Phé Song ‘Thao, phuong Tho Son, thinh phé Viet Tri, tinh Phi Tho Ss CONG TY CO PHAN HOA CHAT VIET TRI VITRICI Tel: 02103911696 ~ Fax: 02103911512 PHIEU AN TOAN HOA CHAT ODIUM HYDROXIDE (NaOH) 32% (Mau theo Thong we s6 32 /2017/TT-BCT Sap 28 thing 12 ndm 2017 ctia BG Cong Tincong) 1T Giai thich ing héa chat va nha cung cap a) MA phAn loai san phim theo GHS: - $6 CAS: 1310-73-2; ~ $6 UN: 1824; ~ $6 dang ky EC: 215-185-5; thuong mai: Sodium Hydroxide. b) Muc dich sir dung va han ché khi sir dung: Ding trons ,4nh cdng nghiép nhu chat tay rita, son, sin xuat gidy, cdng nghé loe diu, céng nghé det | | nhugm, thye phim, xir ly nuée. ©) Thong tin nha sin xu: = Céng ty CP Hoa chit Vi - Phé Séng Thao, phuing Tho Son, thinh phé Viet Tri tinh Phi Tho. - Sé dign thoai: 02103911696. d) Sé dign thoai lién hé trong trong hop khan cap: Tel: 02103911511 (24h/24h) hin dang die tinh nguy hiém cia héa chat ‘) Phin loai theo GHS va théng tin phan loai theo theo sé ligu hgp I¢ c6 sin ct quéc gia, khu vyc, 16 chite thir nghigm. (Vi dy: EU, My, OSHA...) | Phan loai theo hé théng hai ha toan cu GHS: - An mon da (loai 1A) | Theo HMIS (M§) : | - Phan tng: 2 || - Bio vé ca 1 ai ‘Theo WHMIS (Canada): Chat an mon nhom E b) Cae yéu té nhan theo GHS: (Canh bao nguy hiém, hudng dan bao quan, str dung.) ELE, Wo? SO ONew3 4 Théng tin vé thanh, phan cac chit Bién php so ciru ve y té Giai thich - Caah bao nguy hiém: CAp 1 ERE Renate eee = Huong din bio quan sir dung: Déng gai trong binh chita, bao bi kin dam bao chéc chin bang vat ligu chuyén dung. ©) Cac théng tin nguy hai khae: Chua ¢6 thong tin, Nhin dang héa chat, néng d@, phim trim néng 46 trong khodng xac dinh cia tat c4 cae chat do hai trén ngwéng quy jn a) Tén thong thong: Xiit, wiit an da, hydroxit nat natri hydroxit; b) Cac nhan dang khde eda sin pha: | 86 CAS: 1310-73-2; ¢) Tén thong mai: Netti bydroxyt Céng thire héa hge: NaOH, d) Tap chat va chdt én dinh c6 anh hwéng dén vige phan logi héa chat: Khong 6. Han hop chat - Nang do NaOH: 32 %; ~ Thanh phan cht déc hai trén ngudng quy dinh: | Sodium Hydroxide (NaOH). bign php twong tng véi ce dieng phot ~ Trudug hgp tai nan khi tiép xtc v6i mit (bi ving, day vio mit): Rita mat ngay bang nude sach ria nbiéu lan trong it nhat 15 phuit (gitt cho mat mé khi rita) sau d6 nhanh chong goi cdp ctu hoe chuyén dén coasty te, - Trurdng hgp tai nan tiép wite trén da (bj day vio da): Rita ngay bing nude sgch trong it nbét 15 phot, ‘bang bé vet thuong, sau 46 nhanh chéng goi cp cin hode chuyén dén co s6y té. - Truong hgp tai nan tiép xc theo dwong bé hap (bit thé phai héa chat nguy hiém dang hoi, khi): + Chuyén noi thodng khi nghi ngoi, dit nan nhéa tr thé nita ndim nia ngdi, thdi ngat khi edn thidt; + Cho