SS CPP 04 Physics Chemistry Mathematics 2020

CPP-04
SS JEE(M) &
ADVANCED
Physics
Chapterwise Practise Problems (CPP) for JEE (Main & Advanced)
Chapter - Moving Charges and Magnetism and Magnetism and Matter
Level-1
SECTION - A 3. The magnetic field at the centre of the circular loop

as shown in the figure, where a single wire is bent to
Straight Objective Type form a circular loop and also extends to form straight
This section contains multiple choice questions. Each sections
question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
R
1. A conductor of mass m and length  is placed hori-
zontally perpendicular to a horizontal uniform mag- 
netic field B. Suddenly a certain amount of charge is
passed through it, when it is found to jump to a height
h. The amount of charge that passes through the 0  1 
0 
conductor is (A) (B) 1 
2R 2R  2 2 
m gh 2m gh
(A) (B) 0   1  0   1 
B 3B (C) 1  (D) 1 
2R   2 2R   2
m 2gh
(C) (D) None of the above 4. A long cylindrical wire of radius ‘a’ carries a current i
B
distributed uniformly over its cross-section. If the
2. A wire of cross-sectional area A forms the four sides magnetic field at distance r and R from the axis have
of a square and is free to turn about an axis OO. If equal magnitude, then,
the stucture is deflected by an angle  from the ver-
tical when current i passes through it, in a magnetic Rr
field B acting vertically upward and density of wire is (A) a = (B) a = Rr
2
, the value of  is given by
(C) a = Rr / R + r (D) a = R2 / r
B
5. A circular conducting loop of radius R carries a current
O O
 
I. Another straight infinite conductor carrying same
current  passes through the diameter of this loop as
shown in the figure. The magnitude of force exerted
by the straight conductor on the loop is
2Ag
(A)  cot  l
iB l
2Ag o R
(B)  tan 
iB
A g
(C)  sin 
iB (A) 02 (B) 02
Ag 0  2 0  2
(D)  cos  (C) (D)
2iB 2 
(1)
Moving Charges and Magnetism & Magnetism and Matter Aakash Institute
6. A positively charged particle of charge ‘q’ travelling
along positive x-axis initially enters in a uniform
4m
magnetic field ‘B’ directed inward and is deflected a
distance y0 after travelling a distance x0 as shown in ××× ××× ×
the figure. Then the magnitude of linear momentum ×× × ××
× × × × ×R
of the particle is × × × × ××
××××××××
x x x x x x x x x x
y
x x x x x x x x x x (A) The block does not move
x x x x x x x x x x
y (B) The loop starts rotating about y-axis
x x x x x x x x x 0x
x x x x x x x x x x
x x x x x x x x x x (C) The loop moves down with constant velocity
x0
x xq x x x x x x x x
(D) The acceleration of the block is constant but not
zero
qBx0 qB  x02 
(A) (B)   x0 
2 2  y0  9. In a certain region uniform electric field E and

magnetic field B are present in the opposite
direction. At the instant t = 0, a particle of mass
(C)
qB 2
2y 0
x0  y02  qB 2
0
2
(D) 2y x0  y0   m carrying a charge q is given velocity v0 at an
angle , with the y axis, in the yz plane. The time
7. What is the magnetic field at distance y from the after which the speed of the particle would be
centre of the axis of a disc of radius r and uniform minimum is equal to
surface charge denstiy ? The disc spins with angular x
velocity .
z
y E  B
 y
r v0
mv 0 mv 0 sin 
(A) (B)
qE qE
0   r 2  2y 2 
(A)   2y 
3  r 2  y2  mv 0 cos  2m
 
(C) (D)
qE qB
0   r 2  y 2 
(B)   10. Suppose a hypothetical magnetic field exists in
3  r2  y2  
  space B  B0uˆ r , where ûr is a unit vector directed
0   r 2  2y 2  radially outward from a point P at a height h above

(C)   2y  the earth’s surface. A light charged particle has to
2  r 2  y2 
  perform uniform circular motion with the centre
(D) None of these above P, in the combined gravitational field of earth
and the hypothetical magnetic field with speed v
8. A block of mass 4m and a conducting square loop of and radius r. Height of the plane of motion from
mass m (with a cell of emf E and resistance R) are earth surface will be (h << Re i.e. radius of earth)
connected by a light insulating string passing over a
firctionless pulley as shown in the figure. The plane v2 4v 2
(A) h (B) h 
of the loop (initially at rest) is perpendicular to g g
magnetic field. As the system is released
4v 2 v2
(C) h (D) h 
g g
D:/ Math equation.pm6/aloke/Determinant (2)

Aakash Institute Moving Charges and Magnetism & Magnetism and Matter
11. A neutral particle at rest in a magnetic field decays dimension. If in the region x < 0 and x > d1 + d2
into two charged particles of different mass. The 
energy released goes into their kinetic energy. charge particle has velocity v  v 0i choose the
Then what can be the path of the two particles? proper relation.
Neglect any interaction between the two charges
 d1  d2
(A)  (B)   d
 d2 1
(A)
 2d1  2d2
(C)  (D)   d
 d2 1
SECTION - B
Multiple Correct Answer Type
This section contains multiple choice questions. Each

point of question has 4 choices (A), (B), (C) and (D) for its answer,
(B)
collision out of which ONE OR MORE is/are correct.
14. Consider a wire carrying a steady current, I placed

in a uniform magnetic field B perpendicular to its
(C) length. Consider the charges inside the wire. It is
known that magnetic forces do no work on isoated
charges. This implies that,
(A) motion of charges inside the conductor is

unaffected by B since they do not absorb energy
(D) None of these
(B) some charges inside the wire move to the surface
12. The space has electromagnetic field which is given as a result of B
 
as B  B0 k and E  E0 k . A charged particle
(C) if the wire moves under the influence of B, no
having mass m and positive charge q is given
work is done by the force
velocity v i at origin at t = 0 sec. The z-coordinate
0
of the particle when it passes through the z-axis (D) if the wire moves under the influence of B, no
(neglect gravity through motion) work is done by the magentic forces on the ions,
assumed fixed within the wire
22mE0 42mE0
(A) (B) 15. An observer A and a charge Q are fixed in a
qB02 qB02 stationary frame F1. An observer B is fixed in a
2mE0 4 2mE0 frame F2, which is moving with respect to F1
(C) (D)
qB02 qB02
A B
13. A charged particle having charge +q and mass m Q
enters in a region where magnetic field varies with x-
F1 F2
coordinate as :
0 x<0

B  k 0 < x < d1 (A) Both A and B will observe electric fields

k d1 + d2 > x > d1 (B) Both A and B will observe magnetic fields
0 x > d1 + d2 (C) Neither A nor B will observe magnetic field
where  and  are positive constant with appropriate (D) B will observe a magnetic field, but A will not
(3)
16. A wire frame ABCDEF is kept as shown in figure.
(A) A magnetic field B0 î will slow down rod
I is the current in the wire frame
(B) An electric field E0 ˆj will slow down rod
 
(C) An electric field E0  ˆj will slow down rod
(D) A magnetic field can not slow down the rod
19. Two charged particles A and B having charge +2q
and +q respectively are moving on the same circle
of radius r, with same angular velocity , in the
same direction. The angle between the radii joining
(A) The direction of magnetic field at ‘O’ due to the the particles to the centre of the circle is . Then
 i  j 
wire frame will be along  
 2 
(B) The direction of net magnetic field at P (0, a,

0) due to wire CD and EF will be along – ĵ
(C) The direction of net magnetic field at Q (a, 0, (A) the net magnetic field at the centre of the
3 0 q 
0) due to wire EF and CD will be along (  ĵ ) circle will be 
4 r
(D) The direction of net magnetic field at P(0, a, 0) (B) the net magnetic dipole moment of the system
due to wire AF and CB will be along (  î ) depends upon 
(C) the force acting on B due to the magnetic field
17. Figure shows cross section view of a infinite
produced by A. depends upon 
cylindrical wire with a cavity, current density is
 (D) the coulomb force applied by A on B will be
uniform j   j0kˆ as shown in figure
q2
y

80r 2 sin2
2
20. A particle of charge + q and mass m moves under
the influence of a uniform electric field E i and a uni-
x
a
form magnetic field B k , follows trajectory from P to
â  î
Q as shown in the figure. The velocities at P and Q
 
are v i and 2v j respectively. Which of the follow-
ing statement(s) is/are true ?
(A) Magnetic field inside cavity is uniform
 3 mv 2
(B) Magnetic field inside cavity along a (A) E =
4 qa
(C) Magnetic field inside cavity is perpendicular
 (B) Rate of work done by electric field at P is
to a 3 mv 3
(D) If an electron is projected with velocity v0 ĵ 2 a
y
inside the cavity it will move undeviated
v B
18. A charged rod having charge as shown is rotating P
with angular velocity  about a hinge at its centre. a
Q x
At the instant shown rod is along x-axis. Consider 2a
effect of field at the instant shown 2v
y (C) Rate of work done by electric field at P is not

zero.

– – – – – – + + + + + + x (D) Rate of work done by both the fields at Q is not
zero.
SECTION - C a a
(C) 3v 0 (D) 4v
Linked Comprehension Type 0
This section contains paragraph. Based upon this Paragraph for Question Nos 24 and 25
paragraph, some multiple choice questions have to be An infinitely long wire lying along z-axis carries a current
answered. Each question has 4 choices (A), (B), (C) and I, flowing towards positive z-direction. There is no other
(D) for its answer, out of which ONLY ONE OR MORE is/ current, consider a circle in x-y plane with centre at (2
are correct. meter, 0, 0) and radius 1 meter. Divide the circle in small
segments and let d denote the length of a small
Paragraph for Question Nos. 21 to 23
segment in anticlockwise direction, as shown.
Read the paragraph carefully and answer the following
y
questions :
y
1m d
x • •
(2,0,0)
I x
z
In the region between the plane z = 0 and z = a (a>0), the  
uniform electric and magnetic fields are given by  B.d  of the total magnetic field
24. The path integral 
 
  
E  E0 k  j ,B  B0i . The region defined by a  z  b B along the perimeter of the given circle is

contains only magnetic field B  B0 i . Beyond z > b no 0I 0I
(A) (B)
field exists. A positive point charge q is projected from the 8 2
2 qE0 a (C) 0I (D) 0
origin with velocity v o k . Assume its mass to be 3 2
v0 25. Consider two points A(3, 0, 0) and B(2, 1, 0) on
B  
21. The value of E0 such that the point charge moves
undeviated upto the plane z = a, is the given circle. The path integral  B.d  of the
A

v 0B 0 total magnetic field B along the perimeter of the
(A) (B) v0B0 given circle from B to A is
2
0I 1 0I 1
v 0B0 (A) tan1 (B) tan1
(C) v0B0 2 (D) 12 2 2 2
2
22. Given that the point charge moves undeviated upto 0I 1
(C) tan1 (D) 0
the plane z = a, the minimum value of b such that 4 2
the point charge reverses its initial direction, at t =
0, completely after passing through the region a  Paragraph for Question Nos. 26 and 27
z  b, is A beam of electrons has radius and contains ‘n’ electrons

