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Environmental
Chemicals
Desk Reference

John H. Montgomery
Thomas Roy Crompton
Environmental Chemicals
Desk Reference
Environmental Chemicals
Desk Reference

John H. Montgomery and Thomas Roy Crompton


CRC Press
Taylor & Francis Group
6000 Broken Sound Parkway NW, Suite 300
Boca Raton, FL 33487-2742

© 2018 by Taylor & Francis Group, LLC


CRC Press is an imprint of Taylor & Francis Group, an Informa business

No claim to original U.S. Government works

Printed on acid-free paper

International Standard Book Number-13: 978-1-4987-7573-1 (Hardback)

This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and
information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors
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Library of Congress Cataloging-in-Publication Data

Names: Montgomery, John H. (John Harold), 1955- | Crompton, T. R. (Thomas


Roy) | Montgomery, John H. (John Harold), 1955- Agrochemicals desk
reference. | Montgomery, John H. (John Harold), 1955- Groundwater
chemicals desk reference.
Title: Environmental chemicals desk reference / John H. Montgomery and Thomas
Roy Crompton.
Description: Boca Raton : CRC Press, [2017] | A concise version of the
Agrochemicals desk reference, and the Groundwater chemicals desk
reference. | Includes bibliographical references and index.
Identifiers: LCCN 2017003200| ISBN 9781498775731 (hardback : alk. paper) |
ISBN 9781315169026 (ebook)
Subjects: LCSH: Agricultural chemicals--Environmental aspects--Handbooks,
manuals, etc. | Agricultural chemicals--Handbooks, manuals, etc. |
Groundwater--Pollution--Handbooks, manuals, etc. | Pollutants--Handbooks,
manuals, etc. | Environmental chemistry--Handbooks, manuals, etc.
Classification: LCC TD196.A34 M68 2017 | DDC 628.5/2--dc23
LC record available at https://lccn.loc.gov/2017003200

Visit the Taylor & Francis Web site at


http://www.taylorandfrancis.com
and the CRC Press Web site at
http://www.crcpress.com
Contents

Preface............................................................................................................................................................................................................................... xxi
Abbreviations and Symbols....................................................................................................................................................................................xxiii
Designations................................................................................................................................................................................................................xxvii
Physical and Chemical Symbols......................................................................................................................................................................... xxxvii
Registration, Evaluation, Authorization, and Restriction of Chemicals (REACH)................................................................................... xliii
Introduction.................................................................................................................................................................................................................... xlv

Chapter 1 Physical Properties of Agrochemicals..............................................................................................................................................1


Acephate....................................................................................................................................................................................................1
Alachlor.......................................................................................................................................................................................................2
Aldicarb.......................................................................................................................................................................................................4
Allidochlor.................................................................................................................................................................................................7
Ametryn......................................................................................................................................................................................................9
Aminocarb...............................................................................................................................................................................................11
Amitrole....................................................................................................................................................................................................11
Anilazine.................................................................................................................................................................................................. 13
Aspon������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������ 14
Asulam..................................................................................................................................................................................................... 14
Atrazine.................................................................................................................................................................................................... 15
Azinphos-Methyl.................................................................................................................................................................................. 21
Bendiocarb............................................................................................................................................................................................. 23
Benfluralin............................................................................................................................................................................................... 24
Benomyl................................................................................................................................................................................................... 25
Bentazone............................................................................................................................................................................................... 26
Bifenox..................................................................................................................................................................................................... 27
Bromacil................................................................................................................................................................................................... 28
Bromoxynil............................................................................................................................................................................................. 31
Bromoxynil Octanoate....................................................................................................................................................................... 31
Butifos...................................................................................................................................................................................................... 32
Butylate.................................................................................................................................................................................................... 32
Captan...................................................................................................................................................................................................... 33
Carbophenothion................................................................................................................................................................................ 34
Carboxin.................................................................................................................................................................................................. 35
Chloramben........................................................................................................................................................................................... 36
Chlordimeform...................................................................................................................................................................................... 37
Chlorobenzilate.................................................................................................................................................................................... 38
Chlorothalonil........................................................................................................................................................................................ 39
Chloroxuron...........................................................................................................................................................................................40
Chlorpropham....................................................................................................................................................................................... 41
Chlorsulfuron......................................................................................................................................................................................... 43
Chlorthal-Dimethyl..............................................................................................................................................................................44
Crotoxyphos........................................................................................................................................................................................... 45
Cyanazine................................................................................................................................................................................................ 45
Cycloate................................................................................................................................................................................................... 47
Cyfluthrin................................................................................................................................................................................................. 47
Cypermethrin.........................................................................................................................................................................................48

v
vi    Contents

Cyromazine.............................................................................................................................................................................................48
Dalapon-Sodium.................................................................................................................................................................................. 49
Dazomet.................................................................................................................................................................................................. 50
Desmedipham....................................................................................................................................................................................... 51
Dialifos...................................................................................................................................................................................................... 51
Diallate..................................................................................................................................................................................................... 52
Diazinon................................................................................................................................................................................................... 53
Dicamba.................................................................................................................................................................................................. 56
Dichlobenil............................................................................................................................................................................................. 57
Dichlone.................................................................................................................................................................................................. 59
Diclofop-Methyl.................................................................................................................................................................................... 60
Dicofol...................................................................................................................................................................................................... 60
Dicrotophos........................................................................................................................................................................................... 61
Dienochlor.............................................................................................................................................................................................. 62
Difenzoquat Methyl Sulfate.............................................................................................................................................................. 63
Diflubenzuron.......................................................................................................................................................................................64
Dimethoate............................................................................................................................................................................................64
Dinoseb....................................................................................................................................................................................................66
Diphenamid........................................................................................................................................................................................... 67
Dipropetryn............................................................................................................................................................................................ 68
Diquat....................................................................................................................................................................................................... 68
Disulfoton............................................................................................................................................................................................... 70
Endothall................................................................................................................................................................................................. 71
EPTC��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������� 72
Esfenvalerate.......................................................................................................................................................................................... 74
Ethephon................................................................................................................................................................................................. 74
Ethiofencarb........................................................................................................................................................................................... 75
Ethion....................................................................................................................................................................................................... 75
Ethoprop................................................................................................................................................................................................. 77
Fenamiphos............................................................................................................................................................................................ 78
Fenbutatin Oxide.................................................................................................................................................................................. 79
Fenoxaprop-Ethyl................................................................................................................................................................................. 80
Fensulfothion......................................................................................................................................................................................... 80
Fenthion.................................................................................................................................................................................................. 81
Fenvalerate............................................................................................................................................................................................. 82
Ferbam..................................................................................................................................................................................................... 83
Flucythrinate..........................................................................................................................................................................................84
Fluometuron..........................................................................................................................................................................................84
Fonofos.................................................................................................................................................................................................... 85
Fosamine-Ammonium....................................................................................................................................................................... 86
Fosetyl-Aluminum............................................................................................................................................................................... 87
Glyphosate.............................................................................................................................................................................................. 87
Hexazinone............................................................................................................................................................................................. 89
Hexythiazox............................................................................................................................................................................................ 91
Iprodione................................................................................................................................................................................................. 91
Isofenphos.............................................................................................................................................................................................. 92
Linuron..................................................................................................................................................................................................... 93
Maleic Hydrazide.................................................................................................................................................................................. 95
Mancozeb................................................................................................................................................................................................ 96
MCPA�������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������� 97
Mefluidide............................................................................................................................................................................................... 98
Metalaxyl................................................................................................................................................................................................. 98
Metaldehyde........................................................................................................................................................................................100
Methamidophos.................................................................................................................................................................................100
Methidathion.......................................................................................................................................................................................101
Contents    vii

Methiocarb...........................................................................................................................................................................................102
Methomyl..............................................................................................................................................................................................103
Methyl Isothiocyanate......................................................................................................................................................................104
Metribuzin............................................................................................................................................................................................104
Metsulfuron-Methyl..........................................................................................................................................................................106
Molinate.................................................................................................................................................................................................106
Monalide...............................................................................................................................................................................................107
Monocrotophos..................................................................................................................................................................................108
Monuron................................................................................................................................................................................................109
Napropamide........................................................................................................................................................................................111
Naptalam............................................................................................................................................................................................... 113
Neburon................................................................................................................................................................................................. 114
Oxadiazon............................................................................................................................................................................................. 114
Oxamyl................................................................................................................................................................................................... 115
Oxydemeton-Methyl......................................................................................................................................................................... 117
Pebulate................................................................................................................................................................................................. 118
Pendimethalin..................................................................................................................................................................................... 118
Pentachlorobenzene.........................................................................................................................................................................120
Pentachloronitrobenzene............................................................................................................................................................... 121
Pentachlorophenol............................................................................................................................................................................ 121
Permethrin............................................................................................................................................................................................ 124
Phenmedipham.................................................................................................................................................................................. 126
Phorate................................................................................................................................................................................................... 126
Phosalone.............................................................................................................................................................................................128
Phosmet.................................................................................................................................................................................................129
Phosphamidon....................................................................................................................................................................................130
Picloram................................................................................................................................................................................................. 131
Profenofos............................................................................................................................................................................................. 133
Prometon..............................................................................................................................................................................................134
Prometryn.............................................................................................................................................................................................136
Propachlor............................................................................................................................................................................................138
Propanil.................................................................................................................................................................................................. 139
Propazine..............................................................................................................................................................................................140
Propham................................................................................................................................................................................................ 142
Propoxur................................................................................................................................................................................................143
Propyzamide........................................................................................................................................................................................144
Quinomethionate..............................................................................................................................................................................145
Quizalofop-Ethyl.................................................................................................................................................................................146
Siduron...................................................................................................................................................................................................146
Simazine................................................................................................................................................................................................ 147
Sulfometuron-Methyl....................................................................................................................................................................... 152
Sulprofos............................................................................................................................................................................................... 153
Tebuthiuron..........................................................................................................................................................................................154
Terbacil...................................................................................................................................................................................................154
Terbufos................................................................................................................................................................................................. 155
Terbutryn...............................................................................................................................................................................................156
Thiabendazole.....................................................................................................................................................................................157
Thiameturon-Methyl.........................................................................................................................................................................158
Thidiazuron.......................................................................................................................................................................................... 159
Thiodicarb............................................................................................................................................................................................. 159
Triadimefon..........................................................................................................................................................................................160
Triallate................................................................................................................................................................................................... 161
Trichlorfon............................................................................................................................................................................................162
2,3,6-Trichlorobenzoic Acid............................................................................................................................................................163
Triclopyr.................................................................................................................................................................................................164
viii    Contents

