Textbook The Photomultiplier Handbook 1St Edition A G Wright Ebook All Chapter PDF

You might also like

Download as pdf or txt
Download as pdf or txt
You are on page 1of 52

The photomultiplier handbook 1st

Edition A.G. Wright


Visit to download the full and correct content document:
https://textbookfull.com/product/the-photomultiplier-handbook-1st-edition-a-g-wright/
More products digital (pdf, epub, mobi) instant
download maybe you interests ...

The International Loan Documentation Handbook 3rd


Edition Wright

https://textbookfull.com/product/the-international-loan-
documentation-handbook-3rd-edition-wright/

THE OXFORD HANDBOOK OF CORPORATE GOVERNANCE 1st Edi


Mike Wright

https://textbookfull.com/product/the-oxford-handbook-of-
corporate-governance-1st-edition-mike-wright/

The Routledge Handbook of Vegan Studies 1st Edition


Laura Wright (Editor)

https://textbookfull.com/product/the-routledge-handbook-of-vegan-
studies-1st-edition-laura-wright-editor/

Cautious The Everyday Heroes World 1st Edition Candice


Wright [Wright

https://textbookfull.com/product/cautious-the-everyday-heroes-
world-1st-edition-candice-wright-wright/
Fierce Obsessions The Phoenix Pack 6 1st Edition
Suzanne Wright Wright Suzanne

https://textbookfull.com/product/fierce-obsessions-the-phoenix-
pack-6-1st-edition-suzanne-wright-wright-suzanne/

Wild Hunger The Phoenix Pack 7 1st Edition Suzanne


Wright Wright Suzanne

https://textbookfull.com/product/wild-hunger-the-phoenix-
pack-7-1st-edition-suzanne-wright-wright-suzanne/

Untamed Delights The Phoenix Pack 8 1st Edition Suzanne


Wright Wright Suzanne

https://textbookfull.com/product/untamed-delights-the-phoenix-
pack-8-1st-edition-suzanne-wright-wright-suzanne/

The Favor 1st Edition Suzanne Wright

https://textbookfull.com/product/the-favor-1st-edition-suzanne-
wright/

The Oxford Handbook of Industrial Policy 1st Edition


Arkebe Oqubay Christopher Cramer Ha Joon Chang Richard
Kozul Wright

https://textbookfull.com/product/the-oxford-handbook-of-
industrial-policy-1st-edition-arkebe-oqubay-christopher-cramer-
ha-joon-chang-richard-kozul-wright/
THE PHOTOMULTIPLIER HANDBOOK
The Photomultiplier Handbook

A. G. Wright

1
3
Great Clarendon Street, Oxford, OX2 6DP,
United Kingdom
Oxford University Press is a department of the University of Oxford.
It furthers the University’s objective of excellence in research, scholarship,
and education by publishing worldwide. Oxford is a registered trade mark of
Oxford University Press in the UK and in certain other countries
© Tony Wright 2017
The moral rights of the author have been asserted
First Edition published in 2017
Impression: 1
All rights reserved. No part of this publication may be reproduced, stored in
a retrieval system, or transmitted, in any form or by any means, without the
prior permission in writing of Oxford University Press, or as expressly permitted
by law, by licence or under terms agreed with the appropriate reprographics
rights organization. Enquiries concerning reproduction outside the scope of the
above should be sent to the Rights Department, Oxford University Press, at the
address above
You must not circulate this work in any other form
and you must impose this same condition on any acquirer
Published in the United States of America by Oxford University Press
198 Madison Avenue, New York, NY 10016, United States of America
British Library Cataloguing in Publication Data
Data available
Library of Congress Control Number: 2017933575
ISBN 978–0–19–956509–2
DOI: 10.1093/oso/9780199565092.001.0001
Printed and bound by
CPI Group (UK) Ltd, Croydon, CR0 4YY
Links to third party websites are provided by Oxford in good faith and
for information only. Oxford disclaims any responsibility for the materials
contained in any third party website referenced in this work.
Dedicated in memory of John Barton.
Contents

Preface xix
Figure credits xxi

1 Why photomultipliers? 1
1.1 Aspects of light detection 2
1.1.1 Introduction 2
1.1.2 Brief history of PMTs 3
1.1.3 The statistical case for PMTs 4
1.1.4 DC detection with a PMT 7
1.1.5 Detection of single photoelectrons 9
1.1.6 Detection of multi-photoelectron signals 10
1.1.7 Summary of PMT key attributes 11
1.2 Other light detectors 12
1.2.1 Silicon PIN diodes 12
1.2.2 APDs 12
1.2.3 SiPMs 14
1.2.4 Summary of silicon key attributes 16
1.2.5 Visible-light photon counters 17
1.2.6 CCDs 17
1.2.7 Hybrid photodetectors and APDs 17
1.3 Pulse height resolution 18
1.4 Position resolution 21
1.5 Signal-to-background considerations 21

2 Photocathodes 24
2.1 Introduction 25
2.1.1 Solid angles 26
2.2 Fundamentals of photosensitivity 27
2.2.1 The electromagnetic spectrum 27
2.2.2 Photoelectric phenomena 28
2.2.3 Photoelectron energy distribution 29
2.3 Spectral radiation and photometric units 30
2.3.1 Spectral radiant energy 30
2.3.2 Photometric units and standards 30
2.3.3 Filter measurements 33
2.3.4 Calibration laboratories and absolute radiation standards 35
2.3.5 Trap detectors 35
viii Contents

2.4 Optical properties of end window photocathodes 37


2.4.1 Refraction in dielectrics 37
2.4.2 Reflection from dielectrics 40
2.4.3 Photocathode optical properties 42
2.4.4 Techniques for measuring photocathode reflectance 43
2.4.5 Limits to reliable measurement 44
2.4.6 Determination of transmission and absorptance 45
2.5 Spectral sensitivity of photocathodes 50
2.5.1 Three foremost photocathodes 50
2.5.2 Photocathode response to scintillator light 52
2.5.3 Solar blind photocathodes 54
2.5.4 Infrared photocathodes 56
2.5.5 High-temperature photocathodes 58
2.6 Photocathode geometries 58
2.6.1 Range of end window PMTs 58
2.6.2 Range of side window PMTs 60
2.6.3 Window materials 61
2.7 Photocathode resistivity 62
2.8 QE temperature dependence 65
2.8.1 Laboratory and commercial applications, 30  C to +60  C 65
2.8.2 Ultra-low temperature performance, 273  C to 30  C 67
2.8.3 High-temperature operation, +60 ºC to +200 ºC 68
2.9 Dark count temperature sensitivity 69
2.10 Critical photocathode properties 69
2.10.1 Photocathode uniformity 69
2.10.2 Ionizing radiation 72
2.11 Summary of factors affecting photocathode response 73

3 The optical interface to PMTs 78


3.1 Introduction 79
3.2 Light attenuation and reflection coefficients 80
3.2.1 Light attenuation length, γ 80
3.2.2 Reflectance coefficients, ρ 81
3.2.3 Optical coupling of scintillators 83
3.3 Point light source 84
3.4 Interfacing to small volume scintillators 86
3.4.1 Interfacing to scintillators of high Z 88
3.4.2 Interfacing to scintillators of low Z 90
3.5 Light concentrators 90
3.5.1 Light concentrators: Theory 90
3.5.2 Light concentrators: Winston cone 91
3.5.3 Integrating spheres 92
Contents ix

3.6 Scintillators with diffuse reflecting walls 93


3.7 Light output from scintillator slabs 95
3.7.1 Escape cones 95
3.8 Light guides 97
3.8.1 Hollow guides with specular reflecting walls 98
3.8.2 Solid guides based on TIR 98
3.8.3 Adiabatic light guides 99
3.9 Light detection efficiency for scintillators 101
3.9.1 PMT viewing a large-area face 101
3.9.2 PMT viewing small-area face 103
3.9.3 Photoelectron yield for scintillation counters 105
3.9.4 Monte Carlo simulations 107
3.10 Uniformity of response in large-area detectors 107
3.11 WLS light guides 109
3.12 Optical fibres 110
3.12.1 Application of fibres to scintillating tiles 112
3.12.2 Use of fibres with large-area plastic scintillator slabs 114
3.13 Techniques for enhancing light detection 115
3.13.1 Anti-reflection coatings 115
3.13.2 Sandblasting 115
3.13.3 Theory of light recycling 117
3.13.4 Internal prismatic window 119
3.13.5 External optical enhancement devices 120
3.13.6 WLS coatings 123

