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Phase Milestone-2_13th_JEE_Mains_(Hindi)
TEST DATE 13-08-2023
Syllabus State of Matter Complete, Some Basic Concept of Chemistry Complete, Redox
Reaction Complete, Atomic structure Complete.
Submission Date 26-08-23 Type Date 26-07-2023 | Devendra Gurjar
Proof reader Name Lipi ma’am F. P. Date
Test Maker Rajeev Ranjan Sir Signature
Test Checker Harish Patidar Sir Signature
Guardian Name NB Sir Signature

Mains Pattern Instruction

Section A Section B
(Marking Scheme : Correct +4, (Marking Scheme : Correct +4,
Incorrect –1) Incorrect 0)
Subject Question Type : SCQs Question Type : Numerical Value Marks
Number of Number of Number of Number of
Questions in Questions can be Questions in Questions can be
paper attempted paper attempted
Physics 20 20 10 5 100
Chemistry 20 20 10 5 100
Maths 20 20 10 5 100
Total 90 Questions | 75 Questions can be attempted 300
Note: Mains Integers answers should be positive 0 to 999 only.
Single Correct Questions: 10 Numerical Type Questions: 5

Single Choice Questions Single Choice Questions

1. For a real gas its deviation from ideal behavior is 1. ,d okLrfod xSl ds fy, vkn”kZ O;ogkj ls bldk
maximum at: fopyu vf/kdre gksrk gS:
(A) 0ºC and 10 atm (A) 0ºC rki vkSj 10 atm nkc ij
(B) 100ºC and 5 atm (B) 100ºC rki vkSj 5 atm nkc ij
(C) – 20ºC and 5 atm
(C) – 20ºC rki vkSj 5 atm nkc ij
(D) – 40ºC and 20 atm
(D) – 40ºC rki vkSj 20 atm nkc ij
Sol. (D)
Sol. (D)
Theory based
Theory based

T 
2. What is the ratio of time periods  1  in third orbit 2. He+ vk;u dh r`rh; d{kk vkSj Li+2 vk;u dh f}rh;
 T2  T 
of He+ ion and second orbit of Li+2 ion? d{kk esa vkorZdky  1  dk vuqikr D;k gS?
 T2 
3 2
(A) (B) 3 2
2 3 (A) (B)
2 3
243 32
(C) (D) 243 32
32 243 (C) (D)
32 243
Sol. (C)
Sol. (C)
33
T0  5 33
T1
= 22 =  3  = 243 T0  5
  T1 2 2  3  243
T2 23  2  32 = =  =
T0  2 T2 23  2  32
3 T0  2
3
 2

3. For the redox reaction 3. fuEu jsMkWDl vfHkfØ;k ds fy,]

MnO−4 + C2O42− + +2
+ H → Mn + CO2 + H2O MnO−4 + C2O42− + H+ → Mn +2 + CO2 + H2O
The correct coefficients of the product (Mn+2, CO2, larqfyr vfHkfØ;k ds fy, mRikn (Mn+2, CO2, H2O)
H2O) for the balanced reaction respectively are: ds lgh fLFkjkad Øe”k: gSa:
(A) 2, 5, 16 (B) 2, 10, 8 (A) 2, 5, 16 (B) 2, 10, 8
(C) 2, 10, 16 (D) 4, 10, 8 (C) 2, 10, 16 (D) 4, 10, 8
Sol. (B) Sol. (B)
MnO−4 + 8H+ + 5e− → Mn+2 + 4H2O  2 MnO−4 + 8H+ + 5e− → Mn+2 + 4H2O  2
   
C2O42− → 2CO2 + 2e−   5 C2O42− → 2CO2 + 2e−   5
   
+ +2
2MnO4– + 5C2O2–
4 + 16H → 2Mn + 10CO2 + 8H2O 2MnO4– + 5C2O2– + +2
4 + 16H = 2Mn + 10CO2 + 8H2O

4. The mass of H2O2 present in 500 mL of 5.675 V 4. 5.675 V, H2O2 foy;u ds 500 mL esa mifLFkr H2O2
H2O2 solution is: dk nzO;eku gS:
(A) 17 g (B) 34 g
(A) 17 g (B) 34 g
(C) 68 g (D) 8.5 g
(C) 68 g (D) 8.5 g
Sol. (D)
Sol. (D)
 5.675 
m ( H2O2 ) = 0.5     34g = 8.5g  5.675 
 11.35  m ( H2O2 ) = 0.5     34g = 8.5g
 11.35 

