Eamcet 2009

EAMCET (Engg.
) • Solved Paper 2009 | 1
EAMCET
Engineering Entrance Exam
Solved Paper 2009
PHYSICS
1. When a wave traverses a medium, the 4. A motor of power P0 is used to deliver water at a
displacement of a particle located at x at a time t certain rate through a given horizontal pipe. To
is given by y = a sin (bt − cx ), where a, b and c increase the rate of flow of water through the
are constants of the wave, which of the same pipe n times, the power of the motor is
following is a quantity with dimensions? increased to P1. The ratio of P1 to P0 is
y (a) n : 1 (b) n2 : 1
(a) (b) bt 3
a (c) n : 1 (d) n4 : 1
(c) cx (d)
b 5. A body of mass 5 kg makes an elastic collision
c with another body at rest and continues to move
2. A body is projected vertically upwards at time in the original direction after collision with a
1
t = 0 and it is seen at a height H at time t 1 and t 2 velocity equal to th of its original velocity.
second during its flight. The maximum height 10
attained is (g is acceleration due to gravity) Then the mass of the second body is
(a) 4.09 kg (b) 0.5 kg
g(t 2 − t 1 )2 g(t 1 + t 2 )2
(a) (b) (c) 5 kg (d) 5.09 kg
8 4
2 6. A particle of mass 4 m explodes into three pieces
g(t 1 + t 2 ) g(t 2 − t 1 )2 of masses m, m and 2 m. The equal masses move
(c) (d)
8 4 along X-axis and Y-axis with velocities 4 ms−1
3. A particle is projected up from a point at an and 6 ms−1 respectively. The magnitude of the
angle θ with the horizontal direction. At any velocity of the heavier mass is
time t, if p is the linear momentum, y is the (a) 17 ms−1 (b) 2 13 ms−1
vertical displacement, x is horizontal
13
displacement, the graph among the following (c) 13 ms−1 (d) ms−1
which does not represent the variation of kinetic 2
energy KE of the particle is 7. A body is projected vertically upwards from the
surface of the earth with a velocity equal to half
the escape velocity. If R is the radius of the earth,
maximum height attained by the body from the
(A) KE (B) KE surface of the earth is
R R 2R
(a) (b) (c) (d) R
6 3 3
y t 8. The displacement of a particle executing SHM is
given by
 π
y = 5 sin  4 t +  .
 3
(C) KE (D) KE
If T is the time period and the mass of the
particle is 2 g, the kinetic energy of the particle
T
when t = is given by
x p2 4
(a) graph (A) (b) graph (B) (a) 0.4 J (b) 0.5 J
(c) graph (C) (d) graph (D) (c) 3 J (d) 0.3 J
2 | EAMCET (Engg.) • Solved Paper 2009
9. If the ratio of lengths, radii and Young’s modulus 14. An ideal gas is subjected to a cyclic process ABCD
of steel and brass wires shown in the figure are as depicted in the p-V diagram given below
a, b and c respectively, the ratio between the A B
increase in lengths of brass and steel wires
would be
p
C
Brass
D
2 kg
V
Steel
Which of the following curves represents the
2 kg equivalent cyclic process?
b2a bc
(a) (b) A B A B
2c 2 a2
ba2 a (a) p (b) V
(c) (d)
2c 2 b2c C C
D D
10. A soap bubble of radius r is blown up to form a
T T
bubble of radius 2 r under isothermal conditions.
If T is the surface tension of soap solution, the
energy spent in the blowing A B A B
(a) 3πTr2 (b) 6πTr2
2
(c) 12πTr (d) 24πTr2 (c) p (d) V
11. Eight spherical rain drops of the same mass and C C
radius are falling down with a terminal speed of D D
6 cm- s−1. If they coalesce to form one big drop, T T
what will be the terminal speed of bigger drop?
15. An ideal gas is subjected to cyclic process
(Neglect the buoyancy of the air)
involving four thermodynamic states, the
(a) 1.5 cm- s–1 (b) 6 cm- s−1
amounts of heat (Q ) and work (W ) involved in
(c) 24 cm- s−1 (d) 32 cm- s−1 each of these states are
12. A clock pendulum made of invar has a period of Q1 = 6000 J, Q 2 = − 5500 J; Q 3 = − 3000 J;
0.5 s, at 20°C. If the clock is used in a climate Q 4 = 3500 J
where the temperature averages to 30°C, how W1 = 2500 J; W2 = − 1000 J; W3 = − 1200 J;
much time does the clock lose in each W4 = x J.
oscillation? (For invar, α = 9 × 10−7 / ° C, The ratio of the net work done by the gas to the
g = constant) total heat absorbed by the gas is η. The values of
(a) 2.25 × 10−6 s (b) 2.5 × 10−7 s x and η respectively are
−7 (a) 500; 7.5% (b) 700; 10.5%
(c) 5 × 10 s (d) 1.125 × 10−6 s
(c) 1000; 21% (d) 1500; 15%
13. A piece of metal weighs 45 g in air and 25 g in a 16. Two cylinders A and B fitted with pistons
liquid of density 1.5 × 103 kg- m−3 kept at 30°C. contain equal number of moles of an ideal
When the temperature of the liquid is raised to monoatomic gas at 400 K. The piston of A is free
40°C, the metal piece weighs 27 g. The density to move while that of B is held fixed. Same
of liquid at 40°C is 1.25 × 103 kg- m−3. The amount of heat energy is given to the gas in each
cylinder. If the rise in temperature of the gas in A
coefficient of linear expansion of metal is is 42 K, the rise in temperature of the gas in B is
(a) 1.3 × 10−3/ ° C (b) 5.2 × 10−3/ ° C (a) 21 K (b) 35 K
(c) 2.6 × 10−3/ ° C (d) 0.26 × 10−3/ ° C (c) 42 K (d) 70 K
EAMCET (Engg.) • Solved Paper 2009 | 3
17. Three rods of same dimensional have thermal 22. Four light sources produce the following four
conductivity 3 K, 2 K and K. They are arranged waves :
as shown in the figure below (i) y1 = a sin (ωt + φ1 )
50°C (ii) y 2 = a sin 2ωt
(iii) y 3 = a′ sin (ωt + φ2 )
T K (iv) y 4 = a′ sin (3ωt + φ )
3K 2
100°C Superposition of which two waves give rise to
interference?
(a) (i) and (ii) (b) (ii) and (iii)
K
0°C (c) (i) and (iii) (d) (iii) and (iv)
Then, the temperature of the junction in steady 23. The two lenses of an achromatic doublet should
state is have
200 100 (a) equal powers
(a) °C (b) °C
3 3 (b) equal dispersive powers
50 (c) equal ratio of their power and dispersive
(c) 75°C (d) °C
3 power
18. Two sources A and B are sending notes of (d) sum of the product of their powers and
frequency 680 Hz. A listener moves from A and B dispersive power equal to zero
with a constant velocity u. If the speed of sound 24. Two bar magnets A and B are placed one over
in air is 340 ms−1, what must be the value of u so the other and are allowed to vibrate in a
vibration magnetometer. They make
that he hears 10 beats per second? 20 oscillations per minute when the similar
(a) 2.0 ms−1 (b) 2.5 ms–1 poles of A and B are on the same side, while they
(c) 3.0 ms−1 (d) 3.5 ms–1 make 15 oscillations per minute when their
19. Two identical piano wires have a fundamental opposite poles lie on the same side. If M A and
frequency of 600 cycle per second when kept M B are the magnetic moments of A and B and if
under the same tension. What fractional M A > M B , the ratio of M A and M B is
increase in the tension of one wires will lead to (a) 4 : 3 (b) 25 : 7
the occurrence of 6 beats per second when both (c) 7 : 5 (d) 25 : 16
wires vibrate simultaneously? 25. A bar magnet is 10 cm long is kept with its north
(a) 0.01 (b) 0.02 (N)-pole pointing north. A neutral point is
(c) 0.03 (d) 0.04 formed at a distance of 15 cm from each pole.
Given the horizontal component of earth’s field
20. In the Young’s double slit experiment, the
is 0.4 Gauss, the pole strength of the magnet is
intensities at two points P1 and P2 on the screen
(a) 9 A-m (b) 6.75 A-m
are respectively I1 and I 2. If P1 is located at the
(c) 27 A-m (d) 1.35 A-m
centre of a bright fringe and P2 is located at a
distance equal to a quarter of fringe width from 26. An infinitely long thin straight wire has uniform
1
I
P1, then 1 is linear charge density of Cm−1. Then, the
I2 3
magnitude of the electric intensity at a point
1
(a) 2 (b) (c) 4 (d) 16 18 cm away is (given ε 0 = 8.8 × 10−12 C 2 Nm–2 )
2
(a) 0.33 × 1011 NC −1 (b) 3 × 1011 NC −1
21. In Young’s double slit experiment, the 10th
(c) 0.66 × 1011 NC −1 (d) 1.32 × 1011 NC −1
maximum of wavelength λ 1 is at a distance of y1
from the central maximum. When the 27. Two point charges −q and + q are located at
wavelength of the source is changed to λ 2, 5th points (0, 0, − a) and (0, 0, a) respectively. The
electric potential at a point (0, 0, z ), where z > a
maximum is at a distance of y 2 from its central
is
y 
maximum. The ratio  1  is (a)
qa
(b)
q
 y2  4πε 0z 2 4πε 0a
2λ 1 2λ 2 λ λ 2qa 2qa
(a) (b) (c) 1 (d) 2 (c) (d)
λ2 λ1 2λ 2 2λ 1 4πε 0(z 2 − a2 ) 4πε 0(z 2 + a2 )
28. In the adjacent shown circuit, a voltmeter of 32. An infinitely long
internal resistance R, when connected across B straight conductor is R
100 bent into the shape O
and C reads V. Neglecting the internal I
3 as shown below. It
resistance of the battery, the value of R is carries a current of
A
I ampere and the radius of the circular loop is
R metre. Then, the magnitude of magnetic
induction at the centre of the circular loop is
50 kΩ µ I µ nI
(a) 0 (b) 0
100 V B
2πR 2R
µ 0I µ 0I
(c) (π + 1) (d) (π − 1)
50 kΩ 2πR 2πR
33. The work function of a certain metal is
C 3.31 × 10−19 J. Then, the maximum kinetic
energy of photoelectrons emitted by incident
(a) 100 kΩ (b) 75 kΩ radiation of wavelength 5000 Å is
(c) 50 kΩ (d) 25 kΩ (Given, h = 6.62 × 10−34 J-s, c = 3 × 108 ms−1,
29. A cell in secondary circuit gives null deflection e = 1.6 × 10−19 C )
for 2.5 m length of potentiometer having 10 m (a) 2.48 eV (b) 0.41 eV
length of wire. If the length of the potentiometer (c) 2.07 eV (d) 0.82 eV
wire is increased by 1 m without changing the
34. A photon of energy E ejects a photoelectron from
cell in the primary, the position of the null point
a metal surface whose work function is W0. If
now is
this electron enters into a uniform magnetic field
(a) 3.5 m (b) 3 m
of induction B in a direction perpendicular to the
(c) 2.75 m (d) 2.0 m field and describes a circular path of radius r,
30. The following series L-C-R circuit, when driven then the radius r is given by, (in the usual
by an emf source of angular frequency notation)
70 kilo-radians per second, the circuit effectively 2m(E − W0 )
behaves like (a) (b) 2m(E − W0 )eB
eB
100 µH 1 µF 10 Ω 2e(E − W0 ) 2m(E − W0 )
(c) (d)
mB eB
35. Two radioactive materials X 1 and X 2 have decay
constants 10λ and λ respectively. If initially they
have the same number of nuclei, then the ratio
of the number of nuclei of X 1 to that of X 2 will be
1/e after a time
(a) purely resistive circuit (a) (1 / 10λ ) (b) 1 /(11λ )
(b) series R-L circuit (c) 11 /(10λ ) (d) 1 /(9λ )
(c) series R-C circuit 36. Currents flowing in each of the following circuits
(d) series L-C circuit with R = 0 A and B respectively are
4Ω 4Ω
31. A wire of length l is bent into a circular loop of
radius R and carries a current I. The magnetic
field at the centre of the loop is B. The same wire
is now bent into a double loop of equal radii. If 4Ω 4Ω
both loops carry the same current I and it is in
the same direction, the magnetic field at the
centre of the double loop will be 8V 8V
(Circuit A) (Circuit B)
(a) Zero (b) 2 B
(c) 4 B (d) 8 B (a) 1 A, 2 A (b) 2 A, 1 A
(c) 4 A, 2 A (d) 2 A, 4 A
37. A bullet of mass 0.02 kg travelling horizontally 39. A rod of length l is held vertically stationary with
with velocity 250 ms−1 strikes a block of wood of its lower end located at a point P, on the
mass 0.23 kg which rests on a rough horizontal horizontal plane. When the rod is released to
surface. After the impact, the block and bullet topple about P, the velocity of the upper end of
move together and come to rest after travelling a the rod with which it hits the ground is
distance of 40 m. The coefficient of sliding
g
friction of the rough surface is (g = 9.8 ms–2 ) (a) (b) 3gl
l
(a) 0.75 (b) 0.61
(c) 0.51 (d) 0.30 g 3g
(c) 3 (d)
38. Two persons A and B are located in X-Y plane at l l
the points (0, 0) and (0, 10) respectively. (The 40. A wheel of radius 0.4 m can rotate freely about
distances are measured in MKS unit). At a time its axis as shown in the figure. A string is
t = 0, they start moving simultaneously with wrapped over its rim and a mass of 4 kg is hung.
→ →
velocities v = 2j ms–1
A and v = 2$i ms–1
B
An angular acceleration of 8 rad-s −2 is produced
respectively. The time after which A and B are at in it due to the torque. Then, moment of inertia
their closest distance is of the wheel is (g = 10 ms−2 )
(a) 2.5 s (b) 4 s (a) 2 kg-m 2 (b) 1 kg-m 2
10
(c) 1 s (d) s (c) 4 kg-m 2 (d) 8 kg-m 2
2
CHEMISTRY
41. Given that ∆H f (H) = 218 kJ/ mol, express the 45. The number of pπ - dπ ‘pi’ bonds present in XeO 3
H—H bond energy in kcal/mol. and XeO 4 molecules, respectively are
(a) 52.15 (b) 911 (a) 3, 4 (b) 4, 2
(c) 104 (d) 52153 (c) 2, 3 (d) 3, 2
42. Identify the alkyne in the following sequence of 46. The wavelengths of electron waves in two orbits
reactions, is 3 : 5. The ratio of kinetic energy of electrons
will be
2 H Ozonolysis
Alkyne → A → B (a) 25 : 9 (b) 5 : 3
Lindlar’s catalyst only (c) 9 : 25 (d) 3 : 5
Wacker CH ==CH
← 47. Which one of the following sets correctly
process 2 2
represents the increase in the paramagnetic
(a) H3C —C ≡≡C —CH3 property of the ions?
(b) H3C —CH2—C ≡≡CH (a) Cu 2+ > V 2+ > Cr 2+ > Mn 2+
(c) H2C ==CH—C ≡≡CH (b) Cu 2+ < Cr 2+ < V 2+ < Mn 2+
(d) HC ≡≡C —CH2 —C ≡≡CH (c) Cu 2+ < V 2+ < Cr 2+ < Mn 2+
43. Fluorine reacts with dilute NaOH and forms a
(d) V 2+ < Cu 2+ < Cr 2+ < Mn 2+
gaseous product A. The bond angle in the
molecule of A is 48. Electrons with a kinetic energy of
(a) 104°40′ (b) 103° 6.023 × 104 J/ mol are evolved from the surface
(c) 107° (d) 109°28′ of a metal, when it is exposed to radiation of
wavelength of 600 nm. The minimum amount of
44. One mole of alkene X on ozonolysis gave one
energy required to remove an electron from the
mole of acetaldehyde and one mole of acetone. metal atom is
The IUPAC name of X is
(a) 2.3125 × 10−19 J (b) 3 × 10−19 J
(a) 2-methyl-2-butene (b) 2-methyl-1-butene
(c) 2-butene (d) 1-butene (c) 6.02 × 10−19 J (d) 6.62 × 10−34 J
49. The chemical entities present in thermosphere 58. Assertion (A) K, Rb and Cs form superoxides.
of the atmosphere are Reason (R) The stability of the superoxides
(a) O +2 , O + , NO + (b) O 3 increases from ‘K’ to ‘Cs’ due to decrease in
lattice energy.
(c) N 2, O 2, CO 2, H2O (d) O 3, O +2 , O 2
The correct answer is
50. The type of bonds present in sulphuric (a) Both (A) and (R) are true and (R) is the
anhydride are correct explanation of (A)
(a) 3σ and three pπ - dπ (b) Both (A) and (R) are true but (R) is not the
(b) 3σ, one pπ - pπ and two pπ - dπ correct explanation of (A)
(c) 2σ and three pπ - dπ (c) (A) is true but (R) is not true
(d) 2σ and two pπ - dπ (d) (A) is not true but (R) is true
51. In Gattermann reaction, a diazonium group is 59. How many ‘mL’ of perhydrol is required to
replaced by X using Y. X and Y are produce sufficient oxygen which can be used to
X Y completely convert 2 L of SO 2 gas to SO 3 gas?
(a) Cls Cu/HCl (a) 10 mL (b) 5 mL
(b) Cl ⊕ CuCl 2 / HCl (c) 20 mL (d) 30 mL
(c) Cl s CuCl / HCl 60. pH of a buffer solution decreases by 0.02 units
2
when 0.12 g of acetic acid is added to 250 mL of
(d) Cl 2 Cu 2O / HCl a buffer solution of acetic acid and potassium
52. Which pair of oxyacids of phosphorus contains acetate at 27°C. The buffer capacity of the
‘ P— H’ bonds? solution is
(a) H3PO 4, H3PO 3 (b) H3PO 5, H4P2O7 (a) 0.1 (b) 10 (c) 1 (d) 0.4
(c) H3PO 3, H3PO 2 (d) H3PO 2, HPO 3 61. Match the following.
53. Dipole moment of HCl =1.03 D, HI = 0.38 D. List I List II
Bond length of HCl = 1.3 Å and HI = 1.6 Å. The (A) Feldspar (I) [Ag 3 SbS3 ]
ratio of fraction of electric charge, δ, existing on (B) Asbestos (II) Al 2 O3 ⋅ H 2 O
each atom in HCl and HI is (C) Pyrargyrite (III) MgSO4 ⋅ H 2 O
(a) 12 : 1 (b) 2.7 : 1
(D) Diaspore (IV) KAlSi 3 O8
(c) 3.3 : 1 (d) 1 : 3.3
(V) CaMg 3 (SiO3 )4
54. SiCl 4 on hydrolysis forms ‘ X ’ and HCl.
Compound ‘ X ’ loses water at 1000°C and gives The correct answer is
‘ Y ’ . Compounds ‘ X ’ and ‘ Y ’ respectively are (A) (B) (C) (D)
(a) H2SiCl 6, SiO 2 (b) H4SiO 4, Si (a) IV V II I
(c) SiO 2, Si (d) H4SiO 4, SiO 2 (b) IV V I II
55. 1.5 g of CdCl 2 was found to contain 0.9 g of Cd. (c) IV I III II
Calculate the atomic weight of Cd. (d) II V IV I
(a) 118 (b) 112
62. Which one of the following order is correct for
(c) 106.5 (d) 53.25 the first ionisation energies of the elements?
56. Aluminium reacts with NaOH and forms (a) B< Be< N < O
compound ‘ X ’. If the coordination number of (b) Be< B< N < O
aluminium in ‘ X ’ is 6, the correct formula of X is (c) B< Be< O < N
(a) [Al(H2O)4(OH)2]+ (b) [Al(H2O)3(OH)3] (d) B< O < Be< N
(c) [Al(H2O)2(OH)4]− (d) [Al(H2O)6](OH)3 63. What are X and Y in the following reaction
sequence?
57. The average kinetic energy of one molecule of
an ideal gas at 27°C and 1 atm pressure is Cl Cl
C 2H5OH →
2
X →
2
Y
(a) 900 cal K −1 mol −1
(a) C 2H5Cl, CH3CHO
(b) 6.21 × 10−21 JK −1 molecule−1
(b) CH3CHO, CH3CO 2H
(c) 336.7 JK −1 molecule−1
(c) CH3CHO, CCl 3CHO
(d) 3741.3 JK −1 mol −1 (d) C 2H5Cl, CCl 3CHO
64. What are A, B, C in the following reactions? CH2CH2NH2 CH2—CHCO2H
∆
(I) (CH3CO 2 )2Ca → A NH2
HI
(II) CH3CO 2H → B (c) (d)
Red P
OH OH
P4 O10
(III) 2CH3CO 2H → C OH OH
A B C 69. During the depression in freezing point
(a) C 2H6 CH3COCH3 (CH3CO)2O experiment, an equilibrium is established
(b) (CH3CO)2O C 2H6 CH3COCH3 between the molecules of
(c) CH3COCH3 C 2H6 (CH3CO)2O (a) liquid solvent and solid solvent
(d) CH3COCH3 (CH3CO)2O C 2 H6 (b) liquid solute and solid solvent
65. One per cent composition of an organic (c) liquid solute and solid solute
compound A is, carbon : 85.71% and hydrogen (d) liquid solvent and solid solute
14.29%. Its vapour density is 14. Consider the
70. Consider the following reaction,
following reaction sequence
EtOH /H O
Cl /H O (i) KCN /EtOH C 2H5Cl + AgCN →
2
X (major)
A →
2 2
B → C
+ (ii) H 3 O Which one of the following statements is true for
X?
Identify C,
(I) It gives propionic acid on hydrolysis
(a) CH3—CH —CO 2H (II) It has an ester functional group
 (III) It has a nitrogen linked to ethyl carbon
OH
(IV) It has a cyanide group
(b) HO —CH2—CH2—CO 2H (a) IV (b) III
(c) HO —CH2—CO 2H (c) II (d) I
(d) CH3—CH2 —CO 2H 71. For the following cell reaction,
66. How many tripeptides can be prepared by Ag| Ag+ | AgCl|Cls |Cl 2, Pt
linking the amino acids glycine, alanine and
