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Chapter 3
Chapter 3
Chapter 3
ETTEITIVE HOTI:S
l. Relative atomic mass of an element Calculate the number of moles of nitrogen molecules,
The avera mass of one atom of an element N2 which consist of i.Ol x 1025 nitrogen molecules.
Hitung bilangan mol molekul nitrogen, N2 yang
x the mass of one atom of carbon-l2
n mengandungi 3.Ol x 1023 molekul nitrogen.
Jisim atom relatif suatu unsur So I uti on/Pe n5t e le s aian :
Jisim purata satu atom unsu,r
1
jisim satu atom karbon-L2
Number of moles: Number of molecules
E x
Bilangan mol
/vA
Bilangan molehul
2. Relative molecular mass of a substance Na
The average mass of one molecule 3.01 x 1023
I
x the mass of one atom of carbon-I2 6.02 x 1025
12 : 0.5 mol
Jisim molekul relatif suatu bahan
Jisim purata satu molekul
I -..-
jisim Example @/Contoh
x satu atom karbon-L2 @:
=*
LZ What is the mass in grams of 0.5 mol of carbon
Mole ConcepUl(o nsep Mot dioxide, CO2?
l. I mol of substance : The number of particles in I 2 g ot [Relative atomic mass: C: I2; O : l6]
carbon-12 Berapakah jisim dalam grdm bagi 0.5 rrrol karbon
1 mol bahan Bilangan zarah dalam 12 g dioksida, COz?
= lJisim atom relatif: C = L2; O = 161
karbon-L2
: 6.02 x 1023 particles/zarah Sol ution/Pe ny e le saian:
2. The value of 6.02 x known as the Avogadro constant
1025 is
Mass
Nilai 6.02 x L023 dikenali sebagai pemalir Aaogad.ro. Number of moles:
Relative molecular mass
3. The relationship between the number of motes, the Jisim
number of particles, the mass and the volume of gas Bilangan mol
Jisim molekul relatif
are shown below.
Hubungan antara bilangan mol, bilangan zarah, jisim 0.5 : Mass/Jisim
dan isi padu gas ditunjukkan di bawah. ll2+(2x16)l
:O.5x44
*Nn :229
a-*
xNn
Nn : Avogadro constant/Pemalar Auogadro
: 6.02 x 1023 Example @/Contoh @:
Calculate the volume of gas occupied by 1.5 mol of
,Mr sulphur dioxide, SO, at room condition.
XM, [Molar volume: 24 dms mol-r]
Hitung isi padu gas yang ditempati oleh L.5 mol sulfur
M, : Relative atomic/molecular mass dioksida, SO2 pada keadaan bilik.
Jisim atom / molekul relatif [Isi padu molar: 24 dms mol-1]
,Mv Sol uti o n/Pe ny e le s aian:
a-€ Volume of gas
XM, Number of moles:
M, : Molar volume/si padu molar Molar volume of gas
Bilangan mol Isi padu gas
- Room condition/Keadaanbilik:24.O dm3 mol-r Isi padu molar gas
- STP : 22.4 dm3 mol-l Volume of ga s/Isi padu gas
1.5 :
At the same temperature and atmospheric pressure, all 24
gases occupy the same amount of volume. :1.5x24
Pada suhu dan tekanan atmosfera, yang santa, sernud gas : 36 dm3
menempati jumlah isi padu yang sarna.
2t
Chemical Formulae Ghemical Equations
Formula Kimia
l. Empirical formula is a chemical formula
thai shows the simplest ratio number
of atoms for each type of element in a
compound.
ffi
VIDEO
Persamaan Kimia
l. A chemical equation is an equation written by using
symbols and chemical formulae.
Persamaan kimia ialah persarnaan yang ditulis dengan
rnenggunakan simbol dan forrnula kimia'
Fortnula emp irih ialah formula kimia 2. easi;" information that can be obtained from a
yang menunjukkan nisbahpaling ringkas bagi bilangan
chemical equation are qualitative aspect and
atom setiaP ients uns ur dalam suatu sebatian. quantitative asPect.
2. Molecular formula is a chemica I formula that shows the Maklumat asai yang dapat diperoleh dglyy sesuatu
actual number of atoms for each type of element that prito,*o"n kimii adZtah a'speh kualitatif dan aspeh
are present in a molecule of a compound' kuantitotif.
