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Procedia CIRP
Procedia 00 (2017)
CIRP
Procedia CIRP 000–000
00 (2019)
96 000–000
(2021) 175–180 www.elsevier.com/locate/procedia
Procedia CIRP 00 (2019) 000–000 www.elsevier.com/locate/procedia
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CIRPe 2020 – 8th CIRP Global Web Conference – Flexible Mass Customisation
CIRPe 2020 – 8th CIRP Global Web Conference – Flexible Mass Customisation
Analysis of the Variety of Lithium-Ion Battery Modules and the Challenges
Analysis of thefor VarietyanCIRP
28th ofDesign
Agile Lithium-Ion
Conference,Battery
Automated May 2018,Modules
Disassembly Nantes,System and the Challenges
France
for an Agile Automated Disassembly System
Eduard Gerlitza,∗, Marvin Greifensteina , Janna Hofmanna , Jürgen Fleischera
A new methodology
Eduard Gerlitz a,∗to analyze the functional
, Marvin Greifenstein a and physicala architecture
a of
wbk Instituteaof Production Science, KIT Karlsruhe Institute ,ofJanna Hofmann
Technology, Kaiserstr. 12, ,76131
Jürgen Fleischer
Karlsruhe, Germany
existing products a for an
wbk Institute of Production assembly
Science, oriented
KIT Karlsruhe Institute product
of Technology, family
Kaiserstr. 12, 76131 identification
Karlsruhe, Germany

