basic education Department: Basic Education REPUBLIC OF SOUTH AFRICA SENIOR CERTIFCETEERAO NATIONAL SENIOR C; MARKS: 150 TIME: 3 hours This question paper consists of 16 pages and 4 data sheets. Copyright reserved Please tum overDownloaded from Stanmorephysics.com 2 Physical Sciences? pBe/2028 sonse INSTRUCTIONS AND INFORMATION 1 Write your centre number and examination number in the appropriate spaces on the ANSWER BOOK. 2 ‘This question paper consists of NINE questions. Answer ALL the questions in the ANSWER BOOK 3. ‘Start EACH question on a NEW page in the ANSWER BOOK. 4 Number the answers correctly according to the numbering system used in this question paper. 5 Leave ONE line between two subquestions, ¢.g. between QUESTION 2.1 and QUESTION 2.2, 6 ‘You may use a non-programmable calculator. 7 ‘You may use appropriate mathematical instruments. 8 ‘Show ALL formulae and substitutions in ALL calculations. a Round off your FINAL numerical answers to a minimum of TWO decimal places. 40. Give brief motivations, discussions, etc. where required 14. You are advised to use the attached DATA SHEETS, 12. Write neatly and legibly. Copyright reserved a Please tum overDownloaded from Stanmorephysics.com Physical Sciences/2 DBE 2023 sons QUESTION 4; MULTIPLE-CHOICE QUESTIONS. Various options are provided as possible answers to the following questions. Each question has only.ONE correct answer. Choose the answer and write only the letter (A-D) next to the question numbers (1.1 to 1.10) in the ANSWER BOOK, eg. 1.11 E 1.1 For which ONE of the following molecular formulae are CHAIN isomers possible? A Gilt BCs © CHO D C3HsO (2) 1.2 Which ONE of the following compounds has the LOWEST vapour pressure under the same conditions? Th Tia A HOE EH B H—C—C—6 HHH 4 HOH OH HoH 4 aa it? CTE EPO [DoE H HH HO (2) 1.3 The type of organic compound formed when a haloalkane is heated in the presence of a concentrated strong base is an A alkane. a B alkene. a = C alkyne = D alcohol. @) Copyright reserved s Please turn overDownloaded from Stanmorephysics.com 4 Physical Sciences/2 sows 14 EXCESS HCt(aq) of concentration 0,1 mol-dm® reacts with 2g of Mg under different conditions, Which ONE-of the following combinations of conditions will produce the largest volume of Ha(g) in the FIRST MINUTE of the reaction? 7” STATE OF TEMPERATURE OF HC@(aq) DIVISION OF Mg (ec) A Powder 20 B Granules 2 c Powder 5 D Granules ia 50 1.5 The potential energy diagram for a chemical reaction is shown below. Potential energy (kJ) ‘Course of reaction Which ONE of the following combinations is CORRECT for the FORWARD reaction? POTENTIAL ENERGY OF aH er THE ACTIVATED COMPLEX A YX ZY z 8 ex zy ZY c X-¥ ZY z __ | D XY z ZY Conyright reserved Pease turnover DBE2023 (2)e 16 17 18 Copyright reserved ical Sciences/P2 wnloaded from Stanmorephysics.com 5 DBE 2023 sonise Consider the following reaction that reaches equilibrium in a beaker: 2C1O% (aq) + 2H*(aq) = Cr,0% (aq) + H20() A few drops of concentrated NaOH(aq) are now added to the beaker. Which ONE of the following combinations correctly identifies the DISTURBANCE ON THE SYSTEM and the SYSTEM'S RESPONSE to the disturbance? DISTURBANCE ‘ON THE | systems Response | [H'] decreases Forward reaction favoured IH'] decreases ~ | Reverse reaction favoured [CrO#)] decreases Reverse reaction favoured [Cr07] increases Fonward reaction favoured 2) According to the Lowry-Bronsted theory, a conjugate base is formed when alan ‘A proton is added to the acid. B electron is added to the acid C proton is removed from the acid. D__ electron is removed from the acid (2) Consider the statements below regarding an alkaline substance. An alkaline substance: (Reacts with an acid to form a neutral solution (i) Turns red litmus blue (iil) Forms a salt when it reacts with an acid ‘Which of the statements above are ALWAYS TRUE? A (i. Gi) and (ii) B (i) and (i) only (and (ii) only D Gil and (ii) only @) Please turn overPhysical Scienoos/P2 19 4.10 Downloaded from Stanmorephysics.com BE/2023 6 SCINSC Consider the celi notation for a galvanic cell. Pt | Ha(g) | OH™(aq) | H20() || Ag"(aa) | Aals) Which ONE of the following equati place at the positive electrode? ns represents the half-reaction taking A Ag'(aq) + & — Agis) B Agi(s) + Ag'(aq) + & C 2H,0(0) + 2e° — Hz(g) + 20H (aq) D Hag) + 2OH™ (aq) —+ 2H20() + 267 @ ‘A concentrated solution of sodium chloride, NaCtlaq), undergoes electrolysis. ‘Which ONE of the combinations correctly shows the products formed at each electrode? ‘CATHODE ‘ANODE, A Na Ch B He ori c Ch He and OH™ D H; and OH Ch 2) [20] Copyright reserved a Please turn overDownloaded from ‘Stanmorephysics. com (2) (1) @) @) i) Phraeel SoenceoP 2 pee2023 sense QUESTION 2 (Start on a new page.) ‘Study the table below and answer the questions that follow. pte 4 4 yeu fon | aa | i AU ! ii ot |B) H—C—¢G—c—o— oe —C—C—H | | | 1 HoH OH HoH H [o [Gunso ~ E | CxHyOz 21 Define the term unsaturated hydrocarbon. 22 Write down the: 224 Letter that represents an UNSATURATED hydrocarbon 22.2 IUPAC name of compound A 22.3 IUPAC name of the POSITIONAL isomer of compound B 224 IUPAC name of compound D- 225 Balanced equation, using MOLECULAR FORMULAE, for the complete combustion of compound A 2.3 The formula CsHyO represents two compounds that are functional isomers of each other. 23.1 Define the term functional isomer. 23.2 Write down the STRUCTURAL FORMULAE ofeach of these two FUNCTIONAL isomers. 