phenyl alanine? ∆G °f (AgCl) = − 109 kJ/ mol
(a) One (b) Three ∆G ° (Cls ) = − 129 kJ/ mol
f
(c) Six (d) Twelve
67. A codon has a sequence of A, and specifies a ∆G °f (Ag+ )=78 kJ/ mol
particular B that is to be incorporated into a C. E ° of the cell is
What are A, B, C? (a) –0.60 V (b) 0.60 V
A B C (c) 6.0 V (d) None of these
(a) 3 bases amino acid carbohydrate 72. The synthesis of crotonaldehyde from
(b) 3 acids carbohydrate protein acetaldehyde is an example of …… reaction.
(c) 3 bases protein amino acid (a) nucleophilic addition
(d) 3 bases amino acid protein (b) elimination
(c) electrophilic addition
68. Parkinson’s disease is linked to abnormalities in (d) nucleophilic addition-elimination
the levels of dopamine in the body. The
73. At 25°C, the molar conductances at infinite
structure of dopamine is
dilution for the strong electrolytes NaOH, NaCl
CH2NH2 CH2CH2CH2NH2 and BaCl 2 are 248 × 10−4, 126 × 10−4 and
280 × 10−4 Sm2 mol −1 respectively, λ°m Ba(OH)2
(a) (b) in Sm2 mol −1 is
OH OH (a) 52.4 × 10−4 (b) 524 × 10−4
−4
(c) 402 × 10 (d) 262 × 10−4
OH OH
74. The cubic unit cell of a metal (molar mass 78. 20 mL of 0.1 M acetic acid is mixed with 50 mL
= 63.55 g mol −1) has an edge length of 362 pm. of potassium acetate. K a of acetic acid
Its density is 8.92 g cm–3. The type of unit cell is = 1.8 × 10−5 at 27°C. Calculate concentration of
potassium acetate if pH of the mixture is 4.8.
(a) primitive (b) face centred
(a) 0.1 M (b) 0.04 M
(c) body centred (d) end centred
(c) 0.4 M (d) 0.02 M
75. The equilibrium constant for the given reaction
79. Calculate ∆H ° for the reaction,
is 100.
Na 2O(s ) + SO 3(g ) → Na 2SO 4(g ) given the
N 2(g ) + 2O 2(g )º 2NO 2(g ) following :
What is the equilibrium constant for the reaction 1
(A) Na(s ) + H2O(l) → NaOH(s ) + H2(g )
given below? 2
1 ∆H ° = − 146 kJ
NO 2(g ) º N 2(g ) + O 2(g )
2 (B) Na 2SO 4(s ) + H2O(l) → 2NaOH(s )
(a) 10 (b) 1 (c) 0.1 (d) 0.01 + SO 3(g )
76. For a first order reaction at 27°C, the ratio of ∆H ° = + 418 kJ
time required for 75% completion to 25% (C) 2Na 2O(s ) + 2H2(g ) → 4Na(s ) + 2H2O(l)
completion of reaction is ∆H ° = + 259 kJ
(a) 3.0 (b) 2.303 (c) 4.8 (d) 0.477 (a) +823 kJ
77. The concentration of an organic compound in (b) –581 kJ
chloroform is 6.15 g per 100 mL of solution. A (c) –435 kJ
portion of this solution in a 5 cm polarimeter (d) +531 kJ
tube causes an observed rotation of –1.2°. What 80. Which one of the following is most effective in
is the specific rotation of the compound? causing the coagulation of an As2S3 sol?
(a) +12° (b) –3.9° (a) KCl (b) AlCl 3
(c) –39° (d) +61.5° (c) MgSO 4 (d) K 3Fe(CN)6
MATHEMATICS
81. If f :[ 2, 3] → R is defined by 84. The number of subsets of {1, 2, 3, . . . , 9}
f ( x ) = x 3 + 3x − 2, then the range f ( x ) is containing at least one odd number is
contained in the interval (a) 324 (b) 396
(a) [1, 12] (b) [12, 34] (c) 496 (d) 512
(c) [ 35, 50] (d) [ −12, 12] 85. p points are chosen on each of the three coplanar
 2x − 1  lines. The maximum number of triangles formed
82.  x ∈ R : 3 2
∈ R  equals with vertices at these points is
 x + 4 x + 3 x  1
(a) p3 + 3p2 (b) ( p3 + p)
(a) R − {0} 2
(b) R − {0, 1, 3} p2
(c) (5p − 3) (d) p2(4 p − 3)
(c) R − {0, − 1, − 3} 2
 1 86. A binary sequence is an array of 0’s and 1’s. The
(d) R − 0, − 1, − 3, +  number of n-digit binary sequences which
 2
contain even number of 0’s is
83. Using mathematical induction, the numbers an’s (a) 2n − 1 (b) 2n − 1
are defined by,
(c) 2n − 1 − 1 (d) 2n
a0 = 1, an + 1 = 3n2 + n + an, (n ≥ 0).
87. The coefficient of x 24 in the expansion of
Then, an is equal to (1 + x 2 )12(1 + x12 )(1 + x 24 ) is
(a) n3 + n2 + 1 (b) n3 − n2 + 1 (a) 12C 6 (b) 12C 6 + 2
(c) n3 − n2 (d) n3 + n2 (c) 12C 6 + 4 (d) 12C 6 + 6
88. If x is numerically so small so that x 2 and higher 95. Let A and B be two symmetric matrices of same
powers of x can be neglected, then order. Then, the matrix AB − BA is
 2 x
3/ 2 (a) a symmetric matrix
1 +  ⋅ (32 + 5x )−1/ 5 is approximately (b) a skew-symmetric matrix
 3
(c) a null matrix
equal to (d) the identity matrix
32 + 31 x 31 + 32x
(a) (b) 3 5 x
64 64 96. If one of the roots of  7 x 7  = 0 is –10,
31 − 32x 1 − 2x  
(c) (d)  x 5 3
64 64
then the other roots are
89. For| x | < 1, the constant term in the expansion
1 (a) 3, 7 (b) 4, 7
of is (c) 3, 9 (d) 3, 4
( x − 1)2( x − 2)
97. If x, y, z are all positive and are the pth, qth and
(a) 2 (b) 1 rth terms of a geometric progression
1 respectively, then the value of the determinant
(c) 0 (d) −
2  log x p 1 
1  log y q 1 equals
90. (ex + e5x ) = a0 + a1 x + a2 x 2 + K  
e3x
 log z r 1 
⇒ 2a1 + 23 a3 + 25 a5 + . . . is equal to
(a) log xyz (b) ( p − 1)(q − 1)(r − 1)
(a) e (b) e−1 (c) pqr (d) 0
(c) 1 (d) 0  1 −1 x 
91. The roots of 98. If 1 x 1  has no inverse, then the real
( x − a)( x − a − 1) + ( x − a − 1)( x − a − 2)  
 x −1 1 
+ ( x − a)( x − a − 2) = 0, a ∈ R are always
value of x is
(a) equal (a) 2 (b) 3
(b) imaginary (c) 0 (d) 1
(c) real and distinct 99. If α and β are the roots of x 2 − 2x + 4 = 0, then
(d) rational and equal the value of α 6 + β 6 is
92. Let f ( x ) = x 2 + ax + b, where a, b ∈ R . If (a) 32 (b) 64
f ( x ) = 0 has all its roots imaginary, then the (c) 128 (d) 256
roots of f ( x ) + f ′ ( x ) + f ′ ′ ( x ) = 0 are 100. The locus of z satisfying the inequality
(a) real and distinct
 z + 2i 
  < 1, where z = x + iy, is
(b) imaginary
 2z + i 
(c) equal
(d) rational and equal (a) x 2 + y 2 < 1 (b) x 2 − y 2 < 1
93. If α , β, γ are the roots of x 3 + 4 x + 1 = 0, then (c) x 2 + y 2 > 1 (d) 2 x 2 + 3y 2 < 1
α2 β2 101. If n is an integer which leaves remainder one
the equation whose roots are , ,
β+γ γ+α when divided by three, then
γ2 (1 + 3 i )n + (1 − 3 i )n equals
is
α+β (a) −2n + 1 (b) 2n + 1
(a) x 3 − 4 x − 1 = 0 (b) x 3 − 4 x + 1 = 0 (c) − (−2)n (d) − 2n
(c) x 3 + 4 x − 1 = 0 (d) x 3 + 4 x + 1 = 0 102. The period of sin 4 x + cos4 x is
94. If f ( x ) = 2 x 4 − 13x 2 + ax + b is divisible by π4 π2
(a) (b)
x 2 − 3x + 2, then (a, b) is equal to 2 2
π π
(a) (−9, − 2) (b) (6, 4) (c) (d)
4 2
(c) (9, 2) (d) (2, 9)
cos x 110. P is a point on the segment joining the feet of
103. = λ ⇒ tan ( x − y ) tan y is equal to
cos ( x − 2y ) two vertical poles of heights a and b. The angles
1+ λ 1−λ of elevation of the tops of the poles from P are
(a) (b) 45° each. Then, the square of the distance
1−λ 1+ λ between the tops of the poles is
λ λ a2 + b2
(c) (d) (a) (b) a2 + b2
1+ λ 1−λ 2
104. cos A cos 2 A cos 4 A K cos 2n − 1 A equals (c) 2(a2 + b2 ) (d) 4 (a2 + b2 )
sin 2n A 2n sin 2n A 111. In a quadrilateral ABCD, the point P divides DC
(a) (b) in the ratio 1 : 2 and Q is the mid point of AC. If
2n sin A sin A
→ → → → →
2n sin A sin A AB + 2 AD + BC − 2 DC = k PQ, then k is equal
(c) (d) n
sin 2n A 2 sin 2n A to
(a) –6 (b) – 4
105. If 3 cos x ≠ 2 sin x, then the general solution of
(c) 6 (d) 4
sin 2 x − cos 2 x = 2 − sin 2 x is
112. The angle between the lines whose direction
π
(a) nπ + (−1)n , n ∈ Z cosines satisfy the equations l + m + n = 0,
2 l2 + m2 − n2 = 0 is
nπ
(b) , n ∈Z π π
2 (a) (b)
π 6 4
(c) (4n ± 1) , n ∈ Z π π
2 (c) (d)
3 2
(d) (2 n − 1) π , n ∈ Z → →
 −1   1  −1  113. If a = − $i + $j + 2k$ , b = 2$i − $j − k$ and
106. cos−1   − 2 sin −1   + 3 cos−1  
 2  2  2 →
c = − 2$i + $j + 3k$ , then the angle between
−1
− 4 tan (−1) equals → → → →
2 a − c and a + b is
19π 35π
(a) (b) π π
12 12 (a) (b)
47 π 43π 4 3
(c) (d) π 3π
12 12 (c) (d)
2 2
107. sinh −1 2 + sinh −1 3 = x ⇒ cosh x is equal to 114. If m1, m2, m3 and m4 are respectively the
1 1 magnitudes of the vectors
(a) (3 5 + 2 10 ) (b) (3 5 − 2 10 ) → →
2 2 a1 = 2$i − $j + k$ , a = 3$i − 4$j − 4k$ ,
2
1 1 → →
(c) (12 + 2 50 ) (d) (12 − 2 50 ) a 3 = $i + $j − k$ and a 4 = − i$ + 3$j + k$ ,
2 2
then the correct order of m1, m2, m3 and m4 is
108. In any ∆ ABC, a (b cos C − c cos B ) equals
(a) b2 + c2 (b) b2 − c2 (a) m3 < m1 < m4 < m2
1 1 1 1 (b) m3 < m1 < m2 < m4
(c) + (d) 2 − 2
b c b c (c) m3 < m4 < m1 < m2
109. In a ∆ ABC (d) m3 < m4 < m2 < m1
(a + b + c)(b + c − a)(c + a − b)(a + b − c) → →
115. Suppose a = λ$i − 7 $j + 3k$ , b = λi$ + $j + 2λk$ . If
4b2c2 → →
equals the angle between a and b is greater than 90°,
(a) cos2 A (b) cos2 B then λ satisfies the inequality
(c) sin 2 A (d) sin 2 B (a) −7 < λ < 1 (b) λ > 1
(c) 1 < λ < 7 (d) −5 < λ < 1
116. The volume of the tetrahedron having the edges 121. If X is a binomial variate with the range
i$ + 2$j − k$ , $i + $j + k$ , i$ − $j + λk$ as coterminous, {0, 1, 2, 3, 4, 5, 6} and P ( X = 2) = 4P ( X = 4),
2 then the parameter p of X is
is cubic unit. Then λ equals 1 1 2 3
3 (a) (b) (c) (d)
(a) 1 (b) 2 3 2 3 4
(c) 3 (d) 4 122. The transformed equation of x 2 + y 2 = r2 when
117. If A and B are events of a random experiment the axes are rotated through an angle 36° is
4 7 (a) 5X 2 − 4 XY + Y 2 = r2
such that P ( A ∪ B ) = , P ( A ∪ B ) = and
5 10 (b) X 2 + 2XY − 5Y 2 = r2
2
P (B ) = , then P ( A ) equals (c) X 2 − Y 2 = r2
5
9 8 7 3 (d) X 2 + Y 2 = r2
(a) (b) (c) (d)
10 10 10 5 123. The area (in square unit) of the circle which
118. The probability of choosing randomly a number touches the lines 4 x + 3y = 15 and 4 x + 3y = 5
c from the set {1, 2, 3, . . . , 9} such that the is
quadratic equation x 2 + 4 x + c = 0 has real (a) 4π (b) 3π
(c) 2 π (d) π
roots is
1 2 124. The point on the line 3x + 4 y = 5 which is
(a) (b) equidistant from (1, 2) and (3, 4) is
9 9
3 4 (a) (7, − 4) (b) (15, − 10)
(c) (d) (c) (1 / 7, 8 / 7 ) (d) (0, 5/ 4)
9 9
119. Suppose that E1 and E 2 are two events of 125. The equation of the straight line perpendicular
1 to the straight line 3x + 2 y = 0 and passing
a random experiment such that P (E1 ) = , through the point of intersection of the lines
4
1 1 x + 3y − 1 = 0 and x − 2y + 4 = 0 is
P (E 2/ E1 ) = and P (E1 / E 2 ) = , observe the (a) 2 x − 3y + 1 = 0 (b) 2 x − 3y + 3 = 0
2 4
lists given below (c) 2 x − 3y + 5 = 0 (d) 2 x − 3y + 7 = 0
List I List II 126. The value of λ with | λ | < 16 such that
(A) P (E 2 ) (i) 1/4 2x 2 − 10 xy + 12y 2 + 5x + λy − 3 = 0 represents
(B) P (E1 ∪ E 2 ) (ii) 5/8 a pair of straight lines, is
(C) P (E1 / E 2 ) (iii) 1/8 (a) –10 (b) –9
(c) 10 (d) 9
(D) P (E1 / E 2 ) (iv) 1/2
127. The area (in square unit) of the triangle formed
(v) 3/8
by x + y + 1 = 0 and the pair of straight lines
(vi) 3/4
x 2 − 3xy + 2y 2 = 0 is
The correct matching of the List I from the List II is 7 5 1 1
(A) (B) (C) (D) (a) (b) (c) (d)
12 12 12 6
(a) (ii) (iii) (vi) (i)
(b) (iv) (v) (vi) (i) 128. The pairs of straight lines x 2 − 3xy + 2 y 2 = 0
(c) (iv) (ii) (vi) (i) and x 2 − 3xy + 2y 2 + x − 2 = 0 form a
(d) (i) (ii) (iii) (iv) (a) square but not rhombus
120. If m and σ 2 are the mean and variance of the (b) rhombus
random variable X, whose distribution is given (c) parallelogram
by (d) rectangle but not a square
129. The equations of the circle which pass through
X = x 0 1 2 3
the origin and makes intercepts of lengths 4 and
P( X = x ) 1 1 0 1
8 on the x and y-axes respectively are
3 2 6
(a) x 2 + y 2 ± 4 x ± 8 y = 0
Then (b) x 2 + y 2 ± 2x ± 4 y = 0
(a) m = σ 2 = 2 (b) m = 1, σ 2 = 2 (c) x 2 + y 2 ± 8 x ± 16 y = 0
(c) m = σ 2 = 1 (d) m = 2, σ 2 = 1 (d) x 2 + y 2 ± x ± y = 0
130. The locus of centre of a circle which passes 136. If the circle x 2 + y 2 = a2 intersects the
through the origin and cuts off a length of 4 unit hyperbola xy = c2 in four points ( x i, y i ), for
from the line x = 3 is i = 1, 2, 3 and 4, then y1 + y 2 + y 3 + y 4 equals
(a) y 2 + 6 x = 0 (a) 0 (b) c
(b) y 2 + 6 x = 13 (c) a (d) c4
137. The mid point of the chord 4 x − 3y = 5 of the
(c) y 2 + 6 x = 10 hyperbola 2x 2 − 3y 2 = 12 is
(d) x 2 + 6 y = 13  5
(a)  0, −  (b) (2, 1)
131. The diameters of a circle are along  3
2x + y − 7 = 0 and x + 3y − 11 = 0. Then, the 5   11 
(c)  , 0 (d)  , 2
equation of this circle, which also passes 4   4 
through (5, 7 ), is 138. The eccentricity of the conic
(a) x 2 + y 2 − 4 x − 6 y − 16 = 0 5
= 2 + 3 cos θ + 4 sin θ is
(b) x 2 + y 2 − 4 x − 6 y − 20 = 0 r
1 3 5
(c) x 2 + y 2 − 4 x − 6 y − 12 = 0 (a) (b) 1 (c) (d)
2 2 2
(d) x 2 + y 2 + 4 x + 6 y − 12 = 0
139. The perimeter of the triangle with vertices at
132. The point (3, − 4) lies on both the circles (1, 0, 0), (0, 1, 0) and (0, 0, 1) is
x 2 + y 2 − 2x + 8 y + 13 = 0 and (a) 3 (b) 2
2 2
x + y − 4 x + 6 y + 11 = 0. Then, the angle (c) 2 2 (d) 3 2
between the circles is 140. If a line in the space makes angle α, β and γ with
 1 the coordinate axes, then
(a) 60° (b) tan −1   cos 2α + cos 2β + cos 2γ + sin 2 α + sin 2 β
 2
 3 + sin 2 γ equals
(c) tan −1   (d) 135°
 5 (a) –1 (b) 0 (c) 1 (d) 2
133. The equation of the circle which passes through 141. The image of the point (3, 2, 1) in the plane
the origin and cuts orthogonally each of the 2x − y + 3z = 7 is
circles x2 + y2 − 6x + 8 = 0 and (a) (1, 2, 3) (b) (2, 3, 1)
2 2
x + y − 2x − 2y = 7 is (c) (3, 2, 1) (d) (2, 1, 3)
142. The radius of the sphere
(a) 3x 2 + 3y 2 − 8 x − 13y = 0
x 2 + y 2 + z 2 = 12x + 4 y + 3z is
(b) 3x 2 + 3y 2 − 8 x + 29 y = 0 13
(a) (b) 13
(c) 3x 2 + 3y 2 + 8 x + 29 y = 0 2
(c) 26 (d) 52
(d) 3x 2 + 3y 2 − 8 x − 29 y = 0 x+ 3
 x + 5
134. The number of normals drawn to the parabola 143. lim   equals
x → ∞  x + 2
y 2 = 4 x from the point (1, 0) is
(a) 0 (b) 1 (a) e (b) e2
(c) 2 (d) 3 (c) e3 (d) e5
135. If the distance between the foci of an ellipse is 6 144. If f : R → R is defined by
and the length of the minor axis is 8, then the  2 sin x − sin 2x
 , if x ≠ 0
eccentricity is f (x) =  2x cos x ,
1 1  a, if x = 0
(a) (b) 
5 2
then the value of a so that f is continuous at 0 is
3 4
(c) (d) (a) 2 (b) 1
5 5
(c) –1 (d) 0
1− y dy  2 − sin 2x 
∫  1 − cos 2x  e dx is equal to
x
145. x = ⇒ is equal to 154.
1+ y dx
4 4( x − 1) (a) − ex cot x + c (b) ex cot x + c
(a) (b)
( x + 1)2 (1 + x )3 (c) 2 ex cot x + c (d) −2 ex cot x + c
x −1 4
(c) (d) 155. If I n = ∫ sin n x dx, then nI n − (n − 1)I n − 2 equals
(1 + x )3 ( x + 1)3
(a) sin n − 1 x cos x
 1   t 
146. x = cos−1  , y = sin −1   ⇒ dy (b) cosn − 1 x sin x
 1 + t2  1 + t2 dx
    (c) − sin n − 1 x cos x
is equal to (d) − cosn − 1 x sin x
(a) 0 (b) tan t
π 1
(c) 1 (d) sin t cos t 156. ∫01 + sin x
dx is equal to
d   x − 1  1
147.  a tan −1 x + b log   = 4 (a) 1 (b) 2
dx   x + 1  x − 1
(c) –1 (d) –2
⇒ a − 2b is equal to π
(a) 1 (b) –1 157. The line x = divides the area of the region
4
(c) 0 (d) 2
−1
bounded by y = sin x, y = cos x and x-axis
148. y = ea sin x
⇒ (1 − x 2 ) y n + 2 − (2n + 1) xy n + 1 is  π
 0 ≤ x ≤  into two regions of areas A1 and A2.
equal to  2
(a) − (n2 + a2 ) y n (b) (n2 − a2 ) y n Then A1, A2 equals
(c) (n2 + a2 ) y n (d) − (n2 − a2 ) y n (a) 4 : 1 (b) 3 : 1
(c) 2 : 1 (d) 1 : 1
149. There is an error of ± 0.04 cm in the
measurement of the diameter of a sphere. When 158. The velocity of a particle which starts from rest is
the radius is 10 cm, the percentage error in the given by the following table.
volume of the sphere is
t (in second) 0 2 4 6 8 10
(a) ± 1.2 (b) ± 1.0
(c) ± 0.8 (d) ± 0.6 v (in m/s) 0 12 16 20 35 60
150. The function f ( x ) = x 3 + ax 2 + bx + c, a2 ≤ 3b
The total distance travelled (in metre) by the
has particles in 10 s, using Trapezoidal rule is given
(a) one maximum value by
(b) one minimum value (a) 113 (b) 226
(c) no extreme value (c) 143 (d) 246
(d) one maximum and one minimum value
159. The solution of the differential equation
log x
151. The maximum value of , 0 < x < ∞ is dy
= sin ( x + y ) tan ( x + y ) − 1 is
x dx
(a) ∞ (b) e (c) 1 (d) e−1
(a) cosec ( x + y ) + tan ( x + y ) = x + c
152. z = tan ( y + ax ) + y − ax ⇒ zxx − a2z yy is
(b) x + cosec ( x + y ) = c
equal to
(c) x + tan ( x + y ) = c
(a) 0 (b) 2
(c) zx + z y (d) zx z y (d) x + sec ( x + y ) = c
dx 160. The differential equation of the family
153. ∫ is equal to
( x + 1) 4 x + 3 y = aex + bx ex + cx 2ex of curves, where a, b, c
are arbitrary constants, is
(a) tan −1 4x + 3 + c (a) y′′′ + 3y′′ + 3y′ + y = 0
(b) 3 tan −1 4x + 3 + c (b) y′′′ + 3y′′ − 3y′ − y = 0
−1
(c) 2 tan 4x + 3 + c (c) y′′′ − 3y′′ − 3y′ + y = 0
(d) 4 tan −1 4x + 3 + c (d) y′′′ − 3y′′ + 3y′ − y = 0
Answers
❐ PHYSICS
1. (c) 2. (a) 3. (b) 4. (a) 5. (a) 6. (a) 7. (c) 8. (a) 9. (a) 10. (b)
11. (a) 12. (c) 13. (c) 14. (d) 15. (c) 16. (c) 17. (b) 18. (c) 19. (a) 20. (d)
21. (b) 22. (c) 23. (c) 24. (c) 25. (b) 26. (c) 27. (d) 28. (c) 29. (a) 30. (b)
31. (a) 32. (d) 33. (b) 34. (b) 35. (c) 36. (c) 37. (c) 38. (b) 39. (b) 40. (b)
❐ CHEMISTRY
41. (c) 42. (a) 43. (b) 44. (a) 45. (a) 46. (a) 47. (c) 48. (a) 49. (a) 50. (b)
51. (a) 52. (c) 53. (c) 54. (d) 55. (c) 56. (c) 57. (b) 58. (c) 59. (a) 60. (d)
61. (b) 62. (c) 63. (c) 64. (c) 65. (b) 66. (c) 67. (d) 68. (c) 69. (a) 70. (b)
71. (a) 72. (d) 73. (b) 74. (b) 75. (c) 76. (c) 77. (c) 78. (b) 79. (b) 80. (b)
❐ MATHEMATICS
81. (b) 82. (c) 83. (b) 84. (c) 85. (d) 86. (a) 87. (b) 88. (a) 89. (d) 90. (d)
91. (c) 92. (b) 93. (c) 94. (c) 95. (b) 96. (a) 97. (d) 98. (d) 99. (c) 100. (c)
101. (c) 102. (d) 103. (b) 104. (a) 105. (c) 106. (d) 107. (c) 108. (b) 109. (c) 110. (c)
111. (a) 112. (c) 113. (b) 114. (a) 115. (a) 116. (a) 117. (c) 118. (d) 119. (c) 120. (c)
121. (a) 122. (d) 123. (d) 124. (b) 125. (d) 126. (b) 127. (c) 128. (c) 129. (a) 130. (b)
131. (c) 132. (d) 133. (b) 134. (b) 135. (c) 136. (a) 137. (b) 138. (d) 139. (d) 140. (c)
141. (c) 142. (a) 143. (c) 144. (d) 145. (b) 146. (c) 147. (b) 148. (c) 149. (d) 150. (c)
151. (d) 152. (a) 153. (c) 154. (a) 155. (c) 156. (b) 157. (d) 158. (b) 159. (b) 160. (d)
Solutions
PHYSICS
1. Given, y = a sin (bt − cx ) 3. Momentum, p = m⋅ v
Comparing the given equation with general
y v
wave equation
vy
 2πt 2πx 
y = a sin  − 
 T λ  P vx
2π 2π (x, y)
we get b= ,c= θ
T λ O x
y metre [L]
(a) Dimensions of = =
a metre [L]  p
⇒ v= 
 m
= Dimensionless
2π [T] 1
(b) Dimensions of bt = ⋅t = Kinetic energy, KE = mv 2
T [T] 2
1  p2  1 2
= Dimensionless = m  2 = p
2π [L] 2  m  2m
(c) Dimensions of cx = ⋅x =
λ [L] 1
⇒ KE ∝ p2 (Q = constant)
= Dimensionless 2m
b 2π 2π Hence, the graph between KE and p2 will be
(d) Dimensions of = linear as shown below
c T λ
= λ / T = [LT −1] y
Thus, option (d) has dimensions.