Formula molekul ialah formula kimia yang menunjukhan l. from the qualitative aspect, the chemical equations give
bilangan sebenar atom setiap jenis unsur ydng terdapat the following information:
dalam satu molekul suatu sebatian' Dari segi asiek kualitatif, persarnaan kimia memberikan
maklumat Yang berikut:
:
Molecular formula (Empirical formula)r, (a) The tYPes of reactants
n is a Positiveinteger ,: Jenis bahan tindak balas
Formuia molekul -'(Formula empirlk)* (b) The tyPes of Products formed
n adalah integer Positif l
MgCl2
2
t
Formula kimia
Slep l/Langhah 3=
Balince thJnumber of atoms for each element by
6. The total positive charge of cation must be equal to the iJlrtting the coefficients in front of the chemical
total n"gitir" charge 6f anion when writing a chemical formulae.
formula for an ionic comPound. Seimbanghan bilangan atom bagi setiap unsur dengan
Jumlah cas positif basi- kation mestilah sanna dengan iena*bZhkan pekiti di hadapan setiap formula kimia'
jwnlah i"gotif ba-gi anion senxosa menulis formula
"orsebatian ion.
kimia bagi
22
Day: .............................. Date:
PBD
Relative Atomic Mass and Relative Molecular Mass
Jisim Atom Relatif dan Jisim Molekut Retatif
I Complete the following equations. lsa.r.r f,lll
Lengkapkan persamaan yang berikut.
2 Mark (_/ ) the reasons -n-Ly carbon-l2 is used as a standard for determining relative atomic mass and relative
molecular mass. r-ss.r.r llp
Tancral@n | / | sebab mengapa kabon-12 digwakan sebagai piawaj untuk menentukan jisim atom rclatif dan jisim motekul relatif.
3 Calculate the relative molecular mass and relative formula mass for the substances in the table below. r_Sa.t.z t[
Hitung iisim molekul rdatif dan iisim formuta relatil bagi bahan dalam jadual di bawah.
Relative
(a) Tetrachloromethane
Tetraklorometana cc14
[Relative atomic mass lJisim atom rdatif. C= 12;N= 14;O = 16;Na=23;Mg=24rS = 32; Cl = 35.5; Fe =56;Zn=651
23
Day: Date:
Mole Concept
Konsep Mol
Ghemical Formulae
Formula Kimia
4 Answer all the questions below. LS3.2.4, g.g.c EIS
Jawab semua soalan di bawah
(a) A compound consists of 40o/o calcium, l2o/o carbon and 48o/o oxygen' What is the emp irical formula of the
compound?
-
[Relative atomic mass: C 12; O = 16; Ca = 40]
aa' 48Yo oksigen' Apakah formula empiik bagi sebatian itu?
Suatu sebatian mengandungi 4Oo/o kalsium, 12o/o karboi
Uisrm atom relatif: C = 12; O = 16; Ca = 40I
Solution/ Penyel esai an :
(b) 1.2 gof magnesium produces 2.0 gof magnesium oxide after complete heating' What is the
empirical formula
of magnesium oxide?
[Relative atomic mass: O = 16; Mg - Z+] -- .,-empiik
---:r,-,---:
bagi -^,
magnesium
1.2 g magnesrum menghasilkan 2.0 g mignesium oksidase/epas pembakaran lengkap' Apakah formula
oksida?
tJ,s,m atom relatif: O = 16; Mg = l4l
Solution/ P eny el esai an z
(c) Hydrocarbon X contains 4.32 g of 0J2 g of -hydrogen'- The relative molecular mass of
carbon
-and
hydrocarbon X is 70. Determin. ih. empirical and molecular formulae of hydrocarbon X.
[Relative atomic mass: H = 1; C = L2)
Hidrokarbon X mengandungi 4.32 g karbon dan O12 g hidrogen' Jisim molekul relatif bagi
hidrokahon X ialah
70. Tentukan
formula empirik dan formula molekul bagi hidrokarbon Y
Ursim atom relatif; H = 1; C = 121
Solution/ P e ny el esai an t
(d) An organic comPound has an empirical formula of CH2 and the relative molecular mass is 112' What is the
molecular formula of the comPound?
[Relative atomic mass: H = 1; C = 12) formula molekul bagisebatian
Suatu sebatian organik mempunyai formula empirik CH2dan iisim molekul relatif ialah 112' Apakah
itu?
tJ,s,m atom relatif: H = 1; C = 12]
Solution/ P eny elesai an z
24
Day: Date:
Chemical Formulae
Formula Kimia
5 Write the chemical formula for the following compounds. 1s3.3.5 EIg
Tulis formula kimia bagi sebatian yang berikut.
(0 Potassium manganate(Vll)
Kalium manganat('lll)
Chemical Equations
Persamaan Kimia
6 Mark ( / ) the balanced chemical equations. 153.4.1 EIE fi![} Applyine
Tandakan ( / ) pada persamaan kimia yang seimbang.
