Professional Documents
Culture Documents
Flow Data & Concept of Loading
Flow Data & Concept of Loading
The contents in this chapter are mainly applicable to treatment plant monitoring, but the main concepts
are also applicable to water quality monitoring (discharge of effluents in water bodies).
CHAPTER CONTENTS
2.1 The Importance of Flow Data and the Concept of Load . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
2.2 Measuring Flow Rates and Analysing Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
2.3 Using Flow Rates to Assess Performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
2.4 Check-List for Your Report . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
© 2020 The Authors. This is an Open Access book chapter distributed under the terms of the Creative Commons Attribution Licence (CC BY-
NC-ND 4.0), which permits copying and redistribution for non-commercial purposes with no derivatives, provided the original work is properly
cited (https://creativecommons.org/licenses/by-nc-nd/4.0/). This does not affect the rights licensed or assigned from any third party in this
book. The chapter is from the book Assessment of Treatment Plant Performance and Water Quality Data: A Guide for Students,
Researchers and Practitioners, Marcos von Sperling, Matthew E. Verbyla and Sílvia M. A. C. Oliveira (Authors).
doi: 10.2166/9781780409320_0021
Mass loads have the dimension of mass per unit time and are generally calculated as
g 3 g
m
Load = flow × concentration (2.2)
d d m3
If you want to express loads as kg/d, as is usually done, the value calculated in Equation 2.2 should be
divided by 1000 g/kg:
kg flow (m3 /d) × concentration(g/m3 )
Load = (2.3)
d 1000(g/kg)
Loads can also be expressed as kg/year, kg/h, g/h, g/min, or by any other suitable unit representing
mass over time, provided consistency is given to all units in the calculation. Concentrations can also be
expressed in other mass units, such as μg/L or ng/L, or even MPN/100 mL (MPN = most probable
Figure 2.1 The difference between the concentration and the loading of a pollutant. Each circle contains a
mass of 1 mg of the constituent.
number), if we are dealing with microorganisms; eggs/L, if we are studying helminths; and so on. The
concept of load can be applied to the influent and to the effluent of a treatment unit and is essential in
the evaluation of its performance.
A treatment unit can be affected in a somewhat similar way if it receives a small flow with a high
concentration or a high flow with a small concentration, provided the loads are the same. A comparable
comment can be made regarding the pollution potential from wastewaters discharged into a river:
sewage, with a high flow and low concentration, can have a similar impact of an industrial discharge,
with a small flow and a high concentration, in case both of the loads are the same. Of course, there are
hydraulic implications, directly associated with flow, but this general concept can be maintained when
making an analysis of the behaviour of a treatment unit.
In a treatment plant with several inputs and outputs in each treatment unit, it should also be understood
S. 12.3 that each concentration is directly associated with its respective flow. As will be seen in the section on mass
balances (Section 12.3), we can add or subtract flows and loads, but not concentrations.
In a mass balance (see Section 12.3) of several units in a treatment plant, if the load and flow are known,
the concentration can be estimated by simple rearrangement of Equation 2.3:
Example 2.1 shows how to undertake the calculation of a load based on values of flow and concentration.
For a more detailed description of mass loadings and some example problems, see Chapter 13 that deals with
C. 13 the loading rates applied to treatment units.
Flow rates are also used to determine appropriate dosing rates of chemicals used in treatment processes
such as coagulation and flocculation, as shown in Example 2.2.
Flow rate information can also let you know if the treatment system is operating under or over its design
capacity.
(a) Calculate the total load of a certain constituent in the influent to a treatment unit, given that
• concentration = 300 mg/L
• flow = 50 L/s
Solution:
Expressing flow in m3/d
(50 L/s) × (86,400 s/d)
Q= = 4320 m3 /d
1000 L/m3
The load is (Equation 2.3)
(300 g/m3 ) × (4320 m3 /d)
Load = = 1296 kg/d
1000 g/kg
(b) In the same works, calculate the concentration of another constituent in the influent to a treatment
unit, given that the influent load is 35 kg/d.
Example
EXAMPLE 2.2 USING FLOW RATES TO DETERMINE DOSING FLOW
RATES FOR COAGULANTS
Assume that a water treatment plant has determined that 15 mg/L of ferric chloride and 4 mg/L of
polymer are required to optimize the coagulation–flocculation process. Industrial ferric chloride is
supplied to the treatment facility in barrels at a concentration of 40% (40 g/100 mL or 400 g/L).
Industrial stock polymer, likewise, is supplied at a concentration of 50% (500 g/L). If the flow rate of
raw water coming into the system is constant at 300,000 m3/d, what flow rates should be provided
for ferric chloride and polymer?
Solution:
First, convert the units of the required concentrations of coagulants (ferric chloride and polymer) from
mg/L to g/m3 (remember, 1 mg/L = 1 g/m3). Then, multiply the required coagulant concentrations
by the design flow rate to get the loading of coagulant required. Then, divide that loading by the
concentration of the coagulant stock to calculate the required flow rate of coagulant that should be
dosed into the raw water.
