CaRceR [=> ALLEN SRGBT-4 [Pec RONEN ‘Academic Session : 2016-17 JEE (MAIN+ADVANCED) 2017 Cresin PYSTRERIA LG cree SINGLE CORRECT [+3 & -1] 1, Calculate [H*] of 0.01 MA*B* salt solution if K, HB = 10-2 (a) 10M (B) 107M (C) 62 x 10° (D)16 x 10M Ans. (D) Sol. 0.01 MHB B +H,O—=HB+OH t=0C cli-a) Ca Ca _Ca® IMBIIOH] Ky _jg2 ia B]CK,, 06 [OH] = Ca = 06 x 10% io H"] = ——_, = 16x10" W607 2. The solubilty of Co(OH), in water will be given by which of the following options if ts solubility product is 2.7 x 10 Mt uM y 6) 107 2 (a)3 x10" M (B) 10-7" M ozM (D)27 x 10M, Ans. (D) Sol. Co(OH}; ==Co™ +30H s 3s sx 278 =2.7 x 10 s=107M | But [OH] from water = 107M >> 10" 5-200" © 27102M 10 3. Forthe reaction takes place at certain temperature NHgHS(s}-—— NHs(g)+H,S(), ifequilibrium pressure is X bar, then A,G° would be (a)-2RTInx (B)-RTIn(X-In2)—(C)-2RT(InX-In2)__(D) None of these Ans. (C) Sol. Pri, AG°=-RTInK, = RT (In X — In2) CHEMISTRY. 1 [LN]4. Ifheat of reaction at constant volume exceeds that at constant pressure for an endothermic reaction at 25°C by 1192 Cal, what is the value of ratio K, /K, (R = 2 cal = 0.0821 L atm). (A) (0.0821 x 298)? (B) (0.0821 x 298) (C) (0.0821 x 2987 {D) Can't be calculated Ans. (A) Sol. AU = AH + 1192 1192 AH = AU +An,RT (i) => AH AU =Dn,RT or Ang = 555 RT) => DP = (0.0821 298)? K, =K(RTY"* on, 5. What will be the effect of adding 100 ml of 10% MHCI solution to a solution of HA having concentration O.1MPK, of HA = 10-5) (A) degree of dissociation of HA will decreases pH will remain constant {B) degree of dissociation of HA will increase and pH decreases. {C)neither pH nor degree ofdissociation of HA will change. {D) both degree of dissociation and pH will decrease Ans. (C) Sol. HAH’ +Ay OK x x ® 10° =x=10" =x - No effet on the cone. of H+ on adding 10° MHCI pHwill not change. « Degree of dissociation will not changes. 6. _Fromthe phase diagram of water and an aqueous solution containing non volatile solute, identify the incorrect option: (A) At temperattite T,, vapourpressure of solid and vapour pressure of liquid will be same. {B) Order of vapour pressure (P,,P,, P,) are P, > P,> P, Spat) (R=Pe sgt (PR =Pe Ans. (C) CHEMISTRY. 2 [JLN]Sol. (A) Temperature T,, represent tipple point of solvent where Solid = Liquid are in equilibrium hence vapour pressure of solid arid vapour pressure of liquid will be same. (B) Figure showing P, > P, > P, ‘vapour (C) Line corespondingto P,and P, vapour pressure Solid = vapour PAH [11 Henceln = Ra (D) Line correspondingto P, and P, vapour pressure Liquid = vapour AH, yf 11 R Rk T MORE THAN ONE CORRECT [+4 & -1] Hence In 7. Forthe exothermic action A\g) + Baja) C24) which of the following statements regarding change and effects fare true (A) Ifinert gas is added at constant pressure condition without affecting temperature then concentration of C, at new equilibrium will be more as compared to that at old equilibrium. (B) On increase of temperature extent of dissociation of A will decrease (C) On increase in pressure at constant temperature, the reaction willshiftin backward direction (0) If 46859 = 0 forthe reaction then AGREE wil bea negative value Ans. (BCD) 8. Whichof the following options are comet? (A) The difference between ionisation enthalpy (H,) and ionisation eneray (IE) is directly depencent on absolute temperature. (B) heat added to the system at lower temperature causes greater randomness as compared to same