4E0 a  4E0  per cubic meter moving with velocity v along the beam
(A) 3v 0B0 (B) a  1   (figure). Assume that a beam that is much longer than its
 3v 0B0  diameter forms a cylindrically symmetric distribution of
charge and current. The beam expands if the electric force
2E0 a  2E0 
(C) (D) a  1  exceeds the magnetic force. So long as the expansion is
3v 0B0 
 3v 0B0  slow, the approximations of cylindrical symmetry and
static fields remain valid
23. When the point charge just reverse its direction, all
the fields are switched off. Time taken by it to touch –e –e
the plane z = 0 from that instant is v v
–e v –e r
(A) a/v0 (B) a/2v0 v
(5)
26. What is electric field produced on the edge of the Paragraph for Question Nos. 31 and 32
beam?
A conducting wire is bend into a loop as shown in the
 ner  ner figure. The segment AOB is parabolic given by the equation
(A) E rˆ (B) E  2 rˆ y2 = 2x, while segment BA is a straight line x = 2.
40 0

 ner  ner The magnetic field in the region B  8k tesla and the
(C) E rˆ (D) E  2 rˆ current in wire is 2A
4 0 0
27. What is net force on the electron at the edge of

the beam?
2ne2r ne2r
(A)
0
 
1  00 v 2 rˆ (B)
2 0
 
1  0 0 v 2 rˆ
4ne2r ne2r
(C)
0
 
1  0 0 v 2 rˆ (D)
4 0
 
1  0 0 v 2 rˆ
31. The torque on the loop will be
Paragraph for Question Nos : 28 to 30
(A) 16 2N  m (B) 16N – m
A uniform and constant magnetic field

B  (20iˆ  30ˆj  50k)
ˆ Tesla exists in space. A charged (C) 18 2N  m (D) Zero
3 32. The magnetic field created by the current in the
 q  10
particle with charged to mass ratio    C/kg enters loop at point C will be
 m  19
this region at time t = 0 with a velocity 0  0 
(A)  k (B)  k
 4 8
V  (20iˆ  50ˆj  30k)
ˆ m / s . Assume that the charged
particle always remains in space having the given magnetic 0 2 
(C)  k (D) None
field. (Use 2  1.4 ). 
28. During the further motion of the particle in the
magnetic field, the angle between the magnetic field SECTION-D
 Matrix-Match Type
B and velocity of the particle
(A) remains constant This Section D have “match the following” type question.
(B) increases Question contains two columns, Col-I and Col-II. Match
the entries in Col-I with the entries in Col-II. One or more
(C) decreases entries in Col-I may match with one or more entries in
(D) may increase or decrease Col-II.
29. The frequency of the revolution of the particle in cycles 33. Two concentric coils of radius R and r(r<<R)carry
per second will be currents i1 and i2 respectively. The smaller coil is
rotated slightly by angle  about one of its
103 10 4 diameter (m=mass of inner loop). Then match the
(A) (B) following
 19  38
103 104
(C) (D)
 19 2 19
30. The pitch of the helical path of the motion of the
particle will be
  Column I Column II
(A) m (B) m
100 125
(A) Restoring torque on the (p) i1,i2
  inner loop depends on
(C) m (D) m
215 250

(B) Angular acceleration of (q) r field or combination of uniform fields in any direction.
the inner loop depends Choose the correct option(s) from column II which
on can result the given trajectory in column I.
Column I Column II
(C) Frequency of a oscillation (r) R y
of the inner loop depends
on
(A) (p) A uniform electric field
(D) Time period of oscillation (s)  x
of the inner loop depend only is present in
space
on
y
(t) m
34. A charge particle of charge 1C and mass 10gm is (B) (q) A uniform magnetic
moving with velocity 10iˆ m/s in horizontal plane x
field only is present in
consisting of magnetic field at 0.1kˆ T of width space
3
m and electric field 0.1 ˆj N/C of width d. y
2
Particle enters the magnetic field at t = 0
perpendicularly and follows the path as shown in (C) (r) A uniform gravitational
x
the figure and strikes the wall AB perpendicularly
at A(neglect gravity)
Parabola
field only is present
in space (which can
only act towards  ĵ
direction)
x
(D) z A helix touching (s)Combination of uniform
y axis periodically
Column-I Column-II
electric and uniform
5 3
(A) Time after which it (p) gravitational field is
2 present in space
strikes the wall (in sec)
(gravitational field can
(B) The width of electric field
(in m) (q) 10.00 only act towards  ĵ )
  15 3 (t) Combination of uniform

(C) The distance BA (r) electric field and
30 uniform magnetic field
(in m)
is present in space
(D) Acceleration while (s) 4.25
moving in the electric
field (in m/s2)
35. A charge particle is projected in an XYZ space with

initial velocity v0 î from the origin. The particle
follows the trajectory as shown in the figure in
column –I. Column –II contains the possible uniform
(7)
SECTION-E 38. A closed conducting loop, ACB carrying current 60
A is in the form of a semicircle AB of radius R and
Integer Answer Type
lying in xy-plane with its centre at origin as shown
This section contains Integer type questions. The answer 
to each of the questions is an integer.
in the figure. The magnitude of   Bdl for the circle
x2 + z2 = 3R2 in xz-plane due to current in curve AB
36. Three infinitely long thin wires each carrying current is n0. Find the value of n
 in the same direction are in x-y plane of a gravity
free space. The central wire is along the y-axis while
the other two are along x = ±d. If the central wire is
slightly displaced along z axis and released, show
that it will execute simple harmonic motion. The linear
mass density of the wire is . If the time period of
C
kd  I
this small oscillation is , then find the value
 0
of k.
37. Two circular rings each of radius a are joined together

39. An  particle is moving along a circle of radius R
such that their planes are perpendicular to each other
with a constant angular velocity . Point A lies in
as shown in the figure. The resistance of each half
the same plane at a distance 2R from the centre.
part of the ring is indicated. A very small loop of mass
Point A records magnetic field produced by the 
m and radius r carrying a current o. is placed in the
particle. If the minimum time internal between two
plane of the paper at the common centre of each
successive times at which A records zero
ring. The loop can freely rotate about any of its
magnetic field as mentioned above, is 2/9
diametric axes. If the loop is slightly displaced, find
seconds, then find angular speed  in radians/sec.
the time period of its oscillations. (Given ma =
20  0
)
2


Level-2
SECTION - A
Straight Objective Type
question has 4 choices (A), (B), (C) and (D) for its answer, OA = OB
out of which ONLY ONE is correct.
1. Charge particles having various velocities are sent (A) Will increase
through slit S1. They enter in a velocity filter where (B) Will decrease
uniform magnetic field of 0.1 T and uniform electric (C) Will remains the same
field 100 V/m exists, which are perpendicular to (D) May increase of decrease depending on the value
each other. Only a few particles emerge from the of r
thin slit S2 which is exactly in front of S1. Now 3. Two very long wires parallel to the z-axis and a dis-
they enter in a region where only uniform magnetic tance 4a apart carry equal current I in opposite di-
field of 0.1 T, pointing inward exists, and electric rections as shown in the figure. A cylinder of radius
a and length L has its axis on the z-axis midway
field is absent. If the particles strike the
between the wires. Calculate the net upwards mag-
photographic plate at a distance of 0.42 mm from netic flux through half of the curved cylindrical sur-
slit ‘S2’, the particle should be face above the xz plane.
 0IL  0IL ln3

(A) (B)
 
 0IL ln 2  0IL
(A) -particle (C) (D)
 
4. A neutral particle is initially a rest in a uniform
q 7  magnetic field B. the particle then spontaneously
(B) proton   9.6  10 C / Kg  decays into two fragments, one with a positive
m 
charge +q and mass 3m and the other with a
(C) Lithium ion (Li+1) negative charge –q and mass m. Neglecting the
interaction between the two charged particles and
(D) Sodium ion (Na+) assuming that the speeds are much less than
speed of light, determine the time after the decay
2. The figure shown the cross section of a long cylin-
at which the two fragments first meet. Both the
drical conductor through which a cylindrical hole of
charges have initial velocities in x-y plane and field
radius r is drilled with its centre at point A. O is the
is parallel to z-axis
centre of the conductor. If another identical hole were
to be drilled centred at point B while maintaining the 6m 2m
same current density the magnitude of magnetic field (A) (B)
qB qB
at O
8m 3m
(C) (D)
qB 2qB
(9)
5. A uniformly charged ring of radius R is rotated (A) 3A into the paper, 0.7 × 10–6 T
about its axis with constant linear speed v of each
of its particles. The ratio of electric field to (B) 2A out of the paper, 1.7 × 10–6 T
magnetic field at a point P on the axis of the ring (C) 3A out of the paper, 1.3 × 10–6 T
at a distance x = R from centre of ring is (c is
speed of light) (D) 2A into the paper, 0.7 × 10–6 T
c2 8. An electron of mass m enters perpendicularly into
(A) 
v a uniform magnetic field B with the speed v. The
v
v 2 side-ways deflection z of the electron in travelling
(B) through d = 1m along the flow is :
c O P
c x=R
(C)
v
v
(D)
c z
6. In the diagram shown, a non-uniform magnetic field
B = B0x has been applied in the direction shown.
A particle of mass m and charge –q is projected
with velocity u from origin toward +ve x-axis. The
displacement of the charged particle along x- d
direction when its velocity becomes parallel to y-
direction. mv m2 v 2 mv m2 v 2
(A)  1 (B)  1
mu Bq B2 q2 Bq B2 q2
(A) qB0
mv 2mv
y (C) (D)
Bq Bq
2mu
(B) 9. A non relativistic positive charge particle of charge
qB0
q and mass m is projected perpendicular to
uniform magnetic field B as shown. Neglecting
mu gravity calculate X-coordinate of point on screen at
(C) x
2qB0 which the charge particle will hit (Only the region
shown × has magnetic field directed into the plane
4mu
(D) r 3 mV
qB0 of the paper) : d  , where r 
2 qB
7. Two long straight parallel wires are 2m apart,
perpendicular to the plane of the paper. The wire A v
carries a current of 9.6 A into the paper and B x x x x x x x x B
carries a current, the magnitude and direction of d
x x x x x x x x
which are not known. But this current produces a
magnetic field at a point P such that the total field d
at P = 0. The magnitude and direction of the
Screen
current through B and magnetic field at C is x=0 x
A (A) 0.5 r
(B) 2r
1.6m (C) 2.5 r
2m (D) r
C
B
1.2m
(10/11)m
P
10. An infinite uniform current carrying wire is kept
along z-axis, carrying current 0 in the direction of
the positive z-axis. OABCDEFG represents a circle
(where all the points are equally spaced) whose
centre at point (4m, 0 m) and radius 4m as shown
 