2. Let time taken by the body to fall KE
C
from point C to B is t′.
Then t 1 + 2t ′ = t 2 x
t′
t − t  p2
t ′ =  2 1  …(i)
 2  B Hmax
1
Total time taken to reach point C Now, kinetic energy KE = mv 2
t1 H 2
T = t1 + t ′ The velocity component at point P,
t −t A v y = (u sin θ − gt )
= t1 + 2 1
2 and vx = u cos θ
2t 1 + t 2 − t 1 Resultant velocity at point P,
= →
2 v = v $j + v i$
y x
 t1 + t 2 
=  = (u sin θ − gt ) $j + u cos θ i$
 2 
→
Maximum height attained | v | = (u cos θ )2 + (u sin θ − gt )2
1
H max = g (T )2 = u 2 cos2 θ + u 2 sin 2 θ + g 2t 2 − 2ugt sin θ
2
2
1  t1 + t 2  ∴ = u 2(cos2 θ + sin 2 θ ) + g 2t 2 − 2ugt sin θ
= g 
2  2  1
2
KE = m (u 2 + g 2t 2 − 2ugt sin θ )
1 (t + t 2 ) 2
= g⋅ 1
2 4 ⇒ KE ∝ t 2
1 Hence, graph will be parabolic with intercept on
⇒ H max = g ⋅ (t 1 + t 2 )2 m
8 y-axis.
Hence, the graph between KE and t If rate of flow of water is increased by n times, ie,
(nx ).
mgy′
Increased power P1 =
t
 y′ 
KE = mg   = mgn ⋅ x
t 
= nmgx …(ii)
t
The ratio of power
Now, in case of height P1 nmgx
=
1 P0 mgx
KE = m(v 2 )
2 P1 n
= ⇒ P1 : P0 = n : 1
and v 2 = (u 2 − 2gy ) P0 1
1 5. Mass of the first body m1 = 5 kg, for elastic
∴ KE = m(u 2 − 2gy )
2 collision e = 1.
1 u1 = u
KE = − mgy + mu 2 m1 M
2
u2 = 0
1 2
Intercept on y-axis = mu Suppose initially body m1 moves with velocity v
2
u
after collision velocity becomes   .
 10
B
1 Let after collision velocity of M block becomes
mu2 –mg = tan θ
2 (v2 ).
By conservation of momentum
O A
m1u1 + m2u2 = m1v1 + m2v2
u
1 or 5u + M × 0 = 5 × + Mv2
Now, KE = mv 2 10
2 u
1  x
2 or 5u = + Mv2 …(i)
KE = m   2
2 t Since, v1 − v2 = − e(u1 − u2 )
u
− v2 = − 1(u)
10
u
or + u = v2
KE 10
11u
= v2 …(ii)
x
10
Substituting value of v2 in Eq. (i) from Eq. (ii),
2
KE ∝ x . Thus graph between KE and x will be we get
parabolic. u  11u
5u = + M  
4. Power of motor initially = P0 2  10 
Let, rate of flow of motor = ( x ) 1  11
work mgy or 5− =M  
Since, power, P0 = = 2  10
time t 9 × 10
 y or M =
= mg   , 2 × 11
t
45
y or M =
= x = rate of flow of water 11
t
= 4.09 kg
= mgx …(i)
Y 8. The displacement of particle, executing SHM
u=?  π
y = 5 sin  4 t +  …(i)
–1  3
6. 6 ms 2m1
Velocity of particle
m
 dy  5d  π
θ   = sin  4 t + 
4m
X  dt  dt  3
m → 4ms–1
 π
Let third mass particle (2 m) moves making angle = 5 cos  4 t +  ⋅ 4
 3
θ with X-axis.
 π
The horizontal component of velocity of 2 m = 20 cos  4 t + 
 3
mass particle = u cos θ and vertical component
= u sin θ T 
Velocity at t =  
From conservation of linear momentum in  4
X-direction  dy   T π
  = 20 cos  4 × + 
m1u1 + m2u2 = m1v1 + m2v2  dt  t = T  4 3
4
or 0 = m × 4 + 2m(u cos θ )
 π
or −4 = 2u cos θ or u = 20 cos T +  …(ii)
 3
or −2 = u cos θ …(i)
Comparing the given equation with standard
Again, applying law of conservation of linear
equation of SHM, given by
momentum in Y-direction.
y = a sin (ωt + φ )
0 = m × 6 + 2m(u sin θ )
6 We get ω=4
⇒ − = u sin θ 2π
2 As ω=
T
or −3 = u sin θ …(ii)
2π
Squaring Eqs. (i) and(ii) and adding, we get ⇒ T =
ω
(4) + (9) = u 2 cos2 θ + u 2 sin 2 θ 2π
or T =
= u 2 (cos2 θ + sin 2 θ ) 4
or 13 = u 2  π
or T = 
 2
or u = 13 ms−1
7. Maximum height attained by a projectile Now, putting value of T in Eq. (ii), we get
 π π
v 2R u = 20 cos  + 
h= …(i)  2 3
2gR − v 2
π
Velocity of body = half the escape velocity = − 20 sin
3
v
v= e 3
2 = − 20 ×
2
or
2gR 2gR = − 10 × 3
v= ⇒ v2 = The kinetic energy of particle,
2 4
1
2  gR  KE = mu 2
or v =  2
 2
Q m = 2 g = 2 × 10−3 kg
Now, putting value of v 2 in Eq. (i), we get
1
gR = × 2 × 10−3 × (−10 3)2
⋅R 2
2 gR 2 / 2
h= = = 10−3 × 100 × 3
gR 3gR / 2
2gR −
2 = 3 × 10−1
R KE = 0.3 J
or h=
3
9. Free body diagram of the two blocks are Energy spent
W =T × ∆ A
T′ T = T ⋅ 24πr2
Brass Steel
or W = 24πTr2 J
11. Let now radius of big drop is R.
2g 4 4
Then, πR 3 = × πr 3 ⋅ 8
T 3 3
2g
R = 2r
l1 r Y
Given, = a, 1 = b, 1 = c where r is radius of small drops. Now, terminal
l2 r2 Y2 velocity of drop in liquid.
Let Young’s modulus of steel is Y1 and of brass is 2 r2
ve = × (ρ − σ ) g
Y2. 9 η
F ⋅l
∴ Y1 = 1 1 …(i) where η is coefficient of viscosity and ρ is density
A1 ⋅ ∆l1 of drop σ is density of liquid.
F ⋅l Terminal speed drop is 6 cm s–1
and Y2 = 2 2 …(ii)
A2∆l2 2 r2
∴ 6= × (ρ − σ ) g …(i)
Dividing Eq. (i) by Eq. (ii), we get 9 η
F1 ⋅ l1
Let terminal velocity becomes v′ after coalesce,
Y1 A1 ⋅ ∆l1 then
=
Y2 F2 ⋅ l2 2 R2
A2 ⋅ ∆l2 v′ = (ρ − σ ) g …(ii)
9 η
Y1 F1 ⋅ A2 ⋅ l1 ⋅ ∆l2
or = …(iii) Dividing Eq. (i) by Eq. (ii), we get
Y2 F2 ⋅ A1 ⋅ l2 ⋅ ∆l1 2 r2
(ρ − σ ) g
Force on steel wire from free body diagram 6 9 η
=
T = F1 = (2g ) newton v′ 2 R 2
Force on brass wire from free body diagram (ρ − σ ) g
9 η
F2 = T ′ = T + 2g = (4g ) newton
6 r2
Now, putting the value of F1, F2, in Eq. (iii), we or =
v′ (2 r)2
get
Y1  2g   πr22   l1   ∆l2  or v′ = 24 cm s–1
=  ⋅ ⋅ ⋅ 
Y2  4g   πr12   l2   ∆l1  12. Time period of oscillation,
 ∆l  l
1  1 T = 2π
or c =  2 ⋅ a  2 g
2 b   ∆l1 
∆l1  a  dT 1 dl
or = ⇒ =
 T 2 l
∆l2  2b2c
dl
10. Initially area of soap bubble As, = αdt
l
A1 = 4πr2 dT 1
⇒ = αdt
Under isothermal condition radius becomes 2 r, T 2
Then, area A2 = 4π(2r)2 1
= × 9 × 10−7 × (30 − 20)
= 4π ⋅ 4r2 2
= 4.5 × 10−6
= 16πr2
∴ Loss in time = 4.5 × 10−6 × 0.5
Increase in surface area
∆A = 2( A2 − A1 ) = 2.25 × 10−6 s
= 2(16πr2 − 4πr2 ) = 24πr2
13. The volume of the metal at 30°C is ∆U 3 = Q 3 − W3 = − 3000 + 1200 = − 1800 J
loss of weight ∆U 4 = Q 4 − W4 = 3500 − x
V30 =
specific gravity × g For cyclic process ∆U = 0
(45 − 25) g
= = 13.33 cm3 ∴ 3500 − 4500 − 1800 + 3500 − x = 0
1.5 × g
or x = 700 J
Similarly, volume of metal at 40°C is output
(45 − 27 )g Efficiency, η = × 100
V40 = = 14.40 cm3 input
1.25 × g
W1 + W2 + W3 + W4
Now, V40 = V30[1 + γ(t 2 − t 1 )] = × 100
Q1 + Q 4
V − V30
or γ = 40 (2500 − 1000 − 1200 + 700)
V30(t 2 − t 1 ) = × 100
6000 + 3500
14.40 − 13.33
= 1000
13.33 (40 − 30) = × 100
9500
= 8.03 × 10−3/ ° C
η = 10.5%
∴ Coefficient of linear expansion of the metal is
16. From first law of thermodynamics
γ 8.03 × 10−3
α= = Q = ∆U + W
3 3
For cylinder A pressure remains constant
≈ 2.6 × 10−3/ ° C
∴ Work done by a system
14. A → B → C → D → A is clockwise process. µR
During A → B, pressure is constant and B → C , W = (T1 − T2 )
1 γ −1
process follows p ∝ , it means T is constant.
V For monoatomic gases
During process C → D, both p and V changes and µ =1
1 5
process D → A follows p ∝ which means T is γ=
V 3
constant. 1×R
∴ W = (442 − 400)
5
A B −1
3
p 3
= R × 42
C
2
or W = 63 R
D But ∆U = 0, for cylinder A
V ∴ Q = 0 + 63R
Hence, from above data it is clear that Q = 63R
equivalent cyclic process is For cylinder B volume is constant,
∴ W =0
A B
and Q = µC V ∆T
For monoatomic gas
p
3
CV = R
D
C 2
3
T Q = 1 × R∆T
2
15. From first law of thermodynamics
As heat given to both cylinder is same
Q = ∆U + W 3
or ∆U = Q − W ∴ 63R = R ∆T
2
∴ ∆U 1 = Q1 − W1 = 6000 − 2500 = 3500 J ∆T = 42 K
∆U 2 = Q 2 − W2 = − 5500 + 1000 = − 4500 J
17. According to the figure Dividing Eq. (i) by Eq. (ii), we get
H = H1 + H 2 1 T′
3KA(100 − T ) 2KA(T − 50) KA(T − 0) 2l m = 606
⇒ = +
l l l 1 T 600
300 − 3T = 2T − 100 + T 2l m
⇒ 6T = 400 T′
200 or = (1.01)
or T = °C T
3 T′
18. Listener go from A → B with velocity (u) let the or = (1.02)%
T
apparent frequency of sound from source A by
or T ′ = T (1.02)
listener
Increase in tension
As Bs
∆T ′ = T × 1.02 − T
680 Hz 680 Hz = (0.02T )
 v − vo  Hence, ∆T′ = 0.02
n′ = n  
 v + v s P2
 340 − u 
or n′ = 680  
 340 + 0
S1
The apparent frequency of sound from source B
by listener 20. d P1
 v + vo  S2
n′ ′ = n   D
 v − vs
 340 + u
= 680   λD
 340 − 0 Fringe width β=
d
But listener hear 10 beats per second. Let the amplitude of that place where
Hence, n′ ′ − n′ = 10 constructive inference takes place is a.
 340 + u  340 − u The position of fringe at p2 is
or 680   − 680   = 10
 340   340  nλ D
x=
or 2 (340 + u − 340 + u) = 10 d
 β
or u = 2.5 m s–1 Given, β′ =  
 4
19. Beats per second when both the wires vibrate
λ D nλ D
simultaneously. ∴ =
4d d
n1 ± n2 = 6 1
or n=
1 T 1 T′ 4
or ± =6
2l m 2l m I1 a2
∴ =
1 T′ 1 T I 2  a 2
or − =6  
2l m 2l m  4
1 T′ or I1 : I 2 = 16 : 1
or − 600 = 6
2l m 21. Position fringe from central maxima
1 T′ nλ 1 D
= 606 …(i) y1 =
2l m d
Given that fundamental frequency Given, n = 10
1 T 10λ 1D
= 600 …(ii) ∴ y1 = …(i)
2l m d
For second source OP = 225 − 25 = 200 cm
5λ 2D Since, at the neutral point, magnetic field due to
y2 = …(ii)
d the magnet is equal to B H
10λ 1D µ M
BH = 0 ⋅
∴
y1
= d 4π (OP 2 + AO 2 )3/ 2
y2 5λ 2D M
0.4 × 10−4 = 10−7 ×
d (200 × 10 + 25 × 10−4 )3/ 2
−4
y1 2λ 1
⇒ = 0.4 × 10−4
y2 λ2 × (225 × 10–4 )3/ 2 = M
10−7
22. Interference phenomenon takes place between 0.4 × 103 × 10−6 (225)3/ 2 = M
two waves which have equal frequency and
propagate in same direction. M = 1.35 A- m
Hence, y1 = a sin (ωt + φ1 ) 26. Charge density of long wire
y 3 = a′ sin (ωt + φ2 ) 1
λ = C- m
will give rise to interference as the two waves 3
l
have same frequency ω. and r = 18 × 10−2 m r
23. The two lenses of an achromatic doublet should From Gauss theorem
have, sum of the product of their powers and → → q
dispersive power equal to zero. ∫ E⋅ d S = ε 0
24. Ratio of magnetic moments of two magnets q
of equal size when in sum and difference E ∫ dS =
ε0
position is
q
M A Td2 + T s2 v 2s + vd2 or E × 2πrl =
= = ε0
M B Td2 − T s2 v 2s − vd2
q q/l
2 2 or E= =
 1  1 2πε 0rl 2πε 0r
  + 
 20  15 λ×2 λ×2
= 2 2 = =
 1  1 2πε 0r × 2 4πε 0r
  − 
 15  20 1 1
= 9 × 109 × × 2 ×
400 + 225 3 18 × 10−2
=
400 − 225 1
= × 1011 = 0.33 × 1011
625 25 3
= =
175 7 = 0.33 × 1011 NC –1
⇒ M A : M B = 25 : 7 27. Potential at P due to (+ q) charge
25. Length of magnet = 10 cm =10 × 10–2 m, 1 q
V1 = ⋅
r = 15 × 10−2 m 4πε 0 (z − a)
P y
15
cm cm –q 2a q P
15 Z
A B (0,0,z)
(0,0,–a) (0,0,a)
x
SA BN
O Potential at P due to (−q) charge
5 cm 5 cm
1 −q
V2 = ⋅
4πε 0 (z + a)
Total potential at P due to ( AB ) electric dipole 29. Resistance of potentiometer wire
V = V1 + V2 l
R =ρ ×
1 q 1 q A
= ⋅ − 10
4πε 0 (z − a) 4πε 0 (z + a) 
or R = ρ × 
q (z + a − z + a)  A
=
4πε 0 (z − a)(z + a) The value of 2.5 m length wire
2qa ρ × 10
⇒ V= R′ = × 2.5
4πε 0(z 2 − a2 ) A × 10
 2.5ρ 
A or R′ =  
 A × 10
Potential V′ = I × R ′
50 kΩ
 2.5ρ 
=I 
 A × 10
28. 100 V B
Now, again the length of potentiometer wire is
increased by 1 m, then resistance of null position
R V 50 kΩ
wire.
 ρ×l 
C R′ ′ =  
 11 × A 
Internal resistance of voltmeter is R. V′ ′ = IR ′ ′
Therefore effective resistance across B and C, R′ and V = V′
is given by I × 2.5ρ ρ×l
1 1 1 = ×I
= + A × 10 11 × A
R ′ R 50 2.5 × 11
50 + R or = l = 2.75 m
= 10
50R
 50R  100 µH 1 µF 10 Ω
or R′ =   VL
 50 + R 
According to Ohm’s law 30.
I
V′ = IR ′ VR
100  50R  VC
or =I⋅ 
3  50 + R 
100  50 + R  Impedance, Z = ( X L ~ X C )2 + R 2
or   =I …(i)
3  50R  2
 1  2
Now, total resistance of circuit or Z =  ωL ~  +R
 ωC 
50R
R ′ ′ = 50 + Inductive reactance
50 + R
X L = ωL = 70 × 103 × 100 × 10−6
(2500 + 100R )
or R′ ′ = =7 Ω
(50 + R )
Capacitance reactance
Now, V′ ′ = IR ′ ′ 1 1
100  50 + R  2500 + 100R XC = =
⇒ 100 =   ωC 70 × 103 × 1 × 10−6
3  50R  (50 + R )
1 102 100
= = =
or 150R = 2500 + 100R 7 × 10 −2
7 7
or 50R = 2500 As XC > XL
or R = 50 kΩ Hence, circuit behave like as R-C circuit.
31. Magnetic field at the centre of the loop 33. Work function W0 = 3.31 × 10−19 J
µ I ⋅ 2πR Wavelength of incident radiation
B= 0 ⋅ …(i)
4π R2 λ = 5000 × 10−10 m
For the wire which is looped l
E = W0 + KE
double let radius becomes r (According to Einstein equation)
l B
Then, = 2πr hc
= 3.31 × 10−19 + KE
2 R λ
l
or = (r) 6.62 × 10−34 × 3 × 108
4π I KE = − 3.31 × 10−19 +
µ I ⋅ 2πr × 2 5000 × 10−10
∴ B′ = 0 ⋅ 6.62 × 3
4π r2 = − 3.31 × 10−19 + × 10−19
l 5
I⋅ ⋅2
µ0 2 = (−3.31 × 1.324 × 3) × 10−19
or B′ = ⋅
4π  l  2 = (3.972 − 3.31) × 10−19
 