Abstract Paul Stief *, Jean-Yves Dantan, Alain Etienne, Ali Siadat


Abstract
Within thisÉcole
paperNationale
the initial steps ford’Arts
the realisation of an agile automated
Supérieure et Métiers, Arts et Métiers ParisTech,system
LCFC EAfor4495,
battery module
4 Rue disassembly
Augustin will
Fresnel, Metz be presented.
57078, France The state
of the art
Within battery
this papermodules need
the initial to for
steps be analysed with regards
the realisation to their
of an agile structure,
automated components
system and module
for battery the relationship of thewill
disassembly components to each
be presented. Theother.
state
In
of particular,
the art the key
battery challenges
modules need inbe
to battery module
analysed withdisassembly
regards to up tostructure,
their cell levelcomponents
are identified
andand
theclassified in order
relationship of thetocomponents
systematically
to derive
each the
other.
* Corresponding author. Tel.: +33 3 87 37 54 30; E-mail address: paul.stief@ensam.eu
requirements for the disassembly system. The identified challenges for automated disassembly are twofold: process-related and product-related.
In particular, the key challenges in battery module disassembly up to cell level are identified and classified in order to systematically derive the
The variety offor
requirements battery modules cansystem.
the disassembly be seenThe
as a identified
product-related challenge,
challenges while non-detachable
for automated disassembly joints combined
are twofold: with the hazards
process-related posed by Li-ion
and product-related.
batteries canofbebattery
The variety described as process-related
modules can be seen aschallenge. An approach
a product-related for capturing
challenge, the variety of battery
while non-detachable modules iswith
joints combined donethebyhazards
using the methodology
posed by Li-ion
of a morphological box.
batteries can be described as process-related challenge. An approach for capturing the variety of battery modules is done by using the methodology
Abstract
of a morphological box.
In© 2020 The
©today’s
2021 The
Authors.
business
Authors.
Published by
environment,
Published by
Elsevier
theElsevier B.V.
trend towards
B.V. more product variety and customization is unbroken. Due to this development, the need of
This
©
agile is an
2020
and The open accessPublished
Authors.
reconfigurable article under
production by the CC BY-NC-ND
Elsevier
systems emerged tolicense
B.V. cope with(http://creativecommons.org/licenses/by-nc-nd/4.0/)
various products and product families. To design and optimize production
This is an open access article under the CC BY-NC-ND license (https://creativecommons.org/licenses/by-nc-nd/4.0)
Peer-review
This
systemsis an
as open
Peer-review under
well as the
access
under to responsibility
article the
choose
responsibilityunder of the
the
optimal
of CC scientific
BY-NC-ND
product
scientific committee
license
matches,
committee of the
product
of the CIRPe
analysis
8th 2020 Global
methods
CIRP Global Web Web Conference.
(http://creativecommons.org/licenses/by-nc-nd/4.0/)
areConference
needed. Indeed, mostMass
– Flexible of the known methods aim to
Customisation
Peer-review
analyze a underorthe
product oneresponsibility
product familyof the
on scientific
the physicalcommittee
level. of the CIRPe
Different 2020
product Globalhowever,
families, Web Conference.
may differ largely in terms of the number and
Keywords: Disassembly; Manufacturing system; Separation of Non-Detachable Joints
nature of components. This fact impedes an efficient comparison and choice of appropriate product family combinations for the production
Keywords: Disassembly; Manufacturing system; Separation of Non-Detachable Joints
system. A new methodology is proposed to analyze existing products in view of their functional and physical architecture. The aim is to cluster
these products in new assembly oriented product families for the optimization of existing
recycled [6].assembly
For thislines and thedisintegration
purpose, creation of future reconfigurable
including disas-
assembly systems. Based on Datum Flow Chain, the physical structure of the products is analyzed. Functional subassemblies are identified, and
1. Introduction sembly and shredding can be carried out in dependence
recycled [6]. For this purpose, disintegration including disas- of tech-
a functional analysis is performed. Moreover, a hybrid functional and physical architecture graph (HyFPAG) is the output which depicts the
1. Introduction nological and economic aspects. While disassembling presents
similarity between product families by providing design support to both,sembly and system
production shredding can be
planners carried
and outdesigners.
product in dependence of tech-
An illustrative
The of
example automotive industry
a nail-clipper is usedistoundertaking of tremen- An anological
a processmethodology.
explain the proposed
method andfor study
industrial case
systematically
economic
on two
separating
aspects.
productWhile
a ofproduct
disassembling
families
intopresents
e.g. of
steering columns
its
dous upheaval
The automotive
thyssenkrupp and major
industry
Presta France reorganization
is undertaking
is then [1].
carried out toagive Stricter
process environ-
a firstofindustrial sub-components,
a method
tremen- evaluation of thefor shredding
systematically
proposed presents a destructively method
approach. separating a product into e.g. its of
mental
©dous regulations
2017upheaval
The Authors. (e.g.
andPublished new climate
major reorganization targets
by Elsevier B.V. such as the
[1]. Stricter environ- 2015 breaking down the product into smaller pieces
sub-components, shredding presents a destructively method of[6]. So far, the
Paris
mentalAgreement
Peer-review [2](e.g.
and new
under responsibility
regulations growing
of theenvironmental
climate scientific suchawareness
targetscommittee of the
as the are
28th CIRP
2015 vast number
breaking
Design down of the
electric
Conference 2018.vehicle
product into suppliers and large
smaller pieces [6]. Sovariety of
far, the
only
Paris one way of [2]
Agreement preventing scandals
and growing such as the
environmental ”diesel ex-
awareness are battery modules
vast number hinders avehicle
of electric standardized
suppliersutilization
and large of automated
variety of
haust
Keywords:
only one Assembly;
affair” Design
way[3]of and method;
excessive
preventing Family identification
pollutant
scandals suchemissions. For more
as the ”diesel ex- disassembly concepts. Currently, Li-ion
battery modules hinders a standardized utilization of traction batteries
automated are
than a decade, the search for alternative drive
haust affair” [3] and excessive pollutant emissions. For more concepts has been only disassembled down to a module level
