Generol Orgranie Chemistry

CBasic of organio Chemistrd

Electronie Pisplace mert Effect

Inductive effect (T)
(R qtrT TTa ame fr ETe
Resonance
Mesomerte Effect (M)
ut, tahir a diff. rT 31
. Hypevconjug'atian (1)

Reverse hYperconjugatin (R,4

SIR ffect
tho ffect for acid ty

ffect for basi sitY

permenent effe
7. ortho
Polarizatign fet
Pield ffect
St eric affect
L0 Elecbromerie eFfect (E
Tempora ry efte t
Tnducto meric effect

PojariaibiLity effed

Note
CI- cffect) -partia
1 INDUCTEVE EFEECT
Partial) and (perm enent) displacem ent of sigma elecbon
elect neq ative CE.N) group or oto m
toards more

IS knOn as Tndu ctive Ffect

EN SPsp7sp
to More E N.
CH CH CH= CH
(sp1) (sp) (spa

ch

TT Ke| EN arto m Partial r|

KT(partial) less EN. par tial
chare 3t17T 'f
 (
dentify the compound n which nductive ffect
present p d a l le)
E-diff.
pall)
7 st sp
SP-6
r e E N.
7 6Y

s Tetuene)
Ans e ( ] L4J[ ( a a me*
Inductive efeck
No EN. differen eT eTfEE

every e) hybndizh same

No 6-N. diff.

Some mp. Points about T-effect

It 13 parttel displacement o a e lectwn Ce)>therefore

Partia cha devlops ma adjacent atomn.

L+d-61

Ttis obsevved upto 3 carbonofter 3-canm the

neglegible .
C- effect i s
It ir eak effect poor efect (ar )
Net charge remains constant, ( Total charge same ET)

57 e F e c t is distanca dependent t

T effect
distan
 eqson or Tnd u ctive effect
q Dterence
electronegativity (E-N
- d

cHF
cag
Differene Hybridsation stat
-6
e C CH CH CH2
(spa) sp ) sp (p*)

aeffect /reason &2-<ffect devlope I

direct E N. diff. ta or direct F . differena

T (meanr hbridin accorcding T

yu cgnht
EN Some Tmp CormpoundsLAT 7 Change
T

Compound Hybnidisation Y.S EN.

.
CH-CH sp 25. 2.48 A 5

CH2 CH sp 33.337. 2F5

3 5
50
3. CH EC

25.

3.5
 Identfy the compound in ohich? effect present
t
SP
CH=CH tedH ay CHCH,~cI|

CH-CH, OH Ho(all are Sp)

Br Br 67 CLCl

-gp sp
37
CH=cH
CH=CH

Ans

Ho 1[41 [

1Ypes at T- f e c t

efpect [epE - fet CEE]

4 Effect| Flectron oithdraning effeck"

The Ohich attract the sigma electron (
withdroaw the 6-e) s non as
anup - I effkå
4TT ffe ct Cs-e
[ ? chemistry t e
minus charge TET& thrt
order o T roup
H I N T

(Cyanide /nibik )

e
Hologenso,t>be
og
3

-O)Y -CECH
7 NH2

-7
NO)

--C
-NH,7
OR
-0H)
-C=N 7

-c-NH>

alkyne amine CPh] alkene

7H(last o efect A)
 STE
fl Cmotivale studev)
Nole N CEN - 2-u> Haloqen CErcl>By 7I) 7

COH7 NH

1queston

-cffect (or) E-p. CElecton Donating effot/eroup

The 9 roup hich repel 6eis knon as

+groups
tL-gn
ffect is Knon as tI effect
F electon repel >donat
meais AT group
anrelease nT

order o tqroup
CH2
CH
CH
-Ch CR
7
- cD7
CH, - T -P
HINT
-NH
-6H

less
*Applicationf Thductive ffect Cuestini aTiTp

stabil of carbocatim fect

-ffect
t 1 cstability t
-T
HNT:
+ Group l e s s E-. gonp atom carbm)
- 1 CP
m v e E N.
gropkom O NMalogen