5. A quantity of 1.4 g of a hydrocarbon gives 1.8 g of

5. gkbMªksdkcZu dh 1.4 g ek=k] iw.kZ ngu ij 1.8 g ty
water on complete combustion. The empirical
nsrh gSA gkbMªkd
s kcZu dk ewykuqikrh lw= gS:
formula of hydrocarbon is:
(A) CH (B) CH2
(A) CH (B) CH2
(C) CH3 (D) CH4
(C) CH3 (D) CH4
Sol. (B)
Sol. (B)
C H in Hydrocarbon
C H in Hydrocarbon
1
1 1.4 − 0.2g 1.8 = 0.2g
1.4 − 0.2g 1.8 = 0.2g 9
9
= 1.2g
= 1.2g
1.2 0.2
1.2 0.2 mol mol
mol mol 12 1
12 1
0.1 0.2
0.1 0.2
1 2
1 2
E.F. = CH2
E.F. = CH2

6. (n + ) fu;e ds vuqlkj ‘np’ Lrj iw.kZ Hkjus ds ckn

6. According to (n + ) rule after completing ‘np’ level,
the electron enters into:
bysDVªkWu fdl esa izos”k djsxk:
(A) (n – 1)d (B) (n + 1)s (A) (n – 1)d (B) (n + 1)s
(C) nd (D) (n + 1)p (C) nd (D) (n + 1)p
Sol. (B) Sol. (B)

(n–1)s (n–1)p (n–1)d (n–1)f (n–1)s (n–1)p (n–1)d (n–1)f

ns np nd nf ns np nd nf

(n+1)s (n+1)p (n+1)d (n+1)f (n+1)s (n+1)p (n+1)d (n+1)f

 3

7. (1) HOCl + H2O2 → H3O+ + Cl– + O2 7. (1) HOCl + H2O2 → H3O+ + Cl– + O2
(2) I2 + H2O2 + 2OH– → 2I– + 2H2O + O2 (2) I2 + H2O2 + 2OH– → 2I– + 2H2O + O2
Choose the correct option. lgh fodYi dk p;u dhft,A
(A) H2O2 acts as an oxidising and reducing agent (A) H2O2, lehdj.k (1) vkSj (2) esa Øe”k% vkWDlhdkjd
respectively in equation (1) and (2) vkSj vipk;d ds :i esa dk;Z djrk gSA
(B) H2O2 acts as oxidising agent in equations (1) (B) H2O2, lehdj.k (1) vkSj (2) esa vkWDlhdkjd ds :i
and (2) esa dk;Z djrk gSA
(C) H2O2 acts as reducing agent in equations (1) and
(C) H2O2, lehdj.k (1) vkSj (2) esa vipk;d ds :i esa
(2)
dk;Z djrk gSA
(D) H2O2 acts as reducing and oxidising agent
(D) H2O2, lehdj.k (1) vkSj (2) esa Øe”k% vipk;d
respectively in equation (1) and (2)
Sol. (C)
vkSj vkWDlhdkjd ds :i esa dk;Z djrk gSA
Theory based Sol. (C)
Theory based
8. V mL of a gaseous mixture of O2 and X containing
20% of X diffused through a small hole in 250 8. 20% X ;qDr O2 vkSj X ds xSlh; feJ.k dk V mL, 250
second and same volume of pure O2 under identical lsdMa esa lw{e fNnz ds ek/;e ls folfjr gksrk gS vkSj
condition takes 200 second through the same hole. le:i ifjfLFkfr;ksa esas “kq) O2 dk leku vk;ru] leku
The molar mass of X is: fNnz ls folfjr gksus esa 200 lsdMa ysrk gSA X dk eksyj
(A) 42 (B) 82 nzO;eku gS:
(C) 122 (D) 144 (A) 42 (B) 82
Sol. (C) (C) 122 (D) 144
V Sol. (C)
250 = 32 V
V 80  32 + 20  Mx 250 = 32
200 100 V 80  32 + 20  Mx
2 200 100
4 3200
 5  = 2560 + 20 M 2
  4 3200
 5  = 2560 + 20 M
x

3200   x
2560 + 20 Mx =
0.64 3200
2560 + 20 Mx =
Mx = 122 0.64
Mx = 122
9. 10 mL, 0.5 M K2SO4(aq) solution is mixed with 40
mL, 0.25 M Al2(SO4)3(aq) solution then molarity of 9. 10 mL, 0.5 M K2SO4(aq) foy;u dks 40 mL, 0.25 M

SO24− in the resultant solution is: Al2(SO4)3(aq) foy;u ds lkFk fefJr fd;k tkrk gS] rks

(A) 0.35 (B) 0.7 ifj.kkeh foy;u esa SO24− dh eksyjrk gS:
(C) 1.05 (D) 1.40 (A) 0.35 (B) 0.7
Sol. (B) (C) 1.05 (D) 1.40
10  0.5 + 40  0.25  3 Sol. (B)
SO24−  = = 0.7 M
  10 + 40 10  0.5 + 40  0.25  3
SO24−  = = 0.7 M
  10 + 40
10. For 1 mole of gas the plot of PV vs P at constant
temperature is shown below. 10. 1 eksy xSl ds fy, fu;r rki ij PV cuke P vkys[k
uhps n”kkZ;k x;k gSA P, xSl dk nkc vkSj V, xSl dk
 4

B
vk;ru gSA fcanw B ij lEihM~;rk xq.kkad dk eku D;k
PV gS?