in the figure.  B.d  0 0 in S.I. unit, then the
DEF
k
value of k is
(A) 0avce (B) 20avce
0 ace
(C) (D) 0/avce
v
SECTION - B
(A) 4 (B) 8 question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/are correct.
(C) 3 (D) 6
11. To manufacture a polyethlene film a wide band is 13. The current in coil (as shown in figure) is  (centres
pulled over rollers at v = 15 m/s. During this of all the circular loops lie at same point) and
process the film’s surface acquires a uniformly angular spread of coil is 90°, n is number of turns
per unit radian and R is radius of each turn
distibuted charge , mainly because of friction. An
(Assume that turns are very close)
electric field of strength 20 kV/cm can cause a
discharge in air. To avoid this maximum magnetic
field’s flux density B near the film’s surface may
be
0n
(A) B at common centre will be
2R
(A) 1.33×105 weber/m2 (B) 2.22×106 weber/m2
(C) 4.44×105 weber/m2 (D) 5.55×104 weber/m2 20n
(B) B at common centre will be
12. Water, having positive ions of charge ‘+e’ dissolved R
in it with concentration c (Number of ions/volume), n2R 2
falls from a tube of cross sectional area ‘a’ with a (C) Magnetic moment of loop will be
2
speed ‘v’ in a sieve such that water is not retained
in the sieve. The value of  B.d integrated over (D) Magnetic moment of loop will be 2nR 2
the upper circular part of the sieve will be : [ B

indicates the magnetic field produced by Na+ ions
and d is along the tangent on the periphery of
circular part of the sieve].
(11)
14. An infinitely long straight wire carrying a current I 16. Figure shows a square current carrying coil of edge
is partially surrounded by ABCD loop as shown in length L. The coil is placed in a region having a
figure, arc AD and BC have circular shape and the  By Bx
infinite wire passes through their centre C1C2. The magnetic field given by B  0 î  0 ˆj where B0
loop has a length L, radius R and carries a current L L
I2. The axis of the loop coincides with the wire, is a positive constant (A = cross section area of
ABCD plane and infinite length wire are coplanar. the coil)
Then
y
i
(A) If coil is free to rotate about x axis torque on

1
the coil is given by iAB0 î
2
(B) If coil is free to rotate about y-axis torque on
(A) Net force exerted on the loop by the wire is zero
(B) Net force exerted on the loop by the straight wire 1
coil is given by  iAB0 ˆj
2
0I1I2L
is , in the plane ABCD and towards AB (C) Resultant force on coil is zero
R
(C) Net force exerted on the loop by the wire is  
(D) Equation for the torque   B where  is
0I1I2L magnetic moment of coil is not valid on the coil
, in the plane ABCD and towards CD
R 17. Charge is sprayed onto a large non conducting
(D) Net torque acting on the loop, about axes C1C2 belt above the left hand roller. The belt carries
charge with a uniform surface charge density , as
is zero
it moves with a speed v between the rollers as
15. A charged particle of charge q, mass m is moving shown. The charge is removed by a wiper at right
with initial velocity v as shown in figure in a hand roller. For a point just above the sheet mark
uniform magnetic field – B k̂ . Select the correct the correct option
alternative/alternatives
0 v
(A) Magnetic field is , out of the plane of the
2
(A) Velocity of particle when it comes out from page, parallel to axis of roller
magnetic field v  v cos 60  î  v sin 60  ˆj (B) Magnetic field is 0, out of the plane of the
(B) Time for which the particle was in magnetic page, perpendicular to axis
m 0
field is (C) Electric field is perpendicular to the plane
3qB 2
vm of sheet
(C) Distance travelled in magnetic field is
3qB (D) If an electron moves parallel to V just above
(D) The particle will never come out of magnetic the sheet it will experience an upward
field magnetic force

18. A long cylindrical conductor of radius a has two coordinates as (0,0). Ring has mass m, radius r0 and self
cylindrical cavities of diameter a through its entire inductance L. Assume the acceleration due to gravity as
length as shown in cross-section in figure. A current g.
I is directed out of the page and is uniform throughout
the cross-section of the conductor. Then the magnetic
field in terms of 0, I,r and a is
0 I  2r 2  a2 
(A) at the point P1  
r  4r 2  a2 
19. Find the magnitude of current in the ring at a

0 I  2r 2  a2 
(B) at the point P1   vertical position z
r  4r 2  a2 
1 1
(A) B0 r02 z (B) B0 r02 z
 I  2r 2  a2  L L
(C) at the point P2 0  2 
r  4r  a2 
1 1
(C) B0r02 z (D) B0r02 z
0 I  2r 2  a2  2L L
(D) at the point P2  
r  4r 2  a2  20. Find the vertical coordinates z for equilibrium
position of the ring
SECTION - C
Linked Comprehension Type
mgL mgL
This section contains paragraph. Based upon this (A) (B)
paragraph, some multiple choice questions have to be 2B02 2r04 B02 2r04
answered. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out of which ONLY ONE OR MORE is/
mgL
are correct. (C) Zero (D)
4B0 2 2r0 4
A thin superconducting (zero resistance) ring is held above 21. Find the time period of SHM (for small
a vertical long solenoid as shown in the figure. The axis displacement along z-axis) of the ring
of symmetry of the ring is same to that of the solenoid.
The cylindrically symmetric magnetic field around the ring 1 2mL
(A) 
can be described approximately in terms of the vertical B0r02
and radial component of the magnetic field vector as Bz =
B0 (1 – z) and Br = B0r, where B0, a and  are positive
constants and z and r are vertical and radial position 1 2mL
(B) 
coordinates respectively. Initially plane of the ring is 2B0r02
horizontal, has no current flowing in it. When released, it
starts to move downwards with its axis still vertical. Initial
1 mL
coordinates of the centre of the ring ‘O’ is z = 0 and r = 0. (C)
B0r02 3
In the given diagram point O is on the axis and slightly
above the solenoid having vertical and radial position (D) Ring will not perform SHM
(13)
Paragraph for Question Nos. 22 and 23 24. The trajectory of motion of positive particle lies in
plane
A positively charged particle of mass m and charge q is
projected on a rough horizontal XY plane. Both electric (A) x-y plane (B) y-z plane
 (C) x-z plane (D) Cannot say
and magnetic fields are given by E  10kNˆ / C (into the
 25. The radius of curvature of motion of positive charged
plane) and magnetic field B  5kˆ tesla are present in
particle is given by
the region. The particle enters into the magnetic field at
(4,0,0) m with a velocity 50ˆj m/sec. The particle starts 2mv 0 4mv 0
(A) q JR (B) q JR
into a curved path on the plane. If coefficient of friction 0 0
1
 between particle and plane, then (qE = 2mg, g = 8mv 0 mv0
3 (C) q JR (D) q JR
10m/s2) 0 0
22. Radius of curvature of the path followed by particle, Paragraph for Question Nos. 26 to 28
initially, is The basic principle underlying the Hall effect is the Loretz
(A) 5 m (B) 2.5 m force. When an electron moves along a direction perpen-
dicular to an applied magnetic field, it experiences a force
(C) 1.25 m (D) 10 m acting normal to both the directions and moves in response
to this force and the force exerted by the internal electric
23. The time after which particle comes to rest, is
field. For an n-type, bar-shaped semiconductor, the carri-
(A) 5s (B) 4s ers are predominantly electrons of bulk density n. We
assume that the constant current I flows along the x-axis
(C) 3s (D) 1s
from left to right in the presence of a magnetic field toward
Paragraph for Question Nos 24 and 25 y-axis. Electrons subjected to the lorentz force initially
drift away from the current line toward the negative z-axis,
In a homogenous infinite solid cylindrical wire of radius
resulting in an excess surface electrical charge on the
R, there is a cylindrical and smooth cavity of radius R/
sides of the sample. This charge results in the hall volt-
2 whose axis is parallel to the conducting wire axis
age, a potential drop across the two sides of the sample.
and displaced relative to it by a distance R/2. A direct
current of density Jkˆ flows along the wire whose top The transverse voltage is the hall voltage vH and its magni-
tude is equal to IB/qnd, where I is the current, B is the
view and side view are shown in the figure. A positively
magnetic field, d is the sample thickness and q is the
charged particle with charge q and mass m is given
elementary charge. A silver ribbon lies as shown in the
velocity v 0 î , from point C. Given that the value adjacent figure. (z1 = 11.8 mm and y1 = 0.23 mm) carrying
a current of 120 A in the x-direction in a uniform magnetic
8mv0
 R2 and all type of collisions (if any) are perfectly field B = 0.95 T. If electron density is 5.85 × 1028/m3, then
0qJ
Y
elastic collisions
z
B
z1
R/2
I y X
I
• • C• y1
J
•
O• • x Z
C x
26. Magnitude of the drift velocity of electrons is
• (A) 2.35 mm/s (B) 4.7 mm/s
Axis of wire Axis of cavity (C) 7.05 mm/s (D) 9.4 mm/s

27. What is the magnitude and direction of electric Paragraph for Question Nos. 31 and 32
field?
Analog voltmeters and ammeters work by measuring the
(A) 4.5 × 10–3 V/m in + z dir torque exerted by a magnetic field on a current carrying
(B) 45 × 10–3 V/m ln – z dir coil. The reading is displayed by means of the deflection
of a pointer over a scale. The adjacent figure shows the
(C) 2.25 × 10–3 V/m + x dir essentials of a galvanometer, on which both analog
(D) 2.25 × 10–3 V/m ln – z dir ammetrs and analog voltmeters are based. Assume that
28. What is the value of hall voltage? the coil is rectangular and 2.1 cm high, 1.2 cm wide, has
(A) 53 mV (B) 53 V 250 turns and is mounted so that it can rotate about an
axis (into the page) in auniform radial magnetic field with
(C) 5.3 mV (D) 5.3 V
B = 0.23 T. For any orientation of the coil, the net mag-
Paragraph for Question Nos. 29 and 30 netic field through the coil is perpendicular to the normal
In the figure shown a uniform conducting rod of mass m vector of the coil (and thus parallel to the plane of coil) A
and length l is suspended in vertical plane by two spring SP provides a counter torque that balances the
conducting springs of spring constant K. Upper end of magnetic torque, so that a given steady current I in the
springs are connected to each other by capacitor of
coil results in a steady angular deflection . The greater
capacitance C. A uniform horizontal magnetic field (B0)
perpendicular to plane of springs exists in space. Initially the current is, greater the deflection is, greater the deflec-
rod is in equilibrium but if rod is pulled down and tion is, and thus greater the torque required of the spring.
released, it performs SHM. (Assume resistance of A current of 100 A produces an angular deflection of 28°.
springs and rod are negligible)
31. What must be the torsional constant K of the spring ?