4 Statistical processes 128


4.1 Introduction 129
4.1.1 Single- and multi-photon light sources 129
4.2 Binomial, Poisson, and normal distributions 131
4.3 Mean and variance 132
4.4 Folding of probability density functions 136
4.5 Moments 139
4.5.1 Moments about the origin 139
4.5.2 Central moments 140
4.5.3 Factorial moments 141
4.5.4 Exercise in photon counting 142
4.6 Probability generating functions 145
4.7 Sum of chance integers 147
4.8 Moment generating functions 149
4.9 Folding with probability generating functions 151
4.10 Cascaded processes 153
4.10.1 Generalized two-stage cascading 153
4.10.2 Light detection statistics 154
4.10.3 Multiplier dispersion 155
4.10.4 Pdf at the kth dynode 157
x Contents

4.11 Shot noise in DC detection 161


4.12 Noise in multi-photon excitation 163
4.13 Continuous SER distributions 166
4.14 Multi-photoelectron pdfs 169
4.15 MPHD for an empirical SER 173
4.16 Arrival time statistics 175
4.16.1 Exponential time signatures 175
4.16.2 First two moments for R fixed 177
4.16.3 First two moments for R randomized 178
4.17 Determination of afterpulse rates 180
4.17.1 Afterpulses: Method I 181
4.17.2 Afterpulses: Method II 182
4.18 Scaling and dead time 183
4.18.1 Interval distribution 184
4.18.2 The p-fold time interval 184
4.19 Dead time 188
4.19.1 Sources of dead time 188
4.19.2 Counting losses attributed to dead time 190
4.19.3 Type I, paralysable counters 190
4.19.4 Type II, non-paralysable counters 191
4.19.5 Dead time and variance 193
4.19.6 Determination of dead time 194
4.19.7 Suppressing correlated signals 197

5 Secondary emission and gain 202


5.1 Introduction 203
5.2 Gain generation with discrete dynodes 204
5.3 Single-photoelectron noise spectra 208
5.4 Secondary-electron emission 210
5.4.1 Classical description 210
5.4.2 Secondary-electron yield 214
5.4.3 Theory and measurement 215
5.4.4 Secondary-electron statistics 216
5.4.5 Temperature dependence of gain 218
5.5 Sources of undersized signals 219
5.5.1 Inelastic scattering 219
5.5.2 Gain non-uniformity 222
5.5.3 Events initiated by d1 224
5.5.4 Other sources of undersized signals 224
5.6 Discrete dynodes 225
5.6.1 Venetian blind dynodes and skipping 226
5.6.2 Coarse mesh dynodes 229
Contents xi

5.6.3 Fine-mesh dynodes 230


5.6.4 Metal-channel dynodes 230
5.6.5 Linear and circular focussed dynodes 232
5.6.6 Box-and-grid dynodes 234
5.6.7 Transmission dynodes 234
5.7 Continuous multipliers 237
5.7.1 CEMs 237
5.7.2 MCPs 239
5.7.3 Gain–voltage considerations in MCPs 240
5.8 Multiplier and PMT gain measurement 241
5.8.1 Measurement of G: First method 242
5.8.2 Measurement of G: Second method 243
5.8.3 Measurement of G: Third method 243
5.8.4 Measurement of ‹g›: First method 245
5.8.5 Measurement of ‹g›: Second method 247
5.8.6 Measurement of ‹g›: Third method 248
5.8.7 Measurement of ‹g›: Fourth method 249
5.9 Quick determination of ‹g› 249
5.9.1 Quick determination of ‹g›: First method 251
5.9.2 Quick determination of ‹g›: Second method 251
5.10 Gain–voltage characteristics 252
5.11 Conclusions 253

6 PMT background 257


6.1 Introduction 258
6.2 Dark counts and dark current 259
6.2.1 Subdivision of a dark count distribution 260
6.3 Reconciliation of dark current and dark counts 261
6.4 S/B in DC applications 264
6.5 Light generation within a PMT 265
6.6 Sources of background 266
6.6.1 Region A: Undersized pulses 267
6.6.2 Regions B and C: Single- and multi-electron
background 267
6.6.3 Dependence on temperature 267
6.6.4 Ionizing radiation 269
6.7 Gamma background 271
6.7.1 Radionuclides within PMTs 274
6.8 Cosmic ray muons 276
6.8.1 Cerenkov emission in a PMT window 277
6.8.2 PMT orientation 278
6.9 Means for reducing background 279
6.10 Summary 279
xii Contents

7 Measurement of low light flux 282


7.1 The physical nature of light detection 283
7.1.1 Noise and background 283
7.2 Measurement modes 284
7.2.1 Photon counting 284
7.2.2 DC detection 284
7.2.3 Shot noise power detection 286
7.3 Detection methods and weighting 288
7.3.1 Detection techniques 289
7.4 Difference between two count rates 291
7.4.1 Efficient time allocation 291
7.5 Signal recovery instrumentation 293
7.5.1 Boxcar integrators 293
7.5.2 Lock-in detection 294
7.5.3 Synchronous signal averaging 296
7.5.4 Signal recovery simulation 297
7.5.5 Subdividing time intervals 298
7.5.6 Upper and lower thresholds 300
7.5.7 Signal magnitudes: Photon counting 301
7.5.8 Signal magnitudes: DC detection 302
7.5.9 Excess noise factor 303
7.5.10 Ratemeter operation 304
7.6 PMT selection criteria 306
7.6.1 Optimal gain for DC detection 307
7.6.2 Optimal HV for photon counting 308
7.6.3 MCA plateau characteristic 311
7.6.4 Critical PMT parameters 312
7.6.5 Discriminator threshold 316
7.7 Methods involving DMMs and electrometers 317
7.7.1 Measurements with a DMM 317
7.7.2 Electrometers 318
7.7.3 Voltage dividers 319

8 Timing with PMTs 321


8.1 Electron motion in electric fields 322
8.1.1 Introduction 322
8.1.2 Electron motion in a uniform electric field 328
8.1.3 Electron motion in non-uniform electric fields 329
8.1.4 Laws of motion applied to PMTs 330
8.1.5 Spot size 331
8.2 Evolution of fast linear focussed PMTs 333
8.2.1 The PMT front end 333
8.2.2 Contribution to time dispersion from dynodes 337
Contents xiii

8.2.3 Transit-time effects at the PMT back end 339


8.2.4 Ultra-fast PMTs 341
8.3 PMT output signal 341
8.3.1 Signature of the anode signal 341
8.3.2 Simulation of photoelectron time intervals 343
8.3.3 Simulation of multiplier noise and jitter 345
8.3.4 Oscilloscope traces for NaI(Tl) signals 347
8.3.5 Scintillator rise and fall time 350
8.4 Timing 351
8.4.1 Single-electron time response 351
8.4.2 Transit time, T 353
8.4.3 Effect of amplitude fluctuations on jitter 356
8.4.4 Effect of charge sensitivity on jitter 357
8.4.5 Contribution to jitter from noise 357
8.5 Zero crossing and CF methods 358
8.5.1 Charge threshold for triggering 361
8.5.2 CF technique 363
8.6 Measurement schematics 365
8.7 Multiple statistical sources 369
8.7.1 Single-photoelectron output signatures 369
8.7.2 Photoelectron timing variance 370
8.8 Photon arrival statistics 373
8.9 Timing measurements 376
8.10 Timing summary 378

9 Linear performance 383


9.1 Introduction 384
9.1.1 Modes of operation 385
9.1.2 Rate effect 387
9.1.3 Causes of non-linearity 387
9.1.4 Dynode materials 387
9.2 Dynamic range 388
9.2.1 Achievable dynamic range: Analogue 388
9.2.2 Achievable dynamic range: Pulse mode 389
9.2.3 Onset of DC non-linearity 391
9.2.4 Onset of pulsed non-linearity 392
9.2.5 Bootstrap method 394
9.3 Theoretical considerations 394
9.4 Advanced linearity investigations 398
9.4.1 Single-step method 399
9.4.2 Ratiometric method 402
9.4.3 Shot noise method 403
9.5 Correcting non-linearity 404
9.6 Non-linearity in inorganic crystals 405
9.7 Summary 407
xiv Contents

10 Collection and counting efficiency 410


10.1 Introduction 411
10.2 Lost photoelectrons 412
10.2.1 Front end design 412
10.2.2 Optimal operating conditions 413
10.3 Collection and counting efficiency 414
10.3.1 Collection efficiency, F 414
10.3.2 Anode detection efficiency, ε 415
10.4 Measurement techniques 415
10.4.1 Attenuation using filters 415
10.4.2 Count rate determination 416
10.5 Determination of F 418
10.5.1 Based on d1 gain 418
10.5.2 Shot noise 422
10.5.3 The bi-photonic field 424
10.5.4 Calibrated lamp 425
10.5.5 Cerenkov light source 425
10.5.6 Use of a power meter 426
10.5.7 Calibrated silicon photodiodes 427
10.6 Summary and conclusions 428

