Punjab College P.D.

Khan Campus
Half Book Test (2024) (1st Half) Roll No: ________
Paper Group (A) Name:
Class: Inter Part–I Max. Marks: 68
Subject: Chemistry Time Allowed: 2.40 Hours

Subjective
Section -1
Answer briefly any eight parts from the following: 2×8=16
i. No individual Neon (Ne) atom in the sample of the elements ha a mass of 20.18amu. Why?
ii. What is mass spectrometer? What is function of magnetic field in mass spectrometer?
iii. Mg atom is twice heavier than that of carbon atom.
iv. Calculate volume of 8g of oxygen gas.
v. Write any three applications of principal quantum number..
vi. Calculate number of Oxygen atoms in 9g of Glucose.
vii. How does Gooch crucible increases the rate of filtration?
viii. Explain the best method for drying the crystals during crystallization process.
ix. Differentiate between stationary and mobile phase in chromatography.
x. Throw light on the factor 1/273 in Charles’s law.
xi. Why Pilots feel uncomfortable breathing in unpressurized cabin? XII. Convert 95°F to °Celsius.

Answer briefly any eight parts from the following: 2×8=16

i. What is Joule Thomson effect?
ii. Write two characteristics of plasma.
iii. What is the difference between natural and artificial plasma?
iv. Why ice float on water?
v. Arrange ∆Hv , ∆Hf & ∆ Hs in increasing order with reason.
vi. Why boiling point if water is greater than HF, although Fluorine is more electronegative than Oxygen.
vii. Define polymorphism and anisotropy.
viii. What are crystallographic elements? Explain with diagram.
ix. Explain why ionic crystals are brittle?
x. What is the coordination number of the cation in (a) NaCl (b) CsCl structure? Explain reason for this difference?
xi. Describe monoclinic and triclinic system. xii. What is cubic close and hexagonal close packing?

Answer briefly any six parts from the following: 2×6=12

i. Why nature of anode rays depends on nature of gas?
ii. Derive de-Broglie equation λ = h/mv.
iii. Differentiate between orbit and orbital.
iv. Write down the nuclear reaction involving in the conversion of Cu into Zn.
v. Burning of candle is spontaneous process. Justify.
vi. How much amount left after complete reaction of 4g H2 and 16g of O2.
vii. Why it is necessary to mention the physical states if reactants and products in thermochemical reaction?
viii. Prove that qv = ∆E. ix. Draw and label diagram of bomb calorimeter.

Section –II
Note: attempt any three questions. Each question carries 08 marks. 8*3=24
Q5. (a) Write a method to determine Empirical formula.
(b) What are the densities in kg/m3 for following gases at STP( P= 101325Nm-2, T= 273K, molecular
masses are in kg/mole? (a) Methane (b) oxygen (c) hydrogen . Also compare the values of densities in
proportion to their molecular masses.
Q6. (a) Explain structure of ice with the help of hydrogen bonding.
(b) Write any 7 properties of cathode rays.
Q7. (a) Explain metallic solids with help of different theories.
(b) Write a method to measure heat of Neutralization.
Q8. (a) Calculate the value of R in STP and SI units. (b) Prove ∆H = qp.
Q9. (a) Define Yield, its types and explain why actual yield is always less than theoretical yield.
(b) Explain detects of Bohr’s atomic model.