Chapter 2 Physical Properties of Organic Pollutants.................................................................................................................................165

Chapter 3 Environmental Fate Data for Miscellaneous Compounds...................................................................................................567


Acephate...............................................................................................................................................................................................567
Acetamide.............................................................................................................................................................................................567
Acetophenone....................................................................................................................................................................................567
Alachlor..................................................................................................................................................................................................567
Aldicarb..................................................................................................................................................................................................569
Aldicarb Sulfone.................................................................................................................................................................................571
Aldicarb Sulfoxide..............................................................................................................................................................................571
Allidochlor............................................................................................................................................................................................571
Ametryn.................................................................................................................................................................................................571
Amidosulfuron....................................................................................................................................................................................572
Aminocarb............................................................................................................................................................................................572
2-Amino-3-Chlorobenzoic Acid....................................................................................................................................................572
4-Amino-3,5-Dichlorobenzoic Acid.............................................................................................................................................572
2-Amino-3-Nitrotoluene..................................................................................................................................................................573
Amitrole.................................................................................................................................................................................................573
Anilazine................................................................................................................................................................................................573
Asulam...................................................................................................................................................................................................574
Atrazine..................................................................................................................................................................................................574
Azinphos-Methyl................................................................................................................................................................................578
Bendiocarb...........................................................................................................................................................................................579
Benfluralin.............................................................................................................................................................................................579
Benomyl.................................................................................................................................................................................................580
Bensulfuron..........................................................................................................................................................................................580
Bensulfuron-Methyl...........................................................................................................................................................................580
Bentazone.............................................................................................................................................................................................580
Bifenox...................................................................................................................................................................................................581
Bisphenol A..........................................................................................................................................................................................581
Bromacil.................................................................................................................................................................................................582
p-Bromoaniline...................................................................................................................................................................................582
2-Bromobenzoic Acid.......................................................................................................................................................................583
3-Bromobenzoic Acid.......................................................................................................................................................................583
4-Bromobenzoic Acid.......................................................................................................................................................................583
p-Bromophenol...................................................................................................................................................................................583
Bromoxynil...........................................................................................................................................................................................583
Bromoxynil Octanoate.....................................................................................................................................................................584
Butylate..................................................................................................................................................................................................584
tert-Butyl Formate..............................................................................................................................................................................584
Camphene............................................................................................................................................................................................584
Captan....................................................................................................................................................................................................585
Carbophenothion..............................................................................................................................................................................585
Carboxin................................................................................................................................................................................................585
Catechol.................................................................................................................................................................................................585
Chloramben.........................................................................................................................................................................................585
Chlordimeform....................................................................................................................................................................................586
Chlorimuron-Ethyl.............................................................................................................................................................................586
2-Chlorobenzoic Acid.......................................................................................................................................................................586
3-Chlorobenzoic Acid.......................................................................................................................................................................587
Chlorobenzilate..................................................................................................................................................................................587
2-Chlorobiphenyl...............................................................................................................................................................................587
4-Chlorobiphenyl...............................................................................................................................................................................587
2-Chlorodiphenylmethane.............................................................................................................................................................588
3-Chlorodiphenylmethane.............................................................................................................................................................588
Contents    ix

4-Chlorodiphenylmethane.............................................................................................................................................................588
o-Chloronitrobenzene......................................................................................................................................................................588
3-Chlorophenol...................................................................................................................................................................................588
4-Chlorophenol...................................................................................................................................................................................589
3-Chloro-1-Propanol.........................................................................................................................................................................589
Chlorothalonil......................................................................................................................................................................................589
Chloroxuron.........................................................................................................................................................................................590
Chlorphenamidine.............................................................................................................................................................................590
Chlorpropham.....................................................................................................................................................................................590
Chlorsulfuron.......................................................................................................................................................................................591
Chlorthal-Dimethyl............................................................................................................................................................................591
Cinnamic Acid......................................................................................................................................................................................591
Crotoxyphos.........................................................................................................................................................................................592
Cyanazine..............................................................................................................................................................................................592
Cycloate.................................................................................................................................................................................................592
Cyfluthrin...............................................................................................................................................................................................592
Cypermethrin.......................................................................................................................................................................................592
Cyromazine...........................................................................................................................................................................................593
1-Decanol..............................................................................................................................................................................................593
Dalapon-Sodium................................................................................................................................................................................593
Dazomet................................................................................................................................................................................................593
2-Decanone..........................................................................................................................................................................................593
Desmedipham.....................................................................................................................................................................................594
Dialifor....................................................................................................................................................................................................594
Dialifos....................................................................................................................................................................................................594
Diallate...................................................................................................................................................................................................594
Diazinon.................................................................................................................................................................................................594
Dibutyl Sulfide.....................................................................................................................................................................................596
Dicamba................................................................................................................................................................................................596
Dicapthon.............................................................................................................................................................................................597
Dichlobenil...........................................................................................................................................................................................597
Dichlone................................................................................................................................................................................................598
2,5-Dichlorobenzoic Acid................................................................................................................................................................598
3,4-Dichlorobenzoic Acid................................................................................................................................................................598
3,5-Dichlorobenzoic Acid................................................................................................................................................................598
2,6-Dichlorobenzonitrile..................................................................................................................................................................599
2,4′-Dichlorobiphenyl.......................................................................................................................................................................599
2,4-Dichlorodiphenylmethane......................................................................................................................................................599
2,5-Dichlorodiphenylmethane......................................................................................................................................................599
2,6-Dichlorodiphenylmethane......................................................................................................................................................599
3,4-Dichlorodiphenylmethane..................................................................................................................................................... 600
2,3-Dichloronitrobenzene.............................................................................................................................................................. 600
3,4-Dichloronitrobenzene.............................................................................................................................................................. 600
3,4-Dichlorophenol.......................................................................................................................................................................... 600
1,3-Dichloropropane........................................................................................................................................................................ 600
2,2-Dichloropropane........................................................................................................................................................................ 600
Diclofop-Methyl..................................................................................................................................................................................601
Dicofol....................................................................................................................................................................................................601
Dicrotophos.........................................................................................................................................................................................601
Dienochlor............................................................................................................................................................................................601
2,6-Diethylnaphthalene...................................................................................................................................................................602
Difenzoquat Methyl Sulfate............................................................................................................................................................602
Diflubenzuron.....................................................................................................................................................................................602
Diisobutyl Phthalate..........................................................................................................................................................................602
2,6-Diisopropylnaphthalene..........................................................................................................................................................602
2,7-Diisopropylnaphthalene..........................................................................................................................................................602
x    Contents

Dimethoate..........................................................................................................................................................................................603
2,6-Dimethylnaphthalene...............................................................................................................................................................603
2,2-Dimethyloxirane..........................................................................................................................................................................603
cis-2,3-Dimethyloxirane.................................................................................................................................................................. 604
trans-2,3-Dimethyloxirane............................................................................................................................................................. 604
Dimethyl Sulfide................................................................................................................................................................................ 604
3,5-Dinitrobenzoic Acid.................................................................................................................................................................. 604
Dinoseb................................................................................................................................................................................................. 604
2,4-D, n-Octyl Ester........................................................................................................................................................................... 604
Diphenamid.........................................................................................................................................................................................605
Diphenylamine....................................................................................................................................................................................605
Dipropetryn..........................................................................................................................................................................................605
Disulfoton.............................................................................................................................................................................................605
Diquat.....................................................................................................................................................................................................605
Disulfoton.............................................................................................................................................................................................606
1-Dodecanol........................................................................................................................................................................................607
Endothall...............................................................................................................................................................................................607
EPTC�������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������607
Esfenvalerate........................................................................................................................................................................................608
Ethametsulfuron-Methyl.................................................................................................................................................................608
Ethanol...................................................................................................................................................................................................608
Ethephon...............................................................................................................................................................................................608
Ethiofencarb.........................................................................................................................................................................................608
Ethion.....................................................................................................................................................................................................608
Ethoprop...............................................................................................................................................................................................609
Ethyl tert-Butyl Ether.........................................................................................................................................................................609
Ethylene Oxide....................................................................................................................................................................................609
Ethylene Thiourea..............................................................................................................................................................................609
2-Ethyl-1-Hexanol..............................................................................................................................................................................609
2-Ethylnaphthalene........................................................................................................................................................................... 610
Ethyl Sulfide.......................................................................................................................................................................................... 610
Fenamiphos.......................................................................................................................................................................................... 610
Fenbutatin Oxide................................................................................................................................................................................ 610
Fenoxaprop-Ethyl............................................................................................................................................................................... 610
Fensulfothion....................................................................................................................................................................................... 610
Fenthion................................................................................................................................................................................................ 611
Fenvalerate........................................................................................................................................................................................... 611
Ferbam................................................................................................................................................................................................... 611
Ferulic Acid........................................................................................................................................................................................... 612
Flucythrinate........................................................................................................................................................................................ 612
Fluometuron........................................................................................................................................................................................ 612
Fluorodifen........................................................................................................................................................................................... 612
Fonofos.................................................................................................................................................................................................. 612
Fosamine-Ammonium..................................................................................................................................................................... 613
Fosetyl-Aluminum............................................................................................................................................................................. 613
Glycine.................................................................................................................................................................................................... 613
Glyphosate............................................................................................................................................................................................ 613
1-Heptanol............................................................................................................................................................................................ 614
2,2′,4,4′,5,5′-Hexachlorobiphenyl................................................................................................................................................. 614
1-Hexanol.............................................................................................................................................................................................. 614
Hexazinone........................................................................................................................................................................................... 614
Hexythiazox.......................................................................................................................................................................................... 615
4-Hydroxyacetophenone................................................................................................................................................................ 615
4-Hydroxybenzoic Acid.................................................................................................................................................................... 615
2-Hydroxybiphenyl............................................................................................................................................................................ 615
Imidacloprid......................................................................................................................................................................................... 615
Contents    xi

2-Iodobenzoic Acid........................................................................................................................................................................... 616