11 Signal-induced background 431


11.1 Introduction 432
11.2 Timing instrumentation 432
11.2.1 Amplifier discriminators 432
11.2.2 Configurations for afterpulse measurements 433
11.2.3 Stopstart instrumentation 434
11.3 Prepulses and late pulses 435
11.4 Detector response function 439
11.5 Afterpulses 440
11.5.1 Early measurements 440
11.5.2 Theory of afterpulse generation 442
11.5.3 Contributions to understanding afterpulses 445
11.5.4 Afterpulses in photon counting 447
11.5.5 Exposure of PMTs to helium 448
11.6 Exposure to bright light 449
11.6.1 Settling time: Medium term 449
11.6.2 Settling time: Long term 449
11.7 Summary and conclusions 452

12 Environmental considerations 455


12.1 Introduction 456
12.1.1 Performance in weak magnetic fields 456
12.1.2 Performance in high magnetic fields 458
Contents xv

12.1.3 The effect of electric fields 458


12.1.4 PMT enclosures, modules, and housings 461
12.1.5 Housings for scintillators 463
12.1.6 Light leaks and electric fields 464
12.2 Operation in harsh environments 465
12.2.1 Shock and vibration 465
12.2.2 Operation at high temperature 467

13 Voltage dividers 471


13.1 Introduction 472
13.2 Gain–voltage relationships 473
13.2.1 Resistive dividers 473
13.2.2 Dividers with zener diodes 475
13.3 Analysis of resistive dividers 477
13.4 Resistive divider operation 482
13.5 Inclusion of zener diodes 484
13.6 Active voltage dividers 488
13.6.1 Fully active N-type analysis 489
13.6.2 Fully active P-type analysis 490
13.6.3 Fully active circuits 493
13.6.4 Gain linearity 495
13.6.5 Partially active circuits 496
13.6.6 Cockcroft–Walton dividers 497
13.7 Voltage dividers for pulsed operation 499
13.7.1 Decoupling capacitors 499
13.7.2 Pin connections 501
13.7.3 Decoupling options 501
13.7.4 Switch-on transients 502
13.8 Methods and circuits 503
13.8.1 Power supply polarity and ripple 503
13.8.2 Wiring options 506
13.8.3 Dynode signals 507
13.8.4 Shorting dynodes 509
13.8.5 Single cable dividers 510
13.8.6 Gain adjustment 511
13.8.7 Equivalent circuit at high frequencies 511
13.8.8 Wiring practice 512
13.9 Gating 515
13.9.1 Electro-optical and mechanical gating 517
13.9.2 HV switching 517
13.9.3 Photocathode gating 518
13.9.4 Dynode gating 518
13.9.5 Focus-electrode gating 521
13.9.6 Circuit realization 522
13.9.7 Pulse generators and shielding 522
xvi Contents

14 Electronics for PMTs 527


14.1 Introduction 528
14.2 Charge output transducers 530
14.3 The role of a preamplifier 531
14.3.1 Interfacing and signal transmission 532
14.3.2 Grounding and shielding 534
14.4 Circuit protection and limiting 534
14.5 Modular electronics 535
14.6 PMT equivalent circuit 538
14.6.1 PMT signal bandwidth 541
14.7 Multiple PMT outputs 543
14.8 Passive circuit analysis 544
14.8.1 Anode DC-coupled R||C network 545
14.8.2 Anode AC-coupled R||C network 547
14.9 Signal-shaping preamplifiers 549
14.9.1 Charge-sensitive preamplifiers 550
14.9.2 Commercial charge-sensitive amplifiers 552
14.9.3 Pole-zero cancellation 554
14.9.4 Preamplifier calibration 555
14.10 Signal-shaping main amplifiers 555
14.10.1 Signal-shaping theory 555
14.10.2 Detector noise 559
14.10.3 Modular detection equipment 561
14.11 Fast amplifiers 562
14.11.1 Discrete-component amplifiers 562
14.11.2 Amplifiers incorporating microwave transistors 564
14.11.3 Fast bench-top and NIM preamplifiers 566
14.11.4 Voltage- and current-feedback OP-AMPs 566
14.11.5 Transimpedance amplifier circuits using CFAs 569
14.11.6 Logarithmic amplifiers 571
14.12 Pulsed-light sources 572
14.13 Optimizing PMT performance 573
14.14 DSP 574
Appendix A PMT output distributions 581
A.1 General considerations 581
A.2 Schematics and methods for measuring distributions 583
A.3 Integral pulse height distributions 583
A.4 Differential pulse height distributions 583
A.5 Plateau characteristic 584
A.6 Changing variables 585
A.7 Transformations of an analytic function 588
A.8 Transformation of experimental data 591
Contents xvii

A.9 Single-photoelectron distributions 592


A.10 Probability distributions in high temperature
NaI(Tl) applications 597
A.11 Conclusions 600

Appendix B Light emission by the Cerenkov effect 603


B.1 Introduction 603
B.2 Threshold conditions for the Compton effect 604
B.3 Formulations for Cerenkov emission 606
B.4 The yield from MIPs 608

Appendix C Abbreviations 611

Index 615
Preface

It is usual to indicate the type of reader the author has in mind. This book is aimed
primarily at those who use, or are about to use, vacuum photomultipliers (PMTs).
The aim is to provide a deeper understanding of PMT behaviour as a means for
optimizing performance. Wherever appropriate I have drawn on my experience as
a user and manufacturer of PMTs. My objective in writing this book is to fill
perceived gaps in the literature. For example, the important topic of the optical
interface to PMTs has hitherto received little attention.
Major manufacturers of light detectors, notably EMI, provided ‘Application
Notes’ covering a range of technical topics relating to PMTs. Also, PMT manu-
facturers’ handbooks, refreshingly unbiased by commercial considerations, have
been freely issued over the years, namely,

• RCA (Photomultiplier Manual, 1970)—available online


• Philips (Photomultiplicateurs, 1981)
• Hamamatsu (Photomultiplier Tubes, Basics and Applications, 2006)—avail-
able online
• Philips (Photomultiplier Tubes, Principles and Applications, 1994)
• Photomultiplicateurs, written by G Piétri, in French, reached a wider audi-
ence following an update and translation released in 1994.

It is perhaps worth noting the name changes of the major manufacturers, as


companies have been bought or merged. The evolution of names is as follows:

• Philips ! Photonis ! now based in China


• EMI ! Thorn EMI ! Electron Tubes ! ET Enterprises
• RCA ! Burle ! ceased trading in PMTs

Philips marketed and branded products under different titles: Philips, Mullard,
Valvo, and Amperex. When a specific product type is mentioned in the present
text, the name of the manufacturer at the time of reporting is used.
This book should also be of interest to scientists and engineers involved in
PMT design and manufacture. I have held the opinion throughout my 40 years in
the industry that those who produce new or modified devices should critically
evaluate their performance. This also applies to designers of electronics, for whom
dealing with the equivalent circuit of a current generator may initially appear
xx Preface

arcane. There is sometimes reluctance to investigate PMT behaviour occurring at


a stage prior to the output, because performance is affected by operations before
the signal reaches the anode. PMTs have been commercially available since the
1950s, but optimal or even satisfactory performance still eludes many users. This
is not surprising, since we are dealing with devices of sufficient gain to detect single
photons and with a bandwidth of the order of a gigahertz—clearly, a product with
such performance demands expertise and careful treatment.
PMTs are intriguing scientific transducers that have proved worthy of study in
their own right. They embody the physics of photoemission, electron-optics,
secondary emission, optics, and signal processing, making them the preferred
light detectors for a significant range of commercial instrumentation and
for academic investigations. The principal advances in the evolution of PMTs
inevitably trace back to a scientific requirement, rather than a commercial one.
Hemispherical PMTs (see Fig. 2.23), for example, stemmed from proton-decay
investigations requiring the capture of light over large solid angles. Following their
first introduction in the 1970s, many massive experiments conducted under water,
and in ice, have produced outstanding advances in our understanding of astro-
physical phenomena. Although perhaps 50,000 PMTs of this type have been
produced, virtually none has found commercial application. The majority of
scientific publications concerning PMTs are to be found in the following journals:
Nuclear Instruments and Methods in Physics Research A, IEEE Transactions on
Nuclear Science, Applied Optics, Review of Scientific Instruments, and Journal of
Physics D and E. The first two mentioned are favoured for publishing the pro-
ceedings of international conferences, such as: ‘New Developments in Photode-
tection’ and the ‘IEEE Nuclear Science Symposia’. These conference publications
are highly recommended as a source of current information on light detectors.
Light generation and detection are statistical processes. The family of detectors
that provide gain through electron multiplication are also statistical in their oper-
ation. Hence, the choice of an appropriate detector for a particular application is
strongly influenced by statistical arguments. The first chapter introduces the range
of light detectors and compares their performance, essentially on statistical
grounds. The formulations are stated rather than derived at this stage but they
are fully developed in Chapter 4.
I have been fortunate to have enjoyed constant encouragement, the use of test
facilities, and literature from two managing directors of Thorn EMI and ET
Enterprises, namely, J P Frederiksen and R M McAlpine, respectively, and also
L Ludlum, Vice President, ADIT/Electron Tubes. I also wish to acknowledge
A C Bach, A J Cormack, P J Cook, and C Wade for technical input and suggestions
on presentation and subject coverage. I am especially indebted to my wife, Mary,
who patiently withheld the awkward question ‘When are you going to finish?’
Amersham A. G. WRIGHT
June 2017
Figure credits

