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SOIL-WATER
INTERACTIONS
BOOKS IN SOILS, PLANTS, AND THE ENVIRONMENT
Seed Development and Germination, edited by Jaime Kigel and Gad Galili
Shingo I w a t a
Ibaraki University
Ibaraki, Japan
Toshio Tabuchi
Tokyo University
Tokyo, Japan
Benno P. W a r k e n t i n
Oregon State University
Corvallis, Oregon
Iwata, Shingo
Soil-water interactions: mechanisms and applications / by Shingo Iwata.
Toshio Tabuchi, Benno P. Warkentin. — 2nd ed. rev. and expanded.
p. cm. — (Books in soils, plants, and the environment)
Includes bibliographical references and index.
ISBN 0-8247-9293-9
1. Soil moisture. 2. Soil physics. 3. Soils—Japan.
I. Tabuchi, Toshio. II. Warkentin, Benno P. III. Title. IV. Series
S594.I86, 1994
631.4'32—dc20 94-22883
CIP
The publisher offers discounts on this book when ordered in bulk quantities. For
more information, write to Special Sales/Professional Marketing at the address
below.
Neither this book nor any part may be reproduced or transmitted in any form or
by any means, electronic or mechanical, including photocopying, microfilming,
and recording, or by any information storage and retrieval system, without
permission in writing from the publisher.
Soil has three unique physical characteristics. The first and most conspicuous
is that soil is a porous medium, and consequently possesses a filtering function.
Soil consists of particles with various shapes and sizes—clay, silt, sand, and
larger gravel and stones. Different mechanical composition and different
arrangement of the same particles result in different pore structures, and these
pore structures determine the water retentivity and permeability of soils.
Moreover, natural soils have individual soil profiles, including macropores such
as cracks and pores formed by soil fauna and plant roots, each of which has a
complicated effect on water movement through soil. Second, soil has a very
large specific surface area, which leads to a large interaction between ions and
water molecules with the soil particles. Accordingly, soil possesses the ability
to adsorb electrically neutral solutes. Both the first and second characteristics
produce a high water retentivity in soil. Third, soil contains a high concentration
of electrical charges due to clay and organic matter, a characteristic that allows
soil to retain a high concentration of ions. This characteristic produces a
repulsive force, which plays an important role in the prevention of an irreversible
combination between particles. Swelling is also induced by the existence of this
force.
These characteristics present particular problems that are different from those
in other scientific fields. The first problem is related to physical heterogeneity,
such as nonuniform distribution of ions in the soil solution. The second is
concerned with complicated physical and physicochemical phenomena such as
frost heaving and soil swelling. The third is connected with peculiarities of
water movement such as infiltration into soil with macropores, unsaturated flow
in soil under a near-saturated condition, and unsaturated flow at low water
content.
This book provides a stimulating discussion of these problems, based on new
viewpoints developed in the very useful interdisciplinary study of the interactions
between soil and water. It will be of interest to the many scientists dealing with
water in the vadose zone—soil scientists, agricultural, civil and environmental
engineers, geologists, geochemists, hydrologists, agronomists, and pollution
control scientists. Few books discuss advanced topics in soil water from
different viewpoints. This book will serve that need for scientists from many
fields who find they need an understanding of the interactions of soil and water.
The modeling of these interactions, for example in descriptions of contaminant
transport in soils, requires an understanding of the mechanisms that are discussed
in this book. The interaction of soil particles with water is involved in most of
iii
iv Preface to the Second Edition
the fundamental processes in soils. It is relevant not only to soil science, but
also to the many technologies that deal with clays.
Each topic in this book is developed from fundamental concepts. No prior
knowledge of soil science is assumed, although the reader will need some
background in mathematics, physics, chemistry and thermodynamics. The
authors begin at the atomic level and proceed to the field scale. For example,
water adsorption on clay surfaces is developed from consideration of the nature
of forces holding water at the surface, and then applied to phenomena such as
water flux during frost heaving. The discussions of mechanisms of salt sieving
or of clay swelling begin with the nature and characteristics of charges on clay
particles, then are carried to the field scale in the management of water.
