Narayana (Adv Level) - P1 & P2 Assignment - 13

NARAYANA IIT ACADEMY
JEE (Advanced)-2023
FULL TEST – X
PAPER –1
ASSIGNMENT - 13
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Time Allotted: 3 Hours Maximum Marks: 180
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General Instructions:
 The test consists of total 57 questions.
 Each subject (PCM) has 19 questions.
 This question paper contains Three Parts.
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 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-B & Section-C.
Section – A (01 – 04, 20 – 23, 39 – 42): This section contains TWELVE (12) questions. Each question has
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FOUR options. ONLY ONE of these four options is the correct answer.
Section – A (05 –10, 24 – 29, 43 – 48): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – B (11 – 13, 30 – 32, 49 – 51): This section contains NINE (09) questions. The answer to each
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question is a NON-NEGATIVE INTEGER.

Section – C (14 – 19, 33 – 38, 52 – 57): This section contains NINE (09) question stems. There are TWO
(02) questions corresponding to each question stem. The answer to each question is a NUMERICAL
VALUE. If the numerical value has more than two decimal places, truncate/round-off the value to TWO
A
decimal places.
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MARKING SCHEME
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
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Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
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Full Marks : +4 If only (all) the correct option(s) is (are) chosen;

Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
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of which are correct;

Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
Section – C: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Physics PART – I
Section – A (Maximum Marks: 12)
This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.
1. A thin conducting circular disc of mass m, thickness d and radius R

(R >> d) is released in a uniform horizontal magnetic field of
 
induction B . The magnetic induction vector B is in the plane of B R g
the disc as shown in the fiugre. The acceleration of the disc is
mg
(A)
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(m  20 R2B 2d)
mg
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(B)
(2m  0 R2B 2d)
2mg
(C)
(m  0 R2B 2 d)
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mg
(D)
(m  0 R2B 2 d)
2. AC
Three rigid rods each of mass m and length  are joined to
form an equilateral triangle. The two corners A and B are
A m, B
pivoted in the same horizontal level and this assembly is

kept in a vertical plane. The hinge reaction at A immediately m, m,
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after nail B is removed.

Vertical plane
(A) 3mg C
(B) 2 3mg
A
(C) 3 3mg
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(D) 4 3mg
3. Three alternating voltage sources V1 = 3 sin t volt, V2 = ~V

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5sin(t + 1) volt and V3 = 5 sin(t  2) volt connected across 3

V2
7 ~ 7
a resistance R   as shown in the figure. (Where 1 and 
3 3
V1
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2 correspond) to 30 and 127 respectively). The peak current ~

through the resistor is
(A) 1A
(B) 2A
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(C) 3A
(D) 4A
4. Two identical capacitors A and B shown in the given circuit are

joined in series with a battery. If a dielectric slab of dielectric
constant K is inserted between the plates of capacitor B and battery A
remains connected, then the energy stored in the capacitor A will V
(A) decrease B
(B) increase
(C) remain the same
(D) initially increase and then decrease to initial value

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).
5. Two containers A and B are connected by a conducting solid A B

242 O2 He
cylindrical rod of length cm and radius 8.3 cm. Thermal
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conductivity of the rod is 693 w/m-k and specific heat capacity of the
rod is negligible. The container A contains two moles of oxygen gas
and container B contains four moles of helium gas. At time t = 0
temperature difference of the containers is 50C, after what time
temperature difference between them will be 25C. Transfer of heat
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takes place through the rod only. Neglect radiation loss. (Take R = 8.3
22
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J/mole-k,   and n2 = 0.693)
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(A) 3 sec
(B) 5 sec
(C) 7 sec
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(D) 9 sec
6. A uniform electric field exists in xy plane. The potential at points A(2m,2m), B(2m,2m) and
C(2m,4m) are 4V, 16V, and 12V respectively. The components of electric field in x and y
directions are
(A) Ex  3 V/m
AC
(B) Ex  4 V/m
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(C) E y  4 V/m
(D) E y  4 V/m
7. Two vertical parallel rectangular glass plates are partially submerged in

A
water. The separation between the plates is d = 0.1 mm and the width of
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each plate is  = 10 cm. Assuming that the water between the plates h
does not reach the upper edges of the plates and the contact angle is  =
0. The surface tension of water is T = 7  102 N/m and the density of
water is  = 103 kg/m3. Then choose the correct option(s). (g = 10 m/s2) d
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(A) The water rises upto height h = 14 cm between the plates.

(B) The water rises upto height h = 28 cm between the plates.
(C) The force of mutual attraction between the plates is 4.9 N.
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(D) The force of mutual attraction between the plates is 9.8 N.
8. In the figure A, B and C are three slits each of them individually

producing the same intensity I0 at P when they are illuminated by
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C
parallel beam of light of wavelength . It is given that
 d
BP  AP  . Also given that d <<D, then wavelength  and the B
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resulting intensity I at P will be ( <<d).
2d
2d2
(A)  A
D P
4d2
(B)  D
D
(C) I = 2I0
(D) I = I0
9. Which of the following products in Bohr’s atom are independent of principal quantum number n?
(v  velocity, E  energy, r  radius)
(A) vn
(B) Er
(C) En
(D) vr
10. In a hypothetical atom, potential energy between electron and nucleus is given by U = knr.
Where r is orbital radius and k is a constant. The expression for orbital radius and total energy for
such an atom according to Bohr’s model are
nh
(A) r
2 mk
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nk
(B) r
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2 mk
1  nh  
(C) E    n   k
2  2 mk  
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 nh 
(D) E  k n  
 2 nk 
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Section – B (Maximum Marks: 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.
11. Five identical capacitor plates are arranged such that they 10V
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make four capacitors each of 2F. The plates are

connected to a source of emf 10 V. Find the charge on the
plate C in C.
A
A
B
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D
E
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12. In a certain region, uniform electric field E  E0 kˆ and magnetic z B0 E0
field B  B kˆ are present. At time t = 0, a particle of mass m and

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charge q is given a velocity v  v 0 ˆj  v 0kˆ . Find the time (in sec)

when the speed of the particle becomes minimum. (Given
mv 0  4qE0 )
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13. A spring mass system is kept on a rough horizontal m=1kg

surface having co-efficient of friction  = 0.4. One end of k=100 N/m
the spring is fixed to the vertical wall as shown in the m
figure. Initially the spring is stretched by 27 cm and then
it is released. The total distance covered by the block
before it comes to permanent rest is x cm. Find x. (Take
g = 10 m/s2)
Section – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.
Question Stem for Question Nos. 14 and 15
Question Stem
The space has electromagnetic field which varies with time whose variation is given as:
y
 ˆ m
 B 0 k if 0  t 
 qB0  2 m
Y
 0 if 0t
  m 2m   qB0 O
B  B0 ˆj if t and E   x
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 qB 0 qB 0 E kˆ 2 m
if t
 2m  0 qB0
 0 if t
 qB0
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A charge particle having mass m and positive charge q is given a velocity v 0 î at origin at t = 0. The
coordinates of the point on xy plane where it again passes through the xy plane for the first time are
 Kmv 0 v0 2mv 0 
 , , 0 .
 q

14.
E0B0 NqB0
The value of K is ………..


 AC
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15. The value of N is ………..

A
Question Stem
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Ring, solid cylinder and solid sphere are placed on the top of a rough inclined plane of inclination  and all
of them are released from rest at same instant from same point. Only solid sphere can just roll without
 t ring 
slipping. The ratio of their time to reach the ground  is X and the ratio of their time to reach the
 t sphere 
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 
 t cylinder 
ground  is Y.
 t sphere 
 
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16. The value of X is………………

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17. The value of Y is……………….

Question Stem
A river has width d. A fisherman in a boat crosses the river twice. During the first crossing, his goal is to
minimize the crossing time. During the second crossing, his goal is to minimize the distance that the boat
is carried downstream. In the first case, the crossing time is t while in the second case, the crossing time
 1d  Y d
is 3t. The speed of fisherman is   and the speed of river is   .
 X t 2 2 t
18. The value of X is ………..
19. The value of Y is ………..
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A
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Chemistry PART – II
20. The major product of the reaction is
1 NaOH
H3C C C 
  Product  P 
 2 H /H2O
O O
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(A) OH
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H3C C C OH
O
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(B) OH
C C
O
OH
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(C) O O
H3C C C OH
A
(D) O
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H3C C OH
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OH
21. Beryl  Be3 Al2 Si6 O18  is a silicate. The number of oxygen atom of structural unit of SiO44  shared
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with neighbouring unit in Beryl are:

(A) 1
(B) 2
(C) 3
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(D) 4
22. Which of the following statements is incorrect?