sie miéng muée sach nhidu lan, sau dé nhanh chong goi cdp ettu hoge chuyén dén co soy té 2Tr Noi dung Giai thich Bign php xit ly khi cd héa hoan chimg/tie hai nghiém trong tic thoi | va amb hung sau nai = Mat: Xit_ain_mon niém mac, gay tén_thuong a mit, c6 thé gay mi vinh vin; ~ Da: Xiit gfy kich tmg an mén da. Da bi phéng rd tay dé, c6 thé gay bong nghiém trong: ~ Hé tigu héa: Khi nudt phai xtit sé cd cam gite bong rit, soe nang c6 edm gide dau 6 ving bung | ¢) Cae chi thj vi hung din cfp citu dic biét khi | cém thidt: Chua c6 théng tin, a) Cae phurong tign chita chay thieh hop: Si dung bat ky phurong tign chia chay nao b) Che chat déc duge sinh ra khi bj ebay (khi dgec....): Khong duge coi la chét dé chay tign, trang phye bao hé va it na phong de, quin ig thm nude, ting, ging tay cao su. Bign phap phong ing phé khi c | a) Trang thiét bj bao hd va quy trinh ting phé sy eb: | ~ Trang bi béo h6: Quin Ao, ting, gang tay cao su; kinh mat; khdu trang, ~ Quy trinh img pho + Khi tran dé, 19 ri 6 mac nh6: - Kiém sodt ngay tai ngudn phat sinh; - Ding nude xéi nia Lam loding. ~ Khi tran d6, r6 ri lén & dign rong: + Tim cdch ngén rd ri (Ding cat a xung quanh khéng dé héa chat chy lan réng) két hop bom hoje ding dung cu mic thu gom chita vio thiét bj chia khée, sau 46 ding axit pha loang hod phen trung hoa, phun nude lim sach noi bj tran hay. + Lien hé véi cic bé phin, don vj c6 chive nang img, phé giai quyét su cé. | b) Cac canh bao vé mdi trudn; Cava cay corr) earn Cte iat) , vat ligu vé sinh sau Khi xay ra sir 06 da hvong dung dich tran dé + Viée Géu huy nhing dung cu ¢6 dinh hod chit tuan theo quy dinh ciia Nha nude. 3 iene AcE aTTr ‘ji dung Yiu cdu vé sir dung, bao quin Kiém soit phoi nhiém/yéu ciu vé thiét bj bao vé ci nhan a) Bign phap, diéu kign cin ap dlymg Ki si dy, thao tie voi héa chit guy = Trang bj day di quin éo BHL Dy gidy hode ing: kinh nhya BHLD, ging tay vai hoe gang tay cao su, khdu trang; = Thong gid trong hé thong nha (phéng) kin, b) Bign phap, digu kign cdn Ap dung khi bao quan = Thiét bj chita dim bio c6 d6 che chin, kin dee Jam bing vot liu chuyén dung; ajt 6 noi thodng | mnit, nbigt dG mdi trvdéng, cach xa ngudn nhigt, ngudn gay chay: - Khu vite chiza 06 nén xi mang chéng x6i mon, phai c6 bi ngiin, phuong Khong dé lan voi cae chit c6 tinh exit, khong, due chita vio logi vd lam bang Nhom, Kem, Niken, hop kim cia ching. ‘a) Cae thang $6 kidm sodit: Tuygt d6i khong dirge ‘p xtie true tiép vai héa chat, ning dd cho phép ti da trong khong khi | 2 mg/m’ khéng khi. b) Cac bign phap kiém soat thiét bi phi hgp: - Kho, thiét bj chita, cursng éng dam bao chae chan. an foi, kin; tudn tha ding ede quy dink cia Nha nuée ve aan toan hi ~ Kho, thiét bj chira pha o6 