Professional Documents
Culture Documents
Amber Perfumes, Compounds and Specialties
Amber Perfumes, Compounds and Specialties
Amber Perfumes, Compounds and Specialties
By Danute Pajaujis Anonis, Consulting Chemist Perfumer, Rego Park, New York
n two previous articles on amber notes in perfumey, we Extract No. 72 contains approximately 25 grams of the
Ihavediscussedamberodors o~mim~origin,name~Y absolute. Extract No, 36 contains approximately 12,5 grams
ambergris, and amber odors of vegetable origin, the main of the absolute,
ones being labdanum and cistus, 2 Here is a later formula, from a time when flower pomade
This article will discuss the development and applica- extracts were no longer used,
tions of amber perfumes, synthetic amber compounds and
wci~ties. Amber Extract4
It can be said in general that every good perfume com- ambergris
infusion 200
position should include amber in at least a trace amount; or musk tmq.in infusion 50
more, depending on the perfume we. ambrette seed 5T0in dcobol 50
vanilla Bourbon 10% in alcohol 50
Ambergris was used as a base in perfumes in the early
rose m. 5
stage of perfume~, but played a more important role as a CIarysage terpleless 2
background note and a fixative in fragrances. otis absolute 0.5
Later, when the demand for ambergris exceeded the aldebyde c-9 10% 0.5
supply, synthetic amber compounds were developed. Findfy, alcohol c-9 1
rose absolute 5
research on natumf fmatives identified new ambeqqis com-
j=min absolute 3
ponents. They were close in odor to naturaf ambergris, and tuber.,. absolute P.1’tidly
they played a role in the development of amber specialties. demloriz,sd 2
akobol 90% q, 1
Amber Perfumes
Early amber perfumes were based on natural ambergris The following amber perfume example uses Iabdanum.
infusions and flower pomade extracts, including flower
absolutes. When aroma chemicals became available, afcobols ExtractNo. !37’75(AmbreantiqueCoty type)
and afdehydes were used to enhance the top note of the j-reinliquid
S.A. 250
perfume extract. The following formula may serve as an extrodor labdanum 150
me liquid S.A. lfm
example.
n+diomne ‘w
Amber PerfumeHF3 orris concrete 80
ambrette seed w
ambergrisinfusion 100 cm3
be,ganmt 60
musk Tonquin infusion 20 “
benzoin resinoid 50
civet infusion 25 “
vanilla rmimid 50
vmilla infusion 20 “
sandakvmd E.]. 40
ambrette seed infusion 10 “
vetiver Bowbm 3s
anbrei.e synthetic 5% solution 25 ‘$
opoponzxminoid 25
rose pomade extract No. 72 500 “
tonka resimid 10
j=~in pom~e e~ract NO 36 100 “
tuber.,. pomade extract N.. 36 200 $’ 1,030
rose absolute ~“ ,$ wnbergrk i“fusioi. 306
~ $, alcohol 9496% 8,7(YJ
j=min absoblte
tubems. absolute 6 “
10,030
m,. otto 15 “
alcohol c-9 zg
aldehyde c-9 25 drops As more aroma chemicals became available, they were
ddehyde C-8 lo ,, used in amber perfumes. The folfowing illustrates this.
For the top note For the floral note Other fixatives and Trace components
alcohol C-a contributors to the
citronellol angelica root
balsamic note
alcohol C-9 nerol ambrette seed
amyl benzoate
aldehyde C-9 phenyl ethyl alcohol cardamom
amyl cinnamate
aldehyde C-10 rhodinol celery
benzoin resinoid
aldehyde C-11 (enic) rose otto clary sage terpeneless
coumarin
bergamot cyclamen aldehyde hyssop
dimethyl hydmquimme
hnalyl acetate jasmin absolute nutmeg
ethyl vanillin
For nuances jasmin synthetic tuberose (partially
heliotropic
eugenol neroli Bigarade decolonized)
isobutyl cinnamate
farnesol hydroxycitronellal
oakmoss resinoid
geranium For wocdy notes
otibanum absolute
methyl naphthyl ketone cedarwood obbanum resinoid
?methykonone sandalwood opoponax resinoid
ortis patchouli Peru baisam
ikone patchoulol tolu balsam
vetiver vanilla resinoid
vetiverol methyl cinnamate
Animal fixativas musk ambretie
castoreum resinoid musk ketone
civet synthetic vanillin
Iabdamun absolute or Iabdan.m fractions Ambedyn (Quest), to cite a few. Today, isomer mixtures of
(in which the acrid md resinous odors of the this furanderivative prcwideless expensive amber notes.
head fraction b.,. been removed) This was discussed in greater detaif in the first aticle on
civet absolute
amber notesl (in which, inadvetiently, the ending of the
.astore.m absolute
cypress oil ketones chemical name for Ambrinol was misprinted as “octanile”).
dw.bydm mphtbylfmm.ldehyde
tetmbydm napbtbylawtaldehyde
Dermatological Considerations
diisopmpyl benzaldebyde According to IFRA’s Code of Practice, several components
diis.pmpyl ethylgly.id.ate
of traditional amber compounds cause sensitization or are
dibrmmbut)d meta.resylnmthyletber
unyl .inmnmte phototoxic. Some ofthese components tbereforehave to be of
high purity or specially processed. Others ae to be used in
Some ambergris substitutes were built on an olibanum limited percentage or are to be entirely eliminated, Among
and cistus base to which hydroxycitronelkd and a small such perfume materiafs ae the folfowing
amount of eugenol were added. For the sweet, bafsarnic
● Angelica root-limited to3.9%in any compound
note, Peru balsam, benzoin resinoid and vanillin or ethyl
used in products applied toskinexposed to sun.
wmiflin were used.