Chapter 2
Fig. 2.10(a). Jones, D. P. (1976). Photomultiplier sensitivity variation with angle of incidence on the
photocathode. Appl. Opt., 15, No. 4, 910–14. 44
Fig. 2.10(b). Moorhead and Tanner (1996). Optical properties of an EMI K2CsSb bialkali photocathode.
Nucl. Instr. and Meth. in Phys. Res. A, 378, 162–70. Reprinted from Elsevier Science ©1996. 44
Figs 2.11 to 2.14. Moorhead and Tanner (1996). Optical properties of an EMI K2CsSb bialkali photocathode.
Nucl. Instr. and Meth. in Phys. Res. A, 378, 162–70. Reprinted from Elsevier Science ©1996. 46–8
Fig. 2.15. Hallensleben et al. (2000). Optical constants for the S20 photocathode, and their application to
increasing photomultiplier quantum efficiency. Optics Communications, 180, 89–102. Reprinted
from Elsevier Science ©2000. 49

Chapter 3
Figs 3.9 to 3.11. Welford, W. T. and Winston, R. (1978). The optics of non-imaging concentrators. Light and
solar energy. Academic Press, New York. Reprinted from Academic Press ©1978. 90–2
Fig. 3.26. Aota, S. et al. (1999). Mass production of tile/fibre units for the CDF plug upgrade
EM calorimeter. Nucl. Instr. and Meth. in Phys. Res. A 420, 48–61. Reprinted from Elsevier
Science ©1999. 113
Fig. 3.27. Artikov, A. et al. (2006). New generation large area muon scintillation counters with wavelength
shifter fibre readout for CDF II. Physics of particles and nuclear letters, 3, Issue 3,
188–200. Reprinted from Springer ©2006. 114
Fig. 3.34. Gunter, W. D., Grant, G. R. and Shaw, S. A. (1970). Optical devices to increase photocathode
quantum efficiency. Appl. Opt., 9, No. 2, 251–7. Reprinted with permission from OSA ©1970. 122
Table 3.2. Courtesy of J Mc Millan, private communication. 83

Chapter 4
Figs 4.14 and 4.15. Wright A. G. (2005). The statistics of multi-photoelectron pulse height distributions.
Nucl. Instr. and Meth. in Phys. Res. A., 579, 96772. Reprinted from Elsevier Science ©2005. 174, 177
Fig. 4.16. Arrival time statistics. Kelbert, M., Sazonov, I. and Wright, A. G. (2006). Exact expression
for the variance of the photon emission process in scintillation counters. Nucl. Instr. and
Meth. in Phys. Res. A., 564, 1859. Reprinted from Elsevier Science ©2006. 179
Chapter 5
Fig. 5.10. Simon, R. E. and Williams, B. F. (1968). Secondary-electron emission. IEEE Trans NS15,
16670. Reprinted with permission from IEEE. ©1968. 215
xxii Figure credits

Fig. 5.12. Sommer, A. (1972). Bialkali (K2CsSb) photocathodes as a high gain secondary electron
emitter. J. Appl. Phys., 43, No. 5, 24792480. Reprinted with permission from AIP© (1972). 217
Fig. 5.23. Kuroda, K., Sillou, D., and Takeutchi, F. (1981). New type of position sensitive photomultiplier.
Rev. Sci. Instrum., 52(3), 337346. Reprinted with permission from AIP© (1981). 229
Fig. 5.24. Agoritsas, V., Kuroda., K. and Nemoz, Ch. (1989). A new type of position-sensitive electron
multiplier. Nucl. Instr. and Meth. in Phys. Res. A, 277, 237241. Order number 3620250895810.
Reprinted from Elsevier Science ©1989. 229
Fig. 5.26. Chirikov-Zorin, I., Fedorko, I., Menzione, A., Pikna, M., Sỷkora, I., and Tokảr, S. (2001).
Method for precise analysis of the metal package photomultiplier single photoelectron spectra.
Nucl. Instr. and Meth. in Phys. Res. A, 456, 310324. Reprinted from Elsevier Science ©2001. 231
Chapter 6
Table 6.1. Viehmann, W, et al. (1975). Photomultiplier window materials under electron irradiation:
fluorescence and phosphorescence. Appl. Opt., 14, No. 9. 2104–15. Reprinted with
permission from OSA ©1975. 271

Chapter 10
Figs 10.5 to 10.11 and equations (10.6) and (10.7). Wright, A. G. (2010). Method for the determination
of photomultiplier collection efficiency, F. Appl. Opt., 49, 2059–65. Reprinted with
permission from OSA ©1970. 419–23

Chapter 14
Fig. 14.24. Blanch, O. et al. (1999). Performance of a fast low noise front-end preamplifier for
the MAGIC imaging Cerenkov telescope. IEEE Trans. NS. 46, 800–5. Reprinted with
permission from IEEE. ©1968. 565
Fig. 14.25, Fig. 14.26, and Fig. 14.27. Giachero, A., Gotti, C., Maino, M., and Pessina, G. (2011).
Current feedback operational amplifiers as fast charge sensitive preamplifiers for
photomultiplier read out. J Inst. 6, P05004, 1–19. Reprinted with permission from
IOP ©2011. 567, 568, 570
1
Why photomultipliers?
1 2 Why photomultipliers?

1.1 Aspects of light detection


1.1.1 Introduction
Photon detectors transform information, carried by light, to an electrical analogue.
A light signal primarily contains information on: time relative to some initiating
event; intensity in terms of a number of photons; position of a detected signal on
the photocathode; and wavelength. Not all this information is necessarily sought
by a user, and some detectors are superior to others concerning a particular
performance attribute. Intensity may refer to the number of photons per event,
or per unit time, with consideration for the detector area. Photon rates may be
constant with time (DC detection), slowly varying, or transient in nature. The time
response of a detector is generally specified in terms of some property of the pulse
shape, such as its rise time; or the response may be described in terms of band-
width. All detectors are sensitive to the wavelength of a signal but without the
capability for its direct determination: this demands additional instrumentation,
such as a monochromator.
The process of light detection is a quantum mechanical one of absorbing the
energy of a photon to produce a free electron. Given the generation of sufficient
photoelectrons per unit time, it is possible to quantify this charge in terms of a
current or voltage to provide a measure of the light input. The ability to detect a
light signal depends broadly on two considerations. The first is the sensitivity of the
photocathode, in terms of quantum efficiency (QE), η: that is, the ratio of the
number of photoelectrons produced to the number of incident photons and
second, the level of background. QE is always less than unity, although in certain
solid state detectors the QE approaches unity over a limited wavelength band.
Other detectors, such as photomultipliers (PMTs), are often used at infrared
wavelengths, where QEs are very low. It is, however, still feasible to make meas-
urements under these circumstances since PMTs are capable of detecting single
photoelectrons, by virtue of their high and relatively noiseless gain. Until the 1970s
PMTs were the only commercially available devices with this capability, but now
solid state PMTs, SiPMs, with intrinsic gain are readily available.
A brief introduction to the terminology is appropriate at the outset, to remove
possible confusion. The following terms are encountered throughout the scientific
literature: signal current and signal counts, where the meanings are obvious.
Associated with these two variables we have dark current and dark counts, or
equivalently, background current, and background counts. The words dark and
background apply to the output from a detector in the absence of light input but
the terms actually refer to signals, albeit unwanted ones. Noise is reserved for the
description of statistical aspects of light, such as shot noise; it is not a signal but
rather a fluctuation within an existing one. ‘Noise in signal’ and ‘noise in back-
ground’ are the appropriate terms for the shot noise inherent in the current
produced by a light signal, and that produced by a background signal, respectively.

The Photomultiplier Handbook. Tony Wright.


© Tony Wright 2017. Published 2017 by Oxford University Press.
DOI: 10.1093/oso/9780199565092.001.0001
Aspects of light detection 3 1

Throughout this book background and noise will always refer to different aspects
of performance, as described here.
Light detectors may be divided into two broad categories: those that provide an
image and those that are non-imaging. Further subcategories are:

• vacuum devices, such as PMTs, microchannel plate PMTs (MCPPMTs),


and hybrid PMTs, in which a discrete multiplier is replaced by a solid state
diode
• solid state devices, such as PIN diodes, avalanche photodiodes (APDs);
pixelated silicon PMs (SiPMs), and charge-coupled devices (CCDs)

Throughout the book, the acronym PMT refers to traditional vacuum PMTs.

