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Adv Paper 2 (03.05.2024) - 1
Adv Paper 2 (03.05.2024) - 1
Adv Paper 2 (03.05.2024) - 1
MOCK TEST
JEE (Advanced)
(03.05.2024)
PAPER – 2
General Instructions:
1. Part–A (01 – 07) contains 7 multiple choice questions which have only one correct answer.
Each question carries +3 marks for correct answer and –1 mark for wrong answer.
Part-A (08 – 14) contains 7 multiple choice questions which have one or more than one
correct answer. Each question carries +4 marks for correct answer and –2 marks for wrong
answer.
Partial Marks +1 for each correct option provided no incorrect option is selected.
Part–A (15 – 18) contains 2 paragraphs. Each paragraph is having 2 multiple choice questions
having 4 options with only one correct answer. Each question carries +3 marks
for correct answer. There is no negative marking.
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2
Physics SECTION – I
PART – A
(One Options Correct Type)
This part contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. In the Young’s double slit experiment using a monochromatic light of wavelength , the
path difference (in terms of an integer n) corresponding to any point having half the peak
intensity is
(A) (2n 1) (B) (2n 1)
2 4
(C) (2n 1) (D) (2n 1)
8 16
2. The speed of a wave on a string is 150 m/s when the tension is 120 N. The percentage
increase in the tension in order to raise the wave speed by 20% is:
(A) 44% (B) 40%
(C) 20% (D) 10%
R
3. A frictionless tunnel is dug along a chord of the earth at a perpendicular distance
2
from the centre of earth (where R is radius of earth). An object is released from one end
of the tunnel. The correct graph, showing the variation of acceleration of particle with its
distance r from centre of earth is
a a
(A) (B)
r r
R R R R
2 2
a a
(C) (D)
r r
R R R R
2 2
Space for Rough work
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4. A closed organ pipe of length L is vibrating in its first overtone. There is a point Q inside
the pipe at a distance 7L/9 from the open end. The ratio of pressure amplitude at Q to
the maximum pressure amplitude in the pipe is
(A) 1 : 2 (B) 2 : 1
(C) 1 : 1 (D) 2 : 3
6. When the electron in a hydrogen atom jumps from the second orbit to the first orbit, the
wavelength of the radiation emitted is . When the electron jumps from the third to the
first orbit, the wavelength of the radiation emitted as
9 4
(A) (B)
4 9
27 32
(C) (D)
32 27
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8. A bimetallic strip is formed by two identical strips, one of copper and the other of brass.
The coefficients of linear expansion of the two metals are C and B . On heating, the
temperature of the strip goes up by T and the strip bends to from an arc of radius of
curvature R. Then R is
(A) proportional to T (B) inversely proportional to T
(C) proportional to B C (D) inversely proportional to B C
9. Two parallel long straight conductors lie on a smooth horizontal surface. Two other
parallel conductors rest on them at right angles so as to form a square of side a initially.
A uniform magnetic field B exists in vertical direction. Now all the four conductors start
moving outwards with a constant velocity v. The induced e.m.f. e and induced current i
will vary with time t as
e
e
(A) (B)
t
t
i i
(C) (D)
t t
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11. In a thermodynamic process Helium gas obeys the law TP2/5 constant. If temperature of
2 moles of the gas is raised from T to 3T, then
(A) Heat given to the gas is 9 RT
(B) Heat given t the gas zero
(C) Work done by the gas is 6RT
(D) VdP for the process in the given temperature range is 10RT
12. Sounds from two identical sources S1 and S2 reach a point P. when the sounds reach
directly and in the same phase the intensity at P is l0. The power of S1 is now reduced by
64% and the phase difference between S1 and S2 is varied continuously the maximum
and minimum intensities recorded at P are now lmax and lmin
(A) lmax 0.64 l0 (B) lmin 0.36 l0
(C) lmax / lmin 16 (D) lmax / lmin 1.64 / 0.36
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14. A cannon shell is fired to hit a target at a horizontal distance R, however it breaks into
two equal parts at its highest point, one part returns to the cannon. The other part
(A) will fall at a distance R beyond target (B) will fall at a distance 3R beyond target
(C) will hit the target (D) have nine times kinetic energy of first
This part contains 02 paragraph each describing theory, experiment, data etc. Four questions relate to
the paragraph. Each question of a paragraph has Only One correct answer among the four choices
(A), (B), (C) and (D).