(A) Glycerol (1 mole) on reaction with periodic acid (2 moles) yields formaldehyde and formic
acid
(B) Glycerol on dehydration in presence of conc. H2 SO 4 yields unpleasant smelling
compound
(C) Oxidation of glycerol with conc. HNO3 gives mainly glyceric acid
(D) Glycerol on heating with large excess of HI produces allyl iodide
23. O
CH3
N
CH3

H   P  Major product 
CH3
P is
(A)
CH3
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(B)
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H
CH3
(C)
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(D)
AC
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A
24. Consider the following cell:

M  s  | MX2  s  , X   0.2 M  || M2  0.01 M | M  s 
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The EMF of the cell at 298 K is 0.236 V

( MX2  s  being the sparingly soluble salt):
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Pick out the correct options of the following:

(A) The solubility product of MX2 is 2.0  10 11 M3
(B) The solubility of MX2 in 0.2 M X is 1.0  1010 M
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(C) The solubility product of MX2 is 4.0  1012 M3

(D) The solubility of MX2 in pure water is 1.0  10 4 M
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25. The correct statement(s) regarding cellulose is/are

(A) It is polymer of D-glucose
(B) It has   1, 4  glycosidic linkage
(C) It has general formula (C6H10O5)n
(D) It is used for making rayon fibre
26. Which of the following pairs consists of ore of same metal and both are oxides?
(A) Haematite, Magnetite
(B) Anglesite, Cerrusite
(C) Bauxite, Corundum
(D) Cuprite, Cassiterite
27. Kjeldahl’s method cannot be used for estimation of nitrogen present in

(A)
CONH2
(B)
N N
(C)
Y
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(D)
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H3C NO 2
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28. In container ‘A’, an ice cube of pure D2 O is to be placed in pure liquid H2 O . In container ‘B’, an
ice cube of pure H2 O is to be placed in pure liquid D2 O . Which of the following is/are correct
statements?
(A)
(B)
(C)
Ice cube will sink in container A. AC
Ice cube will float in both containers A and B.
Ice cube will sink in both containers A and B.

(D) Ice cube will float over in container B.
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29. HO CH3
1 H SO
A
2
 2 
4
 P Major product 
Products are
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(A) CH3
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OH
(B) CH3
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(C) CH3
(D) CH3
10

INTEGER.
30. What is the total number of correct statements in the following?

(A) Antiseptics are applied to living tissues.
(B) Aspirin is non-narcotic analgesic.
(C) Disinfectants are applied to inanimate.
(D) Aspartame is an artificial sweetener.
(E) Aspirin is acetyl salicylic acid.
(F) Insulin is a co-enzyme.
(G) Aluminium hydroxide is an antacid.
(H) D.D.T. is non-biodegradable pollutant.
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31. If P, Q, R, S is the total number of unpaired electrons in t 2g or t 2 set of orbitals in
2 4
K 3 Fe  CN6  , FeCl4  , Fe  H2 O 6  Cl3 , FeF6  respectively, then what is the value of
‘P + Q + R + S’?
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32. If closed vessel contains 5 g of ice at 10o C , then how much heat in kJ must be added to
convert it into steam at 205.56o C
[Given: Specific heat capacity (ice)  2.00 J / go C
Specific heat capacity of water  4.18 J / go C
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Specific heat capacity of steam  1.8 J / go C
Enthalpy of fusion of water = 333 J/g
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Enthalpy of vaporization of water = 2439 J/g

A
AN

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Question Stem
One mole each of ammonium di-chromate, ammonium nitrate and mercuric nitrate are heated strongly
and the gases evolved are collected. If ‘X’ is the total volume of diatomic gas/gases (in litres at S.T.P.)
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and ‘Y’ is the total volume of triatomic gas/gases (in litres at S.T.P.), ( molar volume of a gas at STP is
22.4 L), then
33. The value of ‘X’ is_______

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34. The value of ‘Y’ is_______

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Question Stem
A solution of 1.660 g of KI in 100 g of water freezes at ‘X’ Kelvin. The freezing point of this solution
saturated with solid HgI2 (Sparingly soluble in water) is ‘Y’ Kelvin. Considering KI and any species formed
to be completely ionized, answer the following.
[Given: K f  water   1.86 K kg mol1, freezing point of water = 273.15 K, Atomic mass of K = 39, I = 127]
35. What is the value of Y(in Kelvin)?
36. What is the value of Y – X (in Kelvin)?
Y
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Question Stem
A hydrogen-like species (atomic number Z) is in an excited state of quantum number n. An energy 3.40
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eV is required to remove the electron completely from this excited atomic species. Also, this excited atom
can make a transition to the IInd excited state by successively emitted two photons of energies 4.25 eV
and 5.95 eV respectively.
37. What is the value of ‘Z’?

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38. What is the ionization energy of first excited state of the atomic species?
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A
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Mathematics PART – III

39. Consider two curves C1 : y 2  4  y  x and C2 : x2  4  x  y where [.] denotes the greatest
integer function), then the area of region enclosed by these two curves within the square formed
by the lines x = 1, y = 1, x = 4, y = 4
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(A)
9
Y
11
(B)
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7
11
(C)
5
11
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(D)
3
x
40. A differentiable function g satisfy
(A) 12x2 – 24x + 26 – 26e–x

0 AC
  x  t  1 g  t  dt  x
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 x 2  x  0, then g(x) is
(B) 12x2 + 24x + 26 – 26e–x

(C) 12x2 + 24x – 26 – 26e–x
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(D) 12x2 – 24x – 26 – 26e–x
41. For a real number a, let [a] denote the greatest integer less than or equal to a. Let R denote the
region in the coordinate plane consisting of points (x, y) such that [x]2 + [y]2 = 25, the region R is
A
completely contained in a disk of radius r (a disk is the union of a circle and its interior), the
minimum values of r can be
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130
(A)
2
130
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(B)
2
130
(C)
2
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130
(D)
4
Maya lists all the positive divisors of 20102. She then randomly selects two distinct divisors from
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42.
this list. Then the probability that exactly one of the selected divisors is a perfect square is
32
(A)
81
26
(B)
81
16
(C)
81
34
(D)
81
13

43. A pyramid with vertex at the point P, whose position vector is 4iˆ  2ˆj  2 3 kˆ has a regular
hexagonal base ABCDEF. Position vectors of a point A and B are î and î  2ˆj respectively
centre of the base has the position vector î  ˆj  3 kˆ . Altitude drawn from P on the base meets
the diagonal AD at G, then the possible position vectors of G will be, it is given that volume of the
pyramid is 6 3 cubic units
(A) î  2ˆj  2 3 kˆ
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(B) î  2ˆj  3 kˆ
(C) î  2ˆj  2 3 kˆ
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(D) 3iˆ  2ˆj  2 3 kˆ
44. Integral value of x  [0, 2] which satisfy the inequality 2cos x  1  sin2x  1  sin 2x  2 is
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(A) 1
(B) 2
(C) 3
(D) 4
2 
AC 1
45. If the quadratic equation 4sec A x 2  2x   B2  B    0 have real roots, then the possible value
 2 
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of cos A + cos–1 B is

(A)
3
A

(B) 1
3
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
(C) 1
3

(D) 
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3
      
46. Let r  a   and r  b   are two lines through the point A and B with position vectors a and

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b respectively, then position vector of P and Q are where PQ is the shortest distance between
the given lines
     
   
ab      
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(A) P a
  2
  
     
    
a  b       
(B) P a
  2
  
     
   
ab      
(C) Q b
  2
   
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     
    
a b     
(D) Q b
  2
  
47. There are real numbers a, b, c and d such that –20, is a root of x 3 + ax + b and –21 is a root of
x3 + cx2 + d. These two polynomials have a complex root m  n i , where m, n are positive
integers and i  1 , then m and n can be
(A) m = 10
(B) m = 320
(C) n = 320
(D) n = 10
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 1  x a x 1  cos 2x  if
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Let f  x   
0  x 1
48. , if Rolle’s theorem is applicable to f(x) for x  [0,
 0 if x 0
1], then a, can be
(A) –2
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(B) –1
1
(C)
2
(D) 1

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INTEGER.
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x 2 x 3 x 4 x5
49. Let f  x   x     and g(x) = f –1(x), then g(0) is
2 3 4 5
A
50. Let ABC be a triangle such that AB = 7, and let the angle bisector of BAC intersect line BC at D.
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If there exist point E and F on sides AC and BC, respectively such that lines AD and EF are
parallel and divide triangle ABC into three parts of equal area, determine the number of possible
integral values of BC
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51. The value of 3p, so that lim xp

x 
 3

x  1  3 x  1  2  3 x is equal to some non-zero real number

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Question Stem
Let f: R  R such that f(0) = 1 and f(x + 2y) = f(x) + f(2y) + ex + 2y (x + 2y) – x·ex – 2y e2y + 4xy for all x, y
 R, then
2
52. The value of f(2) – 2e is
53. The value of f(3) – 4e3 is

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Question Stem
Let C1 be the curve xy = 1 and C2 the reflection of C1 in the line y = 2x let the equation of C1 be written in
the form of 12x2 + bxy + cy2 + d = 0
54. Then the value of b.c. is
55. The value of d is
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Question Stem
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A function f is defined for all real numbers and satisfy f(2 + x) = f(2 – x) and f(7 + x) = f(7 – x) for all real x
56. If x = 0 is a root of f(x) = 0, then the least number of roots of f(x) = 0 in the interval [–1000, 1000]
is
AD
57. The period of f(x) is
AC
IIT
A
AN
AY
AR
N
JEE (Advanced)-2023
FULL TEST – X
PAPER –1
ASSIGNMENT - 13
Y
EM
ANSWERS, HINTS & SOLUTIONS
AD
Physics PART – I
Section – A
1.
Sol.
D
E = Bv
AC
 A
q  0 Ed
IIT
d
q  0 R2Bv
dq dv
I  0 R2B
dt dt
A
dv
m  mg  BId
AN
dt
dv dv
m  mg  0 R2B2 d
dt dt
AY
dv
(m  0 R2B2 d)  mg
dt
dv mg
a 
AR
dt (m  0 R2B 2 d)
2. A
Sol. When the nail B is removed Ny
N
 3m 2
3mg  IA    /2
2 2 A B
  = g/ …(i) Nx 30
 g  g G
Also, a      Removed
3  3 3 nail
Nx = 3ma cos 60
a C
3
 Nx  mg
2
3mg  Ny = 3ma sin 60
3mg
 Ny 
2
N  N2X  N2Y  3mg
3. C
Sol. V1 = 3sin t; V2 = 5sin (t + 1) and V3 = 5sin(t  2) 5
2
5 3  2
30
Vmax     (1.5)  21 3
 2
 
