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EXTREME TRIBOLOGY
Fundamentals and Challenges
Ahmed Abdelbary
Ph.D., M.Sc., B.Sc.(Eng.), EGTRIB Mem
Chief Engineer and Tribology Consultant
Egyptian Government
Alexandria, Egypt
p,
p,
A SCIENCE PUBLISHERS BOOK
A SCIENCE PUBLISHERS BOOK
CRC Press
Taylor & Francis Group
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situations. On the other hand, there are not too many papers or books that are especially dedicated to the
education of senior and graduate students interested in these important issues.
The new textbook of the author is, therefore, an ideal solution to this problem. After a comprehensive
introduction to the field of tribology in general, in which the effects of the volume properties of the
tribo-materials, their surface properties and the use of possible lubricants on friction and wear of tribo-
systems are also described, the author focusses the attention of the reader on the theory of friction, factors
affecting the latter, measurement techniques, and friction related heat and temperature effects. Two other
important subjects follow: (a) A description of possible wear mechanisms, including corresponding wear
measurements, and (b) the lubrication of tribo-systems by fluidic, gaseous, grease or solid media, including
various types of additives incorporated in them. In the following, Dr. Abdelbary dedicates two other
chapters to the tribology of polymers and their composites, and to the tribology of automotive components.
Especially in this field, polymer composites have been very successfully used in recent times. It would be
hard to find a polymer for automotive tribo-applications which is not in a composite or a polymer/metal
hybrid form. His work is then concentrated on friction and wear under other extreme conditions, where he
especially emphasizes the mechanisms and effects that occur at high or low cryogenic environments, in a
vacuum, and at high speeds. Also, abrasion aspects in mining, mineral processing, and treatment of solid
concrete are touched upon. This is followed by a chapter on lubrication and coating challenges in extreme
conditions, which also considers vacuum effects in space tribology and lubrication in artificial joints, to
mention only a few. The two concluding chapters deal with the simulation and modelling of tribo-systems,
and with failures in particular types of wear components, like gears, bearings, wheels and artificial implants.
The book is not only intended to teach postgraduate students in the field of tribology in general,
but also under extreme conditions in particular. Nevertheless, it will be also of interest as a balanced
textbook for different levels of readers: (1) those who are active or intend to become active in research on
materials’ tribology in general (material scientists, physical chemists, mechanical engineers); (2) those
who have encountered a practical friction or wear problem and wish to learn more methods of solving
such problems (designers, engineers and technologists in industries dealing with selection, processing and
application of engineering materials); (3) professors at universities, who want to set-up new courses in this
field. This is very important, since by now, the average mechanical engineer receives only a few hours of
instruction on wear during his/her university studies. Therefore, the book is highly recommendable for a
broad engineering community.
Kaiserslautern, 28th June 2019
Prof. Dr.-Ing. Dr. hc Klaus Friedrich
Institute for Composite Materials (IVW GmbH)
67663 Kaiserslautern, Germany
References
Friedrich, K. 2018. Polymer composites for tribological applications (A review). Advanced Industrial and Engineering
Polymer Research 1: 3–39.
Friedrich, K. and Breuer, U. (eds.). 2015. Multifunctionality of Polymer Composites, Elsevier, Oxford, UK.
Holmberg, K. and Erdemir, A. 2017. Influence of tribology on global energy consumption. Costs and Emissions,
Friction 5: 263–284.
https://en.wikipedia.org/wiki/Tribology.
Jost, H.P. 1966. Lubrication (Tribology)—A Report on the Present Position and Industry’s Needs. Department of
Education and Science, H.M. Stationary Office, London, UK.
Acknowledgment
First and foremost, I would like to express my sincere gratitude to Prof. Dr. MN Abouelwafa, who has
been instrumental in completing my postgraduate degrees and has been my role model since the moment
I started my research career until his death in 2013.
I would like to record my gratitude and thanks to Prof. Klaus Friedrich. His contribution to this work
is immense and cannot be acknowledged in words.