 4π 
= 0.662 × 10−19 J
2
µ0 Il × 16π
or B′ = ⋅ …(ii) 0.662 × 10−19
4π l2 ⇒ E=
1.6 × 10−19
µ0 I⋅l  l 
Now, B= ⋅ 2 
R= …(iii)
4π  l  2π  = 0.41 eV
  34. From Einstein’s equation
 2π 
1
Dividing Eq. (ii) by Eq. (iii), we get E = W0 + mv 2
2
µ 0 I ⋅ l ⋅ 16π 2
⋅ 2(E − W0 )
B′ 4π l2 =v
= m
B µ 0 Il ⋅ 4π 2
⋅ or A charged particle placed in uniform
4π l2
magnetic field experience a force
B′
or =4 mv 2
B F =
r
or B′ = 4B
mv 2
or evB =
r
R
32. mv
O or r=
I eB
2(E − W0 )
Magnetic field due to long wire at O point m
or r= m
µ  I
B1 = 0   (upward direction) eB
2π  R 
2m(E − W0 )
Magnetic field due to loop at O point ⇒ r=
eB
µ I ⋅ 2πR
B2 = 0 ⋅ 35. N1 = N 0e−10λt
4π R2
µ I and N 2 = N 0e−λt
B2 = 0 ⋅ (in upward direction) N1 1
2 R ⇒ = = e−1 = e( −10λ + λ )t
Hence, resultant magnetic field at centre O N2 e
B = B1 + B 2 = e−9λt
µ I 1
B = 0 (π + 1) T ⇒ t =
2π ⋅ R 9λ
36. In circuit A, both (p-n) junction diode act as or y 2 = l = 4 t 2 + 4 t 2 + 100 − 40 t
forward biasing. Hence, current flows in ⇒ l = 8 t 2 + 100 − 40 t
circuit A.
dl
Total resistance R is given by Now, = (16 t − 40) = 0
1 1 1 dt
= + 40
R 4 4 t = = 2.5 s
1 2 16
or = d 2l
R 4 As = 16 = (+ ve)
or R = 2Ω dt 2
According to Ohm’ s law Hence, l will be minimum.
V = I AR 39. In this process potential B
energy of the metre stick
or 8 = IA × 2
will be converted into
or IA = 4 A rotational kinetic energy. CG
In circuit B, lower p-n-junction diode is reverse mgl
biased. Hence, no current will flow but upper PE of metre stick = l/2
2
diode is forward biased so current can flow
Because its centre of A
through it
gravity lies at the middle v
V = IB R of the rod.
or 8 = IB × 4 1
Rotational kinetic energy E = Iω 2
or IB = 2 A 2
37. After impact the I = moment of inertia of metre stick about point
bullet and block 250 ms–1
m ml2
move together and 0.23 kg A= .
3
comes to rest after m = 0.2 kg
covering a distance
u2 = 0 By the law of conservation of energy
of 40 m.  l 1
mg   = Iω 2
By conservation of momentum  2 2
2
m1u1 + m2u2 = m1v1 + m2v2 1 ml2  vB 
=  
or 0.02 × 250 + 0.23 × 0 = 0.02 v + 0.23 v 2 3  l
5 + 0 = v (0.25) By solving, we get vB = 3gl
500
= v = 20 ms−1 40. Given, r = 0.4 m,
25
Now, by conservation of energy
1
Mv 2 = µR ⋅ d
2
1
or × 0.25 × 400 = µ × 0.25 × 9.8 × 40
2 4 kg
200
⇒ µ= = 0.51
9.8 × 40 α = 8 rad s −1,
y
38. Let after the time (t ) m = 4 kg, I = ?
→ ^
the position of A is B vB = 2j ms–1 Torque, τ = Iα
(0,10)
(0, v At ) and position of →
mgr = I ⋅α
^
vA = 2j ms–1 or 4 × 10 × 0.4 = I × 8
B = (vBt , 10). Distance A x
(0,0) 16
between them ⇒ I= = 2 kg- m2
2 2
8
y = (0 − vBt ) + (v At − 10)
or I = 2 kg- m2
or y 2 = (2t )2 + (2t − 10)2
CHEMISTRY
41. Given : ∆H f (H) = 218 kJ/ mol Due to repulsion between two lone pairs of
1 electrons, its shape gets distorted. Therefore, the
ie, H2 → H; ∆H = 218 kJ/ mol bond angle in the molecule is 103°.
2
or H2 → 2H; ∆H = 436 kJ/ mol 44. To decide the structure of alkene that undergoes
436 ozonolysis, bring the products together in such a
= = 104.3 kcal/ mol way that O atoms are face to face, and replace O
4.18
by double (==) bond. Thus,
Thus, 104.3 kcal/mol energy is absorbed for
breaking one mole of H—H bonds. Hence, H—H H3C CH3
bond energy is 104.3 kcal/mol. C ==O + O==C
42. In Wacker process, alkene is oxidised into H CH3
aldehyde. acetaldehyde acetone
1 PdCl 2⋅ CuCl 2 4 1
CH2==CH2 + O 2 → CH3CHO H3C CH3
2 H 2O (B ) Replacement 3 2
→ C ==C
Since on ozonolysis, only alkenes produce of O by double bond
H CH3
aldehydes, ‘ A ’ must be an alkene. To decide the 2-methyl-2-butene
structure of alkene that undergoes ozonolysis, 45. Structure of XeO 3
bring the products together in such a way that O
atoms are face to face and, replace O by double Xe
(==) bond. Thus, O O
H3C CH3 O
C ==O + O==C ⇒ 3pπ - dπ pi bonds.
H H Structure of XeO 4
‘B ’ ‘B ’
O
H3C CH3
Replacement of
→ C ==C
O by double bond Xe
H H
‘A’ O O
O
Therefore, alkyne must be
⇒ 4 pπ - dπ bonds.
2 H
CH3 —C ≡≡C —CH3 → 46. From de-Broglie’s equation
(alkyne) Lindlar’s catalyst
h
H3C CH3 λ=
mv
C ==C 2 h2
⇒ λ = 2 2
H H m v
‘ A’
h2
43. 2F2 + 2NaOH → 2NaF + OF2 ↑ + H2O ⇒ mv 2 =
dilute ( A) mλ2
The structure of ‘ A ’ (OF2 ) is as 1
Q KE (K ) = mv 2
2
O
F 1 h2
103.2 F ∴ KE (K ) =
2 mλ2
σ bonds made by O = 2 2 2
K1  λ 2   5
Lone pairs of electrons on O = 2 ⇒ =  = 
K 2  λ1   3
∴ No. of orbitals used by O for hybridisation
= 2+ 2= 4 ∴ K1 : K 2 = 25 : 9
∴ Hybridisation of O in OF2 = sp3
47. Paramagnetic property depends upon the CH3 CH3
number of unpaired electrons. Higher the +
number of unpaired electrons, higher the
N2Cl– Cl
Cu/HCl
paramagnetic property will be. 51. Gattermann
+ N2
Cu 2+ = [ Ar] 3d 9, no. of unpaired electrons = 1 reaction
V 2+ = [ Ar] 3d 3, no. of unpaired electrons = 3 H