37
Vmax 21 21 3
Imax     3A 5
Y
R 7/3 7
EM
4. B
C kC
Sol. Ceq  and Ceq   Ceq  Ceq
2 k 1
 Q > Q
AD
5. A
KA(1  2 )
Sol. i …(i)
d

Thermodynamics process in both the vessels are isochoric
i i
AC
 1   …(ii)
dt 5R 5R
2
IIT
2
d 2 i i
  …(iii)
dt 3R 6R
4
2
A
Addding (ii) and (iii), we get

d(1  2 ) 11i
AN
 
dt 30R
d(1  2 ) 11KA(1  2 )
  
dt 30R
AY
25 t
d kA  11
 
50


30R
dt 
0
(where, 1  2 = )
AR
0.693  30  242  10 2  8.3  7

t = 3 sec
693  7  22  8.3  10 4  11
N
6. A, D
12
Sol. Ex   Ex  3 V/m
4
8
Ey   Ey  4 V/m
2
7. A, D
Sol. 2T = dhg
2T 2  7  102
h  3  14  10 2 m  14cm h
gd 10  10  1 10 4
Force of mutual attraction between the plates is
h
gh2
F   gydy 
0
2 d
103  10  0.10  (14  10 2 )2

2
= 19.6/2= 9.8 N
Y
8. B, D
EM
 C
Sol. D2  4d2  D 
2
45
 1 4d2  
 D 1   2  1  B A
AD
 2 D  2
4d2

D
9.
Resulting intensity at point P is I = I0
A, B
AC
1 1
Sol. v , r  n2 ; E  2
IIT
n n
10. A, C
dU d k
Sol. F   (k nr)  
A
dr dr r
mv 2 k nh k
AN
 ; mvr  ;v
r r 2 m
k nh nh
 m r ;r 
m 2
AY
2 mk
1 k k
Again: E = U + k = knr + m   knr
2 m 2
1  nh  
AR
E  k   n  
2  2 mk  
Section – B
N
11. 40
Sol. Potential across each capacitor is 10 V
Charge = 20 C
Charge on plate C = 40 C (both sides included)
12. 4
qE0
Sol. aE  (along negative z-direction)
m
Electric field will make z-component of velocity zero. At that time speed of the particle will be
minimum and that minimum speed is the other component, i.e. v 0.
This is minimum when,

v z  uz  a z t
qE0
Or 0  v 0  t
m
mv 0
Or t  = 4 sec
qE 0
13. 90
2mg 2  0.4  1 10
Sol. The maximum displacement on each side decreases by   8 cm
k 100
mg
Y
It stops completely if comes to rest between   4 cm
k
EM
 S = 27 + (19 + 19) + (11 + 11) + 3 = 90 cm
Section – C
AD
14. 02.00
15. 01.00
Sol. (for Q.14-15):
2mv 0 1  qE0
qB0
 
2 m
 2
t

AC
4m2 v 0
 t2
q2E0B0
IIT
2m v0
x  v0  t  x  v0
q E0B0
A
16. 01.00
AN
17. 01.00
Sol. (for Q. 16-17):
For solid sphere to just start rolling without slipping.
AY
tan  2
  tan 
mR 2 7
1
I
AR
gsin  5
asphere  = gsin 
I 7
1
mR2
N
5
acylinder  g(sin    cos ) = gsin 
7
5
aring  g(sin    cos ) = gsin 
7
Ring, solid cylinder and solid sphere have same acceleration.
18. 01.00
19. 03.00
Sol. (for Q. 18-19):
During the first crossing,
d d
tv
v t
X= 1
During the second crossing,
v d
sin   and  3t  cos  = 1/3
u v cos 
v 3 d
u 
sin  2 2 t
Y
Y=3
EM
AD
AC
IIT
A
AN
AY
AR
N
Section – A
20. A
Sol. O O O O
H3C C C Ph OH 
  H3C C C OH
(EDG)
Ph
Y
EM
OH O O O
Acid  base
H3C C C O H3C C C OH
reaction
Ph Ph
AD
H / H2 O
H3C
OH O
C C OH
AC
Ph
IIT
21. B
Sol. Beryl is cyclic silicate, two oxygen atoms per tetrahedron are shared to form closed ring.
A
22. D
Sol. (A) CH2OH
AN
CHOH  2HIO4  2HCHO  HCOOH  2HI  H2 O
CH2OH
AY
(B) CH2OH CH2 CH2

CHOH Conc. H SO
2 4 Tautomerises
  C   CH
AR
or
P2 O5  Heat 
CH2OH Dehydrating agent  CHOH CHO
H2O
Unstable Acrolein
N
 unpleasant smell
(C) CH2OH COOH
CHOH Conc. HNO3

 CHOH
O
CH2OH CH2OH
Glyceric acid
(D) CH2OH CH2
CHOH  3HI 

 CH  I2
CH2OH CH2I
Allyl iodide
Allyl iodide formed further reacts with HI.
CH2 CH3 CH3
CH3
CH  HI   CHI 
I2
 CH Hi
  CHI
CH2I CH2I CH3
CH2
Y
Unstable Propene Isopropyl iodide
EM
23. B
Sol. Amine oxide on heating follows syn-elimination thus producing alkene
O
AD
CH3
N
CH3 CH3

  HO N
H
CH3
H
CH3
AC
CH3
24. B, C, D
IIT
M2 
0.059   right
Sol. Ecell  log
2 2 
M 
 left
A
0.059 0.01
0.236  log
2 M2 
AN
  left
M2    1  10 10 M
 left
 Solubility of MX2 in 0.2 M X   1  1010 M
AY
2 2
K SP of MX 2  M2   X    1  10 10   0.2   4  1012 M3
1/3 1/3
K   4.0  10 12 
AR
Solubility of MX2 in water   SP     1.0  104 M

 4   4 
25. A, B, C, D
N
Sol. Cellulose, a polymer of D-glucose, has   1, 4  glycosidic linkage .
26. A, C
Sol. Haematite  Fe2 O3 Bauxite  Al2 O3 .2H2 O 
 Oxide ores of same metal
Magnetite  Fe3 O 4 Corundum  Al2 O3 
Anglesite  PbSO4 Cuprite  Cu2 O
Cerrusite  PbCO3 Cassiterite  SnO2

Oxide ores of different metals
27. B, C, D
Sol. Kjeldahl’s method is not applicable to compounds in which nitrogen atom is present in ring and to
compounds containing nitro and azo groups.
28. B, D
Sol. Ice cube of D2 O has greater density than H2 O (liquid) and hence will sink.
Ice cube H2 O has smaller density than D2 O (liquid) and hence will float on it.
29. C, D
Sol. H3C
H3C OH OH 2 CH3 CH3 CH3
Y

H H O 
 2
 
 H
  
EM
H H
Section – B
AD
30. 7
Sol. All statements except (F) are true.
Insulin is a harmone and not co-enzyme.
31.
Sol.
9
AC eg
IIT
K 3 Fe  CN 6  : Fe3   3d5

A
t 2g P 1
AN
t2
AY
2
FeCl4  : Fe2   3d6
AR
e Q3
eg
N
Fe H2 O   Cl3 : Fe3   3d5

 6
t 2g R3
eg
4
FeF6  : Fe2   3d6
t 2g S2
P  Q  R  S  1 3  3  2  9
32. 17
Sol. the process involved are
Y
q1 q2 q3 q4 q5
H2 O  s   H2 O  s   H2 O     H2 O     H2 O  g  H2 O  g 
EM
 10 C
o
0o C 0o C 100o C 100o C 205.56o C
Q  q1  q2  q3  q4  q5
 5  2  10  333  4.18  100  2439  1.8  105.56 
AD
= 17000 J
Section – C
33. 44.80 AC
34. 67.20
Sol. (for Q. 33 and 34):
IIT

NH4 2 Cr2 O7   N2  Cr2 O3  4H2 O

NH4 NO3   N2 O  2H2 O

Hg NO3 2 
A
 Hg  2NO2  O2
Total number of moles of diatomic gases (X)  N2 1 mole   O 2 1 mole 
AN
= 2 moles
 Volume  2  22.4  44.8 litres
Total number of moles of triatomic gases  N2 O 1 mole   NO2  2 moles 
AY
= 3 moles
 Volume  3  22.4  67.2 litres
AR
35. 272.87
(272.86 – 272.88)
36. 00.09
N

1.66  1000
Molality of KI solution   0.1
166  100
Effective molality  i  0.1  2  0.1  0.2
Tf  KI  K f  m  1.86  0.2  0.372
‘X’ freezing point of KI solution = 273.15 – 0.372 = 272.778 = 272.78 K
In KI solution saturated with solid HgI2 we get K 2 HgI4 
2
2K   2I  HgI2  s   2K   HgI4 
Now, effective molality  1.5  0.1  0.15
10
‘Y’ (Freezing point of saturated solution) = 273.15 – (1.86 × 0.15)