I was fortunate to have assistance from Dr. Maged E Elnady for proof reading this book. His invaluable
mentorship, stimulating discussions and support were instrumental in completing this work.
I would also like to extend my gratitude and thanks to Dr. Yasser S Mohamed (Assistant Professor,
Faculty of Engineering, Alexandria University) for going through the book and suggesting helpful changes
and ideas.
I owe my family the deepest debt. My mother, thank you for your love and constant support. My wife,
Gigi, and my children, thank you for bearing added stress during the elaboration of this book.
A Abdelbary
Contents
Foreword v
Acknowledgment vii
1. Introduction to Tribology 1
1.1 Introduction 1
1.2 History of Tribology 3
1.3 Development and Future Challenges 6
1.4 Knowledge of Tribology: Education, Publications and Researches 8
References 19
2. Tribo-material Properties 20
2.1 Introduction 20
2.2 Volume Properties 20
2.2.1 Elastic Deformation 20
2.2.2 Plastic Deformation 22
2.2.3 Creep Deformation 23
2.2.4 Hardness 24
2.2.5 Fatigue and Fracture Mechanics 25
2.3 Thermal Properties 27
2.4 Surface Properties 27
2.4.1 Adhesion 27
2.4.2 Surface Reactivity 30
2.4.3 Surface Roughness 31
2.5 Lubricant Properties 35
2.5.1 Density and Specific Gravity 36
2.5.2 Viscosity 36
2.5.3 Thermal Properties 38
2.5.4 Other Properties 39
References 41
3. Friction 43
3.1 Introduction 43
3.2 Contact of Solid Surfaces 43
3.3 Theories of Friction 44
3.3.1 Adhesion Theory of Friction 44
3.3.2 Junction Growth Theory 47
3.3.3 Asperity Interlocking Theory 48
3.3.4 Stick-Slip Theory 48
3.4 Laws of Sliding Friction 49
3.5 Laws of Rolling Friction 50
3.6 Factors Affecting Friction and Wear 51
x Extreme Tribology: Fundamentals and Challenges
4. Wear 72
4.1 Introduction 72
4.2 Wear Mechanisms 72
4.2.1 Adhesive Wear 72
4.2.2 Abrasive Wear 75
4.2.3 Surface Fatigue Wear 77
4.2.4 Corrosive Wear 79
4.2.5 Fretting Wear 80
4.2.6 Impact Wear 82
4.2.7 Erosive Wear 83
4.2.8 Thermal Wear 86
4.2.9 Other Types of Wear 87
4.3 Wear-regime Maps 87
4.4 Generation of Wear Debris 90
4.5 Measurement of Wear (Tribo-measurements) 94
4.5.1 Sliding Wear Test 96
4.5.2 Rolling Wear Test 97
4.5.3 Scratch Wear Test 99
4.5.4 Abrasion Wear Test 100
4.5.5 Erosion Wear Test 101
4.5.6 Impact Wear Test 102
References 102
1.1 Introduction
Tribology is a relatively new word, although it represents phenomena and problems that have been
around since the Stone Age and extend to our present lives. The word “tribology” was introduced in 1964,
when a working group chaired by Dr. H. Peter Jost CBE was invited by the UK Department of Education
and Science to investigate the state of lubrication education and research, and to give an opinion on the
needs of the industry. When the group introduced the report in February 1966, they proposed, for the
first time, the word “tribology” to describe this field (Jost, 1966). The word comes from the ancient Greek
“tribo” meaning “rubbing” and the suffix “logy” for “the knowledge of”, so the literal translation would
be “the science of rubbing”. Currently, dictionaries define tribology as “the study of friction, wear and
lubrication, and the design of bearings” or “the science of interacting surfaces in relative motion” (Oxford,
Dictionary).
