1

Yakeen NEET 2.0 (Alpha)

Solution DPP-04

1. Which of the following is not a characteristic of 6. Which of the following is the correct mathematical
ideal solution? expression for ideal solution of A and B?
(1) Vmix = 0 (2) Smix = +ve (1) P = PA XA + PB XB
o o

(3) Hmix = 0 (4) Gmix = +ve (2) P  PA XA + PB XB

o o

(3) P  PA XA + PB XB
o o
2. Solutions in which both the component has nearly
same polar nature as well as molecular size will (4) None
form.
(1) ideal solution (2) non-ideal solution 7. A solution which boils at constant temperature is
(3) Both (1) & (2) (4) None of these called:
(1) Azeotrope (2) Ideal solution
(3) Saline water (4) Alkaline solution
3. The diagram given below is a vapour pressure
composition diagram for a binary solution of A and
8. A mixture of water and benzene is a/an:
B. (1) ideal solution
(2) non-ideal solution with positive deviation
(3) non-ideal solution with negative deviation
(4) none of these

9. An azeotropic mixture of two liquids boils at a lower

temperature than either of them when:
(1) it is saturated
In the solution, A – B interactions are: (2) it does not deviate from Raoult’s law
(1) similar to A – A and B – B interactions (3) it shows negative deviation from Raoult’s law
(2) greater than A – A and B – B interactions (4) it shows positive deviation from Raoult’s law
(3) smaller than A – A and B – B interactions
(4) unpredictable 10. Which of the following is not a characteristic of non-
ideal solution with positive deviation?
4. Solution of methanol and ethanol will form: (1) Vmix > 0 (2) Hmix > 0
(1) ideal solution. (3) Smix < 0 (4) Gmix < 0
(2) non-ideal solution with positive deviation.
(3) non-ideal solution with negative deviation. 11. A solution of strong acid and water is an:
(4) none (1) ideal solution
(2) non-ideal solution with positive deviation
5. A solution consists of two components X and Y. (3) non-ideal solution with negative deviation
Which of the following relation of inter action (4) none of the above
between molecules is true for ideal solution of X and
Y? 12. A non-ideal solution with negative deviation are
called:
(1) X – X = Y – Y  X – Y
(1) maximum boiling azeotropes
(2) X – X  Y – Y = X – Y
(2) minimum boiling azeotropes
(3) X – X  Y – Y  X – Y (3) both (1) & (2)
(4) X – X = Y – Y = X – Y (4) none of these
 2

13. Which of the following is a characteristic of non- 21. The molarity of a solution of sodium chloride (mol
ideal solution with negative deviation? wt. = 58.5) in water containing 5.85 g of sodium
(1) Vmix < 0 (2) Hmix > 0 chloride in 500 mL of solution is:
(3) Smix < 0 (4) Gmix > 0 (1) 0.25
(2) 2.0
14. Colligative properties of the solution depend upon: (3) 1.0
(1) nature of the solution (4) 0.2
(2) nature of the solvent
(3) number of solute particles 22. Equal weight of NaCl and KCl are dissolved
(4) number of moles of solvent separately in equal volumes of solutions then
molarity of the two solutions will be:
15. If 0.4 g of NaOH is present in 40 mL of solution. (1) Equal
What is the molarity and normality of solution? (2) That of NaCl will be less than that of KCl
[Molecular mass of NaOH = 40] (3) That of NaCl will be more than that of KCl
(1) 0.25 N; 0.25 M (2) 0.025 N; 0.025 M solution
(3) 2.5 N; 2.5 M (4) 0.50 N; 0.50 M (4) That of NaCl will be half of that of KCl
solution
16. Find out the molarity of 93% (w/w) H2SO4 (density
= 1.84 g/ml). 23. In a solution of 7.8 g benzene (C6H6) and 46.0 g
(1) 174.6 (2) 17.46 M toluene (C6H5CH3) the mole fraction of benzene is:
(3) 1.746 M (4) All of these 1 1
(1) (2)
6 5
17. A 100 cm3 solution is prepared by dissolving 2 g of 1 1
(3) (4)
NaOH in water. Calculate the normality of the 2 3
solution.
(1) 1 N (2) N/2 24. An X molal solution of a compound in benzene has
(3) 0.5N (4) Both (2) and (3) mole fraction of solute equal to 0.2. The value of X
is:
18. Find the percentage by mass of aspirin in the (1) 14 (2) 3.2
solution prepared by dissolving 3.65 g of aspirin in (3) 1.4 (4) 2
25.08 g of water.
(1) 12.7% (2) 1.27% 25. A 500 g tooth paste sample has 0.02 g fluoride
(3) 0.127% (4) 0.0127% concentration. What is the concentration of fluorine
in terms of ppm level:
19. A solution was prepared by adding 125 cm3 of (1) 250 (2) 40
isopropyl alcohol to water until the volume of the (3) 400 (4) 1000
solution was 175 cm3. Find the volume/volume
percent of isopropyl alcohol in the solution. 26. H2O2 solution used for hair bleaching is sold as a
(1) 71.4% (2) 7.14% solution of approximately 5.0 g H2O2 per 100 mL of
(3) 0.714% (4) None of these the solution. The molecular mass of H2O2 is 34. The
molarity of this solution is approximately:
20. Calculate the mole percentage of CH3OH and H2O (1) 0.15 M
respectively in 60% (by mass) aqueous solution of (2) 1.5 M
CH3OH. (3) 3.0 M
(1) 45.8, 54.2 (2) 54.2, 45.8 (4) 3.4 M
(3) 50, 50 (4) 60, 40
 3