(A) 2.6 × 10–8 Nm/degree
29. Find time period of oscillation of rod
(B) 5.2 × 10–8 Nm/degree
m 22
B l C
(A) 2 (B) 2 (C) 2.6 × 10–4 Nm/degree
2K 2K
(D) 5.2 × 10–4 Nm/degree
m  B2l2C m  B2l2C 32. If number of turns in coil are made half keeping other
(C)  (D) 2 parameters same (like area of coil, magnetic field
2K 2K
and torsional constant), then voltage sensitivity of
30. Choose correct options from following the galvanometer will:
(A) Electrical energy stored in capacitor is (A) Become half
maximum when rod is at its lower extreme
position (B) Become two times
(B) Electric energy stored in capacitor is maximum (C) Become one forth
when rod is at its mean position
(C) Current in rod in maximum at mean position of (D) Remains same
rod
(D) If magnetic field is switched off then mean
position of rod will change
(15)
the field is along
SECTION-D
x-axis.
Matrix-Match Type
(t) If a magnetic
This Section D have “match the following” type question.
Question contains two columns, Col-I and Col-II. Match the 
field B0 î  ˆj  kˆ 
entries in Col-I with the entries in Col-II. One or more entries
in Col-I may match with one or more entries in Col-II. is switched on,
33. Column–I shows four current carrying loops. The the torque
magnetic properties of the loops are given in
experience
Column-II. Match the properties in Coumn – II with
the corresponding loop(s) in Column-I.[Current values by loop is zero.
are adjusted so that magnetic moment has same
magnitude for all loops and values of a,b,c and d are
34. The figures in list-I show some charge and current
not equal.]
distribution with a charged particle projected in some
Column I Column II specific direction list II gives certain conditions which
(A) (p) The non-zero may exist in the subsequent motion of the charged
particle. match list I with list II and select the correct
components of
answer using the codes given below the lists :
the magnetic (Neglect gravity force on charged particle)
field of the loop Column I Column II
(A) A positively charged (p) Magnitude of
at O along the particle is projected acceleration of the
coordinate axis along the axis of two charged particle is
coaxial current carrying constant
are equal in
rings, carrying currents
magnitude. in opposite directions
(B) (q) The non-zero as shown
components of
the magnetic
moment of the
loop along the (B) Two long line charges (q) Kinetic energy of
having equal charge the charged
coordinate axis density , parallel to particle is
are equal in z-axis passing through constant
points A(a,0,0) and
magnitude . B(–a, 0, 0) and a
(C) (r) If uniform positive charge
projected along Y-axis
magnetic field is from point C(0, 2a, 0)
switched on, PE
of the loop is
least when the
field is along
x-axis.
(D) (s) If uniform
magnetic field is
switched on, PE
of the loop is (C) A positive charge is (r) Angular
maximum when projected from an momentum of

inside point on the the charged z
(B) (q) Net force on 
axis of a long solenoid particle about
at some angle  with the point of have no
axis as shown. projection is x-component
Charge does not hit constant y
+Q
the solenoid
x
r P
–Q
Dipole () is placed
symmetrically in front of a
long uniformly negatively
charged wire parallel

to x-axis, such that p is
(D) A positive charge (s) Path of the 
perpendicular to r
and dipole is kept parallel
projected from a point charged
to z-axis
particle
in between two large is straight (C) z (r) Net torque on 
parallel oppositely is along x-axis
charged horizontal plates
at some angle  with i
horizontal as shown.
y
Charge does not hit the
i
positive plate
x
A square current carrying

––––––––––– –
coil () is placed in
35. Column-I shows some charge distributions and
current distributions accompanied by their xy-plane with centre at
descriptions. Column-II shows the instantaneous origin and sides parallel to
characteristics. Here  symbolizes the system on
which results are to be obtained. x-axis and y-axis, and a
Column I Column II long wire placed parallel
(A) (p) Net force above square cutting z-axis
z on  is zero
E and parallel to x-axis
–
– –––––––
–
–++
(D) y (s) Net torque on 

––
y
++
x ++++++
is zero
+ B
Circular ring () half positive

and other half negative
placed in a uniform electric x
field, with centre at origin
(17)
A circular current coil () z
with one half in yz-plane
other half in xz-plane,
R o y
placed in a uniform
(D) i (s) None
magnetic field in
x
x-direction
SECTION-E
(t) Direction of
Integer Answer Type
magnetic dipole This section contains Integer type questions. The answer
moment of  to each of the questions is an integer.
   37. A conducting light string is wound on the rim of a

along   i  j 
  conducting ring (resistance = 0) of radius r and mass
m. Free end of string is connected to ceiling. A verti-
36. Column I shows four current configurations. Match cal large conducting smooth plane is always tan-
each entry of column I with those axes in column gent to the ring. The ring is released in a uniform
II along which the magnetic field at origin has magnetic field B. String and plane are connected to
positive component each other by resistance R as shown. the terminal
Column I Column II
mgR
[+ve velocity attained by centre of ring is . Find n
component nB2r 2
( > 0) of
magnetic field
at origin]
z
R o y
(A) i (p) x
38. Figure shows a square loop 10 cm on each side in
x the x – y plane with its centre at the origin. An infi-
z nite wire is at z = 12 cm above y-axis
i/2 z
R i i1 = 65A
o
(B) y (q) y
i
i/2 D
x 12 cm
A
z y
10 cm
R o y C
i B i2 = 78A
(C) (r) z x
x What is torque on loop due to magnetic force? If
torque is expressed as x × 10–7 N-m, find value of x/
360 ____

CPP-04
SS JEE(M) &
ADVANCED
ANSWERS
LEVEL-1
1. (C) 2. (A) 3. (A) 4. (B) 5. (B) 6. (C)
7. (C) 8. (D) 9. (B) 10. (A) 11. (B) 12. (A)
13. (A) 14. (B,D) 15. (A,D) 16. (A,B,C,D) 17. (A,C,D) 18. (C,D)
19. (A,C,D) 20. (A,C) 21. (B) 22. (B) 23. (B) 24. (D)
25. (B) 26. (D) 27. (B) 28. (A) 29. (B) 30. (D)
31. (D) 32. (D) 33. (A-p,q,r,s, B-p,r,s,t ,C-p,r,t, D-p,r,t) 34. (A-r, B-p ,C-s, D-q)
35. (A-p,q,s,t, B-q ,C-p,r,s, D-t) 36. (2) 37. (4) 38. (30) 39. (3)
LEVEL-2
1. (A) 2. (C) 3. (B) 4. (A) 5. (A) 6. (B)
7. (C) 8. (A) 9. (B) 10. (B) 11. (A) 12. (A)
13. (A,D) 14. (B,D) 15. (A,B,C) 16. (A,B,C,D) 17. (A,D) 18. (A,C)
19. (A) 20. (A) 21. (A) 22. (A) 23. (A) 24. (C)
25. (B) 26. (B) 27. (A) 28. (B) 29. (D) 30. (B)
31. (B) 32. (D) 33. (A-p,q,t, B-p,q,t ,C-p,q,t, D-p,q) 34.(A-p,q,r,s, B-r,s ,C-p,q, D-p)
35. (A-p,q,r, B-q,r,p, C-q,r,D-p,q,t) 36.(A-p,r, B-s ,C-p,q,r, D-p,r) 37. (4) 38. (2)
  
(19)
CPP-04
SS JEE(M) &
ADVANCED
Chemistry
Chapter - Chemical Kinetics
Level-1
SECTION - A (C) Only the first step of such reactions follows

zero order kinetics.
Straight Objective Type
(D) The rate of such reactions depends on the
This section contains multiple choice questions. Each intensity of radiations absorbed.
question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct. 4. The desorption of gas molecules from the
adsorbent surface obeys Arrhenius equation. The
1. Radon 220 decays to Bismuth 212 by the following average time upto which a N 2 molecule may
series of decay : remain adsorbed at Pt-surface at 400 K is
86 Rn
220
84 Po216  2 He4 ; T1/ 2  55 s [Given : Pre-exponential factor, A  1.25  108 s1 ;
Activation energy of desorption =16 Kcal ;
216
84 Po 82 Pb212  2 He4 ; T1/ 2  0.016s
e 20  5  108 ]
212
82 Pb 83 Bi212  1 e0 ; T1/ 2  10.6 hrs
(A) 0.25 sec (B) 4 sec
If certain mass of radon is allowed to decay in
certain container, after five minutes element with (C) 8 sec (D) 0.125 sec
greatest and least amount will respectively be : 5. Saponification of ethyl acetate (CH3COOC2H5) by
(A) Radon, bismuth (B) Polonium, lead NaOH is studied by titration of the reaction mixture,
have 1 : 1 molar ratio of the reactants. If 10 ml of 1 N
(C) Lead, bismuth (D) Bismuth, lead HCl is required by 5 ml of the solution at the start
and 8 ml of 1 N HCl is required by another 5 ml after
2. Two radioactive materials X1 and X2 have decay 10 minutes, then rate constant is––
constants 10 and  respectively. If initially they
have the same number of nuclei, then the ratio of 2.303 10
the number of nuclei of X1 to that of X2 will be 1/ (A) k  log
10 8
e after a time :
1 1 2.303 10
(A) (B) (B) k  log
10 11 10 2
11 1
(C) (D) 1 1 1 
10 9 (C) k  
10  8 10 
3. Which of the following statement is incorrect for a
photochemical reaction ?
1 1 1 
(D) k  
(A) Photochem ical reactions are complex 10  2 10 
reactions.
(B) Overall order of photochemical reactions is

always zero.
(1)
Chemical Kinetics Aakash Institute
6. For the reaction, A (g) + 2B (g)  C (g) + D (g) 10. The half-life of the nuclide 220Rn is 54.5s. What mass
of radon is equivalent to 1 millicurie (mci)?
dx
 k  A B (A) 1.06 × 10–15 kg (B) 1.26 × 10–16 kg
2
dt
(C) 1.36 × 10–12 kg (D) 2.46 × 10–8 kg
Initial pressure of A and B are respectively 0.60 atm
and 0.80 atm. At a time when pressure of C is 0.20 11. For the reaction,
atm, rate of the reaction, relative to the initial value A(g)  B(g) + C(g) + D(g), if the pressures of the
is–– gas mixtures are P0, Pt and P at time, t = 0, t
1 1 = t and t =  respectively, then which of the
(A) (B) following is correct about rate constant K of this
6 48
reaction?
1 1
(C) (D) 2.303  2P0 
4 24 log 
(A) K = 
t  P0 – 2P 
7. The nucleic ratio of H3 to H in a sample of water is
8.0 × 10–18 : 1. Tritium undergoes decay with half-life
period of 12.3 years. How many tritium atoms would 2.303  P0 
(B) K = log  
10.0g of such a sample contains 40 years after the t  P0 – Pt 
original sample is collected?
(A) 5.624 × 105 atom (B) 5.624 × 103 atom 2.303  2P0 
(C) K = log  
t  3P0 – Pt 
(C) 5.624 × 106 atom (D) 1.624 × 105 atom
8. 84
Po210 decays with  particle to 82Pb206 with a half- 2.303  3P0 
life of 138.4 days. If 1.0 g of 84Po210 is placed in a (D) K = log  
t  2P0 – Pt 
sealed tube, how much helium will accumulate in
69.2 days. Express the answer in cm3 at STP.
12. The rate constant for the first order decomposition
(A) 11.25 cm3 (B) 21.25 cm3 of a certain reaction is given by the equation
(C) 31.25 cm3 (D) 41.25 cm3 1.25  10 4

ln K(sec 1 )  14.34 
T
9. For the following reaction, the value of rate
constant 0.2 mol l–1 min–1 The energy of activation will be
H2 /Ni
CH2 = CH2  CH3—CH3 (A) 25 kcal (B) 35 kcal
The graph for rate of reaction and pressure of H2 (C) 2.0 kcal (D) 15 kcal
gas would be (other things remaining constant)
SECTION - B
(A) R (B) R This section contains multiple choice questions. Each

answer, out of which ONE OR MORE is/are correct.
PH2 PH 2
13. Which of the following statements are correct

about the reaction in presence of catalyst ?
(A) Catalyst does not alter the heat of reaction
(C) R (D) R
(B) Catalyst alters the equilibrium constant of the
reaction
PH 2 PH 2
(C) Catalyst does not alter the G  of the reaction

(D) Catalyst changes the rate constant of forward
and backward reaction to the same extent.