By definition, tribology is an interfacial phenomenon that is affected by physical and mechanical
properties of the two interacting surfaces as well as operational conditions. Since surface interactions are
highly complex aspects, their understanding requires studying a variety of fields, including mechanical
engineering, material science, surface topography and fluid mechanics. Moreover, there is a further
complexity due to the fact that tribology is strongly associated with a wide range of practical applications,
with small possibilities of theoretical formulation for a limited range of them.
If we try to explore the principal constituents of tribology of interacting solid surfaces, we realize that
friction and wear are very ancient ones. In fact, solid surfaces are in contact with each other in relative
motion, that is, surfaces sliding, rolling and rubbing on each other. For effective solution of tribology
problems, all three constituents should be considered carefully and equally.
Since time immemorial, efforts have been made in order to minimize wear and control friction. This
has triggered the need for lubrication, in which fluids (or solids) are introduced as a lubricant film to
reduce the contact between moving surfaces in order to save power and material, Fig. 1.1 represents an
illustration for tribology triangle.
The word “friction” came into usage in the middle of the 16th century, it comes from the Latin
frictiō, meaning “a chafing or rubbing”, and from Middle French friction as a noun of action from the
past participle stem of fricare, meaning “to rub”. The first record of using friction as “resistance to motion”
was in the middle of the 17th century (Oxford, Dictionary). Even though many scientific definitions were
introduced in order to describe this phenomenon, most of them have the common essence that there are
two regimes of friction: Static friction between non-moving surfaces and kinetic (or dynamic) friction
between moving surfaces.
Friction is expressed in quantitative terms as the force generated between the two surfaces in the
direction opposite to the direction of motion (for kinetic friction) or potential motion (for static friction). To
easily differentiate between the two cases, one can observe that, in static friction, the force is insufficient
to cause motion, whereas in dynamic friction, it is sufficient.
2 Extreme Tribology: Fundamentals and Challenges
In general, the friction force is described in terms of a coefficient of friction (µ) which is the ratio of
the friction force (F) to the normal load (W) acting between both surfaces:
F
µ= (1.1)
W
The coefficient is called either static or dynamic coefficient of friction, depending on the friction case.
The main factors contributing to the friction coefficient are: Topography of surfaces in contact, surface
area, normal pressure, sliding velocity and the time during which the surfaces remain in contact. Other
factors, such as temperature, humidity, etc., may have a considerable influence on the nature of friction
(Dowson, 1998).
In the late of the 13th, century the word “wear” was used in reference to clothing in order to express the
gradual damage caused by continued use. In material science, wear is related to the removal and deformation
of material on a solid surface as a result of mechanical action of the opposite surface (Materials, 2001).
Among several definitions of this process, wear can be simply expressed as “progressive loss of substance
from the operating surface of a body occurring as a result of relative motion at the surface” (Materials,
1969; Rabinowicz, 1995; Halling, 1979).
Although wear is generally thought of as a harmful phenomenon, this is not totally true. Even though
this can be found in the majority of practical cases, there are a considerable number of useful applications
of the wear process. For instance, surface production and surface finishing of manufactured objects using
abrasion processes and the use of a pencil or a chalk are examples of desirable wear. Thus, practically
speaking, wear is not always to be avoided.
Wear can be described by three basic terms: (i) wear mechanism, (ii) wear process, and (iii) wear
type. Although our consideration of the various mechanisms of wear is now improving, no unique law
(compared to that for friction) has been generalized. The main reason for this is that the wear process
involves diverse phenomena interacting in a largely unpredictable manner.
The first record of using the word “lubrication” was in the early 19th century. The Latin
lūbricātus, past participle of lūbricāre, means “to make slippery” (Oxford, Dictionary). Since lubrication
can effectively change the performance of tribo-systems (any system containing tribological components),
one of the most general definitions is that “a lubricant is a substance capable of altering the nature of the
surface interaction between contacting solids”. We should emphasize here that the term “substance” in
the previous definition is not simply exclusive to oil or grease as it may be thought of, even though they
are the most common lubricants in use. In fact, there are other conditions of lubrication, such as fluid
lubrication, grease, solid lubrication, and air and gas lubrication.
