1. Calculate the pH and pOH of a 1.00 x 10-3 M solution of acetic acid. (Ka= 1.

76 x 10-5)

CH COOH CH COO t H30t

1 10 3M O O
I
E EE Hy tf
5
1 76 10 CH COO Hzot
5
TYCOON
1.76 10
11 10
7
X 430 3 1.242 10 4M
4
PH log 1.242 10

pH 3.91

POH 14 pH 14 3.91 10.09

2. The basicity constant for ammonia is 1.75 x 10-5 at 25 oC. Calculate the pH and pOH for
a 1.00 x 10-3 M solution of ammonia.

Kb 1.75 10 5
x

x 1.242 10 4 M OH

1.292 10 4
pot log OH log
pot 3.91

PH 14 3.91 10.01
3. What is the Kb for the equilibrium
CN- + H2O ↔ HCN + OH-

Kb I
LHCEL.jo
4. Calculate the [H3O+] in a 0.120M nitrous acid. The principal equilibrium is
HNO2 + H2O ↔ H3O+ + NO2 Ka= 7.1 x 10-4

HNozcaq I 430 t NOI

I 0 120
C x tx tx
E T x x x

7 1 d

Iffy
10

X 430 7 8.88 10 3

5. Calculate the [OH-] of a 0.0750 M NH3 solution . The predominant equilibrium is

NH3 + H2O ↔ NH4+ + OH Kb= 1. 75 x 105

NHat t off
NH3 I
I 0.075 O O

E É7s x

105
1.75
o.IT X
 1 14 10 3 OH
X
6. Calculate the pH of a bu er prepared by adding 10 ml of 0.10 M acetic acid to 20 ml of
0.10 M sodium acetate.

pit phat log

qq.ge
5
Ka 1.76 10
10 5 4.75
plea log 1.76

pH 4.75 t log
g
pH 505
7. Calculate the pH of a solution that is 0.200 M in NH3 and 0.300 M in NH4Cl . The Ka for
NH4+ is 5.70 x 10-10.

10
pH log 5.7 10 log

pH 9.07
Kc 242
1
32
Kc H2O t 0233
In

EYE
 c

Kc Mg 4 32

KC

EMEA
 Formic acid 430T HCoo
PhthalicAcid 430 10248042
Acetic acid H30t CH Coo
430 10033
fgiigimifj.tnIie 43010045
Bart OH
chlorousAcid 430 10032
Boricacid Haft 0102
13033
Hoot
copper il hydroxide at OH
Ammonia NH4t NHI

1 10 8 8 Basic
1 10 12M 2 Acidic

Ht and Oat are equal

Ht Oft
At L Ht
O

a
by

axon
or
gjff
a
4134370T Y.TL

next page's
 fifth
a ka

Ka 1 32 10 5

b na
841am
31
10
3 96 X 10

sisters
a na

9
Ka 1 02 X 10
acid base conacid conbase

base acid conacid conbase

acid base conbase conacid

 sp Agt 1z
b Ksp Agt 503
C
Ksp Agt A5043
d Ksp Pba CIF 2
a
Agrozest Agt t v03

Ksp Agt V03 J 7.1 10 4

Ksp 5.041 10 7

b Pb 103 2 Pb't t 2103

4.3 10 5
Ksp Pb't 103 72
Ksp 7.95 10 14

c Th Colt yes 5 That got

Ksp That OH 34 3.3 10 4

Ksp 3.91 10 18
a Ksp CAgt V05
0.05 7,1 10 4
Ksp 3.55 10 5

b Isp PS4 103 32

0.05 4.3 10 512
9.245 10
Ksp
C Ksp that OH 34
0 05 3.3 10 4 4
Ksp 5.93 10 16
4 Ba NO322 Ba't t 2ND
0,02 0.02 210.02

Ba 10372 5 Bat t 2103

CBazty o.jp
Ksp Bart 103 3 1.57 10 9

Ksp C 0215 2512 1.57 10 9

5 1.4 10 4
 3 Fe OH Cs 3N9N03Cag 5 Fe OH es
3 241013Calf t
313950419874noprecipitate

p.jjIjj
3 2 Caz 04726 6 Nacl aq 9 Ca Poy i
bbsoyes

1.0488 10 39
1398047 5mg
4
2 447 10 3 9 2

2 Ksp PbF 5042 3 1.25 10 4

Ksp 1 563 10 8
3 Ksp Cart 5042 7 2.4 10 5
10
1 89 0.6679
FIT 4.9
3mg I
4 9 Fez 40373 2Fe3t t 3032
Ksp Fest 2 63273

b La 10373 0 193T t 3103

Ksp 2193 3 103 73

c Mn OH z Must 204
Ksp My Zt OH 32

d Pb 804 5 Pba 5042

Ksp Pba 5042