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Full Chapter Lectures On Quantum Mechanics Perturbed Evolution Englert PDF
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Other Lecture Notes by the Author
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To my teachers, colleagues, and students
This page intentionally left blank
Preface
vii
viii Lectures on Quantum Mechanics: Perturbed Evolution
All three books owe their existence to the outstanding teachers, col-
leagues, and students from whom I learned so much. I dedicate these lec-
tures to them.
I am grateful for the encouragement of Professors Choo Hiap Oh and
Kok Khoo Phua who initiated this project. The professional help by the
staff of World Scientific Publishing Co. was crucial for the completion; I
acknowledge the invaluable support of Miss Ying Oi Chiew and Miss Lai
Fun Kwong with particular gratitude. But nothing would have come about,
were it not for the initiative and devotion of Miss Jia Li Goh who turned
the original handwritten notes into electronic files that I could then edit.
I wish to thank my dear wife Ola for her continuing understanding and
patience by which she is giving me the peace of mind that is the source of
all achievements.
Singapore, March 2006 BG Englert
Preface vii
Glossary xiii
Miscellanea . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xiii
Latin alphabet . . . . . . . . . . . . . . . . . . . . . . . . . . . xiv
Greek alphabet and Greek-Latin combinations . . . . . . . . . . xvi
2. Time-Dependent Perturbations 41
2.1 Born series . . . . . . . . . . . . . . . . . . . . . . . . . . 41
2.2 Scattering operator . . . . . . . . . . . . . . . . . . . . . . 43
ix
x Lectures on Quantum Mechanics: Perturbed Evolution
3. Scattering 79
3.1 Probability density, probability current density . . . . . . 79
3.2 One-dimensional prelude: Forces scatter . . . . . . . . . . 82
3.3 Scattering by a localized potential . . . . . . . . . . . . . 86
3.3.1 Golden-rule approximation . . . . . . . . . . . . . . 86
3.3.2 Example: Yukawa potential . . . . . . . . . . . . . 90
3.3.3 Rutherford cross section as a limit . . . . . . . . . 91
3.4 Lippmann–Schwinger equation . . . . . . . . . . . . . . . 92
3.4.1 Born approximation . . . . . . . . . . . . . . . . . . 100
3.4.2 Transition operator . . . . . . . . . . . . . . . . . . 100
3.4.3 Optical theorem . . . . . . . . . . . . . . . . . . . . 102
3.4.4 Example of an exact solution . . . . . . . . . . . . 104
3.5 Partial waves . . . . . . . . . . . . . . . . . . . . . . . . . 105
3.6 s-wave scattering . . . . . . . . . . . . . . . . . . . . . . . 110
Index 187
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Glossary
Here is a list of the symbols used in the text; the numbers in square brackets
indicate the pages of first occurrence or of other significance.
Miscellanea
0 null symbol: number 0, or null column, or null matrix,
or null ket, or null bra, or null operator, et cetera
1 unit symbol: number 1, or unit matrix, or identity
operator, et cetera
A= bB read “A represents B” or “A is represented by B”
Max{ } , Min{ } maximum, minimum of a set of real numbers
a∗ , a complex conjugate of a, absolute value of a
Re(a) , Im(a) real, imaginary part of a
a= a length of vector a
a · b, a × b scalar, vector product of vectors a and b
†
A adjoint of A [3]
det(A), tr(A) determinant [144], trace of A [14]
| i, h |; |1i, ha| generic ket, bra; labeled ket, bra [1]
|initi, hfin| initial ket, final bra [63]
|ini, |outi kets for incoming, outgoing particles [92]
|j1 , j2 ; j, mi, |(j1 , m1 )(j2 , m2 )i kets for composite angular momentum [120]
h | i, | ih | bra-ket, ket-bra [2,3]
| . . . , ti, h. . . , t| ket, bra at time t [27]
h. . . , t1 |. . . , t2 i time transformation function [29]
hAi mean value, expectation value of A
[A, B] commutator of A and B [19]
A(t)A(t0 ) > time-ordered product [46]
↑, ↓ spin-up, spin-down [122]
x! factorial of x [152]
f 2 (x), f −1 (x) x 7→ f (x):