Introduction to Tribology 3
In Fluid lubrication, any fluid, including water, can be used as a lubricant in the proper application.
In fluid lubrication, the lubrication regime is considered according to the condition of the lubricant
introduced into a sliding system. The three distinct situations are fluid film lubrication, boundary
lubrication, and mixed lubrication. The most important property of the lubricant in fluid lubrication is the
viscosity of the lubricant.
Grease is a stabilized mixture of a liquid lubricant (mineral or synthetic fluid) and a thickening agent.
Some additives may be introduced to add particular properties.
Solid lubrication occurs when a soft solid film (e.g., Molybdenum disulfide MoS2) is introduced
between sliding surfaces. Also, it may be found as a result of a chemical reaction between the sliding
surface and its environment.
Air or gas is now a rather common lubricant in high-speed bearing applications.
For all previous kinds of lubrication, the main task is to reduce friction, wear and surface adhesion. In
other cases, lubrication is introduced in tribo-systems in order to control the interfacial temperature. When
lubrication breaks down, components can rub destructively against each other, causing heat, local welding,
destructive damage and, finally, failure.
Figure 1.2: (a) Drawing of a car with two studded wheels, circa 1338 A.D., and (b) Wooden bearing for stone wheels,
ancient Egypt.
4 Extreme Tribology: Fundamentals and Challenges
Figure 1.3: Transporting an Egyptian statue, El Bersheh, circa 1900 B.C. (Artificial arrangement of the persons probably
arises from the Egyptian artist’s inability to draw perspective).
Figure 1.4: Drawing of sled friction test geometry, Leonardo da Vinci (1452–1519).
path of motion (Bhushan, 2013). Dowson assumed that each slave can pull about 800 newtons (Dowson,
1998). Consequently, the total work required should be at least equal to the friction force. This would
suggest a coefficient of friction of about 0.23 which is comparable to lubricated sliding of wood. Thus,
we can infer that Fig. 1.3 is a true record of what actually occurred (Davison, 1961).
Introduction to Tribology 5
Egyptians also used organic lubricants around the same period. A chariot in an Egyptian tomb still
contains some of the original animal-fat lubricant in its wheel bearings. It is interesting to know that this
lubricant was contaminated with road dirt in the form of quartz, compounds of aluminum, iron and lime
(Halling, 1979).
From a tribological point of view, the wheel has been considered as one of the most important
innovations, with the transition from sledges to wheeled vehicles first discovered in about 3500 B.C. The
remains of many wheels, dating back to the third millennium, have been found in Europe, Asia and Africa.
In 1928, fragments of what looks like a 2000-year-old thrust ball-bearing were found in Italy, near Rome.
This ball-bearing was probably used in supporting a statue in a sculptor’s workshop.
The scientific study of the friction phenomenon is much more recent than what the abovementioned
applications might suggest. During the Renaissance period (1450–1600 A.D.), Leonardo da Vinci
(1452–1519) postulated the first scientific approach to study friction in his manuscripts, Fig. 1.3. The
most important mathematical result of his studies demonstrated that the friction force is proportional to
load and independent of the apparent (or nominal) area of contact. Another important study was a description
of a low-friction bearing alloy, early form of ball-bearing cage, and ball-and-roller pivot bearings. Although
da Vinci was a pioneer in his findings, his manuscripts had no historical influence because they remained
unpublished for hundreds of years.
Another development for wheel bearings was achieved in 1684 by Robert Hooke (1635–1703). He
suggested that the combination of steel shafts and metal bushes would be preferable to the direct contact
between wooden wheels and iron shafts. Consequently, he presented a series of concepts on bearing design,
seals, materials and lubrication.
The German mathematician Leonard Euler (1707–1783) published two important papers concerning
friction. He introduced a mathematical definition of the force required to move a weight up a slope inclined
to the horizontal plane and defined the coefficient of friction as a function of that slope. The most important
outcome of his studies was his differentiation between kinetic and static friction.
