CWT-2 Halogen Derivatives T-201717

5/4/24, 11:07 AM Glorifire Authors
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Test Paper Name: CWT-2_Halogen Derivatives_T-201717
Duration: 60min | Test Type : Concept Test | Goal: JEE(M) | Bucket Type: Glorifire
No. of Attempts : 0 Language : en-us

Test Pause : No Shuffle :
Test Questions:
Section Name: Section 1 No. of sub Section: 2
Sub Section Name: Single Correct Type Mandatory
Question Type : SMCQ

Marks Per Question : 4
Total Questions : 20 Par. Marks Per Question : 0
Mandatory Questions : 20 Neg. Marks Per Question : -1
Q1.
ID:
Q-1207513
Options are:
(A)
(B)
(C)
(D)
Q2. A dextro-rotatory optically active alkyl halide undergoes

hydrolysis by SN 2 mechanism. The resulting alcohol is :
ID:
Q-1207530
Options are:
(A) Dextrorotatory
(B) Laevorotatory
(C) Optically inactive due to racemization
(D) May be dextro or laevorotatory
99+ Q3. Neopentyl bromide undergoes dehydro halogenation to give

alkene even though it has no β -hydrogen. This is due to:
ID:
Q-1207533
Options are:
(A) E2 mechanism
K
https://authors.glorifire.com/content/preview/6635c793ecb8985426360bc7testpapers 1/9
(B) by direct dehydrohalogenation
(C) rearrangement of carbocation by E1 mechanism
(D) E1cB mechanism
Q4.
ID:
Q-1207551
Options are:
(A)
(B)
(C)
(D)
Q5.
ID:
Q-1207596
Options are:
(A)
(B)
(C)
(D) A & C Both
Q6.
99+ ID:
Q-1207608
Options are:
(A)
(B)
(C)
(D)
Q7. Which one of the following is not E2 reaction?

ID:
Q-1207637
Options are:
(A)
(B)
(C)
(D)
Q8. Most reactive alkyl halide towards E2 mechanism is :

ID:
Q-1207642
Options are:
(A)
(B)
(C)
(D)
Q9. An S N 2 reaction at an asymmetric carbon of a compound

always gives :
ID:
99+
Q-1207655
Options are:
(A) an enantiomer of the substrate
(B) A product with opposite optical rotation
K (C) A mixture of diastereomers
(D) A single stereoisomer
Q10.
(x) and (y) are :

ID:
Q-1207660
Options are:
(A) Structural isomers
(B) Enantiomers
(C) Different compounds
(D) Identical compounds
Q11.
ID:
Q-1207668
Options are:
(A)
(B)
(C)
(D)
Q12. The product in the given reaction is:
ID:
Q-1207751
Options are:
99+
(A)
(B)
(C)
(D)
Q13.
major product is
ID:
Q-1207830
Options are:
(A)
(B)
(C)
(D)
Q14. What is the product in following reaction?
ID:
Q-1207854
Options are:
(A)
99+
(B)
(C)
(D)
Q15. Consider the following groups:

(I) —OAc (II) —OMe (III) —O—SO2—Me
(IV) —O—SO2—CF3
The order of leaving group nature is:
ID:
Q-850551
Options are:
(A) I > II > III > IV
(B) IV > III > I > II
(C) III > II > I > IV
(D) II > III > IV > I
Q16. Arrange the following compounds in decreasing order of

their reactivity for hydrolysis reaction
ID:
Q-850724
Options are:
(A) I > II > III > IV
(B) IV > II > I > III
(C) III > IV > II > I
(D) IV > III > II > I
Q17.
A is :
ID:
Q-850959
Options are:
(A)
99+
(B)
(C) Both
K (D) None
Q18. The major product formed in the following reaction is :
ID:
Q-852253
Options are:
(A)
(B)
(C)
(D)
Q19. In the given pairs, which pair represent correct order of rate
dehydrohalogenation reaction.
ID:
Q-852508
Options are:
(A)
(B)
(C)
(D)
99+
Q20. Consider the given reaction:
In the given reaction the product P is:

ID:
K Q-919414
Options are:
(A)
(B)
(C)
(D)
Sub Section Name: Numerical Mandatory
Question Type : Numerical

Marks Per Question : 4
Total Questions : 5 Par. Marks Per Question : 0
Mandatory Questions : 5 Neg. Marks Per Question : -1
Q21. The number of resonance structures for Z is:
ID:
Q-1207864
Correct answer is 9
Positive tolerance is 0
Negative tolerance is 0
Q22.
Molecular mass of P is:

ID:
Q-1207869
Correct answer is 94
Q23. How many statements are correct?

