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Uhde Brochures PDF en 18.00
Uhde Brochures PDF en 18.00
Uhde Brochures PDF en 18.00
by tradition
A new dimension in cokemaking technology
ThyssenKrupp
A company
of ThyssenKrupp
Technologies
Uhde
2
Table of contents
Page
1. Company profile 3
4. Heating systems 8
5. Heating-up burners 9
8. Environmental protection 12
9. Heat-recovery cokemaking 14
With its highly specialised workforce of more than 4,100 employees and an
international network of subsidiaries and branch offices, the Dortmund-based
engineering contractor Uhde has successfully designed and built over 2,000
plants throughout the world.
The company's international reputation has been built on the successful application
of Engineering with ideas to yield cost-effective high-tech solutions for its
customers. The ever-increasing demands placed upon process and application
technology in the fields of chemical processing, energy and environmental
protection are met through a combination of specialist know-how, all-round
service packages, top-quality engineering and impeccable punctuality.
In 2004 ThyssenKrupp EnCoke was integrated into Uhde, adding its internationally
renowned coke plant technologies to the company's portfolio. Since then, EnCoke's
customers have benefited from EnCoke being part of a company with international
sales and engineering offices and high competence in executing demanding
projects.
We provide a wide range of solutions in the field of cokemaking technologies,
from complex hot repairs and revamps to completely new plants, and can thus
make a major contribution to cost-effective, environmentally-friendly steel
production. Our latest achievement, the 2.6 million-tonne coke plant in
Schwelgern (near Duisburg, Germany) which came on stream in March 2003,
has set new international standards in cokemaking.
4
2. Competence and know-how by tradition
A global leader for more than 130 years
Uhde's coke plant technologies division, the own companies in 1898 and 1901, respect-
former ThyssenKrupp EnCoke, is proud to ively, and enjoyed great success for many
offer the entire range of technologies and decades. In the 70's and 80's the companies
know-how from the most famous names in founded by these cokemaking pioneers were
coke plant engineering. taken over by the groups Krupp (Koppers)
and Thyssen (Still, Otto and Didier).
The origin of the division can be traced back Ultimately, the merger of the groups Thyssen
to the company Dr. C. Otto & Comp. which and Krupp resulted in the combination
was founded in the year 1872. Carl Still and of all cokemaking technology activities into
Heinrich Koppers, both employed as junior ThyssenKrupp EnCoke GmbH in 1999,
engineers by Dr. C. Otto, then formed their followed by the integration into Uhde GmbH.
Integrated in the ThyssenKrupp group with building new coke plants, Uhde has a long
its global spectrum of activities Uhde has history of providing comprehensive technologies
assumed the task of continuous improvement, for modernising and repairing entire plants or
building on the decades of accumulated individual plant components. We work jointly
know-how and maintaining the tradition of with the customer to develop the most cost-
quality established by its founders. effective solution to satisfy specific needs.
Uhde has been designing and building coke introduction of compound ovens and the
oven plants for more than 130 years, making it gradual enlargement in chamber height to
the longest established coke plant engineering well over 8 m and in oven volume to over
company in the world. Our competence and 90 m3.
know-how – gained through the construction
of more than 100,000 coke ovens worldwide The principle of multi-stage heating –
– are embodied in numerous inventions and nowadays standard technology for heating
developments which are today recognised coke ovens – was introduced by Carl Still as
standards in modern cokemaking technology: early as 1926. Uhde can now supply the
for example multi-stage heating. Uhde has optimum heating concept to meet any
always been a front runner in the technical specific demand: COMBIFLAME® and
development of coke oven plants. TWINFLUE for compound ovens of either the
Among these inventions and developments gun-flue or underjet type, and MULTISTAGE
are the principle of regenerative heating, the for purely rich gas ovens.
GLD, Detroit, USA Top view of the battery at Schwelgern, ThyssenKrupp Stahl AG, Germany
7
Battery front of 6.2 m ovens at the GLD coke plant, Detroit, USA
Battery
Battery cross-section
Coke wharf
The increasing heights of oven chambers and sealing systems for oven doors and other
the associated stability requirements for main- oven closures. Depending on the application,
taining the refractory materials demand fully Uhde offers either FLEXZED® or FLEXIT®
effective oven bracing systems. Over the oven doors.
course of approximately 30 years Uhde has
developed the CONTROLPRESS® system based The newly developed PROven® system for the
on intensive research and development, individual control of oven chamber pressure
accompanied by data from practical experience. provides a new generation with virtually
emission-free battery operation during coking
Fugitive emissions at coke oven batteries and charging.
have been drastically reduced by well proven
8
4. Heating systems
Optimised heat distribution – low NOx
Lean gas
Air
Waste gas
Uhde has developed a new procedure for needed to protect the brickwork. Flame safety
heating-up batteries by means of external is provided by automatic burner management
fan burners. These are proven standard systems, eliminating the manpower formerly
industrial units, specially selected and required for this purpose.
equipped for the task.