Concepts and measurements on interaction of water with soil particles date
from about 50 years ago, when modern descriptions of soil water potential and
physicochemical interaction of charged surfaces were developed. During
subsequent years our understanding of the mechanisms of interaction has
improved and applications have been made to various problems. Applications
have been made in different scientific disciplines. The authors evaluate this
work and then draw attention to those areas where our understanding is very
incomplete, for example, flow of water and solutes through clay layers.
Some special features add to the value of this book. There is a thorough
discussion of physical and chemical properties of allophane. The electric
potential distribution around allophane particles is used to explain characteristics
such as the development of a highly stable soil structure or fast flocculation.
The differences between variable charge and constant charge mineral surfaces are
discussed. There is a discussion of both capillary and surface forces in the
description of water retention and water flow in soils and clays. The discussion
of water fluxes shows the need to consider different physical processes for flow
at different water saturation levels in the soil. The water regimes of paddy fields
are discussed—a technology not familiar to most people working with soil water.
Much of the material is based in part on the authors' own research.
Another distinct strength of this book is that it draws on the Japanese and
Russian literature as well as English language research papers. Too many books
written in English ignore the findings and ideas published in other languages.
There is an extensive bibliography on many of the topics.
This revised edition, six years after the appearance of the first edition, gave
us the opportunity to treat some topics now being developed in the soil physics
literature, and to delete some topics available in other textbooks. About a third
of the book has been rewritten, and about a quarter of the figures are new.
Some of the main revisions are:
Preface to the Second Edition v
We hope this revised edition will continue to serve a need in the literature
of soil physics.
The authors acknowledge the important assistance of Pam Wegner, who
prepared the manuscript for publication.
Shingo Iwata
Toshio Tabuchi
Benno P. Warkentin
Preface to the First Edition
Physical, chemical, and biological changes proceed ceaselessly in the soil. These
changes make the existence of life in the soil possible; plants and animals of the
field cannot live without these changes. Soil water is not only indispensable for
life, but plays a most important role in the changes through its movement. Ion
exchange and transfer of heat and solutes are brought about in the processes of
wetting and drying of soil. In spite of the importance of soil water, there are yet
many problems that must be solved in scientific fields related to soil water. The
clarification of these problems is of great importance for the existence of
humankind.
During the past three decades, significant developments have occurred in
science fields connected with soil water. Mechanisms of flocculation and
dispersion of soil particles in soil solution, soil freezing, and soil swelling have
been clarified with concepts from physical chemistry. Analyses of water uptake
by plant roots, water movement due to temperature differences, water movement
under a near-saturated condition, and flow of solution through clay layers have
developed to a notable extent. It is regrettable, however, that a systematic
account of the results obtained from this research has yet to be written. In
Japan, the phenomena related to water movement in paddy fields, such as
unsaturated percolation, capillary flow, and outflow of fertilizers from paddy
fields, have formed the subjects of investigation for many researchers over a
number of years. Some of their achievements have attracted a great deal of
attention; however, since their research papers have been reported in Japanese,
soil scientists in other countries have been less able to benefit from this new
knowledge.
We hope that this book will help to satisfy both the need for a clear and
systematic description of the phenomena in question and a basic introduction to
pioneering achievements that have recently come to the fore in science fields
connected with soil water.