16. The potential of the sphere when emission of photoelectrons will stop is
(A) 0.7 V (B) 0.5 V
(C) 0.6 V (D) 0.8 V
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Chemistry SECTION – II
PART – A
(One Options Correct Type)
This part contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. O
i SOCl
2
Product Major is
OH 2 2
ii CH N
Ph Me iii Ag2O
iv EtOH
O
OEt
(A) (B)
OEt Ph Me
Ph Me
OEt OH
(C) Ph Me (D) Ph Me
O O
2. Which one of the following reagent can be used for differentiating the Cu2+ and Bi3+?
(A) H2S gas in presence of dil HCl (B) NH4OH(excess)
(C) K4[Fe(CN)6] (D) (B) and (C) both
O
HCl Cat.
3. X
The compound[X] is
O O
(A) (B)
O
(C) (D)
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5. The pair of compounds having the same hybridization for the central atom is
(A) [Cu(NH3)4]2+ and [Ni(NH3)4]2+ (B) [NiCl4]2– and [PtCl4]2–
2+ 2+
(C) [Cu(NH3)4] and [Zn(NH3)4] (D) [Co(NH3)6]3+ and [Co(H2O)6]3+
M
OH
H 3
I/Na
C
N OH
CH
2N N
2
(A) H3C
M= N=
N OH N OCH3
(B)
M= N=
N OCH 3 N O
CH3
(C)
M= N=
N O N OCH3
CH3
(D) H3C
M= N=
N O N OH
CH3
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7. The highest occupied MO in N2 and O 2 respectively are (take x-axis as inter nuclear
axis)
(A) 2px, 2py (B) 2py, 2pz
(C) 2px, 2px (D) 2py, 2pz
9. Which of the following statements is/are true about the transition metal alkene
complexes?
K [Pt Cl3C2H4]
(A) Back bonding weakens the double bond of the alkene
(B) bonding and back-bonding synergistically strengthen metal alkene interaction
(C) Electron withdrawing substituents on alkene reduce back bonding
(D) –acidic co-ligands on metal strengthen back bonding
11. Which of them can act as oxidizing agent in acidic as well as in alkaline medium?
(A) KMnO4 (B) K2Cr2O7
(C) H2O2 (D) Cl2
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12. In which of the following reactions benzaldehyde will form in final product.
CN CH3
(A) (B)
SnCl HCl CrO Cl /CS
2
2 2
H O
2
H O 3 3
OH
CO HCl
(C)
Anhyd.AlCl /CuCl
(D)
3 KOH/
CCl4
H
13. A dilute solution contains ‘t’ moles of solute X in 1 kg of solvent with molal elevation
constant Kb. The solute dimerises in the solution according to the following equation. The
degree of association is .
2X X2
2 K b t Tb
(A) The degree of association
KbT
(B) The molecular mass observed will be lesser than actual molecular mass
(C) The colligative properties observed will be Tb obs < Tb theoretical ; Tf obs < Tf theoretical;
P obs < Ptheoretical
K K t Tb
(D) The equilibrium constant for the process can be expressed as: K b b 2
2Tb K b t
14. The correct statements about the following reaction are
CH3
2 6 1B H CH3 COCl/Pyridine H3 O
2 H O /OH
X Y Z Acetic acid
2 2
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This part contains 02 paragraph each describing theory, experiment, data etc. Four questions relate to
the paragraph. Each question of a paragraph has Only One correct answer among the four choices
(A), (B), (C) and (D).
MnO2 is the most important oxide of manganese. MnO2 occurs naturally as the black coloured
mineral pyrolusite. It is an oxidizing agent and decomposes to Mn3O4 on heating to 530oC. It is
used in the preparation of potassium permanganate and in the production of Cl2 gas. Over half
a million tons per year of MnO2 is used in dry batteries.