square, inverse of the function
f 2 (x) = f f (x) , f f −1 (x) = x, f −1 f (x) = x
xiii
xiv Lectures on Quantum Mechanics: Perturbed Evolution
Latin alphabet
a range of the hard-sphere potential [110]
a0 Bohr radius, a0 = 0.529 Å [151]
a(t), b(t) probability amplitudes [70]
a(s) Laplace transform of α(t) [60]
A, aj generic operator, its jth eigenvalue [1]
A(t) collection of dynamical variables [27]
A± , A†± harmonic-oscillator ladder operators [129]
A(r ), B(r ) vector potential, magnetic field at r [125]
Å angstrom unit, 1Å = 10−10 m = 0.1 nm [151]
c speed of light, c = 2.99792 × 108 cm s−1 [125]
cos, sin, . . . trigonometric functions
cosh, sinh, . . . hyperbolic functions
e elementary charge, e = 4.80320 × 10−10 Fr [91]
e; ex = exp(x) Euler’s number, e = 2.71828 . . . ; exponential function
E, En , E energy, nth eigenenergy [48], Lagrange parameter [157]
f (uk , vl) normalized mixed matrix element [12]
f k 0, k scattering amplitude [98]
F, F (x) force [35,85]
G, G1 , G2 generators [32]
G± (r , r 0 ), G Green’s functions [94], Green’s operator [101]
h = 2π~ Planck’s constant,
~ = 1.05457 × 10−34 J s = 0.658212 eV fs [19]
H, Ht , H Hamilton operator [27], at time t [29], matrix for H [68]
H0 , H1 ; H1 dominant, small part of H [41]; interaction picture [45]
Hatom , Hphot , atom, photon part of H [53]
Hint ; Hrot interaction part of H [53]; H for rotation [115]
Glossary xv
† †
... = ... , ... = ... , (1.1.1)
aj : A aj = aj aj , (1.1.2)
1
2 Basic Kinematics and Dynamics
The complex number hbk |aj i is the probability amplitude for the measure-
ment result bk in state |aj i; its absolute square is the associated probability.
This amplitude has all properties that are required of an inner product, in
particular
a = a0 + a00 : b a = b a0 + b a00 ,
a = α λ: b a = b α λ, (1.1.5)
are therefore always equal. There is, of course, a lot of circumstantial ev-
idence for the validity of this fundamental symmetry, but — elementary
situations aside — there does not seem to be a systematic direct experi-
mental test.
∗ David Hilbert (1862–1943)
Brief review of basic kinematics 3
so that the kets |aj i make up a basis for the ket space and the bras haj |
compose a basis for the bra space. As an immediate consequence, we note
that the eigenket equation
A aj = aj aj , (1.1.12)
multiplied by haj | on the right and then summed over j, yields
X
A= aj aj aj , (1.1.13)
j
indeed. Similarly, you easily show that it works for other powers of A, then
for all polynomials, then for all functions that can be approximated by, or
related to, polynomials, and so forth. But what is really needed to ensure
that f (A) is well defined is that the numerical function f (aj ) is well defined
for all eigenvalues aj . As a consequence, two functions of A are the same
if they agree for all aj ,
for which the inverse equals the adjoint; see Exercises 2 and 3 for properties
of hermitian and unitary operators and the link between them.
Several observables A, B, C, . . . have their state kets |aj i, |bk i, |cl i, . . .
with probability amplitudes haj |bk i, hbk |cl i, hcl |aj i, . . . . These amplitudes
are not independent, however, but must obey the composition law
X
aj bk = aj cl cl bk , (1.1.22)
l
The wrong interpretation after (1.1.22) would then imply that both C and
D have definite, though unknown, values at the intermediate stage because
the two sums are on equal footing. But this is utterly impossible.
Given operator A with its (nondegenerate) eigenvalues aj and the kets
|aj i, can we always find another observable, B, such that A, B are a pair
of complementary observables? Yes, we can by an explicit construction, for
which
N
1 X 2π
bk = √ aj ei N jk (1.1.27)
N j=1
is the basic example; more about this in Section 1.2.1. It is here assumed
that we deal with a quantum degree of freedom for which there can be at
most N different values for any measurement.
We need to verify that the B states of this construction are orthonormal.
