kilpatrick: 8. Bull. soc. chim. Belg. 42, 229 (1933).
1. Chem. Rev. 39, 435 (1940). 9. Bull. soc. chim. Belg. 44, 593 (1935).
Pitzer and Scott: 10. Bull. soc. chim. Belg. 47, 47 (1938).
Powell and Giauque: van Risseghem, Gredy, and Piaux:
Prevost: Robertson, Fox, and Martin:
1. Ann. Chim. 10, 113 (1928). 1. Proc. Roy. Soc. (London) A157, 579 (1936).
2. Bull. soc. chim. 8, 89 (1941). Rodebush:
3. Compt. rend. 186, 1209 (1928). 1. Phys. Rev. 40, 113 (1932).
Prevost and Daujat: Rosa and Babcock:
1. Bull. soc. chim. 47, 588 (1930). 1. Bull. Bur. Standards 4, 121 (1907-08) S73.
Prosen, Gilmont, and Rossini: Rossini:
1. J. Research Natl. Bur. Standards 34, 65 (1945). 1. Bur. Standards J Research 4, 313 (1930).
Prosen, Jessup, and Rossini: 2. Proc. Natl. Acad. Sci. 16, 694 (1930).
1. J. Research Natl. Bur. Standards 33, 447 (1945). 3. Bur. Standards J. Research 6, 1 (1931).
Prosen, Johnson, and Rossini: 4. Bur. Standards J. Research 6, 37 (1931).
Prosen, Pitzer, and Rossini: 8. Bur. Standards J. Research 7, 329 (1931).
1. J. Research Natl. Bur. Standards 34, 255 (1945). 9. Proc. Natl. Acad. Sci. 17, 343 (1931).
480
11. Bur. Standards J. Research 9, 679 (1932). 1. J. Research Natl. Bur. Standards 25, 747 (1940).
12. Bur. Standards J. Research 11, 553 (1933). Scott:
13. Bur. Standards J. Research 12, 735 (1934). 1. Unpublished data, National Bureau of Standards,
14. Proc. Natl. Acad. Sci. 20, 323 (1934). Washington, D. C.
15. J. Research Natl. Bur. Standards 13, 21 (1934). Scott and Brickwedde:
17. J. Chem. Phys. 3, 438 (1935). Scott, Ferguson, and Brickwedde:
19. J. Research Natl. Bur. Standards 17, 629 (1936). Scott and Mellors:
21. Chem. Rev. 27, 1 (1940). Seyer:
Rossini and Deming: 1. J. Am. Chem. Soc. 53, 3588 (1931).
1. J. Wash. Acad. Sci. 29, 416 (1939). 2. J. Am. Chem. Soc. 60, 827 (1938).
Rossini and Jessup: Shand and Spurr:
Rossini and Knowlton: Shell Development Co.:
1. J. Research Natl. Bur. Standards 19, 249 (1937). 1. Unpublished data, Emeryville, Calif.
2. J. Research Natl. Bur. Standards 19, 339 (1937). Shepherd and Bailey:
3. J. Chem. Phys. 6, 569 (1938). 1. J. Research Natl. Bur. Standards 26, 347 (1941).
4. J. Research Natl. Bur. Standards 22, 415 (1939). Shepherd, Henne, and Midgley:
Rossini and Prosen: 1. J. Am. Chem. Soc. 53, 1948 (1931).
1. J. Am. Chem. Soc. 62, 2250 (1940). Sherrill, Baldwin, and Haas:
Rossini, Prosen, and Pitzer: 1. J. Am. Chem. Soc. 51, 3034 (1929).
1. J. Research Natl. Bur. Standards 27, 529 (1941). Sherrill and Launspach:
Rossini, Prosen, and Wagman: 1. J. Am. Chem. Soc. 60, 2562 (1938).
1. Unpublished data, National Bureau of Standards, Sherrill and Matlock:
Washington, D. C. 1. J. Am. Chem. Soc. 59, 2134 (1937).
Roth and von Auwers: Sherrill, Mayer, and Walter:
1. Liebigs Ann. Chem. 407, 145 (1915). 1. J. Am. Chem. Soc. 56, 926 (1934).