disassembly concepts. Currently, Li-ion traction batteries are due to the lack of
unavoidable - with electric mobility leading
than a decade, the search for alternative drive concepts has been the way. Conse- standardized
only battery
disassembled modules
down to a[7, 8].
module Afterwards,
level due it
tois state
the of
lack the
of
quently, the sales volume of electric vehicles
unavoidable - with electric mobility leading the way. Conse- has grown enor- art that the
standardized single
batterymodules
modules are shredded
[7, 8]. because
Afterwards, it would
is state other-
of the
1.mously
Introduction of theimply
wise product highrange and characteristics
economic costs manufactured
when disassembling [9].and/or
Nev-
quently,[4].the Hereby,
sales volume Li-ionofbatteries
electricgained
vehiclesin market
has grown shareenor-
dur- art that the single modules are shredded because it would other-
ing the past years [1], while on the same time questions regard- assembled
ertheless, in
the this system.
potential of In this context,
increasing the the main
disassembling challenge
granu- in
mously [4]. Hereby, Li-ion batteries gained in market share dur- wise imply high economic costs when disassembling [9]. Nev-
Due to the fast development in the domain of modelling
larity downthe and analysis
to potential
the cell levelis now not
seems to be only to cope with single
ing the
disassembly
past yearsat[1], end of life
while on the(EOL)
samescenarios
time questionsincluding re-
regard- ertheless, of increasing theinevitable
disassemblingfor a sustain-
granu-
communication and an ongoing trend of digitization and products, a limited
able recycling product
of cell
Li-ion range or existingdisassembling
batteries. product families,
manufacturing,
ing disassemblyrecycling
at end ofand lifethe sustainable
(EOL) scenarios usage of scarce
including re- larity down to the level seems toThrough
be inevitable for a sustain- Li-
digitalization,
raw materials manufacturing
occurred enterprises areoffacing important but
ionalso to bebatteries
traction able to analyze and granular
intobatteries.
more to compare productsthe
structures, to define
purity
manufacturing, recycling[5]. andThe the exiguity
sustainable ausage
circular econ-
of scarce able recycling of Li-ion Through disassembling Li-
challenges
omy materials
and valuein recovery
today’s market environments: a achieved
continuing new product families.
of individual It increases
fractionsinto can be observed that classical
and supersedes existing
further recy-
raw occurred from [5]. TheEOL productsof
exiguity cana be circular by
econ- ion traction batteries more granular structures, the purity
tendency towardsproceedings:
reduction of reusing,
product remanufacturing
development times andand product
cling families [6].
processes are regrouped
Furthermore, in function of clients or features.
threeand
omy substantial
value recovery from EOL products can be achieved re-
by of individual fractions increases functioning
and supersedes components such
further recy-
shortened
cycling product
[6]. Products lifecycles. In addition,
that are inreusing, there
a good remanufacturing is an increasing
condition can be reused, However,
as battery assembly
cells could oriented product families
possibly be remanufactured are hardly to find.
or utilized for
three substantial proceedings: and re- cling processes [6]. Furthermore, functioning components such
demand of customization,
while inoperable products being need
at the same time in a global On the product
second-use family[10,
applications level,
11]. products differ mainly in two
cycling [6]. Products that aremayin a goodto be remanufactured
condition can be reused, or as battery cells could possibly be remanufactured or utilized for
competition with competitors all over the world. This trend, main characteristics:
This paper (i) the number
is addressing of components and (ii) the
while inoperable products may need to be remanufactured or second-use applications [10,the 11].disassembly step ”battery mod-
which is inducing the development from macro to micro type of
uleThis components
into paper (e.g.
cells”,isasaddressing mechanical,
there is still electrical, electronical).
∗ Corresponding author. Tel.: +49-1523-9502614 ; +49-721608-45005. the potential
disassembly for economic
step ”battery automa-
mod-
markets, results eduard.gerlitz@kit.edu
in diminished lot(Eduard sizes Gerlitz).
due to augmenting Classical
tion. The methodologies
overall goal is to considering
achieve an mainly
agile single products
disassembly system,
∗ E-mail address:
Corresponding author. Tel.: +49-1523-9502614 ; +49-721608-45005. ule into cells”, as there is still potential for economic automa-
product varieties (high-volume to low-volume production) [1].
E-mail address: eduard.gerlitz@kit.edu (Eduard Gerlitz).
or solitary,
which
tion. The already
canoverall
adapt existing
cost-efficiently
goal is to achieve product
to families
anchanges
agile in the
disassemblyanalyze
batch the
size
system,
To cope with this augmenting variety as
2212-8271 © 2020 The Authors. Published by Elsevier B.V. well as to be able to product
as wellcan
which structure
as the
adapt on
varietya physical
cost-efficiently level
of variants towith (components
different
changes level)
kindbatch
in the which
of joints
size
identify
This possible
is an open
2212-8271 access
© 2020
optimization
Thearticle under
Authors. the CCpotentials
Published BY-NC-ND in the
license
by Elsevier B.V.
existing causes
as well difficulties
as the varietyregarding
(http://creativecommons.org/licenses/by-nc-nd/4.0/)
of variants anwithefficient
different definition
kind of jointsand
production
Peer-review
This is an opensystem,
under it is important
the responsibility
access article CCto
of the
under the have acommittee
scientific
BY-NC-ND precise knowledge
of comparison
the CIRPe 2020 Global of different product families. Addressing this
Web Conference.
license (http://creativecommons.org/licenses/by-nc-nd/4.0/)
Peer-review under the responsibility of the scientific committee of the CIRPe 2020 Global Web Conference.
2212-8271 © 2021 The Authors. Published by Elsevier B.V.
This is an©open
2212-8271 2017access article Published
The Authors. under theby CC BY-NC-ND
Elsevier B.V. license (https://creativecommons.org/licenses/by-nc-nd/4.0)
Peer-review
Peer-review under
under responsibility
responsibility of scientific
of the the scientific committee
committee of the of theCIRP
28th 8th CIRP
DesignGlobal Web2018.
Conference Conference – Flexible Mass Customisation
10.1016/j.procir.2021.01.071
176 Eduard Gerlitz et al. / Procedia CIRP 96 (2021) 175–180
Gerlitz et al. / Procedia CIRP 00 (2019) 000–000