Indeed, they are,
1 X −i 2π jk 2π
bk bl = e N aj am ei N lm
N j,m | {z }
= δjm
N
1 X −i 2π j(k − l)
= e N = δkl . (1.1.28)
N j=1
Then,
X
B= bk bk bk (1.1.29)
k
with any convenient choice for the nondegenerate B values bk will do. By
construction, we have
2 2
1 2π 1
aj bk = √ ei N jk = (1.1.30)
N N
so that A, B are a complementary pair, indeed. We note that this property
is actually primarily a property of the two bases of kets (and bras) associ-
ated with the pair of observables. A common terminology is to call such
pairs of bases unbiased.
Bohr’s principle of complementarity 7
a1 −→ a2 = U a1 ,
a2 −→ a3 = U a2 ,
..
.
aN −→ a1 = U aN , (1.2.1)
generally
U aj = aj+1 , (1.2.2)
U 2 aj = aj+2 , (1.2.3)
U N aj = aj+N = aj . (1.2.4)
Accordingly, we have
UN = 1 (1.2.5)
uN = 1 if U u = u u (1.2.6)
for which
2π
uk = ei N k , k = 1, 2, . . . , N (1.2.7)
are the possible solutions, all of which occur. We can, therefore, write the
equation for U also in the factorized form
U N − 1 = (U − u1 )(U − u2 ) · · · (U − uN )
N
Y
= (U − uk ) . (1.2.8)
k=1
to X = U/uk ,
N
X −1
N N
U − 1 = (U/uk ) − 1 = (U/uk − 1) (U/uk )l
l=0
N
X
= (U/uk − 1) (U/uk )l , (1.2.12)
l=1
Bohr’s principle of complementarity 9
where the first step exploits uNk = 1 and the last step makes use of
(U/uk )0 = 1 = (U/uk )N . Now, for U → uk , the sum equals N , and so we
arrive at
N
1 X l
uk uk = U/uk . (1.2.13)
N
l=1
We have now a second set of bras and kets, for which we can repeat the
story of cyclic permutations, effected by the unitary operator V ,
uk V = uk+1 ,
uk V 2 = uk+2 ,
..
.
uk V N = uk . (1.2.20)
In full analogy with what we did above for U , we conclude here that
N
1 X k
vl v l = (V /vl ) (1.2.22)
N
k=1
and then
2 1
uN vl vl uN = uN vl = . (1.2.24)
N
1
Here, too, we choose huN |vl i = √ and establish
N
N
1 X −i 2π kl
vl = √ e N uk (1.2.25)
N k=1
as well as
N
1 X 2π
vl = √ uk ei N kl . (1.2.26)
N k=1
Bohr’s principle of complementarity 11
Can we continue like this and get more and more sets of kets? No!
Because the kets |vl i are identical with the kets |al i; see
N
X 1 2π
vl = uk √ ei N kl
N
k=1 | {z }
= uk al
!
X
= uk uk al = al . (1.2.27)
k
| {z }
=1
UN = 1 , V N = 1. (1.2.29)
uk U V = uk uk V = uk uk+1 ,
uk V U = uk+1 U = uk+1 uk+1 . (1.2.32)
2π
Since uk+1 = uk ei N , this establishes
2π 2π
uk V U = ei N uk uk+1 = ei N uk U V , (1.2.33)
12 Basic Kinematics and Dynamics
The generalization to
2π 2π
U k V l = e−i N kl V l U k , V l U k = ei N kl U k V l (1.2.35)
is immediate. These are the Weyl∗ commutation relations for the comple-
mentary pair U, V .
or can be brought into this form. It is written here such that all U s are
to the left of all V s in the products, but this is no restriction because the
relations (1.2.35) state that other products can always be brought into this
U, V -ordered form.
In fact, all such functions of U and V make up all operators for this
degree of freedom, which is to say that the complementary pair U, V is
algebraically complete. To make this point, we consider an arbitrary opera-
tor F and note that then the numbers huk |F |vl i are known. We normalize
these mixed matrix elements by dividing by huk |vl i, thus defining the set
of N 2 numbers
uk F vl
f (uk , vl ) = . (1.2.37)
uk vl
Multiply by |uk ihuk | from the left and by |vl ihvl | from the right and sum
over k and l,
X X
uk uk f (uk , vl ) vl vl = uk uk vl f (uk , vl ) vl
k,l k,l
| {z }
= uk F vl
X X
= uk uk F vl vl = F . (1.2.38)
k l
| {z } | {z }
=1 =1
∗ Claus Hugo Hermann Weyl (1885–1955)
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would have served to strengthen and rest him. But how to come by
so much now? How?