Roth and Macheleidt: Sherrill, Otto, and Pickett:
1. Unpublished dissertation, Braunschweig, 1921, 1. J. Am. Chem. Soc. 51, 3023 (1929).
Landolt-Bornstein, Physikalisch-chemische Ta- Sherrill and Walter:
bellen, 5th ed., Vol. II, p. 1588, Berlin, Julius 1. J. Am. Chem. Soc. 58, 742 (1936).
Springer (1923). Shoemaker and Boord:
Roth and Pahlke: 1. J. Am. Chem. Soc. 53, 1505 (1931).
1. Z. angew. Chem. 49, 618 (1936). Shorygin and Shorygina:
Rudel: 1. J. Gen. Chem. (U.S.S.R.) 5, 551 (1935).
1. Thesis, Ohio State University (1938). Silsbee and Gross:
Rudenko and Shubnikov: 1. J. Research Natl. Bur. Standards 27, 269 (1941).
1. Physik. Z. Sowjetunion 8, 179 (1935). de Simo, McMillan, and Cheney:
Ruehrwein and Huffman: 1. Unpublished data, Shell Development Co., Emery¬
1. J. Am. Chem. Soc. 65, 1620 (1943). ville, Calif.
Simons, Archer, and Randall:
1. J. Am. Chem. Soc. 61, 1821 (1939).
s Simons and Hart:
Sage, Evans, and Lacey: 1. J. Am. Chem. Soc. 66, 1309 (1944).
1. Ind. Eng. Chem. 31, 763 (1939). Slabey:
Scatchard, Wood, and Mochel: 1. Technical Note No. 1023, National Advisory Com¬
1. J. Am. Chem. Soc. 61, 3206 (1939). mittee for Aeronautics, Aircraft Engine Re¬
Schlapfer and Debrunner: search Laboratory, Cleveland, Ohio.
1. Helv. Chim. Acta 7, 31 (1924). Smith, E. A.:
Schlesman: 1. Unpublished data, Catalytic Development Cor¬
1. Unpublished data, Socony-Vacuum Oil Co., Pauls- poration, Marcus Hook, Pa.
boro, N. J. Smith, E. R.:
Schmerling, Friedman, and Ipatieff: 1. J. Research Natl. Bur. Standards 24, 229 (1940).
Schmidlin: Smith, R. A.:
1. Ann. chim. phys. 7, 245 (1906). 1. J. Am. Chem. Soc. 59, 899( 1937).
Schmidt, Hopp, and Schoeller: Smith and Cass:
1. Ber. 72B, 1893 (1939). 1. J. Am. Chem. Soc. 54, 1603 (1932).
Schmidt and Schoeller: 2. J. Am. Chem. Soc. 54, 1611 (1932).
1. Ber. 74B, 258 (1941). Smith and Kiess:
Schmidt, Schoeller, and Eberlein: 1. J. Am. Chem. Soc. 61, 989 (1939).
1. Ber. 74B, 1313 (1941). Smith and Lund:
Schmitt: 1. J. Am. Chem. Soc. 52, 4144 (1930).
1. Compt. rend. 199, 1299 (1934). Smith and MacDougall:
Schmitt and Boord: 1. J. Am. Chem. Soc. 51, 3001 (1929).
1. J. Am. Chem. Soc. 53, 2427 (1931). Smith and Pennekamp:
Schorger: 2. J. Am. Chem. Soc. 67, 279 (1945).
1. J. Am. Chem. Soc. 39, 2671 (1917). Smith and Spillane:
Schuit, Hoog, and Verheus: 1. J. Am. Chem. Soc. 62, 2639 (1940).
1. Rec. trav. chim. 59, 793 (1940). Smittenberg, Hoog, and Henkes:
Schumann, Aston, and Sagenkahn: 1. J. Am. Chem. Soc. 60, 17 (1938).
1. J. Am. Chem. Soc. 64,1039 (1942). Smoker and Burchfield:
Schurman and Boord: 1. Ind. Eng. Chem., Anal. Ed. 15, 128 (1943).
1. J. Am. Chem. Soc. 55, 4932 (1933). Smyth and Stoops:
Schwab and Wickers: 1. J. Am. Chem. Soc. 50, 1883 (1928).
481
Soday and Boord: Timmermans and Hennaut-Roland:

1. J. Am. Chem. Soc. 55, 3293 (1933). 1. J. chim. phys. 27, 401 (1930).
Soroos and Willis: 2. J. chim. phys. 29, 529 (1932).
1. J. Am. Chem. Soc. 63, 881 (1941). 3. J. chim. phys. 32, 501, 589 (1935)..
Spitzer and Huffman: 4. J. chim. phys. 34, 693 (1937).
1. J. Am. Chem. Soc. 69, 211 (1947). Timmermans and Martin:
Spitzer and Pitzer: 1. J. chim. phys. 23, 733 (1926).
1. J. Am. Chem. Soc. 68, 2537 (1946). 2. J. chim. phys. 23, 747 (1926).
Stewart, Dod, and Stenmark: 3. J. chim. phys. 25, 411 (1928).
1. J. Am. Chem. Soc. 59, 1765 (1937). Tistchenko:
Stockmayer, Kavanagh, and Mickley: 1. Bull. soc. chim. 53, 1428 (1933).
1. J. Chem. Phys. 12, 408 (1944). Todd, Oliver, and Huffman:
Stohmann, Ivleber, and Langbein: 1. J. Am. Chem. Soc. 69, 000 (1947).
1. J. prakt. Chem. 40, 77 (1889). Todd and Parks:
2. Z. physik Chem. 6, 338 (1890). 1. J. Am. Chem. Soc. 58,134 (1936).
3. J. prakt. Chem. 43, 1 (1891). Tolman:
Stohmann, Rodatz, and Herzberg: 1. “The Principles of Statistical Mechanics,” Oxford
1. J. prakt. Chem. 33, 241 (1886). University Press, New York, N. Y. (1938).
2. J. prakt. Chem. 35, 22 (1887). Tongberg, Pickens, Fenske, and Whitmore:
Streiff, Murphy, Cahill, Flanagan, Sedlak, Willingham, 1. J. Am. Chem. Soc. 54, 3706 (1932).
and Rossini: Trautz and Adler:
1. J. Research Natl. Bur. Standards 38, 53 (1947). 1. Z. Physik 89, 1 (1934).
Streiff, Murphy, Cahill, Soule, Sedlak, Willingham, and Troyan:
Rossini: 1. J. Am. Chem. Soc. 64, 3056 (1942).
1. Unpublished data, National Bureau of Standards, Tuot:
Washington, D. C. 1. Compt. rend. 197, 1434 (1933).
Streiff, Murphy, Sedlak, Willingham, and Rossini: 2. Compt. rend, 211, 561 (1940).
1. J. Research Natl. Bur. Standards 37, 331 (1946). 3. Bull. soc. chim. 9, 899 (1942).
Stuckey and Saylor: Turk:
Stull: Turkevich:
2. Unpublished data, Dow Chemical Company, Mid¬ Turner and Lesslie:
land, Mich. 1. Unpublished data, University of Cambridge, Cam¬
Swietoslowski: bridge, England.
1. J. Am. Chem. Soc. 42, 1092 (1920). Turova-Pollak and Polyakova:
Swietoslowski and Usakiewicj: 1. J. Gen. Chem. (U.S.S.R.) 9, 233 (1939).
1. Roczmiki Chem. 13, 495 (1933).
U
T Urry and Kharasch:
Tanaka and Koana: 1. J. Am. Chem. Soc. 66, 1438 (1944).
1. Proc. Phys.-Math. Soc. Japan 16, 365 (1934).