1.1.2 Brief history of PMTs


The invention of the PMT in 1936 is usually credited to the RCA Corporation in
the USA. However, Lubsandorzhiev (2006) makes a case in favour of L A
Kubetsky, a Russian, who produced a PMT in 1933–4 with an S1 photocathode,
consequently predating the work at RCA. This is arguable, but what cannot be
disputed is the leading role of RCA in the development of commercially available
product, starting in 1934. PMTs evolved from studies in electron secondary
emission at the turn of the twentieth century. It was observed, for certain metals,
that the process of secondary electron emission generated more electrons than
primary emission did—hence a means of amplification. RCA produced a single-
stage PMT in 1935, with a gain of 8 (Engstrom 1980). A multistage magnetically
focussed PMT followed in 1936 from researchers who were to become the leaders
in the PMT industry—Zworykin, Morton, and Malter (1936). This PMT was not
commercialized because of the difficult operating conditions imposed by the need
for both electrostatic and magnetic focussing. The first commercially available
PMT was the side window 931 with electrostatic focussing only, designed by
Zworykin and Rajchman (1939). Throughout the 1950s and 1960s, RCA
extended the range of photocathodes through the research of A H Sommer
(1980), who invented the bialkali and S20 photocathode types. During this period,
Philips and EMI between them enjoyed a share of about 30 % of the market,
specializing, respectively, in fast and low-background PMTs. The development
of negative affinity photocathodes in the 1970s made detection into the far
infrared, beyond one micron, possible. Several specialist companies exploited
these photocathodes mainly for military night vision purposes. Towards the end
of the 1970s a Japanese company, Hamamatsu, began to dominate the side
window market as RCA’s position waned. The only manufacturer of side window
PMTs is currently Hamamatsu, with a range of some 30 types of 10 mm and 30 mm
geometries. The historical industry standards are still available, such as the 931,
IP21, and the IP28; current product is similar in construction to the historical
1 4 Why photomultipliers?

versions but totally different in performance. The introduction of the S20 R928 in
the 1970s signalled a significant advance with infrared sensitivity of two to three
times that offered by the competitors, who to date have yet to find the key to
manufacturing this outstanding side window PMT type. Hamamatsu produce
both the world’s smallest vacuum PMT, the µPMT®, which is about the size of a
thumbnail, and the biggest, which is a hemispherical tube with a diameter of 2000 ;
they are the leaders of the PMT market with a share in excess of 90 %. Hamamatsu
also have the leading position in the silicon detector market. RCA, Photonis, and
Hamamatsu handbooks are available, all of which include a detailed historical
sketch of PMT development (Engstrom 1980; Flyckt and Marmonier 2002;
Hamamatsu 2007). Hamamatsu has set overall standards for consistency of
performance, particularly with respect to gain and sensitivity, and nowadays it is
unnecessary to allow a run-in period. Forty years ago the advice from experienced
users was to switch on a week in advance of intended use. This has long been
unacceptable as customers expect immediate stability of performance.

1.1.3 The statistical case for PMTs


A review article by Lallemand (1962), of the Paris Observatory, makes the case for
PMTs by investigating the limitations imposed by well-known laws of physics.
There are of course other reviews but Lallemand’s treatment is novel, and his
institute has the rare distinction of having made their own PMTs. His approach
will be adopted, based initially on the analysis of a photocell, comprising a
photocathode and an anode only; this is followed by the inclusion of a multiplier.
Consider the illumination of a photocathode with a random but steady source
of light that produces a photocurrent, Ik. Random implies all frequency compo-
nents are equally probable. By steady it is meant that the average current, meas-
ured over sufficiently long successive periods, is constant but superimposed on
this current is a random component arising from the quantized nature of light and
charge. This phenomenon is known as the Schottky effect. The rms noise current,
‹is2 ›1=2 , is the shot noise and is given by

‹is2 ›1=2 ¼ ð2eIk Δf Þ1=2 ; ð1:1Þ


where e is the electronic charge, and Δf is the noise bandwidth. Note that shot noise
only exists when a signal, Ik , is present: it may be interpreted as a random although
quantifiable modulation, ‹is2 ›1=2 , on Ik. Equation (1.1) is one of the more important
relationship in the subject of light measurement, and its influence on detectivity is
particularly felt whenever light levels are low. An inescapable consequence of (1.1) is
that precise measurement of Ik presents a considerable challenge by the presence of
this intrinsic noise, ‹is2 ›1=2 . It is customary in PMT applications to perform current-
to-voltage conversion at the anode by including a load resistor, R. However, all
resistors are a source of EMF with associated noise, the magnitude of which is
given by the Johnson noise formula:
Aspects of light detection 5 1

 
4kT Δf 1=2
‹ij2 ›1=2 ¼ ; ð1:2Þ
R
where k = 1.38  1023 J/K is the Boltzmann constant, and T the absolute
temperature, usually taken as 300 K. The thermal noise expression in terms of
voltage follows from (1.2) as

‹ν2j ›1=2 ¼ ð4kTRΔf Þ1=2 ; ð1:3Þ

and it appears to predict an EMF with infinite noise for an open circuit (infinite
resistance). However, the inescapable presence of stray capacitance, in addition to
any deliberately added for bandwidth control, presents finite impedance to the
signal. It is appropriate at this juncture to stress that, wherever noise is under
consideration, the appropriate bandwidth is Δf = 1/(4RC), and not the more
familiar signal bandwidth, 1/(2πRC), although the numerical difference is small.
Equation (1.3) then reduces to ‹νj2› = kT/C. It is useful to compare the relative
contributions to noise from these two major sources, assuming typical values for
the parameters involved.
Consider a photocurrent Ik = 1015 A, for example, which corresponds to an
average flow of 6300 photoelectrons (pe)/s. This is a weak, but not ultra-weak
signal, in PMT terms. Bandwidth, Δf, appears in both noise expressions, and for
the present ratio metric analysis we take Δf = 1, R = 1, T = 300, and ‹g› = 106 in
equations (1.4)–(1.6), which follow. There is no loss in generality because the
formulae readily scale. The mean gain, ‹g›, of the multiplier, is enclosed in chevrons
to emphasize its statistical nature. Shot noise originates from the current flow in the
photocathode but it is enhanced by the multiplier gain, ‹g›, when observed at the
anode. On the other hand, Johnson noise is outside the influence of the PMT, since
its source lies in an added load resistor. The contributions, taking Δf and R equal to
unity, from shot and Johnson noise at the anode are

‹is2 ›1=2 ¼ ð2eIk Þ1=2 ‹g› ¼ ð2  1:6  1019  1015 Þ1=2  106 ¼ 18 pA; ð1:4Þ

‹ij2 ›1=2 ¼ ð4kT =RÞ1=2 ¼ ð4  1:38  1023  300Þ1=2 ¼ 129 pA: ð1:5Þ

The combined noise is given by adding contributions in quadrature, noting that


(1.4) is signal dependent and (1.5) is not,

‹iðsþjÞ2 ›1=2 ¼ ð‹is2 ›2 þ ‹ij2 ›2 Þ1=2 ¼ ð182  1292 Þ1=2 ¼ 130 pA: ð1:6Þ

Equations (1.1), (1.2), and (1.6) are plotted in Fig. 1.1 as a function of R by
adopting unit bandwidth, as is standard practice. Note how the procedure of adding
in quadrature makes the net effect of the shot contribution negligible, in this case.
The two contributions are equal when
 
‹is2 ›1=2 2eIk R
¼  ‹g› ¼ 1: ð1:7Þ
‹ij2 ›1=2 4kT
1 6 Why photomultipliers?

1000

Combined noise
100

‹ia›1/2 (pA/√Hz)
Shot noise
10
Johnson noise

1
1 10 100 1000 10000
R (Ω)

Fig. 1.1. Comparison of the magnitudes of shot and Johnson noise, at the anode, for an
assumed cathode current of 1015 A, and a multiplier gain of 106. Note that the two noise
sources are the same in magnitude for a load resistance of 50 Ω—a value favoured for signal
transmission via matched coaxial cable. The combined noise is the sum of the two sources
taken in quadrature.