However, in 1699, Guillaume Amontons, independently of Leonardo da Vinci, discovered the rules
of friction after he studied dry sliding between two flat surfaces.
Another important finding in tribology studies, introduced in 1785 by Charles-Augustin Coulomb,
states that once motion starts, the friction force becomes independent of velocity (Amontons, 1699;
Coulomb, 1785). It is important to mention here that the above findings of friction are still considered as
reasonably true, even today.
In 1920, a resurgent interest in the adhesion hypothesis began and it became readily possible to
examine the friction properties of a surface with different degrees of contamination (Hardly and Hardly,
1919; Tomlinson, 1929). Further investigations pointed out that there was a crucial difference between the
apparent and the real area of contact, and that it was the real area alone which determined the magnitude
of the friction force (Holm, 1938; Bowden and Tabor, 1950). To date, there has been an increasing interest
in studying the friction process, especially the way the friction force is produced.
Developments in lubrication were coupled with the petroleum industry. The production of bitumen and
oils from petroleum started in Scotland, Canada and the United States in the 1850s. In fact, the scientific
understanding of the principles of hydrodynamic lubrication started with the experimental investigations
of Beauchamp Tower (Tower, 1884) and the perceptive theoretical interpretation by Reynolds (Osborne,
1886) and related work by Petroff (Petroff, 1883). Since that time, there has been a steady increase of
interest in hydrodynamic bearing theory and practice to meet the demand for reliable bearings in new
machinery.
Conversely, when we turn to investigate the history of wear and adhesion, we find it a much younger
subject than friction and bearing development, although wear phenomena must have been first recognized
many years earlier. This unexpected situation is attributed to the historically very late study of wear process
and the very recent explanation of its governing laws. The Industrial Revolution period (1750–1850) was
the golden age of rapid production machinery development. Consequently, the need for reliable machine
components emerged. Since the beginning of the 20th century, enormous industrial growth has lead to
6 Extreme Tribology: Fundamentals and Challenges
high demand for better tribology. Accordingly, knowledge in wear process has expanded tremendously.
The earliest substantial contributions to the scientific study of wear were performed in the mid-twentieth
century by Holm (Holm, 1946) and followed by Bowden and Tabor (Bowden and Tabor, 1950). Over the
past three decades, the understanding of wear mechanisms, especially in extraordinary operation conditions,
has developed rapidly with the use of advanced measuring devices and methods. There are now many
examples of advanced engineering products whose development and successful use are possible only
through the understanding and successful control of wear processes.
Table 1.1: World’s tribology developments and tendencies in the 21st century. After Sviridenok et al. (2015), with permission
from Springer.
− switching from micro- to nano-level of analysis of nature and frictional activity mechanisms;
tribobiology, tribomechanics)
(tribophysics, tribochemistry,
− development of discrete frictional contact mechanics with regard to the three level model (macro,
micro, nano);
Triboanalysis
− development of thermal calculations of frictional contact in order to measure the mutual influence
between basic force, speed, and structural characteristics of friction materials and surfaces;
− development of theory of frictional adhesion in discrete zones of micro- and nano-contacts;
− expanding the field of research of friction behavior features in moving biological objects in order
to apply biological control methods of friction properties created by nature and implemented in
human articulation joints;
− studying the mechanisms and modelling of resistance against the motion of fish and sea creatures.
− development of new micro- and nano-filled lubrication agents of high temperature resistance and
load bearing capacity;
Science
− creation of lubricants of extraordinarily low resistance (friction factor) in ultrathin layers to ensure
functioning of new micro- and nano-mechanisms;
− creation of a new class of low degrading friction (braking) materials;
− creation of a new class of extra hard friction materials for cutting instruments, including
drilling tools.
for tribosurfaces;
− development of theory and methods of frictional properties control during pressure treatment of
metals, recycling into polymer and composite items, during jet transportation of bulk products, etc.;
− development of application methods for thin ultra-lubricant coatings; improving durability of
cutting tools during processing of materials at a high speed.