Taylor: V
1. J. Research Natl. Bur. Standards 35, 151 (1945). Villars:
Taylor, Wagman, Williams, Pitzer, and Rossini: 1. Proc. Natl. Acad. Sci. 16, 396 (1930).
1. J. Research Natl. Bur. Standards 37, 95 (1946). Voge and May:
Templeton, Davies, and Felsing: 1. J. Am. Chem. Soc. 68, 550 (1946).
1. J. Am. Chem. Soc. 66, 2033 (1944). Vogel:
2. Unpublished data, University of Texas, Austin, 1. J. Chem. Soc. 1323 (1938).
Tex.
Thompson and Sherrill:
1. J. Am. Chem. Soc. 58, 745 (1936). W
Thomsen: Waddington and Douslin:
1. “Thermochemische Untersuchungen, ” Vol I, J. A. 1. J. Am. Chem. Soc. 69, 000 (1947).
Barth, Leipzig (1882-86). Waddington, Todd, and Huffman:
2. “Thermochemische Untersuchungen,” Vol. II, J. A. 1. J. Am. Chem. Soc. 69, 22 (1947).
Barth, Leipzig (1882-86). Wagman, Kilpatrick, Pitzer, and Rossini:
3. “Thermochemische Untersuchungen,” Vol III, J. A. 1. J. Research Natl. Bur. Standards 35, 467 (1945).
Barth, Leipzig (1882-86). Wagman, Kilpatrick, Taylor, Pitzer, and Rossini:
4. “Thermochemische Untersuchungen,” Vol. IV, J. A. 1. J. Research Natl. Bur. Standards 34, 143 (1945).
Barth, Leipzig (1882-86). Wagman, Taylor, Ebert, and Rossini:
Thomson: 1. Unpublished. American Petroleum Institute Re¬
1. Chem. Rev. 38, 1 (1946). search Project 44, National Bureau of Stand¬
Thorpe and Larsen: ards, Washington, D. C.
1. Ind. Eng. Chem. 34, 853 (1942). Ward:,
Thorpe and Rodger: 1. Unpublished data. United Gas Improvement Com¬
1. Phil. Trans. 185A, 397 (1894). pany, Philadelphia, Pa.
Tiffeneau: Ward and Kurtz:
1. Ann. 10 (1907). 1. Ind. Eng. Chem. Anal. Ed. 10, 559 (1938).
2. Compt. rend. 139, 481 (1904). Washburn:
Tilton: 1. J. Research Natl. Bur. Standards 10, 525 (1933).
1. Unpublished data, National Bureau of Standards, Waterman and de Kok:
Washington, D. C. 1. Rec. trav. chim. 52, 251 (1933).
Timmermans: 2. Rec. trav. chim. 52, 298 (1933).
1. Bull. soc. chim. Belg. 31, 389 (1922). Waterman and Leendertse:
2. Bull. soc. chim. Belg. 36, 502 (1927). 1. J. Inst. Petroleum 25, 89 (1939).
3. Bureau International des Etalons Physicochimi- Waterman and Te Nuyl:
que, University of Brussels, Brussels, Belgium. 1. Rec. trav. chim. 51, 533 (1932).
482
Weber: Wibaut and Langedijk:

1. Ann. Physik 154, 367 (1875). 1. Rec. trav. chim. 59, 1220 (1940).
2. Ann. Physik 154, 553 (1875). Wibaut and van Pelt-:
Welsh and Hennion: 1. Rec. trav. chim. 57, 1055 (1938).
1. J. Am. Chem. Soc. 63, 2603 (1941). Wibaut, van Pelt, Santilhano, and Beuskens:
Wenner, Thomas, Cooter, and Kotter: 1. Rec. trav. chim. 61, 265 (1942).
1. J. Wash. Acad. Sci. 29, 313 (1939). Wiebe and Brevoort:
Whitby and Crozier: 1. J. Am. Chem. Soc. 52, 622 (1930).
1. Can. J. Research 6, 203 (1932). Wiebe, Hubbard, and Brevoort:
Whitby and Gallay: 1. J. Am. Chem. Soc. 52, 611 (1930).
1. Can. J. Research 6, 281 (1932). Wiest i
White and Glasgow: 1. Thesis, Ohio State University (1940).
1. J. Research Natl. Bur. Standards 19, 423 (1937). Willingham, Taylor, Pignocco, and Rossini:
White and Rose: Wilson:
1. J. Research Natl. Bur. Standards 9, 711 (1932). 1. J. Chem. Phys. 4, 526 (1936).
2. J. Research Natl. Bur. Standards 10, 639 (1933). Winstein and Lucas:
White, Rose, Calingaert, and Soroos: Wislicenus:
1. J. Research Natl. Bur. Standards 22, 315 (1939). 1. Liebigs Ann. Chem. 313, 207 (1900).
Whitmore and Carney: Witmer:
Whitmore and Church: Witt and Kemp:
Whitmore, Fenske, Quiggle, Bernstein, Carney, Law- Wojciechowski:
roski, Popkin, Wagner, Wheeler, and Whitaker: 1. J. Research Natl. Bur. Standards 17, 453 (1936).
Whitmore and Herndon: 3. Przemysl Chem. 23, 129 (1939).
1. J. Am. Chem. Soc. 55, 3428 (1933). 4. Proc. Am. Acad. Arts Sci. 73, 361 (1940).
Whitmore and Homeyer: Worthing:
1. J. Am. Chem. Soc. 55, 4555 (1933). 1. Phys. Rev. 12, 199 (1918).
Whitmore and Houk: Wu:
Whitmore and Laughlin:
1. J. Am. Chem. Soc. 54, 4014 (1932).
2. J. Am. Chem. Soc. 54, 4392 (1932). Y
3. J. Am. Chem. Soc. 55, 3732 (1933). Yost, Osborne, and Garner:
Whitmore and Meunier: 1. J. Am. Chem. Soc. 63, 3492 (1941).
1. J. Am. Chem. Soc. 55, 3721 (1933). Young, Dillon, and Lucas:
Whitmore and Mosher: 1. J. Am. Chem. Soc. 51, 2528 (1929).
1. J. Am. Chem. Soc. 63, 1120 (1941). Young, Jasaitis, and Levanas:
Whitmore and Orem: 1. J. Am. Chem. Soc. 59, 403 (1937).
1. J. Am. Chem. Soc. 60, 2573 (1938).
Whitmore, Popkin, Bernstein, and Wilkins:
1. J. Am. Chem. Soc. 63, 124 (1941). Z
Whitmore, Rowland, Wrenn, and Kilmer: Zeise:
1. J. Am. Chem. Soc. 64, 2970 (1942). 1. Z. Elektrochem. 39, 895 (1933).
Whitmore and Simpson: Zelinsky:
1. J. Am. Chem. Soc. 55, 3811 (1933). 1. Ber. 35, 2677 (1902).
Whitmore and Southgate: Zelinsky and Gawerdowskaja:
1. J. Am. Chem. Soc. 60, 2571 (1938). 1. Ber. 61, 1049 (1928).
Whitmore and Stahly: Zelinsky, Kasansky, and Plate:
1. J. Am. Chem. Soc. 55, 4153 (1933). 1. Ber. 68, 1869 (1935).
Whitmore and Others: Zelinsky, Packindorff, and Khokhlova:
1. Unpublished data, Pennsylvania State College, 1. Ber. 68, 98 (1935).
State College, Pa. Zelinsky and Uspensky:
Wibaut and Geldof: 1. Ber. 35, 1470 (1913).
1. Rec. trav. chim. 65, 125 (1946). Ziegler and Andrews:
Wibaut and Gitsels: 1. J. Am. Chem. Soc. 64, 2482 (1942).
1. Rec. trav. chim. 59, 947 (1940). Zmaczynski:
2. Rec. trav. chim. 60, 241 (1941). 1. J. chim. phys. 27, 503 (1930).
Wibaut, Hoog, Langedijk, Overhoff, Smittenberg, Ben- Zubow:
ninga, Bouman, van Dijk, Gaade, Geldof, Hack- 1. J. Russ. Phys. Chem. Soc. 30, 926 (1898).
mann, Jonker, Paap, and Zuiderweg: 2. J. Russ. Phys. Chem. Soc. 33, 708 (1901).
