+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + +
+ + ASPEN PLUS CALCULATION REPORT + +
+ + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

ASPEN PLUS IS A TRADEMARK OF HOTLINE:

ASPEN TECHNOLOGY, INC. U.S.A. 888/996-7100
781/221-6400 EUROPE (44) 1189-226555

PLATFORM: WIN-X64 APRIL 18, 2024

VERSION: 39.0 Build 116 THURSDAY
INSTALLATION: 3:51:25 P.M.

ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE I

ASPEN PLUS (R) IS A PROPRIETARY PRODUCT OF ASPEN TECHNOLOGY, INC.

(ASPENTECH), AND MAY BE USED ONLY UNDER AGREEMENT WITH ASPENTECH.
RESTRICTED RIGHTS LEGEND: USE, REPRODUCTION, OR DISCLOSURE BY THE
U.S. GOVERNMENT IS SUBJECT TO RESTRICTIONS SET FORTH IN
(i) FAR 52.227-14, Alt. III, (ii) FAR 52.227-19, (iii) DFARS
252.227-7013(c)(1)(ii), or (iv) THE ACCOMPANYING LICENSE AGREEMENT,
AS APPLICABLE. FOR PURPOSES OF THE FAR, THIS SOFTWARE SHALL BE DEEMED
TO BE "UNPUBLISHED" AND LICENSED WITH DISCLOSURE PROHIBITIONS.
CONTRACTOR/SUBCONTRACTOR: ASPEN TECHNOLOGY, INC. 20 CROSBY DRIVE,
BEDFORD, MA 01730.
TABLE OF CONTENTS

RUN CONTROL SECTION.................................... 1

RUN CONTROL INFORMATION........................... 1

FLOWSHEET SECTION...................................... 2
FLOWSHEET CONNECTIVITY BY STREAMS................. 2
FLOWSHEET CONNECTIVITY BY BLOCKS.................. 2
COMPUTATIONAL SEQUENCE............................ 2
OVERALL FLOWSHEET BALANCE......................... 2

PHYSICAL PROPERTIES SECTION............................ 3

COMPONENTS........................................ 3

U-O-S BLOCK SECTION.................................... 4

BLOCK: B2 MODEL: HEATX..................... 4
 HEATX COLD-TQCU B2 TQCURV INLET............. 7
HEATX HOT-TQCUR B2 TQCURV INLET............. 8

STREAM SECTION......................................... 9
EG-IN EG-OUT F-IN F-OUT........................... 9

PROBLEM STATUS SECTION................................. 10

BLOCK STATUS...................................... 10
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 1

RUN CONTROL SECTION

RUN CONTROL INFORMATION

-----------------------

THIS COPY OF ASPEN PLUS LICENSED TO NATIONAL INSTITUTE OF TE

TYPE OF RUN: NEW

INPUT FILE NAME: _2209zsx.inm

OUTPUT PROBLEM DATA FILE NAME: _2209zsx

LOCATED IN:

PDF SIZE USED FOR INPUT TRANSLATION:

NUMBER OF FILE RECORDS (PSIZE) = 0
NUMBER OF IN-CORE RECORDS = 256
PSIZE NEEDED FOR SIMULATION = 256

CALLING PROGRAM NAME: apmain

LOCATED IN: C:\Program Files\AspenTech\Aspen Plus V12.1\Engine\\xeq

SIMULATION REQUESTED FOR ENTIRE FLOWSHEET

ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 2

FLOWSHEET SECTION

FLOWSHEET CONNECTIVITY BY STREAMS

---------------------------------

STREAM SOURCE DEST STREAM SOURCE DEST

F-IN ---- B2 EG-IN ---- B2
EG-OUT B2 ---- F-OUT B2 ----

FLOWSHEET CONNECTIVITY BY BLOCKS

--------------------------------
 BLOCK INLETS OUTLETS
B2 EG-IN F-IN EG-OUT F-OUT

COMPUTATIONAL SEQUENCE
----------------------

SEQUENCE USED WAS:

B2

OVERALL FLOWSHEET BALANCE

-------------------------

*** MASS AND ENERGY BALANCE ***

IN OUT RELATIVE DIFF.
CONVENTIONAL COMPONENTS (KMOL/HR )
DICHL-01 87.3354 87.3354 0.00000
ETHYL-01 161.112 161.112 0.00000
TOTAL BALANCE
MOLE(KMOL/HR ) 248.448 248.448 0.00000
MASS(KG/HR ) 20560.0 20560.0 0.00000
ENTHALPY(CAL/SEC ) -0.782007E+07 -0.782007E+07 0.238188E-15