The eager and generous support of Dr. Benno P. Warkentin of Oregon State
University has encouraged the authors to write this book in a way that will
interest and stimulate researchers from many fields to open new directions in the
rapidly expanding theoretical and empirical notions of soil physics. Thus, the
appearance of this book owes much to Dr. Warkentin.
vi
Preface to the First Edition vii
Shingo Iwata
Toshio Tabuchi
Contents
ix
x Contents
REFERENCES 62
REFERENCES 142
REFERENCES 218
xiv Contents
4 CAPILLARITY 229
REFERENCES 255
REFERENCES 317
REFERENCES 385
REFERENCES 428
Index 435
1
ENERGY CONCEPT AND
THERMODYNAMICS OF WATER IN SOIL
Capillary Potential
Buckingham (1907) introduced the concept that flow of water results from a
difference in capillary potential between two points in the soil. He considered
that the soil exerts an attraction sufficient to hold water against the action of
gravity, and that this attraction decreases as the amount of water held by the soil
increases. He proposed the term "capillary potential," \|/, to describe this
attraction. \|/(0) was defined as the work required to pull a unit mass of water
away from the large mass of soil whose water content is 0, the volume fraction
of water. He introduced the equation
*=gx (1.1)
1
2 CHAPTER 1
125
_ 10C
^j
"o>
2 75
o>
TO
<1>
o 5C
.o
«J
JZ
g>
x<l> 2e
0 5 10 15 20 25 30 35
Water content (percent)
* = -g x (1.2)
Fig. 1.2. Soil column at moisture equilibrium with a free water surface.
water from one point to another is zero, as pointed out correctly by Buckingham.
On the other hand, when a soil column of infinite height is brought into contact
with a free water surface, and if the gravitational field does not exist, water
continues to rise by capillary force. The capillary force field or capillary
potential does not exist in this system.
The same conclusion is recognized in a system where a soil column with a
free water surface is placed in a centrifugal force field. A capillary potential
appears to exist, which is numerically equal to the potential of the centrifugal
force and opposite in sign.
Capillary potential, as used by Buckingham, should have been related to a
physical quantity other than a potential in the mechanical sense. A potential
whose existence is possible only under conditions where the system comes to
equilibrium in an external force field should be related to the change of state of
the substance in the system. Buckingham did not recognize this point. The
theoretical analysis of the system shown in Fig. 1.2 can be performed exactly by
use of a chemical potential, as discussed by Russell (1942). That is,
Au. w = g x = 0
Therefore,
AH W = -gx
where Aj^ is the chemical potential of water in soil, based on that of bulk water.
4 CHAPTER 1
* = / ^ d.3)
J
P
where p is the density of water in soil and P is the pressure of water in soil
relative to atmospheric pressure. In the general case, p is a function of pressure;
however, assuming that water is incompressible, \\t becomes equal to P/p. The
introduction of this relationship between \|/ and P led to the development of
tensiometer and suction plate apparatus for measuring capillary potential of water
in soil which was not in contact with a free water surface.
The further development of studies on soil water required a more general concept
to express the state of water in soil. Studies of the relationship between plant
growth and soil water could not ignore the existence of solutes in soil solution.
Moreover, research into the physical and mechanical properties of soil needed a
concept to compare the state of water over the whole water content range from
saturation to oven-dry.
Various concepts were proposed in the decade after 1935 to satisfy this
demand. They include pF by Schofield (1935), water potential by Veihmeyer
and Edlefsen (1937), osmotic potential and pressure potential by Day (1947), and
soil moisture stress, the sum of water suction and osmotic pressure, by Wadleigh
and Ayers (1945). Although these concepts have different names, they are all
expressions of chemical potential (total potential) of water in soil relative to free
water at the same temperature. pF is the base 10 logarithm of the absolute value
of chemical potential expressed in a gravitational system of units, assuming that
solutes are negligible. Water potential is the chemical potential of water.
Pressure potential and osmotic potential are equivalent to the decrement of
chemical potential due to surface tension effects and/or electric and van der
Waals force fields, and due to solutes. Water suction and osmotic pressure are,
respectively, equal to the value of pressure potential and osmotic potential
divided by the partial volume of water in soil.
THERMODYNAMICS OF WATER IN SOIL 5
The state of water in soil can be described exactly on the basis of thermody-
namic concepts such as chemical potential. Buckingham (1907) wrote: "It is
obvious that a rigorous treatment of the subject, with no restrictions imposed on
either the water content or the soluble salt content of soil, would have to use
thermodynamic reasoning. But the simple conception will suffice for the present
purpose, though it is not impossible that with more comprehensive experimental
data available we should have to use thermodynamic potential or free energy."