tem nhan, nhiin dng hoe | chit phi: hop véi ting Joai héa chat. bid qua dio lao, huan tuyen-va dage cde cp cé thim quyén cong nhan méi duge thye higa céng vige; khi thue hign cong viée phai trang bi day du quin 40 BHLD, giay ho%e ting; kinh nhye BHLD, ging tay vai hodc gang tay cao su, khéu trang, mat na phdng dé. Die tinh 1y, héa eta hoa chat a) Trang thai vat ung dich trong svat, trén be mat hé cd J6p vang méng, b) Diém s6i (°C): 1,390 °C (1.663 K). c) Mau sie: Khéng mau. d) Diém nding ehay (°C): 318°C (591 K). ) Mii die trung: Phan bigt khong 13 (boi ndng) ¢) Diém chay (°C) (Flash point) theo phuong phip xe dinh: Chua xic dinh. g) Ap suit héa hoi (mm Hg) & mhigt do, ap suat tigu chan: Chwra xée din.TT 12 Noi dung Giai thich c) The hai tire thi, t4e hai lau dai va nhimg anh hwéng min tinh do phoi nbiém ngin hyn va dai gn: Chua e6 thong tin, } d) Ligt ké nhiing thong sé v8 dgc tinh (use tinh mtic d§ dc edp tinh): Chua 6 thong tin ‘Théng tin vé sinh thai a) Dic mai trumg (nmrée va trén ean): Chua 06 thong tin b) Tinh bén ving, khé phan hiiy va kha ning phan hity: Chua c6 thang tin. c) Kha ning tich lity sinh hoe: Cé thé tich liy sinh héa. d) D6 linh 4Ong trong dat: Néu sa at, ching sé c6 Icha nang Linh déng va o6 thé lam 6 nhiém nude ngam. __| ) Cée thc hai khde: Chua cé théng tin. 13 Cfe théng tin xir ly an ton, cde bign php that bé, cé tinh dén bao bi nhiém déc: - Cin eff theo Luat Héa Chit s6 06/2007/QH12 ngay 21 théng 11 nim 2007 va cdc van ban huéng dan; - Xép loai nguy hiém ctia chat thai: Mi CTNH 020201; Ma EC 060203, 060204; Ma Basel (A) A4090; Ma Basel (Y) Y 35; = Bién phap thai bé: Ding axit loding trung héa dén khi pH = 7 chuyén thanh cac muéi va nude. 4 ‘Thing tin khi a) Sé higu UN: 1823 b) Tén phuong tign vgn chuyén duing bin: Sodium Hydroxide c) Logi nhom hing nguy hiém trong vin chuyé Losi 8 d) Quy céch déng géi (néu e6): Nhom LI 4) Doc méi trudng (chit 6 nhiém dai duong): Chua co6 théng tin e) Vin chuyén trong tau Ién: Xitéc, bin chia... bang vat liéu chuyén dung. g) Nhiing cinh bao dic biét ma ngudi sit dung cAn Luu ¥, cin (uain thi trong van chuyén: ~ Thidt bi chita, dudémg dng, van phai sir dung bing vat Jigu chuyén dung, dim bao chie chin, kin. - Tuyét déi khéng duoc chira xit bing cdc vat liu Nhém, kém, thiéc, chi va cdc hop kim cia ching. 15 Théng tin vé phap luat Cac théng tin phap In3t vé an toan, sire khée va mdi trudng déi voi hoa chat: ~ Luat héa chat ngay 21 thang 11 nam 2007; - = Nghi dinh s6 113/2017/ND-CP ngay 09/10/2017 iia 6Giai thich 1b) Nhigt 46 tw chy (C): Chua xée dinh. i) Ty trong hoi (Khéng khi = 1) & nhigt a9, 4p | suat tiga chun: Chua xac dinh, k) Gidi han ndng 46 chay, nb tren (% hon hop | voi khong khi): Khong phi hop. D