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C25 GRAND BTEST (ADV) CHEMISTRY PAPER-2

SINGLE CORRECT TYPE

Q.1 The reaction: A2 + B2 ⟶ 2AB, is bound to obey the following mechanism

k1
A2 ⇋ A + A (fast)
k−1
k2
A + B2 → AB + B (slow)
A + B ⟶ AB (fast)
The order of overall reaction is
(A) 3 (B) 2 (C) 2.5 (D) 1.5
Solution : (D)

k1 [A]2 k1
= ⇒ [A] = √ [A ]
k −1 [A2 ] k −1 2
Rate = k 2 [A][B]( r.d.s.)
k1
= k2 × √ [A ] × [B2 ]
k −1 2

k1
= k2 × √ × [A2 ]1/2 [B2 ]
k −1
1
⇒ Order of reaction = + 1 = 1.5
2
Q.2 On heating a mixture of Cu2 O and Cu2 S, we get
(A) Cu + SO2 (B) Cu + SO3 (C) CuO + CuS (D) Cu2 SO3
Solution : (A)
2Cu2 O + Cu2 S ⟶ 6Cu + SO2
Q.3 Borax is written as
(A) Na2 [B4 O5 (OH)4 ] ⋅ 8H2 O (B) Na2 B4 (OH)7 O2 ⋅ 3H2 O
(C) Na2 OB4 O8 H2 (D) Na2 B4 O17 H2 O
Solution : (A)

Q.4 Among the following substituted silanes the one which will give rise to cross linked silicone polymer
on hydrolysis is
(A) R 4 Si (B) R 2 SiCl2 (C) RSiCl3 (D) R 3 SiCl

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Solution : (C)
The cross linked polymers will be formed by RSiCl3

MULTIPLE CORRECT TYPE

Q.5 A plot of the number of neutrons (N) against the number of protons (P) of stable nuclei exhibits
upward deviation from linearity for atomic number, Z > 20. For an unstable nucleus having N/P
ratio less than 1, the possible mode(s) of decay is/are
(A) β− -decay (β emission) (B) Orbital or K-electron capture
(C) Neutron emission (D) β+ -decay (positron emission)
Solution : (BD)

Q.6 Aryl halides are practically inert towards nucleophilic substitution reactions. The reasons for this fact
are
(A) Because C − X bond has partial double bond character due to conjugation between lone pair of X
and π electrons of aromatic ring.
(B) No SN1 reaction because aryl carbocations are unstable
(C) No SN2 reaction because aromatic π electron cloud do not allow backside attack of Nu −
(D) Product obtained through nucleophilic substitution reactions are non aromatic
Solution : (ABC)

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Q.7 Find out the correct statement(s) :

Solution : (CD)

INTEGER TYPE
(Single Digit Answer)

Q.8 Consider the following statements and identify how many statements are correct.
(A) Ψ3,2,0 represent the orbital which has no angular node.
(B) Spin magnetic moment of Fe atom and Ni2+ ion are the same
(C) At given temperature intensity of radiations emitted from black body always keep on increasing
with decrease in wavelength.
(D) For a hypothetical electron moving in 2D, then only any two parameter can change out of r, θ
and ϕ.
(E) For 2px orbital, number of angular node or nodal plane are the same.

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(F) The actual electronic configuration of Cr([Ar]. 4s1 3d5 ) is more stable than theoretical electronic
configuration of Cr([Ar], 4s 2 , 3d4 ) due to both maximum multiplicity and maximum exchange
energy.
(G) The electromagnetic wave radiated from it's source ultimately dissipates away in space, but the
de-Broglie matter wave never gets separated from its source.
(H) Heisenberg's uncertainty principle can be applicable for any conjugate pair of variables (e.g.
momentum and position, energy and time).
(I) Sixth line of Balmer series in hydrogen atom belong to ultraviolet region of spectrum.
Solution : (6)
D, E, F, G, H and I are correct
(A) Ψ3,2,0 represent 3d2z (z) orbital
(B) Fe(26) ⋅ [Ar]4s 2 , 3d6 ⇒ 4 unpaired electron Ni2+ (26). [Ar]4s0 , 3d8 ⇒ 2 unpaired electron
(C) It first increases and then decreases
(D) For 2D motion, any two coordinate are required.
(E) Angular nodes and angular planes are the same
(F) For Cr[Ar]4s1 , 3d5 for both multiplicity and exchange energy an higher.
(G) Fact
h h
(H) Δ p. Δx ≥ 4π : ΔE ⋅ Δt ≥ 4π
1 1 1
(l) λ = 109678 [22 − 82 ]

Q.9 How many of the following are planar?