amount of heat added at higher temperature. (C) Acontainer having N,O, gas if heated will show an increase in intensity of brown colour, (D) Itis easier to remove H" from HPO}-as compared to that from H,PO,, ‘Ans. (ABC) COMPREHENSION TYPE [+3 & -1] Paragraph for Q.9 to Q.10 [One or More than one Correct] Rubber bands comprise of loosely packed chains of atoms. When streched, the chain of atoms get neatly lined up in rows and hence the entropy of system decreases where as when contracted the chains get tangled up in a mess increasing entropy of system. Also on stretching rubber band, its observed that any substance brought in its contact gets heated up. Based on this information, answer the following question. 9. Which of the following statement(s) is/are rue regardingthe change Rubber band ..icheay) ——> Rubberband gersead? (A) The changes spontaneous (B) The processis endothermic in nature (C) Entropy of the rubber band is inereasingin the process (D) Entropy of surroundings decreasing in the process. Ans. (ABCD) CHEMISTRY. 3 [LN]Sol. (A) Because AS increases so change is spontaneous, (B) Contraction is endothermic (Reverse of stretching) (C) Molecules get tangled up so entropy increases, (D) Process of endothermic so 4 Suey = SO OS Tae rer <0 10. Whatshould happen when a rubber band is heated ? (A) It should expand and get stretched (B) Itshould eontract. (C) Bonds/Attractions between the molecules of rubber band will keep on weakening. (D) The chains of molecules wil gt more tale Ans. (BCD) Sol. (A) On heatingit will get unstretched {B) should get contracted (C}On heetingbonds wll breek and attraction will keep on weekening (D) On contraction chain of molecules will get tangled up. MATRIX MATCH [+8 & 0] 11. Forthe given endothermic reaction Ag) —=2B(9) ‘The variation in concentration due to different changesis plotted. In column Il various changes are given and \you are supposed to match the entries in column-I with possible changes the system have undergone. Neglect the slope of change in concentration when system approaches equilibrium. Assume that changes are carried out very fast. § | g T effect effect effectll effect IV Time > Column Column I (A) Effect-1 (P) Addition of inert at constant pressure (B) Effect-ll (Q) Decrease in total equilibrium pressure by changing volume (C) Effect-it (R) Decreases in temperature at constant volume (D) Effect-1V (S) Addition of Bonly at constant volume (T) Addition of inert gas at constant volume Ans. (A) - (S), (B) - (T), (C) - (PQ), (D) - (R) CHEMISTRY. 4 [JUN]INTEGER TYPE [+4 & -1] 12. Calculate the heat required to completely vaporise 2 mols of a liquid A at constant pressure condition if its normal boiling point is 250 K. Express your answer in Keal (rounded off of nearest integer) [Given : R = 1.98 calimok K] [Give your answer round off & sum of digits and fill OMR sheet] Ans. (1) Sol. From Trouton nile Soap AS = 10,5 = = Tae Aap! & 250 «1,98 10.5 =5197.5eal For 2 moles 2 x 5197 = 10395 cal or 10.395 Keal 13. Calculate AG,,, Aig) + Bata) = 2AB a) (les/mol) for the given reaction at 300 K. and at partial pressure of 10% bar, 10" bar and 10 bar respectively for A,, B, and AB. Given : SH) AB = 180 kimol AH? A, = 60 kdimol SH} B,=29.5kimol 5 S} AB = 210 d/K mol AS; A, = 190J/Kmol AS) B, = 205 J/K mol Use : 2.308 R x 300 = 5750 Jimole [Give your answer as sum of digits and fill OMR sheet] Ans. (9) Sol. Aya) +Bojg = 2AB ia MS