Aakash Institute Chemical Kinetics
14. Arrhenius equation may be written as (D) The time for 90% reaction will be equal to
2.303/K, irrespective of initial concentration of
d (ln K ) E d (ln K) E
(A)  (B)  the reactant.
dT RT 2 dT RT
d (ln K) E k1
18. For two reactions : A  k2
P and B  Q of
(C)  (D) K = Ae–E/RT
dT RT 2 first and second order respectively, if the initial
15. Choose the incorrect statement(s). concentrations of A and B are same (1 M), then
the time taken by A and B to reach at 0.5 M
(A) It is possible to change the specific rate concentration is same. Which of the following is/
constant for a reaction by changing the are correct statement(s) regarding the reactions ?
temperature.
(A) The initial rate of reaction of A is greater.
(B) The specific rate constant for a reaction is (B) The initial rate of reaction of B is greater.
independent of reactant concentrations.
(C) The magnitude of K1 is greater than that of K2
(C) The rate of a catalysed reaction is always
independent of the concentration of the (D) The magnitude of K2 is greater than that of K1.
catalyst.
19. Select the correct statement about the following
(D) In stepwise reactions, the rate-determining graph. (Given NE:- number of molecules having
step in the slowest one. energy E. NT:-total number of molecules)
16. W hich of the following statements is/are t t+10

incorrect ? NE b
Nt
(A) The order of reaction is the sum of power of all
the concentration terms in the rate equation. E 1 E 2 Ea
a
(B) The order of reaction with respect to one kE
reactant is the ratio of the rate of change of
(A) E1 is the most probable energy at temperature
logarithm of the rate of the reaction to rate of t.
the change in the logarithm of the
concentration of the particular reactant, (B) Area 'a' shows fraction of molecules reacting at
t
keeping the concentrations of all other
reactants constant. (C) Area 'b' shows fraction of molecules which
react at (t + 10)
(C) Orders of reactions can be whole numbers or
fractional numbers. (D) E2 is the most probable energy at (t+10)
K1
(D) The order of a reaction can only be determined B
from the stoichiometric equation for the 20. For a 1st order reaction A K
reaction. K2
C
17. Which of the following is an incorrect statement Which of the following relation is/are correct?
about first order reaction ? (A) K = K1 + K2
(A) The time for 93.75% completion of reaction is 1 1 1
two times the time for 75% completion of (B)         tav 
1 2
reaction.
1 1 1
 
(B) Half life is the half of the time of complete (C) t
1/2  t1/2 1  t1/2 2
reaction
1 1 1
(C) About 63% reaction completes in time, equal (D) K  K  K
1 2
to 1/K.
(3)
Activated Complex Activated Complex
SECTION - C
Linked Comprehension Type Ea
E nergy
E nergy
Ea
(C+D)
This section contains paragraphs. Based upon this Products
paragraph, some multiple choice questions have to be
(A + B)
answered. Each question has 4 choices (A), (B), (C) and Reactants (A + B)
Reactants
(C+D)
(D) for its answer, out of which ONE OR MORE THAN ONE Products
is/are correct. Progress of reaction (exothemic) Progress of reaction (endothermic)
When temperature is increased, the number of ac-

Paragraph for Question Nos. 21 and 22
tive molecules increases, i.e. the number of effec-
1 tive collisions will increase and the rate of reaction
N2O5(g)  2NO2(g) + O (g) will increase.
2 2
The above reaction follows first order kinetics in which Activation energy (Ea) = E(activated complex) – E(ground state)
0.2 mole of N2O5 was taken in 2.0 L vessel and heated
at 25ºC. The concentration of N2O5 is measured at H  Ea  f   Ea  b
different intervals. Following graph ‘A and B’ were
obtained from the data. [ t1/2 (N O = 2.5 × 10–3 s] 23. The activation energy of exothermic reaction, A 
5)
2
B, is 80 kJ. The heat of reaction is –200 kJ. The
(A) (B) activation energy for the reaction, B  A, will be
(A) 80 kJ (B) 120 kJ
T  temperature
log [N 2 O 5 ]
(C) 280 kJ (D) 200 kJ

log K
24. The activation energy for the forward reaction, X Y,

is 60 kJ mol–1 and H is –20 kJ/mol–1, the activation
energy for the reverse reaction is––
Time (1/T)
(A) 40 kJ/mol (B) 60 kJ/mol
21. If the slope of the line in graph (3) is –6670. The
value of activation energy is (C) 80 kJ/mol (D) 20 kJ/mol
(A) 12.77 kJ (B) 127.7 kJ
SECTION-D
(C) 127.7 J (D) 8.31 × 103 kJ
22. The rate of reaction after 5.0 × 10–3 s is Matrix-Match Type
(A) 6.93 mol/L/s (B) 27.72 mol/L/s This Section D have “match the following” type question.
Question contains two columns, Col-I and Col-II. Match
(C) 1.73 mol/L/s (D) 13.86 mol/L/s
the entries in Col-I with the entries in Col-II. One or more
Paragraph for Question Nos. 23 and 24 entries in Col-I may match with one or more entries in
Col-II.
A collision between high energy molecules over-
comes the forces of repulsion and brings the forma- 25. Match the following columns:
tion of an unstable molecule cluster, called activated
complex. The life span of an activated complex is Column I Column II
very small. Thus, the activated complex breaks ei- (Reactions) (Unit of K)
ther into reactants again or new substances, i.e.
products. The activation energy (Ea) depends upon (A) SO2Cl2  SO2 + Cl2 (p) s–1
the nature of chemical bonds undergoing rupture and
is independent of enthalpies of reactants and prod- (B) CH3COOC2H5+NaOH (q) min–1
ucts. The energy changes during exothermic and
CH3COONa+C2H5OH
endothermic versus the progress of the reaction are
as shown below.
(C) 2H2O2  2H2O + O2 (r) Lmol–1 min–1
(D) H2O2 + 2I– + 2H+  2H2O + I2 (s) Lmol–1 s–1

26. Match the following columns:
SECTION-E
Column I Column II
Integer Answer Type
(Reactions) (Increase in rate
when concentration This section contains Integer type questions. The answer
of reactant is to each of the questions is a single digit integer, ranging
doubled) from 0 to 9. The appropriate bubbles below the respective
question numbers in the ORS have to be darkened. For
(A) CH3CHO  CH4 + CO (p) 2 times example, if the correct answers to question numbers X,
Y and Z(say) are 6, 0 and 9, respectively, then the correct
(B) SO2Cl2  SO2 + Cl2 (q) 21.5 times darkening of bubbles will look like the following :
(C) 2H2O2  2H2O + O2 (r) 2 times in acid
medium X Y Z
(D) HOH
CH3COOC2H5  (s) 22 times in basic 0 0 0

CH3COOH +C2H5OH medium 1 1 1
27. Match Column I with Column II 2 2 2

3 3 3
Column I Column II
4 4 4
(A) Rate = k × Intensity of light (p) Second order 5 5 5
(B) Rate = k[A]1[B]1 (q) Zero order 6 6 6
(C) Rate = k[A]3/2[B]1/2 (r) First order 7 7 7

when A is 8 8 8
excess
9 9 9
(D) Rate = k[A]2[B]1 (s) Second order
when B is
excess 29. For any elementary reaction A  B shown in figure.
28. Match the kinetic equation of Column I with the
The sum of slopes of curves ‘A’ and ‘B’ at the inter-
unit of its rate constant in Column II
section point is
Column I Column II
[A]o B
(A) x = kt (p) s–1
[Ao]
2.303  a  2
(B) k log10   (q) L mol–1 s–1 A
t ax
[B]o t
1 1 1
(C) k    (r) mol L–1 s–1 30. Number of neutrons in a parent nucleus X, which gives
t  (a  x) a 
14
7 N after two successive -emission would be
2.303  b(a  x) 
(D) k log  –1 –1
 (s) atm s
t(a  b)  a(b  x) 
(5)
31. Starting with one mole of a compound it is found that 32. In the reaction
the reaction is 3 completed in 1 hour. Calculate the 2
4 1H  13H  24He  10n
rate constant (in L mol–1hr–1) if the reaction is of 2nd

If the binding energies of 12H , 13H and 24He are 2,
order
3 and 10 (in MeV) respectively, then the energy (in
MeV) released in the reaction is ________.
  

Level-2
(A) Will increase by 2.828 times

SECTION - A
Straight Objective Type (B) Will increase by 11.313 times
This section contains multiple choice questions. Each (C) Will not change
answer, out of which ONLY ONE is correct.
(D) Will increase by 4 times
1. W hich of the following is incorrect regarding
4. A first order reaction A  B, requires activation en-
catalysis ?
ergy of 70 kJmol–1. When a 20% solution of A was
(A) Change in catalyst of reaction may not change kept at 25°C for 20 minutes, 25% decomposition
the reaction product. took place. What will be the percent decomposition
in the same time in a 30% solution maintained at
(B) Catalyst changes the pathway of reaction.
40°C? Assume that activation energy remains con-
(C) In case of negative catalysis, each step of stant in this range of temperature.
mechanism occur at higher threshold energy (A) 67.21% (B) 37.18%
than uncatalysed reaction.
(C) 47.2% (D) 27.3%
(D) Enzyme catalysis is homogeneous catalysis.
2. The following informations are available for the 5. 84
Po218 ( t 21 = 3.05 mins) decays to 82Pb214 ( t 21 = 2.68
reaction : R  P . min) by -emission while Pb214 is a -emitter. In an