= 273.15 – 0.279
= 272.87 K
 Y  X  272.87  272.78
= 0.09 K
37. 03.00
38. 30.60
1 1 
E  3.4 eV  13.6Z 2  2  2 
n  
Y
2
Z
3.4  13.6 2 … (1)
EM
n
Energy emitted in the transition from excited state to the IInd excited state (n = 3)
 1 1
E  4.25  5.95  13.6Z2  2  2 
 3 n 
AD
2
 n  9 
10.20  13.6 Z 2  2 
… (2)
 9n 
From (1) and (2), we get
10.20 n2  9
3.4

2
9
AC
n 9
3 n6
9
IIT
3.40  n2
From Eq. (1) Z2  Z3
13.6
1 1 
Ionization energy of first excited state (n = 2) of the atomic species E  13.6  32  2  2 
A
2  
AN
1
 13.6  9 
4
= 30.6 eV
AY
AR
N
11

Section – A
39. D
Sol. y 2  4  y  x  y  1, 4   y   1
y=4
 y2 = 4x similarly x  1, 4   x   1
x2 = 4y
2 4
 x2  11
 
Required area  2 x  1 dx    2 x   dx =
4 3
y=4
Y
1 2 
EM
x=1 x=4
40. A
x
AD
4
Sol.   x  t  1 g  t  dt  x  x 2 ; differentiating with respect to x
0
x
2
g  x    g  t  dt  4x 3  2x ; differentiating again g(x) + g(x) = 12x + 2
0
So, g(x) = 12x2 – 24x + 26 – 26e–x AC
41. A
Sol. The desired region consists of 12 boxes, whose lower left corners are integers solution of x 2 + y2
IIT
= 25, i.e. (5, 0), (0, 5), (3, 4), (4, 3)
 1 1
Since, the points them self are symmetric about (0, 0) the boxes are symmetric about  ,  ,
 2 2
A
 1 1
then distance from  ,  to the fullest point on a box that lays on the axis
 2 2
AN
130
So, minimum values r 
2
AY
42. B
2 2 2 2 2
Sol. 2010 = 2  3  5  67
4 4 4
Total divisors = 3  3  3  3 = 3 i.e. (2 + 1) and (1 + 1) of which are squares
AR
26
So, required probability =
81
43. A, C
N
Sol. Let the centre of base is (0) E D

  1 
P 4iˆ  2ˆj  2 3 kˆ 
AB  2ˆj  AB  2  OAB =  4 3
4 F G C
 Base area = 6 3
Let height of pyramid = h
1
 6 3h  6 3  h = 3
A î  
B î  2jˆ 
3
    
AP  3iˆ  2ˆj  2 3 kˆ  AP  5  AG  4 . Now AG and AO are collinear
    
 AG   AO  AG    AO   = 2  G  î  2  ˆj  3 î 
12

 G = î  2ˆj  2 3 kˆ or î  2ˆj  2 3 kˆ
44. A, B, C, D
Sol. Since, 1  sin2x  1  sin 2x  2  x  [0, 2]
  3 
Now, if cos x  0  2 cos x  1  sin2x  1  sin 2x  x   , 
2 2 
2
If cos x > 0, then 4 cos x  1 + sin 2x + 1 – sin 2x – 2 1  sin2 2x  cos 2x  0
  3   5  7    7 
x ,   ,   x ,  so, x = 1, 2, 3, 4
4 4   4 4  4 4 
Y
45. B, C
 1
EM
2
Sol. 4sec A
x 2  2x   B2  B    0 have real roots
 2
2  1 2 1 1
 D  0  4sec A  B 2  B    1 but 4sec A  4, B2  B  
 2 2 4
AD
2 1 1
 Equation will satisfy when 4sec A  4 and B2  B  
2 4
2
 1 1
 sec A = 1 and  B    0  cos2 A = 1 and B 
2

1
2
 
 A = n and B   cos A  cos 1 B   1 ;  1
2 AC
2 3 3
IIT
46. A, C  
  
Sol. Let p and q be the pv of P and Q r  a  
      
Let p  a  t1 ; q  b  s1 P A a
     
A

 p  q  a  b  t1  s1
 

B b
AN
Taking dot product of this equation with  and  , we have Q   

       r  b  
 
O  a  b    t1       s1    and  
        
     
O  a  b    t1     s1    solving for t1 and t2, we get p and q
AY
47. A, C
Sol. Since, x3 + ax + b = 0 ; x 3 + cx2 + d = 0 have complex root so it appears in conjugate pairs
AR
Let z  m  n i ; z  m  n i ; So z  z  2m ; zz  m2  n
For the equation x3 + ax + bn = 0  –20 + z + z = 0 ; z  z  20  m = 10
and for equation x3 + cx2 + d = 0  –21z – 21z + zz  0  n = 320
N
48. C, D
Sol. Clearly f(x) is not define at x = 1 if a < 0 and if a > 0, then all the conditions of Rolle’s theorem
holds on f(x)
Section – B
49. 1
Sol. Since, g(0) = 0 and f(g(x)) = x
5 2 4

 g  x   3 f   g  x     f   g  x      f   g  x     f   g  x    g(0) = 1
13
50. 13
Area of ADC C
Sol. E, F exist if and only if 2
Area of ADB
Since, AD is the angle bisector, and the ratio of area of triangles with F
equal height is the ratio of their bases E D
AC DC Area ADC
   2  AC = 2AB
AB DB Area ADB
Let BC = d so, by triangle inequality d + 7 > 14 ; 7 + 14 > d A B
7
 7 < d < 21
So, there are 13 possible integral values of BC
Y
51. 5
1 1 1
 
1 p   1  3  1 3  1 3 
EM
Sol. Put t   lim t   1    1  2  
x t 0  t  t  t 
 
1
p   1 1
 1
t t2 1
t t2
 lim t 3
 1  t  3  1  t  3  2
 use expansion  1  t  3  1  ;  1  t  3  1 
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t 0
  3 9 3 9
1 1 5
p 
3
 2t 2  2 p  2  3 2 p 5
 lim t     t    t 3 so, p   3p = 5
t 0
 9  9 9 3
Section – C AC
52. 04.00
IIT
53. 06.00
Sol. (for Q. 52 to 53):
f(x + 2y) = f(x) + f(2y) + ex + 2y (x + 2y) – x ex – 2y e2y + 4xy
Replace x, y = 0  f(0) = 0
A
Put 2y = –x, we have f(0) = f(x) + f(–x) – xex + xe–x – 2x2

f  x  h  f  x 
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 –f(x) = f(–x) – x ex + xe–x – 2x2. Now, f(x) = lim

h 0 h
x x 2
f  x  h   f  x   xe  xe  2x
= lim
h 0 h
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f  h   ehh   x  h  e x h  xe x  2  x  h  x  xe x  xe x  2x 2

= lim
h 0 h
h x h
f  h   e h  xe e  2hx  xe x
 f  h   f  0    eh h  e x  1  xe x  eh  1  2hx
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lim = lim
h 0 h h 0 h
2 x 2
 f  x   x  xe  f  2   4  2e
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54. 84.00
55. 25.00
Sol. (for Q. 54 to 55):
Let P1(u, v) be any point of C1 and P2(x, y) be the C1
corresponding point on C2
Since, P1P2 (line joining) is perpendicular to y = 2x so, y = 2x
1 P1 (u, v)
C2
its slope = 
2
yv 1 P2(x, y)
 ….. (1)
2x  u 2
14
and midpoint of P1P2 lies on y = 2x

yv  x u
 2  ….. (2)
2  2 
Solving equation (1) and (2), we get 12x2 – 7xy – 12y2 + 25 = 0
56. 401.00
57. 10.00
Sol. (for Q. 56 to 57):
f(2 + x) = f(2 – x)  f(4 – x) = f(x) ..... (1)
From f(7 + x) = f(7 – x)  f(14 – x) = f(x) ..... (2)
From equation (1) and (2), we get f(x + 10) = f(x) so period is 10
Y
Now, replacing x by x + 10 and then x – 10 is equation (3) continuity in this ways
f(x + 10n) = f(x) ..... (4)
EM
for n = 1, 2, 3 .....
Since, f(0) = 0 equation (4)
f(10) = f(20) ..... = f(1000) = 0. so total 201
Now, x = 0, in equation (1) f(x) = f(0) = 0 from equation (1), we have 200 more roots
AD
AC
IIT
A
AN
AY
AR
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JEE (Advanced)-2023
FULL TEST – X
PAPER –2
ASSIGNMENT - 13
Y
Time Allotted: 3 Hours Maximum Marks: 180
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General Instructions:
 The test consists of total 57 questions.
 Each subject (PCM) has 19 questions.
 This question paper contains Three Parts.
AD
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-B & Section-C.
Section – A (01 –06, 20 – 25, 39 – 44): This section contains EIGHTEEN (18) questions. Each question has
AC
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – A (07 –10, 26 – 29, 45 – 48): This section contains SIX (06) paragraphs. Based on each
paragraph, there are TWO (02) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE
of these four options is the correct answer.
Section – B (11 – 13, 30 – 32, 49 – 51): This section contains NINE (09) questions. The answer to each
IIT
question is a NON-NEGATIVE INTEGER.