16. In which of the following species, the colour is due to charge transfer.
(I) [Mn(OH)4]2– (ii) MnO24 (iii) MnO2 (iv) KMnO4
(A) I, II, III correct (B) II, IV are correct
(C) I, III are correct (D) only IV is correct
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Acid-base indicators are either weak organic acids or weak organic bases. Indicators change
colour in dilute solution when the hydronium ion concentration reaches a particular value. For
example, phenolphthalein is a colourless substance in any aqueous solution with pH less than
8.3. In between the pH range 8.3 to 10, transition of colour(colourless to pink) takes place and if
pH of solution is greater than 10 solution is dark pink. Considering an acid indicator HIn, the
equilibrium involving it and it’s conjugate base(In–) can be represented as:
HIn
H In
acidic form basic form
In
pH of solution can be computed as: pH pK In log
HIn
In general, transition of colour takes place in between the pH range, pKIn 1.
17. An indicator is a weak acid and pH range is 4.0 to 6.0. If indicator in 50% ionized in a
given solution, then what is the ionization constant of the acid?
(A) 10–4 (B) 10–5
–6
(C) 10 (D) None of these
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PART – A
(One Options Correct Type)
This part contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1.
If roots of quadratic equation x 2 a2 7 x 15a 0 lie on either side of 2, then
complete set of values of a is:
9
(A) (–2, 4) (B) 2,
2
9 3
(C) , 2 (D) , 6
2 2
2. Consider a triangle ABC and let a, b and c denote the lengths of the sides opposite to
vertices A, B and C respectively. If a 1,b 3 and C 60o , then sin2 B is equal to:
27 3
(A) (B)
28 28
81 1
(C) (D)
28 3
B C
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nxn1 n 1 xn 1
5. lim where n 100 is equal to:
x 1
e x
e sin x
5050 100
(A) (B)
e e
5050 4950
(C) (D)
e e
x 3/5 if x 1
6. Let f x 3
then the number of critical points on the graph of the
x 2 if x 1
function is:
(A) 1 (B) 2
(C) 3 (D) 4
7. The equation to the orthogonal trajectories of the system of parabolas y ax2 is:
x2 y2
(A) y2 c (B) x 2 c
2 2
x2 y2
(C) y2 c (D) x 2 c
2 2
Space for Rough work
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x dx
9. x 4
equals:
x2 1
2 2x 2 1 1 1 2x 1 1 2x 1
(A) tan1 C (B) tan tan C
3 3 3 3 3
1 2x 2 1 1 1 2x 1 1 2x 1
(C) tan1 C (D) tan tan C
3 3 3 3 3
Where C is an arbitrary constant.
x 3 5x 2
10. The co – ordinates of the point (s) on the graph of the function, f x
7x 4
3 2
where the tangent drawn cut off intercepts from the co – ordinate axes which are equal
in magnitude but opposite in sign, is:
8 7
(A) 2, (B) 3,
3 2
5
(C) 1, (D) none of these
6
x 1
11. Let f x then which of the following is correct?
x2
(A) f x has minima but no maxima.
(B) f x increases in the interval (0, 2) and decreases in the interval ,0 2, .
(C) f x is concave down in ,0 0,3
(D) x = 3 is point of inflection
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12.
If 2xy dy x 2 y 2 1 dx, y 1 0 and y x 0 3, then x 0 can be:
(A) 2 (B) –2
(C) 3 (D) –3
13. A line L passing through the point P (1, 4, 3), is perpendicular to both the lines
x 1 y 3 z2 x 2 y 4 z 1
and .
2 1 4 3 2 2
2
If the position vector of point Q on L is a1,a2 ,a3 such that PQ 357, then
a a 2 a3 can be:
(A) 16 (B) 15
(C) 2 (D) 1
This part contains 02 paragraph each describing theory, experiment, data etc. Four questions relate to
the paragraph. Each question of a paragraph has Only One correct answer among the four choices
(A), (B), (C) and (D).