It follows from (1.7) for Ik = 1015 A, and ‹g› = 106, that R is 50 Ω, and
independent of Δf. The smallest measurable cathode current is determined by
the Johnson noise in the load resistor. The principal attribute of an electron multiplier
is that it gives current amplification without a resistor.
Handling fast, nanosecond rise time, output pulses from a detector demands a
bandwidth in the region of 100 MHz and preferably a load resistor of 50 Ω, for the
reasons previously given. The combined noise is
0 11=2
4kT
‹iðsþjÞ 2 ›1=2 ¼@ þ 2eIk ‹g›2 A Δf 1=2 ð1:8Þ
R
11
¼ 2:56  10  √10 ¼ 0:256 μA rms:
8

With, in this example, equal contributions derive from the two noise sources.
The effect of the wide bandwidth is to increase the noise from 25.6 pA rms, at
unity bandwidth, to 0.256 μA rms at 100 MHz bandwidth.
The gain required, such that multiplier noise will exceed Johnson noise is
given by
 1=2    
4kT 0:052 1=2 0:052 1=2
‹g›  ¼ ¼ ; ‹g›  7000: ð1:9Þ
2eIk R Ik R 109
Another random document with
no related content on Scribd:
"It's got to be something universal," I told Rizzo. "Something
universal ... in the widest sense of the term."
He looked up from his desk, which was wedged in between the end
of his bunk and the curving dome wall. The desk was littered with
printout sheets from the computer, each one of them part of the
message.
"You've only said that a half-million times in the past couple weeks.
What the hell is universal? If you can figure that out, you're damned
good."
What is universal? I wondered. You're an astronomer. You look out
at the universe. What do you see? I thought about it. What do I see?
Stars, gas, dust clouds, planets ... what's universal about them?
What do they all have that....
"Atoms!" I blurted.
Rizzo cocked a weary eye at me. "Atoms?"
"Atoms. Elements. Look...." I grabbed up a fistful of the sheets and
thumbed through them. "Look ... each message starts with a list of
numbers. Then there's a long blank to separate the opening list from
the rest of the message. See? Every time, the same length list."
"So?"
"The periodic table of the elements!" I shouted into his ear. "That's
the key!"
Rizzo shook his head. "I thought of that two days ago. No soap. In
the first place, the list that starts each message isn't always the
same. It's the same length, all right, but the numbers change. In the
second place, it always begins with 100000. I looked up the atomic
weight of hydrogen—it's 1.008 something."
That stopped me for a moment. But then something clicked into
place in my mind.
"Why is the hydrogen weight 1.008?" Before Rizzo could answer, I
went on, "For two reasons. The system we use arbitrarily rates
oxygen as 16-even. Right? All the other weights are calculated from
oxygen's. And we also give the average weight of an element,
counting all its isotopes. Our weight for hydrogen also includes an
adjustment for tiny amounts of deuterium and tritium. Right? Well,
suppose they have a system that rates hydrogen as a flat one:
1.00000. Doesn't that make sense?"
"You're getting punchy," Rizzo grumbled. "What about the isotopes?
How can they expect us to handle decimal points if they don't tell us
about them ... mental telepathy? What about...."
"Stop arguing and start calculating," I snapped. "Change that list of
numbers to agree with our periodic table. Change 1.00000 to 1.008-
whatever-it-is and tackle the next few elements. The decimals
shouldn't be so hard to figure out."
Rizzo grumbled to himself, but started working out the calculations. I
stepped over to the dome's microspool library and found an
elementary physics text. Within a few minutes, Rizzo had some
numbers and I had the periodic table focused on the microspool
reading machine.
"Nothing," Rizzo said, leaning over my shoulder and looking at the
screen. "They don't match at all."
"Try another list. They're not all the same."
He shrugged and returned to his desk. After a while he called out,
"their second number is 3.97123; it works out to 4.003-something."
It checked! "Good. That's helium. What about the next one, lithium?"
"That's 6.940."
"Right!"
Rizzo went to work furiously after that. I pushed a chair to the desk
and began working up from the end of the list. It all checked out,
from hydrogen to a few elements beyond the artificial ones that had
been created in the laboratories here on Earth.
"That's it," I said. "That's the key. That's our Rosetta Stone ... the
periodic table."
Rizzo stared at the scribbled numbers and jumble of papers. "I bet I
know what the other lists are ... the ones that don't make sense."
"Oh?"
"There are other ways to identify the elements ... vibration
resonances, quantum wavelengths ... somebody named Lewis came
out a couple years ago with a Quantum Periodic Table...."
"They're covering all the possibilities. There are messages for many
different levels of understanding. We just decoded the simplest one."
"Yeah."
I noticed that as he spoke, Rizzo's hand—still tightly clutching the
pencil—was trembling and white with tension.
"Well?"
Rizzo licked his lips. "Let's get to work."

We were like two men possessed. Eating, sleeping, even talking was
ignored completely as we waded through the hundreds of sheets of
paper. We could decode only a small percentage of them, but they
still represented many hours of communication. The sheets that we
couldn't decode, we suspected, were repetitions of the same
message that we were working on.
We lost all concept of time. We must have slept, more than once, but
I simply don't remember. All I can recall is thousands of numbers,
row upon row, sheet after sheet of numbers ... and my pencil
scratching symbols of the various chemical elements over them until
my hand was so cramped I could no longer open the fingers.
The message consisted of a long series of formulas; that much was
certain. But, without punctuation, with no knowledge of the symbols
that denote even such simple things as "plus" or "equals" or "yields,"
it took us more weeks of hard work to unravel the sense of each
equation. And even then, there was more to the message than met
the eye:
"Just what the hell are they driving at?" Rizzo wondered aloud. His
face had changed: it was thinner, hollow-eyed, weary, covered with a
scraggly beard.
"Then you think there's a meaning behind all these equations, too?"
He nodded. "It's a message, not just a contact. They're going to an
awful lot of trouble to beam out this message, and they're repeating
it every seven hours. They haven't added anything new in the weeks
we've been watching."
"I wonder how many years or centuries they've been sending out this
message, waiting for someone to pick it up, looking for someone to
answer them."
"Maybe we should call Washington...."
"No!"
Rizzo grinned. "Afraid of breaking radio silence?"
"Hell no. I just want to wait until we're relieved, so we can make this
announcement in person. I'm not going to let some old wheezer in
Washington get credit for this.... Besides, I want to know just what
they're trying to tell us."
It was agonizing, painstaking work. Most of the formulas meant
nothing to either one of us. We had to ransack the dome's meager
library of microspools to piece them together. They started simply
enough—basic chemical combinations: carbon and two oxygens
yield CO2; two hydrogens and oxygen give water. A primer ... not of
words, but of equations.
The equations became steadily longer and more complex. Then,
abruptly, they simplified, only to begin a new deepening, simplify
again, and finally become very complicated just at the end. The last
few lines were obviously repetitious.
Gradually, their meaning became clear to us.
The first set of equations started off with simple, naturally-occurring
energy yielding formulas. The oxidation of cellulose (we found the
formula for that in an organic chemistry text left behind by one of the
dome's previous occupants), which probably referred to the burning
of plants and vegetation. A string of formulas that had groupings in
them that I dimly recognized as amino acids—no doubt something to
do with digesting food. There were many others, including a few that
Rizzo claimed had the expression for chlorophyll in them.
"Naturally-occurring, energy-yielding reactions," Rizzo summarized.
"They're probably trying to describe the biological set-up on their
planet."
It seemed an inspired guess.

The second set of equations again began with simple formulas. The
cellulose-burning reaction appeared again, but this time it was
followed by equations dealing with the oxidation of hydrocarbons:
coal and oil burning? A long series of equations that bore repeatedly
the symbols for many different metals came up next, followed by
more on hydrocarbons, and then a string of formulas that we couldn't
decipher at all.
This time it was my guess: "These look like energy-yielding
reactions, too. At least in the beginning. But they don't seem to be
naturally occurring types. Then comes a long story about metals.
They're trying to tell us the history of their technological development
—burning wood, coal and eventually oil; smelting metals ... they're
showing us how they developed their technology."
The final set of equations began with an ominous simplicity: a short
series of very brief symbols that had the net result of four hydrogen
atoms building into a helium atom. Nuclear fusion.
"That's the proton-proton reaction," I explained to Rizzo. "The type of
fusion that goes on in the Sun."
The next series of equations spelled out the more complex carbon-
nitrogen cycle of nuclear fusion, which was probably the primary
energy source of their own Cepheid variable star. Then came a long
series of equations that we couldn't decode in detail, but the symbols
for uranium and plutonium, and some of the heavier elements, kept
cropping up.
Then came one line that told us the whole story: the lithium-hydride
equation—nuclear fusion bombs.
The equations went on to more complex reactions, formulas that no
man on Earth had ever seen before. They were showing us the
summation of their knowledge, and they had obviously been dealing
with nuclear energies for much longer than we have on Earth.
But interspersed among the new equations, they repeated a set of
formulas that always began with the lithium-hydride fusion reaction.
The message ended in a way that wrenched my stomach: the fusion
bomb reaction and its cohorts were repeated ten straight times.