3-Iodobenzoic Acid........................................................................................................................................................................... 616
4-Iodobenzoic Acid........................................................................................................................................................................... 616
Iprodione............................................................................................................................................................................................... 616
Isofenphos............................................................................................................................................................................................ 616
Isopropyl Alcohol............................................................................................................................................................................... 617
2-Isopropylnaphthalene.................................................................................................................................................................. 617
Isoxaflutole........................................................................................................................................................................................... 617
Leptophos............................................................................................................................................................................................. 617
d-Limonene.......................................................................................................................................................................................... 618
Linuron................................................................................................................................................................................................... 618
Maleic Hydrazide................................................................................................................................................................................ 618
Mancozeb.............................................................................................................................................................................................. 619
Maneb.................................................................................................................................................................................................... 619
MCPA������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������619
MDTC�����������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������620
Mecoprop..............................................................................................................................................................................................620
Mefluidide.............................................................................................................................................................................................620
Metalaxyl...............................................................................................................................................................................................620
Metaldehyde........................................................................................................................................................................................621
Methabenzthiazuron........................................................................................................................................................................621
Methacrylonitrile................................................................................................................................................................................621
Methazole.............................................................................................................................................................................................621
Methidathion.......................................................................................................................................................................................621
Methiocarb...........................................................................................................................................................................................622
Methomyl..............................................................................................................................................................................................622
3-Methyl-2-Butanone.......................................................................................................................................................................622
2-Methyl-2-Butene.............................................................................................................................................................................623
Methyl Chlorpyrifos...........................................................................................................................................................................623
Methyl tert-Butyl Ether.....................................................................................................................................................................623
Methylene Bromide...........................................................................................................................................................................624
1-Methylnaphthalene.......................................................................................................................................................................624
Methyl Sulfide......................................................................................................................................................................................624
Metobromuron...................................................................................................................................................................................624
Metolachlor..........................................................................................................................................................................................624
Metribuzin............................................................................................................................................................................................625
Metsulfuron-Methyl..........................................................................................................................................................................626
Molinate.................................................................................................................................................................................................626
Monalide...............................................................................................................................................................................................626
Monocrotophos..................................................................................................................................................................................627
Monuron................................................................................................................................................................................................627
Napropamide.......................................................................................................................................................................................628
Naptalam...............................................................................................................................................................................................629
Neburon.................................................................................................................................................................................................629
Nicosulfuron.........................................................................................................................................................................................629
3-Nitrobenzoic Acid...........................................................................................................................................................................629
4-Nitrobenzoic Acid...........................................................................................................................................................................629
Nitrofen..................................................................................................................................................................................................629
1-Nonanol.............................................................................................................................................................................................629
1-Octanol..............................................................................................................................................................................................630
2-Octanone..........................................................................................................................................................................................630
Oxadiazon.............................................................................................................................................................................................630
Oxamyl...................................................................................................................................................................................................630
Oxydemeton-Methyl.........................................................................................................................................................................630
Pebulate.................................................................................................................................................................................................631
Pendimethalin.....................................................................................................................................................................................631
xii    Contents

Pentachloronitrobenzene...............................................................................................................................................................632
1,1,2,3,3-Pentachloropropane.......................................................................................................................................................632
1-Pentanol.............................................................................................................................................................................................632
3-Pentanone.........................................................................................................................................................................................632
Permethrin............................................................................................................................................................................................632
α-Phellandrene...................................................................................................................................................................................633
Phenmedipham..................................................................................................................................................................................633
o-Phenyphenol....................................................................................................................................................................................633
Phorate...................................................................................................................................................................................................634
Phorate Sulfone..................................................................................................................................................................................635
Phorate Sulfoxide...............................................................................................................................................................................635
Phosalone.............................................................................................................................................................................................635
Phosmet.................................................................................................................................................................................................635
Picloram.................................................................................................................................................................................................635
α-Pinene................................................................................................................................................................................................636
β-Pinene.................................................................................................................................................................................................636
Primisulfuron-Methyl........................................................................................................................................................................637
Profenofos.............................................................................................................................................................................................637
Prometon..............................................................................................................................................................................................637
Prometryn.............................................................................................................................................................................................637
Propachlor............................................................................................................................................................................................638
Propanil..................................................................................................................................................................................................639
Propazine............................................................................................................................................................................................. 640
Propham............................................................................................................................................................................................... 640
Propoxur............................................................................................................................................................................................... 640
Propylthiourea.....................................................................................................................................................................................641
Propyzamide........................................................................................................................................................................................641
Prosulfuron...........................................................................................................................................................................................641
Protocatechuic Acid..........................................................................................................................................................................641
Quizalofop-Ethyl.................................................................................................................................................................................642
Rotenone...............................................................................................................................................................................................642
Siduron...................................................................................................................................................................................................642
Simazine................................................................................................................................................................................................642
Sulfometuron-Methyl.......................................................................................................................................................................643
Sulprofos...............................................................................................................................................................................................643
Syringaldehyde.................................................................................................................................................................................. 644
Syringic Acid....................................................................................................................................................................................... 644
Tebuthiuron......................................................................................................................................................................................... 644
Terbacil.................................................................................................................................................................................................. 644
Terbufos.................................................................................................................................................................................................645
Terbufos Sulfone.................................................................................................................................................................................645
Terbufos Sulfoxide.............................................................................................................................................................................645
Terbuthylazin.......................................................................................................................................................................................645
Terbutol..................................................................................................................................................................................................645
Terbutryn.............................................................................................................................................................................................. 646
3,3′,4,4′-Tetrachlorobiphenyl........................................................................................................................................................ 646
1,1,1,2-Tetrachloroethane.............................................................................................................................................................. 646
2,3,4,5-Tetrachlorophenol.............................................................................................................................................................. 646
1,1,2,3-Tetrachloropropane........................................................................................................................................................... 646
Tetramethyloxirane...........................................................................................................................................................................647
Thiabendazole.....................................................................................................................................................................................647
Thiadiazuron........................................................................................................................................................................................647
Thifensulfuron-Methyl......................................................................................................................................................................647
Thiobencarb.........................................................................................................................................................................................647
Thiodicarb.............................................................................................................................................................................................647
Thiometon............................................................................................................................................................................................647
Contents    xiii

p-Toluidine........................................................................................................................................................................................... 648
Triadimefon......................................................................................................................................................................................... 648
Triallate.................................................................................................................................................................................................. 648
Triapenthenol..................................................................................................................................................................................... 648
Triasulfuron.......................................................................................................................................................................................... 648
Tribenuron-Methyl.............................................................................................................................................................................649
Trichlorfon............................................................................................................................................................................................649
2,3,6-Trichlorobenzoic Acid............................................................................................................................................................649
2,4,5-Trichlorobiphenyl....................................................................................................................................................................649
4,5,6-Trichloroguaiacol.....................................................................................................................................................................649
2,3,4-Trichlorophenol........................................................................................................................................................................650
2,4,5-Trichlorophenol........................................................................................................................................................................650
1,1,1-Trichloro-2,2,2-Trifluoroethane...........................................................................................................................................650
Triclopyr.................................................................................................................................................................................................650
2,2,3-Trimethyloxirane......................................................................................................................................................................651
1-Undecanol.........................................................................................................................................................................................651
Urea��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������651
Vanillin....................................................................................................................................................................................................651
Vanillic Acid..........................................................................................................................................................................................651
Vinclozolin............................................................................................................................................................................................651

Chapter 4 Physical Properties of Individual Groundwater Chemicals.................................................................................................653


Acenaphthene.....................................................................................................................................................................................653
Acenaphthylene.................................................................................................................................................................................657
Acetaldehyde.......................................................................................................................................................................................659
Acetic Acid............................................................................................................................................................................................662
Acetic Anhydride................................................................................................................................................................................665
Acetone..................................................................................................................................................................................................666
Acetonitrile...........................................................................................................................................................................................670
2-Acetylaminofluorene....................................................................................................................................................................672
Acrolein..................................................................................................................................................................................................673
Acrylamide............................................................................................................................................................................................675
Acrylonitrile..........................................................................................................................................................................................677
Aldrin�����������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������680
Allyl Alcohol.........................................................................................................................................................................................683
Allyl Chloride........................................................................................................................................................................................685
Allyl Glycidyl Ether.............................................................................................................................................................................686
4-Aminobiphenyl...............................................................................................................................................................................688
2-Aminopyridine................................................................................................................................................................................689
Ammonia...............................................................................................................................................................................................690
Amyl Acetate........................................................................................................................................................................................691
sec-Amyl Acetate................................................................................................................................................................................693
Aniline....................................................................................................................................................................................................694
o-Anisidine............................................................................................................................................................................................698
p-Anisidine............................................................................................................................................................................................699
Anthracene...........................................................................................................................................................................................700
Antu��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������706
Benzene.................................................................................................................................................................................................707
Benzidine...............................................................................................................................................................................................714
Benzo[a]Anthracene.........................................................................................................................................................................716
Benzo[b]Fluoranthene...................................................................................................................................................................... 719
Benzo[k]Fluoranthene......................................................................................................................................................................721
Benzoic Acid.........................................................................................................................................................................................723
Benzo[ghi]Perylene............................................................................................................................................................................726
Benzo[a]Pyrene...................................................................................................................................................................................727
xiv    Contents

Benzo[e]Pyrene...................................................................................................................................................................................732
Benzyl Alcohol.....................................................................................................................................................................................734
Benzyl Butyl Phthalate.....................................................................................................................................................................736
Benzyl Chloride...................................................................................................................................................................................738
α-BHC.....................................................................................................................................................................................................740
β-BHC�����������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������742
δ-BHC�����������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������744
Biphenyl.................................................................................................................................................................................................745
Bis(2-Chloroethoxy)Methane.........................................................................................................................................................749
Bis(2-Chloroethyl) Ether...................................................................................................................................................................750
Bis(2-Chloroisopropyl) Ether..........................................................................................................................................................752
Bis(2-Ethylhexyl) Phthalate.............................................................................................................................................................753
Bromobenzene....................................................................................................................................................................................757
Bromochloromethane......................................................................................................................................................................759
Bromodichloromethane..................................................................................................................................................................760
Bromoform...........................................................................................................................................................................................762
4-Bromophenyl Phenyl Ether.........................................................................................................................................................764
Bromotrifluoromethane..................................................................................................................................................................765
1,3-Butadiene......................................................................................................................................................................................766
Butane....................................................................................................................................................................................................768
1-Butanol...............................................................................................................................................................................................771
2-Butanone...........................................................................................................................................................................................774
1-Butene................................................................................................................................................................................................777
2-Butoxyethanol.................................................................................................................................................................................779
Butyl Acetate........................................................................................................................................................................................781
sec-Butyl Acetate................................................................................................................................................................................783
tert-Butyl Acetate...............................................................................................................................................................................784
sec-Butyl Alcohol................................................................................................................................................................................785
tert-Butyl Alcohol...............................................................................................................................................................................787
Butylbenzene.......................................................................................................................................................................................789
sec-Butylbenzene...............................................................................................................................................................................791
tert-Butylbenzene..............................................................................................................................................................................793
Butyl Mercaptan.................................................................................................................................................................................794
Camphor................................................................................................................................................................................................795
Carbaryl..................................................................................................................................................................................................797
Carbofuran............................................................................................................................................................................................802
Carbon Disulfide.................................................................................................................................................................................805
Carbon Tetrachloride........................................................................................................................................................................807
Chlordane............................................................................................................................................................................................. 811
cis-Chlordane....................................................................................................................................................................................... 814
trans-Chlordane.................................................................................................................................................................................. 815
Chloroacetaldehyde.......................................................................................................................................................................... 817
α-Chloroacetophenone................................................................................................................................................................... 818
4-Chloroaniline................................................................................................................................................................................... 819
Chlorobenzene....................................................................................................................................................................................821
o-Chlorobenzylidenemalononitrile.............................................................................................................................................826
p-Chloro-m-Cresol.............................................................................................................................................................................827
Chloroethane.......................................................................................................................................................................................828
2-Chloroethyl Vinyl Ether.................................................................................................................................................................830
Chloroform...........................................................................................................................................................................................831
2-Chloronaphthalene.......................................................................................................................................................................835
p-Chloronitrobenzene......................................................................................................................................................................836
1-Chloro-1-Nitropropane................................................................................................................................................................838
2-Chlorophenol...................................................................................................................................................................................839
4-Chlorophenyl Phenyl Ether.........................................................................................................................................................842
Chloropicrin.........................................................................................................................................................................................843
Contents    xv