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16. If both roots of the equation f x 0 lies in interval 0, , then range of a, is :
2
(A) , 2 (B) , 2
3
(C) 0, (D)
6x 2 13
Let f be an even function satisfying f x 2 f x 2 x R and
x 2
3x, 0 x 1
f x
4 x, 1 x 4
[Note: [y] denotes greatest integer function of y.]
17. The area bounded by the graph of f x and the x – axis from x = –1 to x = 9 is:
31
(A) (B) 15
2
15
(C) 12 (D)
2
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FIITJEE MOCK TEST
Q. Q. Q.
PHYSICS CHEMISTRY MATHEMATICS
No. No. No.
1. B 1. C 1. D
2. A 2. D 2. A
3. D 3. C 3. D
4. A 4. C 4. D
5. B 5. A 5. C
6. C 6. C 6. C
7. C 7. A 7. A
8. BD 8. ACD 8. AC
9. AD 9. AB 9. BC
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FIITJEE
MOCK TEST
JEE (Advanced)
(03.05.2024)
PAPER – 2
PART – A
1. B
2
Sol. = x = (2n 1)
2
2. A
T 6V
Sol. v V'
5
T' 36
V' T' T
25
% T = 44 %
3. D
Sol. Let mass of the earth is Me and mass of object is m.
GMem A
Force on object at A r towards centre.
r
3 Re
R
2
R2
r2
GMem 4
Force on object along the tunnel 3
r
R r
GM R2
Acceleration of object along the tunnel 3 e r 2
R 4
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4. A
Sol. Pm = 2P0 cos kx (assuming closed end as origin)
7L 2L
At point Q, x = L
9 9
2 2L
Pm = 2P0 cos P0
9
Required ratio = 1 : 2
5. B
mv 0 2mv 0
Sol. d=
qB 2qB
6. C
hc 1 1 3
Sol. R 2 2 R …(i)
1 2 4
hc 1 1 8
R 2 2 R …(ii)
' 1 3 9
' 3 9 27
, '
4 8 32
7. C
3 1
Sol. = ; V=8 ; m=
2 3
V V
1+m=
f 2R
8. BD
l
Sol. R
B C t
9. AD
d(emf ) d
Sol. Bu = constant
dt dt
Bu
i= = constant
10. AC
Sol. All the mass defect will convert into KE of -particle.
11. BCD
Sol. TP2/5 = constant
PV 5/3 = constant or P3/5 V = k
This an adiabatic process.
H = 0
Work done = –U = 6RT
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k dP nRT
VdP P 3/5
= 10 RT
(5 / 2)
12. AC
Sol. Let I be the power of source S1 and S2.
2
Initially Io = 4I, finally Imax = I 0.36I 2.56I
2
and Imin = I 0.36I 0.16I
13. ABCD
Sol. y = 2a cos (t + ) cos (Kx) comparison with given equation gives
2 1
K 10 m
5
= 2f = 50 f = 25 Hz
v = 5 ms–1
at x = 0.15 m
cos (10 × 0.15) = cos (1.5) = –1 for all t
at x = 0.3
cos (10 × 0.3) = cos 3 = – 0 for all t
14. AD
Sol. At highest point, linear momentum
2 mv = mv1 – mv
v1 = 3v
At highest point, velocity of other part after explosion = 3v
Centre of mass of particles will be at a distance R from initial point on ground.
15. A
hc 12408
Sol. Work function of the metal () = 2.5 eV
green 4963
40
No. of photon emitted from the power source per unit time = 1020
2.5 1.6 10 19
photons
1020 (1 102 )2
No. of photons incident on the metallic surface per unit time = 2.5 1015
4 (1)2
photons
No. of photoelectrons coming out from the metal surface per unit time
2.5 1015
= 6
= 2.5 × 109 photoelectrons
10
16. B
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hc
Sol. The emission of photoelectron will stop when eV , where V is the potential of
violet
sphere.