1. Rec. trav. chim. 58, 329 (1939). 3. J. Russ. Phys. Chem. Soc. 35, 815 (1903).
VI. PUBLICATIONS OF THE AMERICAN PETROLEUM INSTITUTE RESEARCH
PROJECT 44
1. Application of Polya’s theorem to optical, geo¬ series of hydrocarbons. Edward J. Prosen, Wal¬
metrical, and structural isomerism. William J. ter H. Johnson, and Frederick D. Rossini. J.
Taylor, J. Chem. Phys. 11, 532 (1943). Research Natl. Bur. Standards 37, 51 (1946).
2. The calory and the joule in thermodynamics and 17. Heats, equilibrium constants, and free energies of
thermochemistry. Eugene F. Mueller and Fred¬ formation of the alkylbenzenes. William J.
erick D. Rossini. Am. J. Phys. 12, 1 (1944). Taylor, Donald D. Wagman, Mary G. Williams,
3. Theoretical analysis of certain time-temperature Kenneth S. Pitzer, and Frederick D. Rossini. J.
freezing and melting curves as applied to hydro¬ Research Natl. Bur. Standards 37, 95 (1946).
carbons. William J. Taylor and Frederick D. 18. Heat content, free energy function, entropy, and
Rossini. J. Research Natl. Bur. Standards 32, heat capacity of ethylene, propylene, and the
197 (1944). four butenes, to 1,500°K. John E. Kilpatrick and
4. Heats of formation and combustion of 1,3-buta- Kenneth S. Pitzer. J. Research Natl. Bur. Stan¬
diene and styrene. Edward J. Prosen and Fred¬ dards 37, 163 (1946).
erick D. Rossini. J. Research Natl. Bur. Stan¬ 19. Upper and lower bounds to Rayleigh’s frequency
dards 34, 59 (1945). for a vibrating system. William J. Taylor. J.
5. Heats, free energies, and equilibrium constants of Chem. Phys. 14, 570 (1946).
some reactions involving Oa, H:, H.O, C, CO, C02 20. The entropies and related properties of branched
and CH<. Donald D. Wagman, John E. Kilpatrick, paraffin hydrocarbons. Kenneth S. Pitzer and
William J. Taylor, Kenneth S. Pitzer, and Fred¬ John E. Kilpatrick. Chem. Rev. 39, 435 (1946).
erick D. Rossini. J. Research Natl. Bur. Stan¬ 21. The thermodynamics of styrene and its methyl
dards 34, 143 (1945). derivatives. Charles W. Beckett and Kenneth S.
6. Free energies and equilibria of isomerization of Pitzer. J. Am. Chem. Soc. 68, 2213 (1946).
the 18 octanes. Edward J. Prosen, Kenneth S. 22. Vibrational frequencies of semirigid molecules: A
Pitzer, and Frederick D. Rossini. J. Research general method and values for ethylbenzene.
Natl. Bur. Standards 34, 255 (1945). William J. Taylor and Kenneth S. Pitzer. J.
7. Heats of combustion and formation of the paraffin Research Natl. Bur. Standards 38, 1 (1947).
hydrocarbons at 25°C. Edward J. Prosen and 23. Normal coordinate analysis of the vibrational fre¬
Frederick D. Rossini. J. Research Natl. Bur. quencies of ethylene, propylene, cis-2-butene,
Standards 34, 2f>3 (1945). trans-2-butene, and isobutene. John E. Kilpatrick
8. Heats and free energies of formation of the paraffin and Kenneth S. Pitzer, J. Research Natl. Bur.
hydrocarbons in the gaseous state, to 1,500°K. Standards 38, 191 (1947).
Edward J. Prosen, Kenneth S. Pitzer, and Fred¬ 24. Average square length and radius of unbranched
erick D. Rossini. J. Research Natl. Bur. Stan¬ long-chain molecules with restricted internal
dards 34, 403 (1945). rotation. William J. Taylor. J. Chem. Phys. 15,
9. Method for calculating the properties of hydro¬ 412 (1947).
carbons and its application to the refractive in¬ 25. Tautomerism in cyclohexane derivatives; reas¬