24 A 2g sample of compound E contains 1,09gcarbon and 0,18 g hydrogen, The molecular mass of compound E is 88 g-mof'' Determine the molecular formula of compound E by means of a calculation. Copyright reserved Please tum over 3) (2) 4) (6) [25]Downloaded from Stanmorephysics.com Physical SciencesP2 8 pBe/2023 sense QUESTION 3 (Start on a new page.) Learners investigate the boiling points of the four organic compounds given below. ORGANIC COMPOUND MOLECULAR MASS (g-mol") Butanone 72 Butan-t-ol 74 ___ Propanoic acid 74 - ‘Zmethylpropan-1-ol 74 3.1. Define the term boiling point @) 3.2 Which compound, butan-1-ol or 2-methylpropan-t-cl, will have the higher boiling point? Fully explain the answer. (4) The curves P, G, R and $ below were obtained from the results of the investigation. X represents a specific temperature. g 2 2 & s a E & & Time (minute) 3.3. Which physical property is represented by temperature X? (1) 3.4 Which curve (P, Q, R or S) represents 3.4.1 Butanone ay 342 Propanoic acid ay 343 2-methylpropan-t-ol a 3.5 Give a reason for the answer to QUESTION 3.4.2. a) 11] Copyright reserved Ped Please turn overDownloaded from Stanmorephysics.com Physical SciencosP2 8 pae/2023 somsc QUESTION 4 (Start on a new page.) 44 The flow diagram below shows different organic reactions, P, Q and R are organic compounds. Alcohol P Reaction 3 Compound R (major product) Reaction 4 Reaction 2 Het Compound Q Bro| Reaction 1 1,2-dibromo-2-methylpropane Reaction 1 is an addition reaction, Write down: 44.1 The TYPE of addition reaction 4.1.2 ONE observable change which occurs in the container during the reaction 44.3 The STRUCTURAL FORMULA of compound Q Consider reaction 2. 4.1.4 Write down the IUPAC name of compound R. For reaction 3, write down 44.5 A balanced equation using STRUCTURAL FORMULAE for the organic compounds 4.1.6 The IUPAC name of alcohol P Reaction 4 is an elimination reaction. 4.1.7 Write down the TYPE of elimination reaction 42 Butan-1-l reacts with propanoic acid in the presence of a catalyst. Write down the: 4.2.1 TYPE of reaction that takes place 4.22 IUPAC name of the organic product formed Copyright reserved ae Please turn over ty a) @) 2) (6) (2) a a) (2) [18]Downloaded from Stanmorephysics.com Physical Sclences/P2 10 0BE/2023 sense QUESTION 5 (Start on a new page.) Consider the following decomposition reaction that takes place in a sealed 2. dm? container: 2NzOs(g) 4NOz(g) + O29) The graph below shows how the concentrations of N2Os(g) and NOz(g) change with time. Concentration-time graph 30 250) 209} Concentration (x 10% mol-dm*) 5.1 Refer to the graph above and give a reason why curve A represents the change in the concentration of NO2(a). a 5.2 Consider the statement below: The rate of decomposition of N2Os(g) is half the rate of formation of NO-(o). Is this statement TRUE or FALSE? Give a reason for the answer. @) Copyright reserved = Please turn over &Downloaded from Stanmorephysics.com Physical SciencesiP2 tt DBE2023 scmse 5.3 Calculate the: 5.3.1 Mass of NOz(g) present in the container at 400 s (4) 5.3.2 |” Average rate of production of O2(g) in moldm*-s" in 700 s (4) 5.4 The MaxwellBoltzmann distribution curve for the NzOs(q) initially present in the container is shown below. & 3 2 E 5 2 Kinetic energy The initial concentration of the N2O:(g) is now INCREASED. 5.4.1 Redraw the distribution curve above in the ANSWER BOOK and label this curve as P. ‘On the same set of axes, sketch the curve that will be obtained for the higher concentration of NzOs(g). Label this curve as Q. (2) 54.2 Will the rate of decomposition of N;Os(g) at the higher concentration be HIGHER THAN, LOWER THAN or EQUAL TO the original rate of decomposition? Explain the answer using the collision theory @) (16) Copyright reserves Fe Please turn overDownloaded from Stanmorephysics.com Physical Sciences/™2 12 DBE 2023 sense QUESTION 6 (Start on a new page.) ‘One mole of pure hydrogen iodide gas, HI(g). is sealed in a 1 dm° container at 721K. Equilibrium is reached aocording to the following balanced equation: 2HI(g) = Hag) + I2(9) Itis found that 0,11 moles of I2(g) are present at equilibrium. 64 State Le Chatelier's principle. (2) 6.2 Determine the number of moles of EACH of the following at equilibrium: 6.2.1 Hg) a) 62.2 HI(g) (1) 6.3 The equilibrium constant, Ke, at 721 K is 0,02. ‘The temperature of the container is now increased to 850 K. The equilibrium constant, K., at 850 K is 0,09. 6.3.1 Is the forward reaction EXOTHERMIC or ENDOTHERMIC? (ty 63.2 Fully explain the answer to QUESTION 6.3.1, @) 63.3 Calculate the mass of HI(g) present at the new equilibrium at 850 K. (8) (16) Copyright reserved Please turn overDownloaded from Shaeananephipsncs com Physical Sciences/P2 DBE/2023 sonise QUESTION 7 (Start on a new page.) 7.1 The conductivity of three acid solutions, A, B and C, as shown below is investigated at the same temperature. A | 0,1 moldm® H2S0.(aq) B | 0,1 mol-dm* HNO3(aq) C | 0,1 moldm? CHsCOOH(aq) The brightness of the bulb in the apparatus shown below is used as a measure of the conductivity of the solutions. ‘Carbon electrode ‘Acid The acid solutions are electrolytes. 7.1.1 Define the term electrolyte. 2) The brightness of the bulb for each of the solutions is compared 7.1.2 In which solution, A or B, will the bulb be brighter? Give a reason for the answer by referring to the types of acids. 