• Ferric chloride
15 g/m3 × 300,000 m3/d = 4,500,000 g/d
(4,500,000 g/d)/(400 g/L) = 11,250 L/d = 7.81 L//min
• Polymer
4 g/m3 × 300,000 m3/d = 1,200,000 g/d
(1,200,000 g/d)/(500 g/L) = 2400 L/d = 1.67 L//min
to let the first side start to fill up again. Each time the device tips, a count
is registered by an electromagnetic sensor, allowing for the calculation
of the volume flowing per unit time throughout the day.
Advantages
• Simple operation
• Low cost
• May be more accurate than flow measurement in channels or weirs
in the case of very small flows
Disadvantages
• Requires a clearance for flow to fall into the device
25
show the differences between these different flow measurement structures and devices and the typical
applications for water, wastewater, and stormwater treatment systems.
The larger the relative volume of the equalization tank or basin, the more stable the concentration of
pollutants will be throughout the course of the day. Thus, when assessing treatment plant performance, it
is often useful to be able to predict the impact of flow equalization on the concentration of pollutants
(Example 2.3) (Metcalf & Eddy, 2003).
C. 12
Please note that in this example, we anticipate some concepts that will be detailed in Chapter 12, relative
to water and mass balances.
Use the flow data in the Excel spreadsheet associated with this example. Calculate the effect of a
50,000 m3 equalization basin on the following biochemical oxygen demand (BOD) concentrations:
Solution:
First, calculate average hourly flow rates and use those to determine the average volume of flow
entering the equalization basin each hour. The overall volume of water in the basin at any given time
is then computed by subtracting the average daily flow rate from the fluctuating hourly flow rate.
Finally, the BOD concentration leaving the basin (assuming the basin is well mixed) is calculated as
follows, where BODin and BODbasin are the influent and effluent concentrations of BOD to the
equalization basin, Vin is the volume entering the basin within an hour, and Vbasin is the volume of
water stored in the basin at time t or t − 1:
BODin,t Vin,t + BODbasin,t−1 Vbasin,t−1
BODbasin,t =
Vbasin,t−1 + Vin,t
Because the data set is very large, we will not show the calculations here, and you should consult the
Excel spreadsheet.
The results, shown in the plots below, demonstrate the smoothing effect of flow equalization on BOD
concentrations. The minimum and maximum concentrations (dry season) without equalization are 42
and 314 mg/L; with equalization, the minimum and maximum concentrations are 126 and 202 mg/L.
S. 9.5
The plotting position (PP) is determined using Equation 2.5, where R is the rank of the data point and n is
the total number of data points (this concept is further detailed in Section 9.5).
R
PP = (2.5)
n+1
The normal score is calculated in Excel using the command NORM.S.INV() and then referring to the PP
value. If the points connect to form a straight line, then the distribution may be considered to be normal. If
the points form a curved line, then the distribution may be log-normal, but you need to verify by plotting the
points on a log scale or calculating the log of the values and then plotting them on a normal scale. If
log-transformed points form a straight line, then the flow data may be considered to be log-normally
C. 8
distributed. In Chapter 8, we will present in a more formal way the procedures for assessing the
adherence of your data to a normal distribution and a log-normal distribution.
Example
EXAMPLE 2.4 DETERMINING THE DISTRIBUTION OF FLOW DATA
Use the data shown in the spreadsheet associated with this example. Determine the distribution of the
flow rate data collected daily over one year during wet and dry weather. Use the data to determine the
typical (mean) flow rates during each season, as well as the peaking factor associated with the 95th
percentile flow rates.
Solution:
Because the data set is very large, we will not show all the calculations here, and you should consult the
Excel spreadsheet.
First, rank the values from 1 to 365. Then, use the rank to calculate the plotting position (Equation
2.5). The following tables show the first few rows of data and then the few rows of ranked data for
each season with the calculated PPs and normal scores.
We have n = 184 data for the wet season and n = 181 data for the dry season.
=1/(184+1) =1/(181+1)
… … … … … … … … … … …
Below is a plot of the measured flow rates versus the plotting position, first on an arithmetic scale and
then on a logarithmic scale. The trend is curved on the arithmetic scale (top panel) and linear on the
logarithmic scale (bottom panel), which indicates that the data are closer to a log-normal distribution.
S. 5.6.4 Therefore, the geometric mean is a better representation of the typical flow rates for each season
(see Section 5.6.4 for the concept of geometric means).
Plots of the measured flow rates with respect to the normal Z score associated with their plotting
position on an arithmetic scale (above) and on a logarithmic scale (below). The shapes of the curves
indicate that the data are closer to a log-normal distribution.
The typical flow rates are calculated using the geometric mean, since the data are log-normally
distributed.
• Geometric mean wet weather flow rate: 410 m3/ h
• Geometric mean dry weather flow rate: 60 m3/ h
The peaking factors associated with the 95th percentile are determined using the plotting positions.
To get the 95th percentile peaking factors, divide the flow rate associated with the plotting position of
0.95 by the geometric mean flow rate for each season.