A B
PV
P
P is the pressure and V is the volume of the gas. A
What is the value of compressibility factor at point P
B?
a b
(A) 1 − (B) 1 +
a b VRT V
(A) 1 − (B) 1 +
VRT V Pb Pb
(C) 1 + (D) 1 −
Pb Pb RT RT
(C) 1 + (D) 1 −
RT RT Sol. (3)
Sol. (C) At high pressure
At high pressure P(V–b) = RT
P(V–b) = RT PV – Pb = RT
PV – Pb = RT
Pb
Z– =1
Pb RT
Z– =1
RT Pb
Z=1+
Pb RT
Z=1+
RT

Numerical Type Questions Numerical Type Questions

1. If oxidation state of Cr in CrO5 is x and oxidation 1. ;fn CrO5 esa Cr dh vkWDlhdj.k voLFkk x gS vkSj
state of Cr in K3CrO8 is y, then x + y is______. K3CrO8 esa Cr dh vkWDlhdj.k voLFkk y gS, rks x + y
Sol. (11) ______ gS:
x=6 ; y=5 Sol. (11)
x + y = 11 x=6 ; y=5
x + y = 11
2. If x = ratio of Boyle’s temperature to its critical
temperature 2. ;fn x = ckW;y rkieku vkSj blds Økafrd rki dk
z = compressibility factor at critical point then
x vuqikr gSA
z x
is______. z = Økafrd fcanq ij lEihM~;rk xq.kkad gS] rks gS:
z
Sol. (9) Sol. (9)
a a
Rb 27
x= = x = Rb =
27
8 a 8 8 a 8
27 Rb 27 Rb
Pc Vc 3
z= = z=
Pc Vc 3
=
RTc 8 RTc 8
27 27
x 8
= =9 x 8
= =9
z 3 z 3
8 8
 5

3. Among the following the total number of 3. fuEu esa ls lkanzrk inksa dh dqy la[;k crkb,] tks
concentration terms which depends on temperature rkieku ij fuHkZj djrh gS&
is/are: (a) % w/w (b) % w/v
(a) % w/w (b) % w/v (c) lkeF;Z (d) eksyyrk
(c) strength (d) molality (e) eksyjrk (f) ukWeZyrk
(e) molarity (f) Normality
Sol. (4)
Sol. (4)
Theory based
Theory based

4. Li+2 vk;u dh ckej Js.kh dh izFke js[kk dh rjax la[;k

4. The ratio of wave number of first line of Balmer
vkSj He+ vk;u dh czsdVs Js.kh dh f}rh; js[kk dh rjax
series of Li+2 ion to wave number of second line in
la[;k dk vuqikr x gSA x dk eku …………gSA
brackett series of He+ ion is x. The value of x
Sol. (9)
is_______.
1 1
Sol. (9) R H  32   − 
4 9 =9
1 1 x=
R H  32   −  1 1
4 9 =9 R H  22   − 
x=  16 36 
1 1
R H  22   − 
 16 36 

5. ;fn izksVkWu vkSj vYQk d.k dh ns&czkWXyh rjaxnS/;Z dk

1
5. If ratio of de Broglie wavelength of a proton and an vuqikr gS] rks mudh xfrt ÅtkZ dk vuqikr gksxk:
1 3
alpha particle is then ratio of their kinetic energy (fn;k x;k gS: izkV
s kWu vkSj vYQk d.kksa dk nzO;eku Øe”k:
3
will be: (Given : mass of proton and alpha particles 1 amu vkSj 4 amu gSa)
are 1 amu and 4 amu respectively) Sol. (36)
Sol. (36) h
h p 2mp KE p m KE
= =
p 2mp KE p m KE  h mp KE p
= = 2m KE
 h mp KE p
2m KE 2
KE   p  mp
=  
KE   p  mp
2
KE p    m
=  
KE p    m 2
KEp    m
=  
KE  p  mp
2
KEp    m
=  
KE  p  mp KE p
= 32  4 = 36
KE p KE
= 32  4 = 36
KE