KATHERINE ARIAS FERNANDEZ

MODELADO Y SIMULACION
PRIMER EJERCICIO-EXAMEN PARCIAL
clc;
V1=1000;
V2=1500;
V3=100;
V4=500%[L]

V4 = 500

Fo=1000; %[L/mol]
F5=100;
F6=1000;
Caf=1; %[mol/L]
k1=0.1;
k2=0.2;
k3=0.4;
k4=0.3;
%Siendo x(1)=Ca1, x(2)=Ca2, x(3)=Ca3, x(4)=Ca4; x(5)=F1 x(6)=F2
%f3=x(7) x(8)=F7
r1=@(x) k*x(1);
r2=@(x) k*x(2);
r3=@(x) k*x(3);
r4=@(x) k*x(4);

F1=Fo;
F2=F1+F6;
F3=F2+F5;
F7=F3-F6;
F4=F7;

Ca1=@(t,x) (Fo/V1)*Caf-(F1/V1)*x(1)-k1*x(1);
Ca2=@(t,x) (F1/V2)*x(1)+(F6/V2)*x(3)-(F2/V2)*x(2)-k2*x(2);
Ca3=@(t,x) (F2/V3)*x(2)+(F5/V3)*x(4)-(F3/V3)*x(3)-k3*x(3);
Ca4=@(t,x) (F7/V4)*x(3)-(F4/V4)*x(4)-k4*x(4);

%ODE solver
fun=@(t,x)[Ca1(t,x);Ca2(t,x);Ca3(t,x);Ca4(t,x)];
[t,x]=ode45(fun,[0:0.1:10],[0 0 0 0]);

plot(t,x(:,1),t,x(:,2),t,x(:,3),t,x(:,4));
xlabel('Tiempo[s]');ylabel('Concentraciones [mol/l]');
title('Ci vs t');legend('Ca1','Ca2','Ca3','Ca4');grid on;

1
 %Concentraciones en tabla
Tiempo_final=t(100);%Tiempo escogido
Concentracion_final=x(100);
table(Tiempo_final,Concentracion_final)

ans = 1×2 table

Tiempo_final Concentracion_final

1 9.9000 0.9091

CONCENTRACIONES EN ESTADO ESTACIONARIO

eqn1=@(x) (Fo/V1)*Caf-(F1/V1)*x(1)-k1*x(1);
eqn2=@(x) (F1/V2)*x(1)+(F6/V2)*x(3)-(F2/V2)*x(2)-k2*x(2);
eqn3=@(x) (F2/V3)*x(2)+(F5/V3)*x(4)-(F3/V3)*x(3)-k3*x(3);
eqn4=@(x) (F7/V4)*x(3)-(F4/V4)*x(4)-k4*x(4);

sis1=@(x) [eqn1(x);eqn2(x);eqn3(x);eqn4(x)]

sis1 = function_handle with value:

@(x)[eqn1(x);eqn2(x);eqn3(x);eqn4(x)]

%ODE solver
x=fsolve(sis1,[0 0 0 0])

Equation solved.

fsolve completed because the vector of function values is near zero

as measured by the value of the function tolerance, and
the problem appears regular as measured by the gradient.

2
<stopping criteria details>
x = 1×4
0.9091 0.6859 0.6685 0.5883

Ca1e=x(1) %[mol/L]

Ca1e = 0.9091

Ca2e=x(2)

Ca2e = 0.6859

Ca3e=x(3)

Ca3e = 0.6685

Ca4e=x(4)

Ca4e = 0.5883