27. Benzene and toluene forms an ideal solution. 29. At 40° C, vapour pressure in torr of methanol and
Vapour pressure of pure benzene is 100 torr while ethanol solution is P = 119x + 135, where x is the
that of pure toluene is 50 torr. If mole faction of mole fraction of methanol. Hence:
1 (1) vapour pressure of pure methanol is 119 torr
benzene in liquid phase is . Then calculate the
3 (2) vapour pressure of pure ethanol is 135 torr
mole fraction of benzene in vapour phase. (3) vapour pressure of equimolar mixture of each is
2 1 127 torr
(1) (2) (4) mixture is completely immiscible.
3 2
2 1
(3) (4)
5 3

28. Mole fraction of the toluene in the vapour phase

which is in equilibrium with a solution of benzene
(p° = 120 torr) and toluene (p° = 80 torr) having 2.0
mol of each is:
(1) 0.50 (2) 0.25
(3) 0.60 (4) 0.40
 4

Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (4) 16. (2)
2. (1) 17. (4)
3. (3) 18. (1)
4. (1) 19. (1)
5. (4) 20. (1)
6. (1) 21. (4)
7. (1) 22. (3)
8. (2) 23. (1)
9. (4) 24. (2)
10. (3) 25. (2)
11. (3) 26. (2)
12. (1) 27. (2)
13. (1) 28. (4)
14. (3) 29. (2)
15. (1)

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Yakeen NEET 2.0 (Alpha)

Solution DPP-03

1. At vapour pressure: 8. The vapour pressure of ethanol is 115 torr at 34.9°C.

(1) (rate)evaporation = (rate)condensation if Hvap of ethanol is 38.6 kJ/mol. Calculate the
(2) (rate)evaporation > (rate)condensation temp. (°C) when then vapour pressure is 760 torr.
(3) (rate)evaporation < (rate)condensation (1) 69°C (2) 89°C
(4) None of the above (3) 99°C (4) 79°C

2. Vapour pressure is achieved in:

9. A solution which is ideal in nature follows.
(1) open container (2) closed container
(1) Graham’s Law (2) Ostwald Law
(3) both (1) & (2) (4) none of these
(3) Fleming’s Law (4) Raoult’s Law
3. At vapour pressure: 10. A container having liquid in equilibrium with its
(1) forward change is favoured vapour has volume of 10 L. If the volume of
(2) backward change is favoured container is reduced to 5 L, the vapour pressure
(3) both forward & backward changes are favoured (consider constant temperature)
but with equal rate (1) is reduced by 50%
(4) none of these (2) is increased by 50%
(3) remain constant
4. Among the following, which has highest boiling
(4) none of these
point?
(1) Water (2) Ethyl alcohol 11. Which of the following solution has least value of
(3) Acetone (4) Chloroform vapour pressure?
(1) HCl + H2O (2) NaOH + H2O
5. The factor which affect vapour pressure is:
(3) R–OH + H2O (4) CH3–Cl + H2O
(1) forces between liquid molecules
(2) temperature 12. If vapour pressure of 10 gram of a liquid solution is
(3) volatile solute ‘P’, then what is the vapour pressure of 5 gram of
(4) all of these same liquid solution?
(1) P (2) 2P
6. Maximum value of partial pressure at a particular
(3) P/2 (4) none of these
temperature is called:
(1) Osmotic pressure 13. The correct relationship of vapour pressure and
(2) -pressure temperature is given by:
(3) atmospheric pressure
(4) vapour pressure