Chloroprene........................................................................................................................................................................................ 844
Chlorpyrifos..........................................................................................................................................................................................845
Chrysene............................................................................................................................................................................................... 848
Crotonaldehyde..................................................................................................................................................................................851
Cycloheptane.......................................................................................................................................................................................853
Cyclohexane.........................................................................................................................................................................................854
Cyclohexanol.......................................................................................................................................................................................857
Cyclohexanone...................................................................................................................................................................................859
Cyclohexene.........................................................................................................................................................................................860
Cyclopentadiene................................................................................................................................................................................862
Cyclopentane...................................................................................................................................................................................... 864
Cyclopentene.......................................................................................................................................................................................865
2,4-D�������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������867
p,p′-DDD................................................................................................................................................................................................872
p,p′-DDE.................................................................................................................................................................................................873
p,p′-DDT.................................................................................................................................................................................................876
Decahydronaphthalene...................................................................................................................................................................882
Decane...................................................................................................................................................................................................883
Diacetone Alcohol.............................................................................................................................................................................886
Dibenz[a,h]Anthracene....................................................................................................................................................................887
Dibenzofuran.......................................................................................................................................................................................889
1,4-Dibromobenzene........................................................................................................................................................................891
Dibromochloromethane.................................................................................................................................................................893
1,2-Dibromo-3-Chloropropane.....................................................................................................................................................895
Dibromodifluoromethane..............................................................................................................................................................897
Di-n-Butyl Phthalate..........................................................................................................................................................................898
1,2-Dichlorobenzene........................................................................................................................................................................901
1,3-Dichlorobenzene........................................................................................................................................................................905
1,4-Dichlorobenzene........................................................................................................................................................................908
3,3′-Dichlorobenzidine..................................................................................................................................................................... 912
Dichlorodifluoromethane............................................................................................................................................................... 913
1,3-Dichloro-5,5-Dimethylhydantoin.......................................................................................................................................... 915
1,1-Dichloroethane............................................................................................................................................................................916
1,2-Dichloroethane............................................................................................................................................................................ 918
1,1-Dichloroethylene........................................................................................................................................................................921
trans-1,2-Dichloroethylene.............................................................................................................................................................924
Dichlorofluoromethane...................................................................................................................................................................926
sym-Dichloromethyl Ether..............................................................................................................................................................927
2,4-Dichlorophenol...........................................................................................................................................................................928
1,2-Dichloropropane.........................................................................................................................................................................931
cis-1,3-Dichloropropylene...............................................................................................................................................................934
trans-1,3-Dichloropropylene..........................................................................................................................................................936
Dichlorvos.............................................................................................................................................................................................938
Dieldrin................................................................................................................................................................................................. 940
Diethylamine.......................................................................................................................................................................................943
2-Diethylaminoethanol....................................................................................................................................................................945
Diethyl Phthalate............................................................................................................................................................................... 946
1,1-Difluorotetrachloroethane......................................................................................................................................................949
1,2-Difluorotetrachloroethane......................................................................................................................................................949
Diisobutyl Ketone...............................................................................................................................................................................950
Diisopropylamine...............................................................................................................................................................................952
N,N-Dimethylacetamide..................................................................................................................................................................953
Dimethylamine...................................................................................................................................................................................954
p-Dimethylaminoazobenzene.......................................................................................................................................................956
Dimethylaniline..................................................................................................................................................................................958
2,2-Dimethylbutane..........................................................................................................................................................................959
xvi    Contents

2,3-Dimethylbutane..........................................................................................................................................................................961
cis-1,2-Dimethylcyclohexane.........................................................................................................................................................963
trans-1,2-Dimethylcyclohexane................................................................................................................................................... 964
N,N-Dimethylformamide.................................................................................................................................................................965
1,2-Dimethylhydrazine.....................................................................................................................................................................967
2,3-Dimethylpentane........................................................................................................................................................................968
2,4-Dimethylpentane........................................................................................................................................................................969
3,3-Dimethylpentane........................................................................................................................................................................971
2,4-Dimethylphenol..........................................................................................................................................................................972
Dimethyl Phthalate............................................................................................................................................................................974
2,2-Dimethylpropane.......................................................................................................................................................................977
2,7-Dimethylquinoline.....................................................................................................................................................................978
Dimethyl Sulfate.................................................................................................................................................................................979
1,2-Dinitrobenzene............................................................................................................................................................................980
1,3-Dinitrobenzene............................................................................................................................................................................981
1,4-Dinitrobenzene............................................................................................................................................................................982
4,6-Dinitro-o-Cresol...........................................................................................................................................................................984
2,4-Dinitrophenol...............................................................................................................................................................................985
2,4-Dinitrotoluene.............................................................................................................................................................................987
2,6-Dinitrotoluene.............................................................................................................................................................................989
Di-n-Octyl Phthalate..........................................................................................................................................................................991
1,4-Dioxane..........................................................................................................................................................................................992
1,2-Diphenylhydrazine.....................................................................................................................................................................995
Diuron.....................................................................................................................................................................................................996
Dodecane..............................................................................................................................................................................................999
α-Endosulfan.................................................................................................................................................................................... 1001
β-Endosulfan..................................................................................................................................................................................... 1004
Endosulfan Sulfate.......................................................................................................................................................................... 1006
Endrin.................................................................................................................................................................................................. 1007
Endrin Aldehyde...............................................................................................................................................................................1010
Epichlorohydrin................................................................................................................................................................................ 1011
EPN������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������ 1012
Ethanolamine....................................................................................................................................................................................1014
2-Ethoxyethanol...............................................................................................................................................................................1015
2-Ethoxyethyl Acetate....................................................................................................................................................................1017
Ethyl Acetate......................................................................................................................................................................................1019
Ethyl Acrylate.....................................................................................................................................................................................1021
Ethylamine..........................................................................................................................................................................................1022
Ethylbenzene.....................................................................................................................................................................................1024
Ethyl Bromide....................................................................................................................................................................................1028
Ethylcyclopentane.......................................................................................................................................................................... 1030
Ethylene Chlorohydrin...................................................................................................................................................................1031
Ethylenediamine..............................................................................................................................................................................1032
Ethylene Dibromide....................................................................................................................................................................... 1034
Ethylenimine..................................................................................................................................................................................... 1036
Ethyl Ether.......................................................................................................................................................................................... 1038
Ethyl Formate.................................................................................................................................................................................... 1040
Ethyl Mercaptan................................................................................................................................................................................1041
4-Ethylmorpholine.......................................................................................................................................................................... 1043
2-Ethylthiophene............................................................................................................................................................................ 1044
Fluoranthene.................................................................................................................................................................................... 1044
Fluorene.............................................................................................................................................................................................. 1048
Formaldehyde...................................................................................................................................................................................1052
Formic Acid.........................................................................................................................................................................................1055
Furfural.................................................................................................................................................................................................1057
Furfuryl Alcohol................................................................................................................................................................................1059
Contents    xvii

Glycidol............................................................................................................................................................................................... 1060
Heptachlor......................................................................................................................................................................................... 1062
Heptachlor Epoxide........................................................................................................................................................................ 1064
Heptane.............................................................................................................................................................................................. 1066
2-Heptanone..................................................................................................................................................................................... 1069
3-Heptanone......................................................................................................................................................................................1071
cis-2-Heptene.....................................................................................................................................................................................1072
trans-2-Heptene................................................................................................................................................................................1073
Hexachlorobenzene........................................................................................................................................................................1074
Hexachlorobutadiene.....................................................................................................................................................................1078
Hexachlorocyclopentadiene....................................................................................................................................................... 1080
Hexachloroethane...........................................................................................................................................................................1081
Hexane................................................................................................................................................................................................ 1084
2-Hexanone....................................................................................................................................................................................... 1087
1-Hexene............................................................................................................................................................................................ 1088
sec-Hexyl Acetate............................................................................................................................................................................ 1090
Hydroquinone...................................................................................................................................................................................1091
Indan��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������� 1093
Indeno[1,2,3-cd]Pyrene................................................................................................................................................................. 1094
Indole�������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������� 1096
Indoline............................................................................................................................................................................................... 1097
1-Iodopropane................................................................................................................................................................................. 1098
Isoamyl Acetate................................................................................................................................................................................ 1099
Isoamyl Alcohol.................................................................................................................................................................................1100
Isoamyl Acetate.................................................................................................................................................................................1102
Isobutyl Alcohol................................................................................................................................................................................1103
Isobutylbenzene...............................................................................................................................................................................1106
Isophorone.........................................................................................................................................................................................1107
Isopropyl Acetate.............................................................................................................................................................................1109
Isopropylbenzene............................................................................................................................................................................ 1110
Isopropyl Ether.................................................................................................................................................................................. 1113
Kepone................................................................................................................................................................................................. 1115
Lindane................................................................................................................................................................................................ 1116
Malathion............................................................................................................................................................................................1122
Maleic Anhydride............................................................................................................................................................................. 1126
Mesityl Oxide..................................................................................................................................................................................... 1127
Methanol.............................................................................................................................................................................................1128
Methoxychlor.................................................................................................................................................................................... 1131
Methyl Acetate..................................................................................................................................................................................1134
Methyl Acrylate................................................................................................................................................................................. 1135
Methylal............................................................................................................................................................................................... 1137
Methylamine......................................................................................................................................................................................1138
Methylaniline..................................................................................................................................................................................... 1139
2-Methylanthracene........................................................................................................................................................................1140
Methyl Bromide................................................................................................................................................................................ 1142
2-Methyl-1,3-Butadiene.................................................................................................................................................................1143
2-Methylbutane................................................................................................................................................................................1145
3-Methyl-1-Butene........................................................................................................................................................................... 1147
Methyl Cellosolve.............................................................................................................................................................................1148
Methyl Cellosolve Acetate.............................................................................................................................................................1150
Methyl Chloride................................................................................................................................................................................ 1151
Methylcyclohexane......................................................................................................................................................................... 1153
o-Methylcyclohexanone................................................................................................................................................................ 1155
1-Methylcyclohexene.....................................................................................................................................................................1156
Methylcyclopentane....................................................................................................................................................................... 1157
Methylene Chloride.........................................................................................................................................................................1158
xviii    Contents