The character of the places frequented by the coolies, bhisties
(water-carriers), hadjis and even beggars like Ibn, while without any
of the so-called luxuries of these others, and to the frequenters of
which the frequenters of these were less than the dust under their
feet, were still, to these latter, excellent enough. Yea, despised as
they were, they contained charpoys on which each could sit with his
little water-chatty beside him, and in the centre of the circle one such
as even the lowly Ibn, a beggar, singing his loudest or reciting some
tale—for such as they. It was in such places as these, before his
voice had wholly deserted him, that Ibn had told his tales. Here,
then, for the price of a few anna, they could munch the leavings of
the khat market, drink kishr and discuss the state of the world and
their respective fortunes. Compared to Ibn in his present state, they
were indeed as lords, even princes.
But, by Allah, although having been a carrier and a vendor himself
in his day, and although born above them, yet having now no voice
nor any tales worth the telling, he was not even now looked upon as
one who could stand up and tell of the wonders of the Jinn and
demons and the great kings and queens who had reigned of old.
Indeed, so low had he fallen that he could not even interest this
despised caste. His only gift now was listening, or to make a pathetic
picture, or recite the ills that were his.
Nevertheless necessity, a stern master, compelled him to think
better of his quondam tale-telling art. Only, being, as he knew, wholly
unsuited to recite any tale now, he also knew that the best he could
do would be to make the effort, a pretense, in the hope that those
present, realizing his age and unfitness, would spare him the
spectacle he would make of himself and give him a few anna
wherewith to ease himself then and there. Accordingly, the hour
having come when the proffered services of a singer or story-teller
would be welcomed in any mabraz, he made his way to this region of
many of them and where beggars were so common. Only, glancing
through the door of the first one, he discovered that there were far
too few patrons for his mood. They would be in nowise gay, hence
neither kind nor generous as yet, and the keeper would be cold. In a
second, a little farther on, a tom-tom was beginning, but the guests
were only seven in number and but newly settled in their pleasure. In
a third, when the diaphanous sky without was beginning to pale to a
deep steel and the evening star was hanging like a solitaire from the
pure breast of the western firmament, he pushed aside the veiling
cords of beads of one and entered, for here was a large company
resting upon their pillows and charpoys, their chatties and hubbuks
beside them, but no singer or beater of a tom-tom or teller of tales as
yet before them.
“O friends,” he began with some diffidence and imaginings, for well
he knew how harsh were the moods and cynical the judgments of
some of these lowest of life’s offerings, “be generous and hearken to
the tale of one whose life has been long and full of many unfortunate
adventures, one who although he is known to you—”
“What!” called Hussein, the peddler of firewood, reclining at his
ease in his corner, a spray of all but wilted khat in his hand. “Is it not
even Ibn Abdullah? And has he turned tale-teller once more? By
Allah, a great teller of tales—one of rare voice! The camels and
jackals will be singing in Hodeidah next!”
“An my eyes deceive me not,” cried Waidi, the water-carrier, at his
ease also, a cup of kishr in his hands, “this is not Ibn Abdullah, but
Sindbad, fresh from a voyage!”
“Or Ali Baba himself,” cried Yussuf, the carrier, hoarsely. “Thou
hast a bag of jewels somewhere about thee? Now indeed we shall
hear things!”
“And in what a voice!” added Haifa the tobacco-tramp, noting the
husky, wheezy tones with which Ibn opened his plea. “This is to be a
treat, truly. And now we may rest and have wonders upon wonders.
Ibn of Mecca and Jiddah, and even of marvelous Hodeidah itself, will
now tell us much. A cup of kishr, ho! This must be listened to!”
But now Bab-al Oman, the keeper, a stout and cumbrous soul,
coming forth from his storeroom, gazed upon Ibn with mingled
astonishment and no little disfavor, for it was not customary to permit
any of his customers of the past to beg in here, and as for a singer or
story-teller he had never thought of Ibn in that light these many
years. He was too old, without the slightest power to do aught but
begin in a wheezy voice.