7. Change in surface area has following effect on (1) (2)

vapour pressure.
(1) increases
(2) decreases
(3) do not affects vapour pressure
(4) none of the above (3) (4)
 2

14. According to Raoult’s law, vapour pressure of a 16. The correct expression for vapour pressure of a
solution containing non-volatile solute, is directly solution contain volatile Solute A and Solvent B is:
proportional to mole fraction of: (1) P = PA XA − PB XB
o o

(1) solute
(2) P = PA + (PB  PA )XB
o o o
(2) solvent
(3) P = PB + (PA − PB )XA
o o o
(3) both solute and solvent
(4) none of these (4) None of the above
15. If P° → vapour pressure of solvent and
o
P → vapour pressure of solution then. 17. A container contains component A with PA = 200
(assume the solute used is non-volatile) o
mm and component B of PB = 500 mm. If moles of
(1) P° > P (2) P° < P
A = 2 and moles of B = 3, find vapour pressure of
(3) P° = P (4) none of these
solution if solute is volatile.
(1) 120 mm (2) 520 mm
(3) 380 mm (4) 420 mm
 3

Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (1) 10. (3)
2. (2) 11. (3)
3. (3) 12. (1)
4. (1) 13. (1)
5. (4) 14. (2)
6. (4) 15. (1)
7. (3) 16. (3)
8. (4) 17. (3)
9. (4)

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Yakeen NEET 2.0 (Alpha)

Solution DPP-02

1. Which of the following is insoluble in water? 8. HgI2 is made soluble in water by

(1) salt (2) acid (1) increasing pressure
(3) base (4) oil (2) decreasing pressure
(3) forming complex with KI
2. On increasing temperature, the solubility of NaOH (4) none of the above
in water.
9. Generally a solid is made more soluble in liquid by
(1) Increases (1) increasing temperature
(2) Decreases (2) making the solid in powdered form
(3) Remains unaffected (3) both (1) & (2)
(4) Cannot be determined (4) none of the above

3. On increasing temperature, the solubility of NaNO3 10. According to the law ‘like dissolves like’
in water. (1) salt is soluble in oil
(1) Increases (2) I2 is soluble in water
(2) Decreases (3) NaOH is soluble in crude oil
(3) Remains unaffected (4) acid is soluble in water
(4) Cannot be determined
11. Which of the following cannot dissolve any
4. What is the effect of complex formation on electrolyte?
solubility of I2? (1) Ether (2) NH3(l)
(3) Water (4) Acidic solution
(1) Increases (2) Decreases
(3) Remains same (4) None of the above 12. Electrolytes easily dissolve in water due to
(1) high dielectric constant
5. Solid forms of carboxylic acids are soluble in
(2) cooling nature
(1) Water (2) Acetone
(3) high potential
(3) Wax (4) Oil (4) low pressure
6. The factor that does not affect the solubility of solid
13. Which of the following dissolves in water due to H-
in water is bond formation?
(1) temperature (1) NaCl (2) BaSO4
(2) nature of bond (3) R – O – H (4) AgCl
(3) complex formation
(4) pressure 14. Benzene is soluble in
(1) Water (2) Naphthalene
7. A substance is less soluble in water, which of the (3) Acid (4) Alcohol
following measure should be taken to increase its
solubility? 15. When a solid solute is added to the solvent some
(1) rise in temperature solute dissolves and its concentration increases in
(2) lowering temperature solution. This process is called
(3) increase in pressure (1) Osmosis
(2) Dissolution
(4) decrease in pressure
(3) Preferential osmosis
(4) Discharging
 2

16. Fishes feel uncomfortable in warm water due to 24. A person feels more fatigue at high altitudes due to
(1) fishes do not like warmness (1) low pressure of oxygen
(2) higher amount of impurities (2) low temperature
(3) low solubility of oxygen at higher temperature (3) nausea
(4) greater population of fishes (4) contraction of body