I'm not sure of what day it was on the calendar, but the clock on the
master control console said it was well past eleven.
Rizzo rubbed a weary hand across his eyes. "Well, what do you
think?"
"It's pretty obvious," I said. "They have the bombs. They've had them
for quite some time. They must have a lot of other weapons, too—
more ... advanced. They're trying to tell us their history with the
equations. First they depended on natural sources of energy, plants
and animals; then they developed artificial energy sources and built
up a technology; finally they discovered nuclear energy."
"How long do you think they've had the bombs?"
"Hard to tell. A generation ... a century. What difference does it
make? They have them. They probably thought, at first, that they
could learn to live with them ... but imagine what it must be like to
have those weapons at your fingertips ... for a century. Forever. Now
they're so scared of them that they're beaming their whole history out
into space, looking for someone to tell them how to live with the
bombs, how to avoid using them."
"You could be wrong," Rizzo said. "They could be boasting about
their arsenal."
"Why? For what reason? No ... the way they keep repeating those
last equations. They're pleading for help."
Rizzo turned to the oscilloscope. It was flickering again.
"Think it's the same thing?"
"No doubt. You're taping it anyway, aren't you?"
"Yeah, sure. Automatically."
Suddenly, in mid-flight, the signal winked off. The pulsations didn't
simply smooth out into a steady line, as they had before. The screen
simply went dead.
"That's funny," Rizzo said, puzzled. He checked the oscilloscope.
"Nothing wrong here. Something must've happened to the
telescope."
Suddenly I knew what had happened. "Take the spectrometer off and
turn on the image-amplifier," I told him.
I knew what we would see. I knew why the oscilloscope beam had
suddenly gone off scale. And the knowledge was making me sick.
Rizzo removed the spectrometer set-up and flicked the switch that
energized the image-amplifier's viewscreen.
"Holy God!"
The dome was flooded with light. The star had exploded.
"They had the bombs all right," I heard myself saying. "And they
couldn't prevent themselves from using them. And they had a lot
more, too. Enough to push their star past its natural limits."
Rizzo's face was etched in the harsh light.
"I've gotta get out of here," he muttered, looking all around the
cramped dome. "I've gotta get back to my wife and find someplace
where it's safe...."
"Someplace?" I asked, staring at the screen. "Where?"

THE END

[1] Astronomers have been able, since about 1910, to estimate


the distances of Cepheid variable stars by timing their pulsations.
The length of this type of star's pulsation is a true measure of its
intrinsic brightness. Comparing the star's actual brightness to its
apparent brightness, as seen from Earth, gives a good value for
the star's distance.
*** END OF THE PROJECT GUTENBERG EBOOK ANSWER,
PLEASE ANSWER ***

Updated editions will replace the previous one—the old editions will
be renamed.

Creating the works from print editions not protected by U.S.


copyright law means that no one owns a United States copyright in
these works, so the Foundation (and you!) can copy and distribute it
in the United States without permission and without paying copyright
royalties. Special rules, set forth in the General Terms of Use part of
this license, apply to copying and distributing Project Gutenberg™
electronic works to protect the PROJECT GUTENBERG™ concept
and trademark. Project Gutenberg is a registered trademark, and
may not be used if you charge for an eBook, except by following the
terms of the trademark license, including paying royalties for use of
the Project Gutenberg trademark. If you do not charge anything for
copies of this eBook, complying with the trademark license is very
easy. You may use this eBook for nearly any purpose such as
creation of derivative works, reports, performances and research.
Project Gutenberg eBooks may be modified and printed and given
away—you may do practically ANYTHING in the United States with
eBooks not protected by U.S. copyright law. Redistribution is subject
to the trademark license, especially commercial redistribution.

START: FULL LICENSE


THE FULL PROJECT GUTENBERG LICENSE
PLEASE READ THIS BEFORE YOU DISTRIBUTE OR USE THIS WORK

To protect the Project Gutenberg™ mission of promoting the free


distribution of electronic works, by using or distributing this work (or
any other work associated in any way with the phrase “Project
Gutenberg”), you agree to comply with all the terms of the Full
Project Gutenberg™ License available with this file or online at
www.gutenberg.org/license.

Section 1. General Terms of Use and


Redistributing Project Gutenberg™
electronic works
1.A. By reading or using any part of this Project Gutenberg™
electronic work, you indicate that you have read, understand, agree
to and accept all the terms of this license and intellectual property
(trademark/copyright) agreement. If you do not agree to abide by all
the terms of this agreement, you must cease using and return or
destroy all copies of Project Gutenberg™ electronic works in your
possession. If you paid a fee for obtaining a copy of or access to a
Project Gutenberg™ electronic work and you do not agree to be
bound by the terms of this agreement, you may obtain a refund from
the person or entity to whom you paid the fee as set forth in
paragraph 1.E.8.

1.B. “Project Gutenberg” is a registered trademark. It may only be


used on or associated in any way with an electronic work by people
who agree to be bound by the terms of this agreement. There are a
few things that you can do with most Project Gutenberg™ electronic
works even without complying with the full terms of this agreement.
See paragraph 1.C below. There are a lot of things you can do with
Project Gutenberg™ electronic works if you follow the terms of this
agreement and help preserve free future access to Project
Gutenberg™ electronic works. See paragraph 1.E below.
1.C. The Project Gutenberg Literary Archive Foundation (“the
Foundation” or PGLAF), owns a compilation copyright in the
collection of Project Gutenberg™ electronic works. Nearly all the
individual works in the collection are in the public domain in the
United States. If an individual work is unprotected by copyright law in
the United States and you are located in the United States, we do
not claim a right to prevent you from copying, distributing,
performing, displaying or creating derivative works based on the
work as long as all references to Project Gutenberg are removed. Of
course, we hope that you will support the Project Gutenberg™
mission of promoting free access to electronic works by freely
sharing Project Gutenberg™ works in compliance with the terms of
this agreement for keeping the Project Gutenberg™ name
associated with the work. You can easily comply with the terms of
this agreement by keeping this work in the same format with its
attached full Project Gutenberg™ License when you share it without
charge with others.

1.D. The copyright laws of the place where you are located also
govern what you can do with this work. Copyright laws in most
countries are in a constant state of change. If you are outside the
United States, check the laws of your country in addition to the terms
of this agreement before downloading, copying, displaying,
performing, distributing or creating derivative works based on this
work or any other Project Gutenberg™ work. The Foundation makes
no representations concerning the copyright status of any work in
any country other than the United States.

1.E. Unless you have removed all references to Project Gutenberg:

1.E.1. The following sentence, with active links to, or other


immediate access to, the full Project Gutenberg™ License must
appear prominently whenever any copy of a Project Gutenberg™
work (any work on which the phrase “Project Gutenberg” appears, or
with which the phrase “Project Gutenberg” is associated) is
accessed, displayed, performed, viewed, copied or distributed:
This eBook is for the use of anyone anywhere in the United
States and most other parts of the world at no cost and with
almost no restrictions whatsoever. You may copy it, give it away
or re-use it under the terms of the Project Gutenberg License
included with this eBook or online at www.gutenberg.org. If you
are not located in the United States, you will have to check the
laws of the country where you are located before using this
eBook.

1.E.2. If an individual Project Gutenberg™ electronic work is derived


from texts not protected by U.S. copyright law (does not contain a
notice indicating that it is posted with permission of the copyright
holder), the work can be copied and distributed to anyone in the
United States without paying any fees or charges. If you are
redistributing or providing access to a work with the phrase “Project
Gutenberg” associated with or appearing on the work, you must
comply either with the requirements of paragraphs 1.E.1 through
1.E.7 or obtain permission for the use of the work and the Project
Gutenberg™ trademark as set forth in paragraphs 1.E.8 or 1.E.9.

1.E.3. If an individual Project Gutenberg™ electronic work is posted


with the permission of the copyright holder, your use and distribution
must comply with both paragraphs 1.E.1 through 1.E.7 and any
additional terms imposed by the copyright holder. Additional terms
will be linked to the Project Gutenberg™ License for all works posted
with the permission of the copyright holder found at the beginning of
this work.

1.E.4. Do not unlink or detach or remove the full Project


Gutenberg™ License terms from this work, or any files containing a
part of this work or any other work associated with Project
Gutenberg™.

1.E.5. Do not copy, display, perform, distribute or redistribute this


electronic work, or any part of this electronic work, without
prominently displaying the sentence set forth in paragraph 1.E.1 with
active links or immediate access to the full terms of the Project
Gutenberg™ License.
1.E.6. You may convert to and distribute this work in any binary,
compressed, marked up, nonproprietary or proprietary form,
including any word processing or hypertext form. However, if you
provide access to or distribute copies of a Project Gutenberg™ work
in a format other than “Plain Vanilla ASCII” or other format used in
the official version posted on the official Project Gutenberg™ website
(www.gutenberg.org), you must, at no additional cost, fee or expense
to the user, provide a copy, a means of exporting a copy, or a means
of obtaining a copy upon request, of the work in its original “Plain
Vanilla ASCII” or other form. Any alternate format must include the
full Project Gutenberg™ License as specified in paragraph 1.E.1.

1.E.7. Do not charge a fee for access to, viewing, displaying,


performing, copying or distributing any Project Gutenberg™ works
unless you comply with paragraph 1.E.8 or 1.E.9.