Methyl Formate................................................................................................................................................................................. 1161


3-Methylheptane..............................................................................................................................................................................1163
5-Methyl-3-Heptanone..................................................................................................................................................................1164
2-Methylhexane................................................................................................................................................................................1165
3-Methylhexane................................................................................................................................................................................1167
Methylhydrazine...............................................................................................................................................................................1168
Methyl Iodide.....................................................................................................................................................................................1169
Methyl Isocyanate............................................................................................................................................................................ 1170
Methyl Mercaptan............................................................................................................................................................................1172
Methyl Methacrylate....................................................................................................................................................................... 1173
2-Methylnaphthalene..................................................................................................................................................................... 1175
4-Methyloctane.................................................................................................................................................................................1177
2-Methylpentane.............................................................................................................................................................................. 1178
3-Methylpentane..............................................................................................................................................................................1180
4-Methyl-2-Pentanone...................................................................................................................................................................1182
2-Methyl-1-Pentene........................................................................................................................................................................1184
4-Methyl-1-Pentene........................................................................................................................................................................1185
1-Methylphenanthrene..................................................................................................................................................................1186
2-Methylphenol................................................................................................................................................................................1188
4-Methylphenol................................................................................................................................................................................ 1191
2-Methylpropane.............................................................................................................................................................................1193
2-Methylpropene.............................................................................................................................................................................1195
α-Methylstyrene...............................................................................................................................................................................1197
Mevinphos..........................................................................................................................................................................................1198
Morpholine........................................................................................................................................................................................ 1200
Naled��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������� 1202
Naphthalene......................................................................................................................................................................................1203
1-Naphthylamine............................................................................................................................................................................. 1211
2-Naphthylamine.............................................................................................................................................................................1213
Nitrapyrin............................................................................................................................................................................................1214
2-Nitroaniline.....................................................................................................................................................................................1215
3-Nitroaniline..................................................................................................................................................................................... 1217
4-Nitroaniline.....................................................................................................................................................................................1219
Nitrobenzene.....................................................................................................................................................................................1221
4-Nitrobiphenyl.................................................................................................................................................................................1224
Nitroethane........................................................................................................................................................................................1225
Nitromethane....................................................................................................................................................................................1226
2-Nitrophenol....................................................................................................................................................................................1228
4-Nitrophenol....................................................................................................................................................................................1230
1-Nitropropane................................................................................................................................................................................ 1234
2-Nitropropane.................................................................................................................................................................................1235
N-Nitrosodimethylamine...............................................................................................................................................................1236
N-Nitrosodiphenylamine...............................................................................................................................................................1238
N-Nitrosodi-n-Propylamine..........................................................................................................................................................1239
2-Nitrotoluene...................................................................................................................................................................................1240
3-Nitrotoluene...................................................................................................................................................................................1241
4-Nitrotoluene...................................................................................................................................................................................1242
Nonane................................................................................................................................................................................................1244
Octachloronaphthalene................................................................................................................................................................1246
Octane..................................................................................................................................................................................................1247
1-Octene..............................................................................................................................................................................................1250
Oxalic Acid..........................................................................................................................................................................................1252
Parathion.............................................................................................................................................................................................1253
PCB-1016.............................................................................................................................................................................................1259
PCB-1221.............................................................................................................................................................................................1260
PCB-1232.............................................................................................................................................................................................1262
Contents    xix

PCB-1242.............................................................................................................................................................................................1263
PCB-1248.............................................................................................................................................................................................1266
PCB-1254.............................................................................................................................................................................................1267
PCB-1260.............................................................................................................................................................................................1270
Pentachlorobenzene.......................................................................................................................................................................1273
Pentachloroethane..........................................................................................................................................................................1276
Pentachlorophenol..........................................................................................................................................................................1277
1,4-Pentadiene..................................................................................................................................................................................1283
Pentane............................................................................................................................................................................................... 1284
2-Pentanone.......................................................................................................................................................................................1287
1-Pentene............................................................................................................................................................................................1289
cis-2-Pentene.................................................................................................................................................................................... 1290
trans-2-Pentene................................................................................................................................................................................1292
Pentylcyclopentane.........................................................................................................................................................................1293
Phenanthrene................................................................................................................................................................................... 1294
Phenol................................................................................................................................................................................................. 1300
p-Phenylenediamine...................................................................................................................................................................... 1306
Phenylhydrazine...............................................................................................................................................................................1307
Phthalic Anhydride......................................................................................................................................................................... 1308
Picric Acid............................................................................................................................................................................................1310
Pindone................................................................................................................................................................................................ 1311
Propane................................................................................................................................................................................................ 1312
1-Propanol..........................................................................................................................................................................................1314
β-Propiolactone................................................................................................................................................................................1316
Propyl Acetate................................................................................................................................................................................... 1317
Propylbenzene..................................................................................................................................................................................1319
Propylcyclopentane........................................................................................................................................................................1322
Propylene Oxide...............................................................................................................................................................................1323
Propyl Nitrate.....................................................................................................................................................................................1325
Propyne................................................................................................................................................................................................1326
Pyrene..................................................................................................................................................................................................1327
Pyridine................................................................................................................................................................................................1332
p-Quinone...........................................................................................................................................................................................1334
Ronnel..................................................................................................................................................................................................1335
Strychnine...........................................................................................................................................................................................1337
Styrene.................................................................................................................................................................................................1338
Sulfotepp.............................................................................................................................................................................................1341
2,4,5-T...................................................................................................................................................................................................1342
TCDD��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������� 1345
1,2,4,5-Tetrabromobenzene........................................................................................................................................................ 1348
1,1,2,2-Tetrabromoethane.............................................................................................................................................................1349
1,2,3,4-Tetrachlorobenzene..........................................................................................................................................................1350
1,2,3,5-Tetrachlorobenzene..........................................................................................................................................................1353
1,2,4,5-Tetrachlorobenzene..........................................................................................................................................................1355
1,1,2,2-Tetrachloroethane.............................................................................................................................................................1357
Tetrachloroethylene....................................................................................................................................................................... 1360
Tetraethyl Pyrophosphate............................................................................................................................................................ 1364
Tetrahydrofuran................................................................................................................................................................................1365
1,2,4,5-Tetramethylbenzene........................................................................................................................................................ 1366
Tetranitromethane.......................................................................................................................................................................... 1368
Tetryl��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������� 1369
Thiophene...........................................................................................................................................................................................1370
Thiram..................................................................................................................................................................................................1371
Toluene................................................................................................................................................................................................1373
2,4-Toluene Diisocyanate............................................................................................................................................................. 1380
o-Toluidine..........................................................................................................................................................................................1382
xx    Contents

Toxaphene..........................................................................................................................................................................................1383
1,3,5-Tribromobenzene..................................................................................................................................................................1385
Tributyl Phosphate......................................................................................................................................................................... 1386
1,2,3-Trichlorobenzene.................................................................................................................................................................. 1388
1,2,4-Trichlorobenzene...................................................................................................................................................................1390
1,3,5-Trichlorobenzene...................................................................................................................................................................1393
1,1,1-Trichloroethane......................................................................................................................................................................1395
1,1,2-Trichloroethane......................................................................................................................................................................1399
Trichloroethylene............................................................................................................................................................................ 1402
Trichlorofluoromethane............................................................................................................................................................... 1407
2,4,5-Trichlorophenol..................................................................................................................................................................... 1409
2,4,6-Trichlorophenol...................................................................................................................................................................... 1411
1,2,3-Trichaloropropane................................................................................................................................................................. 1413
1,1,2-Trichlorotrifluoroethane......................................................................................................................................................1415
Tri-o-Cresyl Phosphate...................................................................................................................................................................1416
Triethylamine..................................................................................................................................................................................... 1417
Trifluralin.............................................................................................................................................................................................1419
1,2,3-Trimethylbenzene.................................................................................................................................................................1423
1,2,4-Trimethylbenzene.................................................................................................................................................................1424
1,3,5-Trimethylbenzene.................................................................................................................................................................1426
1,1,3-Trimethylcyclohexane..........................................................................................................................................................1429
1,1,3-Trimethylcyclopentane.......................................................................................................................................................1430
2,2,5-Trimethylhexane....................................................................................................................................................................1431
2,2,4-Trimethylpentane..................................................................................................................................................................1432
2,3,4-Trimethylpentane................................................................................................................................................................. 1434
2,4,6-Trinitrotoluene........................................................................................................................................................................1435
Triphenyl Phosphate.......................................................................................................................................................................1437
Vinyl Acetate......................................................................................................................................................................................1438
Vinyl Chloride................................................................................................................................................................................... 1440
Warfarin.............................................................................................................................................................................................. 1443
o-Xylene.............................................................................................................................................................................................. 1444
m-Xylene............................................................................................................................................................................................ 1448
p-Xylene...............................................................................................................................................................................................1451
Appendices.................................................................................................................................................................................................................1457
References.................................................................................................................................................................................................................. 1487
CASRN Index..............................................................................................................................................................................................................1619
Empirical Formula Index..................................................................................................................................................................................... 1623
Degradation Products, Impurities, and Chemical Composition Index........................................................................................1627
Preface