• Wet weather 95th percentile flow rate: 939 m3/ h
• Wet weather peaking factor = 95th percentile/geometric mean = 939/410 = 2.29
• Dry weather 95th percentile flow rate: 70 m3/ h
• Dry weather peaking factor = 95th percentile/geometric mean = 70/60 = 1.17
Use the data shown in the spreadsheet associated with this example. The spreadsheet contains
example flow rate measurements collected at the influent of a wastewater treatment facility during
seven random days in the dry season and seven random days in the wet season.
(a) Calculate the mean, minimum, and maximum daily flow rates and the mean, minimum, and
maximum hourly flow rates.
(b) Plot daily hydrographs showing wet and dry season conditions using the mean hourly flow rate
data from these seven random days.
(c) Calculate a flow rate peaking factor for wet conditions (compared to dry conditions) using the upper
99% prediction interval for data from the rainy season (assumed equal to the mean value plus three
times the standard deviation).
Flow rate data with respect to time of day for the dry and rainy seasons.
Mean hourly flow rates for the dry and rainy seasons, with error bars corresponding to the 95%
confidence intervals.
Upper limit of the 99% prediction interval for the hourly flow rates during the rainy season.
V
HRT = (2.6)
Q
Thus, flow rate data are used to calculate daily and seasonal variations in the theoretical mean HRT of a
treatment unit process. This can give you some insight regarding why the performance of a system may
fluctuate throughout the year. Example 2.6 shows an example of monthly mean HRTs calculated for a
wastewater treatment facility that utilizes waste stabilization ponds.
We present here only introductory concepts related to this highly important process variable. In
reality, due to mixing, the true retention time in a reactor is a distribution, rather than a single
value. Some water molecules move more quickly through the reactor, while others may stay around
C. 13
for longer before leaving in the effluent. The distribution of HRT can be estimated using data from
a tracer study. It is important to note that the actual mean HRT (calculated using data from a
tracer study) is often different from the theoretical mean HRT (e.g., V/Q). See Chapter 13 for
more details on this regard. In Section 13.2, we cover the concept of HRT in a thorough way,
including the factors that may lead to the actual mean HRT being different from the theoretical one,
calculated by Equation 2.6.
A waste stabilization pond system has an overall volume of 15,000 m3 and a flow rate that varies
throughout the year between 280 and 659 m3/d. Use the flow rate data in the associated
spreadsheet to calculate the mean theoretical hydraulic retention time (HRT) and plot that with
respect to the per cent BOD removal. Determine if the trend is for BOD removal to increase or
decrease with respect to increasing hydraulic retention times.
Using the flow rate data provided, the HRT ranged from 22.8 to 53.6 days, with lower retention times
corresponding with the months of December through April (see figure).
Mean theoretical hydraulic retention time for a waste stabilization pond system with respect to month of
the year.
When these retention times are plotted against the per cent BOD removal, there are some
indications that higher retention times may correlate with higher BOD removal values, which would
be expected. The more time wastewater stays inside the ponds, the more BOD degradation should
occur. However, you can also see that the data points show a wide scatter, and therefore, it is
difficult to conclude whether there is a significant correlation between HRT and BOD removal
C. 11 efficiency. This is a very important point, and it will be discussed in detail in Chapter 11 that deals
with correlation and regression analysis.
Per cent BOD removal versus mean theoretical hydraulic retention time for a waste stabilization
pond system.
water storage reservoirs may have retention times on the order of months. Underground water aquifers may
have retention times on the order of years or even decades.
Water levels in surface and groundwater reservoirs will often fluctuate throughout the year in a seasonal
pattern, storing more water during the winter when the demand is low, and drawing down the additional
storage during the summer months when the demand is high. In cases where hydraulic retention times
are measured on the order of days, weeks, or months, it may be necessary to account for water losses
and gains in order to accurately assess the concentrations of pollutants going into or coming out of the
facility.
A mass balance approach can be used to balance the water in a treatment unit. To start, define the
boundary of the system. Then, record flow rate measurements at all influent and effluent points of the
system. A comparison of the recorded flow rates entering the system and the recorded flow rates exiting
or withdrawn from the system over a long period of time will allow you to estimate net gains or losses
of water due to evaporation or rainfall.
Influent flow rates are commonly used for design purposes; however, for performance assessment, the
average influent and effluent flow rates should be used if available.
The subject of water balance is very important in treatment plant assessment and is covered in detail in
S. 12.2 Section 12.2.
✓ Check that the flow rates have been measured using appropriate devices depending on whether the
flow is through an open channel or a closed conduit.
✓ Flow rate data are collected either manually or using a data logger; verify whether it is important that
raw flow rate data are included in the appendix of the report.
✓ Verify whether the distribution of flow rate data has been assessed.
✓ Typical seasonal flow rates, daily flow rates, and hourly flow rates are calculated using the arithmetic
or geometric mean as necessary based on the assessment of the flow rate distribution.
✓ Hourly peaking factors are reported.
✓ Mean theoretical hydraulic retention times are calculated using the flow rates and the reactor volume.