2) 7.1.3 Inwhich solution, B or C, will the bulb be brighter? Give a reason for the answer by referring to the types of acids 2) Copyright reserved a Please turn overDownloaded from Stanmorephysics.com Physical Sciences/2 14 DBE /2023 sonse 7.2 A hydrochloric acid solution, HCt(aq), is standardised by trating it against 25cm? of a 0,04mol-:dm™ sodium carbonate solution NazCO(aq). At the endpoint, it is found that 19,5 cm’ of HCt(aq) has reacted, The balanced equation for the reaction is: Na;CO,(aq) + 2HCt(ag) + 2NaCt(aq) + COAg) + Hz0(t) 7.2.1 Caloulate the concentration of the HCt(aq) @) 7.2.2 Suppose a few drops of water were present in the burette before it was filled with the hydrochloric acid solution. How will the volume of the HCt solution needed to reach the endpoint be affected? Choose from GREATER THAN, SMALLER THAN or REMAINS. THE SAME. Give a reason for the answer. (2) A concentrated household product, ChemClean, contains ammonia as the main cleaning agent. To determine the amount of ammonia present in 1 dm* of ChemClean, the following procedure is followed: 20 cm? of ChemClean is added to a 250 cm’ flask, The flask is then filled to the 250 cm? mark with distilled water. oremcoa{ 1308 Distilled water 20 cm’. Concentrated 250 om® diluted ChemClean ‘ChemClean The diluted solution is titrated against the hydrochloric acid solution of the concentration as calculated in QUESTION 7.2.1 During the titration, 22 om® of the diluted ChemClean solution is neutralised by 18,7 om’ of the HCt solution, The balanced equation for the reaction is’ NHs(ag) + HCt(aq) — NH;(aq) + Ct-(aq) 7.2.3 Caloulate the mass of ammonia in 1 dm* of ChemClean. 7) 7.2.4 Will the pH of the solution at the end of the titration be GREATER THAN 7, EQUAL TO 7 or LESS THAN 77 ‘Write down the relevant equation as motivation for the answer. (3) 1 Copyright reserved s Ploase tum overDownloaded from Stanmorephysics. com Physica! Sciences P2 sete peeroza QUESTION 8 (Start on a new page.) Learners want to identify an unknown metal X using a standard half-cell, x| X*" They set up an electrochemical cell under standard conditions using two half-cells, as ‘shown in the diagram below. H2(9) Platinum The initial emf of this cell is 1,20 V. 8.1 State the standard conditions under which this cell functions. @) 82 State ONE function of component Y. Oy After the cell has operated for some time, it is found that the mass of electrode X has increased, 83 Identify X by means of a suitable calculation. 6) 84 Write down the oxidation half-reaction that takes place in this cell 2) Half-cell X| X?* is now replaced by an Au| Au®* half-cell, The initial emf of the cell is now 1,50 V. As the cell operates, the Au electrode increases in mass. 85 Arrange the oxidising agents, x’, Au* and H’, in order of increasing strength Fully explain the answer. (3) 14) Copyright reserved = Please turn overDownloaded from Stanmorephysics.com Pnysical SciencesP2 6 DBE 2023 sons QUESTION 9 (Start on a now page.) The simplified electrolytic cell below is used to electroplate a metal spring. Zinc nitrate, Zn(NOz),aa), is used as an electrolyte and R is an electrode Power supply ‘Metal spring Zn(NOs)2(aq) 9.1 Define the term electrolytic cell 2 9.2 Which electrode (R or METAL SPRING) is the ANODE? Give a reason for the answer. @) 9.3 Write down the: 9.3.1 Equation for the half-reaction occurring at the metal spring 2) 93.2 NAME or FORMULA of a suitable metal that can be used as electrode R O) 9.4 Explain the answer to QUESTION 9.3.2. (2) [9] TOTAL: 150 Copyright reserved aDownloaded from Stanmorephysics.com Physical SciencesiP2 1 sows DATA FOR PHYSICAL SCIENCES GRADE 12 PAPER 2 (CHEMISTRY) GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12 VRAESTEL 2 (CHEMIE) TABLE 1; PHYSICAL CONSTANTSI/TABEL 1: FISIESE KONSTANTES BE 023 NAME/NAAM SYMBOL/SIMBOOL VALUE/WAARDE Standesrddrak © pe 1,013 x 10° Pa Molaro eeseteh Sr Ven 22,4 dm°-mol* Standecrdfonporatur r 279K {aay op sutton e 6x10" Avogadro-kenstante Na 6.02 x 10" mot" TABLE 2: FORMULAE/TABEL 2: FORMULES pH = -log[H30"] Ky = [HsO°J}OH] = 1 x 10 atiby 298 K = Fh = Eig, Ele TES, = Ela | orlof Een = Etceten taase ~ Coats eS ~ Enso rescingsent Copyright reserved Please turn overJeno win) asi sos | zor tor | oot | 66 | 86 | us | 96 47 | ON) PW | 44] Sa) 4D | Ya | wo!) wy) ng! dN| A | ed so | v6 | c6 | ze | 16 Séb | elt 691 sgh SOL cob 6st nT} QA | wi | 4a | OH | Ag | aL ust | zsb po | ng | ws | wa! PN | Jd ost | | yee | tee panies jyBurdog te | oc | 69 | 89 | 29 | 99 | so | v9 | e9 | zo | 19 | 09 | 6S oz [oz [voz [toz |zer [ser |zer [oer [sar [var | Od 8 !8 2/4de)aLe/6H inv fad | 4 eu | M va ice |ze_ jie |oe (62 | ee | SL vk 82 44 901 OL | 96 eLnass Pd Sua 8) a 8 OL SOW s zw is sy sv ey aw 6S 6S $s es ag visyy IN 2/99 = e4 Z/UING 49 3 ve 8 2@ st ve ze sa ob (a) (Nt) oO Sh owh kth essewuooje emaneje/ epsopeueg Sseu! swWoye oxnejos opewosddy yooquys: “ tL, wenmneBau0nya/3 joqutg | 9D © | Ayanesau0nsa13 6% t seyobuscony TALNFTSIAIN sequinu s1Woyy o 6 8 £ 9 s SLNIWITI NVA 798VL IMFGONNId FId :€ 1IGVL SINAWS13 4O 37aVi D100Rd3d SHL °€ 31SVL ezowsaq ‘Oswos z zt s z 60 ZA/SOUBIOS [201SAedDownloaded from Stanmorephysics.com Physical SciencosiP2 3 BE /2023 sonsc TABLE 4A: STANDARD REDUCTION POTENTIALS TABEL 4A: STANDAARD-REDUKSIEPOTENSIALE Half-reactions/Halfreaksies | € Figeae =F oe] Core = cot | tas LO+2H's2e HO | +177 MnO, 8H" +50 Mn eat | +181 Ctxg) +26 = ace +136 & — [cnoF sree = ace +70 | +439 owraitete . 