ARIOLA, AVZEL P

201 -Ol|t
BS cnE
E O322-2: CAEMICAL REÁCTION ENGINEERING

Assignment 1.2
a Derive the Damkonler (Da = eCot) as atunction ot con:lversion XA tor Oth And 2nd
n PFR with variable volume

* Zerot Order with variable volume [ pFP

dfa

dfA = Fo dA
-FHodKA
dy
dv
FA6
dxA
XA
dv
d¥A
-ra

Fto where

XA

= XA = Da

LFRI
A Gecond Orderwith variable volume
dYA -
2

CAO

CAO
LeCAO = Da = (texA)* dxA
(l- XA )
XA

(- 2XA +XA)
 - ln
XA) l2£(6+1) (e+1)2At E2XA+ =Da
XA) (- 2e)n (2¬*t+(et)XAt tA =Da
(I-X*) 26+1)|" Jo (E2+ 6XAt =Da
XA
-2¬-2¬
B
tB(i-o) z£(o)-et=A 262(0
t
22+1 =t A
A+6(i-) E+l= 2¬c)- LE) t
A+B(I-
Let XA); -g+|= 2¬XA 2¬XAt
=| XA
(l-XA)2
2¬XA-E: 22XA+ (|-XA)
|
DecompositiDn:. FractiOn artial Using
XAd =
Da
XA
-E+| 2exA 2XAt
tE) 22XA -
Division Long sing t: Con
AIZEL
P. ARIOLA,
AR\OLA, AIZEL P
Dwhat does high or (ow Da inply?
which is a
Damkohler number (Da) is a dimensionless numloer,
reactíon time,
ratio o a cnaracteris tic liquid residence time to the
reaction i's fast
hence a hioh Da indi cates that the torward
kinetically Controlled.
while ow Da means that the reaction is
end.