*** CO2 EQUIVALENT SUMMARY ***

FEED STREAMS CO2E 0.115104E+09 KG/HR
PRODUCT STREAMS CO2E 0.115104E+09 KG/HR
NET STREAMS CO2E PRODUCTION 0.00000 KG/HR
UTILITIES CO2E PRODUCTION 0.00000 KG/HR
TOTAL CO2E PRODUCTION 0.00000 KG/HR
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 3

PHYSICAL PROPERTIES SECTION

COMPONENTS
----------

ID TYPE ALIAS NAME

DICHL-01 C CCL2F2 DICHLORODIFLUOROMETHANE
ETHYL-01 C C2H6O2 ETHYLENE-GLYCOL
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 4

U-O-S BLOCK SECTION

BLOCK: B2 MODEL: HEATX

-----------------------------
HOT SIDE:
---------
INLET STREAM: EG-IN
OUTLET STREAM: EG-OUT
 PROPERTY OPTION SET: UNIFAC UNIFAC / REDLICH-KWONG
COLD SIDE:
----------
INLET STREAM: F-IN
OUTLET STREAM: F-OUT
PROPERTY OPTION SET: UNIFAC UNIFAC / REDLICH-KWONG

*** MASS AND ENERGY BALANCE ***

IN OUT RELATIVE DIFF.
TOTAL BALANCE
MOLE(KMOL/HR ) 248.448 248.448 0.00000
MASS(KG/HR ) 20560.0 20560.0 0.00000
ENTHALPY(CAL/SEC ) -0.782007E+07 -0.782007E+07 0.238188E-15

*** CO2 EQUIVALENT SUMMARY ***

FEED STREAMS CO2E 0.115104E+09 KG/HR
PRODUCT STREAMS CO2E 0.115104E+09 KG/HR
NET STREAMS CO2E PRODUCTION 0.00000 KG/HR
UTILITIES CO2E PRODUCTION 0.00000 KG/HR
TOTAL CO2E PRODUCTION 0.00000 KG/HR

*** INPUT DATA ***

FLASH SPECS FOR HOT SIDE:

TWO PHASE FLASH
MAXIMUM NO. ITERATIONS 30
CONVERGENCE TOLERANCE 0.000100000

FLASH SPECS FOR COLD SIDE:

TWO PHASE FLASH
MAXIMUM NO. ITERATIONS 30
CONVERGENCE TOLERANCE 0.000100000

FLOW DIRECTION AND SPECIFICATION:

COUNTERCURRENT HEAT EXCHANGER
SPECIFIED COLD OUTLET TEMP
SPECIFIED VALUE C 26.8500
LMTD CORRECTION FACTOR 1.00000
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 5

U-O-S BLOCK SECTION

BLOCK: B2 MODEL: HEATX (CONTINUED)

PRESSURE SPECIFICATION:
HOT SIDE PRESSURE DROP BAR 0.0000
COLD SIDE PRESSURE DROP BAR 0.0000

HEAT TRANSFER COEFFICIENT SPECIFICATION:

 HOT LIQUID COLD LIQUID CAL/SEC-SQCM-K 0.0203
HOT 2-PHASE COLD LIQUID CAL/SEC-SQCM-K 0.0203
HOT VAPOR COLD LIQUID CAL/SEC-SQCM-K 0.0203
HOT LIQUID COLD 2-PHASE CAL/SEC-SQCM-K 0.0203
HOT 2-PHASE COLD 2-PHASE CAL/SEC-SQCM-K 0.0203
HOT VAPOR COLD 2-PHASE CAL/SEC-SQCM-K 0.0203
HOT LIQUID COLD VAPOR CAL/SEC-SQCM-K 0.0203
HOT 2-PHASE COLD VAPOR CAL/SEC-SQCM-K 0.0203
HOT VAPOR COLD VAPOR CAL/SEC-SQCM-K 0.0203

*** OVERALL RESULTS ***

STREAMS:
--------------------------------------
| |
EG-IN ----->| HOT |-----> EG-OUT
T= 7.6850D+01 | | T= 5.3261D+01
P= 2.0265D+00 | | P= 2.0265D+00
V= 0.0000D+00 | | V= 0.0000D+00
| |
F-OUT <-----| COLD |<----- F-IN
T= 2.6850D+01 | | T= -3.3150D+01
P= 7.0927D+00 | | P= 7.0927D+00
V= 0.0000D+00 | | V= 0.0000D+00
--------------------------------------