240 ota] 4 MoOe+4H" +20 2 Mn+ 2H | +123 3 g Pevsze 2m | 3430 3 2 Bal) +2e 28° | et0r é vo; saree 2 wep eano | case 3 Hg" +20 = Hal | +065 3 3 Ate = Ag 0,80 3 s NOS +2H' re = Noug)+HHO | +080 5 § Fete a Fe +077 s g Orig) #24" +20 HDs +068 § sa +054 £ = cu +082 o = S#2H,0 +045 3 2 tow | 040 5 tte > Gu | +036 é : so? +aw'sze - soxp-2no] son] — & é cise OF coe] 8 5 Sit s20 2S | tons a 4 S+2i's2e = H4:8Q) | +08 & 3 2H +76 His) 0.00 2 2 Fe"+3e Fe ~008 > 2 Poste pb | cots 2 3 Sn"+2e = Sn pote 3 2 Ni 426 2 Ni oz 3 é co" +22 = Co 028 3 5 co +20 2 ca ~040 € & ce Lor | oan 2 : rs cia] § £ Cr +3e = Cr -0,74 a 8 Za $20 a Zn -078 2 £ 2%:0+20 = Hyg)+20H | 083 3 3 Cr +20 = ce -0.91 8 g Wn +26 0 Mn 118 8 2 Ae s5e AL ~198 = Mig s2e og cae + Nate a Ne an cette 2 ca 287 Se +20 usr 209 Ga +20. Oe -290 Cete 2 os 292 Kite a K 299 Ure =u = 305 Copyright reserved SS Please turn overDownloaded from Stanmorephysics.com Physical Sciences/P2 Copyright reserved 4 scnse TABLE 48: STANDARD REDUCTION POTENTIALS TABEL 4B: STANDAARD-REDUKSIEPOTENSIALE DBE/2023 Half-reactions/Halfreaksies ew) tee Kite os'+e Bat +20 Sf" 26 ca" +26 Nae Mah + 26 APY + 36 ai + 26 cr +20 2Hi0 + 26 Zn +26 ce + 20 Fe +26 cr +e ca +26 co +20 Ni + 26 sa +26 Po + 26 Fo + 36 2H +26 S+ 2H" +20 sn + 26 cute SO] +4H" +20 cu + 26 20 + 0» + 40 802+ 4H" + 40 cute bas 2e Oxo) + 2H" + 20 Fe"+e NO, +2H' +8 Bro{t) + 2e° Pe +ze nop 4H" = 26 Ou) 4H" = 40 eno + +6 14g) +20 Wo, + 8H se tide #2420 core Fg) +20 or K cs 88 ca Na Ma at Mo or alg) + 20H zn cr Fe Hg) HS) sn” cu 04(g) + 24:0 NOx(g) + 420 a9 Hoi Nog) + 24:0) 2B Pt Mn « 24.0 2H0 26r" + 7H0 2ce Mae + 440) 2:0 co" 3.05 2.93 292 =2.90 -209 -287 + “21 - 2.36 ~ 186 118 -091 = 083 = 076 -078 | oa =o. 040 028 -027 04 0.13 0.08 0,00 +016 +048 +08 +047 | +036 i) | +048 +082 +984 +088 +077 +080 +080 +085 +096 +107 +120 +123 +123 +133 +136 +181 “7 +181 +287 Increasing strength of reducing agents /Toenemende sterkte van reduseermiddelsbasic education Department: Basic Education REPUBLIC OF SOUTH AFRICA PHYSICAL S: TH FISIESE earnedchis MARKS/PUNTE: 150 proved: Umalusi Moderators Wilbon Kosten ee 30/5/23 30/5/23 30/5/23 These marking guidelines consist of 20 pages. Hierdie nasienriglyne bestaan uit 20 bladsye. [BEPARERENT OF BASIC DUCA SaamE GaSe MeTORA TT Bey 108 05 30 APPROVED MARKING GUIDELINE PUBLIC EXAMINATION, Copyright reserved/Kepiereg voorbehou Please tun over/6laai om assebliet Henanisics.com DBE/2023 Phys Bao worlere Ged hysics.. EE SOY CS OO cane QUESTION/VRAAG 1 14 Avy 1.2 1.3 14 15 16 17 Cv 18 DY 190 Avy 110 Dvv QUESTION/VRAAG 2 2.1 Compounds with one or more multiple bonds between C atoms in the hydrocarbon chain. v'V (2 or 0) Verbindings met een of meer. meervoudige bindings tussen C-atome in die koolwaterstofkettings. (2 of 0) ORIOF Anhydrocarbon with two or more bonds between the C-atoms. ‘n Koolwaterstof met twee of meer bindings tussen die C-atome. ORIOF Hydrocarbons containing not only single bonds between C atoms. Koolwaterstowwe wat nie slegs enkelhindings tussen die C-atome bevat nie ACCEPT/AANVAAR: - Compounds with one or more double/tple bonds between C atoms in the hydrocarbon chain. Verbindings met een of meerdubbel/trippelbindings tussen C-atome in die koohwaterstotkettings. 221 Dv DEPARTMENT OF ©. EDUGATION. PRIVATE BAG Kaos, PRETORIA D007 2023 -05- 3 APPROVED MARKING GUIDELINE HUREIG EXAMINATION Copyright reserved Kupieney wourbeliou (2) (2) @) (2) (2) (2) (2) (2) [20] (2)pnp waloaded from, Stanmorephysics.com e028 'SCINSC/SSINSS ~ Markiny Guitfelines/Nasienriglyne 2.2.2 2,4-dimethylhexane VV 2,4-dimetielheksaan Marking criteria: + Correct stem i.e. hexane. ¥ wents (dimethyl) correctly identified. Tame completely correct incl.ding numbering, sequence, hyphens and © Kéttakle stam di. heksaan, 7 © Substituente (dimetie)) korrek geidenifiseer. ¥ © /UPAC-naam heeltemal korrek insluitende nommering, volgorde, koppeltekens en kommas. (3) 2.2.3 _Propan-2-ol /2-propanol v¥_ ue Marking criteria: © Correct stem i.e. propanol. + IUPAC name completely correct including numbering and hyphens. “ Nasienkriteria: + Korrekte stam dij. propanol. (2) * _IUPAC-naam heeltemal korrek insluitende nommering en koppeltekens. 2.2.4 hepl-t-ene/1-heptene “~ hept-1-een/t-hepteen Marking criteria; * Correct stem i.e. heptene. «IUPAC name completely correct including numbering and hyphens. Nasienkriteria: + Korrekte stam di. hepteen. * _IUPAC-naam heeltemal korrek insluitende nommering en koppeltekens. ¥_ (2) 2.2.5 | Marking criteria/Nasier — Correct molecular formula: CsH:s ¥ 2 Korrekte molekulére formula: Cotte a * Correct molecular formula of inorgaric reactant and products. “ 3 Korrekte molekulére formule vir die anorganiese reaktant en produkte. Biz Balancing/Balansering Hit 3 5 2CsHisv + 2502 —» 16CO2 + 18H.OV Balv 3 jotesi i a aly ‘Ignore double arrows and phases./Ignoreer dubbelpyle en fases. ale! © Marking rule 6.3.10/Nesienrest 6.3.19. £/5 © If condensed structural formulae used:/indien gekondenseerde a|* 7 2 struktuurformules gebruik: MadMaks. % @ Ta - 2.3.1 Marking criteria/Nas/enkriteria Jonny If any one of the underlined key phrases in the correct context igcomitted, deduct 1 mark.lindien enige van die onderstreepte frases in die korrekte kontaks uitgelaat is, trek 1 punt af. Compounds wilh the same molecular formula but different functional groups/homologous series. v Verbindings met dieselfde_molekulére formule maar verskillende funksionele ) groepe/homoloé reekse. Copyright reserved/Mopiereg voorbehou Please tum over/Blaal om assebliofPHeDbBRITSA DESC tt TRU Or EP AYSICS A200 ayne fete 2.3.2 [Marking ori lenkriteria ¢ Functional group for aldehyde correct “ |* Functional group for ketone correct Funksionele grep van aldehied korrek | Funksionele groep van ketoon korrek * Whole structure of aldehyde correct ¥ —_|* Whole structure of ketone correct Hole struktuur van aldehied korrek Hele struktuur van ketoon korrek H—G H 24 ising criteria ‘© Caloulate the mass/percentage of oxygen. * Substitute correct mass and molar mass for both C and H into n gia < v + Substitute correct mass and molar mass for O into n =F. ‘+ Simplify ratio. (Accept correct empirical formula if no ratio is given.) ~ Correct molecular formula. ¥¥ ¢ Bereken die