(c) Na2CO3(s lp) + 2HCl(aq/ ak) -+ NaCl(aq/ ak) + HzO(ll ce) + CO2(g)
7 Write a balanced chemical equation for each of the following reactions. Ls3.4.1 m @[) Applyins
Tulis persamaan kimia yang seimbang bagi setiap tindak balas yang berikut.
25
PAPER T
Instructions: Each question is followed by four alternative answers, A, B, C and D. Choos€ one correct arswer for each question.
Arahan: Setap soa,an diikuti old empat pilihan iawapan, A B, C dan D. Pilih sa hwapan yang betul bagisetiap soalan.
4 What is the volume occupied by 100 g of carbon What is the mass of aluminum nitrate formed when
dioxide gas at room condition? 14.85 g of aluminium powder are reacted with excess
W nitric acid?
[Relative atomic mass: C -- 12; O = 16; Molar volume
= 24.0 dm3 mol-l] [Relative atomic mass: N = 14; O = 16; Al = 27)
Berapakah isi padu yang ditempati oleh 100 g gas karbon Berapakah jisim aluminium nitrat yang terbentuk apabila 14.85 g
dioksida pada keadaan bilik? serbuk aluminium beftindak balas dengan asid nitrik berlebihan?
lJisim atom relatif: C = 12;O = 16; tsi padu molar =24.0 dm3 mol-11 lJisim atom relatif: N = 14; O = 16; Al = 27)
A 34.6 dm3 B 45.5 dm3 A s8.6 g B rr7.2 g
c 52.3 dm3 D 54.5 dm3 C 234.3 g D 267.9 g
26
Day: Date
PAPER 2
Section A
Instructions: Answer all the questions.
Arahan: Jawab semua soalan.
I Table 1 shows the names, chemical formulae and relative molecular mass of some chemical compounds.
Jadual 1 menunjukkan nama, formula kimia dan jisim molekul relatif bagi beberapa sebatian kimia.
Nitric acid
Asid nitrik
HNO3
Glucose
c6H1206
Glukosa
Chloroform
Kloroform
cHCl3
Quinine c2oH24N2O2
Kuinin
rABLE IIIADUAL t
(a) Complete Table 1 by filling in the relative molecular mass of each of the compounds
[Relative atomic mass: H = 1; O = 16; C - l2;N = 14; Cl = 35.5]
Lengkapkan Jadual 1 dengan mengisi jisim molekul relatif bagi setiap sebatian itu.
lJisim atom relatif; H = 1; O = 16; C = 12; N = 14; Cl = 35.51
13 markslS markah)
(b) What are the number of molecules are there in the following nitric acid and glucose?
Berapakah bilangan molekul yang terdapat dalam asid nitrik dan glukosa yang berikut?
(i) 10 g of nitric acid
10 g asid nitrik
ll marklt markah)
(ii) 10 g of glucose
10 g glukosa
ll markll markah)
27
Day:
[2 marlcslL ma*ahl
(ii) In the combustion of carbon, 3 mol of orygen molecules are used. How many oxygen molecules are involved
in this reaction?
[Avogadro's constant = 6.02 x 1023 mol-l]
bataipembakaran l<arbon,3 mol molekul oksigen digunakan. Benpakah bilangan molekul oksigen yang terlibat dalam tindak
balas ini?
lPemalar Avogadro = 6.02 x 1d3 mol-11
lL markll markahl
(iii) How many moles of carbon dioxide gas are released in this reaction?
Berapakah bilangan mol gas tcabon dioksida yang ditruMskan dalam tindak balas ini?
ll markll markahl
(iv) What is the mass of carbon dioxide gas released?
Benpakah 1i'slm gas karbon dioksida yang dibebaskan?
ll markll martahl
28
Date:
.1 Chemlcal Formulae
Fonnula Kmia
Chemlcal Equalions
Pe's,amaan Ktmla
- 2_ A student carries out an experiment to determine the empirical formula of magnesium oxide. Table 2 shows the
$ results obtained from the experiment.
- *o{arry nuid nenldenken @inE,| untuk nr/n?,tfirtut fo l/u/la ffipirtk bagd zragnosium oksda "ldud 2 t lE,vniu*tan lc,putusf,l
Wp diperoleh c*ldD€cb?/l<s,€/tinan iU.
Crucible + lid
Mangkuk pijar + Wnutup
55.35
TABLE AJADUAL2
ll markh makah)
(b) How to ensure all magnesium has completely reacted?
Bagaimanakah untuk memastil<an semua magnesium bertindak balas dengan lengkap?
I ll markll markahl
a
(c) Based on Table 2, determine the empirical formula of magnesium oxide.
[Relative atomic mass: O = 16; Mg = Z+l
Berda rkan Jadual2, tentukan formula empiik bagi magnesium oksida.
tJ,s,m atom relatif: O = 16; Mg = 24I
13 markslS markah)
(d) List two precautionary steps that must be taken during the heating process carried out.