experiment starting with 1g atom of pure Po218, how
; rate=r1 much time would be required for the number of nu-
R  P
clei of 82Pb214 to reach maximum?
A
R  P ; rate=r2 (A) 10.2 mins (B) 5.8 mins
(C) 4.12 mins (D) 2.12 mins
B
R  P ; rate=r3
6. The decomposition of ethane into ethene and hydro-
C ; rate=r4 gen involves 5 different steps, having rate constants
R  P
K1, K2, K3, K4 and K5. The rate law is given by :
D
R  P ; rate=r5 1
d  C2H6  K K K 2
A C ; rate=r6   1 3 4   C2H6 
R  P dt  K 
5
A D ; rate=r7
R  P
if Ea1 (10 kJ/mol), Ea3 (5kJ/mol), Ea4 (3 kJ/mol) and
If r3 < r1= r4= r5 <r7 <r2<r6, then the only incorrect
Ea5 (0) are the energies of activation associated with
statement is
1st, 3rd, 4th and 5th steps respectively, find the over-
(A) B is inhibitor. all energy of activation for ethane decomposition.
(B) C is catalytic promotor of catalyst A. (A) 12 KJ/mol (B) 9 KJ/mol
(C) D is catalytic poison of catalyst A. (C) 13 KJ/mole (D) 18 KJ/mole
(D) A is catalytic promotor of catalyst C 7.
238
92 U by successive radioactive decay changes to
3. The thermal decomposition of acetaldehyde, CH3CHO 206
Pb . A sample of uranium ore was analysed and
 CH 4 + CO, has rate constant of 82
1.8 × 10–3 mole –1/2 L1/2 min–1 at a given temperature. found to contain 1.0 gm of 238U and 0.1 gm of 206Pb.
Assuming that all the 206Pb has accumulated due to
d CH3 CHO  decay of 238U, find the age of the ore (half-life of 238U
How would  will change if concentra-
dt = 4.5 × 109 years).
tion of acetaldehyde is doubled keeping the tem- (A) 2.098 × 108 years (B) 7.098 × 108 years
perature constant?
(C) 2.098 × 103 years (D) 1.098 × 105 years
(7)
8. The rate expression for a reaction is and following first order kinetics with half life of 100
dc c days. Based on these informations, select the
 where , >0. If Co is the initial correct statement(s) from the following:
dt 1   c
concentration of the reactant, then t½ of this (A) Concentration of SO3 in Kolkata is 1.25  10–
reaction is given by 5 M (assume) SO present in air reaches
3
steady state).
1 .Co 2  n 2  Co
(A)  n2  (B) 
 2  2 (B) If 103 L of air is passed through 1 L pure
water (assuming all SO3 is dissolved in it) and
1 Co 2  n 2 Co resulting solution is titrated against 1 N-NaOH
(C) n2 (D) 
    solution, 15 mL of NaOH solution is required
to reach the end point.
SECTION - B
(C) An industry is manufacturing H2SO 4 at the
Multiple Correct Answer Type rate of 980 kg per day with the use of SO3 in
This section contains multiple choice questions. Each air, it should use 810–5 L air per day.
answer, out of which ONE OR MORE is/are correct. (D) If SO3 emission is stopped, then after 1000
days, its concentration will reduce to 1.25 5 
9. For a complex reaction
10–8 M.
(A) the overall rate is the rate of slowest step
13. Consider the reactions :
(B) the overall molecularity has no significance
k 6.93102 min1 k 13.86 102 min1
(C) molecularity and order may or may not be A 
1
B and A 
2
C
same A, B and C all are optically active compounds. If
(D) the overall order is always the order of slowest the optical rotations of A, B and C per unit
step concentration are 60°,–72° and 42°, respectively
10. In a consecutive reaction system and the initial concentration of A is 2 M, then
E1 E2
A  B   C when E 1 is much greater (A) the solution will be optically active and
than E2, the yield of B increases with dextrorotatory after very long time.
(A) increase in temperature (B) the solution will be optically active and
(B) decreases in temperature laevorotatory after very long time.
(C) increase in initial concentration of A (C) half life for overall reaction of A is 15 min.
(D) decrease in initial concentration of A (D) After 75% conversion of A into B and C, the
optical rotation of solution will be 36°.
11. For the reaction A  Products, if R = k[A]n then
14. For the first order parallel reactions, starting with
(A) The degree of dissociation is euqal to (1 – e–kt), if 1 M of A, which of the following statement(s) is/
n=1 are correct?
1
(B) A plot of vs time gives a straight line, if n = 3k
A  B
[A]
2
2k
A  2C
(C) The time taken for the completion of 75% reaction
is 3 × t1/2, If n = 1 k
A   3D
(D) The pre-exponential factor in Arrhenius equation (A) [B]t : [C]t : [D]t is independent of time
has unit Molarity–1 s–1 for n = 2
(B) [C]t > [B]t = [D]t
12. SO3 gas is entering the environment at a constant
(C) [C  ]  0. 67 M
rate of 6.93  10–6 g/L/day due to emission of
polluting gases from thermal power plant at (D) If k=0.5 min–1, then [B] =1 M after 1.386 min.
Kolkata, but at the same time it is decomposing

15. According to collision theory "pre exponential (B) t1/2 ln n = ln (constant) + lna0
factor" is affected by (C) ln t1/2 = ln n + ln (constant) – lna0
(A) Temperature (B) Activation energy (D) ln t1/2 = n lna0
(C) Steric factor (D) Molarity Paragraph for Question Nos. 19 to 22
SECTION - C When the temperature is increased, heat is supplied which

increases the kinetic energy of the reacting
Linked Comprehension Type molecules. This shall increase the number of collisions
This section contains paragraphs. Based upon this and ultimately the rate of reaction shall be enhanced.
paragraph, some multiple choice questions have to be Arrhenius suggested a equation which describes K as a
answered. Each question has 4 choices (A), (B), (C) and function of temperature, i.e
(D) for its answer, out of which ONE OR MORE THAN ONE
k  Ae  Ea /RT
is/are correct.
Where,
k = rate constant
If a unimolecular reaction, A (g)  Products, takes place
according to the mechanism A = a constant (frequency factor)
K
Ea = energy of activation

(i) A  A  K  A  A
1
1
Ea  1 
log10 k  log10 A 

(ii) A 
k2
P 2.303R  T 
Y = C + MX
Where k1, k–1 and k2 are the rate constants and P, A and
It is the equation of straight line with negative slope. On
A  stand for product molecule, normal molecule of reac-
tant and activated molecules of reactant respectively.  1
plotting log10K against   we get a straight line as shown
16. Which of the following expressions are correct? T 
below :
d  A  
 k1  A   K 1  A    A   k 2  A  
2
(A)
dt C=log10A
d  A  
(B) 0 Log10K
dt
k1  A 
2
(C)  A  

k 1  A   k 2 
Ea
(D) All of the above Slope =1 tan  
T 2.303R
17. Which of the following statements are correct?
The slope gives activation energy and intercept gives fre-
(A) At high pressure of A, i.e. high concentration of
quency factor.
A, reaction obeys first order kinetics.
(B) At low pressure of A reaction follows first order
k2 Ea  T2  T1 
kinetics. Also log   
k1 2.303R  T1 T2 
(C) Rate of reaction depends on both steps at all
pressure.
19. The rate constant of a reaction is increased by 5%
(D) All of the above statement are correct. when its temperature is raised from 27°C to 28°C.
The activation energy of the reaction in kJ/mol is––
18. The order ‘n’, initial concentration a0 and time of half
reaction t1/ 2 , for a reaction are related as– (A) 36.6 (B) 16.6
(A) ln t1/2 = ln (constant) – (n – 1) lna0 (C) 46.6 (D) 26.6
(9)
20. The activation energy of a reaction is 9 kcal/mol. (C) (r) r(y – axis),
The increase in rate constant when its temperature t(x – axis)(order > 0)
is raised from 295 to 300 K is approximately.
(A) 10% (B) 50% (D) (s) r(y – axis),

(C) 100% (D) 28% t(x – axis)(order = 0)
21. A first order reaction is 50% complete in 30 minutes (t) t½(y – axis), [A0]
at 27°C and 10 minutes at 47°C. The energy of acti- (x – axis) (order > 1)
vation of the reaction is––
(A) 43.84 kJ/mol 1

(u) (y – axis),
(B) 34.84 kJ/mol [A]
t (x – axis)
(C) 84.00 kJ/mol (order = 2)
(D) 30.00 kJ/mol (v) r(y – axis), [A]

(x – axis)(order = 1)
22. The rate of certain reaction increases by 2.5 times
when the temperature is raised from 300 K to 310 K.
SECTION-E
If k is the rate constant at 300 K then rate constant
at 310 K will be equal to–– Integer Answer Type
(A) k (B) 2 k This section contains Integer type questions. The answer
to each of the questions is a single digit integer, ranging
(C) 2.5 k (D) 13 k
from 0 to 9. The appropriate bubbles below the respective
SECTION-D question numbers in the ORS have to be darkened. For
example, if the correct answers to question numbers X,
Matrix-Match Type Y and Z(say) are 6, 0 and 9, respectively, then the correct
This Section D have “match the following” type question. darkening of bubbles will look like the following :
Question contains two columns, Col-I and Col-II. Match
the entries in Col-I with the entries in Col-II. One or more X Y Z
entries in Col-I may match with one or more entries in
0 0 0
Col-II.
1 1 1
23. Match the following columns 2 2 2
3 3 3
Column I Column II
4 4 4
5 5 5
(Graphs reaction (Co-ordinates)
A  Products) 6 6 6
7 7 7
(A) (p) ln[A] (y – axis),
8 8 8
t(x – axis)
9 9 9
(B) (q) t½(y – axis), [A0]
(x – axis) (order = 1)

24. The half-lives of two sample are 0.1 and 0.4 second. 27. For the reaction
Their respective initial concentrations are 200 and
50 respectively. What is the order of the reaction? A  B
t0 a 0
25. A reaction X2  g  Z  g  21 Y(g) exhibits an in- time  t a – x x
crease in pressure from 150 mm to 170 mm in 10
min. The average rate of disappearance of X2 in mm  dx 
If the graph is drawn between log   (y-axis)
per min is ....  dt 
Kf
and log (a – x) (x-axis), the slope of the line is
26. For a reversible first order reaction A  K B ; Kf = found to be 45º. Find out the order of reaction.
b
Beq
10–2 sec–1 and  4 ; if Ao = 0.01 ML–1 and Bo = 0.
A eq
The concentration of ‘B’ after 30 sec is 2.5 × 10–x M.
The value of x is
  
(11)
CPP-04
SS JEE(M) &
ADVANCED
ANSWERS
LEVEL-1
1. (C) 2. (D) 3. (B) 4. (B) 5. (C) 6. (A)
7. (A) 8. (C) 9. (C) 10. (A) 11. (C) 12. (A)
13. (A,C,D) 14. (A,D) 15. (C) 16. (D) 17. (B) 18. (B,D)
19. (A,B,C,D) 20. (A,B,C) 21. (B) 22. (A) 23. (C) 24. (C)
25. (A-p,q,B-r,s,C-p,q,D-r,s) 26. (A-q,B-pC-p,D-r,s) 27. (A-q,B-p,r,C-p,D-r,s)
28. (A-r,B-p,C-q,s,D-q,s) 29. (0) 30. (9) 31. (3) 32. (5)
LEVEL-2
1. (A) 2. (C) 3. (A) 4. (A) 5. (C) 6. (B)
7. (B) 8. (A) 9. (A,B,C) 10. (A,C) 11. (A,B,D) 12. (A,D)
13. (A,D) 14. (A,B,C) 15. (A,C,D) 16. (D) 17. (A) 18. (A)
19. (A) 20. (D) 21. (A) 22. (C) 23. (A-p,B-q,s,C-r,t,v,D-u)
24. (2) 25. (4) 26. (3) 27. (1)
  