massa/persentasie suurstof. + Vorvang korrokte massa on molére massa vir beide ©.en ITin n= 5 + Vervang korrekte massa en molére massa vir O inn = 2. v + Vereenvoudig verhouding. (Aanvaar korrekte empiriese formule indien geen verhouding nie ) ” + Korrekte molekulére formule, ‘OPTION TOPSIET { o } ~ | 2= (1,09 + 0,18) ¥ Mass / Massa 7,08 Moles fmol 1,09 | Simplest ratio Eenvoudigste z verhouding Empirical formula Empiriese formule CaHKO M(C2H20) x } Molecular formula of compound X/ | Mofekulére formule van verbinding X: CsHeOo ¥¥. Copyright reecrvod/Kopioreg voorbehou Please tum over/Blaai om asseblielDownloaded from Stanmorephysics.com Physical Sciences P2/Fisiese Wetenskappe V2 DBE/2023 SC/NSC/SS/NSS — Marking Guidelines/Nasienriglyne | OPTION 2/0PTION 2 c recat ° Perceftage/Persentasie 4,5 9 36,57 Molés-ino! se v 16 v =2,28 Simplest ratio. v Eenvoudigste ce 4 Ee: verhouding Empirical formula Empiriese formule Calls M(C2H«0) x 44n n Molecular formula of compound X/ iinding X: CaHeO2 vv Copyright reserved/Kopiereg voorbehou Please tum over/Blaai om assebliof (6) [25]Prysidownoaksdefromnstormorephysics.com DBE /2028 SCINSC/SSINSS = Marking iseneshacritme QUESTIONIVRAAG 3 3.4 3.2 Marking criteria/Nasienkriteria If any one of the underlined key phrascs in the correot context is omitted, deduct 4 markJindien enige van die onderstreepie frases in dia korrokte konteks ultgoleat fs, iture af which the vapour pressure (of a compound) equals photic pressure. “¥ atuur waarby die damparuk (van ‘n verbinding) gelvk is aan die atmosferiese druk. Marking criteria/Nasienkriteria ‘* Compare compounds in terms of branches/chain lengths/surface area. ¥ Vergelyk verbindings in terme van vertakkings/kettinglengte/opperviakarea. + Compare strengths of IMF's/ Vergelyk sterkte van IMK'e.7 + Compare energy/Vergelyk energie Butan-1-ol ~ * Has a longer chain lenath,/is less branched./has a larger surface area! contact area, ¥ ¢ — Strenath of the intermolecular forces is areater./There are more sites for London forces. ~ * More eneray is needed to overoome/break intermolecular forces. * Het _'n_langer _kettinglenate./is_ minder vertak met 'n groter kontakopperviakireaksieapperviak. . ikte van die intermolekulére kragte verhoog./Daar is meer plekke vir Londonkragte. . word ben e_kragte te oorkom/breek. ¥ aaa 2-methvlpropan-1-ol has a shorler chain lenath./is more branched. has a smaller surface area/contact area. © Strenath of the intermolecular fo-ces is weaker,/There are fewer sites for London forces. © Lesser eneray is needed to overcome/break intermolecular forces. * 2:metieipropan-1-ol_het_‘n_korter kettinglenate./is meer vertak/het 'n Kleiner kontakopperviak/reaksieopperviak. + Sterkte van die intermolekulére Kraate is swakker./Daar is minder plekke vir Londonkragte. * Minder energie word _benodia om __intermolekulét oorkonvbreek. d 3.3 Boiling point/Kookpunt “ [PEPARINENT OF OAS 34 3.4.1 sv 342 PY Copynght reserved/Kopiereg Voorbehou EDUCATION. by 207% -D5-.3.9 APFROVED MARKING GUIDELINE PUBLIC EXAMINATION Ploase turn over/Blaai om assebiicf (2) (ly (1)Downloaded from Stanmorephysics.com Physical Sciences P2/Fisiese Wetenskappe V2 DBE/2023 'SUNSC/SS/RISS = Marking Sulzeiesasionrigiyne 343° RY a5 Propanoic acid/P has the strongest intermolecular forces. OR Two si forces}! Mic OR fi 1 Most phitay needed to separate the chains. PropanoésuunP het die sterkste intermolekulére kragte. OF Twee plekke vir waterstofbindings (wat sterker is as die ander intermolekulére kragte). OF Meeste energie benodig om kettings ie skei. 1 hydrogen bonding (which is stronger than other intermolecular QUESTIONIVRAAG 4 44 4.4.4 Halogenation/Bromination Halogenering/Brominering 4.4.2 The bromine water/Brz/solution decolourises./Brown colour disappears. Die broomwater/Br2/oplossing ontKleur./Bruin kleur verdwyn, OR/OF Bromine water/Bra/solution changes fom brown/reddish to colourless. Broomwater/Bro/oplossing verander van bruin/rooierig na kleurloos. 413 4 Marking criteria/Nasienkriteria ee * Functional group correct “ H—¢ Funksionele groep korrek a * Whole structure correct Hele struktuur korrek ti WG HY H 4.1.4 2:chloro-2-methylv propane” /2-chlors-2-metieipropaan ACCEPT/AANVAAR: 5 2-chloromethylpropane / 2-chlorometieipropaan Copyright reserved/Kopiereg voorbehou Please tum over/Blaai om asseblief (1) M1] (1) (2) (2)PueiownloadedGrmoter Stanmorephysics. com BE /2023 415 H I | ! NaOH(aqy’ | a aga WW — H-G-—-E-——H+ Nactlag)/ H SCINSC/SSINSS ~ Marking Guidelines/Nasienriglyne Ct atom on second C atom on compound R ¥ Whole structure of compound R correct ¥ replaces Ct atom at the seme position. jucture of alcohol correct, KCt(ag/LiCt(aq) OR HCt(aq) ¥ rrespond to the inorganic reactant used) i fa m op tweede C-atoom van verbinding Rv Hele struktuur van verbinding R korrok ¥ + React compound R with NaQH(aq)/ KOH(aq)/LiOH(aq) OR HeO OH-aroep vervang Clatoom by dieselfde posisio. Hele struktuur van alkohol korrek, NaCtag/KCKaqVLiCt(aq) OF HCt(aq) (most ooreenstem met die anorganiese reaktans gebruik) 4 H H—C Hv ud Hv i Ht i 4 H Il iM i + Reageer verbinding R met NaOH(aq\/ KOh(aq/LiOH(aq) OF HzO ¥ KOH(aq)/ H LIOH(aq)/ 4 (} 4 eta v ot ORIOF Aa fi Het Notes/Aantekeninge: + Ignorelignoreer == i Accept all inorganic reagents as concensed./Aanvaar alle anorganiese reagense j i as gekondenseerd. + Accept coefficients that are multiples. Aanvaar koéffisiénte wat veelvoude is. + Any additional reactants and/or products Enige addisionele reaktanso en/of produkte: ‘+ Incorrect balancing! Verkeerde balansaring: Max/Maks.5/, Max Maks. Sf PUBLIC EXAMINATION APPROVED MARKING GUIDELINE + Molecular formulae/Molekulére formu: Max.