6 CHAPTER 1
However, a long period of 36 years was required to establish this general energy
concept.
In the early 1980s, a noteworthy thermodynamic analysis of unsaturated soil
was done by Sposito and Chu (1981, 1982). They attempted to describe the state
of an unsaturated soil with a set of independent variables: the masses of the
three components of soil—solids, water, and air—together with the applied
pressure and absolute temperature. At the present stage the analysis is not
sufficiently complete to be used for practical purposes such as a thermodynamic
study of the total soil system, including not only the water but the solids and air.
Such an analysis will be important in future research on soil water. In addition,
the balance of internal energy for water in soil has been studied (Hassanizadeh
and Gray, 1979a,b, 1980; Sposito and Chu, 1981), and the fundamental Richards
equation was deduced as a special case of internal energy balance for water in
an unsaturated soil (Sposito and Chu, 1982).
The total potential, \|/p of the constituent water in soil at temperature T{), is
the amount of useful work per unit mass of pure water that must be done by
means of externally applied forces to transfer reversibly and isothermally an
infinitesimal amount of water from the state S0 to the soil liquid phase at the
point under consideration. It is convenient to divide the transfer process
referred to above into several steps, by introducing substandards.
S,: a pool of pure, free water as in S0, but situated at the same height as the
soil liquid phase under consideration, hx, i.e., S, is at T0, hx, P0.
S2: a pool of free solution identical in composition with the soil liquid
phase at the point under consideration, having an osmotic pressure, ft, but
otherwise identical with S,, i.e., S2 is at T0, hx, P0.
The Colony Range is so cared for and fertilized that the growing
pullet, for the Spring and Summer months, finds an unlimited supply
of succulent green food at her door.
CHAPTER XI
Anthracite Coal Ashes—A Substitute for Many
More Expensive Necessities
The feather of a bird is composed almost entirely of phosphorous,
and phosphorous is a great aid to the bird in digesting food. In fact,
there are manufactured “grits” offered on the market, which base
their efficiency on the amount of phosphorous they carry.
Anthracite, or hard, coal ashes, carry a considerable quantity of
phosphorous, and this is the reason chickens in all stages of their
existence are so fond of them. Our attention was first called to this
fact by observing the large number of pullets on the Colony Range,
where some loads of ashes had been used the previous season in
mixing with the fertilizer for the growing of potatoes. It was noticed
that these small heaps of ashes were very soon consumed, and
when they were replenished the pullets were never absent from the
piles. The experiment was then made of placing a small heap at the
extreme end of the chick runs from the Brooder House, and to our
surprise we found one was unable to see the ashes because of the
moving mass of yellow which covered them. It was necessary to
replenish these heaps almost daily. As ashes are perfectly sanitary
we decided to cover the entire chick run with them, which we did,
and every few days, through the brooding season, a fresh coating is
necessary, as the youngsters consume so much of the surface
constantly.
Orders for hatching eggs are booked by such a system that people
receive them when we agree to deliver the goods, and the illustration
herewith plainly shows the plan.
$ ........ SUNNY SLOPE FARM No.
THE GREAT CORNING EGG FARM
BREEDERS OF THE STRAIN OF S. C. WHITE LEGHORNS
WHICH CANNOT BE SURPASSED
BY ....................
CHAPTER XIII
Policing the Farm—With Bloodhounds,
Searchlights and Rifles
In the Fall of each year, from almost every part of the Country,
come reports of what seems to be organized thieving in the poultry
line. Both large and small farms are generally sufferers. For a
number of years people in the vicinity of the The Corning Egg Farm
have met with losses, and in the year 1910 an organized gang was
unearthed, which had a camp on the adjacent hills, and made nightly
raids, then shipped the birds by crossing the Watchung Mountains
and reaching railroad communication on the other side, sending their
stolen feathered plunder into the New York Market.