(1) Boiling point order of alkyl halides will be
R − I > R − Br > R − Cl > R − F
(2) Haloalkanes reacts with KCN to form alkyl isocyanide
as main product while AgCN forms cyanides as main
product.
(3) Finkelstein reaction carried out with alkyl
chloride/bromide and NaI in acetone.
(4) Elimination of HBr from 2-Bromobutane results in the
formation of predominantly 2-Butene.
99+ (5) 1-Bromo-1-phenylethane shows greater reactivity
towards SN 1 , and SN 2 reaction compared to isopropyl
bromide.
(6) Allyl bromide gives SN 1 reaction but vinyl bromide does
not.
(7) CH3 − CH2 − O − CH2 Br is less reactive than tert-
K Butyl bromide for SN 1 reaction.
(8) Alkyl halides are soluble in organic solvents and
insoluble in water generally.
ID:
Q-1207870
Correct answer is 6
Q24. Number of alkyl chloride (including stereoisomers) which on

reaction with alcoholic KOH gives 2-Methylbut-2-ene as a
major product.
ID:
Q-1207873
Correct answer is 3
Q25. How many statements are NOT true?

(1) 3∘ halide generally does not give S N 2 reaction.
(2) SN 1 is unimolecular and pseudo 1st order kinetics.
(3) Rate of SN 2 increase with weak Nu− but SN 1
increases with strong Nu− .
(4) Aryl halide does not give S N 1 reaction.
(5) Synthesis of alkyl fluorides is best accomplished by
AgF, Hg2 F2 , CoF2 or SbF3 .
(6) SN 1 reaction favours in polar protic solvent while SN 2
reaction favours in polar aprotic solvent.
(7) The rate of solvolysis of 1-Chloropent-2-ene is greater
than 1-Chloropentane in water.
(8) The solvolysis of 1-Chloropropene and 1-Chloroethane
do not take place in water.
ID:
Q-1207877
Correct answer is 1
99+

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5/4/24, 11:07 AM Glorifire Authors

Test Paper Name: CWT-2_Halogen Derivatives_T-201717

No. of Attempts : 0 Language : en-us

Section Name: Section 1 No. of sub Section: 2

Sub Section Name: Single Correct Type Mandatory

Question Type : SMCQ

Q2. A dextro-rotatory optically active alkyl halide undergoes

(C) Optically inactive due to racemization

(D) May be dextro or laevorotatory

99+ Q3. Neopentyl bromide undergoes dehydro halogenation to give

(B) by direct dehydrohalogenation

(C) rearrangement of carbocation by E1 mechanism

(D) E1cB mechanism

(D) A & C Both

Q7. Which one of the following is not E2 reaction?

Q8. Most reactive alkyl halide towards E2 mechanism is :

Q9. An S N 2 reaction at an asymmetric carbon of a compound

(A) an enantiomer of the substrate

(B) A product with opposite optical rotation

K (C) A mixture of diastereomers

(D) A single stereoisomer

(x) and (y) are :

(A) Structural isomers

(C) Different compounds

(D) Identical compounds

Q12. The product in the given reaction is:

Q14. What is the product in following reaction?

Q15. Consider the following groups:

(A) I > II > III > IV

(B) IV > III > I > II

(C) III > II > I > IV

(D) II > III > IV > I

Q16. Arrange the following compounds in decreasing order of

(A) I > II > III > IV

(B) IV > II > I > III

(C) III > IV > II > I

(D) IV > III > II > I

Q18. The major product formed in the following reaction is :

Q20. Consider the given reaction:

In the given reaction the product P is:

Sub Section Name: Numerical Mandatory

Question Type : Numerical

Q21. The number of resonance structures for Z is:

Molecular mass of P is:

Q23. How many statements are correct?

Q24. Number of alkyl chloride (including stereoisomers) which on

Q25. How many statements are NOT true?

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