through flexibility and reconfigurability, similar to an agile as-


sembly system [12].
In particular, the focus of this paper is to systematically iden-
tify and classify the key challenges to take a step towards an ag-
ile automated disassembly system. The dismantling of battery a) b) c)
modules is particularly accompanied by different challenges,
whereby in the following a classification between product- Fig. 1. a) cylindrical cell, b) prismatic cell, c) pouch cell
related and process-related challenges is made. The vast vari-
ety of battery modules and their components can be named as
trical contact to the metal foils of the respective electrodes and
a product-related challenge. Currently, there is no standardized
are electrically insulated from each other. During charging, the
design for battery modules, e.g. in the form of a norm [13]. The
Li ions flow from the cathode (metal oxide) through the sep-
battery cell type is selected according to the customer standard,
arator to the anode (graphite) and form an intercalation com-
which ultimately influences the design of the battery module
pound with the graphite. When discharging, the reverse process
[14]. Scientific work regarding the development of standards
occurs. The electron flow takes place externally [18]. During
for battery modules, e.g. [15], already exist but have not been
charging/discharging and thus entry/exit of Li-ions into/from
fully implemented. The process-related challenge is posed by
the graphite grid a change in volume of the grid occurs, which
non-detachable joints combined with the dangers posed by Li-
is expressed particularly in the form of a change in thickness
ion batteries. Non-detachable joints require destructive or par-
of the battery cell [18]. This effect is known as cell respiration
tially destructive separation processes [16]. Due to the dangers
and should be taken into account especially in module design
posed by the Li-ion battery, only certain separation processes
as well as assembly and disassembly due to the occurring me-
are suitable. The following approaches are used to address the
chanical tensions [22].
two challenges described above: The variety of state of the art
In principle, one differentiates between the cell types cylin-
battery modules is captured by identifying similarities and dif-
drical, prismatic and pouch cells [18], which are illustrated in
ferences referring to each component and using the method-
Fig. 1. The cylindrical and prismatic cells consist of a hard case
ology of a morphological box. Regarding the process-related
(usually aluminum or stainless steel [23]) in which an electrode
challenges the non-detachable joints are identified, classified
coil is inserted. The hard case is then welded. In pouch cells,
and the location between the battery module components is
the electrode stack, which is mainly produced by z-folding
shown in a component-relationship-matrix (based on [17]). Fur-
or stacking, is enclosed by a form-unstable pouch foil. The
thermore, the hazards relevant for disassembly are identified in
foil is polyamide-aluminum-polypropylene compound, which
order to derive the requirements for the disassembly process.
is closed by a heat-sealing process [23, 18]. In the following,
In the following, the fundamentals of Li-ion batteries are ex-
the battery module is divided into its subsystems (components)
plained as well as the product- and process-related challenges
from a disassembly point of view. The structure of a module is
are examined in more detail.
primarily dependent on the utilized cell type. Nevertheless, the
following six components can be identified across all cell types
(according to [20]): Battery cell, cooling system, cell contactor,
2. Fundamentals of Li-ion batteries
Battery Management System (BMS), cell fixation and housing.
A detailed description of each component can be found in the
Li-ion batteries can be found in different areas and are used
following chapter.
especially as traction batteries due to their advantages such as
high power and energy density [18]. Further battery types like
redox-flow- or metal-air batteries offer an enormous potential 3. Product-related challenges
but are currently connected with challenges and therefore sub-
ject of current research [19]. In this paper, a morphological analysis as a method to inves-
The Li-ion traction battery can be divided into three hier- tigate the totality of all relations in multidimensional, mostly
archical levels. The highest level is the battery system, which unquantifiable problems following Fritz Zwicky (1967) [24]
consists of battery modules. The modules are made up of indi- was used in combination with a branching structure. The mor-
vidual cells that form the actual energy storage [20]. phological box, as illustrated in Fig. 2, merges all Li-ion bat-
In general, Li-ion battery cells consists of the components tery module components and their differentiating characteris-
anode, separator, cathode, an electrolyte, the current collectors tics into one single model. Every battery module can be dis-
as well as a housing [21]. The anode and cathode are made of assembled into the same six main components: battery cells,
active material coated on a thin metal foil. In the most com- cell contacting, cell fixation, housing, thermal management and
mon configuration, the anode consists of a copper foil with the BMS (including its periphery). When choosing a path, e.g.
coated graphite and the cathode is an aluminum foil coated with a prismatic cell, it is evident that some of the following paths
LiNixCoyMnzO2 [18]. The separator, which is only permeable are dependant of that particular choice. All decision branches
for Li ions, separates the anode from the cathode. The elec- are illustrated with bold lines on the side walls of the morpho-
trolyte consists of a non-aqueous solvent (e.g. ethylene carbon- logical box. Once a bold line is on the bottom, the tree branch
ate) and solution salt LiPF6. The two collectors form an elec- ends, and the following path can be independently chosen. At
Eduard Gerlitz et al. / Procedia CIRP 96 (2021) 175–180 177
Gerlitz et al. / Procedia CIRP 00 (2019) 000–000