1.E.8. You may charge a reasonable fee for copies of or providing


access to or distributing Project Gutenberg™ electronic works
provided that:

• You pay a royalty fee of 20% of the gross profits you derive from
the use of Project Gutenberg™ works calculated using the
method you already use to calculate your applicable taxes. The
fee is owed to the owner of the Project Gutenberg™ trademark,
but he has agreed to donate royalties under this paragraph to
the Project Gutenberg Literary Archive Foundation. Royalty
payments must be paid within 60 days following each date on
which you prepare (or are legally required to prepare) your
periodic tax returns. Royalty payments should be clearly marked
as such and sent to the Project Gutenberg Literary Archive
Foundation at the address specified in Section 4, “Information
about donations to the Project Gutenberg Literary Archive
Foundation.”

• You provide a full refund of any money paid by a user who


notifies you in writing (or by e-mail) within 30 days of receipt that
s/he does not agree to the terms of the full Project Gutenberg™
License. You must require such a user to return or destroy all
copies of the works possessed in a physical medium and
discontinue all use of and all access to other copies of Project
Gutenberg™ works.

• You provide, in accordance with paragraph 1.F.3, a full refund of


any money paid for a work or a replacement copy, if a defect in
the electronic work is discovered and reported to you within 90
days of receipt of the work.

• You comply with all other terms of this agreement for free
distribution of Project Gutenberg™ works.

1.E.9. If you wish to charge a fee or distribute a Project Gutenberg™


electronic work or group of works on different terms than are set
forth in this agreement, you must obtain permission in writing from
the Project Gutenberg Literary Archive Foundation, the manager of
the Project Gutenberg™ trademark. Contact the Foundation as set
forth in Section 3 below.

1.F.

1.F.1. Project Gutenberg volunteers and employees expend


considerable effort to identify, do copyright research on, transcribe
and proofread works not protected by U.S. copyright law in creating
the Project Gutenberg™ collection. Despite these efforts, Project
Gutenberg™ electronic works, and the medium on which they may
be stored, may contain “Defects,” such as, but not limited to,
incomplete, inaccurate or corrupt data, transcription errors, a
copyright or other intellectual property infringement, a defective or
damaged disk or other medium, a computer virus, or computer
codes that damage or cannot be read by your equipment.

1.F.2. LIMITED WARRANTY, DISCLAIMER OF DAMAGES - Except


for the “Right of Replacement or Refund” described in paragraph
1.F.3, the Project Gutenberg Literary Archive Foundation, the owner
of the Project Gutenberg™ trademark, and any other party
distributing a Project Gutenberg™ electronic work under this
agreement, disclaim all liability to you for damages, costs and
expenses, including legal fees. YOU AGREE THAT YOU HAVE NO
REMEDIES FOR NEGLIGENCE, STRICT LIABILITY, BREACH OF
WARRANTY OR BREACH OF CONTRACT EXCEPT THOSE
PROVIDED IN PARAGRAPH 1.F.3. YOU AGREE THAT THE
FOUNDATION, THE TRADEMARK OWNER, AND ANY
DISTRIBUTOR UNDER THIS AGREEMENT WILL NOT BE LIABLE
TO YOU FOR ACTUAL, DIRECT, INDIRECT, CONSEQUENTIAL,
PUNITIVE OR INCIDENTAL DAMAGES EVEN IF YOU GIVE
NOTICE OF THE POSSIBILITY OF SUCH DAMAGE.

1.F.3. LIMITED RIGHT OF REPLACEMENT OR REFUND - If you


discover a defect in this electronic work within 90 days of receiving it,
you can receive a refund of the money (if any) you paid for it by
sending a written explanation to the person you received the work
from. If you received the work on a physical medium, you must
return the medium with your written explanation. The person or entity
that provided you with the defective work may elect to provide a
replacement copy in lieu of a refund. If you received the work
electronically, the person or entity providing it to you may choose to
give you a second opportunity to receive the work electronically in
lieu of a refund. If the second copy is also defective, you may
demand a refund in writing without further opportunities to fix the
problem.

1.F.4. Except for the limited right of replacement or refund set forth in
paragraph 1.F.3, this work is provided to you ‘AS-IS’, WITH NO
OTHER WARRANTIES OF ANY KIND, EXPRESS OR IMPLIED,
INCLUDING BUT NOT LIMITED TO WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR ANY PURPOSE.

1.F.5. Some states do not allow disclaimers of certain implied


warranties or the exclusion or limitation of certain types of damages.
If any disclaimer or limitation set forth in this agreement violates the
law of the state applicable to this agreement, the agreement shall be
interpreted to make the maximum disclaimer or limitation permitted
by the applicable state law. The invalidity or unenforceability of any
provision of this agreement shall not void the remaining provisions.
1.F.6. INDEMNITY - You agree to indemnify and hold the
Foundation, the trademark owner, any agent or employee of the
Foundation, anyone providing copies of Project Gutenberg™
electronic works in accordance with this agreement, and any
volunteers associated with the production, promotion and distribution
of Project Gutenberg™ electronic works, harmless from all liability,
costs and expenses, including legal fees, that arise directly or
indirectly from any of the following which you do or cause to occur:
(a) distribution of this or any Project Gutenberg™ work, (b)
alteration, modification, or additions or deletions to any Project
Gutenberg™ work, and (c) any Defect you cause.

Section 2. Information about the Mission of


Project Gutenberg™
Project Gutenberg™ is synonymous with the free distribution of
electronic works in formats readable by the widest variety of
computers including obsolete, old, middle-aged and new computers.
It exists because of the efforts of hundreds of volunteers and
donations from people in all walks of life.

Volunteers and financial support to provide volunteers with the


assistance they need are critical to reaching Project Gutenberg™’s
goals and ensuring that the Project Gutenberg™ collection will
remain freely available for generations to come. In 2001, the Project
Gutenberg Literary Archive Foundation was created to provide a
secure and permanent future for Project Gutenberg™ and future
generations. To learn more about the Project Gutenberg Literary
Archive Foundation and how your efforts and donations can help,
see Sections 3 and 4 and the Foundation information page at
www.gutenberg.org.

Section 3. Information about the Project


Gutenberg Literary Archive Foundation
The Project Gutenberg Literary Archive Foundation is a non-profit
501(c)(3) educational corporation organized under the laws of the
state of Mississippi and granted tax exempt status by the Internal
Revenue Service. The Foundation’s EIN or federal tax identification
number is 64-6221541. Contributions to the Project Gutenberg
Literary Archive Foundation are tax deductible to the full extent
permitted by U.S. federal laws and your state’s laws.

The Foundation’s business office is located at 809 North 1500 West,


Salt Lake City, UT 84116, (801) 596-1887. Email contact links and up
to date contact information can be found at the Foundation’s website
and official page at www.gutenberg.org/contact

Section 4. Information about Donations to


the Project Gutenberg Literary Archive
Foundation
Project Gutenberg™ depends upon and cannot survive without
widespread public support and donations to carry out its mission of
increasing the number of public domain and licensed works that can
be freely distributed in machine-readable form accessible by the
widest array of equipment including outdated equipment. Many small
donations ($1 to $5,000) are particularly important to maintaining tax
exempt status with the IRS.

The Foundation is committed to complying with the laws regulating


charities and charitable donations in all 50 states of the United
States. Compliance requirements are not uniform and it takes a
considerable effort, much paperwork and many fees to meet and
keep up with these requirements. We do not solicit donations in
locations where we have not received written confirmation of
compliance. To SEND DONATIONS or determine the status of
compliance for any particular state visit www.gutenberg.org/donate.

While we cannot and do not solicit contributions from states where


we have not met the solicitation requirements, we know of no
prohibition against accepting unsolicited donations from donors in
such states who approach us with offers to donate.

International donations are gratefully accepted, but we cannot make


any statements concerning tax treatment of donations received from
outside the United States. U.S. laws alone swamp our small staff.

Please check the Project Gutenberg web pages for current donation
methods and addresses. Donations are accepted in a number of
other ways including checks, online payments and credit card
donations. To donate, please visit: www.gutenberg.org/donate.

Section 5. General Information About Project


Gutenberg™ electronic works
Professor Michael S. Hart was the originator of the Project
Gutenberg™ concept of a library of electronic works that could be
freely shared with anyone. For forty years, he produced and
distributed Project Gutenberg™ eBooks with only a loose network of
volunteer support.

Project Gutenberg™ eBooks are often created from several printed


editions, all of which are confirmed as not protected by copyright in
the U.S. unless a copyright notice is included. Thus, we do not
necessarily keep eBooks in compliance with any particular paper
edition.

Most people start at our website which has the main PG search
facility: www.gutenberg.org.

This website includes information about Project Gutenberg™,


including how to make donations to the Project Gutenberg Literary
Archive Foundation, how to help produce our new eBooks, and how
to subscribe to our email newsletter to hear about new eBooks.

You might also like