2+ 4

Cr = [ Ar] 3d , no. of unpaired electrons = 4 52. H 3PO 3 ⇒ H—O — P —O — H}
Mn 2+ 5
= [ Ar] 3d , no. of unpaired electrons = 5 ↓
O
Hence, correct order is O
Cu 2+ < V 2+ < Cr 2+ < Mn 2+ 
H 3PO 2 ⇒ P—OH
48. Q 1 mol = 6.023 × 1023 atoms
H
KE of 1 mol = 6.023 × 104 J H
144244 3
or KE of 6.023 × 1023 atoms two P— H bonds
53. From the definition of dipole moment,
= 6.023 × 104 J
µ =δ × d
6.023 × 104 where, δ = magnitude of electric charge
∴ KE of 1 atom =
6.023 × 1023 d = distance between particles (here
= 1.0 × 10−19 J bond length)
µ
hc 6.626 × 10−34 × 3 × 108 ∴ δ=
hν energy = = d
λ 600 × 10−9 δ HCl µ HCl dHI
or, = ×
= 3.313 × 10−19 J δ HI dHCl µ HI
Minimum amount of energy required to remove 1.03 × 1.6
= = 3.3 : 1
an electron from the metal ion (ie, Threshold 1.3 × 0.38
energy)
54. SiCl 4 + 4H2O → H4SiO 4 + 4HCl
= hν − KE
= 3.313 × 10−19 − 1.0 × 10−19 ∆
H4SiO 4 → SiO 2 + 2H2O
−19 1000° C
= 2.313 × 10 J
0.9
49. The thermosphere is the fourth layer of the 55. % of Cd in CdCl 2 = × 100
1.5
earth’s atmosphere and is located above the
= 60%
mesosphere. The air is thin in the thermosphere.
Therefore, % of Cl 2 in CdCl 2 = 100 − 60 = 40%
The earth’s thermosphere also includes the
Q 40% part (Cl 2 ) has atomic weight
region of the atmosphere, called the ionosphere.
= 2 × 35.5 = 71.0
The ionosphere is the region of the atmosphere
∴ 60% part (Cd) has atomic weight
that is filled with charged particles such as O +2 ,
71.0 × 60
O + , NO + . The high temperature in the =
40
thermosphere can cause molecules to ionize. = 106.5
50. Sulphuric anhydride is SO 3 and its structure is as
follows : 56. 2Al + 2NaOH+ 2H2O → 2NaAlO 2 + 3H2
sodium
O meta
aluminate
S Sodium metaaluminate, thus formed, is soluble