− analysis and creation of friction units for micro- and nano-electromechanical systems, nano-
computers, nano-manipulators, etc.;
− development of the 3D prototyping method in terms of modeling complex friction units;
Tribotechnics
− development of new principles of consumption (use) of vehicle braking friction energy in order to
increase their effectiveness and operation life and to reduce noise and environmental pollution;
− creation of new tribo-devices of increased operation life having been exposed to ionizing radiation
and high temperatures, operating in the void and in sea water;
− development of CAD systems for the majority of unified tribojoints;
− development of new structures of tribo-joints with a provision for computer-based control of
friction parameters.
− creation of tribo-technical data banks and sharing computer based access to them with broad
Triboinformatics
National Academy of Sciences of Belarus V.A. Belyi Metal Polymer Research Institute http://www.nasb.gov.by/rus
Belarus Belarusian National Technical University Mechanical Engineering Technology http://www.en.bntu.by
Russian Academy of Sciences Interdepartmental research council on tribology http://www.ras.ru/en/index.aspx
Brazil University of Sao Paulo Surface Phenomena Laboratory http://www.usp.br
Dalhousie University Advanced Tribology Lab http://dal.ca
Canada University of Waterloo Tribology Research Group http://www.uwaterloo.ca
University of Windsor Tribology of Materials Research Group http://www.uwindsor.ca
Chinese Academy of Sciences State Key Laboratory of Solid Lubrication http://www. cas.ac.cn
China Hefei University of Technology Institute of Tribology http://www.hfut.edu.cn
Tsinghua University State Key Laboratory of Tribology http://www.tsinghua.edu.cn
Ecole Centrale de Lyon Laboratory of Tribology and Dynamics of Systems http://www.ec-lyon.fr/en
Institut Supérieur de Mécanique de Paris Laboratoire d’Ingénierie des Systèmes Mécaniques et des Matériaux http://www.supmeca.fr
France
INSA Lyon/University of Lyon Contact and Structural Mechanics Laboratory http://www.insa-lyon.fr
University of Poitiers Laboratory of Solids Mechanics http://www.univ-poitiers.fr
Karlsruhe Institute of Technology Microtribology Centre http://www.kit.edu
RWTH Aachen University Institute for Machine Elements and Machine Design http://www.rwth-aachen.de
Germany
Technical University of Berlin Fachgebiet Systemdynamik und Reibungsphysik http://www.tu-berlin.de
University of Technology Munich Forschungsstelle für Zahnräder und Getriebebau http://www.tum.de
Universiti Kebangsaan Malaysia Advanced Materials Processing & Integrity Group http://www.ukm.my
Malaysia
Universiti Teknologi MARA Tribology Researcher http://www.uitm.edu.my
Universiti Teknikal Malaysia Melaka Green Tribology & Engine Performance Research Group http://www.utem.edu.my
Universiti Teknologi Malaysia Tribology Researcher http://www.utm.my
Universiti Sains Malaysia Nanofabrication & Functional Materials Research Group http://www.usm.my
Delft University of Technology Tribology Research Group http://www.tudelft.nl/en
Netherlands
University of Twente Laboratory for Surface Technology and Tribology http://www.utwente.nl/en
Portugal Aveiro University Machining & Tribology Research Group http://www.ua.pt
Luleå University of Technology Machine Elements Research Group http://www.ltu.se
Sweden
Uppsala University Tribomaterials Research Group http://www.uu.se
Bournemouth University Sustainable Design Research Centre http://www.bournemouth.ac.uk
Cardiff University Tribology and Contact Mechanics Research Group http://www.cardiff.ac.uk
Imperial College London Tribology Group http://www.imperial.ac.uk
University of Cambridge Tribology Research Group http://www.cam.ac.uk
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