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Ue Gray pe rrp ue ofL-2016 3. Batch adsorption of 1000 mg/L phenol was studied at 298 K using 20 mL aliquot at an optimized dose of 0.5 g of activated carbon. What is the adsorption capacity in mg/g at an equilibrium concentration of 750 mg/L? Solution: / Initial phenol concentration, Ca= 1000 mg/L Volume of the solution, V =20 mL Weight of the adsorbent, w= 0.5 g Equilibrium concentration, C.= 750 mg/L Using, os xV where qe= the adsorption capacity in mg/g We have, “ (1000-750) x2 1000-750) 20 19mg 9.51000 mere The adsorption capacity is 10 mg/g. 4. For an adsorbate-adsorbent system, having Langmuir isotherm constant of 0.001 Lg’, calculate the theoretical monolayer adsorption capacity, ay, if the amount of the adsorbate adsorbed per unit mass of the adsorbent was 17.97 mg/g at an equilibrium concentration of 814.03 mg/L. Solution: ‘The Linearised form of typical Langmuir isotherm is given by [@_. p(y — Fy 8 —_ eA 1g / \/ where C,= Equilibrium concentration of adsorbate in mi/E~ I} / 4a = Experimental adsorption capacity in mg/g (Q —a.= monolayer adsorption capacity (mg/g) bb, = Langmuir isotherm constant (Lg)¥ L2016 1. 3.1210° g of palmitic acid (CisHs,COOH) dissolved in benzene was spread on the surface of water. The minimum area to which the acid layer could be compressed (before it would crumble) after the benzene had evaporated, was 123 em’. Calculate the area occupied by a single molecule of the acid. What would be the length of the molecule if the density of the acid is 0.81 gem”, Solution: Molecular weight of Palmitic acid =256 g/mol Number of molecules of acid =2:22%107*6.02x10" _ 745,19 256 Area occupied = 123 cm” 123 733010" 3.12x10* 081 Area per molecule= = 1.675x10"em*, 85x10 om? Volume of acid = 3.8510 7.33x10° V_ 5252x107 Length of a molecule, =~ =~ em= 3.1310 ngth of a molecule, I= = 7 em ‘em, ‘Volume of one molecule, V= =5.252x10 cm? 2. It was found that 0.016 mg of an adsorbate covered 5.0107 m’ of a solid surface. If the molar mass of the adsorbate was 0.284 Kg mol", calculate the molecular area of the adsorbate. Solution: Molar mass of the adsorbate = 0.284 Kg mol''= 284 g mol 16x10" x 6.02310" ‘No. of molecules of adsorbate =- na =2.248%10'7 ‘Area occupied = 5.0*107 m? a Molecular area of the adsorbate =—>-*10_ 9.2910" 2.248x10"”@ L2016 Using equation (1) a ee 14-(814.05%0.0055]. Therefore, the theoretical monolayer adsorption capacity of the adsorbent is 40.05 mg/g. 5, Calculate the empirical Freundlich constant, nr for an aqueous system where the Solution: We have q.=31.96mg/g C,=520.6mg/L k,=0.010%mg.g")\(Lmg") ‘The linearised form of Freundlich equation is loga, =—+logC, +logk, 2 5 _ loed.—log ky ny logC, _1og1.96) -1og(0.0109) > 10g520.6 1.504 +1.962 And this gives n, Since 1/n, >1, it indicates cooperative adsorption.“ 6. The following data was obtained for adsorption of Nz on 5 g of charcoal Pressure(mm Hg) 100 200 500 900 Gas adsorbed (mg) 3.62 444 5.08 5.32 If the area of cross-section of Nz molecules is 16 A’, calculate the surface area per gram of charcoal.L-2016 Solution: Ip = 10107 5x107 2x103 1.1107 Vx =0.276 0.225 0.196 0.187 y=9.990x+0.175 0.002 0 += 0.002 0.004 0.006 0.008 «9.010.012. Vee MP The Plot of 1/x versus 1/p gives an intercept of Va, 2 0475 =x, =5.714mg Thus, the weight of nitrogen that forms a unimolecular layer of 5g charcoal is 5.714 mg. 5.714x107 x 6.0210" 28 Total area= 1.229%10"°%16«10" m*=19.664 m* ‘Number of nitrogen molecules =. =1.229x10" 19.664 28x5 Therefore, area per gram =; 140m?