(Maks. 3/, j J+ Condensed formulae/Gekondenseerde formule: Max/Maks. 4/. t As -OH as condensed / -OH as gekondenseerd Condensed formulae/Gekondenseorde fermule: CHsC(CHs)CLCHs ¥ + NaOH(ag)/ —® CHsC(CHs)OHCI + NaCt(aq)/ KOH(aq)/ => keliaqy LiOH(aq)’ Lict(agy/ : OR/OF OR/IOF , i poe 6) ‘Copynght reserved/kopiereg voorenou Please turn over/tiaal om assebiiet #Downloaded from Stanmorephysics.com Physical Sciences P2/Fisiose Wetenskappe V2 416 447 4.21 4.2.2 SU/NSC/SS/NSS ~ Marking Guidetnes/vasienriglyne 2-methyl/ propan-2-olv/2-methyl-2-propanol 2:metielpropan-2-0l/2-metiel-2-propanol ACCEPTIAANVAAR: Methylpropan-2-0l/ Metielpropan-2-01 /Dehidrasie/Dehidratering pos tsterfiSation/Condensation v Ver 1g/Esterfikasie/Kondensasie ButylY propanoate ¥ Butielpropanoaat QUESTION/VRAAG 5 5.1 5.2 Copyright reservediKopiereg voorbehou Initial concentration is 0 (of NO2)./Concentration increases. / Curve starts at 0. v Beainkonsentrasie is 0 (van NO2)./Kcnsentrasie verhoog./Kurwe begin by 0. OR/OF Curve B has an initial concentration and is the reactant as its concentration decreases. Kunwe B het'n beginkonsentrasie en is die reaktant aangesien sy konsentrasie afneem. True/Waar ¥ nmol of NzOs forms 2n mol of NO2per unit time. ~ nmol NzOsvorm 2n mol NOz per eenteidstyd. ORIOF Gradient of graph for NOz is twice the gradient of graph for NzOs. Gradiént van grafiek vir NOp is twee keer die gradiént van grafiek vir N2Os. NOTEILET WEL: If gradients calculated correctly award mark Indien gradiénte korrek bereken word punt toegeken. etn ano 00 po NED UIE aio puBe Please turn over/Blaai om assebliet DBE/2023 (2) (1) (1) (2) [18] (1) (2)PrysiBownteakediefromnStornorephysics.com oBE/2023 5.3.4 5.3.2 Copyright reserved/kopiereg voorbenou SC/NSC/SSINSS ~ Marking Sdidelines/Nasienriglyne ‘Marking criteria/Nasienkriferia; m + Formula: © = 577 / n(NOz) = oV / n(NO2) =F + Substitute change in concentration. Vervang verandering in konsentrasie + Substituta M (48) and V (2)./Vervang If (46) en V (2). 7 « Finale6ttect answer! Finale korrekte antwoord: 1,84. ¥ OPTION4/OPSIE 1 OPTION 2/OPSIE 2 mv n(NO2) ve = NO = ‘ ue 200 x 10x 2 ‘2 200 x 104 v= —™> enige x 107 mol (462) 7 een ¥ both/ m= 184g v beide concentration into rate formula. ¥ Vervang verandering in konsentrasie in tempo formule. ‘+ Substitute time into the rate formula,/ Vervang tyd in tempo formule. + Use mol ratio/Gebruik molverhouding: rateltempo(Oz) = % rateltempo(NzOs)/ rateltempo(O2) = % rateltempo(NOz) ¥ + Final correct answer/Finale Korrekte antwoord: 1 x 10% (mokdm?-s#) “ NOTE/LET WEL If concentration is converted to moles, firal moles per s (mol-s“) must be converted back to concentration (mol-dm’s"). ie. there must be multiplication and division by 2. If one of these is omitted: Max.2/4 Indien Konsentrasie omgeskakel is na mol, moet die finale mol per s (mols) lomgeskakel word na konsentrasie (mol-dm*-s"') d.w.s daar moet vermenigvuldig en gedeel word deur 2. Indien een van hierdie uitgelaat word: Maks.2/ 4 OPTION 1/OPSIE 1 Ac(N20¢ ‘Ave rate/gem tempo = - somes) (60 x 104 - 200 x 10% ) v 700 (-0)v x 10% (mol-dm-s“) Yarate(NoOs) = %4(2 x 108) rate(O2) =1x405(mo-dm?s) v | OPTION 2/OPSIE 2 Ac(NOz ) Ave rate/gem tempo = a (280 x10 (0))y “700 (- 0) 7 = 4x40° (mol-drr-s't) rate(O2) = % rate(NOz) = (4 x10) ¥ =1x105(mokdms4) v_ Yiease turn over/tlaal om assebliet (4)nyse teoloaded from, Stanmorephysics.com SCINSCISSINSS ~ Marking SuideinesMasienraiyne DBE/2023 OPTION 3/0PSIE 3 4, Ac(NeOs) OR/OF % (60 x 104 — 200 x 104) v ils (140 x 10) 1x 10? mold? Ac(Or) x 10° mol-dm? x 10° mol-dmv> Ac(2) At (7x10%) “ 700-0) =1x108 (moldm-st) ¥ Ave rate/gem tempo = A280 x 104 ¥(— 0) 54 5.41 a . Number of particles J Kinetic energy Marking critoria/Nasionkriteria Curve Q must be above the given curve P and have the same shape as the given curve P and the peaks have to correspond. Kuwe Q must bo dis gegewe kurwe P wees en moet dieselfde vorm hé as die gegewe kurwe P en die maksimums moet coreenstem Slats at origin and not arossing curve v Begin by oorsprong en nie kruis met kurwe P nio. 5.4.2 Higher than/Hoér as ~ * When the concentration of NzOs is higher there are more NoOs particles per unit volume. ¥ Copyright resesved/Kopiereg voorbehou « More effective collisions per unit time/second. ¥ OR Higher frequency of effective collisions. += ‘in Hoér konsentrasie van N2Os bevat mocr N2Os.dooitiios per eonheidsvolume. ¥ ¢ Meer effektiewe botsings per eenheidstyd/sekonde. “ OF Hoér frekwensie van effektiowe botsinas. Please turn over/Blaai om assobliof (2) (3) [16]a . DBE/2023 DO HATER GEE ene a teRnOre BAY SIES COM ing QUESTION/VRAAG 6 64 62 6.2.4 6.2.2 6.3 6.34 6.3.2 Marking criteria/Nasienkriteri If any one of the underlined key phrases in the correct context is omitted, deduct 1 mark.Jindien enige van die onderstreepte frases in die korrekte konteks uitgelaat is, trek 1 pital. hen! wilibrium by favour disturbante. v7 uilibrium in a closed system is disturbed, the system will re-instate ing_the reaction that will_cancelannase the Wanneer die ewewig in 'n geslote sisteem versteur word, sal die sisteem ‘n (nuwe) ewewig instel deur die reaksie le bevoordee! wat die versteuring kanselleer/teenwerk. (2) nfHe(g)] = 0,11 (mol) ~ (1) OPTION 1/OPSIE 1 OPTION 2/OPSIE 2 1n(HDseatgotraz = 2n(I2) (Hollla} =2(0,11) THIE n(HD)eq = 1 - 0,22 (0,11)(0,11) = 0,78 (mol) ¥ f ray? = 0,78 mokdm? Bote n(Hl) = 0,78 (mol) v (1) Endothermic/Endotermies () Ke increased: * The concentration of the product/H2(g) and I2(g) is increased. v” OR: The concentration of the reactant/HI decreases. * The increase in temperature favou'es the