50 Organic Chemistry - Some Basic Principles and Techniques NCERT Maps

1. Number of σ and π bonds present in the 4. IUPAC name of the given compound is (c) In methyl halide, carbon is electrophilic
given molecule respectively are centre
CH3 – CH = CH – CH = CH – CN Correct statements are
[NCERT Pg. 335] (1) (a) and (b) only (2) (b) and (c) only
(1) 13 and 3 (2) 13 and 2 (3) (a), (b) and (c) (4) (a) and (c) only
[NCERT Pg. 343] 8. Which among the following is a temporary
(3) 14 and 4 (4) 13 and 4
(1) 1-Butyl-3-ethylcyclopentane effect? [NCERT Pg. 355]
2. Which among the following is heterocyclic
(2) 3-Butyl-1-ethylcyclopentane (1) Hyperconjugation
aromatic compound? [NCERT Pg. 340]
(3) 1-Butyl-4-ethylcyclopentane (2) Resonance
(3) Inductive effect
(4) 4-Butyl-1-ethylcyclopentane
(1) (2) (4) Electromeric effect
5. Propanone and propanal are
9. Consider the following species
[NCERT Pg. 349]
(1) Chain isomers
(3) (4)
(2) Metamers
(3) Position isomers
3. Isobutyl group among the following is
[NCERT Pg. 341] (4) Functional group isomers
(1) CH3 − CH2 − CH − 6. Most stable carbocation among the
[NCERT Pg. 355]
| following is [NCERT Pg. 349]
CH3 Hyperconjugation will be observed in
⊕ +
(1) Ph − CH2 (2) (CH3 )3C (1) (i) and (ii) only
(2) CH3 − CH − CH2 −
| + + (2) (ii) and (iii) only
CH3 (3) (CH3 )2CH (4) CH3CH2
(3) (i) and (iii) only
CH3 7. Consider the following statements. (4) (i), (ii), (iii) and (iv)
| [NCERT Pg. 351] 10. The group which shows –I and –R effect is
(3) CH3 − C −
(a) A reagent that takes away an electron [NCERT Pg. 352, 354]
|
CH3 pair is called an electrophile (1) –Cl (2) –OR
(4) CH3 – CH2 – CH2 – CH2 – (b) A nucleophile is electron rich species (3) –NO2 (4) –NHCOR
NCERT Maps Organic Chemistry - Some Basic Principles and Techniques 51
11. Mixture of aniline and chloroform can be 17. Commonly used adsorbent(s) in column
easily separated by [NCERT Pg. 357] chromatography is/are [NCERT Pg. 360]
(1)
(1) Distillation (1) Silica gel
(2) Alumina
(2) Fractional distillation
(3) Charcoal
(3) Steam distillation
(2) (4) Both (1) and (2)
(4) Sublimation
18. Which among the following is a nucleophile?
12. On treating sodium fusion extract with
[NCERT Pg. 351]
sodium nitroprusside solution blood red
(3) (1) BF3 (2) B2H6
colour is obtained. It indicates the presence
of which element(s) in the organic (3) SH (4) AlCl3
compound? [NCERT Pg. 363]
(4) 19. IUPAC name of the given compound is
(1) Nitrogen only
15. In sulphur estimation 0.25 g of an organic
(2) Sulphur only
compound gave 0.466 g of barium sulphate.
(3) Phosphorous only Percentage of sulphur in the compound is
(4) Nitrogen and sulphur both [NCERT Pg. 367]
13. Most stable carbanion among the following (1) 45.5% [NCERT Pg. 347]
is [NCERT Pg. 350] (2) 16.4% (1) 4-Ethyl-2-methylaniline
 (3) 56.5% (2) 4-Amino-1-ethyl-3-methylbenzene
(1) CH2 − NO2
(3) 4-Ethyl-6-methylaniline
(4) 25.6%

(2) CH3 (4) 4-Amino-1-ethyl-5-methylbenzene
16. The element which cannot be detected by
Lassaigne’s test is [NCERT Pg. 362] 20. Which among the following is a planar