Components * Different. Properties Manifestations

cell type CYLINDRICAL PRISMATIC POUCH (with compression pads)


battery cell row multiple rows single-rowed two-rowed single-rowed
arrester position opposite side same side same side opposite side
CYLINDRICAL PRISMATIC POUCH
yes connection type adhesive bond adhesive bond traction/form fit adhesive bond traction/form fit
yes joining technology welding welding screwing welding screwing
cell contacting
busbar <with bonding wires> busbar hole-busbar busbar screw threads-/ hole-
yes bridge [tab-to-tab]
(collector sheets) [tab-to-busbar] [tab-to-busbar] [tab-to-busbar] busbar
yes support plate no yes no no no no
CYLINDRICAL PRISMATIC POUCH
primary fixation rigid spacer, spacer strip,
yes <gluing> <gluing> <cell frame> <gluing>
cell fixation (cell-to-cell) mounting bracket (incl. recesses)
secondary fixation detachable joined end plates and/or side panels
no non-detachable joined side panels
(cell-group) <with tension/stretch unit>
- function-integration in cell fixation yes no
modul
no amount of individual parts one-part two-part multipartite
housing
no joining type of individual parts detachable joined non-detachable joined

thermal cooling types air cooling fluid cooling


no
management types floor/head cooling side cooling arrestor cooling cooling plate (fluid) heat-conducting plate
BMS & centralized (all units integrated master/slave, PMU & MMU master/slave, MMU & CMU distributed software
no topology
periphery within master) integrated within master integrated within slave BMS

Legend < > optional element * battery cell dependency [ ] technical expression

Fig. 2. Morphological box with manifestation of the battery modul components

this point, it should be mentioned that there is no guarantee of and support plates or traction/form fit connected with screw-
completeness since there is a rapid development in electric mo- ing/latching as joining technology and hole-busbars as bridge
bility research and furthermore, the car manufacturers and sub [31, 29]. Pouch cells can also be connected by adhesive bond
supplier only provide a limited access to information. Never- connections by welding (e.g. ultrasound) and in either tab-to-
theless, the following subparagraphs investigate the main com- tab [32] or tab2busbar bridges [36] without support plates. Oth-
ponents in more detail and approach of systematically capture erwise, it may be connected by a traction/ form fit connection
trends and tendencies for an overall overview. with screwing as joining technology and screw thread-/ hole-
busbars as bridge without any support plates [36].
3.1. Battery cell types