17. The gas for which Henry’s law is not applicable in 25. Henry’s law is not applicable for aqueous solution of
aqueous solution is (1) O2 (2) N2
(1) HCl (2) N2 (3) SO3 (4) He
(3) Xe (4) He
26. Henry’s law is not applicable at
18. Unit of Henry’s constant KH is same as that of (1) low pressure
(1) Volume (2) Temperature (2) high pressure
(3) Energy (4) Pressure (3) gas does not react with liquid
(4) high temperature
19. If partial pressure of Gas A = 0.4 bar, Gas B = 0.2
bar and Gas C = 0.5 bar, then the gas having 27. O2 is bubbled through water at 293K. Assume that
maximum solubility (neglecting other factors) is O2 exerts a partial pressure of 0.98 bar, find the
(1) A (2) B solubility of O2 in g L–1. The value of Henry’s law
(3) C (4) All are equal soluble constant KH for O2 is 34.84 k bar.
(1) 0.05
20. Which law states that the amount of gas that is (2) 0.08
soluble in a liquid is directly proportional to the (3) 0.07
partial pressure of that gas above the liquid when the (4) 0.01
temperature is kept constant?
(1) Raoult’s Law (2) Henry’s Law 28. Gases with their Henry’s constant values are given.
(3) Coloumb’s Law (4) Dalton’s Law The gas having maximum solubility will be
Gas A KH = 21.2 k bar
21. The value of Henry’s constant (KH) depends on
Gas B KH = 11.2 k bar
(1) nature of the gas
Gas C KH = 5.6 k bar
(2) nature of the solvent
Gas D KH = 2.4 k bar
(3) temperature and pressure
(1) A (2) B
(4) all of these
(3) C (4) D
22. The factor which decreases the solubility of gas in
liquid is 29. The gas which is expected to have maximum value
(1) low temperature of KH will be
(2) interaction between molecules of gas & liquid (1) BH3 (2) CO2
(3) high temperature (3) H2S (4) He
(4) high pressure
30. An unopened soda has an aqueous concentration of
23. The gas dissolved in carbonated drinks escapes an CO2 at 25°C equal to 0.05 mole kg–1. The pressure
opening the bottle due to of CO2 gas in the can is (KH = 0.34 mole/kg bar)
(1) increase in temperature (1) 0.671 bar
(2) increase in pressure (2) 1.49 bar
(3) decrease in pressure over gas (3) 0.147 bar
(4) Increase in molecular interaction (4) 1.71 bar
 3

Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (4) 16. (3)
2. (2) 17. (1)
3. (1) 18. (4)
4. (1) 19. (3)
5. (1) 20. (2)
6. (4) 21. (4)
7. (1) 22. (3)
8. (3) 23. (3)
9. (3) 24. (1)
10. (4) 25. (3)
11. (1) 26. (2)
12. (1) 27. (1)
13. (3) 28. (4)
14. (2) 29. (4)
15. (2) 30. (3)

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Yakeen NEET 2.0 (Alpha)

Solution DPP-01

1. If sea water is assumed to contain 40 g of salt per 9. What is the concentration in mass/volume if 67 g of
200 g of sea water then percentage by mass of salt solute is dissolved to make 1.2 litre of solution?
present is: (1) 6% (2) 8%
(1) 15% (2) 40% (3) 24% (4) 12%
(3) 20% (4) 10%
10. What amount of solute is dissolved in 0.5 L of
2. If 2 moles of CaCO3 is dissolved in 900 g of water solution to make it 20% (w/v)?
then percentage by mass of solution formed is: (1) 120 g (2) 150 g
(1) 36.36% (2) 9.9%
(3) 100 g (4) 200 g
(3) 18.18% (4) 11.75%

3. 0.5 moles of benzene was dissolved in 2 moles of 11. An aqueous solution of NaOH is 20% mass by mass.
toluene. Find mass % of benzene in the solution Find the mass of NaOH is 200 g of solution.
formed. (1) 40 g (2) 60 g
(1) 25.48% (2) 9.52% (3) 20 g (4) 80 g
(3) 15.92% (4) 17.48%
12. A solution is made by mixing 50 g of water 20 g of
4. 60 mL of liquid A is mixed with another liquid B salt and 30 g of sugar. Mass % of salt and sugar are
and the solution was made upto 300 mL. Find respectively.
volume % of liquid B in the solution formed (1) 10, 40 (2) 20, 40
(1) 40% (2) 60% (3) 20, 30 (4) 50, 50
(3) 20% (4) 80%