The increased flow of heating gas from the
The high overall volume flow of flue gas start allows the heating-up time to be redu-
produced by the fan burners generates a ced by 2 - 3 weeks.
positive pressure in the entire oven block from
the very beginning of heat-up, accompanied These burners are not only applied for the hea-
by optimum heat transfer throughout the ting-up of new batteries. They have also been
system. Since the hot flue gas is generated successfully used in refractory hot repairs,
outside of the coke oven chamber, local where certain areas of the batteries have to be
overheating in the area behind the coke oven kept at a minimum temperature level.
door is ruled out. Dutch ovens are no longer
900
600
500
400
300
200
100
10 20 30 40 50 60
Heating-up day
Heating-up curve: excellence compliance between set point and actual values
10
6. High stability and gas tightness
Prerequisites for safe operation and long service life
Oven roof
protection
plate
Oven roof
protection
plate
Wall
protection
plate Oven roof bracing
COMBIFLAME®
heating wall Buckstay
Regenerator
protection plate
Pressure elements
for regenerator
protection plate
Regenerator bracing
Sliding joint
Lasting tightness
The FLEXIT® and FLEXZED® coke oven doors suitable for coke ovens with a large chamber
developed by Uhde ideally suit today's height and chamber width. Its high elasticity
requirements for an environmentally results in a excellent capacity to compensate
responsible and for the bending of sealing surfaces,
low-maintenance ensuring maximum gas tightness.
door system. Hence it comes as no surprise that
the tallest and largest coke ovens
The large gas worldwide are equipped with FLEXIT®
escape channels coke oven doors.
at the door plug
reduce the gas The standard door for all oven sizes
pressure at the is the FLEXZED® door, which has
door seal – an been installed in thousands of coke
important ovens worldwide over the decades.
prerequisite for With its adjustable Z-sealing strip
the avoidance of door and its robust cast-iron door body this door
emissions. The seals of these coke oven has proved extremely reliable in withstanding
doors automatically adapt to the door jamb the severe requirements of coke oven
contour, with the required sealing forces operation. Its special features are a high
being provided by springs acting on the sea- level of gas tightness, a robust structure
ling strips. The FLEXIT® coke oven door with and low maintenance requirements.
its flexible stainless steel membrane and door
body made of ductile cast iron is particularly
Installed oven doors
mmWG
0
20% 40% 60% 80% 100%
A low chamber pressure is set at the beginning in the gas generation rate inside the oven.
of the coking time so that the large raw gas When the amount of generated gas declines
quantities generated in this phase are at the end of the coking process, the pressure
discharged without high gas pressures at the in the oven is raised to the point where no air
oven doors. Door and oven top emissions are can be drawn in at the doors. This protects
thus prevented almost entirely. the refractory walls from combustion in the
end zone of the chambers, thus prolonging
As coking proceeds, the chamber pressure is the service life of the ovens.
gradually increased in line with the reduction
13
Pressure
Pressure measurement line controller
NH3 - water Pneumatic
cylinder
Control valve
Standpipe
Fix cup-valve:
Oven roof ∆h~∆P
GC-main
The Uhde heat-recovery cokemaking techno- which develop a higher coking pressure and
logy provides an interesting alternative to are thus unsuitable for carbonisation in hori-
conventional coke production in those cases zontal chamber ovens can therefore be carbo-
in which demand is predominantly for coke. nised safely in heat-recovery ovens.
It dates back to a technology that was wide-
spread in Europe and America prior to the The crude gas produced from the coal is first
introduction of by-product coke ovens. partially combusted in the free space above
the coal charge. The generated mixture of
In heat-recovery ovens, the complete gas waste gas and crude gas is led through verti-
produced from coal carbonisation is combu- cal ducts in the side walls (downcomers) into
sted directly in the oven space, thus creating the heating flue system under the oven sole.
the heat needed for carbonisation. In contrast Here the combustion is completed with the
to the horizontal chamber oven, the coal staged supply of air so that the coal layer is
charge in the heat-recovery oven lies in an evenly heated from top and bottom.
approx.