The proliferation of research publications and continu- or proposed by the U.S. Environmental Protection Agency
ing public awareness dealing with the fate, transport, and (EPA) are also deleted from this edition. In many instances,
remediation of hazardous substances in the environment states have promulgated groundwater and/or drinking water
has again necessitated expansion of the fourth edition of the standards that are equal to or more stringent than U.S. EPA
Groundwater Chemicals Desk Reference. Information in this drinking water standards. Therefore, it is recommended that
publication was combined with similar information in the the reader refer to the appropriate state regulations as guid-
Agrochemicals Chemicals Desk Reference, which resulted in ance for complying with these standards on a case-by-case
the Environmental Chemicals Desk Reference. Agrochemical basis.
data that appeared in both publications are listed only in the Since the publications of the Groundwater Chemicals
Groundwater Chemicals chapter. Desk Reference and the Agrochemicals Chemicals Desk
To accommodate additional information while main- Reference, additional data have been critically reviewed.
taining this book in a single volume, the Synonym Index Much of the additional data and information was focused on
was deleted. Also, the Exposure Limits section was deleted the environmental fate and behavior of these chemicals. A
because these data are constantly being reviewed and revised concerted effort was undertaken to review information from
periodically by independent organizations (e.g., American original publications to replace references from secondary
Conference of Governmental Hygienists), and state and/ (quoted) sources.
or federal regulatory agencies (e.g., Occupational Safety The book is based on more than 4,600 references, an
and Health Administration and the National Institute of increase of more than 300 references since the third edition.
Occupational Safety and Health). Consequently, any changes Most of the citations cited herein were obtained from peer-
to exposure data included in this type of publication would reviewed, original publications in the documented litera-
be quickly outdated. Therefore, it is recommended the ture. Every effort has been made to present precise, accurate,
user refer to the originators of these data and/or a certified and reliable information in a clear, consistent format. The
Industrial Hygienist or equivalent for up-to-date exposure publisher and author would appreciate hearing from readers
information to ensure appropriate actions are employed to regarding the corrections and suggestions for material that
protect human health. Also deleted in this edition is the might be included for use in future editions.
Symptoms of Exposure section. Generally, this information We hope that this latest edition will continue to be a valuable
accompanies exposure limit data in various publications. resource to those in the environmental community dedicated
Lastly, the Drinking Water Standards promulgated and/ in preserving, protecting, and remediating our environment.

xxi
Abbreviations and Symbols

A ampere DSC differential scanning calorimetry


Å angstrom dsoln density of solution
ACGIH American Conference of Governmental dv vapor density
Industrial Hygienists dw density of water
ai/ha active ingredient per hectare DWEL drinking water exposure limit
aq aqueous dyn dyne
ASTM American Society for Testing and Materials EC50 concentration necessary for 50% of the
asym- asymmetric aquatic species tested showing abnormal
atm atmosphere behavior
ATSDR Agency for Toxic Substances and Disease ECD electron capture detection/detector
Registry EDTA ethylenediaminetetraacetic acid
b aperture of fracture EINECS European Inventory of Existing Chemical
B average soil bulk density (g/cm3) Substances
BAF bioaccumulation factor EPA (U.S.) Environmental Protection Agency
BCF bioconcentration factor EPICS equilibrium partitioning in a closed system
BN base neutral et al. and others
BOD biological oxygen demand (g O2/g chemical) eV electron volts
bp boiling point f frequency
BRN Beilstein Registry Number FA fulvic acid
C ceiling FEMA Federal Emergency Management Agency
C equilibrium concentration (e.g., mg/L) FID flame ionization detector
Ca calcium (as in Ca-montmorillonite) fl p flash point
Ca2+ calcium ion foc fraction of organic carbon
cal calorie ft3 cubic feet
CAS Chemical Abstracts Service FTIR Fourier transform infrared spectroscopy
CASRN Chemical Abstracts Service Registry Number g gram
CCRIS Chemical Carcinogenesis Research Information G gram of solute/liter of solution
System GAC granular activated carbon
CEC cation exchange capacity (meq/100 g) gal gallon
ceff effective concentration GC/FID gas chromatography/flame ionization detector
CERCLA Comprehensive Environmental Response, GC/MS gas chromatography/mass spectrometry
Compensation and Liability Act GLC gas–liquid chromatography
CFR U.S. Code of Federal Regulations GSC gas–solid chromatography
CHRIS Chemical Hazard Response Information System H Henry’s law constant (M/atm)
cis- stereochemical opposite of trans- h hour(s)
CL concentration of solute in solution H* effective Henry’s law constant
cm centimeter ha hectare
cmolc/kg centimoles of charge per kilogram HCl hydrogen chloride or hydrochloric acid
CO2 carbon dioxide Hf heat of fusion
COD chemical oxygen demand (g O2/g chemical) HPLC high-performance liquid chromatography
cps centipoise HSDB Hazardous Substances Data Bank
CS concentration of sorbed solute H-t1/2 hydrolysis half-life
Cs+ cesium ion Hz hertz
Cu copper (as in Cu-montmorillonite) IARC International Agency for Research on Cancer
Cu2+ copper ion IC50 concentration necessary to reduce growth or
D diffusivity immobilization 50%
DOT Department of Transportation (U.S.) IDLH immediately dangerous to life or health
ds density of a substance IP ionization potential

xxiii
xxiv    Abbreviations and Symbols

K kelvin (°C + 273.15) (cal/mol) n nano (as in nanogram) or porosity


k rate constant N normality (equivalents/liter)
Ka acid dissociation constant n-, N- normal (as in n-propyl, N-nitroso)
KA distribution coefficient (cm) NA not available or not assigned
Kb base dissociation constant Na sodium (as in Na-montmorillonite)
kcal kilocalories Na+ sodium ion
Kd distribution coefficient (cm3/g) NaCl sodium chloride
KF Freundlich adsorption coefficient (various units) NaOH sodium hydroxide
kg kilogram ND not detected
KH Henry’s law constant (atm ⋅ m3/mol ⋅ K) ne effective porosity
KH′ Henry’s law constant (unitless) ng nanogram
kHz kilohertz NIOSH National Institute for Occupational Safety and
kJ kilojoules Health
km kilometer nm nanometer
Koc soil organic carbon/water partition coefficient NMR nuclear magnetic resonance
Kom soil organic matter/water partition coefficient No. number
Kow n-octanol/water partition coefficient NOEC no-observed effect concentration
kPa kilopascal NOEL no-observed effect level
Kw dissociation constant for water (10−14 at 25°C) NSC National Safety Council
L liter o- ortho (as in o-dichlorobenzene)
lb pound OECD Organization for Economic Cooperation and
LC liquid chromatography Development
LC/MS liquid chromatography/mass spectrometry OH hydroxyl
LC100 lethal concentration necessary to kill 100% of OSHA Occupational Safety and Health Administration
aquatic species tested p- para (as in p-dichlorobenzene)
LC50 lethal concentration necessary to kill 50% of p pico
aquatic species tested P pressure
LD50 lethal dose necessary to kill 50% of mammals Pa pascal
tested PAH polycyclic aromatic hydrocarbon
lel lower-explosive limit pair vapor density of air
LLE liquid–liquid extraction PCBs polychlorinated biphenyls
LOEC lowest-observed effect concentration PEL permissible exposure limit
LOEL lowest-observed effect level pg picogram
LSC liquid scintillation counting pH −log10 hydrogen ion activity (concentration)
LSE liquid–solid extraction pKa −log10 dissociation constant of an acid
M mass pKb −log10 dissociation constant of a base
m- meta (as in m-dichlorobenzene) pKw −log10 dissociation constant of water
m meter ppb parts per billion (µg/L)
m molality ppbv parts per billion by volume
M molarity (moles/liter) pph parts per hundred
MCL maximum contaminant level ppm parts per million (mg/L)
MCLG maximum contaminant level goal ppmv parts per million by volume
meq milliequivalents ppt parts per thousand
mg milligram Pt platinum
MHz megahertz P-t1/2 photolysis half-life
min minute(s) pv specific vapor density
ML mass of solute in solution QSAR quantitative structure–activity relationships
mL milliliter R ideal gas constant (8.20575 × 10−5 atm ⋅ m3/mol)
mM millimolar (millimoles per liter, mmol/L) Ra retardation factor for an acid
mmHg millimeters of mercury Rb retardation factor for a base
mmol millimole RCRA Resource Conservation and Recovery Act
mol mole Rd retardation factor
mp melting point REL recommended exposure limit
MS mass of sorbed solute Rf retention factor
MS mass spectrometer/mass spectrometry RP-HPLC reverse-phase high-performance liquid
mV millivolt chromatography
Abbreviations and Symbols    xxv

rpm revolutions per minute VLE vapor­–liquid equilibrium


RTECS Registry of Toxic Effects of Chemical Substances VLLE vapor–liquid–liquid equilibrium
Ru rubidium VOC volatile organic compound
S solubility vp vapor pressure
Sa solute concentration in air (mol/L) Vm molar volume of water (e.g., m3/mol)
SARA Superfund Amendments and Reauthorization Vw average linear velocity of groundwater
Act (e.g., ft/day)
s second w equivalent molecular weight of solution
sec- secondary (as in sec-butyl) W watt
Sf entropy of fusion wt weight
So solubility in organics x mole fraction
sOW spreading coefficient of organic liquid at air– x/m amount of solute adsorbed (e.g., mg/g of
water table interface (dyn/cm) absorbent)
sp. species Xa effective mole fraction
SPE solid-phase extraction y solute concentration in air (mole fraction)
SPME solid-phase microextraction Z+ positively charged species (milliequivalents/cm3)
spp. species (plural) % percent
STEL short-term exposure limit < less than
Sw solubility in water > greater than
sym symmetric ≈ approximately equal to
t- tertiary (as in t-butyl; but tert-butyl) ≤ less than or equal to
t1/2 half-life ≥ greater than or equal to
Temp. temperature °C degrees Centigrade (Celsius)
ThOD theoretical oxygen demand °F degrees Fahrenheit
TLC thin layer chromatography ‰ salinity (parts per thousand)
TLm median tolerance level α alpha
TLV threshold limit value αa percent of acid that is nondissociated
TOC total organic carbon (mg/L) αb percent of base that is nondissociated
trans- stereochemical opposite of cis- β beta
Ts temperature of a substance γ gamma
Tw temperature of water γO(W) surface tension of organic liquid saturated with
TWA time-weighted average water (dyn/cm)
U.K. United Kingdom γOW interfacial tension between organic liquid and
U.S. EPA United States Environmental Protection Agency water (dyn/cm)
uel upper-explosive limit γW(O) surface tension of water saturated with organic
UN United Nations liquid (dyn/cm)
unsym unsymmetric δ delta
UV ultraviolet ε dielectric constant
V molar volume η viscosity
V, vol volume λ wavelength
Va molar volume of air (e.g., m3/mol) µ micro (10−6)
vap d vapor density µg microgram
Vc average linear velocity of contaminant µm micrometer
(e.g., ft/day) ρ specific density (unitless)
Designations