5. A solute A was put into a solvent to make a solution 13. Find mass by mass % of a solution of 20 mL volume
of mass 240 gram. What should be the mass of A so having solute of mass 4 g.
that its mass % in solution is 40? (density of solution = 1.4 g/mL)
(1) 96 g (2) 24 g (1) 7.14% (2) 8.2%
(3) 48 g (4) 36 g (3) 9.64% (4) 14.28%

6. How much solute should be dissolved in 20 mL of 14. What is the number of ppm of NaCl in the solution
solution so that mass by volume % of solute is 30? with 117 g of NaCl dissolved in 500 mL of water?
(1) 6 g (2) 4 g (1) 1.89 × 105 (2) 2.78 × 105
(3) 8 g (4) 10 g (3) 9.12 × 10 5
(4) 6.54 × 105

7. What should be the mass by volume % of a solution 15. What is the concentration of mercury in ppm if 3 g
which is 20% mass by mass? mercury is found in 15 kg sample of ocean water?
(density of the solution is 1.02 g/mL) (1) 300 (2) 400
(1) 13.2% (2) 10.2% (3) 500 (4) 200
(3) 12.4% (4) 20.4%
16. If 3.0 mg of Cr+6 is dissolved in 3 L of water, find
8. Calculate the mass of cane sugar required to prepare the concentration of Cr+6 in ppm.
250 g of 25% cane sugar solution with water. (1) 2 ppm (2) 1 ppm
(1) 6.25 g (2) 187.5 g (3) 3 ppm (4) 9 ppm
(3) 18.75 g (4) 62.5 g
 2

17. What is the number of ppm of methanol dissolved in 23. A solution contains 50 g of CaCO3 dissolved in 3
68 g of water? (Taking mass of methanol 32 g) liters of water. Find the molarity of the solution
(1) 160000 (2) 480000 formed.
(3) 320000 (4) 520000 1 1
(1) (2)
2 3
18. A tank contains 5 moles of oxygen, 2 moles of
1 1
nitrogen and 20 g of hydrogen at room temperature. (3) (4)
Find the mole fraction of hydrogen.
6 4
5 2
(1) (2) 24. The concentration of CaCl2 solution is 0.5 mole L–1.
17 15
Find the moles of CaCl2 in 500 mL in the solution.
8 10 (1) 0.25 (2) 0.45
(3) (4)
15 17 (3) 0.3 (4) 0.5
19. A room has oxygen and nitrogen in mass ratio of 8:
25. What is the molality of a solution containing 2 moles
7. Find mole fraction of oxygen gas.
of a solute dissolved in 500 g of a solvent?
(1) 0.2 (2) 0.3
(1) 3 (2) 2
(3) 0.5 (4) 0.8
(3) 1 (4) 4
20. An aqueous solution of ethanol contains 23 g of
ethanol dissolved in 90 g of water. Find mole 26. An aqueous solution of glucose is prepared by
fraction of ethanol in the solution. dissolving 45 g of glucose in 1 liter of water. Find
3 3 molality of solution formed.
(1) (2) 1 3
4 5 (1) (2)
2 1 4 5
(3) (4) 1 2
7 11 (3) (4)
3 3
21. A liquid solution consists of three liquids A, B and C
with mole fractions of A = 0.3 and mole fraction of 27. A mixture of H2 and He contains 3 moles of H2 & 10
B = 0.2. Find mole fraction of C. moles of He. Find molality of H2.
(1) 0.5 (2) 0.2 (1) 35 (2) 82
(3) 0.3 (4) 0.7 (3) 75 (4) 40

22. Find molarity of a sample of pure water. Consider 28. If a gas mixture of two gases. A and B contains gas
density = 1 g/mL. A of mole fraction 0.3. Find molality of A.
(1) 27.7 (2) 33.3 (Molar mass of A = 10 g; B = 20g)
(3) 55.5 (4) 11.1 (1) 21.42 (2) 6.7
(3) 12.14 (4) 8.21
 3

Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (3) 15. (4)
2. (3) 16. (2)
3. (4) 17. (3)
4. (4) 18. (4)
5. (1) 19. (3)
6. (1) 20. (4)
7. (4) 21. (1)
8. (4) 22. (3)
9. (1) 23. (3)
10. (3) 24. (1)
11. (1) 25. (4)
12. (3) 26. (1)
13. (4) 27. (3)
14. (1) 28. (1)

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