dices, densities, and boiling points of the paraffin signment of configuration of the 1,3-dimethyl-
and monoolefin hydrocarbons. William J. Taylor, cylohexanes. Kenneth S. Pitzer and Charles W.
Joan M. Pignocco, and Frederick D. Rossini. J. Beckett. J. Am. Chem. Soc. 69, 977 (1947).
Research Natl. Bur. Standards 34, 413 (1945). 26. Relabeling of the cis- and trans-isomers of 1,3-
10. Method of lagrangian curvilinear interpolation. dimethylcyclohexane. Frederick D. Rossini and
William J. Taylor. J. Research Natl. Bur. Stan¬ Kenneth S. Pitzer. Science 105, 647 (1947).
dards 35, 151 (1945). 27. Heats of formation and isomerization of the eight
11. Vapor pressures and boiling points of some paraffin, C*H,« alkylcyclohexanes. Edward J. Prosen,
alkylcyclopentane, alkylcyelohexane, and alkyl- Walter H. Johnson, and Frederick D. Rossini. J.
benzene hydrocarbons. Charles B. Willingham, Research Natl. Bur. Standards 39 (1947).
William J. Taylor, Joan M. Pignocco, and Fred¬ 28. The thermodynamic properties and molecular struc¬
erick D. Rossini. J. Research Natl. Bur. Stan¬ ture of cyclohexane, methylcyclohexane, ethyl-
dards 35, 219 (1945). cyclohexane, and the seven dimethylcyclohex-
12. Heats, equilibrium constants, and free energies of anes. Charles W. Beckett, Kenneth S. Pitzer
formation of the acetylene hydrocarbons through and Ralph Spitzer. J. Am. Chem. Soc. 69,
the pentynes, to 1,500°K. Donald D. Wagman, (1947).
John E. Kilpatrick, Kenneth S. Pitzer, and Fred¬ 29. Thermodynamics and molecular structure of cy¬
erick D. Rossini. J. Research Natl. Bur. Standards clopentane. John E. Kilpatrick, Kenneth S.
35, 4G7 (19151. Pitzer and Ralph Spitzer, J. Am. Chem. Soc. 69,
13. Heats of formation, hydrogenation, and combustion (1947).
of the monoolefin hydrocarbons through the 30. Technical and scientific services of the National
hexenes, and of the higher 1-alkenes, in the gas¬ Bureau of Standards for the Petroleum Industry.
eous state, at 25°C. Edward J. Prosen and Frederick D. Rossini. Division of Chemical Edu¬
Frederick D. Rossini. J. Research Natl. Bur. cation and Division of Petroleum Chemistry,
Standards 36, 269, (1946). American Chemical Society, Atlantic City, N. J.,
14. Heats of combustion and formation at 25°C of the April 1947.
alkylbenzenes through C„>Hu and of the higher 31. Heats, equilibrium constants, and free energies of
normal monoalkylbenzenes. Edward Jr Prosen, formation of the alkylcyclopentanes and alkyl¬
Walter H. Johnson, and Frederick D. Rossini. cyclohexanes. John E. Kilpatrick, Helene G.
J. Research Natl. Bur. Standards 36, 455 (1946). Werner, Charles W. Beckett, Kenneth S. Pitzer,
15. Heats, equilibrium constants, and free energies of and Frederick D. Rossini. J. Research Natl. Bur.
formation of the monoolefin hydrocarbons. John Standard 39, (1947).
E. Kilpatrick, Edward J. Prosen, Kenneth S. 32. Chemical thermodynamic properties of hydrocar¬
Pitzer, and Frederick D. Rossini. J. Research bons. Frederick D. Rossini. For volume V of
Natl. Bur. Standards 36, 559 (1946). Science of Petroleum (1947).
16. Heats of formation and combustion of the normal 33. Average square length and radius of normal
alkylcyclopentanes and cyclohexanes, and the paraffin hydrocarbon molecules. William J.
increments per CH2 group for several homologous Taylor (1947).
U. S. GOVERNMENT PRINTING OFFICE 0—1947 483