CAS Registry Number (CASRN): This unique identifier information, contact NIOSH, U.S. Department of Health
is assigned by the American Chemical Society to chemi- and Human Services, Mail Stop C-13, 4676 Columbia
cals recorded in the CAS Registry System. This number is Parkway, Cincinnati, OH 45226-1998 (toll free: 1-800-35-
used to access various chemical databases, including the NIOSH; fax: 513-533-8573).
Hazardous Substances Data Bank (HSDB), CAS Online,
Merck Index: The two sets of numbers refer to the edition
Chemical Substances Information Network, and many oth-
and monograph number as found in the 12th edition of The
ers. This entry is also useful to conclusively identify a sub-
Merck Index (Budavari et al., 2001). For example, the entry
stance regardless of the assigned name.
12, 1063 refers to an entry in the 12th edition as monograph
Department of Transportation designation: This is number 1063.
a four-digit number assigned by the U.S. Department of
Physical state, color, and odor: The appearance, includ-
Transportation to hazardous materials and is identical to the
ing the color and physical state (solid, liquid, or gas) of
United Nations identification number (which is preceded by
a chemical at room temperature (20–25°C), is provided.
the letters UN). This number is required on shipping papers,
If the compound can be detected by the olfactory sense,
on placards or orange panels on tanks, and on a label or
the odor is noted. Unless noted otherwise, the information
package containing the material. These numbers are widely
provided in this category is for the pure substance and was
used by personnel responding to emergency situations,
obtained from many sources (CHRIS, 1984; HSDB, 1989;
for example, overturned tractor trailers, to identify trans-
Hawley, 1981; Keith and Walters, 1992; Sax, 1984; Sax and
ported material quickly and easily. The DOT designations
Lewis, 1987; Toxic and Hazardous Industrial Chemicals
and appropriate responses to each chemical or compounds
Safety Manual for Handling and Disposal with Toxicity
are cross-referenced in the Emergency Response Guidebook.
and Hazard Data, 1986; Sittig, 1985; Verschueren, 1983;
Additional information is provided in this book, which may
Windholz et al., 1983). If available, odor thresholds in
be obtained from the U.S. Department of Transportation,
air and/or taste thresholds in water are given. There are
Research and Special Programs Administration, Materials
two types of thresholds. According to the American
Transportation Bureau, Washington, DC 20590.
Petroleum Institute (API, 1985), the detection threshold is
DOT label: This label is the hazard classification assigned defined as “the lowest concentration of stimulus that can
by the U.S. Department of Transportation. Federal regula- be discriminated from stimulus-free blanks.” The recog-
tions require it on all containers shipped. nition threshold is defined as “the lowest concentration
of stimulus that can be described as possessing a char-
Molecular formula: This is arranged by carbon, hydrogen,
acter (i.e., sweet, rancid).” The thresholds reported in air
and remaining elements in alphabetical order in accordance
are usually reported as parts per billion (ppb) or parts per
with the system developed by Hill (1900). Molecular formu-
million as micrograms per cubic meter (µg/m 3) or milli-
las are useful for identifying isomers (i.e., compounds with
gram per cubic meter (mg/m 3), respectively. Sometimes
identical molecular formulas) and are required to calculate
the odor threshold in water is given and is reported as µg/
the formula weight of a substance.
kg. Taste thresholds in water are usually given in mass per
Formula weight: This is calculated to the nearest hun- unit volume (e.g., µg/L, mg/L).
dredth using the empirical formula and the 1981 Table
Boiling point: This is defined as the temperature at which
of Standard Atomic Weights as reported in Weast (1986).
the vapor pressure of a liquid equals the atmospheric pres-
Formula weights are required for many calculations, such as
sure. Unless otherwise noted, all boiling points are reported
converting weight/volume units, for example, mg/L or g/L,
at 1.0 atmosphere pressure (760 mmHg). Although not used
to molar units (mol/L); with density for calculating molar
in environmental assessments, boiling points for aromatic
volumes; and estimating Henry’s law constants.
compounds have been found to be linearly correlated with
Registry of Toxic Effects of Chemical Substances aqueous solubility (Almgren et al., 1979). Boiling points are
(RTECS) number: Many compounds are assigned a unique also useful for assessing entry of toxic substances into the
accession number consisting of two letters followed by body. Body contact with high-boiling liquids is the most
seven numerals. This number is needed to quickly and eas- common means of entry of toxic substances into the body.
ily locate additional toxicity and health-based data that Inhalation is the most common means of entry into the
are cross-referenced in the RTECS (1985). For additional body for low-boiling liquids (Shafer, 1987).

xxvii
xxviii    Designations

Diffusivity in water: Molecular diffusion is defined as the where Kw is the dissociation constant for water (10−14 at
transport of molecules (e.g., organic compounds) in either 25°C), Ka is the acid dissociation constant, and K b is the base
liquid or gaseous states. Typically, molecular diffusion is not dissociation constant.
a major factor under the majority of environmental condi- The dissociation constant is usually expressed as pKa =
tions. However, in saturated aquifers with low-pore water −log10 Ka. Equation D.4 becomes
velocities (i.e., <0.002 cm/s), diffusion can be a contributing
factor in the transport of organic compounds. pK w = pK a + pK b (D.5)
Very few experimentally determined diffusivities of
organic substances in water are available in the documented When the pH of the solution and the pKa are equal, 50%
literature. If experimentally determined diffusivity values of the acid will have dissociated into ions. The percent dis-
are not available, Hayduk and Laudie (1974) recommend the sociation of an acid or base can be calculated if the pH of the
following equation for estimating this parameter: solution and the pKa of the compound are known (Guswa
et al., 1984):
1.326 × 10−4
D= (D.1)  100 
η1.14 V 0.589 For organic acids: α a =   (D.6)
 1 + 10( pH−pKa )

