Gaseous State-4

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CHEMISTRY

Course: VelocIITy 1.0. VPS - 4 Date: 10 – 08 – 2017


JR. C+ STATES OF MATTER

1. Among N2,O2 and SO2 the gas with high rate of diffusion is
A) O2 B) SO2 C) N2 D) All are same

2. Which of the following pair of gases diffuse through a porous plug with the same rates of
diffusion.
A) CO, NO B) NO2, CO2 C) NH3, PH3 D) NO, C2H6

3. A mixture of 3 gases X(density= 0.90), Y (density=0.178) and Z (density=0.42) is enclosed


in a vessel at constant temperature. When the equilibrium is established the
A) Gas X will be at the top of the vessel
B) Gas Y will be at the top of the vessel
C) Gas Z will be at the top of the vessel
D) Gases will mix homogeneously through out the vessel

4. Which of the following mixture of gases cannot be separated by diffusion method?


A) NO + C2H6 B) NO + NO2 C) CO + CO2 D) C2H4 + C2H6

5. The correct order of diffusion for the gases H2, N2, O2 and NH3 is
A) H2> N2> O2 > NH3 B) NH3> O2> N2> H2
C) H2> N2> NH3> O2 D) H2> NH3> N2> O2

6. Under the same conditions the rates of diffusion of two gases are in the ratio 1 : 4. The
ratio of their vapour densities is
A) 2 : 1 B) 1 : 2 C) 16 : 1 D) 1 : 16

7. Rate of diffusion of a gas is 720 mL/minute. But the gas diffused for 20 seconds only.
The volume of the gas diffused in mL is
A) 240 B) 120 C) 60 D) 30

8. Assuming that at S.T.P. gas A has a density of 0.09 gram per litre and gas B has a density
of 1.44 gram per litre, the ratio between the rates of diffusion of A and B is
A) 1 :16 B) 16:1 C) 2 :1 D) 4 : 1

9. Two grams of H2 diffuses in 10 minutes. The weight of O2 that can diffuse from the same
container in the same time under similar conditions is
A) 4 g B) 0.5 g C) 6 g D) 8 g

10. One litre of methane takes 20 minutes to diffuse out of a vessel. How long will it take to
diffuse one litre of SO2 through the vessel under the same conditions of temperature and
pressure.
A) 40 min. B) 24 min C) 20 min D) 10 min

11. According to Graham’s law at a given temperature, the rates of diffusion rA / rB of gasses A
and B is given by (where, P and M are partial pressure and molar masses)
1 1 1 1
p  M 2 M  p 2 p  M 2 M  p 2
(A) A  A  (B) A  A  (C) A  B  (D) A  A 
pB  MB  MB  pB  pB  M A  MB  pB 
2

12. A uniform glass tube of 100 cm length is connected to a bulb containing Hydrogen at one
end and another bulb containing oxygen at the other end at the same temperature and
pressure. The two gases meet for the first time at the following distance from the oxygen
end.
A) 80 cm B) 50 cm C) 20 cm D) 6.66 cm

13. Oxygen is filled in one vessel and Hydrogen is filled in another vessel at the same
conditions. if oxygen escapes out at 95cc per hour, hydrogen will escapes out at
A) 270 cc per hour B) 380 cc per hour
C) 240 cc per hour D) 300 cc per hour

14. Rate of diffusion of a gas X is twice that of another gas of molecular weight 64. Molecular
weight of gas X is
A) 16 B) 32 C) 8 D) 2

15. At the same temperature and pressure two identical balloons were filled with methane
and sulphurdioxide. If sulphurdioxide escaped at the rate of 100ml per second the
methane would escape at the rate of
A) 50 mL/sec B) 100 mL/sec C) 200 mL/sec D) 400 mL/sec

235 238
16. The ratio of the rates of diffusion of UF6 and UF6 is
A) 3 B) 1.55 C) 1.414 D) 1.006

17. At a certain temperature and pressure, 100 mL of CO2 diffuses in some time. In the same
time volume of N2O diffused in mL is
A) 200 B) 400 C) 100 D) 600

18. Two gases A and B having the same volume, effuse through an orifice in 30 and 10
seconds respectively. If molar mass of A is 162, the molar mass of gas B will be
A) 18 B) 36 C) 54 D) 72

19. 180 mL of a hydrocarbon of molecular weight 16 diffuses in 1.5 minutes. Under the same
conditions, the time taken by 120 mL of SO2 to diffuse in minutes is
A) 2 B) 1.5 C) 1 D) 1.75

20. 50 mL of H2 gas diffuse through a small hole from a vessel in 20 min. Time taken by
40 mL of O2 gas to diffuse under similar conditions will be
(A) 12 min (B) 64 min (C) 8 min (D) 32 min

21. 100 mL of O2 gas diffuse in 10 s. 100 mL of gas X diffuse in t s. Gas X and time t
respectively can be
(A) H2 , 2.5 s (B) SO2 , 16s (C) CO, 10 s (D) He, 4 s

22. If helium and methane are allowed to diffuse out of the container under the similar
conditions of temperature and pressure, then the ratio of rate of diffusion of helium to
methane is
(A) 2.0 (B) 1.0 (C) 0.5 (D) 4.0

23. 1 mole of helium and 3 moles of N2 exert a pressure of 16 atm. Due to a hole in the vessel
in which mixture is placed, mixture leaks out. Thus, composition of the mixture effusing
out initially is
(A) 1.14 (B) 0.88 (C) 2.65 (D) 0.38
3

Key

1 2 3 4 5 6 7 8 9

C D D A D C A D D

10 11 12 13 14 15 16 17 18

A C C B A C D C A

19 20 21 22 23

A B A A B

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