“Hearken,” he called, coming over and laying a hand on him, the
while the audience gazed and grinned, “hast thou either anna or
rupee wherewith to fulfill thy account in case thou hast either khat or
kishr?” The rags and the mummy-like pallor of the old man offended
him.
“Do but let him speak,” insisted Hussein the peddler gaily, “or
sing,” for he was already feeling the effects of his ease and the
restorative power of the plant. “This will be wonderful. By the voices
of eleven hundred elephants!”
“Yea, a story,” called Waidi, “or perhaps that of the good Cadi of
Taiz and the sacred waters of Jezer!”
“Or of the Cadi of Mecca and the tobacco that was too pure!”
Ibn heard full well and knew the spectacle he was making of
himself. The references were all too plain. Only age and want and a
depressing feebleness, which had been growing for days, caused
him to forget, or prevented, rather, his generating a natural rage and
replying in kind. These wretched enemies of his, dogs lower than
himself, had never forgiven him that he had been born out of their
caste, or, having been so, that he had permitted himself to sink to
labor and beg with them. But now his age and weakness were too
great. He was too weary to contend.
“O most generous Oman, best of keepers of a mabraz—and thou,
O comfortable and honorable guests,” he insisted wheezily, “I have
here but one pice, the reward of all my seekings this day. It is true
that I am a beggar and that my coverings are rags, yet do but
consider that I am old and feeble. This day and the day before and
the day before that—”
“Come, come!” said Oman restlessly and feeling that the custom
and trade of his mabraz were being injured, “out! Thou canst not sing
and thou canst not tell a tale, as thou well knowest. Why come here
when thou hast but a single pice wherewith to pay thy way? Beg
more, but not here! Bring but so much as half a rupee, and thou shalt
have service in plenty!”
“But the pice I have here—may not I—O good sons of the Prophet,
a spray of khat, a cup of kishr—suffer me not thus be cast forth! ‘—
and the poor and the son of the road!’ Alms—alms—in the name of
Allah!”
“Out, out!” insisted Oman gently but firmly. “So much as ten anna,
and thou mayst rest here; not otherwise.”
He turned him forth into the night.
And now, weak and fumbling, Ibn stood there for a time,
wondering where else to turn. He was so weak that at last even the
zest for search or to satisfy himself was departing. For a moment, a
part of his old rage and courage returning, he threw away the pice
that had been given him, then turned back, but not along the street
of the bazaars. He was too distrait and disconsolate. Rather, by a
path which he well knew, he circled now to the south of the town,
passing via the Bet-el-Fakin gate to the desert beyond the walls,
where, ever since his days as a pack servant with the Bedouins, he
had thought to come in such an hour. Overhead were the stars in
that glorious æther, lit with a light which never shines on other soils
or seas. The evening star had disappeared, but the moon was now
in the west, a thin feather, yet transfiguring and transforming as by
magic the homely and bare features of the sands. Out here was
something of that beauty which as a herdsman among the Bedouins
he had known, the scent of camels and of goats’ milk, the memory of
low black woolen tents, dotting the lion-tawny sands and gazelle-
brown gravels with a warm and human note, and the camp-fire that,
like a glowworm, had denoted the village centre. Now, as in a dream,
the wild weird songs of the boys and girls of the desert came back,
the bleating of their sheep and goats in the gloaming. And the
measured chant of the spearsmen, gravely stalking behind their
charges, the camels, their song mingling with the bellowing of their
humpy herds.
“It is finished,” he said, once he was free of the city and far into the
desert itself. “I have no more either the skill nor the strength
wherewith to endure or make my way. And without khat one cannot
endure. What will be will be, and I am too old. Let them find me so. I
shall not move. It is better than the other.”
Then upon the dry, warm sands he laid himself, his head toward
Mecca, while overhead the reremouse circled and cried, its tiny
shriek acknowledging its zest for life; and the rave of a jackal,
resounding through the illuminated shade beyond, bespoke its desire
to live also. Most musical of all music, the palm trees now answered
the whispers of the night breeze with the softest tones of falling
water.
“It is done,” sighed Ibn Abdullah, as he lay and wearily rested.
“Worthless I came, O Allah, and worthless I return. It is well.”
VII
TYPHOON