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Part 1 GOC
Part 1 GOC
PojariaibiLity effed
Note
CI- cffect) -partia
1 INDUCTEVE EFEECT
Partial) and (perm enent) displacem ent of sigma elecbon
elect neq ative CE.N) group or oto m
toards more
ch
s Tetuene)
Ans e ( ] L4J[ ( a a me*
Inductive efeck
No EN. differen eT eTfEE
neglegible .
C- effect i s
It ir eak effect poor efect (ar )
Net charge remains constant, ( Total charge same ET)
57 e F e c t is distanca dependent t
T effect
distan
eqson or Tnd u ctive effect
q Dterence
electronegativity (E-N
- d
cHF
cag
Differene Hybridsation stat
-6
e C CH CH CH2
(spa) sp ) sp (p*)
yu cgnht
EN Some Tmp CormpoundsLAT 7 Change
T
.
CH-CH sp 25. 2.48 A 5
3 5
50
3. CH EC
25.
3.5
Identfy the compound in ohich? effect present
t
SP
CH=CH tedH ay CHCH,~cI|
Br Br 67 CLCl
-gp sp
37
CH=cH
CH=CH
Ans
Ho 1[41 [
1Ypes at T- f e c t
(Cyanide /nibik )
e
Hologenso,t>be
og
3
-O)Y -CECH
7 NH2
-7
NO)
--C
-NH,7
OR
-0H)
-C=N 7
-c-NH>
COH7 NH
1queston
order o tqroup
CH2
CH
CH
-Ch CR
7
- cD7
CH, - T -P
HINT
-NH
-6H
less
*Applicationf Thductive ffect Cuestini aTiTp
(+- CT) Cr
CH- ipc
CH) (no effet)
tL T
kns + 1T
i iz itz iv
stabitlS
NoG:-
D H,DT
7
isotPes
C
H
D
+TT7 b>H
+I t t negle
+T:
a b7
iHC CH i CH= Cy
(- -)
()
tI efed lerr EN
| t I effect = more E N
EN
L adee
CH CH,| (
Satye)
11 b 1
CH-CM,- cH- (I 1)
Kc
am
istahe
117
Ans c® = *b>a
L
Ans C-stabildy I* t
- effect order NO2 7F 7CIy Br
LtI fpt ~da Br7c(7 F7NO2
Anr dy c>b>a
d'stana int)
r@
Stabilty |
a)
so laok at ha distancar."
[ e > by a
a
7b 7 C
4T c >bya j
6
10,) -I efect
rder NO CN7||
(0
CHa
TC a 7b>c
all
Angoc R>8
allep
*-I
Stabily fre radical -aT 21 c i
free radica BT 7it T
CH 3 H
CHa
CH,C 7
3
) 3uper 4 - deg rea)
Stabilty of C +
7 H
+tT +ITT
3) TI 372'7ic/ce
. der
Stabi 3°>2°7
cH
(E)
- I TtT -I tt - It
- I order a7b>c
I order cb> a
a7b7 e
CH C CH
7 7
ce
--T
-T11
7 E-CHc
Imp. X 47b i u
6 CHCH-cR b (dis tonu)
shron ohSTT
bh sbong Pers on aE pune * E and >TK
we PCrsmn
CeS
V E h a f
T WeaK 5trong IE. dt grop
E p l a n a t in i
Sarme
S
StanuE
cstaly* six a c by a
sqme period
- CH
3
+T ttTT +I f
3t) (21 )
cstuity +I d e r ay byc
1 rder =
c7 b> a
(sp3) (sp*) Cs
EN. sP >Sp*>sp
cspbilty
43
L
2c
ttabit e t'7273ec37
_lc
c7 ay
- T
e7
+
GHo
cfed
Stabilty of -r
t
-I order NOCN7 ST C
ns.