forward reaction. ” * (According to Le Chatelier's principle) an increase in temperature favours the endothermic reaction. “ Kehet verhoog: * Die konsentrasie van die produkteiH2(g) en I2(g) vethoog. ¥ OF: Die konsentrasie van die reaklanse/l verlag, * 'n Toename in temperatuur bevoorteel die voorwaartse reaksie. “ (Volgens Le Uhatelier se beginsel) sal 'n foename in temperatuur die endotermiese reaksie bevoordeel. “ (3) Copyright roservod/Kopioreg voorbehou | BEPARTMENT OF BASIC] EDUCATION. PRIVATE OAG Xand, PRETORIA BOOT 223 -05- 30 APPROVED MARKING GUIDELINE “BUGLIC EXAMINATION ~ Please (urn over/Blaal om asseblierDownloaded from Stanmorephysics.com Physical Sciences P2/Fisiose Wetenskappe V2 DBE/2023 SUINSC/SS/VSS ~ Marxing Guidelines/Nasienniglyne 6.3.3 Marking criteria: (a) Correct K- expression (formulae in square brackets). (b) Substitution of 0,09 in Ke expression, (c) Corgeet initial moles from 6.2.1 and 6.22¥) (4) USINGFatio- nHI(g) = 2nkslg) = 4-2 ¥ (e) Substitution of concentrations into correct Ke expression, ¥ (Q) Subtraction (HUei — ATHI] ¥ (g) Substitution of 128 in m = nM. (h) Final arse. 80,64 gy (range: 79,36 - 80,64 9) POSITIVE MARKING FROM Q6.2/POSITIE\ JASIEN VANAF V6.2 ‘Nasienkriteriaz (a) Korrekte K, uitdrukking (formules in vierkantige hakies). ~ (b) Vervang 0,09 in Ke uitdrukking. ~ (©) Aanvanitike mol korrek vanaf 6.2.1 en 6.2.2. ¢ (d) GEBRUIK verhouding: nHI(g) : 2nl2(g) v (e) Vervang konsentrasies in korrekte Ke uitdrukking. (9. Verskil [Joon — AfHl) (g) Vervang 128 in m= nl. © (i) Finale antwoord: 80,64 9 ¥ (gebied: 79,36 - 80,64 9) v OPTION 4/OPSIE 1 Halll : Pm ¥ (a) v 0 COA NO11+X) Yee (0.78 - 2x)” Vay x= 0,0775 [HI] equttxiumienewig = [Hfoesny — AHI] = 0,78 — 2(0.0775) vf) = 0,63, moldm? (0,625) n(HI) = (0,63)(1) = 0,63 mol (0,625) m(HI) = nM 0,63)(128) v (9) Copyright reserved/Kopiereg voorbehou ¥ (6) (0,11 andlen 0,78 from 6.2.1 andien 6.2.2) DEPARTMENT OF a EDUCATION IS PRIVATE BAG Rabe PRETORIA Dal yy 203-0 30; APPROVED UARKNNG GUIDELINE OR/OF u(HI) ~ cVM = (0,63)(1)(128) ¥ (a) = 80,64 gv (ny Please turn over/Blaai om asseblistPhysBrowinkoa FED Frey waorephysics.com BE2023 sar ed oo OPTION 2/OPSIE2 E HI a He Initial quantity (mol) Aanvanklike hoeveetheid (mo) | __%78 meee ae 4 ia i Changemol) ato 1:2) Veraridering (mol) a z Ee Quanfity-at equilibrium (mol) i Hooweliela by ewewrg (mol) 0,78-2% | O414+x] Of14+x Equifibrium concentration 078-2 | OAtx | OfiFx Ewewigskonsentrasie 7 7 7 (mold) J ke = Heli vy ©) itso + o%9 = OU ANON AY 6) xe eee A [HI] equitum/ewony = 0.78 — 2(0,0775) ¥ 0,63 mold (0,625) n(HD) = cV (0,63)(1) 0,63 mol (0,625 mol) : (0,63)(1)(128) »* ig) m(HI) = nM = 80,64 g v (hy ! = (0,63)(128) v (9) | 80,64 g (hy (8) [16] QUESTION/VRAAG 7 i 74 j 1.1 ANY ONE. | + A substance whose aqueous solution contains ions. vv (2 or 0) j * Substance that dissolves in water to give a solution that conducts 4 electricity © A substance that forms ions in water/forms ions when molten, ENIGE EEN: * ‘Sto waarvan die oplossina ione bevat. vv (2 of 0) * 'n Stof wat in wator oplos om ‘n oplossing te vorm wat el Hei. (2) © 'n Stof wat ione vorm in water/ione vorm wanneer gesmelic DEPARTMENT OF HAST epucation. © | 2s 2023-05-30: APPROVED MARKING GUIDELINE PURUIG EXAMINATTGRDAD Copyright reserved/Kupisrey vuurbelou tum over/Biaal om assebliet ipy pratloaded from, Stanmorephysics.com e023 71.2 713 72 724 7.22 O — few drops of water will dilute the HCf, “therefore greater, Copyright reserved/Kopiereg voorbehiou SCINSC/SSINSS ~ Marking Guitelines/Nastenviglyie AY H2SOs is diprotic./Donates more than one mole of H* ions per mole of acid (and both acids are of the same concentration)./H2SOs has a higher Ka value. HSOs is diproties./Skenk meer as een mol H* ione per mol suur (en beide sure konsentrasie)/ H»SOz het 'n hoér Ke-waarde. fo produce more than one mole of prolons/H* ions for each mole of 3SO4 has a higher Ka value. Dit ioniseer om meer as een mol protone/ H'-ione vir elke mol HeSOx te vorm./H2SOx het 'n hoér Ke-waarde. BY Stronger acid/onises completely “(and both acids are of the same concentration). /HNOs has a higher Ke value. Sterker suurfoniseer volledig (en beide sure het dieselfde konsentrasie).1 HNOs het 'n hoer Ke-waarde. OR/OF C/CH2COOH is a weaker acid/ionises incompletely. C/CHSCOOH is 'n swak suurfoniseer onvolledig. (Marking criteriaNasienkriteria: J+ Substitute/Vervang 0,04 mol-dm* and 26 x 10° dm? (25 cm) and y 19,5 x 10% dm? (19,5 cm). ¥" a J+ USE mol ratio GEBRUIK molverhouding: n(NasCOs) : HCL = 1:2 | J+_Final answer/Finale antwoord: 0,10 toitot 0,103 mol-dm’ v _|38 ‘OPTION 4/OPSIE 1 OPTION 2/OPSIE 2 ee CoV _ Ne n(Na2COs) = eV és Mm 0.04 x 0,025 oe = 0,001 mol ea V2, n(HCB = 2n(NazCOs) v ig i = 0,002 mol ¥ u 5 €a= 0,10 mold? ¥ (0,103) | Hoy = | : Vv 0,002 0,0195> 10 moldm? ¥ (0,103) Greater than/Groter as ¥ will be needed to neutralise the base. I 'n Paar druppels water sal die HCfverdun, daarom sal 'n gr benodig word om die basis te neutraliseer. Please tum over/Bleai om asseblief (2) (2) ; i : i (3) (2)7.2.3 PrysBownles daticfromnStanmorephysics.com BE/2023 SCINSC/SSINSS ~ Marking Guidelines/Nasienriglyne POSITIVE IG FROM Q7. ‘Marking criteria: (a)Substitute 0,1 mokdm® & 18.7 x 10° dm? (18,7 cm’). v (b)Use mole ratio: 1:11 ¥ fateyn(NH.) / m(NHs) in calculate mole/mass in initial solution.” (9 Use 17 g:motinn= 7. 