12408
2.5 eV ; V 0.5 V
4136
17. C
PB
Sol. TB TA 2T0
PA
13 13
1 1
(2T0 )V09 TC (2V0 )9 TC 25/9 T0
18. B
Sol. Heat is absorbed during the process AB and BC
3 3
Q AB R(TB TA ) = RT0
2 2
3 9 3
QBC R R (TC TB ) R (2 25/9 )T0
2 4 4
3 15
Qabs (4 25/9 )RT0 RT0 [25/9 1.5]
4 8
3 21
Qrej (2 25/9 )RT0 RT0
8 16
3
QCD R(TD TC )
2
3 9
QDA R R (TA TD )
2 4
9 W
W RT0 ; 30%
16 Qabs
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Chemistry SECTION – II
PART – A
(One Options Correct Type)
This part contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. C
Sol. SOCl2
RCOOH
CH2N2
RCOCl
Ag2O
RCOCHN2 RCH C O
EtOH
RCH2 C O
OEt
R=
Ph Me
2. D
Sol. Fact based.
3. C
Sol. O
H
O O HO
H
4. C
Sol. Au 4H NO3 4 Cl
AuCl4 NO 2H2O
3PtCl62 4NO 8H2O
3 Pt 16 H 4NO3 18 Cl
5. A
Sol. Fact based.
6. C
Sol.
CH3I
NaOH
N OH N O
CH3
CH2 N2
N OH N OCH3
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7. A
Sol. For N2
2PY2
KK 2s2 * 2s2 2PX2 2PX2
2PZ2
For O 2
* 2 1
KK 2s2 * 2s2 2PX2 * 2PY2 2PY * 2PZ
2PZ 2PZ
8. ACD
Sol. (B) is incorrect, correct order is Cl2 > Br2 > F2 > I2.
9. AB
Sol. Fact based.
10. ABD
Sol. O2 4H 4e at anode
(A) 2H2O
(B) Aq. AgNO3 at anode 4 OH 2H2O O 2 4 e
(D) Aq. NaOH at anode 4 OH 2H2O O 2 4 e
11. ACD
Sol. K2Cr2O7/H+ acts as oxidant not in basic medium, rest all acts as oxidizing agent in acidic
as well as alkaline medium.
12. ABC
Sol. (A) Stephan’s reduction, (B) Etard’s reaction, (C) Gattermann Koch synthesis
13. ACD
Sol. 2X
X2 i 1
1 2
2
tb 0.65
i 1
Kbt 2
t K t t b
1 b b
2 Kbt Kbt
2 K b t tb
A
Kb t
and as i < 1
MC
1 so MC < Mo
Mo
C.P obs
1 ...... C
C.P cal
14. AD
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Sol. CH3
2 6
1B H CH3 COCl H3O
2 H O /OH
X
Pyridine
Y Z Acetic acid
2 2
CH3 O
OH OC - CH3 OH
X Y Z
15. D
Sol. MnO 4 OH
MnO 2
16. D
Sol. KMnO4 is purple coloured due to charge transfer.
17. B
Sol. For 50% ionization(In–) = [HIn]
pH = PKIn
Thus PKIn= 10–5 (as pH = 5)
18. A
Sol. At midway pH = PKIn
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Mathematics SECTION – III
PART – A
(One Options Correct Type)
This part contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. D
Sol. f 2 0
3
a 6 2a 3 0 a ,6
2
2. A
12 32 c 2 C
Sol. By Cosine law, cos 60o
2.1.3
c 7
b c
Now, (By sine law)
sinB sinC b=3 a=1
3
3
b sin C 2 3 3
sinB
c 7 2 7
27 A c C
Hence, sin2 B
28
3. D
18
Sol. C3 3. 7C3 816 105 711
4. D
Sol. Clearly, f x x 1 As m 1, c 1
1 1 1
Now, tan tan1 tan1 tan1
7 8 18
1 1
1
tan tan1 7 8 tan1
1 1 1 18
7 8
15 1 3 1
tan tan1 tan 1 tan tan 1 tan1
55 18 11 18
3 1
1 1 2
tan tan1 11 18 tan tan1 f
1 3 1 3 3 3
11 18
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5. C
Sol. l lim
nx n x 1 x n 1
x 1
e x
e sin x
Put x 1 h so that as x 1,h 0
l lim
n
h.n 1 h 1 h 1 n
h 0
h
e e 1 sin h
n.h 1 nC1h nC2h2 nC3h3 ...