TTUAdl er 4T4T rder ro kh veywel)

(+- CT) Cr
CH- ipc
CH) (no effet)
tL T
kns + 1T
i iz itz iv

stabitlS
NoG:-

D H,DT
7
isotPes
C
H
D

+TT7 b>H

+I t t negle
+T:

a b7

iHC CH i CH= Cy

(- -)
()
tI efed lerr EN
| t I effect = more E N

EN
L adee
 CH CH,| (
Satye)

11 b 1

CH-CM,- cH- (I 1)
Kc

EN. atem t ef(ecd

T - r der a rl>c
Áns + rder a c7b7a

c tE +T 3'c >a'c 7ac

stability of &

7Ans = azbe cY ayb

am
istahe
117

Ans c® = *b>a
L

+ effect| Carboca tien

staka
A)
- a < (-kn,-H,J <(c0 F,-CHBen
Cdif.all)in Sn me
inall)
b) (C) (4)
wttnimen

Ans C-stabildy I* t
- effect order NO2 7F 7CIy Br
LtI fpt ~da Br7c(7 F7NO2
Anr dy c>b>a

d'stana int)
r@
Stabilty |
a)

g r u p ir f same in atl " F - Iefeet Il Ten1

so laok at ha distancar."

[ e > by a
a
7b 7 C
4T c >bya j

6
10,) -I efect
rder NO CN7||
(0

khr co stailify t -T >b>c

CHa

TC a 7b>c

all
Angoc R>8
allep
*-I
Stabily fre radical -aT 21 c i
free radica BT 7it T
CH 3 H
CHa
CH,C 7

3
) 3uper 4 - deg rea)

Stabilty of C +

7 H

+tT +ITT

3) TI 372'7ic/ce

. der

Stabi 3°>2°7

cH
(E)
- I TtT -I tt - It

- I order a7b>c

I order cb> a

tollao nme bndhy

 -CA)
I d e c - NO CN7 Ha logen (ci

a7b7 e

CH C CH
7 7
ce
--T
-T11

7 E-CHc

Imp. X 47b i u
6 CHCH-cR b (dis tonu)

NCH2 - ch, CCH cH

34312 Weak gronp e ol 5T f Strvng T E. qm)

oTT

shron ohSTT
bh sbong Pers on aE pune * E and >TK

we PCrsmn

oik UTSTT aTPT

 chemisby T K( TU
e.&.

CeS
V E h a f
T WeaK 5trong IE. dt grop

oi domin dver > ne f.t r a

i. TJo Weq T.E. amnp

distana or4T TT (sarne

But cmapt
crefer eZFL-
H
8

E p l a n a t in i

same peri od )* eft hight

ele mentr
These are C N oF
Same perto U Cmept o TTT ?
Fa
s omr e perno4
carbani on E N E-N ord er - FO > N7
element
stabilitY
T

Sarme

SI2e stab1lity of carbanion

fo
Lamup evnen
elemei t t * 7
for sam
car

si tser doon the gp sie TzBr 7cl7F

e SH Se H
S
Se

S
StanuE

cstaly* six a c by a
 sqme period

left Right ENT1se

Cstability N (sAmd perisd enentr)

- CH
3
+T ttTT +I f
3t) (21 )

cstuity +I d e r ay byc
1 rder =
c7 b> a

eHCH L CH CHa CHE

(sp3) (sp*) Cs
EN. sP >Sp*>sp

cspbilty

43
L
2c

ttabit e t'7273ec37
_lc

(conept cha rge present on ore E N. atom i

always mre stabe,

15 Corect decreasing
grder
ofstability Carbanien

c7 ay
- T
e7

+
GHo
cfed
Stabilty of -r
t
-I order NOCN7 ST C

ns.