acson = [2X AS yal = ESagy, + Hb yy) AS = 25 JK"! mole AHeacion = (24Hig]-[Ha, + SH] AH = 270.5 kJ mot! Ph oy? 5 Qe 107x107 AG = AG + RT InQ AG = AH®—TAS + RT In Q 300%25 , 2.303xRx300Ing10 1000 1000 AG = 270.5 ki - 7.5 kJ + 5.75 x AG = 234.5 kdimole = 234 AG = 270.5 kd 14, _Asubstance has normal boiling point of 400 K. If 4S.p at 1 atm and 400 Kis 100 J/K mole, then calculate 1S lamandng at atm and 200 K forthe vaporization proces. Got substance in liquid phase = 50 dimole K Cot substance in vapour phase = 40 Jimole K [Express answer in J/K mole] [Give your answer as eum of digits and fill OMR sheet] Ans. (3) CHEMISTRY. 5 [JLN]Sol. 'S,.5 100 = AH yp, 400% 1003 ASsoundingt200K) For teaction Mi) —>M() Taking T, = 200 K; T, = 400K SH ago ~ AHg09 = AlnCpm)(T2 - Th) 400 x 100 — Hy) = (40 -50)(400 - 200), AHqo = 40000 + 2000 = 42000 Hyp 'Ssemuntag = “Pitt = |S ceraunaing [= 210.1 molK 15. A gaseous reaction A(g}—=BiQ) is a equilibrium under standard condition and 200 K. Calaculate the equilibrium constant ofthe reaction at 400 K if AS?...,,., =6 x 10-°T? Cal/K; where T is temperature in Kelvin. {Given R = 2 Cal'mol K and In 2 = 0.7) Ans. (4) Sol. AS24,=6 * 10°T* Cal/K at equilibrium AG'(200) = {at constant P for standard condition at 1 bar) (AG?) = -48%(aT) AG? AG), = -fastat=—"[ 610° Tat (200)? AGI, = 8 sos oor 00") -RT In K = -2 x 10° x 10° x [4°- 2°) _ 2x10«(64-8) = 2x 400 56x10 _ In K= =14 x07 x In2 =n 16. Calculate at what approximate pH will 10% moles of AKOH),j5) will dissolve in 1 litre of solution if Kato, =8:10" ai aror =! Ans. (9) Sol. AIOH),., All, +30H).,, ; K,, = 8 x 10° i oe 10” ‘Aly +40H,, = ANOHY, ; Ky =“F= On adding two equations, CHEMISTRY. 6 [JLN]AIOH) 5) + OH jy = ANOHYj, : K = K, x Ky = 8x10 as K=10) As Kis very large Al(OH), =10+ moles 17. Inthe fitration of a solution of a weak base BOH with HCI the pH is 8.2 after 10 ml of HCI solution has been ‘added and 7.6 after 20 ml of HCl solution has been added. Calculate the value of pK, of the base and express youranswer asab.cd, [For example if your answer is 3.8 the fill OMR as 4] Ans. (6) Sol. BOH + HCI xmm Mmol 10M 58=pky +o PRy +les 10M 20M 64 =pky, +og—22M_ PKy + los 20M 0.6 = log 210) x-20M) x=30M 58 = pk, -log2 pk, =6.1 18. Forthereaction Br (/)+ Cla) 2BiC{a) ; K, = Latm Ina closed container of volume 164 Lintlly 10 moles of Cé, are present at 27°C. What minimum mass (in ram) of Br,(!) must be introduced into this container so that above equilibrium is maintained at total pressure of 2.25 atm, Vapour pressure of Br,(é) at 27°C is 0.25 atm. Assume that volume occupied by liquid is negligible. (R = 0.082 L atm mot K", Atomic mass of Br = 80) [Give your answer as sum of digits and fill OMR sheet} Ans. (8) Sol. K, T= 300K V= 1641 p= 225 atm. Br, (0) + Cf, (g) = 2BrCt(g) 10 mole (10-x) 2 x 164 = (10—x + 2x) x 0.082 x 300 CHEMISTRY. 7 [JUN]19. A saturated solution of iodine in water contains 0.254 g I,/ L. More than this can dissolve in a KI solution because of the following equilibrium : [p(aq)+1 (aq)——*15(aq). A 0.10 MEI solution (0.10 MI) actually dissolves 12.954 g of iodine/L, most of which converted to I,~. Assuming that the concentration of I, in all saturated solutions s the same, calculate the equilibrium constant for the above reaction. What isthe effect of adding water to a clear saturated of |, in the KI solution ? [Give your answer sum of digits and Fill OMR sheet] Ans. (1) CHEMISTRY. 8 [JLN]