where D is the diffusivity of the substance in water (cm 2/s),
η is the viscosity of water (centipoise, cps), and V is the  100 
For organic bases: α b =   (D.7)
molar volume of the solute (cm3/mol). The molar volume is  1 + 10(pKw−pKb−pH) 
easily determined if the liquid density of the solute is avail-
able. Molar volume may also be determined using the LeBas where αa is the percent of the organic acid that is nondis-
incremental method as described in Lyman et al. (1982). The sociated, αb is the percent of the organic base that is non-
latter method is required to determine the molar volumes of dissociated, pKa is the −log10 dissociation constant for an
substances that are solids at ordinary temperatures. More acid, pKw is the −log10 dissociation constant for water (14.00
recent methods for estimating molar volume using molecu- at 25°C), pK b is the −log10 dissociation constant for base
lar group contributions are described by Baum (1998). (pK b = pKw−pKa), and pH is the −log10 hydrogen ion activ-
Diffusivity values are reported in a modified exponential ity (concentration) of the solution.
form. For example, the experimentally determined diffusiv- Given that ions tend to remain in solution, the degree of
ity of benzene in water is 1.09 × 10−5 cm2/s, but this value is dissociation will affect processes such as volatilization, pho-
reported as 1.09 (×10−5 cm2/s). tolysis, adsorption, and bioconcentration (Howard, 1989).
Dissociation constant: In an aqueous solution, an acid Entropy of fusion: This value is calculated using the
(HA) will dissociate into the carboxylate anion (A−) and expression
hydrogen ion (H+) and may be represented by the general
equation ΔH f
ΔSf = (D.8)
+ −
Tm
HA (aq ) = H + A (D.2)
where ΔHf is the heat of fusion (cal/mol) and Tm is the melt-
At equilibrium, the ratio of the products (ions) to the ing point (K) of the pure material.
reactant (nonionized electrolyte) is related by the equation
Heat of fusion: This value, normally reported in kcal/mol,
+
[H ][A ] − is also referred to as the heat of melting. For solids, the heat
Ka = (D.3) of fusion is required to estimate the solubility of the solute
[HA] to account for crystal lattice interactions. The theoretical
where Ka is the dissociation constant. This expression shows basis for introducing this value into the estimation of aque-
that Ka increases if there is increased ionization and vice ous solubility of organic solids is explained by Irmann (1965)
versa. A strong acid (weak base) such as hydrochloric acid and Yalkowsky and Valvani (1979). Heat of fusion data
ionizes readily and has a large Ka, whereas a weak acid (or are available in many texts, including Dean (1987), Weast
stronger base) such as benzoic acid ionizes to a lesser extent (1986), and CHRIS (1984). Experimentally determined data
and has a lower Ka. The dissociation constants for weak acids were reported by Plato and Glasgow (1969) and Hickley et al.
are sometimes expressed as K b, the dissociation constant for (1990).
the base, and both are related to the dissociation constant Henry’s law constant: Sometimes referred to as the air­–
for water by the expression water partition coefficient, Henry’s law constant is defined
as the ratio of the partial pressure of a compound in air
K w = Ka + Kb (D.4) to the concentration of the compound in water at a given
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12281 Singer J 6G
13
49 Dec
12305 Sweet M, S’t
F 18
Jan
12441 Shoemaker C 8F 65
12
Jan
12538 Stewart A F 2D
27
71 Jan
12562 Sponcerlar Geo
B 31
89 Feb
12668 Shorter W
K 17
123 Mar
12769 Sloan L
D 13
50 Mar
12789 Stroup S
B 17
132 Mar
12793 Seeley N
D 18
75 Mar
12810 Scott R
G 24
April
730 Tweedy R Cav 1A 64
25
Trescott April
743 2C
Samuel 26
40 May
999 Trimmer Wm
H 10
May
1196 Turney U S Cav 2G 64
18
10 May
1496 Thomas Wm Cav
M 30
Aug
4784 Thompson J 2E
5
13 Aug
4951 Toroman W R
E 7
5356 Tierney W Art 1L Aug
11
90 Aug
5552 Tinsley M
B 13
12 Aug
5668 Terilliger N
C 14
32 Aug
6330 Tanner A, S’t
G 21
26 Aug
7224 Thompson V B
C 29
45 Aug
7246 Turner S B
B 30
44 Sept
7640 Thomas Jas
C 2
135 Sept
8850 Talbert R
F 15
103 Sept
9774 Thomas N
B 26
26 Sept
9945 Townsend J
C 28
153 Oct
10471 Tattman B
C 7
93 Oct
10800 Tinway R
- 12
Townsley E M, 89 Nov
11820
S’t B 5
Feb
12577 Tensdale T H Cav 2E 65
3
12 Dec
12251 Uchre S 64
E 9
45 June
2194 Vining W H H
G 19
123 July
3902 Valentine C
H 24
4450 Vaugh B 125 Aug
F 1
103 Aug
4497 Vangrider H
H 1
Aug
5263 Vatier J F Cav 6 -
10
17 Aug
6170 Vail Jno L, S’t
C 19
21 Aug
6859 Vanaman M
E 26
Aug
6985 Vanderveer A 6H
27
Sept
7756 Victor H Art 1D
4
34 Sept
9576 Volis J
H 23
12 Oct
10252 Vail N
K 3
Oct
10389 Vail G M 7D
5
14 Oct
10472 Van Fleet H
I 7
135 Oct
11095 Van Kirk G
B 18
89 Oct
11097 Van Malley J M
G 18
Jan
12554 Vanhorn S Cav 9C 65
30
82 Mch
7 Wiley Samuel 64
A 5
111 Mch
185 Wickman Wm
B 27
45 April
779 Wooley Jno
B 28
45 April
807 Werts Louis
D 30
1085 Wood Wm 89 May
A 14
Wentling 100 May
1449
Joseph K 29
15 June
1604 Wood Joseph
B 4
Wilkinson W, 89 June
1836
Cor D 11
93 June
1913 Wilson Jas
I 13
44 June
2020 Way Jno
I 15
15 June
2041 Windgrove S R
- 15
45 June
2172 Webb E
A 19
June
2358 Walters F 9E
23
June
2536 Wing Cav 2M
26
89 July
2815 Willis A
A 3
89 July
2840 Wroten L
H 3
90 July
3188 Williams D
A 12
April
34 Wright Wm 7H
24
15 July
3310 White H
A 15
75 July
3325 Whitten G
K 14
89 July
4214 West J B
B 29
4681 Witt Jno T 93 Aug
G 4
111 Aug
4688 Won J, Cor
B 4
33 Aug
4695 Wile A, Cor
D 4
70 Aug
5121 Winder I
D 9
Aug
5211 Wood N L Cav 4L
10
145 Aug
5726 Winters Geo
K 15
89 Aug
6314 Wainwright S G
G 20
35 Aug
6318 Wisser F J
A 20
Aug
6362 Wistman N 9G
21
Aug
6397 Wilson E 4A
21
21 Aug
6700 Watson G
A 24
123 Aug
6761 Wood S 64
A 22
59 Aug
7056 Wood W H
E 28
90 Aug
7373 Wyatt J
B 31
72 Sept
7582 Wentworth L
A 1
89 Sept
8298 Wright J S
E 9
14 Sept
8396 Warner T
C 10
73 Sept
8907 Wyckmann D
G 16
9384 Worte J 116 Sept
- 20
135 Sept
9527 Woodruff J M
F 22
93 Sept
9691 Wagner J
F 24
21 Sept
10007 Whitney E
K 29
Oct
10230 Williams Orland C 7K
2
72 Oct
10309 Weaver M
H 4
21 Oct
10402 Ward Francis
H 6
33 Oct
10464 Whitehead A B
E 7
26 Oct
10528 Wiley A
I 8
73 Oct
10733 White I
E 11
Westbrook R L, 135 Oct
10844
Cor F 13
65 Oct
11013 Walker C
I 16
14 Oct
11034 Waldron H
A 16
60 Oct
11417 Williams S M
F 24
122 Nov
11770 Worthen D
B 3
35 Nov
11874 Weason J
F 6
14 Nov
12042 Wickham J
H 16
12073 White R M 15 Nov
D 18
35 Nov
12158 Warner B F
E 25
72 Feb
12584 Whitaker E 65
A 4
57 Mch
12722 Wella E
A 3
Mch McL’s
12759 Winklet T Cav - -
12 Sqn
102 Mch
12786 Warner M
G 16
Webricks Josh Aug
4833 9G 64
H 6
45 April
638 Yuterler W A
E 20
80 Aug
5477 Younker S
F 13
Aug
6068 Young Jno 7E
18
Sept
7816 Yeager Jno Cav 7B
4
Sept
7876 Young J 9F
5
Oct
10583 Young W 6G
10
15 Feb
12659 Young W 65
A 16
100 July
3225 Zubers J M 64
B 12
72 Oct
11253 Zink A J
E 21
Total
1031.
PENNSYLVANIA.
Mch
224 Attwood Abr’m C 18 I 64
29
Mch
250 Armidster M Cav 4A
30
April
468 Ackerman C 8B
9
April
758 Arb Simon Cav 4C
27
May
846 Allbeck G B, S’t 52 F
3
May
975 Algert H K 54 F
9
May
1282 Arble Thos Cav 13 A
26
June
1837 Ait M 21 K
11
June
2348 Akers Geo 90 H
23
June
2398 Allison E 55 K
24
103 June
2547 Anderson D, S’t
K 27
June
2648 Able J 54 F
20
103 July
2956 Amagart Eli, S’t
F 6
July
3018 Ackley G B Art 3B
7
July
3917 Alexander M Cav 1F
14
July
3967 Ardray J F, S’t 13 F
25
4055 Anderson J, Cor 79 I July
27
July
4143 Aches T J 7H
28
145 July
4149 Alcorn Geo W
F 28
July
4495 Archart H 51 C
29
Aug
4673 Allen C Cav 8K
4
Aug
4973 Andertin J Cav 4L
7
103 Aug
5286 Aler B
D 11
101 Aug
5511 Ault J L
C 13
Armstrong Cas, Aug
5862 Cav 4C 64
S’t 16
Aug
6029 Anersen Jno 91 C
18
184 Aug
7163 Arnold Daniel
C 29
Sept
7887 Angstedt Geo W 1F
5
101 Sept
8185 Allen J L
I 8
Sept
8232 Ambler C Cav 13 D
9
Sept
8388 Alexander W Res 2 I
10
Sept
8653 Armstrong A 7K
13
Sept
8655 Arnold L 73 A
13
Sept
8765 Altimus Wm 7E
14
1743 Ainley Wm Cav 3E June
8
Sept
9150 Alcorn J W “ 18 D
18
Sept
9896 Allison D B 55 K
27
135 Oct
10487 Anderson A
F 7
126 Oct
10570 Allen D
A 9
Oct
10823 Allin S Cav 7H
13
149 Oct
11419 Applebay T M
K 24
Oct
11607 Antill J 61 I
28
118 Nov
11710 Auger W
- 1
Nov
11852 Affleck T 2F
6
184 Nov
11860 Amandt J
D 6
142 Jan
12520 Atchinson W P 65
F 25
Mar
228 Bull Frank Cav 4H 64
29
Mar
249 Burton Lafayette C 18 D
30
April
332 Briggs Andrew C 13 H
2
April
427 Begler A 27 C
8
April
543 Breel Jacob, Cor 27 H
14
569 Black Jas A Cav 14 D April
15
April
661 Bradley Alex “ 3F
21
April
671 Burns Sam 73 K
22
April
673 Barra J 54 F
22
145 May
822 Bayne Wm
I 1
May
874 Bradley M Art 3A
4
May
897 Brown Henry 90 H
5
May
938 Brown D 4C
7
May
974 Batting Isaac, Cor Cav 8H
9
May
1046 Baker J D 57 F
12
May
1188 Butler Wm 90 B
18
May
1300 Boyd Thomas 9D
23
May
1309 Bryson J Cav 2D
23
May
1327 Brining J “ 13 B
24
13 May
1375 Burney J “
G 26
May
1393 Brown J B “ 4K
26
June
1576 Boman Sam’l Art 3B
3
103 June
1601 Berfert R
B 4
1654 Brumley Geo Cav 4 I June
5
June
1790 Butler J D 76 B
10
73 June
1859 Berkhawn H
G 12
June
1872 Brooks D S 79 -
12
183 June
1923 Brian Chas
F 14
June
1999 Bixter R 73 C
15
June
2026 Burns Owen Cav 13 C
15
June
2046 Bigler M “ 4 -
15
June
2127 Brown C “ 3B
17
June
2134 Buckhannan W Art 3B
18
June
2180 Ball L 26 K
19
June
2236 Barr J T Cav 4K
20
June
2323 Baker Henry “ 18 I
22
June
2483 Bisel Jno, S’t “ 18 K
25
June
2539 Balsley Wm “ 20 F
26
June
2610 Brown M “ 14 C
28
July
2727 Brenn J 73 K
1
2733 Bolt J H, S’t Cav 18 E July
1
July
2741 Beam Jno 76 E
1
July
2816 Burns Jno Cav 13 A
3
108 July
2913 Bish J
F 5
115 July
2918 Belford Jno
F 5
July
3005 Bryan P Art 3A 64
7
103 July
3019 Barr S
G 7
July
3027 Braney J 48 E
7
101 July
3051 Barnes W, Cor
H 8
118 July
3097 Butler L J
E 10
110 July
3109 Brunt A
G 10
101 July
3216 Beraine A A
B 12
103 July
3294 Burns Jas
F 14
157 July
3442 Brinton J
D 17
103 July
3477 Baker Wm
F 17
July
3535 Burnside J, S’t 57 H
18
103 July
3600 Black W O
G 19
July
3693 Billig J L Cav 3H
21
3716 Brenlinger W R, “ 4D July
S’t 21
148 July
3808 Butter C P
A 22
July
3821 Batchell D 55 D
23
July
3917 Bright E 90 I
23
July
3988 Bradford L 10 I
26
July
4002 Berkley M 50 I
26
116 July
4084 Backner Adam
G 27
July
4330 Barrett J 6K
30
53 July
4360 Brown J
G 31
53 July
4402 Butler D
G 31
Aug
4494 Barton Jas Cav 4B
1
Aug
4500 Burke J 90 A
1
Aug
4610 Baker E, Cor 4K
3
Aug
4667 Behreas A 7E
4
Aug
4752 Bennett Geo 55 D
5
Aug
4989 Bowers J Art 2 I
7
Aug
5040 Bammratta —— 73 D
8
5071 Barber C 6D Aug
8
Aug
5084 Buck B F Cav 2K
8
Aug
5113 Brown M 50 D
9
141 Aug
5324 Burlingame A J
K 11
Aug
5391 Bear Jno 79 D
12
101 Aug
5416 Bruce Jno
C 12
Aug
5526 Bower Benj Cav 6L
13
143 Aug
5587 Burnham H
F 14
Aug
5592 Broadbuck A Cav 11 A
14
Aug
5662 Buck B F “ 2K
14
103 Aug
5877 Browning Thos
A 16
115 Aug
5948 Bohnaberger A
G 17
Aug
5969 Boyer F 43 E
17
101 Aug
6061 Baker Jas
C 18
103 Aug
6074 Bower G W
K 18
Aug
6099 Baily J F 18 D
18
103 Aug
6127 Benhand J A
D 19
55 Aug
6229 Bear Sam’l
G 20

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