O O in water and changes into the complex
[Al(H2O)2(OH)4]– , in which coordination
⇒ 3σ, 1 pπ - pπ , 2 pπ - dπ bonds are present.
number of Al is 6.
57. Average kinetic energy per molecule 61. (A) Feldspar (orthoclase) (KAlSi 3O 8 )
3 It is used in the manufacture of porcelain.
= kT
2 (B) Asbestos {CaMg 3(SiO 3 )4}
3 R It is used for fireproof sheets, cloths etc.
or = T
2 N0 (C) Pyrargyrite (Ruby silver) (Ag 3SbS3 )
3 8.314 It is an ore of silver.
= × × 300 (D) Diaspore (Al 2O 3 ⋅ H2O)
2 6.023 × 1023
It is an ore of aluminium.
= 6.21 × 10–21 JK –1 molecule–1
62. First ionisation energy increases in a period.
58. Superoxides are the species having an O—O Thus, the first IE of the elements of the second
1 period should be as follows
bond and O in an oxidation state of −
2 Be< B< N < O
(superoxide ion is O −2). Usually these are formed But in practice, the elements do not follow the
by active metals such as KO 2, RbO 2 and CsO 2. above order. The first IE of these elements is
For the salts of larger anions (like O −2), lattice B< Be< O < N
energy increases in a group. Since, lattice energy The lower IE of B than that of Be is because in B
is the driving force for the formation of an ionic (1s 2, 2 s 2 2p1), electron is to be removed from 2 p
compound and its stability, the stability of the which is easy while in Be (1s 2, 2s 2 ), electron is to
superoxides from ‘K’ to ‘Cs’ also increases.
be removed from 2 s which is difficult. The low
59. Perhydrol means 30% solution of H2O 2. IE of O than that of N is because of the half-filled
H2O 2 decomposes as 2 p orbitals in N (1s 2, 2s 2 2p3 ).
2H2O 2 → 2H2O + O 2 63. CH3CH2OH+ Cl 2 → CH3CHO
Volume strength of 30% H2O 2 solution is 100 –2HCl X
that means 1 mL of this solution on acetaldehyde
decomposition gives 100 mL oxygen. 3Cl 2
→ CCl 3CHO
1 –3HCl Y
SO 2 + O 2 → SO 3 chloral
2
1L
1
L 1L CH3 COO
∆
2 64. I. Ca → CH3COCH3
CH3CO O – CaCO3
2L 1L 2L
Since, 100 mL of oxygen is obtained by Red P
= 1 mL of H2O 2 II. CH3COOH → 6HI → CH3CH3 + 3I2
∴1000 mL of oxygen will be obtained by + 2H2O
1 CH3CO OH CH3CO
= × 1000 mL of H2O 2 ∆, P4 O10
100 III. → O + H2O
CH3COO H CH3CO
= 10 mL of H2O 2
dC HA 85.71 7.14
60. Buffer capacity, β = , 65. C = 85.71% = =7.14; =1
dpH 12 7.14
where, dC HA = no. of moles of acid added 14.29 14.29
H = 14.29% = =14.29; =2
per litre 1 7.14
dpH = change in pH ∴ Empirical formula = CH2
moles of acetic acid and, empirical formula weight = 12 + 2 = 14
dC HA =
volume Again, molecular formula weight
0.12/ 60 1 = 2 × vapour density
= =
250 / 1000 125 = 2 × 14 = 28
1 / 125 1 28
∴ β= = = 0.4 ∴ n= =2
0.02 2.5 14
∴ Molecular formula = (CH2 )2 = C 2H4 solution is less than that of pure solvent. It is
CH2==CH2 + HOCl → CH2 —CH2—Cl called depression in freezing point.
( A)  EtOH/
OH 70. C 2H5—Cl + AgCN → C 2H5 — NC + AgCl
H 2O
(B )
⇓
EtOH
+ KCN → N-linked to ethyl carbon
H O+ 71. For the given cell,
CH2 —CH2—CN →
3
CH2 —CH2—COOH
  Ag| Ag+ | AgCl|Cls |Cl 2, Pt
OH OH the cell reactions are as follows
(C)
At anode :
66. Tripeptides are amino acids polymers in which Ag → Ag+ + e−
three individual amino acid units, called
residues, are linked together by amide bonds. At cathode :
In these, an amine group from one residue forms AgCl + e− → Ag(s ) + Cl −
an amide bond with the carboxyl group of a
second residue, the amino group of the second Net cell reaction :
forms an amide bond with the carboxyl group of AgCl → Ag+ + Cl –
the third.
∴ °
∆G reaction = Σ∆G °p − Σ∆G R°
Therefore, glycine (NH2—CH2—COOH),
alanine (CH3—CH—COOH) and phenyl alanine = (78 − 129) − (−109)
 = + 58 kJ/ mol
NH2
∆G ° = − nFE °
C 6H5—CH2 —CHCOOH can be linked in six °
58 × 103 J = − 1 × 96500 × E cell

NH2 ° = −58 × 1000
E cell
different ways. 96500
67. A codon is a specific sequence of three adjacent = − 0.6 V
bases on a strand of DNA or RNA that provides 72. Crotonaldehyde is produced by the aldol
genetic code information for a particular amino
condensation of acetaldehyde.
acid.
H H
68. Dopamine is produced in several areas of the ⊕ 
brain. If the amount of dopamine increases in Dil. NaOH
CH3—C ==Os + H—C —CHO →
the brain, the patient may be affected with acetaldehyde  (nucloeophilic
addition)
Parkinson’s disease. The IUPAC name of H
acetaldehyde
dopamine is 2-(3,4-dihydroxyphenyl)
ethylamine and its structure is as follows : H H
  ∆
CH2CH2NH2 CH3—C — C —CHO → CH3CH==CHCHO
– H 2O
  (elimination)
crotonaldehyde
OH H
aldol
OH 73. BaCl 2 + 2NaOH → Ba(OH)2 + 2NaCl
OH λ∞m Ba(OH)2 = λ∞m BaCl 2 + 2λ∞m NaOH − 2λ∞m NaCl
69. Freezing point of a substance is the temperature
= 280 × 10−4 + 2 × 248 × 10−4
at which the solid and the liquid forms of the
substance are in equilibrium. −2 × 126 × 10−4
If a non-volatile solute is added to the solvent, = (280 + 496 − 252) × 10−4
there is decrease in vapour pressure of the
solution and thus the freezing point of the = 524 × 10−4 Sm2 mol –1
MZ log 4
74. Density, d = =
N 0a3 log 4 / 3
where, Z = number of atoms in unit cell log 4
=
dN 0a3 log 4 − log 3
∴ Z=
M 2 × 0.3010
8.92 × 6.023 × 1023 × (362 × 10–10 )3 =
= 2 × 0.3010 − 0.4771
63.55
0.6020
= 4.0 =
0.1249
Thus, metal has face centred unit cell.
= 4.81
75. N 2 + 2O 2 2NO 2
º [α ]observed
[ NO 2]2 77. [α ] =
K1 = l×C
[N 2][O 2]2
−1.2
[NO 2]2 = = − 39°
or 100 = …(i) 6.15
5×
[N 2][O 2]2 1000
1 78. Let the concentration of potassium acetate is x.
Again, [NO 2] º N2 + O 2
2
From Henderson’s equation,
[N ]1/ 2[O 2]
K2 = 2 [salt]
[NO 2] pH = pK a + log
[acid]
[N 2][O 2]2 x × 50
or K 22 = …(ii) 4.8 = − log (1.8 × 10−5 ) + log
[NO 2]2 20 × 0.1 M
Eqs. (i) × (ii), we get 4.8 = 4.74 + log 25x
100 × K 22 = 1
or log 25x = 0.06
1 1
or K 22 = or K 2 = = 0.1 25x = 1.148
100 10
∴ x = 0.045 M
76. For a first order reaction,
C
2.303 a 79. By ‘ 2 A + − B ’ , we get
t = log10 2
λ a− x
Na 2O + SO 3 → Na 2SO 4;
Let initial amount of reactant is 100.
259
100 ∆H = − 2 × 146 + − 418
log 2
t1 100 − 75
= or ∆H = − 580.5 ≈ − 581 kJ
t 2 log 100
100 − 25 80. As2S3 is a negative sol. It is obvious that cations
are effective in coagulating negative sols.
[Q λ remains constant] According to Hardy Schulze rule, greater the
100 valency of the coagulating ion, greater is its
log
25 coagulating power. Thus, out of the given,
=
100 AlCl 3(Al 3+ ) is most effective for causing
log
75 coagulation of As2S3 sol.
MATHEMATICS
81. Given, f ( x ) = x 3 + 3x − 2 [Here, we subtract those triangles which points
On differentiating w.r.t. x, we get are in a line]
(3p)! p!
f ′ ( x ) = 3x 2 + 3 = − 3⋅
(3p − 3)! 3 ! ( p − 3)! 3 !
Put f ′ ( x ) = 0 ⇒ 3x 2 + 3 = 0 3p(3p − 1)(3p − 2) 3 × p( p − 1)( p − 2)
= −
⇒ x2 = −1 3× 2 3× 2
∴ f ( x ) is either increasing or decreasing. p 2 2
= [ 9 p − 9 p + 2 − ( p − 3p + 2)]
At x = 2, f (2) = 23 + 3(2) − 2 = 12 2
At x = 3, f (3) = 33 + 3(3) − 2 = 34 = p2(4 p − 3)
86. The required number of ways = The even
∴ f ( x ) ∈[12, 34].
number of 0’s ie, {0, 2, 4, 6, …}
 2x − 1 
82. Let A =  x ∈ R : 3  n! n! n!
+ 4 2
+ 3 = + +
 x x x  n ! 2 !(n − 2)! 4 !(n − 4)!
Now, x 3 + 4 x 2 + 3x = x( x 2 + 4 x + 3) = nC 0 + nC 2 + nC 4 + K = 2n − 1
= x( x + 3)( x + 1) 87. Now, (1 + x 2 )12(1 + x12 + x 24 + x 36 )
∴ A = R − {0, − 1, − 3} = [1 + 12
C1( x 2 ) + 12
C 2( x 2 )2 + 12
C 3( x 2 )3
83. Given, a0 = 1, an + 1 = 3n2 + n + an + 12
C 4( x 2 )4 + 12
C 5( x 2 )5 + 12
C 6( x 2 )6
12 2 12 12 24
⇒ a1 = 3(0) + 0 + a0 = 1 +K+ C12( x ) ] × (1 + x + x + x 36 )
and a2 = 3(1)2 + 1 + a1 = 3 + 1 + 1 = 5 Coefficient of x 24 = 12C 6 + 12
C12 + 1
From option (b), 12
= C6 + 2
Let P (n) = n3 − n2 + 1  2x 
3/ 2
88. 1 +  (32 + 5x )−1/ 5
∴ P (0) = 0 − 0 + 1 = 1 = a0  3
−1 / 5
P (1) = 13 − 12 + 1 = 1 = a1  3  2x    5 
= 1 +    (32)−1/ 5 1 + x
 
2 3    32 
and P (2) = (2)3 − (2)2 + 1 = 5 = a2
(Neglect higher powers of x)
Hence, option (b) is correct.
 1  5 
84. The total number of subsets of given set is = [1 + x]2−1 1 −   x 
29 = 512  5  32 
Case I When selecting only one even number (Neglect higher powers of x)
{2, 4, 6, 8} 1  x
= (1 + x ) 1 − 
Number of ways = 4C1 = 4 2  32
(1 + x )(32 − x ) 32 + 31 x
Case II When selecting only two even numbers = =
= 4C 2 = 6 64 64
Case III When selecting only three even (Neglect x 2 term)
numbers = 4C 3 = 4 1 1
89. =
Case IV When selecting only four even numbers ( x − 1)2( x − 2)  x
−2(1 − x )2 1 − 
= 4C 4 = 1  2
−1 
∴ Required number of ways 1 −2  x
=− (1 − x ) 1 − 