BG hoa tan trong made: Hoa tan oda toan. m) Giéi han nong dO chay, nd duéi (% hon hop véi khing khi: Khong phit hop. 1n) DG pH: (dung dich 5%) = 14, | 0) TY Ig ha hoi: Khong phi hop. p) Khéi hong riéng (kg/m*): > 1,330 6 25°C. q) Céc tinh chat khiée néu e6: Chua c6 thong tin 10 i ‘M(te én djnh va phan ting ciia héa chat Théng tin vé d6c tinh a) Kha nang phan img: Xit 1a mt bazo (kiém) manh, phan img dae tong la téc dung voi axit, 6 axit, céc mudi kim loai va tic dyng vi mét so kim | Togi nhwr nhém (Al), km (Zn), thiée (Sn), chi (Pb) giai phong ra khi hydro (Hz) gay chay, né. b) Tink én @jnh: On dinh cao. 6) Phan sing nguy hiém: Phin ime v6i nti, kem, chay nd, rung, | ) Cae digu kign cd trinh (vi dp: nh di lie. .): Khong phit hop. a) v: z E e = & . e S g & a é g E é ) Phin tng phan buy va cde sin pha phan ting phin hay: Chua gtin _| a) Thong tin vé ede dudng phoi uhiém khie nhau + Duong thd: Chua e6 théng tin; - Duong tiéu héa: Chua c6 théng tin; ~ Tigp xie mit, du: Cha e6 thong tin, b) Cac trigu ching lién quan dén tinh adc hai cia ha chat va d§e sinh thai - Thé (h6 hap): Cam théy néng rét hong, nghen, ho | kho Khe, viém thank quan, kho thd, dau dau. - Mat: Bong rat, sung tdy d6, chy nude mit oé thé din dén mi loa: ~ Da: Mite d6 thy thude vao thdi gian tiép xte neva da, rit dé, viém hode sumg, cde mé tigp xtc; sinh thai thim den rung 1é, tiép xtc thoi gian dai | | s@ chat cay, + Dong vat tiép xtc thoi gian dai sé chét, 5NOi dung Giai thich Chinh pha ban hanh Nghi dinh quy dinh chi tt va hung dn thi hanh mét s6 diéu cla Luat héa chét; cia CP quy dinh Danh myc hang nguy hiém va van chuyén hang nguy hiém bing phuong tién giao thdng co gidi duong bo; - Thing tu 86 32/2017/TT-BCT ngay 28/12/2017 eta Bé Céng throng quy dinh cy thé va hung dan thi hanh mét sé diéu cia Ludt hoa chit vi Nghi dinh sé 113/2017/ND-CP ngay 09/10/2017 cua Chinh phi quy dinh chi tiét va huéng din thi hanh mét sé diéu cia Luat héa chat. 16 ‘Cée théng tin edn thiét kha, bao gdm cdc théng tin khi xiy dung ‘va higu inh Phiéu an toan héa chat ~ Ngay thang bién soan phiéu: Ngdy 01/8/2007. ~ Ngay thang bé sung gan nhat: Ngay 04/6/2020; - Nhiing théng tin trong phiéu an toan hod chdt nay duoc bién sogn dya trén cdc kién thie hop 18, méi nhdt vé hod chit nguy hiém va phai duge st dung dé thye hign céc bién phép ngin ngira ri ro, tai nan, tuy nhién ching khéng thé dim bao cho su an toan mOt cdch tuyét di, Hoa chdt nguy hiém trong phiéu nay 06 thé cé nhiing tinh chat nguy hiém khdc tuy theo hoan canh sit dung va tiép xéc. Trach nhigm cia ngudi sit dung 1a phai biét 4p dung, xdc dinh nhimg théng tin cdn thiét va st dung ching that than trong trong timg myc dich. = Nghi_dinh_s6 104/2009/ND-CP ngay 09/11/2009 |