DUTY AND AREA:

CALCULATED HEAT DUTY CAL/SEC 40366.7325
CALCULATED (REQUIRED) AREA SQM 2.9875
ACTUAL EXCHANGER AREA SQM 2.9875
PER CENT OVER-DESIGN 0.0000

HEAT TRANSFER COEFFICIENT:

AVERAGE COEFFICIENT (DIRTY) CAL/SEC-SQCM-K 0.0203
UA (DIRTY) CAL/SEC-K 606.5283

LOG-MEAN TEMPERATURE DIFFERENCE:

LMTD CORRECTION FACTOR 1.0000
LMTD (CORRECTED) C 66.5537
NUMBER OF SHELLS IN SERIES 1

PRESSURE DROP:
HOTSIDE, TOTAL BAR 0.0000
COLDSIDE, TOTAL BAR 0.0000
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 6

U-O-S BLOCK SECTION

BLOCK: B2 MODEL: HEATX (CONTINUED)

 *** ZONE RESULTS ***

TEMPERATURE LEAVING EACH ZONE:

HOT
-------------------------------------------------------------
| |
HOT IN | LIQ | HOT OUT
------> | |------>
76.8 | | 53.3
| |
COLDOUT | LIQ | COLDIN
<------ | |<------
26.8 | | -33.2
| |
-------------------------------------------------------------
COLD

ZONE HEAT TRANSFER AND AREA:

ZONE HEAT DUTY AREA LMTD AVERAGE U UA

CAL/SEC SQM C CAL/SEC-SQCM-K CAL/SEC-K

1 40366.733 2.9875 66.5537 0.0203 606.5283

ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 7

U-O-S BLOCK SECTION

HEATX COLD-TQCU B2 TQCURV INLET

-------------------------------------
PRESSURE PROFILE: CONSTANT2
PRESSURE DROP: 0.0 BAR
PROPERTY OPTION SET: UNIFAC UNIFAC / REDLICH-KWONG

-----------------------------------------------------
! DUTY ! PRES ! TEMP ! VFRAC !
! ! ! ! !
! ! ! ! !
! ! ! ! !
! CAL/SEC ! BAR ! C ! !
! ! ! ! !
!============!============!============!============!
! 0.0 ! 7.0927 ! 26.8500 ! 0.0 !
! 1922.2254 ! 7.0927 ! 24.1351 ! 0.0 !
! 3844.4507 ! 7.0927 ! 21.4001 ! 0.0 !
! 5766.6761 ! 7.0927 ! 18.6461 ! 0.0 !
! 7688.9014 ! 7.0927 ! 15.8741 ! 0.0 !
!------------+------------+------------+------------!
! 9611.1268 ! 7.0927 ! 13.0852 ! 0.0 !
! 1.1533+04 ! 7.0927 ! 10.2804 ! 0.0 !
! 1.3456+04 ! 7.0927 ! 7.4607 ! 0.0 !
! 1.5378+04 ! 7.0927 ! 4.6269 ! 0.0 !
! 1.7300+04 ! 7.0927 ! 1.7799 ! 0.0 !
!------------+------------+------------+------------!
! 1.9222+04 ! 7.0927 ! -1.0795 ! 0.0 !
! 2.1144+04 ! 7.0927 ! -3.9504 ! 0.0 !
! 2.3067+04 ! 7.0927 ! -6.8322 ! 0.0 !
! 2.4989+04 ! 7.0927 ! -9.7240 ! 0.0 !
! 2.6911+04 ! 7.0927 ! -12.6253 ! 0.0 !
!------------+------------+------------+------------!
! 2.8833+04 ! 7.0927 ! -15.5355 ! 0.0 !
! 3.0756+04 ! 7.0927 ! -18.4538 ! 0.0 !
! 3.2678+04 ! 7.0927 ! -21.3798 ! 0.0 !
! 3.4600+04 ! 7.0927 ! -24.3129 ! 0.0 !
! 3.6522+04 ! 7.0927 ! -27.2526 ! 0.0 !
!------------+------------+------------+------------!
! 3.8445+04 ! 7.0927 ! -30.1984 ! 0.0 !
! 4.0367+04 ! 7.0927 ! -33.1500 ! 0.0 !
-----------------------------------------------------
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 8

U-O-S BLOCK SECTION

HEATX HOT-TQCUR B2 TQCURV INLET

-------------------------------------
PRESSURE PROFILE: CONSTANT2
PRESSURE DROP: 0.0 BAR
PROPERTY OPTION SET: UNIFAC UNIFAC / REDLICH-KWONG