= 512 − (4 + 6 + 4 + 1) − 1 = 496 2 2
[Here, we subtract 1 for due to the null set] 1  x 
85. Total number of points in a plane is 3p. = − (1 + 2x + . . . ) 1 + + K 
2  2 
∴ Maximum number of triangles
1
= 3p
C 3 − 3⋅ pC 3 ∴Coefficient of constant term is − .
2
1 = αβ + βγ + γα = 4
90. Given, (ex + e5x ) = a0 + a1 x + a2 x 2 + K
e3x α 2β 2γ 2
and = − αβγ = 1
⇒ (e−2x + e2x ) = a0 + a1 x + a2 x 2 + K (β + γ )(γ + α )(α + β )
 (2x )2 (2x )4  (Q α + β + γ = 0)
⇒ 2 1 + + + K
 2 ! 4 !  ∴ Required equation is
= a0 + a1 x + a2 x 2 + K x3 + 4x − 1 = 0
⇒ a1 = a3 = a5 = K = 0 94. Given, f ( x ) = 2x 4 − 13x 2 + ax + b is divisible by
∴ 2a1 + 23 a3 + 25 a5 + K = 0 ( x − 2)( x − 1).
91. Given, ∴ f (2) = 2(2)4 − 13(2)2 + a(2) + b = 0
( x − a)( x − a − 1 ) + ( x − a − 1 )( x − a − 2) ⇒ 2a + b = 20 …(i)
+ ( x − a)( x − a − 2) = 0 and f (1) = 2(1)4 − 13(1)2 + a + b = 0
Let x − a = t , then
⇒ a + b = 11 …(ii)
t (t − 1) + (t − 1)(t − 2) + t (t − 2) = 0
On solving Eqs. (i) and (ii), we get
⇒ t 2 − t + t 2 − 3t + 2 + t 2 − 2t = 0
a = 9, b = 2
⇒ 3t 2 − 6 t + 2 = 0
95. Given, A = A′ , B = B′
6±
36 − 24 6 ± 2 3
⇒ t = = Now, ( AB − BA )′ = ( AB )′ − (BA )′
2(3) 2(3) = B′ A′ − A′ B′
3± 3 = BA − AB
⇒ x −a=
3 = − ( AB − BA )
3± 3 ∴ AB − BA is a skew-symmetric matrix.
⇒ x =a+
3 3 5 x
Hence, x is real and distinct. 96. Given,  7 x 7  = 0
 x 5 3
92. Given, f ( x ) = x 2 + ax + b has imaginary roots.
⇒ 3(3x − 35) − 5(21 − 7 x ) + x(35 − x 2 ) = 0
∴Discriminant, D < 0 ⇒ a2 − 4b < 0
⇒ 9 x − 105 − 105 + 35x + 35x − x 3 = 0
Now, f ′ ( x ) = 2x + a
⇒ x 3 − 79 x + 210 = 0
f ′ ′ (x) = 2
Also, f (x) + f ′ (x) + f ′ ′ (x) = 0 …(i) ⇒ ( x + 10)( x − 3)( x − 7 ) = 0
⇒ x 2 + ax + b + 2 x + a + 2 = 0 ⇒ x = − 10, 3, 7
⇒ x 2 + (a + 2)x + b + a + 2 = 0 97. Let a and R be the first term and common ratio of
a GP.
− (a + 2) ± (a + 2)2 − 4(a + b + 2) ∴ T p = aR p − 1 = x
∴ x=
2 Tq = aR q − 1 = y
− (a + 2) ± a2 − 4b − 4
= and Tr = aR r − 1 = z
2
Since, a2 − 4b < 0 ⇒ log x = log a + ( p − 1) log R
log y = log a + (q − 1) log R
∴ a2 − 4b − 4 < 0
and log z = log a + (r − 1) log R
Hence, Eq. (i) has imaginary roots.
 log x p 1   log a + ( p − 1) log R p 1 
93. Given, α , β and γ are the roots of ∴ log y q 1  =  log a + (q − 1) log R q 1 
x 3 + 4 x + 1 = 0.  log z r 1   log a + (r − 1) log R r 1 
∴ α + β + γ = 0, αβ + βγ + γα = 4, αβγ = − 1  log a p 1   ( p − 1) log R p 1 
=  log a q 1  +  (q − 1) log R q 1 
α2 β2 γ2 α 2 β2 γ2  log a r 1   (r − 1) log R r 1
Now, + + = + +
β + γ γ + α α + β −α −β − γ  1 p 1   p − 1 p − 1 1
= log a 1 q 1  + log R  q − 1 q − 1 1 
= − (α + β + γ ) = 0
2 2
1 r 1   r − 1 r − 1 1
α β β2γ 2 γ 2α 2
+ + (C 2 → C 2 − C 3 )
(β + γ )(γ + α ) (γ + α )(α + β ) (β + γ )(α + β )
=0+ 0=0 (Q two columns are identical)
98. If matrix has no inverse it means the value of 1
=1 − (1 − cos 4 x )
determinant should be zero. 4
 1 −1 x  3 cos 4 x
∴ 1 x 1 = 0 = +
 x −1 1  4 4
2π π
If we put x = 1, then column Ist and IIIrd are ∴ Period of f ( x ) = =
identical. 4 2
Hence, option (d) is correct. sin ( x − y ) sin y 2
103. Now, tan ( x − y ) tan y = ×
99. Given, α, β are the roots of x 2 − 2x + 4 = 0 cos ( x − y ) cos y 2
cos ( x − 2 y ) − cos ( x )
∴ α+β=2 …(i) =
cos ( x − 2 y ) + cos ( x )
and αβ = 4 …(ii)
cos x
Now, α − β = (α + β )2 − 4αβ 1−
cos ( x − 2y )
=
= 4 − 4 × 4 = −12 cos ( x )
1+
⇒ α −β = 2 3i …(iii) cos ( x − 2y )
On solving Eqs. (i) and (ii), we get 1−λ
2 + 2 3i  −1 − 3 i  =
α= = − 2  = − 2ω 2 1+ λ
2  2   
cos x
 −1 + 3 i  Given, λ = 
2 − 2 3i  cos ( x − 2y )
and β = = − 2  = − 2ω
2  2  104. It is a standard result.
Now, α 6 + β 6 = (−2ω 2 )6 + (−2ω)6 cos A cos 2A cos 22 A K cos 2n − 1 A
= 64(ω 3 )4 + 64(ω 3 )2 sin 2n A
3 =
= 128 [Q ω = 1] 2n sin A
100. Let z = x + iy 105. sin 2 x − cos 2x = 2 − sin 2x
Given,  z + 2i 
 < 1 ⇒ 1 − cos2 x − (2 cos2 x − 1)
 2z + i  = 2 − 2 sin x cos x
( x )2 + ( y + 2)2 ⇒ 2
−3 cos x + 2 sin x cos x = 0
⇒ <1
(2 x )2 + (2 y + 1)2 ⇒ cos x (2 sin x − 3 cos x ) = 0
⇒ 2 2 2
x + y + 4 + 4y < 4x + 4y + 1 + 4y 2 ⇒ cos x = 0, (Q 2 sin x − 3 cos x ≠ 0)
π
⇒ 3x 2 + 3y 2 > 3 ⇒ x = 2nπ ±
2
⇒ x2 + y2 > 1 π
⇒ x = (4n ± 1)
2
101. Now, (1 + 3 i )n + (1 − 3 i )n
 1  1  1
 1 + 3i 
n
 1 − 3i 
n
106. cos−1  −  − 2 sin −1   + 3 cos−1  − 
= 2   2  2  2
  + 2  
  2    2  − 4 tan −1 (−1)
= (−2ω 2 )n + (−2ω )n  1  π   1 
= π − cos−1   − 2   + 3  π − cos−1   
= (−2)n [(ω 2 )3r + 1 + (ω )3r + 1]  2  6   2 
[Q n = 3r + 1, where r is an integer] + 4 tan −1 (1)
π π  π π
= (−2)n (ω 2 + ω ) = − (−2)n = π − − + 3 π −  + 4⋅
3 3  4  4
102. Let f ( x ) = sin 4 x + cos4 x π 3π
= + 3⋅ +π
= (sin 2 x + cos2 x )2 − 2 sin 2 x cos2 x 3 4
43π
1 =
=1 − ⋅ 2(sin 2x )2 12
4
107. Given, sinh −1 2 + sinh −1 3 = x → → →
= AC + 2( AC + CD ) − 2 DC
→
−1 −1
⇒ cosh (sinh 2 + sinh 3) = cosh x D
1
−1
⇒ cosh (sinh 2) cosh (sinh −1 3) P
2
+ sinh (sinh −1 2) sinh (sinh −1 3) A C
Q
= cosh x
⇒ cosh x = cosh (cosh −1 1 + 22 ) × B
−1 2 → →
cosh (cosh 1 + 3 )+ 2 × 3
= 3 AC − 4 DC
2 →
⇒ cosh x = ( 5 10 + 6) ×  3 →
2 = 3(2 QC) − 4  PC
2 
1
= (12 + 2 50 ) → → → →
2 = 6 QC − 6 PC = 6(QC + CP )
108. a (b cos C − c cos B ) = ab cos C − ac cos B → → →
⇒ k PQ = 6 QP = − 6 PQ (given)
a2 + b2 − c2 a2 + c2 − b2
= − ⇒ k = −6
2 2
= b2 − c2 112. Given, l + m + n = 0, ⇒ l = − m − n
and l2 + m2 − n2 = 0
109. We know that, 2s = a + b + c
(a + b + c)(b + c − a)(c + a − b)(a + b − c) ∴ (− m − n)2 + m2 − n2 = 0
∴ ⇒ 2m2 + 2mn = 0
4b2c2
2s(2s − 2a)(2s − 2b)(2s − 2c) ⇒ 2 m(m + n) = 0
=
4b2c2 ⇒ m = 0 or m + n = 0
s(s − a) (s − b)(s − c) If m = 0, then l = − n
=4 × l1 m n
bc bc ∴ = 1 =
2 A 2 A
−1 0 1
= 4 cos × sin = sin 2 A and if m + n = 0 ⇒ m = − n, then l = 0
2 2
l2 m2 n2
110. In ∆ APD, ∴ = =
a 0 −1 1
tan 45° = ⇒ AP = a ie, (l1, m1, n1 ) = (−1, 0, 1)
AP
C and (l2, m2, n2 ) = (0, − 1, 1)
0+ 0+1 1
∴ cos θ = =
D 1+ 0+1 0+1+1 2
E
b π
a ⇒ θ=
3
45° 45°
A B 113. Now,
P → →
2 a − c = 2(− i$ + $j + 2k$ ) − (−2i$ + $j + 3k$ )
and in ∆ BPC,
b = $j + k$
tan 45° = ⇒ PB = b
PB → →
and a + b = − i$ + $j + 2k$ + 2i$ − $j − k$
∴ DE = a + b and CE = b − a
In ∆ DEC, = $i + k$
DC 2 = DE 2 + EC 2 →
Let θ be the angle between 2 a − c and a + b.
→ → →
2 2
= (a + b) + (b − a) ($j + k$ )⋅ (i$ + k$ )
= 2(a2 + b2 ) ∴ cos θ =
12 + 12 12 + 12
→ → → →
111. Now, AB + 2 AD + BC − 2 DC 1 1
⇒ cos θ = =
→ → → 2 2 2
= AC + 2 AD − 2 DC
π 4
⇒ θ= ∴ Required probability =
3 9
→ 1  E  1
114. Given, m1 = | a1 | = 22 + (−1)2 + (1)2 = 6 119. (A) Given, P (E1 ) = , P  1  =
4  E2  4
→
m2 = | a 2 | = 32 + (−4)2 + (−4)2 = 41 E  1
→ and P  2  =
2 2
m3 = | a 3 | = 1 + 1 + (−1) = 3 2  E1  2
→ P (E 2 ∩ E1 ) 1
and m4 = | a 4 | = (−1)2 + (3)2 + (1)2 = 11 ⇒ =
P (E1 ) 2
∴ m3 < m1 < m4 < m2 1
→ → ⇒ P (E 2 ∩ E1 ) =
115. Given, a = λi − 7 $j + 3k$ , b = λi$ + $j + 2λk$
$ 8
→ →  E1  1
a ⋅b Also, P  =
∴ cos θ =  E2  4
→ →
| a || b| P (E1 ∩ E 2 ) 1
⇒ =
λ2 − 7 + 6λ P (E 2 ) 4
= <0
λ2 + 49 + 9 λ2 + 1 + 4λ2 1 1
⇒ =
8 P (E 2 ) 4
⇒ (λ + 7 )(λ − 1) < 0
1
⇒ −7 < λ < 1 ⇒ P (E 2 ) =
→ →
2
116. Let a = i + 2j − k , b = $i + $j + k$
$ $ $
(B) P (E1 ∪ E 2 ) = P (E1 ) + P (E 2 ) − P (E1 ∩ E 2 )
→ 1 1 1 5
and c = i$ − $j + λk$ = + − =
4 2 8 8
1 →→→
Since, volume of tetrahedron = [ a b c]  E1  P (E1 ∩ E 2 )
6 (C) P   =
 E2  P (E 2 )
2 1 1 2 −1 
⇒ = 1 1 1 5
3 6  1 −1 λ 1−
1 − P (E1 ∪ E 2 ) 8
= =
2 1 1 − P (E 2 ) 1
⇒ = [1(λ + 1) − 2(λ − 1) − 1 (−1 − 1)] 1−
3 6 2
3
⇒ 4 = [ − λ + 5] ⇒ λ = 1 =
7 4
117. Given, P ( A ∪ B ) = P ( A ∩ B ) =  E1  P (E1 ∩ E 2 )
10 (D) P   =
 E2 P (E 2 )
Since, P ( A ∩ B ) + P ( A ∩ B ) = 1
P (E1 ) − P (E1 ∩ E 2 )
7 3 =
⇒ P( A ∩ B ) = 1 − = 1 − P (E 2 )
10 10
1 1 1
Also, P ( A ∪ B ) = P ( A ) + P (B ) − P ( A ∩ B ) −
1
4 2 3 = 4 8 = 8=
⇒ = P( A ) + − 1 1 4
5 5 10 1−
2 2
4 2 3
⇒ P( A ) = − + 120. Given, distribution is
5 5 10
2 3 7 X = x 0 1 2 3
= + =
5 10 10 P( X = x ) 1 1 0 1
118. Given, x 2 + 4 x + c = 0 3 2 6
4
For real roots, D = b2 − 4ac ≥ 0 ∴ Mean, m = Σ pi x i
i=1
= 16 − 4c ≥ 0
1 1 1
⇒ c = 1, 2, 3, 4 will satisfy the above =0× + 1 × + 2× 0 + 3×
inequality. 3 2 6
1 1 x1 = 15, y1 = − 10
=0+ + 0 + =1
2 2
4
Variance, σ 2 = Σ pi( x i − m)2 125. The point of intersection of lines x + 3y − 1 = 0
i=1 and x − 2y + 4 = 0 is (−2, 1).
1 1 Let equation of line perpendicular to the given
= (0 − 1)2 + (1 − 1)2
3 2 line is 2x − 3y + λ = 0.
1 Since, it passes through (−2, 1).
+ 0(2 − 1)2 + (3 − 1)2
6 ∴ 2(−2) − 3(1) + λ = 0
1 2 ⇒ λ =7
= + 0 + 0 + =1
3 3 ∴ Required line is 2x − 3y + 7 = 0
∴ m = σ2 = 1 126. Given equation is
121. Here, n = 6 2x 2 − 10 xy + 12y 2 + 5x + λy − 3 = 0
According to the question 5 λ
Here, a = 2, h = − 5, b = 12, g = , f = , c = − 3
6
C 2 p2q4 = 4 ⋅6 C 4 p4q2 2 2
a h g
⇒ q2 = 4 p2 For pair of lines  h b f  = 0
g f c
⇒ (1 − p)2 = 4 p2
 2 −5 5/ 2
⇒ 3p2 + 2p − 1 = 0 ⇒  −5 12 λ / 2 = 0
 5/ 2 λ / 2 −3 
⇒ ( p + 1)(3p − 1) = 0
 λ 2
 5λ 
1 ⇒ 2  −36 −  + 5 15 − 
⇒ p=  4  4
3
(Q p cannot be negative) 5  −5λ 
+
 − 30 = 0
2 2 
122. Given equation is x 2 + y 2 = r2. 2
λ 25λ 25λ
After rotation ⇒ −72 − + 75 − − − 75 = 0
2 4 4
x = X cos 36° − Y sin 36° ⇒ λ2 + 25λ + 144 = 0
and y = X sin 36° + Y cos 36° ⇒ (λ + 9)(λ + 16) = 0
∴ X 2(cos2 36° + sin 2 36° ) ⇒ λ = −9 (Q | λ | < 16)
+ Y 2(sin 2 36° + cos2 36° ) = r2 127.Given, x 2 − 2xy − xy + 2y 2 = 0
⇒ X 2 + Y 2 = r2 ⇒ ( x − 2 y )( x − y ) = 0
⇒ x = 2y, x = y …(i)
123. Since, given lines are parallel.
15 − 5 10 Also, x+ y+1=0 …(ii)
∴ d= = On solving Eqs. (i) and (ii), we get
2
4 +3 2 5
 2 1  1 1
A  − , −  , B  − , −  , C(0, 0)
⇒ d = 2 = diameter of the circle  3 3  2 2
∴ Radius of circle = 1 − 2 − 1 1 
∴ Area of circle = πr2 = π sq unit  3 3 
1 1 1 
∴ Area of ∆ABC = − − 1
124. Let point ( x1, y1 ) be on the line 3x + 4 y = 5. 2  2 2 
∴ 3x1 + 4 y1 = 5 …(i) 
 0 0 1 