Section – C (14 – 19, 33 – 38, 52 – 57): This section contains NINE (09) question stems. There are TWO
(02) questions corresponding to each question stem. The answer to each question is a NUMERICAL
VALUE. If the numerical value has more than two decimal places, truncate/round-off the value to TWO
A
decimal places.
AN
MARKING SCHEME
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
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Full Marks : +4 If only (all) the correct option(s) is (are) chosen;

Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both of which
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are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
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Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Section – C: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Physics PART – I

1. Select correct alternatives if both plates of parallel plate Q 2Q B R A

capacitor are given positive charges Q and 2Q as shown in
the figure and at t = 0, switch S is closed : C
Y
S
EM
(A) current in resistance ‘R’ will flow from A to B
(B) electric field intensity between the plates of capacitor will decrease continuously
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Q  t /RC
(C) current in the circuit at time t is e
2RC
(D)
AC
total heat dissipated in the circuit after having switch S closed is
Q2
4C
2. In a setup of displacement method experiment, the distance between the screen and a light
IIT
source is 120 cm and the lens used has a small aperture. By moving the lens between the source
and the screen, sharp images are obtained on the screen for two different positions of the lens.
The ratio of sizes of these two images is 9 : 1. Then choose the correct option(s).
(A) The focal length of the lens is 22.5 cm
A
(B) The focal length of the lens is 45 cm

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(C) The separation between the two different positions of the lens is 30 cm
(D) The separation between the two different positions of the lens is 60 cm
3. In the figure, a block rests on the top of a smooth fixed hemispherical tube of radius R in which it
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can just fit. Two springs are connected to the base as shown. The block is given a small jerk so
that it can slide on the hemisphere. The F-X (F is magnitude of force and X is compression) graph
for the springs is given below. Which of the following may be possible?
F
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Spring 2
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Spring 1
Spring 1 Spring 2
X
(A) The block will compress both springs by same amount.
(B) The block will compress the springs during its to and fro motion about its original position
by different amounts.
(C) The block will perform to and fro motion along the hemispherical surface about the
original position.
(D) The block can never come to the original position.
4. An ideal gas can be expanded from an initial state to a certain volume through two different
2 2
processes (i) PV = constant and (ii) P = KV where K is a positive constant. Then
(A) final temperature in (i) will be greater than that in (ii)
(B) final temperature in (ii) will be greater than that in (i)
(C) total heat given to the gas in case (i) is greater than that in (ii)
(D) total heat given to the gas in case (ii) is greater than that in (i)
5. A particle of m = 1 kg is moved in a circle of radius R = 1m on a rough horizontal surface with

coefficient of friction  = 0.1, with a constant speed of 1 m/s by an external force of constant
magnitude. The magnitude of the external force is (Take g = 10 m/s2)
(A) 2N
(B) 2 2N
Y
(C) 3N
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(D) 2 3N
6. A block A of mass 5 kg rests over F1

another block B of mass 3 kg A 5 kg A 5 kg
AD
which is placed on a smooth F2
horizont al surf ace. T here i s B 3 kg B 3 kg
friction between block A and
block B. A horizontal force F 1
AC
gradually increasing from zero to a maximum value is applied to A so that the blocks move
together without relative motion. Instead of this, another horizontal force F2, gradually increasing
from zero to a maximum value is applied to B so that the blocks move together without relative
motion. Then
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(A) F1 (max) = F2 (max)

(B) F1 (max) > F2 (max)
(C) F1 (max) < F2 (max)
(D) F1 (max) : F2 (max) = 5 : 3
A

AN
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
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Paragraph for Question Nos. 07 and 08
A source emits sound waves of frequency 1000 Hz. The source moves to right with a speed of 32 m/s
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relative to ground. On the right there is a reflecting surface which moves to left with a speed of 64 m/s
relative to ground. The speed of sound in air is 332 m/s.
7. The wavelength of sound in air emitted by the source is

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(A) 0.4 m
(B) 0.22 m
(C) 0.6 m
(D) 0.33 m
8. The number of waves which meet the reflecting surface per second is
(A) 1440
(B) 1280
(C) 1320
(D) 1600
In the figure shown, when a horizontal force F is 

applied to the larger block A, all the four blocks move /3
m m
together. There is no slipping between any two
blocks. (Take m = 1 kg, M = 2 kg,  = 0.3 and g = M M F
2
10 m/s ) B A
=0
9. The maximum value of the applied horizontal force F is

(A) 1N
Y
(B) 2N
(C) 3N
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(D) 4N
10. In the above case, the friction force between the front blocks is
(A) 1N
AD
(B) 2N
(C) 3N
(D) 4N
AC
INTEGER.
IIT
11. A solid cylinder of mass M radius R is resting on a horizontal platform (which is parallel to x-y
plane) with its axis along the y-axis. The platform is given a motion in X-direction given by X = A
cos t. There is sufficient friction present in the surface of contact that can prevent the slipping
between the cylinder and the platform. The maximum torque (in N-m) acting on the cylinder
A
during its motion is (Take M = 6kg, R = 1m, A = 2m,  = 1 rad/s)

AN
12. Two blocks of masses m1 = 2 kg and m2 = 4 kg are

connected by an ideal non-deformed spring of stiffness k F1 k F2
= 150 N/m and placed on a smooth horizontal surface. m1 m2
Two horizontal forces F1 = 9 N and F2 = 27 N are applied
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on the blocks in the opposite directions as shown in the smooth surface

figure. Find the maximum elongation (in cm) produced in
the spring.
AR
13. A solid sphere of mass m and radius r is in pure rolling y

motion on a rough horizontal surface with linear speed v. The
force exerted by the right half of section yy on the left half of
N
Km v 2
section yy is newton. Find K.  V
16r
y


Question Stem
When an -particle with kinetic energy K = 11 MeV collides with a stationary lithium nucleus, the following
nuclear reaction takes place
4
He 7 Li 10 B  n
The Q-value of this reaction is E = 2.86 Mev. If the kinetic energy of the neutron outgoing at right angle
Y
to the incoming direction of -particle is X MeV and the kinetic energy of boron atom is Y MeV.
EM
AD
Question Stem
Magnitude of acceleration of block B is

Ma
4
AC
In figure shown block A starts moving with acceleration a.
and
B
P
a
A
Ka
magnitude of acceleration of point P of string is .
IIT
2
=0
16. The value of M is………………

A
17. The value of K is……………….

AN

Question Stem
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Two tunnels are dug across the earth as shown in the figure. Two T1
particles P1 and P2 are oscillating form one end to the other end of
the tunnels T1 and T2 respectively. At some instant, particles are
getting at the mid points of the tunnels as shown in the figure.
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Phase difference between the particles P1 and P2 is X and the

ratio of maximum velocities of particles P1 and P2 is Y.
P1 T2
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v2
v1 60
P2


20. A non-reacting dry gas, (say N2 ) is bubbled through some liquids separately and samples of
emergent gas are collected at the same temperature and pressure. If definite volume of the
emergent gas weighs more than the same volume of dry gas under identical conditions of
temperature and pressure, the liquid(s) may be
(A) Heavy water  D2 O 
Y
(B) Methanol
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(C) Acetone
(D) 1 : 1 molar mixture of H2 O and D2 O
21. HO
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O 2N N2  
AC
pH X
The incorrect statement (s) is/are

IIT
(A) ‘X’ should be greater than 7 so that phenolic group  OH convert into O and it
activate the aromatic ring towards electrophilic aromatic substitution
(B) ‘X’ should be less than 7 so that more positive charge present on N2 and electrophilic
A
power of electrophile increases in the reaction

AN
(C) The above reaction is an example of electrophilic aromatic substitution

(D) If medium is basic in above reaction then product is
HO
AY
O 2N N N
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22. Select the correct statement(s) of the following:

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(A) If the critical micelle concentration of a soap is 10 3 M , then osmotic pressure of

1  10 4 M solution will be almost equal to that of 1  10 4 M NaCl solution
(B) When some oil soluble dye is added to water-in-oil emulsion, the background appears
coloured
(C) In cataphoresis of a sol formed by peptization of freshly obtained SnO2 by somewhat
excess of NaOH, the sol particles move towards anode
(D) Coagulating power of the following electrolytes in the sol obtained in option (C) will be in
the order Na3 PO4  MgSO 4  AlCl3
23. Which of the following statements is/are incorrect?

(A) Entropy of a system is a measure of available energy to do the useful work.
(B) In an irreversible process the entropy change between the two states is path dependent.
(C) Complete conversion of heat into work is possible in a reversible isothermal expansion of
ideal gas.
(D) Decrease in free energy of a system represents the unavailable energy for doing useful
work.
24. Which of the following statement is/are correct?

(A) CH3 CH2 CH2 OH  CH3 CH2  O  CH3  Boiling po int  .
(B) p-nitrophenol is stronger acid than o-nitrophenol.
(C) Phenol reacts with concentrated sulphuric acid and at low temperature major product is
Y
ortho sulfonated product.
(D) Boiling point of ortho-nitrophenol is less than para nitrophenol.
EM
25. Which of the following is/are alloy(s) containing copper?
(A) Brass
(B) Bellmetal
AD
(C) Nickeloy
(D) Magnalium

AC
answer.