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SELECTED VALUES

CIRCULAR OF THE NATIONAL BUREAU OF STANDARDS C461

Prepared as Part of the work of the

Issued November 1947

U. S. DEPARTMENT OF COMMERCE NATIONAL BUREAU OF STANDARDS

W. Averell Harriman, Secretary E. U. Condon, Director

UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON, D. C.

One of the bulwarks of any technical or scientific research program

To advise the Project in its policy and program of work, the

constant of formation; heat and entropy of fusion; cryoscopic

Edward U. Condon, Director.

TABLES OP SELECTED VALUES OP

COLLECTION OF THE ORIGINAL DATA FROM

PUBLISHED SCIENTIFIC LITERATURE UNPUBLISHED REPORTS

SYSTEMATIC FILING OF DATA ON

Alkylcycloprntane* and Cyclohexane* sod the In¬ REPORTS

. TABLES of SELECTED VALUES

8 (index to parts). Molecular weights.19

8 (part 5). Molecular weights, C20H22 to C30H42. 24

8 (part 10). Molecular weights, C3oH62 to C40H82.29

la-E Paraffins, Ci to C6. 61

Op Heat of formation, r02,H2,H20, N2,C,C0,C02.156

Ou-E 02,H2,0H, H20,N2,N0,C,C0,C02.245

IV. SPECIFIC REFERENCES FOR TABLES OF PROPERTIES.395

V. GENERAL LIST OF REFERENCES.473

Fundamental Constants and Conversion Factors Internal Consistency

propriate places in section IV on specific ref¬ 8 .Molecular weights.

M ACi N ITU OK OF THE ESTIMATED UNCERTAINTIES

WHEN VALUE IS WRITTEN TO—

Property Units 1 0.1 0 01 0.001 0.0001 0.00001

Uncertainty is estimated to be—

Refractive index. ftl) ] f 0.003 0.0002 0.00005

Viscosity (absolute). Centipoise | >0.1 j

Heat content function1. 1 0.10 0.005

Heat of formation. f 0.15 0.015

f 0.04 0 004 0.0010

Summary of Tables as of May 31, 1947

Normal acetylenes (1-alkynes)

Boiling point in °C at 760 mm

Kinematic viscosity in centi-

Heat of vaporization, A//r,

1 >etter Number in block ndicates numbe of pages

Heat of formation, AHf°, and

Ho°)/T, to l,500°K,in cal/

Free-energy function, (F° —

IIo°)/T, to 1,500°K, in cal/ -

Heat capacity, Cp°, to 1,500°-

Values of fundamental con-

American Petroleum Institute Research Project 44

National Bureau of Standards Washington, D, C.

TABLE a (Part 1) - VALUES OF CONSTANTSa

December 31, 1944; revised March 31, 1945

1 sec = 1.00273791 sidereal second sec = mean solar second

g0 = 980.665 cm/sec2 , Definition; gQ = standard gravity

1 liter = 1000.028 * 0.004 cm3

1 atm = 1,013,250. dynes/cm2 Definition; atm = standard atmosphere

1 lnt. ohm = 1.000494 ± 0.000015 abs.ohm b lnt. = International; abs. = absolute

1 lnt. amp = 0.999838 ± 0.000025 abs.amp b amp - ampere

1 lnt. coul - 0.999838 + 0.000025 abs.coul b coul = coulomb