CPP-04
SS JEE(M) &
ADVANCED
Mathematics
Chapter - Matrices and Determinants
Level-1
SECTION - A ( A  AT )2013
5. If A is square matrix of order 3, then
Straight Objective Type 2013
is equal to
question has 4 choices (A), (B), (C) and (D) for its answer, 1 1
(A) (B)
out of which ONLY ONE is correct. 2013 (2013)2013
1
 2 1 2 (C) (D) 0
1. If TrA is trace of matrix A   1 4 7  then value (2013)2012
 
 0 3 2
x 3 x
of sin1  sin(TrA)  is 2
6. If x x 2  Ax 6  Bx5  Cx 4  Dx 3  Ex 2  Fx  G,
(A) 8 – 2 (B) 8 – 3 5 x3 x
(C) 3 – 8 (D) 2 – 8
then A + G=
2. A matrix B satisfies the relation B2 = 3B – 2I, then
B–1 is equal to (A) 32 (B) 31
(C) 24 (D) 25
15I  B 3
(A) 15I – B3 (B)
14
2bc  a2 c2 b2
B 3  15I
(C) B3 – 15I (D) 7. If a + b + c = 0 then c2 2ac  b2 a2
14
b2 a2 2ab  c 2
1 2 2 
3 is equal to
3 3 
 
2 1 2 (A) 0 (B) (a+b+c)2 + 2abc
3. If A     is an orthogonal matrix then
3 3 3
  (C) 1 (D) a3 + b3 + c3 – 3abc
x 2 y 
 3 3 3  8. If (I + A)n + (1 – 2n)A = I where I is the unit matrix
of same order as of A then A is
|x + y| is
(A) Orthogonal matrix (B) Nilpotent matrix
(A) 2 (B) 1
(C) Idempotent matrix (D) Involutory matrix
(C) Zero (D) 3
2 3  x 1
 2 0 1 9. If A    and f ( x )  then f  f  A   is
 1 2  x 1
4. If the matrix A  5 1 0  satisfies the equation
 
0 1 3  2 3   2 3 
(A)   (B)  
A3 – 6A2 + 11A – I = 0, and if A–1 = A2 – kA +  1 2  1 2 
11I, then value of k is
(A) 4 (B) 6  2 3   2 1
(C)   (D)  
(C) –6 (D) 8  1 2  3 2 
(1)
Matrices & Determinants Aakash Institute
10. The system of homogeneous equations tx + (t + 1)y
SECTION - B
+ (t – 1)z = 0, (t + 1)x + ty + (t + 2)z = 0, (t – 1)x +
(t + 2)y + tz = 0 has a non-trivial solution for Multiple Correct Answer Type
(A) exactly three real values of t This section contains multiple choice questions. Each
(B) exactly two real values of t
out of which ONE OR MORE is/are correct.
(C) exactly one real value of t
15. Equation of the plane perpendicular to the planes
(D) infinite number of values of t x – y + z = 10, x – z = 100 and passing through
11. If A = [aij] is a square matrix of even order such that the point (1, 2, 3) is ax + by + cz = 8.
aij = i2 – j2, then
 1 1 1 
(A) A is skew-symmetric matrix
If A   1 0 1 , then
(B) A is a symmetric matrix and det A is a square
a b c 
(C) A is a symmetric matrix and det A is zero
(D) None of these (A) det(A) = 6
12. Let A = [ a ij ] be a 3 x 3 matrix, where a ij = (B) det(adj(adj A)) = 64

1 (C) det (adj A) = 9
(1  ix)  1 for all 1  i, j  3. Then A2 equals
j
lim 5
x 0 x (D) sin–1a + sec–1b + cos–1c =
6
(A) 4A (B) 3A 16. If the system of equations
(C) 2A (D) A ax + y + 2z = 0
x + 2y + z = b
 3 1 
  1 1  2x + y + az = 0
2 2 
13. Let A =  ,B=   and C = ABAT,
 1 3  0 1 has no solution then (a + b) can be equal to
 
2 2  (A) –1 (B) 2
then A C A is equal to
T 3
(C) 3 (D) 4
 3 1 1 0 x 2  4x  3 2x  4 13
    17. Let D(x) = 2x  5x  9 4x  5 26  x 3  x2  x  
2
(A)  2 2 (B)  3 1
 1 0   2  8x 2  6x  1 16x  6 104
then
 3 (A) += 0 (B) += 0
1  1 3 
(C)  2  (D) 0 1 (C) +++= 0 (D) ++= 0
 
0 3 
18. If the system of equations
f(x   ) f(x  2 ) f(x  3 ) (sin ) x + (sin 2) y + (sin 3) z = 0,

f( ) f(2) f(3 ) (sin ) x + (cos ) y + (sin ) z = 0,
14. Let g (x) = , where
f ( ) f (2 ) f (3)
(cos ) x  (sin ) y + (cos ) z = 0,
 is a constant, then lim

g(x)
is equal to has non-zero solution, then can be equal to
x 0 x
3
(A) 0 (B) 1 (A)  (B)
4
( C) 1 (D) none of these
7 11
(C) (D)
2 4

Aakash Institute Matrices & Determinants
23. Inverse of matrix X is
x2 (x  1)2 (x  2)2
19. If ax3 + bx2 + cx + d = (x  1)2 (x  2)2 (x  3)2 ,
 1 2   1 2 
(x  2)2 (x  3)2 (x  4)2  3  3 0   3  3 0
   
(A)  7 5 (B)  7 5
then   1   1
 3 3   3 3 
(A) a = 0 (B) b = 0    
 3 2 1  3 2 1
(C) c = 0 (D) d = –8
x2 (y + z)2 yz  1 2   1 2 
 3 3 0   3  0
20. Let  = y 2
(z  x) 2
zx which of the following   3
 
  7  5 1 7 5
(x  y) (D)   1
2 2
z xy (C)   
3 3  3 3 
   
can be true ?  3 2 1  3 2 1
(A) is divisible by x2 + y2 + z2
SECTION-D
(B) = 0
Single-Match Type
(C) is divisible x + y + z
This section contains Single match questions. Each
(D) is divisible by both (x  y) and ( x + y + z) question contains statements given in two columns which
21. If A= (aij)3x3is a skew symmetric, then have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column
(A) aii= 0  i (B) A + A is a null matrix II are labelled p,q,r,s. Four options A, B, C and D are
given below. Out of which, only one shows the right
(C) A = 0 (D) A is not invertible.
matching
SECTION - C 24. Suppose a,b,c are distinct and x,y,z are connected
by the system of equations
Linked Comprehension Type
x + ay + a2z = a3
This section contains paragraph. Based upon this
paragraph, 2 multiple choice questions have to be x + by + b2z = b3
answered. Each question has 4 choices (A), (B), (C) and x + cy +c2z = c3
(D) for its answer, out of which ONLY ONE is correct.
then
Paragraph for Question Nos. 22 to 23 Column I Column II
 a 0 0 (A) a + b + c (p) x
  (B) bc + ca + ab (q) –y
Let A  2a a 0 and X1, X2, X3 be three column
3a 2a a (C) abc (r) z
matrices such that (D) (b+c) (c+a) (a+b) (s) – (x + yz)
A B C D
a  2a  2a 
(A) r q p s
AX1  0  , AX 2  3a  and AX 3  3a  and let X be a
   
0   0   a  (B) p s q r
(C) s r q p
3 × 3 matrix
whose columns are X1, X2, X3 (D) p q r s
22. Value of det X is

(A) – 2 (B) – 1
(C) 3 (D) 0
(3)
25. Match the following X Y Z
Column I Column II 0 0 0
(A) aij = j2 – i2 (p) Symmetric 1 1 1
(B) aij = i + j (q) Skew-symmetric 2 2 2
(C) aij = 0  i > j (r) Lower triangular
3 3 3
(D) aij = 0  i < j (s) Upper triangular
4 4 4
A B C D
5 5 5
(A) r s q p
6 6 6
(B) p s q r
7 7 7
(C) s r q p
(D) q p s r 8 8 8
26. Match the following for the system of linear equa- 9 9 9

tions
x + y + z = 1
x + y + z =  27. If A is a square matrix of order n such that |adj (adj
A)| = |A|9, then the value of n can be
x + y + z = 2
Column - I Column - II 28. 1 2 1
   2,
x y z
(A) =1 (p) unique solution
3 4 2
(B) 1 (q) infinite solution    1,
x y z
(C)  1, 2 (r) no solution 2 5 2
   3,
(D) = 2 (s) May be consistent x y z
then the value of z is ______

SECTION-E solve the system for z by Cramer’s rule
Integer Answer Type
ex sin 2x tan x 2
This section contains Integer type questions. The answer
to each of the questions is a single digit integer, ranging 29. If (x) = In(1  x) cos x sin x = A + Bx + Cx2
from 0 to 9. The appropriate bubbles below the respective cos x 2 e x  1 sin x 2
question numbers in the ORS have to be darkened. For +............. then B is equal to
example, if the correct answers to question numbers X, Y
and Z(say) are 6, 0 and 9, respectively, then the correct 30. If , ,  are the roots of x3 + ax2 + b = 0, then the
darkening of bubbles will look like the following :   
determinant     equals a, then  =
  


Level-2
6. If A and P are different matrices of order n satisfying

SECTION - A
A3 = P3 and P2A = PA2 (where |A|  |P|) then |A2 + P2|
Straight Objective Type is equal to
question has 4 choices (A), (B), (C) and (D) for its answer, (A) n (B) 0
out of which ONLY ONE is correct. (C) |A| |P| (D) |A + P|
   x y  z
 cos 9 sin
9  
1. Let P    then the value of 7. Let matrix A  1 2 3  , where x, y, z  N. If
  sin  
cos  1 1 2 
 9 9 
|adj(adj(adj(adjA)))| = 48.516, then the number of such
P P
9 18 is matrix is
(A) 1 (B) 2 (A) 28 (B) 36
(C) 3 (D) 0 (C) 45 (D) 55

8. Matrices of order 3x3 are formed by using the ele-
2. a  R; Mn×n is non zero; M2 = M, if
ments of the set A = {-3,-2,-1,0,1,2,3} then probabil-
(I – aM)–1 = I – 3M; 2a = ity that matrix is either symmetric or skew symmet-
ric is
(A) 1 (B) 2
(C) 3 (D) 4 1 1
(A) 6
 3
7 7
3. Let P and Q be two different matrices satisfying
P3 = Q3 and P2Q = Q2P, then 1 1 1
(B) 9
 3  6
(A) det(P2 + Q2) must be zero 7 7 7
(B) det(P – Q) must be zero 1 1

(C) 
(C) det(P2 + Q2 ) as well as det(P – Q) must be 73 79
zero
1 1 1
(D) At least one of det(P2 + Q2) or det(P – Q) (D)  
7 3 7 6 79
must be zero
4. A is a square matrix of order 3 × 3 and I is a unit  C2 0 

9. Let Ck  n Ck for 0  k  n and A k   k 1 2 
matrix of order 3 × 3. If | A | = 2 and AA = I then 0 Ck 
the determinant value of the matrix (A – I) is equal
to
k 0 
(A) 1 (B) 2 for k  1 and A1  A 2  ....  A n   1  , then
0 k 2 
(C) 0 (D) 3
5. A is a n  n matrix whose elements are all ‘1’ and (A) k1  k 2 (B) k1  k 2  2n

C2n  1
B is a n  n matrix whose diagonal elements are
all ‘n’ and other elements are ‘n – r’ then (B – rI) (C) k1  2n
C2n  1 (D) k 2  2n
Cn  1
[B – (n2 – nr + r)I] is
(A) I (B) – I
(C) Null matrix (D) A
(5)
14. Let A be a matrix of order 3 × 3 and matrices B,
SECTION - B
C, D are related such that B = adj. (A), C = adj.