As described in chapter 2, Li-ion battery cells can be subdi-


vided into the three cell types. Apart from the cell types, Li-ion 3.3. Fixation of Li-ion cells
battery cells can be further differentiated regarding their arrester
position and number of rows. Cylindrical cells feature multiple In this paper, the fixation is divided into a primary fixation,
rows with arrester being on opposite sides [25, 26]. Prismatic which keeps the individual cells at its foreseen place (cell-to-
cells feature either single-rowed [27, 28] or two-rowed modules cell fixation) and a secondary fixation, which detachably or
[29, 30] while the arresters are regardless of the row always on non-detachably fixates the cells to a group with e.g. side or end
the same side [28, 31]. Battery modules with pouch cells show panels (cell-group fixation). When fixating the battery cells, one
single-rowed cells with the arresters being positioned either on has to distinguish strongly between the individual cell types.
the same or the opposite side [26, 31]. For pouch cells, cell frames are often used as primary fixation,
in which the cells are inserted, redundantly sealed and flexi-
3.2. Cell contacting bly tensioned [37]. The spaces between the cells could even be
additionally used for a cooling system. Optionally, pouch cells
The electrical connection of all individual cells is of essen- may even be glued [37]. Cylindrical cells have to be fixated by
tial importance [32]. The main function of electrical cell con- rigid spacers, spacer strips or mounting brackets (including re-
tacts is to transmit electrical energy with minimal losses. Hence, cesses) [35, 11]. Due to the geometrical shape of the cells, gaps
the electrical resistance of the cell contacts should be as low are created which can optionally be used for cooling systems
as possible. Additionally, the electrical resistance should re- (e.g. [11]). Additionally, gluing can be used as primary fixation
main constant over the entire service life of the Li-ion batteries. of cylindrical cells [38]. Lastly, prismatic cells can be primar-
Otherwise an even aging of the battery cells, which depends ily fixed by gluing (optional) [30]. This requires a light, elastic
largely on the operation of the cells, can no longer be guar- joining medium to avoid air pockets and thus achieve complete
anteed [33]. Hereby, all cell contacting systems dependant on contact and insulation. When using cell frames or gluing as pri-
the cell type (cf. Fig. 1). Cylindrical cells are adhesive bond mary fixation form, the secondary fixation will independently
connected with busbars by a welding technology and are op- from the cell type either comprise of non-detachable joined side
tionally wire bonded [34, 35]. In this case no support plates panels (e.g. welding) [38, 28] or detachable joined end plates or
are necessary. Prismatic cells are either adhesive bonded by side panels (e.g. tension/ stretch units, threated bar, tension rod,
welding (e.g. laser), with busbars (e.g. connections sheets) [32] tightening straps) [39].
178 Eduard Gerlitz et al. / Procedia CIRP 96 (2021) 175–180
Gerlitz et al. / Procedia CIRP 00 (2019) 000–000

3.4. Battery module housing A B C D E A B C D E


battery cell A X X A X X X

The module housing accommodates the cells of a battery cell contacting B X B


thermal management C C
module and therewith plays a decisive role in the functional-
cell fixation/modul housing D X D
ity, safety and service life of the energy storage system [21]. BMS & periphery E E
It shields the sensitive components from harmful environmen- mechanical joints chemical joints