Senanikan dua langl<ah berjaga-jaga yang perlu diambilsemasa proses pemanasn dijatankan.
l2 marksl2 markahl
(e) Draw an apparatus set up to carry out this experiment. @fi) Applyins
Lukis susunan rudas untuk menjalankan eksperimen ini.
[2 marlcsl2 markah)
29
t
Day: Date:
ll marklt markahl
(ii) Write the empirical formula for butanoic acid.
Tulis formula empirik bagi asid butanoik.
ll markll markah)
(iii) State one similarity and one difference between the molecular formula and empirical formula for butanoic
acid' @El AnalYsine
Nyatakan satu persamaan dan satu perbezaan antara formula molekul dengan formula empirik bagi asid butanoik'
Similarity
Persamaan
Difference
Perbezaan
12 marksl2 markah)
(b) The following equation shows the reaction between zinc and hydrochloric acid.
Persamaan yang berikut menuniukkan tindak balas antara zink dengan asid hidroklorik.
p) + (aql ak) + k) +
(i) -Zn(sl
Balance the above chemical equation -HCl -ZnCl2(aq/a -Hr(g)
Seimbangkan persamaan kimia di atas.
ll markll markahl
(ii) Name the reactants and products for the equation.
Namakan bahan tindak balas dan hasil tindak balas bagi persamaan itu.
Reactants
Products
Qualitatively
Kualitatif
Quantitatively
Kuantitatif
12 marksl2 markah)
30
Day: Date:
Section B
Instructions: Answer all the questions
Arahan: Jawab semua soalan.
TABLE 4I]ADUAL 4
(i) State the scientific name and chemical formula for marble.
Nyatakn nama saintifik dan formula kimia bagi batu marmar,
12 marksl2 martc,hl
(ii) Calculate the maximum volume of carbon dioxide gas produced in the above experiment.
[Relative atomic mass: C = 12; O = 16; Ca = 40; Molar volume = 24.0 dm3 mol-r]
Hitung isi padu makimum W kbon dioksida yang dihasitkan datam elspeimen di atas.
Visim atom relatif: C = 12; O = 16; Ca = 40; lsi padu motat = 24.O dm3 mofll
[4 ffiarl<sl4 mad<ahl
(c) The followiag information is about an organic compound, Y.
Maklumat yang berikut adahh mengenai suatu sebatian organik, y,
(d) Hydrazine It contains 87.5% ofnitrogen and 12.5% ofhydrogen' The relative molecular
can be used as rocket fuel. I
ildruina Ooun digunabn sebagai bahan;pi roket' Hidraziz mengandungi 87 -5% niwen dan 125% hidrcgen' Jisim moletul
relatif bagi hidrazina ialah 32. Tentukan formula empirik bagi hidrazina'
lJisim atom relatif; H = 1; N = 141
14 marksl4 markah)
Section C
Instructions: Answer all the questions.
Arahan: Jawab semua soalan.
Chemical Formulae
Formula Kmia
5 Diagram 5 shows the apparatus set uP to determine the empirical formula of copper(Il) oxide
Raj{h 5 menuniukkan susuian radas untuk menentukan formula empirik bagi kuprum(ll) oksida'
Glass tube (12 cm) Copper(ll) oxide powder
Solur koco (12 cm) Serbuk kuprum(ll) oksido
Rubber tube
Glass tube ( l0 cm)
Solur getoh
Solur koco (10 cm)
Hydrochloric acid
Asid hidroklorik
Water
Air Zinc granules
Ketulon zink
Wooden block
Bongkoh koyu
DIAGRAM SIPAJAH s
(a) By using your knowledge about the chemical equations, wdte all the ions that form copper(Il) oxide' Then' write
a Lalanied chemical equation for the formation of the copper(Il) oxide.
D$gan meng(nratan peigeataan anda tentang persamaan kimia, tulis semua ion @ng membentuk ktprum(lll oksida' Kemudian'
tulis perrfrmejE/n kimia yang sehbang bagi pembentul<an kuprumlll) oksda itu.
14 rnarkst| martah)
(c) Describe an experiment to determine the empirical formula of zinc oxide. Your explanation should include of
the following aspects:
Hunikn satu-eldennen untuk menentukn formuta empiik bagi zink oksida, Penerangan anda hendaklah mengandungi aspek-
aspek yang berikut:
- Procedures for the experiment
Prosedur eksperimen
- Tabulation of data
Penjadualan data
- Calculation of the results obtained
Pengiraan keputusan yang diperoleh
[Relative atomic mass: O = 16; Zn - 65]
lJisim atom relatif: O = 16; Zn = 651
ll0 marksllO markah)
32