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NaOH
O 'Y'

O
A
1 O
3
C10 H16 
 2 ZnH O

2
AN
 X H N2 H4
' Z '  C10 H16 N2 

Considering the above sequence of reactions
AY
26. Which of the following option is true about the structures of X and Y respectively?
(A) CHO
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;
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(B) CHO
(C) CHO
;
(D) CHO
27. Which of the following is the most likely structure of ‘Z’?

(A) N
N
(B) N N
Y
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(C) N
N
AD
(D)
N
N AC
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Sulphur excess of HCl

Philosopher ' s wool  X  
 White substance P    R   S 
Foul smell gas   Solution
A
+
Gas Q Aq. NaOH
AN
 T  white ppt.
 T  is so lub le in excess of NaOH
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Considering the above sequence of reactions, answer the following.
28. Select the incorrect statement:

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(A) Metal present in white substance (P) produces amphoteric oxide.

(B) ‘X’ is yellow powder which on heating becomes white and again on cooling becomes
yellow.
(C) Mixture of  P   BaSO4 is called lithopone
N
(D) ‘X’ on heating with cobalt nitrate gives Rinmann’s Green.
29. Which of the following is not true characteristics of gas (R)

(A) It produces black precipitate, when passed through AgNO3 solution.
(B) It decolourises acidic solution of KMnO 4 .
(C) It produces black precipitate, when passed through  CH3 COO 2 Pb solution.
(D) It produces white precipitate, when passed through  CH3 COO 2 Cd solution.

INTEGER.
30. If the total number of compounds among the following, in which the difference in oxidation state of
two atoms of same element (other than oxygen and hydrogen) is greater than 2 is ‘P’ and
If the total number of compounds among following, in which oxidation state of two atoms of same
element is same (other than oxygen and hydrogen) is ‘Q’. Then what is the value of ‘P’ × ‘Q’.
Cr2 O72 ; NH4 NO2 ; NH4 NO3 ; Hydrazine; Calcium cyanamide; Urea; S2 O32 ; S4 O62 ; H2 S2 O5
31. 3 mole of a mixture, having equal moles each of

AgNO3 ; NaNO3 ; NH4NO3 ; LiNO3 ; Ca NO3  2 ; KNO3 are heated strongly. What is total weight in
Y
gram of NO2  g evolved?
EM
32. How many of the following compounds undergo only decarboxylation simply on heating?
O O
O
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COOH
OH ; H C ; H2C CH CH2 C OH ;
2
COOH
COOH
COOH
;
H2C
H2C
COOH
COOH
; H2C
AC
CH2 COOH
;
CH2 COOH
O
IIT
O COOH
; ;
H3C C CH2 COOH
A
HOOC
AN

AY
AR

Question Stem
N
A 2 litre flask containing a gas X2 at a pressure of 1 atm is connected through a very narrow tube with a
stop cock to another 3 litre flask containing a gas Y2 at a pressure of 2 atm, the two flasks being at the
same temperature. On opening the stopcock the two gases mix and react according to the following
equation
X 2  g   Y2  g  2XY  g
At equilibrium the gaseous product XY has a partial pressure of 0.6 atm. (Assume negligible volume of
the thin tube and no change in temperature of the flasks). Calculate the
33. Partial pressure of X2 (in atm) at equilibrium………

10
34. Equilibrium constant K C of the reaction………

Question Stem
2.0 litre of 0.05 M KCN and 3.0 L of 0.05 M M  CN2 are mixed together at certain temperature T Kelvin,
M being a strongly electropositive element. If ionization constant of CN is 2.0  10 4 and H  in pure
water is 2.0  107 M at T Kelvin; If X  104 is hydrolysis constant of CN ion and “Y” is pH of the
resulting solution. Then,
35. What is the value of X?
Y
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36. What is the value of Y?

Question Stem
AD
When NO and NO2 are mixed together, following equilibria were established in a closed vessel.
2NO2  N2 O4 K P1  6.8 atm 1
NO2  NO  N2 O3 K P2  ' X '
AC
In an experiment , when NO and NO2 are mixed in molar ratio of 1 : 2, final pressure was found to be
5.05 atm. When the partial pressure of N2 O4 (at equilibrium) was 1.7 atm.
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37. Calculate the equilibrium pressure of NO (in atm)?
38. What is the value of K P2  X  ?

A
AN
AY
AR
N
11

39. Let A = {1, 2, 3, ….., 36}. Let B, C, D be set of all 1  1, 2  2, 3  3 matrices that can be formed
using elements of A. If |a| represents determinant of matrix ‘a’, then
(A)  a  666
aB
(B) a  6662
Y
aC
(C) a  6663
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aD
(D) a a
aC aD
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x2 y2
40. Let E :   1 . Let C be a circle concentric with E and inscribed in E and S be locus of foot of
a2 b2
perpendicular from foci of E to any tangent to E. If S is also locus of a point P such that chord of
contact of tangents drawn from P to C subtends right angle at origin, then which of the following
are true?
(A) Eccentricity of E is less than
1
AC
2
(B) Maximum distance between C and S is less than 2 times the radius of C
IIT
2
(C) Maximum distance between C and E is greater than times the radius of C
7
(D) S doesn’t exist
A
2022
r 2022 2022
AN
41. Let S(k) = 2022 – k and P    1

r 0
Cr S k   , then
(A) if k = 0, P is divisible by 4348

(B) if k = 0, P is divisible by 4743
if k = r, P is divisible by 4348
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(C)
(D) if k = r, P is divisible by 4743
42. Let there be a column of square cross-section having side length 2 units and of infinite length
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centred on z-axis. Let P be a random point lying in the section cut off by the plane x + 2y + 2z =
30 in the column. Q is reflection of P in the plane z = 15 and R is locus of point Q, then
(A) area of R is 6 square units
12
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(B) area of R is square units

5
(C) R lies in x + 2y – 2z + 30 = 0
(D) R lies in x – 2y – 2z + 30 = 0
12
1  1
43. Let solutions of the equation z8  i be represented by ai : i = 1, 2, ….., 8 on Argand

2 2

plane such that Arg(ai) < Arg(aj)  i, j (Arg(a)  [0, 2)) (where Arg(a) represents argument of a ),
then
8 8  
(A)  ai  a j  0
i 1 j1
 
(B)  a  a
1 i  j 8
i j 
  44 2 
8 8  
(C)   a  a   0
i  j j1
i j
 
  a  a   4  4
Y
(D) i j 2
1 i  j 8
EM
44. A person walks at a uniform speed of 1 unit/min for a distance of 1 unit. He then turns right and
3
covers of the distance he walked before turning and continues doing this. Let P(t) represent
4
AD
the distance between the persons' current position and starting point  t  0
(A) P(t) is a continuous function  t
(B) P(t) is a differentiable function  t
4
(C) limP  t  
t  5
16
AC
(D) limP  t  
t  25
IIT

A
answer.
AN
r 
Let p, q be selected from a set of first 20 natural numbers. Let A   : r, s  1, 2, ....., 20 
s
AY
p
45. If probability of being a natural number greater than 1 is k, then 10000k equals
q
AR
(A) 67
(B) 66
(C) 48
N
(D) 46
u
46. If a random element of set A is selected, then probability that it is an integer is equal to (where
v
u, v are co-prime integers), then u + v is equals
(A) 55
(B) 275
(C) 301
(D) 321
13
x2
Let there be two particles of same mass inside an elliptical container placed along  y2  1 . Initially,
2
both particles are at (1, 0). At t = 0, first particles (P1) starts moving towards negative x-axis and second

particle (P2) starts moving along a line at an angle of from positive x-axis, both having speed of
3
2 units/s. The particles can collide with container and with each other, all collisions being perfectly
elastic. Let f(t) be a function of distance between the two particles at any time t. Let g(t) and h(t) be
function of distance of P1 and P2 respectively from (1, 0) at any time t
47. Let a, b, c be number of solutions of the equation f(t) = 0, g(t) = 0 and h(t) = 0 respectively
Y
 t  (0, 100], then
EM
(A) a + b = 3c
(B) a + c = 4b
(C) b + c = 3a
(D) a + b = 2c
AD
48. Which of the following are periodic functions?
(A) f(t)
(B) g(t)
(C)
(D)
h(t)
none of these AC
IIT
INTEGER.
49. If in scalene ABC, 2c sin(A – B) cos(A + B) = (b sin B – a sin A) (where all symbols have their
usual meanings), then [5 sin C] equals (where [.] represents greatest integer function)
A
50. Number of distinct quadratic equations with real roots such that the equation remains unchanged
AN
if their roots are cubed equals
x 2 y 2  2xy 2  2y 2  4xy  4y  4
51. If the minimum value of the expression is ‘k’  x, y,  R+, then
AY
xy 2  2y
[10k] equals (where [.] represents greatest integer function)
AR

N

Question Stem
 4
x 1 ln xdx
Let I1   dx and I2  
0
x
 x
e  1 ln e  1  0 4x  x 2
52. The value of I1 equals
53. The value of I2 equals