(3) (CH3 )2CH molecule? [NCERT Pg. 335]
(1) Nitrogen
(1) CH2 = CH – CN

(4) CH2 − Ph (2) Sulphur (2) CH2 = C = CH2
(3) Chlorine (3) CH3 – CH = CH2
14. Kjeldahl’s method is not applicable to which
compound? [NCERT Pg. 366] (4) Oxygen (4) CH3 – CH = CH – CH3
 52 Organic Chemistry - Some Basic Principles and Techniques NCERT Maps
1. Urea can be synthesised by heating 9. In _______ cleavage, radical formation 15. In quantitative estimation of halogens by
_______. [NCERT Pg. 334] takes place. [NCERT Pg. 349] Carius method, a known mass of organic
2. _______ arises due to different alkyl chains compound is heated with fuming nitric acid
10. _______ technique is applied to separate
on either side of the functional group. substances which are steam volatile and are in presence of _______ in Carius tube.
[NCERT Pg. 349] immiscible with water. [NCERT Pg. 359] [NCERT Pg. 367]
3. Alkyl groups directly attached to the 11. Paper chromatography is a type of _______ 16. Hyperconjugation involves delocalization of
positively charged carbon stabilise the chromatography. σ electrons of C – H bond of an alkyl group
carbocations due to _______ and _______ directly attached to an atom of unsaturated
effects. [NCERT Pg. 349] [NCERT Pg. 362] system or to an atom with an unshared
4. A reagent that takes away an electron pair 12. The sodium fusion extract is boiled with _______. [NCERT Pg. 355]
is called _______. [NCERT Pg. 351] ferrous sulphate and then acidified with
17. Methyl propanoate and butanoic acid are
concentrated sulphuric acid, formation of
5. The _______ structures are hypothetical _______. [NCERT Pg. 348]
Prussian blue colour confirms the presence
and individually do not represent any real
of _______. [NCERT Pg. 363] 18. The structural unit _______ is called
molecule. [NCERT Pg. 353]
neopentyl group. [NCERT Pg. 341]
6. The IUPAC group prefix ‘formyl’ is used for 13. Nitrogen, sulphur, halogens and _______
present in an organic compound are 19. Glycerol is separated from spent-lye in soap
_______. [NCERT Pg. 345]
detected by Lassaigne’s test. industry by using _______ technique.
7. _______ structures have same number of [NCERT Pg. 358]
unpaired electrons. [NCERT Pg. 353] [NCERT Pg. 362]
20. [Fe(SCN)]2+ is _______ in colour.
8. _______ is also termed as no bond 14. Ammonium phosphomolybdate is _______
resonance. [NCERT Pg. 356] coloured compound. [NCERT Pg. 363] [NCERT Pg. 363]
  
 150 Answers NCERT Maps
Chapter-11 : The p-Block Elements
Sharpen Your Understanding Thinking in Context 11. Fullerene
1. (3) 2. (4) 1. Si(OH)4 12. CO(g) + H2(g)
3. (4) 4. (3) 2. HF, NaOH
13. H2CO3/ HCO3–
5. (4) 6. (2) 3.
14. ZSM-5
7. (3) 8. (1) 4. sp3
15. Lewis acid
9. (3) 10. (4) 5. Diborane
16. Shorter
11. (1) 12. (4) 6. Alkaline
17. Carboxyhaemoglobin
13. (1) 14. (3) 7. 4
15. (4) 16. (4) 8. Two 18. Lubricant
17. (2) 18. (2) 9. C14 19. Neutral
19. (4) 20. (3) 10. Sn 20. Two
Chapter-12 : Organic Chemistry - Some Basic Principles and Techniques
Sharpen Your Understanding Thinking in Context 11. Partition
1. (4) 2. (2) 1. Ammonium cyanate 12. Nitrogen
3. (2) 4. (1) 2. Metamerism 13. Phosphorus
5. (4) 6. (2) 3. Inductive and hyperconjugation
14. Yellow
7. (3) 8. (4) 4. Electrophile
15. Silver nitrate
9. (3) 10. (3) 5. Resonance
16. p-orbital
11. (1) 12. (4) 6. Aldehyde
17. Functional isomers
13. (1) 14. (3) 7. Resonance
18. (CH3)3CCH2 –
15. (4) 16. (4) 8. Hyperconjugation
19. Distillation under reduced pressure
17. (4) 18. (3) 9. Homolytic
19. (1) 20. (1) 10. Steam Distillation 20. Blood red