1 m thick layer on the approx. 4 m wide and Assuming an annual coke production of
15 m long oven sole. 1,000,000 t, approx. 90 MW electric power
can be generated from the hot waste gas,
As the coal charge is not restrained between depending on the properties of the coal.
heating walls, the lateral coking pressure of
the coal blend plays a much less important
role than in horizontal chamber ovens. Coals
Negative pressure
(suction)
Positive pressure
Direct heat
transfer
from top
Indirect
heat transfer
from sides
Indirect heat
transfer
from bottom
By-product Heat-recovery
coke oven coke oven
As the ovens are operated under suction, cake in a cohesive mass. A moveable cover
there are no battery emissions during can be provided over the coke mass in the
carbonisation and almost no emissions car in cases where more stringent emission
during charging. The waste gas from the limits must be observed. This system elimin-
ovens is dedusted, desulphurised and then ates the need for coke side pollution control
discharged into the atmosphere through systems and their associated baghouses.
suction fans and a stack. It has been adapted from the flatbed pushing
system used successfully for many years at
A proven technology is used to charge the the Illawarra non-recovery coke plant in
ovens with compacted coal. The coal blocks Australia.
are of a uniform height and do not require
levelling. The increased density of the coal The heat-recovery cokemaking technology
charge improves the oven throughput. Fewer is a virtually emission-free process with
ovens are required for a given coke produc- comparably low demands on operating crews.
tion rate and the desired coke quality can be It represents a technically and economically
improved in using a wider range of feed lucrative alternative to classical coke making.
coals.
Air
Coal
Flue gas
Sole flue
Air channel
The significance of coke oven gas and its and our proven detailed know-how make us
constituents has changed substantially over the global leader in this field.
the past decades. Today, the foremost task of
a modern coke oven gas treatment facility is A few examples are:
to convert crude gas into an environmentally
compatible fuel as economically as possible. CYCLASULF® process for the desulphurisation
of coke oven gas and removal of ammonia
To this effect crude gas is cooled, compres- VACASULF® process for the desulphurisation
sed and freed from constituents that might of ammonia-lean coke oven gas
entail hazards to the environment or plant.
Apart from the cleaned coke oven gas, the COMBICLAUS®, MONOCLAUS® and COMBACID®
only by-products produced in modern plants processes for the production of elementary sul-
are crude tar, crude benzol, and sulphur. phur or sulphuric acid in simultaneous combina-
The necessary process steps and equipment tion with ammonia cracking
are chosen to eliminate gaseous emissions
and minimise the level of contaminants in the The many types, combinations and configura-
waste water. tions of available by-product recovery proces-
ses mean that we can provide a flexible solu-
Uhde offers the full palette of possible process tion to meet specific requirements.
steps for the economical cleaning of coke
oven gas and the environmentally responsible
processing of by-products and waste water
streams.
Raw gas
The array of processes developed in-house
The condensation system, which consists of simplify the handling of the tar sludge, a com-
the primary coolers and electrostatic tar preci- pletely closed system has been developed. A
pitators, frees the coke oven gas from tar and centrifuge separates out the tar sludge, which
condensate. The exhausters then compress is then pumped back to the feed coal of the
the gas to the pressure needed for the down- batteries by a high-pressure pump.
stream process units. In most gas treatment
plants the disposal of tar sludge is carried out
manually using equipment that is more or
less open to the atmosphere.
Centrifuge
In order to reduce environmental pollution and
Coal water
tank
Tar
decanter
Tar sludge
Solid pump
Crude tar
Gorator
The well-known CYCLASULF® process for the The standard process for the desulphurisation
removal of H2S and NH3 has undergone many of ammonia-lean coke oven gas is the
detailed improvements. By using structured VACASULF® process, which uses potash
packing, instead of expanded metal packing, solution as an absorbent. The absorbed
for the scrubbers and parts of the desorber, hydrogen sulphide is recovered as sour gas
the dimensions of the columns have been through regeneration under partial vacuum.
reduced significantly. This allows the H2S and The partial vacuum in the H2S stripper allows
the NH3 scrubbers, as well as the deacifier the use of very low-temperature heating
and the fixed and free ammonia stills, to be media. The heat required for regeneration of
combined into single columns. The amount the potash solution is supplied indirectly.
of mechanical equipment and associated The heat requirement can be provided either
investment costs can therefore be reduced by sensible heat from the hot water generated
drastically. The coke oven gas processed in at the top of the primary cooler, by sensible
these purification units can be used as heat from the flushing liquor before it enters
underfiring gas for the coke oven batteries the collecting main of the coke oven battery
or for applications in the blast furnace. or by latent heat using low-pressure steam.