l lim
1 nC1h nC2h2 nC3h3 .... 1
h 0 eh 1 sin h
e h2
h h
n 2 nC 2 2n2 n n 1 n2 n n n 1
e 2e 2 e 2 e
If n 100
5050
l
e
6. C
Sol. A, B, C are the 3 critical points of y f x y
B C
x
0 1
2
7. A
dy y
Sol. 2ax 2x 2
dx x
dy 2y
dx x
dy x dy x
Now m 1 m
dx 2y dx 2y
x2
y2 c
2
8. AC
Sol. 2 cos 2 1 sin 2 5 sin2 2sin 3 0
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3
sin 1 or , now
5
3
If sin 1 cos 0 E 3; If sin
5
7
Hence E
5
9. BC
1
t
1 dt 1 dt 1 2 2 1 tan 1 2t 1
Sol. I . tan1
2 t t 1 2 1 2
2
3 2 3 3 3 3
t 2
2
4
1 2x 2 1
tan1 C
3 3
10. AB
Sol. Since intercepts are equal in magnitude but opposite in sign.
dy
1
dx P
dy
Now x 2 5x 7 1
dx
x 2 5x 6 0
x 2 or 3
11. BCD
2x x3 y
Sol. f ' x 3
and f " x 4 .
x x
1/4
x
O
1 2 3
12. AB
dy
Sol. 2xy x2 y 2 1
dx
dt
Put y 2 t, x x2 t 1
dx
dt t x 2 1
dx x x
1
I.F.
x
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t x2 1 1
Hence 2 dx x C
x x x
2 2
y x 1, C 0 as y 1 0
Now, y x 0 3
3 x 20 1
x 20 4
x 0 2
13. BD
x 1 y 4 z 3
Sol. Equation of the line passing through P(1, 4, 3) is: …….(i)
a b c
x 1 y 3 z 2 x 2 y 4 z 1
Since equation (i) is perpendicular to and
2 1 4 3 2 2
Hence 2a b 4c 0 and 3a 2b 2c 0
a b c a b c
2 8 12 4 4 3 10 16 1
x 1 y 4 z 3
Hence the equation of the lines is ………(ii)
10 16 1
Now any point Q on (2) can be taken as 1 10, 16 4, 3
2 2
Distance of Q from P (1, 4, 3) 10 16 2 357
100 256 1 2 357
1 or 1
Q is 9,20, 4 or 11, 12, 2
Hence a1 a2 a3 15 or 1
14. ABD
dy x ax
Sol. y
dx 1 x 2 1 x2
x 1
1 x2 dx log 1 x 2 1
I.F. e e 2
1 x2
y x
a 3/2
dx C
1 x2 1 x2
Let 1 x 2 2
2x dx 2 d
x dx d
y d a
Hence a 3 C
y a C
y a C 1 x2
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2
y a C2 1 x 2
C2 1 x 2 or C2 x 2 1
2 2
y a C2 x2 C2 or y a C2 x2 C2
2 2
y a x2 y a x2
1 or 1 Centre (0, a)
C2 1 C2 1
15. B
Sol. f x x 2 a 2 x a2 a 2 0 –2
f 2 0
2
4 2a 4 a a 2 0
a2 3a 2 0 1 a 2 a 1, 2
Not integral values of a.
16. D
Sol. Given, x 2 a 2 x a2 a 2 0
2
Now, D 0 a2 ………(i)
3
Product of roots > 0
a2 a 2 0, which is true a R ……….(ii)
and sum of roots 0
a 2 0
a 2 ……….(iii)
Equation i ii iii
a
17. B
1 1
Sol. Required area 2 4 3 2 1 3 15
2 2
18. A
Sol. f 89 f 67 f 46 f 1 f 3 f 2
3 1 2 4
f x 2 f x 6 f x f x 8
y
x
–4 –1 1 4
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