2 2
Also, ( x1 − 1) + ( y1 − 2) = ( x1 − 3) 2  
1 1 1  1  1  1
+ ( y1 − 4)2 = − = =
2  3 6  2  6  12
⇒ x12 + y12 − 2x1 − 4 y1 + 5 = x12 + y12 − 6 x1
128. Given pair of lines are x 2 − 3xy + 2y 2 = 0 and
− 8 y1 + 25
x 2 − 3xy + 2y 2 + x − 2 = 0.
⇒ 4 x1 + 4 y1 = 20 …(ii)
∴ ( x − 2y )( x − y ) = 0
On solving Eqs. (i) and (ii), we get
and ( x − 2y + 2)( x − y − 1) = 0 and x 2 + y 2 − 4 x + 6 y + 11 = 0.
⇒ x − 2y = 0, x − y = 0 and x − 2y + 2 = 0, Here, C1 = (1, − 4), C 2 = (2, − 3),
x − y −1 = 0
⇒ r1 = 1 + 16 − 13 = 2
Since, the lines x − 2y = 0, x − 2y + 2 = 0 and
x − y = 0, x − y − 1 = 0 are parallel. and r2 = 4 + 9 − 11 = 2
Also, angle between x − 2y = 0 and x − y = 0 is Now, d = C1C 2 = (2 − 1)2 + (−3 + 4)2 = 2
not 90°.
∴ It is a parallelogram. d 2 − r12 − r22
∴ cos θ =
129. In ∆OAC, OC 2 = 22 + 42 = 20 2r1r2
2− 4 − 2
=
2× 2× 2
1
4 C(± 2, ±4) =−
2
4
A ⇒ θ = 135°
O 2 32
133. Let the required equation of circle be
x 2 + y 2 + 2gx + 2 fy = 0. Since, the above circle
∴ Required equation of circle is cuts the given circles orthogonally.
( x ± 2)2 + ( y ± 4)2 = 20 ∴ 2(−3g ) + 2 f (0) = 8
8
⇒ x2 + y2 ± 4x ± 8y = 0 ⇒ 2g = −
3
130. Let centre of circle be C (− g, − f ), then equation and −2 g − 2 f = − 7
of circle passing through origin be 8 29
x 2 + y 2 + 2gx + 2 fy = 0 ⇒ 2f = + 7 + =
3 3
∴ Required equation of circle is
8 29
B x2 + y2 − x + y=0
3 3
d
2
or 3x 2 + 3y 2 − 8 x + 29 y = 0
C A
(–g, –f) 2 134. Given curve is y 2 = 4 x.
Also, point (1, 0) is the focus of the parabola. It is
O
clear from the graph that only one normal is
x=3 possible.
y
∴ Distance, d = | − g − 3| = g + 3 y 2 = 4x
In ∆ ABC, (BC )2 = AC 2 + BA 2
⇒ g 2 + f 2 = (g + 3)2 + 22
x′ x
⇒ g 2 + f 2 = g 2 + 6g + 9 + 4 (1,0)
⇒ f 2 = 6g + 13
Hence, required locus is y 2 + 6 x = 13 y′
131. The intersection point of diameter lines is (2, 3)

which is the centre of circle. 135. Here, 2ae = 6 and 2b = 8 ⇒ b = 4
2 2 ⇒ b2 = 16
Now, radius = (5 − 2) + (7 − 3)
⇒ a2(1 − e2 ) = 16
= 9 + 16 = 5
9
∴ Required equation of circle is ⇒ (1 − e2 ) = 16
e2
( x − 2)2 + ( y − 3)2 = 52
⇒ 9 − 9e2 = 16e2
⇒ x 2 + y 2 − 4 x − 6 y − 12 = 0
⇒ 25e2 = 9
132. Given circles are x 2 + y 2 − 2x + 8 y + 13 = 0
3 139. Let A = (1, 0, 0), B = (0, 1, 0) and C = (0, 0, 1)
⇒ e=
5 Now, AB = (0 − 1)2 + (1 − 0)2 + 02 = 2
136. Given, x 2 y 2 = c4 BC = 02 + (0 − 1)2 + (1 − 0)2 = 2

⇒ y 2(a2 − y 2 ) = c4 and CA = (1 − 0)2 + 02 + (0 − 1)2 = 2
4 2 2 4
⇒ y −a y +c =0 ∴ Perimeter of triangle = AB + BC + CA
Let y1, y 2, y 3 and y 4 are the roots. = 2+ 2+ 2=3 2
∴ y1 + y 2 + y 3 + y 4 = 0 140. cos 2α + cos 2β + cos 2γ + sin 2 α + sin 2 β
137. Given, 4 x − 3y = 5 and 2x 2 − 3y 2 = 12 + sin 2 γ
2 2 2 2 2
 5 + 3y  2 = (cos α − sin α ) + (cos β − sin β )
∴ 2  − 3y = 12
 4  + (cos2 γ − sin 2 γ ) + sin 2 α + sin 2 β + sin 2 γ
2
(25 + 9 y + 30 y ) = cos2 α + cos2 β + cos2 γ
⇒ − 3y 2 = 12
8 =1
⇒ 15y 2 − 30 y + 71 = 0 141. We know that image ( x, y, z ) of a point
30 ±
900 − 4260 ( x1, y1, z1 ) in a plane ax + by + cz + d = 0 is
⇒ y=
30 x − x1 y − y1 z − z1
= =
−3360 a b c
=1 ± −2(ax1 + by1 + cz1 + d )
30 =
2 a2 + b2 + c2
2  4 x − 5
Also, 2x − 3   = 12 Here, point is (3, 2, 1) and plane is
 3 
2x − y + 3z = 7.
⇒ 10 x 2 − 40 x + 61 = 0
x − 3 y − 2 z −1
40 ± 1600 − 4 × 10 × 61 ∴ = =
⇒ x= 2 −1 3
2 × 10 −2[ 2(3) − (2) + 3(1) − 7]
=
40 ±
−840 −840 22 + 12 + 32
= = 2± x − 3 y − 2 z −1
20 20 ⇒ = = = − 2(0)
 −840 −3360  2 −1 3
∴ Points are A  2 + ,1+  and ⇒ x = 3, y = 2, z = 1
 20 30 
142. Given equation of sphere is
 −840 −3360 
B 2 − ,1− . x 2 + y 2 + z 2 − 12x − 4 y − 3z = 0
 20 30 
 3
∴ Mid point of AB is (2, 1). ∴ Centre of sphere is  6, 2,  .
 2
5 2
138. Given, = 2 + 3 cos θ + 4 sin θ  3
r ∴ Radius of sphere = (6)2 + (2)2 +  
 2
5 3 4 
⇒ = 2 + 5  cos θ + sin θ 9 169 13
r 5 5  = 36 + 4 + = =
5/ 2 5 4 4 2
⇒ = 1 + (cos φ cos θ + sin φ sin θ ) x+ 3 x+ 3
r 2  x + 5  3 
 3 4 143. lim   = lim 1 + 
 put cos φ = , then sin φ =  x → ∞  x + 2 x→ ∞  x + 2
 5 5 3( x + 3 )
5/ 2 5  x + 2 x+ 2
⇒ = 1 + cos (θ − φ )  3  3 
r 2 
= lim 1 + 
l x → ∞  x + 2 
It is of the form = 1 + e cos θ  
r
5
∴ e=
2
 3
1 +  On integrating both sides, we get
lim 3  x
 x − 1
2
x→ ∞ 
1 +


x
a tan −1 x + b log  
=e = e3  x + 1
 2 sin x − sin 2x 1  1 1 
144. Given, f ( x ) =  2x cos x
, if x ≠ 0 = ∫  − 2
2  x − 1 x + 1 
2
dx
 a, if x = 0
 x − 1
2 sin x − sin 2x ⇒ a tan −1 x + b log  
Now, lim f ( x ) = lim  x + 1
x→ 0 x→ 0 2 x cos x
1  x − 1 1 −1
0  = log   − tan x
 form 4  x + 1 2
0 
1 1
2 cos x − 2 cos 2x ⇒ a=− , b=
= lim 2 4
x → 0 2 (cos x − x sin x )
1  1
2− 2 ∴ a − 2b = − − 2   = − 1
= lim =0 2  4
x → 0 2(1 − 0 ) −1
148. Given, y = ea sin x
Since, f ( x ) is continuous at x = 0
∴ f (0) = lim f ( x ) ⇒ a = 0 On differentiating w.r.t. x, we get
x→ 0 −1 1
y1 = ea sin x a ⋅
x 1− y 1 − x2
145. Given, =
1 1+ y
⇒ y1 1 − x 2 = ay
Applying componendo and dividendo, we get ⇒ (1 − x 2 )y12 = a2 y 2
1 + x (1 + y ) + (1 − y )
= Again, differentiating w.r.t. x, we get
1 − x (1 + y ) − (1 − y )
(1 − x 2 )2y1 y 2 − 2xy12 = a2 2yy1
1+ x 2
⇒ = ⇒ (1 − x 2 )y 2 − xy1 − a2 y = 0
1− x 2 y
2 Using Leibnitz’s rule,
1 − x (1 − x 2 )y n + 2 + nC1 y n + 1(−2x ) + nC 2 y n(−2)
⇒ y= 
1 + x
− xy n + 1 − nC1 y n − a2 y n = 0
On differentiating w.r.t. x, we get
⇒ (1 − x 2 )y n + 2 + xy n + 1(−2n − 1)
dy −2(1 + x )2(1 − x ) − (1 − x )2 ⋅ 2(1 + x )
= + y n[ − n(n − 1) − n − a2] = 0
dx (1 + x )4
(1 − x )(1 + x )(−2 − 2x − 2 + 2x ) ⇒ (1 − x 2 )y n + 2 − (2n + 1)xy n + 1 = (n2 + a2 )y n
=
(1 + x )4 149. Given, error in diameter = ± 0.04
4( x − 1) ∴ Error in radius, dr = ± 0.02
=
( x + 1)3 ∴Per cent error in the volume of sphere
 4 
1  d  πr 3 
146. Given, x = cos−1  dV 3  3dr
 1 + t2 = × 100 = × 100 = × 100
  V 4 3 r
πr
 t  3
and y = sin −1   3 × (± 0.02)
 1 + t2 = × 100 = ± 0.6
  10
⇒ x = tan −1 t , 150. Given, f ( x ) = x 3 + ax 2 + bx + c, a2 ≤ 3b.
and y = tan −1 t On differentiating w.r.t. x, we get
dy f ′ ( x ) = 3x 2 + 2ax + b
∴ y=x ⇒ =1
dx Put f ′ (x) = 0
d  −1  x − 1  1 ⇒ 3x 2 + 2ax + b = 0
147. Given, a tan x + b log   = 4
dx   x + 1  x − 1
−2a ± 4a2 − 12b  2 − sin 2x  x

⇒ x= 154. Let I=∫  e dx
2× 3  1 − cos 2x 
−2a ± 2 a2 − 3b  2 − 2 sin x cos x  x
= =∫  e dx
3  2 sin 2 x 
Since, a2 ≤ 3b, = ∫ cosec 2 x ex dx − ∫ cot x ex dx
∴ x has an imaginary value. II I
Hence, no extreme value of x exist. = − cot x ex − ∫ (− cot x ) ex dx
log x
151. Let y= − ∫ cot x ex dx + c
x
1 = − cot x ex + c
x ⋅ − log x
dy x 1 − log x 155. We know that, if
⇒ = =
dx x2 x2 I n = ∫ sin n x dx, then
dy
Put = 0 ⇒ log x = 1 sin n − 1 x cos x n − 1
dx In = − + In − 2
⇒ x=e n n
2  1 where n is a positive integer.
x  −  − (1 − log x ) 2x
d2 y  x ⇒ nI n − (n − 1) I n − 2 = − sin n − 1 x cos x
Now, 2
=
dx ( x 2 )2 π 1
(3 − 2 log x ) 156. Let I = ∫ dx
=− 1 + sin x
0
x3 π 1
 d y
2
−(3 − 2) 1 =∫ dx
⇒  2 = = − 3 < 0, maxima 0 x
 dx  ( x = e ) e3 e 2 tan
1+ 2
1 x
Hence, maximum value at x = e is . 1 + tan 2
e 2
x
152. Given, z = tan ( y + ax ) + y − ax π
sec 2
2 1 =∫ 2 dx
⇒ zx = sec ( y + ax ) a + (− a) 0 2
2 y − ax  x
1 + tan 
 2
⇒ zxx = 2 sec 2 ( y + ax ) tan ( y + ax )a2
x 1 x
1 (− a2 ) Put tan = t ⇒ sec 2 dx = dt
+ 2 2 2
4( y − ax )3/ 2 ∞
∞ 2 dt  2 
2 1 ∴ I=∫ = −  =2
and z y = sec ( y + ax ) + 0 (1 + t )2
 1 + t 0
2 y − ax
π /4
⇒ z yy = 2 sec 2 ( y + ax ) tan ( y + ax ) 157. Area, A1 = ∫ sin x dx
0
1 = − [cos x]π0 / 4
−
4( y − ax )3/ 2 1 2 −1
=1 − =
∴ zxx − a2z yy = 0 2 2
y
dx
153. Let I=∫ y = cos x
( x + 1) 4 x + 3
Put 4 x + 3 = t 2 ⇒ 4 dx = 2t dt
y=
sin
1 t dt dt A1 A2
∴ I= ∫ 2 = 2∫
x
x′ x
2 t − 3  1 + t2 O π π
 + 1 t 4 2
 4  y′
π /2
= 2 tan −1 t + c = 2 tan −1 4x + 3 + c and area, A2 = ∫ cos x dx
π /4
 1  2 −1 Put sin z = t
= [sin x]ππ // 24 = 1 − =
 2  2 ⇒ cos z dz = dt
2 −1 2 −1 1 1
∴ A1 : A2 = : =1:1 ∴ ∫ t 2 dt = x − c ⇒ −
t
=x−c
2 2
⇒ − cosec z = x − c
158. Given table is
⇒ x + cosec ( x + y ) = c
t 0 2 4 6 8 10 160. Given, y = aex + bx ex + cx 2ex …(i)
v 0 12 16 20 35 60 On differentiating w.r.t. x, we get
10 − 0 y′ = aex + b( xex + ex ) + c( x 2ex + 2xex )
Here, h= =2
5 ⇒ y′ = aex + bxex + cx 2ex + bex + 2cxex
h
∴Total distance = [ f ( x 0 ) + 2{ f ( x1 ) + f ( x 2 ) ⇒ y′ = y + bex + 2cxex …(ii)
2
Again differentiating w.r.t. x, we get
+ f ( x 3 ) + f ( x 4 )} + f ( x 5 )]
2 y′ ′ = y′ + bex + 2c( xex + ex )
= [ 0 + 2(12 + 16 + 20 + 35) + 60]
2 ⇒ y′ ′ = y′ + bex + 2cxex + 2cex
= 166 + 60 = 226 ⇒ y′ ′ = 2y′ − y + 2cex …(iii)
dy [from Eq. (ii)]
159. Given, = sin ( x + y ) tan ( x + y ) − 1
dx Again differentiating w.r.t. x, we get
dy dz
Put x + y = z ⇒ 1 + = y′ ′ ′ = 2y′ ′ − y′ + 2cex
dx dx
dz ⇒ y′ ′ ′ = 2y′ ′ − y′ + ( y′ ′ − 2y′ + y )
∴ − 1 = sin z tan z − 1 [from Eq. (iii)]
dx
cos z ⇒ y′ ′ ′ − 3y′ ′ + 3y′ − y = 0
⇒ ∫ sin 2 z dz = ∫ dx

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EAMCET (Engg.

) • Solved Paper 2009 | 1

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