(adj.A), D = adj  adj  adj A  
out of which ONE OR MORE is/are correct. if adj adj  adj adj ABCD  is A
k
, then k
 3 1 (A) Is less than 256 (B) Has 20 divisors

10. If A    then
 4 1 (C) Is a perfect square (D) Is an even number
15. In a set A = {33, 73, 113, 153, ....} if 9 elements are

5
2 2 3 7 3 selected from set A and a matrix B of order 3×3 is
(A) A   (B) A  
  8  3   12 5  made then, Det(B) must be divisible by
(A) 2 (B) 4
16  33 16  6  12 6 
(C) A   (D) A   24 12 
 64  31   (C) 8 (D) 16
16. If A and B are 3 x 3 matrices and |A| 0, then

 sin  cos    1 1
11. If M =  , A  and
  cos  sin   0 1 (A) | AB | 0  B  0
N = MAMT, then
(B) AB = 0  B is always null matrix
 1 2
(A) MT N2M    1
 0 1 (C) A 1  A
 1 100  (D) 2A  2 A
(B) MT N100M  
0 1 
1 0 0 
(C) MMT  I  
17. If A = 1 0 1  , then
1 99  0 1 0 
(D) MTN99M   
1 1 
(A) A3  A2 = A  I (B) Det (A2010  I)=0
12. If A and B are square matrix of order 3 and
AB = B and BA = A, then
(A) A2–B2=0 (B) A2+B2=A+B 1 0 0  1 1 0 
 
(C) A = 25 1 0 
50
(D) A50= 25 1 0 
(C) (A–B)2=0 (D) (A+B)2=A+B  
25 0 1  25 0 1 
13. The maximum and minimum value of a third order
determinant whose elements belong to the set
{–3, –2, –1, 0, 1, 2, 3} can be SECTION - C
(A) 108 (B) 81 Linked Comprehension Type
(C) – 81 (D) – 108 This section contains paragraph. Based upon this
paragraph, 2 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out of which ONLY ONE is correct.

Paragraph for Question Nos. 18 and 19
3 
Consider the determinant  
22. The value of [3 2 0] U  2 is
0 
p q r
 x y z
(A) 5 (B) 5/2
l m n
(C) 4 (D) 3/2
Mij denotes the minor of an element in ith row and jth column
and Cij denotes the cofactor of an element in ith row and jth SECTION-D
column.
Single-Match Type
18. The value of p C21 + q  C22 + r C23 is This section contains Single match questions. Each
(A) 0 (B) – question contains statements given in two columns which
have to be matched. The statements in Column I are
(C)  (D) 2 labelled A, B, C and D, while the statements in Column
II are labelled p,q,r,s. Four options A,B,C and D are given
19. The value of xC21 + y  C22 + z C23 is
below. Out of which, only one shows the right matching
(A) 0 (B) –
3  4 a 6 
(C)  (D) 2 23. Consider the matrix A    and B  0 1
1  1  
Paragraph for Q.Nos. 20 to 22 Let P be any orthogonal matrix, Q = PAPT,
R = PTQKP, S = PBPT and T = PTSKP.

1 0 0 
Let A   2 1 0  and U1, U2, U3 are columns of a 3 × 3
Column - I Column - II
 
3 2 1  (A) If we vary K from 1 to (p) G.P. with
‘n’ then the elements common ratio a
matrix of U. If column matrices U1, U2 , U3 satisfy at first row first column
of R will form
1   2 2 (B) If we vary k from 1 to n, (q) A.P. with
AU1  0  , AU2  3 , AU3  3
   
then the elements at common differ-
0  0 1  second row second column ence 2
of R will form
20. The value of U is (C) If we vary k from 1 to n, (r) G.P. with

then the elements at first common ratio ‘6’
row first column of T will
(A) 3 (B) 3
form
(C) 3/2 (D) 2
(D) If we vary k from 3 to n, (s) A.P. with
21. The sum of the elements of U is -1 then the elements at first common differ-
row second column of T ence  2
(A) 1 (B) 0 will represent the sum of
(C) 1 (D) 3
(7)
SECTION-E  2 1 3 4   3 4 
26. Let A    , B  2 3  and C   2 3  be
Integer Answer Type  4 1    
This section contains Integer type questions. The answer
to each of the questions is a single digit integer, ranging three given matrices and tr(A) denotes the trace of
from 0 to 9. The appropriate bubbles below the respective
1 
question numbers in the ORS have to be darkened. For the matrix A, then tr( A)  tr  ( ABC )  
example, if the correct answers to question numbers X, Y 2 
and Z(say) are 6, 0 and 9, respectively, then the correct
darkening of bubbles will look like the following : 1  1 
tr  A(BC )2   tr  ( A(BC )3 )   ..... to infinitely
X Y Z 4  8 
0 0 0 many terms is equal to _____.

27. The set of natural numbers M partitioned into
1 1 1
arrays of rows and columns in the form of matrices
2 2 2
2 3
3 3 3 as M1  1 , M 2   ,
4 5
4 4 4
6 7 8
5 5 5 M3   9 10 11 ,........, Mn   n  n
6 6 6 12 13 14 
7 7 7 and so on, where the sum of the elements of the
8 8 8 principal diagonal in M6 is (440 + ) , then  is
9 9 9 _____.
28. Let A and B be two non-singular square matrices such
that B ¹ l and AB2 = BA. If A3 = B–1A3Bn, then value of n is
b2c 3  b3c 2 a3c 2  a2c 3 a2b3  a3b2 _______.
24. If b3c1  b1c 3 a1c 3  a3c1 a3b1  a1b3  49 and
29. If a,b,c, are the roots of x3 + 2x2 + p = 0, then the
b1c 2  b2c1 a2c1  a1c 2 a1b2  a2b1
a b c
value of b c a is
a1 b1 c1 c a b
a3 b3 c 3  k, then the value of |k| is________
a2 b 2 c 2 30. If |a2 – a3| = 6, the maximum value of
2 a3 a2
x 2 x 
f  x  2 a3 2a2  x is , then
6
25. Let x2 x 1  Ax 4  Bx 3  Cx 2  Dx  E and 2 2a3  x a2
x x 2
7A + 5B + 3C + D – E=–K, then K= ________


CPP-04
SS JEE(M) &
ANSWERS ADVANCED
LEVEL-1
1. (C) 2. (B) 3. (D) 4. (B) 5. (D) 6. (B)
7. (A) 8. (C) 9. (C) 10. (C) 11. (A) 12. (B)
13. (D) 14. (A) 15. (A, B, D) 16. (B, C, D) 17. (A, B, D) 18. (A, B, D)
19. (A, B, C, D) 20. (A, C, D) 21. (A, B, C, D) 22. (C) 23. (A) 24. (A)
25. (D) 26. (A-q,s B-p,s,r C-p,s D-r) 27. (4) 28. (3) 29. (0)
30. (3)
LEVEL-2
1. (D) 2. (C) 3. (D) 4.(C) 5. (C) 6. (B)
7. (B) 8. (D) 9. (A) 10. (A, B, C) 11. (A, B, C) 12. (B, C)
13. (A, D) 14. (A, B, D) 15. (A, B, C, D) 16. (A, B, C) 17. (A, B, C) 18. (A)
19. (C) 20. (A) 21. (B) 22. (A) 23. (A-q B-s C-p D-p)
24. (7) 25. (5) 26. (6) 27. (1) 28. (8)
29. (8) 30. (3)

(9)

SS CPP 04 Physics Chemistry Mathematics 2020

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CPP-04

SECTION - A 3. The magnetic field at the centre of the circular loop

0   r 2  2y 2  radially outward from a point P at a height h above

D:/ Math equation.pm6/aloke/Determinant (2)

This section contains multiple choice questions. Each

14. Consider a wire carrying a steady current, I placed

(A) motion of charges inside the conductor is

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(B) The direction of net magnetic field at P (0, a,

y (C) Rate of work done by electric field at P is not

27. What is net force on the electron at the edge of

D:/ Math equation.pm6/aloke/Determinant (6)

  15 3 (t) Combination of uniform

35. A charge particle is projected in an XYZ space with

37. Two circular rings each of radius a are joined together

D:/ Math equation.pm6/aloke/Determinant (8)

 0IL  0IL ln3

the upper circular part of the sieve will be : [ B

(A) If coil is free to rotate about x axis torque on

D:/ Math equation.pm6/aloke/Determinant (12)

19. Find the magnitude of current in the ring at a

D:/ Math equation.pm6/aloke/Determinant (14)

31. What must be the torsional constant K of the spring ?

D:/ Math equation.pm6/aloke/Determinant (16)

A square current carrying

(D) y (s) Net torque on 

Circular ring () half positive

   37. A conducting light string is wound on the rim of a

7. (C) 8. (D) 9. (B) 10. (A) 11. (B) 12. (A)

1. (A) 2. (C) 3. (B) 4. (A) 5. (A) 6. (B)

7. (C) 8. (A) 9. (B) 10. (B) 11. (A) 12. (A)

SECTION - A (C) Only the first step of such reactions follows

(B) Overall order of photochemical reactions is

(C) 31.25 cm3 (D) 41.25 cm3 1.25  10 4

(A) R (B) R This section contains multiple choice questions. Each

13. Which of the following statements are correct

(C) Catalyst does not alter the G  of the reaction

D:/ Math equation.pm6/aloke/Determinant (2)

16. W hich of the following statements is/are t t+10

Linked Comprehension Type Ea

is/are correct. Progress of reaction (exothemic) Progress of reaction (endothermic)

When temperature is increased, the number of ac-

(C) 280 kJ (D) 200 kJ

24. The activation energy for the forward reaction, X Y,

(D) H2O2 + 2I– + 2H+  2H2O + I2 (s) Lmol–1 s–1

D:/ Math equation.pm6/aloke/Determinant (4)

27. Match Column I with Column II 2 2 2

(C) Rate = k[A]3/2[B]1/2 (r) First order 7 7 7

rate constant (in L mol–1hr–1) if the reaction is of 2nd

D:/ Math equation.pm6/aloke/Determinant (6)

(A) Will increase by 2.828 times

reaction : R  P . min) by -emission while Pb214 is a -emitter. In an

D:/ Math equation.pm6/aloke/Determinant (8)

SECTION - C When the temperature is increased, heat is supplied which

(A) 10% (B) 50% (D) (s) r(y – axis),

(A) 43.84 kJ/mol 1

(D) 30.00 kJ/mol (v) r(y – axis), [A]

D:/ Math equation.pm6/aloke/Determinant (10)

1. (C) 2. (D) 3. (B) 4. (B) 5. (C) 6. (A)