Later, basic research on ambergris revealed new compo- . Bergamot-limitedto 0.4% inproducts usedon
nents of natural ambergris. They rendered truer natural skin exposed to sunshine. Forthe expressed oil
ambergris notes, and were used in amber specialties. with terpenes parthfly or totafly removed, the limit
Among the first specialties of this kind were Grisambrol depends on the concentration of terpenes.
by Firmenich, based on a-Ambrinol (2-hydroxy-2,5,5- ● Farne801-minimum 96% of famesol isomers.
trimethyl octafine), and Fixateur 404 (Firmenich), in which
. HydroxycitroneUu—limitedto5% in fragrance
Ambrox (dodecahydrotrimethyl naphtho furan) was used.
compounds.
In the 1980s, Ambrinol and Ambrox became available
per se. Other perfume houses began to produce Ambrox, ● Cinruzmic &oho-limitedto8% inam.mmer
using various processes It became known under various prcducts.
trade names, such as Ambmxan (Henkel), Amberiff (IFF), . Musk ambrette—should not be used as fragrance
component (as per 28th Amendment ).
● Oakmoss—limited to O.670 in consumer products.
. Opopona+xtracts anddistillat escmly,limitedto
0.6% in consumer products.
. Peru bakam+xtract sanddistillate sonly,limited
to 0.4% in consumer products.
Appllcstion
In the past, natural ambergris was used. Today, new
ambergris derivatives and specialties are usedin modem
fragrances.
Natural ambergris is compatible witb musk and civet
odors, to which it contributes sweetness. Ambergris afso
refreshes and underlines rose odors. The same can be said
of the new ambergris replacements.
While ambergris infusions were suitable for powder and
hair lotion perfumes, they were of no vafue in soap. Lab-
danum or cistus resirmids or synthetic amber compounds
were used in soap perfumes Of the earlier types, Ambac
Chypre, Erneraude, Origan, Flaursde Tabacand Chand
No. 5maybementioned. Among single flower soap per-
fumes are hyacinth, jasmin, lilac, and rose, to single out a
few, Amber also blends well with patchmdi, lavender and
pine notes. Today’s soap perfumes have more complex
bouquets and contain fewer natural perfume materials than
past soap fragrances.
Earlier jasmin-mse perfumes were based on soft amber
backgrounds. Later, Chypra and Origcm perfume types
were underlined with amber notes. Amber is also used in
foug~re, tobacco, Cuirck Russit?, Peau dEspagne, ”oriental Amber perfumes per se have lost their appeal in our time,
and woody (light amber note) perfumes, as well as in many but the amber note is indispensable in women’s fragrances
other fantasy bouquets. and in many men’s fragrances, Amber remains both a vafuahle
Amber compounds and specialties also find application background note and a fmative in perfumery
in fragrances with pronounced green notes, such as Ma
References
Griffe, Gardaia and more modern green-type fragrances.
Some examples of older and more recent women’s fra- Address correspondence to Danute Pajaujis Anonis, 98-41 64th
Road, #6F, Rego Park, NY 11374 USA.
grances containing amber are: Quelques Fkws, Shalirmzc
Nuitde Nodl, Cabochard, S&nccx, Kde Krizia, ~ai Ost!, 1. DPAnonis, Peff&F/av20(l) 7-11(1995)
2. DPAnonis, Peti&F/av20(2) 43-46(1995)
Flew-s h Fletms, ]ardanel, Fidgi, Auduce, Magic Noic ]azz,
3. H Fouquet, La TEhniquo Moderne et /es Fomudes de la
Azzaro, Nocturnes, f3alt?che, Cristallt?, Obsession, Balestra, Pa ffumerie, Paris and I_@ga Ubraitie Polylechnique Ch. B6ranger
TrckoC Poison and Sarmara. (1951 )p183
Of the men’s fragrances, Gray Flannel, Haktcm 101, 4. RCerbelaud, Formulaire do Parfumerie, Paris Etitions Op6ra
HaktotI Limited, Gentleman, Hero, Oleg Ca.ssini and Ver- (1951 ) pp 342-343
5. 0 Gerhardt, Das Komponieren in der Parfuemede, Leipzig:
svs maybe mentioned.
Akademische Verlagsgesellschaft MBH (1 931 ) p 175
In the simpler age of men’s fragrances, when dean odors 6. RMGaUefoss6, Formu/aire de Patiumerie etde Cosm6tologie,
were preferred, amber combined with lavender, bergamot Paris Ghardot andCie(195o) pp 147.146
and clary sage provided a base for shaving cream fragrances, 7. US Pat4,162,266, DHelmliger and PNaegel (July 24, l979),
assigned to Givaudan Corporation; ct Fragrances and flavors,
recent developments, Chemical T%hnology Review No 156,3
Torrey, ed, Noyes Data Corporation (1980)pp 170-171
‘Oti@lly leatherW=imbuedwithcivet,windyand mber calms.Thisledt. the
nan.s Cuir de R.ssiemd Pew dfipagrus vii mk andpew, twoFrenchworthfor 6. Gerhardt, p294
leather., 9. Cetbelaud, p549 B