Acidity easitity

Understand conapbJ
]crditY also caled as" Acidie streng th/Audie nature

HDonor Aci Lone pair donor Base

acceptor Acid
Acceptor Base Cpne pair

"Bronst ed oorY HENT

(pois Concapt
proton theory Lone pair
(H

these are -Cohe pt to identify a cids f base.

H-A tA

ad F coriugate base

because {

ef
azET a T TerT ) conjugrat
3 5ATh ar qT
and7 acid cT Conjugatt
Basee
base of H-A.
7means 1S Conugat

catt 34 T Aud ottaf ST

me an a n y s ofub
a HT T and Conugat bare T

e
Hs04 H
Conj u gata base
Aci
H504 s conjugatt base oHs0 au".
(Nott es)
Conugata base Stable TTT/) T a r

Conugate base ST
OT auidie TSTT|

b ase atrT a kdd strong weat

conjugate

more the
conug at bare 3fatT 3f0T add
3tOTT HA)

3 3oT TT sf Reackion
or ward directjm move
H-A HT
+A
fovw ard dire
ction move
n 7
HT ton a>T> 3iK \tOT T E aT
3c5 3T acha H-A aud e13T||

Moretabk the conjugat bqse more yei l be the toma d

rea com

tohich resulty m re
audi
nature ot HA

conjugatt base
mre Stable
more audie (H-A )
acd
()

Q.Compare ad dity auidic hature Ha H-f

H,o

H-F
 10

H, , uget base
H-F
Cmore stabe)
(me Adie)

stabildy im o Oc (same perio eft >right

stabilityE-N(for some period)

move ft to right E N. Ttt> F mr

Awe

EN. anoy230 stabiLt &

mor EN ement harae mwe stablu 81ET & *
nd Tueof STG(stable) 3et audity

Atdt HEH,o

23 Acidic order

CHa NH HO H-F

H O

stabi lit ofce < conju9

base

Stailitp Same period E N.

eft right P T F . N 1T
nsHF> H,o HH H
Mre stab the
Cona Move acidic ti
base
ad

*o for Penod7 E N.

er
9 5iz ore stbla conjugati (or)
charge
 H-F H-c H Br

Br
Conjujat base

stilty F ce B
stability ce ]

Ans Aci dity H-I> H-Br > H - 7 f-F

o a f nf Same part qE a )
Acidic rder diff. part T|
7 c)-CH,-CHa-OH c7 CMCHo
NC-C4,o
-Tt1T ( Samepert

Acidienabured-I fect H T N T

tI effedt|

Pridici_ka7b> d
L me o T a n sans. o f Z(asy metthod)

Coni
metrode c j gat base*

-CHCH-d -CH- cM-o Ceu-o

7
71-
11
c s t a l rly -L < E N
 11

Árranqe tm the oxder ofdec reasira)

2
(F)-CH-CH,oo RCW-Coof
F-cH Cu,-Co Cet-cH-CH2-cr

Fcu,- Coo
c H - CepJ Cer-cH2 CHzce
****
Comept Xcidic naure k a
v T 3T Hqma]
LAcidie nature f Ka

Acidy -T effet - FrcI78rz I

+Iffect

order 7b7 7 4

Aadity rder b y ayd

Cmcept
ACid ic strengthK Ko Acidic strength & 1

pka
Note
bc
Acidic der
a
d, a7b pka C7b7a

k dissociation con st antauf Hda aud n

brcak 7 a o accha aud I 3ctot arch
break TT( means diss out t r |

. hic ofthe foloroing ai has telonoest pke - value

2
b7 CH-CR2
O-1 (HO-
dy CH---4

1 rder- N o 7 CI ** ( g e n e r a l
Acidity -1| rder)
ka +
-T 7a c7

Aity ta d7a 7c >b

Pka lesf
cad
a u d i c

a u l i c
Kdrite the Corect Order Ka-value
Cai die)
ooM)
7 (cooR) 7
(CooH

Cone pt
No. o COof qup Audie nature

aidity Cka) noturelo r «fet

+T ffect t

Aidt
Ckel
b cyd7 a

nature /easie Steng/Besigit

he pair of electon is
The tendeny tdonate
knoun as
basicity
Basic streng th e density fan atom me pa

lone pair SHm narture

naue T iTE
meanfr Tst UG
Basic*
we Can say re . meanr (more bqsi

strength a tI 2ffect|
asi
ffet|

. COmpare basirity )

CH CH2-CH -

N2
y(CCH2 -CH HH lCHaNH,
Csame part) t -L
Bcsicty Ktt
- Banici ovdera 724**
 +I11t
+1 1

Basic ity tI
Ant a7kr
distana If|

B asiuy +
I

Ans: c 7 b z a

c -H-N
(Same part)
p Sp3

Basicity *tI (est EH)

-L(move E N) -zE.N p>ip*zsp3
I ordr az b c
2ogiuty cya C6 N.)
T rder c7b a

dustaneSame
different I order - No,> -cN -Cl7 -cRg
+Ioder -CH27 e7 CN NO

-
4 747 74)
 Compare basiity ? kb value rder
i i Cnare E )

Coept
basic st engte kb
LesENi mre basie

Basic streng th
CBasieity) PR-

m move E N. atorm ir ala(s

Neqative charoe present
mave stable and ess base

Ans E N
Cleft right PT.)
MOre
stabiuty st TCE N)
fI Clesse N')

Stability c Er o 7 HH2 7

Basibity
stabilityf
Basicy AnsCM 7 NR7 O7
(kL)

T
basie
Less E N. more

o1Ttr
Periods T
4 E N. concept
g ep
Ans periods

Basicrty rder ? c F
HEST
Br Si 11
CmesiefBrrEi
stabilily EN I
periog

staility dsi2( sam

BcF
starility Basici
Basictye
 Nota T% qroup
A EN. aTTT Cmupt T oSE
7f1

roup Baric strength 1

S13

Basic order
basiguby od tiesr E.N.)
I mare 6 M)
N
Basie brength = sp737p
Ste 6P3
P
N N

Ca) (lb)
b u t t (a) f (e)
tT C) is least basic
step a

(a) (C)

Basi dty FL Ca) = t I

Ca) more basic than ( b)
Cb) -T

ns. Basiciby : acy b