14

Question Stem
Let z1, z2, z3 be three complex numbers such that z1 + z2 + z3 = i, z1z2 + z2z3 + z1z3 = –1, z1z2z3 = -i
Let maximum value of |z1 – kz2 + (k – 1)z3|  k  [0, 1] equals ‘a’ and minimum value of
|z – z1|2 + |z – z2|2 + |z – z3|2  z is ‘b’ (where i  1 )
54. The value of ‘a’ is
55. The value of ‘b’ is
Y
Question Stem
EM
Let L1, L2, L3 be three straight lines such that no two of them are parallel. Let C1, C2, C3, C4 be circles
touching all the three lines such that radius of C1 is smallest. Let P be point of concurrence of the altitudes
of the triangle formed by centres of C2, C3 and C4. If L1, L2, L3 intersect each other at points A, B and C

such that AB = 3, BC = 4 and ABC  . Let m = min{PA, PB, PC} ; n = max{PA, PB, PC}
AD
2
56. The value of m equals
57. The value of n equals AC

IIT
A
AN
AY
AR
N
JEE (Advanced)-2023
FULL TEST – X
PAPER –2
ASSIGNMENT - 13
Y
EM
ANSWERS, HINTS & SOLUTIONS
AD
Physics PART – I
Section – A
1. B, C
AC
Q  t /RC 3Q/2 3Q/2 B R A
Sol. Q t 
2
e   C
IIT
Q  t /RC –Q/2 +Q/2

lt  e (from B to A)
2RC
2
Q / 2  Q2
A
Total heat dissipated  =

2C 8C
AN
2. A, D
2
Dx 9
Sol.   
D  x 1
AY
 
Dx
3
Dx
D  x  3D  3x
AR
4x = 2D
D 120
x   60 cm
2 2
N
x = 60 cm
D2  x 2 (120  120)  (60  60)
Now, f  
4D 4  120
f = 22.5 cm
3. B, C
Sol. The two springs have different spring constants. Also energy remains conserved during the
motion as no friction is present.
4. B, D
Sol. From equation, PV = nRT 2 B P = KV
2
PC < PB, VC = VB and TB > TC PV = C

W AB > W AC; (TB – TA) > (TC – TA) P
st
So, by 1 law, Q = U + W
QAB > QAC.
A C
VC VS
V
Y
5. A
Sol. Fcos   mg
EM
mv 2 F v
F sin   
R
2
 mv 2 
AD
2 mg
F  mg  
 R 
F  2 N.
6.
Sol.
B, D
Case I:
AC
Since there is no relative motion,
F F F 8
IIT
a  1 f  f  F1 max   Ff
5 3 3
Case II:
F F  Ff 8
a f  2  F2 max   Ff
A
5 3 5
F1max  5
AN
Clearly, F1(max  F2max  and  .

F2 max  3
7. D
AY
v 332
Sol.    0.332m.
n 1000
8. C
AR
Sol. The apparent frequency for reflecting surface as observer is

 332  64 
n  1000    1320 Hz
 332  32 
N
9. C
10. B
Sol. (for Q. 9 to 10):
The maximum acceleration with which the blocks can move together without slipping
mg 0.3  1 10 2
amax    0.5 m/s
3M 32
Fmax  2(M  m)amax  6  0.5  3 N
The friction force between the front blocks,
FS = (M + 2m) amax = 4  0.5 = 2 N
Section – B
11. 4
2
Sol. a + R = A cos t …(i)
f = ma …(ii)

1
fR = mR2  …(iii)
2 a
f + 2f = mA2 cos t
1
f  mA2 cos t f
3
1 1
(max)  mA2R   6  2  1  4 N-m
3 3
Y
EM
12. 20
2  m1F2  m2F1  2  2  27  4  9  2 90
Sol.  max      150  6  0.20 m  20 cm
k  m1  m2  150  24 
AD
13. 3
 m  3r 3mv 2 F
Sol. F    2 =
2 8 16r
AC
IIT
Section – C
A
14. 03.40
AN
15. 04.74
Sol. (for Q. 14 to 15): y
Using conservation of momentum
AY
P = P2 cos  …(i) P1
P1 = P2 sin  …(ii) P
Squaring and adding, we get  x
P2  P12  P22
AR
2mk + 2m1k1 = 2m2K2 P2

4k + k1 = 10k2
10k2  k1 = 4k
N
 10k2  k1 = 44. …(iii)

Also, k1 + k2 = k  |Q|
k1 + k2 = 11.  2.86
k1 + k2 = 8.14 …(iv)
Adding (iii) and (iv), we get
11k2 = 52.14
 k2 = 4.74 MeV
 k1 = 8.14  4.74
k1 = 3.40 MeV
16. 03.00
17. 01.00
Sol. (for Q. 16 to 17):
3a
4TaB  3TaA = 0  aB  M=3
4
3a a
2TaB  TaA  TaP = 0  aP  2aB  aA  a 
2 2
a
aP  K=1
2
18. 180.00
Y
19. 02.00
EM
Sol. (for Q. 18 to 19):
At the instant shown both particles are at their mean positions and moving in opposite direction.
Phase difference = 180
As  is same for both the particles
AD
 GM 
   the phase difference will be maintained throughout and they can never meet.
 R3 
So,
vmax  A
v1

R

v2 R / 2 1
2
AC
 For a particle undergoing S.H.M
IIT
A
AN
AY
AR
N
Section – A
20. B, C
Sol. The V.D. and molar mass of the emergent gas will always be greater than that of pure gas.
  
In case of CH3 OH molar mass 32 g mol1 and acetone (molar mass 58 g mol1 )
 Molar mass of N2 being 28 g mol1
 Molar mass of H2 O being 18 g mol1 .
Molar mass of D2 O being 20 g mol1 .
Y

EM
21. B
Sol. HO
HO
AD
NaOH
O 2N N2  
Fa int ly basic medium
 O 2N N N
AC
22. A, B, C
Sol. (A) Below critical micelle concentration soap behaves like normal electrolyte; no micillisation
IIT
of the anions.
(B) In water-in-oil emulsion, oil forms external (continuous) phase.
(C) SnO2  2NaOH  Na2 SnO3  H2 O
A
(D) Cations will be effective in coagulation of negatively charged sol formed in option (C).
AN
23. A, B, D
Sol. 1. S(entropy) is not the measure of available energy.
2. S between the two states is not path dependent whether reversible or irreversible
S  S2  S1 .
AY
3. Heat supplied into the isothermal reversible expansion of ideal gas is equal to work of
expansion of the gas.
4. G is equal to the available energy of the system to do useful work.
AR
24. A, B, C, D
Sol. 1. Ethers have much lower boiling point than alcohol of similar molecular mass, alcohols
undergo molecular association through intermolecular hydrogen bonding.
N
2. Intramolecular hydrogen bonding makes ortho-isomer weaker acid than para-isomer.

3.  
At lower temperature 20o C , the reaction between phenol and conc. H2 SO 4 is
kinetically controlled and product composition depends on relative rate of formation.
4. Owing to intramolecular H-bonding in ortho-nitrophenol, its boiling point is less than that
of p-nitrophenol (molecular association due to inter molecular H-bonding).
25. A, B, C
Sol. Brass – Cu + Zn
Bell metal – Cu + Sn
Nickeloy – Al + Cu + Ni
Magnalium – Al + Mg + Ni
26. D
27. B
O
 3
1 O

 2 Zn H O 
2
CHO
X
OH N2 H4 / 
Y
O
O O N N
,
EM
CHO ,
CHO CHO
E 
F  G  Z
Possible enolates  Cyclic hydrazene 
AD
CHO
Aldol
 E  

O
AC
Aldol
F  

IIT
OH
O
A
Aldol
 G  

AN
28. B
29. D
AY

Sulphur excess of HCl
ZnO  X  
 ZnS  P    H2 S R   ZnCl2  S 
Philosopher 's wool  White substance  Foul smell gas  Solution 
AR

SO2  Q  Aq. NaOH
Zn  OH2  T 
N
 white ppt.
Excess of NaOH
Na2 ZnO 2
Sol. 28. (A) ZnO – is an amphoteric oxide.
(B) ZnO is white powder which on heating turns yellow but again on cooling becomes white.
(C) Lithopone is mixture of ZnS  BaSO4
(D) ZnO  CoO  CoZnO2 or CoO.ZnO

Rinmann's green
Sol. 29. 3

AgNO
 Ag2 S 
Black 
KMnO 4  Acidic 
H2 S   K 2 SO 4  MnSO 4  S  H2 O
3  CH
2
COO  Pb
PbS 

Black 
3 CH
2
COO  Cd
 CdS 
 Yellow 
Section – B
30. 16
Sol. O O
 3   3   5   0   0   5 
Y
N H4 N O2 O S S S S O have difference of oxidation states
EM
O O greater than 2.
 Total compounds  4  P
2
S
 3   5 
N H4 N O3  6 
AD
O S O
O
AC
Hydrazine NH2 NH2   Both nitrogen have same oxidation state of  2  
Calcium cyanamide  CaNCN  Both nitrogen have same oxidation state of  3  

P
Urea NH2 CONH2   Both nitrogen have same oxidation state of  3  
IIT
Cr2 O72  both chromium have same oxidation state  6 

 
O O
A
HO S S OH
 5   3 
AN
O
 P  Q  4  4  16
31. 92
AY
Sol.  1
AgNO3   Ag  NO2  O2
2
 0.5 mole   0.5 mole 
AR
 1
2LiNO3   Li2 O  2NO2  O2
2
 0.5 mole   0.5 mole 
N
 1
Ca  NO3 2   CaO  2NO2  O2
2
 0.5 mole  0.5  2  1 mole 