-----------------------------------------------------
! DUTY ! PRES ! TEMP ! VFRAC !
! ! ! ! !
! ! ! ! !
! ! ! ! !
! CAL/SEC ! BAR ! C ! !
! ! ! ! !
!============!============!============!============!
! 0.0 ! 2.0265 ! 76.8500 ! 0.0 !
! 1922.2254 ! 2.0265 ! 75.7492 ! 0.0 !
! 3844.4507 ! 2.0265 ! 74.6463 ! 0.0 !
! 5766.6761 ! 2.0265 ! 73.5412 ! 0.0 !
! 7688.9014 ! 2.0265 ! 72.4340 ! 0.0 !
!------------+------------+------------+------------!
! 9611.1268 ! 2.0265 ! 71.3245 ! 0.0 !
! 1.1533+04 ! 2.0265 ! 70.2128 ! 0.0 !
! 1.3456+04 ! 2.0265 ! 69.0988 ! 0.0 !
! 1.5378+04 ! 2.0265 ! 67.9826 ! 0.0 !
! 1.7300+04 ! 2.0265 ! 66.8642 ! 0.0 !
!------------+------------+------------+------------!
! 1.9222+04 ! 2.0265 ! 65.7435 ! 0.0 !
! 2.1144+04 ! 2.0265 ! 64.6205 ! 0.0 !
! 2.3067+04 ! 2.0265 ! 63.4951 ! 0.0 !
! 2.4989+04 ! 2.0265 ! 62.3675 ! 0.0 !
! 2.6911+04 ! 2.0265 ! 61.2375 ! 0.0 !
!------------+------------+------------+------------!
! 2.8833+04 ! 2.0265 ! 60.1052 ! 0.0 !
! 3.0756+04 ! 2.0265 ! 58.9705 ! 0.0 !
! 3.2678+04 ! 2.0265 ! 57.8334 ! 0.0 !
! 3.4600+04 ! 2.0265 ! 56.6939 ! 0.0 !
! 3.6522+04 ! 2.0265 ! 55.5521 ! 0.0 !
!------------+------------+------------+------------!
! 3.8445+04 ! 2.0265 ! 54.4078 ! 0.0 !
! 4.0367+04 ! 2.0265 ! 53.2610 ! 0.0 !
-----------------------------------------------------
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 9

STREAM SECTION

EG-IN EG-OUT F-IN F-OUT

-----------------------

STREAM ID EG-IN EG-OUT F-IN F-OUT

FROM : ---- B2 ---- B2
TO : B2 ---- B2 ----

SUBSTREAM: MIXED
PHASE: LIQUID LIQUID LIQUID LIQUID
COMPONENTS: KMOL/HR
DICHL-01 0.0 0.0 87.3354 87.3354
ETHYL-01 161.1125 161.1125 0.0 0.0
TOTAL FLOW:
KMOL/HR 161.1125 161.1125 87.3354 87.3354
KG/HR 1.0000+04 1.0000+04 1.0560+04 1.0560+04
L/MIN 155.4415 152.2912 117.7011 135.1027
STATE VARIABLES:
TEMP C 76.8500 53.2610 -33.1500 26.8500
PRES BAR 2.0265 2.0265 7.0927 7.0927
VFRAC 0.0 0.0 0.0 0.0
LFRAC 1.0000 1.0000 1.0000 1.0000
SFRAC 0.0 0.0 0.0 0.0
ENTHALPY:
CAL/MOL -1.0792+05 -1.0882+05 -1.2327+05 -1.2160+05
CAL/GM -1738.6797 -1753.2117 -1019.4554 -1005.6941
CAL/SEC -4.8297+06 -4.8700+06 -2.9904+06 -2.9500+06
ENTROPY:
CAL/MOL-K -99.4337 -102.1219 -54.8047 -48.6625
 CAL/GM-K -1.6020 -1.6453 -0.4533 -0.4025
DENSITY:
MOL/CC 1.7275-02 1.7632-02 1.2367-02 1.0774-02
GM/CC 1.0722 1.0944 1.4953 1.3027
AVG MW 62.0684 62.0684 120.9132 120.9132
ASPEN PLUS PLAT: WIN-X64 VER: 39.0 04/18/2024 PAGE 10

PROBLEM STATUS SECTION

BLOCK STATUS
------------

****************************************************************************
* *
* Calculations were completed normally *
* *
* All Unit Operation blocks were completed normally *
* *
* All streams were flashed normally *
* *
****************************************************************************