tal influences such as water, moisture and dust, and is crucial


for a long-term, safe and reliable operation [21]. The module Fig. 3. Positions of mechanical and chemical non-detachable joints
housing may or may not be function-integrated in the cell fixa-
tion [40, 39] and consist of one, two or multiple parts [29, 28].
Ultimately, the joining type of the individual parts can be de- pack management units (PMU) when differentiating the BMS
tachable joined [41] or non-detachable joined [28]. topologies as described in [46]. A centralized BMS unites all
three monitoring units (PMU, MMU and CMU) in a single sys-
3.5. Thermal management tem that performs all tasks required by the BMS [46]. In the sec-
ond topological possibility a central control unit (master) and
A fully functional battery can only be operated optimally slave units are connected to each other, whereas the slave units
within a narrow temperature range. During storage, tempera- are further attached to each cell. The master unit integrates all
tures up to +60°C and during operation, temperatures up to PMU functions, while the slave units comprise the CMU func-
+40°C do not pose any problems and offer a first starting point tions. Although, the master unit comprises the PMU and MMU
for a thermal upper limit [42, 43]. At cell temperatures below some of the functions of the MMU, e.g. inter-cell balancing, can
0°C the battery can even be damaged [44]. The Li-ion batteries be performed either by the master or the slave units, depend-
should be actively cooled or heated to ensure the small operat- ing on the selected balancing concept [46]. The third topologi-
ing temperature windows and to avoid temperature differences cal possibility is based on the same master/slave system, where
[42, 43]. The thermal management is not dependent upon a spe- the master unit integrates the PMU functions and the slave in-
cific cell type. Nevertheless, a distinction of two main cooling tegrates all MMU and CMU functions [46]. Lastly, the fourth
types can be made [43]: Air cooling and fluid cooling. For the topological possibility is a distributed software BMS, in which
air cooling the battery cells are cooled directly with conditioned every subsystem manages one or more cells including function-
air. The required air can be tapped at different points in the ve- alities from all three tiers (CMU, MMU and PMU). Therewith,
hicle, e.g. from a refrigerant-air evaporator [27]. Active cooling a central control unit is distinguished, and the battery pack is
via fluid coolants represents a very flexible and efficient cool- equally and collaboratively managed by all subsystems [46].
ing method. The fluid coolant flows through the cooling plates To sum up, this chapter has allocated six key battery mod-
and provides thermal regulation of the cells. Additionally, fluid ule components and systematically illustrated the state-of-the-
cooling can also be differentiated into various variants regard- art module manifestation variety. While some manifestations
ing to their spatial arrangements. The spatial arrangement is of module components show dependencies to the cell, e.g. cell
mainly based on the necessity of thermal contact with the bat- contacting or cell fixation, others are rather independent, e.g.
tery cell itself in order to cool every single cell. Herein, it can BMS or thermal management. Caused by the different product
be separated into floor/head cooling, side cooling, arrestor cool- manifestations and the mentioned dependencies, an adoption of
ing, cooling plates (fluid-led) and heat-conducted plates [42]. the disassembly sequence seems to be from high importance.
These fluid cooling systems are more complex due to the direct
contact of the cooling apparatus with the cell compared to air 4. Process-related challenges for disassembly
cooling methods. Thus, the thermal management can be split
into fluid and air cooling while the fluid cooling type can be A major challenge when dismantling battery modules in
further differentiated by its spatial arrangements. cells are the non-detachable joints in modules in combination
with the hazards posed by the Li-ion battery cells. In the fol-
3.6. Battery management system (BMS) lowing, non-detachable joints frequently used in battery mod-
ules are localized as well as the key hazards are identified.
The BMS is an independent control unit that monitors and
controls the complete battery system activities and therewith 4.1. Localisation of non-detachable joints
ensures safety and stability. This includes the calculation of
the battery state of charge (SOC) and aging state (state of A basic distinction is made between mechanical (especially
health, SOH) as well as the cell voltage, currents and tempera- welded joints) and chemical joints (adhesive joints). The posi-
tures to guarantee the safe operating window of each individual tions of the identified mechanical and chemical joints are shown
cell [45]. Regarding the component characteristics of the BMS in Fig. 3.
and its periphery, it can be mainly differentiated within four Mechanical non-detachable joining connections can be es-
topologies used by many companies nowadays. Hereby, it is pecially identified when contacting the cell (cell-cell, cell-
essential to employ a three-tier concept consisting of cell mon- contactor) and within cell fixation or housing. The choice of
itoring units (CMU), module management units (MMU) and this type of joint is justified by the high requirements placed on
Eduard Gerlitz et al. / Procedia CIRP 96 (2021) 175–180 179
Gerlitz et al. / Procedia CIRP 00 (2019) 000–000