7 (0)Final answer: 18,08 g / Range: 17 to 19,13 g -OSITIEWE NASIEN VANAF V7. [Nasienkriteria, (a) Vervang 0,1 moldm”® & 18,7 x 10° dm? (18,7 om) ¥ (©) Gebruik molverhouding: 1:1 ¥ |(c)Bereken n(NHa)/m(NH3) in 250 cm’: Vervang 0,25 dm’ (250 cm’). (d)Vervang 0.022 dm’ (22 cm’). ¥ (e)Vervang 0,02 cin (20 cm") om ‘mol/massa van oorspronklike oplossing te bereken. () Gebruik 17 g-mor inn == (g)Finalo antwoord: 18,08 g Gebied: 17 tot 19,13 9 v n(NHs)roactedieegoor = N(HCOrosctodreagoer 1,87 x 10 mo} v(t) n(NHs) in 22 om? = 1,87 x 10° mol (1.87 1005 2 = (1:87 * 10" )(250) n(NHs) in 250 om? = ava = 0,021 mol (2,13 x 102) (NHS) in 0,024 mol cE m 0021 =F m(NHs) = 01367 g in 20 om? (0,357)(1000) 20 (e) = 17,85 g7a)(18,06) m(NHs) BE Copyright reservea/Koplereg voorbehou OPTION 1/OPSIE 1 OPTION 2/OPSIE 2 n(HCe)= oV n(HCe)= cV (O.NV18,7 x 10%) v (ay (0.1)(18,7 x 10°) (a) 1,87 x 10% ol (87 x 19° mol M EPARTMENT OF GASI 8 2003-05 30 be APPROVED MARKING GUIDELINE ,72 x 10g in 22 cms (ce) oak, (3,72.x10°)250) 22 V(d) 0,961 g m(NHs) in initial 20 cm? = opet 9 , (0,361)(1000) 22 m(NHs) in 1 000 em = 207% = 18,06 gv(a) m(NHs) in 250 om? = EDUCATION. Please turn over/Blaai om assebliefmmo eteloaded.£ram. gtanporephysics.com oper023 SC/NSC/SSINSS ~ Marking Suidelines/Nasienrighyne OPTION 3/OPSIE 3 OPTION 4/OPSIE 4 Vb _ Mb, n(HCh= cV tne (0,418.7 x 10°) ¥ (a) ea = 1,87 x 192 mol (NH)roctasroagear = n(HCreoctesieagoor 4,87 x 10° mol vib) pe tale n(NHs) in 22 om? = 1,87 x 10°mol 0,085 3 vid iE nus in 250 ome =:22 2 1071250) oni = 022 i 22 v(a) 61(0,02) ¥ = (0,085)(0.26) v (e) 024 mol ) 1 = 1,06 mol-dm* (20 emé)=c(1 dm?) M = fe m=cvM vv = (1,08)(1)(177) anh in #000 om 222 8,06 g v (a) 06 mol om 108= 55 vin m(NHs) = 18,06 ¢ v(9) 7.2.4 — Less than 7/Minder as 7 ¥ NHa*(aq) + H20(®) ¥ = NHs(aq) + Hs0*(aq) ¥ Notes/Aanfekeninae: *_Ignore single arrowllanoreer_enkelpy: QUESTION/VRAAG 8 81 © Pressure: 1 atmosphere /101,3 kFa /1,01 x 105 Pa ¥ Druk: 4 atmosfeer /1013 kPa /1,01 x 10° Pa + Temperature/Temperatuur: 25 °C [298 K ¥ + Concentration of electrolytes: 1 mol-dm3 Konsentrasie van eleKtroliete: 1 mol-dm3 8.2 To maintain electrical neutrality/To complete the circuit/To all ions between electrolytes “ i Om elektriese neutralitet te verseker/m die stroomBaan to pebOI/Laat ione foe om tussen elektroliete te beweeg Copyright reservad/Kopiareg voorbehou Please turn over/Blaai om assebliet (3)Puysibowntontted frie Garin oraphysics.com DBE/2023 SCINSC/SS/NSS — Aree OY 8.3 84 Copyright! nese ved/Kupicrey vourbetiou hidolines/Nasienriglyne OPTION 1/0PTION 1 Notes/antekeninge Ey Chae ES sae ¥ + Accept any other correct formula from the data sheet./Aanvaar enige ander korrekte formule ARCH vanaf gegewensblad. + Any other formula using unconventional abbreviations, ¢.g. E°ea = E%o,- Ee followed by correct substitutions:/Enige ander formule wat onkonvensionele afkortings gebruik, by, S's = E"ow- E*ren gevolg deur korrekte : : 4 vervangings: Max.Maks. 4 ets xX E=1,20V¥ He > 2H* +20" E*=0.00VY X is PtPlatinum ¥ OPTION 2/OPSIE 2 Ho + XX + 2Ht 20VY He(g) 2H*(aq) + 20 vv" Marking criteria/Nasienkriteria: + 2H*(aq) + 2e Hag) (%) He(g) = 2H"(aq)+2e° (14) He(g) — 2H*(aq)+2e (9%) 2H"(aq) + 2e° = He(q) (%) * Ignore if charge omitted on electron /lgnoreer indien lading weggelaat op elektron. + Ifccharge (+) omitted on H'/indien lading (+) weggelaat op H': Example/Voorboold: H2(g) + 2H(aq) 1 Ze Max./Maks. % DEPARTMENT OF BASIC EEUCATION 2023 -05- 30 ys APPROVED NARKING GUIDELINE PUBLIC = XAMINATION Please tum over/Biaal om assebtiet (6) (2)pnydowtplonded tram, stanmorephysics.com e/023 ‘SC/NSC/SS/NSS — Marking Suidelines/Nasienrigiyno 85 HY Xx (P I, Aut Hz loses/donates electrons to bot Au and X/Pt. ¥ oR Th v Ho is the anodetis oxidised in both cells. elaisre H* is the weakest oxidising agent. juction potential of X| X2* is 1,2 V and that of Au] Au is ‘The reduction potential of X| X2* is smaller than that of Au| Au®*. OR According to the Table of Standard Reduction Potentials Au®* is stronger oxidation agent than Pt. OR The cell containing Au produces higher emf than cell containing X. * Ho verloor/skenk elektrone aan beide Au en X/Pt. ¥ OF Hy is die anode/word geoksideer in beide selle. Daarom is H* die swakste oksideermidde! «Die reduksiepotensiaal van X| X** is 1,2 V en die van Au| Au®* is 15V.0 OF Die reduksiepotensiaal van X| X** is Kleiner as dié van Au| Au. OF Volgens die Tabel van Standaardreduksiepotensiale is Au 'n sterker oksideermiddel as Pt? oF Die sel wat Au bevat het 'n hoér emk as die sel wat X bevat. Copyright reserved/Kopiereg voorbehou DEPARTMENT OF BASIC] EDucaTiIon > 23 -D5- 3.9 APPROVED MARKING GUIDELINE PUBLIC EXAMINATION Please tum over/Blaai om assebliet (3) [4]Pro wetea Ged friars sharin isics.com DBE/2023 Eloy QUESTION/VRAAG 9 941 9.2 9.3 9.3.1 9.3.2 9.4 A cell in which electrical energy is converted into chemical energy. “v (2 or 0) 'n Sel waar elektriese energio na chemigse onergic omgoskakol word. (2 of 0) Rv at Oxidatistitakes place /R loses electrons./R decreases in mass. v Oksidgs##\vind plaas./R verloor elektrone./R se massa sal afneem. Zn*(aq) + 2e° + Zn(s) vv Ignore phases//gnoreer fases Marking eriterla/Nastenkriteria: + Zn(s)—Zn*(aq)+2e (3h) Zn**(aq) +26 = Zn(s) (1%) Zne(aq) +20 + Znls) (94) —_Znls) eZn?aq) +2e (4) + Ignore if charge omitted on electron /Ignorcer indien lading weggelaat op elektron. * If charge (+) omitted on Zn2"/Indien lading (+) weggelaat op Zn?*: Example/ Voorbeeld: Zn(aq) + 2e° + Zn(s) MaxiMaks: 1% ZinolZn/Sink ~ Zn* ions are reduced/Zn?*] decreases. ” Zn* jons must be replaced by oxidation of the Zn electrode. “ Zn" ione word gereduseer/IZn?*] neem af. Zn** jone moet vervang word deur oksidasie van Zn-elektrode. TOTALITOTAAL: Or BASIC EDUGATION. PRIVATE BAG xa85, PRETORIA DOT 2023 -05- 39) APPROVED MARKING GUIDELINE PUBLIC EXAMINATION Copyright reserved Kopierey voorbwliou (2) (2) a) (2) [9] 150 usb