Test:Chemistry Class:2ndYear Chapter #8 Full

1. Choose best possible answer.

i. Which reacts readily with Br2:
(a) C2H6 (b) C3H8 (c) C4H8 (d) C4H10
ii. Ethene is produced from ethyl chloride by reacting with alco.KOH, process is called:
(a) Hydrogenation (b) Dehydrogenation (c) Dehydrohalogenation (d) Oxidation
iii. Substitution reaction in acetylene is possible by:
(a) Na metal (b) NaNH4 (c) Ammonical AgNO3 (d) All
iv. Carbocation is formed as a result of:
(a) Homolytic fission (b) Heterolytic fission (c) Both (d) None
v. Vicinal dihalides on treatment with Zn dust give:
(a) Alkenes (b) Alkynes (c) Alkanes (d) All of them
vi. Hydroxylation of alkene can be carried out by:
(a) Alkaline KMnO4 (b) O3 ( c) H2SO4 (d) K2Cr2O7
vii. Vinyl acetylene reacts with HCl to form:
(a) polyacetylene (b) benzene (c) chloroprene (d) divinyl acetylene
viii. Presence of double bond in a compound is the sign of :
(a) saturation (b) unsaturation (c) substitution (d) condensation
ix. Ozone reacts with ethene to form:
(a) Ozonoid (b) Molozonide (c) Glycol (d) Halohydrin
x. For good quality of polyethylene , ethylene is polymerized in presence of:
(a) aluminum triethyl (b) titanium tetrachloride (c) Ag2O (d) a & b
xi. The final product of oxidation of Ethyne KMnO4 is:
(a) Glyoxal (b) Oxalic acid (c) Melonic acid (d) Molozonoid
xii. Conversion of Acetylene into benzene require catalyst:
(a) Cu tube (b) Zn dust (c) KMnO4 (d) Cu2Cl2,NH4Cl
xiii. Hydrogenolysis is carried out in the presence of:
(a) Ni (b) Pd/C (c) CaO (d) NH2/KOH
xiv. Which gives Carbon black on reaction with Alkanes:
(a) F2 (b) Cl2 (c) Br2 (d) I2
xv. Temperature for Dehydration of 30 alcohol is:
(a) 120 0C (b) 100 0C (c) 85 0C (d) 140 0C
xvi. During partial hydrogenation of alkynes cis Alkenes are formed... catalyst of process is:
(a) Na at -33 0C (B) Liquid NH3 (C) Lindlar's catalyst (d) Pt with Pd or Ni
xvii. The production of Luminous flame on Burning is characteristic is
(a) Alkanes (b) Alkenes (c) Alkynes (d) All
2. Give Short Answers of Followings.

i. Give structural formulae of (a) 4-ethyl-2,2-dimethylhexane (b) 3-propyl-2-hexene?

ii. Write structural formulae of (a) Isobutylene (b) 2,5-Heptadiene?
iii. What is difference b/w Wolfkishner's reduction and Clemmensen reduction? examples?
iv. How can you prepare an Alkene by Dehalogenation of Vicinal dihalides?
v. Define Raney Nickel? give Formation and Use with an Example?
vi. What is Markownikov's rule? Give an example of its Use?
vii. How will you prepare Ethylene glycol from Ethene?
viii. Give reaction of Ethene with Ozone?
ix. Give Addition of Water to Ethyne?
x. Prepare Chloroprene from Ethyne?
xi. How can Ethyne be Converted into Benzene?
xii. Why Alkenes are most Reactive group as compared to that of Alkanes & Alkynes?

3. (A) Prepare ETHYNE by Kolb's Electrolysis of Unsaturated Dicarboxylic acid?

. (B) Give addition of Hydrogen Halides to Alkenes with Mechanism?

. (C) Bring about following conversions:

a) Ethane to Methane ?
b) Acetic acid to Ethane?
c) 1-Chloro-2-Propanol from 1-Propanol?
d) Ethyne from Ethyl alcohol?