the connection. For cell contacting, a particularly high mechan- example, damage to the cell envelope can cause leakage of elec-
ical strength (for both static and dynamic mechanical loads) trolyte and further a formation of hydrofluoric acid [9]. Another
as well as temperature resistance must be present [31]. Fur- example is the thermal runaway, the worst-case scenario for Li-
thermore, the electrical contact resistance should be as low as ion batteries, which can be caused by a short circuit or exces-
possible [31]. Depending on the utilized cell type, laser spot sive heat input during disconnection. For the separation of the
welding (prismatic cell, pouch cell), ultrasonic welding (pouch different kind of non-detachable joints it is essential to make
cell), ultrasonic wedge bonding (cylindrical cell) and projection a specific selection of cutting processes with a wide range of
welding (cylindrical cell) are used for cell contacting [31]. The operations and a safe parameter space. At the same, the battery
module housing, which can also include an integration of the cell should be monitored regarding the temperature to detect
cell fixing function (especially secondary fixing), as explained critical situation.
in more detail in the last chapter, can be joined by a welded
joint [47]. Adhesives are used in battery modules as structural
elements, for electrical insulation, sealing and for thermal man- 5. Conclusion and Outlook
agement as a heat conducting compound [48]. Adhesive bond-
ing is especially found between the individual cells (indepen- In this paper, the key challenges of dismantling Li-ion bat-
dent of cell type), between cells and cooling plates as well as tery modules into cells were systematically identified and clas-
cells and housing plates, as it is illustrated in [28]. Epoxy resin, sified. On the one hand, the variety of battery modules and their
polyurethanes or adhesive tapes [28] can be used as adhesives. components represent a product-related challenge. Capturing a
vast diversity of variants was carried out with the help of a mor-
4.2. Li-ion battery hazards phological box based on the six battery module components.
Consequently, the product-related challenge requests the disas-
Li-ion batteries are classified as hazardous goods and there- sembly system to be adaptable regarding disassembly sequence
fore require special treatment. According to [9], the hazards planning. A process-related challenge in the dismantling of bat-
can be divided into 3 sub-categories: Electrical, Chemical and tery modules is posed by non-detachable joints in combina-
Fire/Explosion. Electrical hazards may be called electric shock tion with the hazards of Li-ion batteries. Non-detachable con-
and further associate burning. This is due to the high system nections can only be separated with the aid of destructive or
voltage of 300 to 400 volts, especially at battery system level. partially destructive separation processes, which require a safe
Moreover, short circuits lead to heating of the battery. Among process parameter space. The non-detachable joints in a bat-
the chemical hazards, the carcinogenic nickel or cobalt can be tery module were identified and then illustrated in the form of
mentioned, which are contained in the active material of the a component relation matrix for both mechanical and chemi-
cathode. If the electrolyte escapes and comes into contact with cal joints. The requirements to the disassembly system derived
water, the solution salt LiPF6 can also produce caustic liquid from the process-challenges is especially affecting the process
acid HF. If a critical temperature is exceeded, an exothermic re- planning: The choice of separation processes with a wide range
action can occur, which is widely known as thermal runaway. of operations and a safe parameter space is crucial while moni-
On the one hand, due to gas formation and thus pressure build- toring the battery cells state. Finally, the product- and process-
up, thermal runaway can lead to the escape of toxic gas or even related challenges both affirm the use of an agile disassembly
explosion. On the other hand, the thermal runaway can degen- system.
erate into a fire due to highly flammable carbonates in the elec-
trolyte such as ethyl methyl carbonate (EMC) and ethylene car- Acknowledgement
bonate (EC). Triggers for heating and consequently a thermal
runaway can be short circuits or overcharging [49, 9]. Causes The authors would like to express their appreciation to all
for a short circuit during battery module disassembly, subse- industry partners, research partners and the Ministry of the En-
quent heating and thus thermal runaway may be mechanical de- vironment, Climate Protection and the Energy Sector Baden-
formation or piercing with a sharp object. Furthermore, an ex- Württemberg for supporting the project ”DeMoBat” (promo-
ternal short circuit between the two electrode poles through an tional reference L7520103). This work contributes to the re-
electrically conductive body will lead to heating and may even- search performed at KIT-BATEC (KIT Battery Technology
tually result in a thermal runaway. Hence, it is recommended to Center) and at CELEST (Center for Electrochemical Energy
permanently monitor the temperature of the cells at this point Storage Ulm-Karlsruhe).
for the detection of critical conditions in order to eject the cells
or even the entire module in an emergency scenario. A critical
temperature rise gradient can be e.g. 0.2 °C/min [50]. The mon- References
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