Most of the equipment is fabricated from
carbon steel, with a negligible portion of
stainless steel.
Gas treatment unit at Schwelgern coke plant, Germany VACASULF® coke plant, Fürstenhausen, Germany
19
The sour gas vapours released from the H2S BTX and/or naphthalene components can be
and NH3 desorption system are further treated removed from the coke oven gas using two
in the sulphur recovery unit. Many coke plants main types of wash oil. The normal degradation
have adopted the CLAUS process with of petroleum-based wash oil makes it more
simultaneous NH3 destruction to produce suited to once-through operation, whereas
liquid sulphur. In order to reduce investment tar-based wash oil can be successfully
and operating costs, a modified MONOCLAUS®- regenerated and recirculated to the BTX
process has been developed by Uhde. removal process. The recovered BTX fraction
has a typical boiling range of 95% at 180°C.
Contrary to the usual CLAUS-process the kiln
is positioned horizontally, the process gas Biological treatment
cooler and sulphur condenser are combined in
a common unit and only one CLAUS reactor is The waste water effluent from the H2S/NH3
used for the catalytic conversion. In this way regeneration unit comprises the water present
the costs for piping, steelwork and as the coal moisture, the water released
instrumentation can be reduced by about during coking and the condensed direct
30%. The tail gas is recycled to the raw coke stripping steam. The total concentration of
oven gas so that no emissions occur. NH3 in the waste water is less than 100 mg/l.
Biological treatment can be used to condition
Depending on specific requirements other the waste water before it is discharged
H2S processing technologies can be provided, from the plant if this is required by local
such as conversion to sulphuric acid for use regulations.
in combination with ammonium sulphate
production.
LP-steam
Claus reactor
H2S/NH3 vapors
Tail gas
Claus kiln
Sulfur
Air
MONOCLAUS® process
20
13. Tar refining
Huge variety of products
The feedstock of the tar refining plant is a centrifuge. This is followed by neutralisation
typically the crude tar recovered in the coke to reduce the corrosion hazard. The separation
oven by-product plant. A wide range of of tar fractions with individual boiling ranges
products can be separated from the crude tar. uses a system of distillation columns with
direct heaters and an efficient heat recovery
The state of the art for primary distillation system. The main products of the primary
consists of two alternative systems. The first distillation are the light oil, naphthalene oil,
is complete vacuum distillation, the second a wash oil and anthracene oil-fractions and
combination of atmospheric and vacuum a normal pitch as the residue.
distillation.
Special oils
Oil mixing
Crude tar
Anthraquinone
Anthracene Anthraquinone
crystallisation oxidation
Special pitch
Pitch
reforming
Hidden treasures
With the emphasis on increasing coke hydrogen-content of coke oven gas makes
production and less on by-products, the use it suitable for direct use as a synthesis gas
of coke oven gas for alternative purposes is (see table below).
becoming more and more attractive. The high
Proven technologies can be applied, such as of the synthesis processes, Uhde has
methanol or ammonia synthesis or H2 developed and diversified the standard gas
separation. In order to meet the requirements treatment process.
Tar +
Water
Desulfuri-
H2S sation
Tar Tar
separation
Composition %
H2 : 63.26%
CO : 29.22%
CO2 : 5.17%
Tail gas
H2O : tr.
Flushing CH4 : 0%
Claus
liquor plant N2 : 2.35%
Sulfur Methanol,
Ammonia, H2
Treatment of coke oven raw gas and tar for generation of synthesis gas
22
15. Coke cooling
Trend-setting for wet and dry quenching
Fresh water
In addition to environmental aspects, energy slowly from the coke. As a result the burden
savings may make CDQ plants the preferred of coarse dust particles in the cooling gas is
option at certain locations. The main high- appreciably smaller, thereby obviating the
lights of Uhde's technology in this field are need for the additional coarse particle separator
as follows: normally required in plants with a circular coke
cooling shaft. A compact plant design is thus
The cross-sectional area of the cooling shaft possible.