NH4 NO3   N2 O  2H2 O 

5
2NaNO3 
 Na2 O  N2  O2  No NO2  g  evolved
2 
5 

2KNO3   K 2 O  N2  O2 
2 
 Total number of moles evolved 0.5  0.5  1  2 mole

Total weight  2  46  mol. mass of NO2   92 g
32. 6
Sol. O
O O
COOH
O
OH ; ;
H3C C CH2 COOH ;
HOOC
O
Y
  keto acid decarboxylates on simple heating
COOH
COOH
EM
; H2C
COOH
COOH
AD
Ge min al diacids also decarboxylates on heating
O
H2C CH CH2 C OH  ,   unsaturated acid decarboxylates simply on heating
H2C COOH
; H2C
CH2 COOH
;
AC
H2C COOH
CH2 COOH
IIT
1,, 4 and 1,, 5  diacid dehydrates on heating.
Section – C
A
33. 00.10
AN
34. 04.00
1 2
Partial pressure of X2 before reaction pX2   0.4 atm
AY
23
23
Partial pressure of Y2 before reaction pY2   1.2 atm
23
AR
0.6
Atm of X2  g  and Y2  g each reacted   0.3 atm
2
pX2  at equilibrium   0.4  0.3  0.1 atm
N
pY2  at equilibrium   1.2  0.3  0.9 atm

2
2
pXY  0.6 
Kp  KC    4.0
pX2  pY2 0.1  0.9
35. 02.00
36. 11.00
2.0  0.05  3.0   2  0.05 
CN  in the resulting solution 
  23
0.4
  0.08 M
5
K W  H  OH   2  10 7  2  107
 4.0  10 14 M2
CN  H2 O  HCN  OH K b  2  104 
14
KW 4  10
K a  of HCN    2  1010
Kb 2  104
KW 4  1014
‘X’ – Hydrolysis constant K H of CN   10
 2.0  104
Ka 2  10
Y
1
‘Y’ – pH = pK W  pK a  log C
EM
2
1
   log 4  10 14  log 2  10 10  log 0.08 
2 
1 3
 14  2log 2  10  log 2  log  2   102   
AD
2 
1
  24  3 log 2  2  3 log 2
2
37.
= 11
01.05
AC
38. 03.43
IIT
(3.42 – 3.43)
Let Po be initial partial pressure of NO.
2Po be initial partial pressure of NO2.
A
2NO2  N2 O 4 K P1  6.8 atm 1

AN
2Po  3.4  P 1.7

NO  NO 2  N2 O3
o o
P P 2P  3.4  P P
AY
1.7
K P  for 1st equilibrium  6.8  2
 2P o
 3.4  P 
AR
or, 2Po  3.4  P  0.5

or, 2Po  P  3.9 …. (1)
Also, total pressure (at equilibrium) PNO2  PN2 O4  PNO  PN2O3
N
5.05  0.5  1.7  Po  P  P

Po  2.85 atm
Now from Equation (1) 2Po  P  3.9
2  2.85  P  3.9  P  1.8 atm
 Equilibrium pressure of NO  Po  P  2.85  1.80 = 1.05 atm.
PN2O3 1.8
K P2    3.42 atm 1 .
PNO  PNO2  1.05  
0.5
10
Section – A
39. A, D
Sol.  a  666,  a   a  0
aB aC aD
40. A, B, C
2 2 2
Sol. C:x +y =b
S : x + y = a where a2 = 2b2
2 2 2
Y
41. A, B, C, D
EM
Sol. if k = 0  P = 0 and if k = r  P = 2022!
42. A, C
4
Sol. Area of R = 6
AD
2/3
2 2
Equation of R : x + 2y + (2 + )z – 30 – 15 = 0 where    = –4
3 2
  4  9
43.
 Equation of R: x + 2y – 2z + 30 = 0
A, C, D
AC
Sol. ai represent vertices of a regular octagon so
8 8    
IIT
 ai  a j  0 ;  ai  a j  4
i  j j1 1 i  j 8
8   8  
  ai  a j   0 ;  a  a i j 4  
2 1
A
i  j j1 1 i  j 8
AN
44. A, C
Sol. P(t) is clearly continuous  t but non-differentiable whenever the person turns
1 9 4
limP  t   1 
9
AY
t  16 5
1
16
45. D
AR
Sol. Make cases based on denominator
46. A
20
N
Sol. Probability is
255
47. B
Sol. a = 50, b = 25, c = 50
48. D
Sol. None of the functions are periodic as local extrema keeps on decreasing after every 4 seconds
11
Section – B
49. 4
Sol. 2c sin(A – B) cos(A + B) = b sin B – a sin A
 c[sin 2A – sin 2B] = b sin B – a sin A
 2 c sin A cos A + a sin A = b sin B + 2c sin B cos B
1 1
c cos A  a  b   c cosB
2 2 1 5 3
   cosC   5 sinC 
sinB sin A 2 2
50. 6
3 3 3
Sol. () =  and  +  =  +    = 0, 1, –1
Y
3
If  = 0  ( + ) =  +    =  = 0, 1 –1
2 2
Corresponding equation are x = 0 ; x  x = 0
EM
3
If  = 1  ( + ) = 4( + )   +  = 0, 2, –2
Corresponding equation are x2  2x + 1 = 0
3
If   = –1  ( + ) + 2( + ) = 0  +  = 0
Corresponding equation is x2 – 1 = 0
AD
51. 8
2
x 2 y 2  4  4xy  2y 2  2xy 2  4y  xy  2   2y 2  2y  xy  2  xy  2 2y
Sol. = =  2 2 2 2
xy 2  2y y  xy  2  y
Section – C
ACxy  2
52. 01.57
IIT
/ 2
2ln  sec y   1 1
 /2
 2lnsec y  1   2ln  cosec y   1
Sol. Let ex – 1 = tan2 y  I1   dy =  dy
0
ln  tan y  2 0 ln tan y
 /2
1 2ln tan y 
A
=  dy 
2 0 ln tan y 2
AN
53. 00.00
Sol. Let x = 2 + y  I2 
2
ln  2  y 
dy 
2

ln 4  y 2  dy
 2  2
AY
2 4y 0 4y
Also, let x = 4 – t2  I2  2
2

ln 4  t 2
 dt  I 2
 I2 = 0
0 4t 2 2
AR
54. 01.41
kz2  1  k  z 3
Sol. zi equals 1, -1, i ; a = min. of z1  = 2
k  1  k 
N
55. 02.67
i 8
Sol. z  b
3 3
56. 01.41
57. 03.16
Sol. (for Q. 56 to 57):
PA  5 ; PB  2 ; PC  10

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Narayana (Adv Level) - P1 & P2 Assignment - 13

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NARAYANA IIT ACADEMY

question is a NON-NEGATIVE INTEGER.

Full Marks : +4 If only (all) the correct option(s) is (are) chosen;

of which are correct;

1. A thin conducting circular disc of mass m, thickness d and radius R

pivoted in the same horizontal level and this assembly is

after nail B is removed.

3. Three alternating voltage sources V1 = 3 sin t volt, V2 = ~V

5sin(t + 1) volt and V3 = 5 sin(t  2) volt connected across 3

2 correspond) to 30 and 127 respectively). The peak current ~

4. Two identical capacitors A and B shown in the given circuit are

Section – A (Maximum Marks: 24)

5. Two containers A and B are connected by a conducting solid A B

7. Two vertical parallel rectangular glass plates are partially submerged in

(A) The water rises upto height h = 14 cm between the plates.

(D) The force of mutual attraction between the plates is 9.8 N.

8. In the figure A, B and C are three slits each of them individually

make four capacitors each of 2F. The plates are

12. In a certain region, uniform electric field E  E0 kˆ and magnetic z B0 E0

field B  B kˆ are present. At time t = 0, a particle of mass m and

charge q is given a velocity v  v 0 ˆj  v 0kˆ . Find the time (in sec)

13. A spring mass system is kept on a rough horizontal m=1kg

Section – C (Maximum Marks: 12)

Question Stem for Question Nos. 14 and 15

The value of K is ………..

Question Stem for Question Nos. 16 and 17

16. The value of X is………………

17. The value of Y is……………….

Question Stem for Question Nos. 18 and 19

19. The value of Y is ………..

20. The major product of the reaction is

with neighbouring unit in Beryl are:

22. Which of the following statements is incorrect?

Section – A (Maximum Marks: 24)

24. Consider the following cell:

The EMF of the cell at 298 K is 0.236 V

Pick out the correct options of the following:

(C) The solubility product of MX2 is 4.0  1012 M3

25. The correct statement(s) regarding cellulose is/are

27. Kjeldahl’s method cannot be used for estimation of nitrogen present in

Ice cube will sink in both containers A and B.

Section – B (Maximum Marks: 12)

30. What is the total number of correct statements in the following?

Enthalpy of vaporization of water = 2439 J/g

Section – C (Maximum Marks: 12)

Question Stem for Question Nos. 33 and 34

33. The value of ‘X’ is_______

34. The value of ‘Y’ is_______

Question Stem for Question Nos. 35 and 36

35. What is the value of Y(in Kelvin)?

36. What is the value of Y – X (in Kelvin)?

37. What is the value of ‘Z’?

Mathematics PART – III

(A) 12x2 – 24x + 26 – 26e–x

(B) 12x2 + 24x + 26 – 26e–x

(D) 12x2 – 24x – 26 – 26e–x

Section – A (Maximum Marks: 24)

Section – B (Maximum Marks: 12)