∙ (+)
C(CN)− + −
3 , CH3 (methyl radical), C H3 , H2 O, Polymeric BeH2 , Polymeric BeCl2 , B2 H6 , C2 H2 , NO2 , NO2 , NO2

Solution : (8)
∙ (+)
+
Planar C(CN)− −
3 , CH3 , C H3 , C2 H2 , NO2 , NO2 , NO2 , H2 O

Detailed Solution :
C(CN)−
3 is planar because negative charge is in conjugation

ĊH3 → sp2
+
CH3 → sp2
NO+ −
2 , NO2 , ṄO2 → planar,
H2 O → planar

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Q.10 1 mol of a monoatomic ideal gas adiabatically expands in vacuum then how many functions are
zero?
ΔSsystem , ΔSsurr , ΔSuniverse , ΔH, ΔT, ΔU w, q
Solution : (6)
Work done in vacuum = 0
q = 0 for adiabatic process
so ΔU = 0, ΔT = 0, ΔH = 0
ΔSsurr = 0
Q.11 NH2 COONH4 ( s) dissociate into 1 L container and equilibrium exists as
NH2 COONH4 (s) ⇌ 2NH3 (g) + CO2 (g)
equilibrium constant (Kp) of the reaction is 4. The total pressure of gases at equilibrium is
Solution : (3)
NH2 COONH4 (s) → 2NH3 + CO2 (g)
∆ 2p p
3
⇒ 4p = 4, p = 1
Q.12 How many of the following have standard heat of formation is zero.
(i) Br2(ℓ) (ii) CO2 (g) (iii) C(graphite) (iv) Cl2 (ℓ)
(v) Cl2(g) (vi) F2(g) (vii) F(g) (viii) I2(g)
(ix) S(monoclinic) (x) N2(g) (xi) P(Black) (xii) P(red)
xiii) CH4
Solution : (5)
Br2 (ℓ); C(graphite) ; F2(g) ; N2(g) : Cl2(g) are exist in most stable form so, it's standard heat of formation
is zero.
Q.13 Cu2 S ⟶ Cu2+ + SO2
What is the valency factor Cu2 S in above chemical equation.
Solution : (8)
+4
Cu+1
2 S
−2
⟶ Cu+2 + SO2
v. f = 2 + 6
=8

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NUMERICAL TYPE
(Questions Based on Paragraph)

Paragraph-1: For Q. No. 14 & 15

Aliphatic nucleophilic substitution is mainly of two type SN1 and SN2 ∙ SN2 reaction proceed with
strong nucleophile in polar aprotic solvent. 3∘ halides do not give SN2 reaction. Inverted products are
obtained in this reaction and mechanism of reaction occurs through the formation of transition state.
SN1 reaction proceed through the formation of carbocation in polar aprotic solvent. Solvent itself acts
as nucleophile in this reaction. Racemization takes place in SN1 reaction.

Q.14 Identify number of substrate those can give SN1 and SN2 reaction both.

Solution : (6)

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Q.15 How many substrates will show rearrangement during SN1 reaction?

Solution : (6)

Paragraph-2 : For Q. No. 16 & 17

The process whereby a hydrogen atom attached to the α-carbon of carbonyl compound moves to the
carbonyl oxygen atom is known as enolization or keto-enol tautomerism. Isomeric carbonyl and enol
structure are tautomers.

Normally, the carbonyl form is favoured but structural factor marked affect K T .
Q.16 Among the following compounds how many will show tautomerism?

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Solution : (8)
(a, c, e, g, h, i, j, k)
Q.17 Correct order of enol content is

(1) a > b > c > d (2) a > d > b > c (3) d > b > c > a (4) d > a > b > c
Write the correct option.
Solution : (2)

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