is rectangular in shape instead of circular as
in traditional CDQ plants and permits the The insulating brick lining of conventional
installation of swing discharge units located coke cooling shafts is encased in a metal skin
at the bottom end of the cooling chamber. and designed to be self-supporting. In contrast
The sequential operation of these discharge to this arrangement the Uhde cooling shaft is
units means that, apart from adjustment of designed as a vessel, with the heat insulating
the throughput rate, the coke flow in the coo- brickwork suspended in a steel framework
ling chamber can also be influenced. This anchored to the vessel walls. Hence, the statical
leads to more even coke cooling correspon- load of the shaft is not borne by the brickwork,
ding to the actual conditions inside the coo- providing relief especially in the area of the
ling chamber. cooling gas outlets where openings in the
shaft wall must necessarily be provided. This
Because of the rectangular design of the transfer of statical load allows the Uhde
cooling shaft a coke-free region is created in design to focus on the demands of the cooling
the upper zone of the cooling chamber just in process without being restricted by considera-
front of the cooling gas outlets. Hence, the tions of brick strength.
coke-free gas collection space acts as a dust
separator for the hot cooling gas emerging
Hot coke
Hot gas
Cold gas
Cross-section
of a CDQ system Cold coke
24
16. Coke plant automation
®
Flexible solutions with COKEMASTER
The challenge
To be able to operate a coke oven plant at The ManuThermTM system is an infrared pyro-
optimum efficiency, it has to be equipped with meter with integral data memory for taking manual
state-of-the-art automation technology. The aim measurements at the heating flues. Its main
of automating the process sequences is to job is to measure heating flue temperatures
facilitate the long term adjustments required to when no AutothermTM measurements are
meet environmental protection requirements. available, for instance when no coke-pushing
is taking place for operational reasons. Also,
The engineering detailed spot measurements can be taken where
heating problems have been detected by
Uhde has been successfully engaged in the AutoThermTM. These temperature measurements
automation of coke oven plants since 1980. are fed into the computer system and can be
The automation systems are tailored to the used for further calculations and evaluations.
customer's specific requirements in each case.
The modular design of the automation systems The BatControlTM system calculates the amount
favours this approach. of heat required for the battery, taking into
account all relevant operating parameters such
The results as coal quality, coal moisture, coke pushing
schedule, etc. The heating situation is controlled
To meet the challenge, the following system automatically and the heat input is corrected
structure has been developed under the immediately upon detecting a fault, such as a
umbrella of the COKEMASTER® automation delay in production or a change in temperature.
architecture:
The PushSchedTM system is an automatic
The AutoTherm measuring system uses its six
TM
pushing and charging schedule calculation
infrared sensor heads to measure the surface program designed to assist operating crews.
temperatures of the two heating walls at three The production plan is recalculated continuously
different levels during each coke pushing after every coke pushing operation, taking into
operation. In other words, the heating walls are account special operating conditions such as
thermally scanned, allowing an exact overview "oven with extended coking time" or "oven out
of the temperature distribution in each heating of service". The resulting production schedule is
wall. The aim is to keep the temperature transmitted to the machines. Confirmations
distribution in the heating walls as uniform as received from the oven machines are forwarded
possible and to detect any changes. to the BatControlTM system so that the heating
can be corrected automatically.
Operator Scheduling of
station Coordination PLC for oven maschines DCS
oven maschines
controlroom
Heat quantity
control
The GasControlTM system is a process model for process control system) and the process model
gas treatment plants. The process model is calculated dynamically. By varying the control
consists of the CHEMCAD commercial simulator parameters (e.g. steam rate, water rate, etc.)
for chemical plants plus extension modules in this virtual plant it is possible to optimise the
developed by Uhde for individual coke-oven- operating results. The control parameters that
specific machinery and equipment. The deliver the best operating results are retransmit-
GasControlTM process model uses chemical and ted to the plant instrumentation to set the local
thermodynamic mass equilibria and streams to controllers in the "real" plant. All important data
rate each individual gas treatment unit and can be displayed on screens, reports and trend
determines the input and output streams, charts. This model is not only a powerful tool for
interlinking them in accordance with the plant plant optimisation and automation - it can also
flowsheet. The model is supplied with the be used in an off-line simulation mode as a
relevant on-line process variables from the plant training tool for operators.
instrumentation in real-time mode (via the
Process control
Process
data
Automation system for gas treatment plant operation
AutoThermTM
ManuTherm TM
MaintControl TM
SimuCoke TM
COKEMASTER®
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17. Repair, modernisation and services
The world’s best references
Cleaning/replacement
Silica welding of of regenerator
wall damage checker bricks