Professional Documents
Culture Documents
Chapter 2
Chapter 2
❑ The shape of an individual particle is conveniently expressed in terms of the sphericity ∅𝒔 which is
independent of particle size.
Sphericity
❑ Sphericity, ∅𝒔 , is the measure of how closely the shape of an object approaches to that of a
mathematically perfect sphere.
▪ This is defined as the ratio of the surface area of a sphere with the same volume as the particle
(Ss) to the surface area of the particle (Sp),
❑ The equivalent diameter is sometimes defined as the diameter of a sphere of equal volume. For fine granular
materials, however, it is difficult to determine the exact volume and surface area of a particle, and Dp is
usually taken to be the nominal size based on screen analyses or microscopic examination.
(2) Particle size
❑ Particle size is the physical property that describes the size of individual particles in a
material.
Why we study about particle size?
❑ Particle size indeed has a significant influence on various material properties. Some of the key
material properties affected by particle size include:
▪ Surface Area
▪ Porosity
▪ Strength and Toughness
▪ Optical Properties
▪ Mechanical Properties
▪ Rheological Behavior
▪ Reactivity and Kinetics
▪ Particle Packing
Mixed particle sizes and size analysis
❑ In a sample of uniform particles of diameter Dp, the total volume of the particles is m/ 𝜌𝑝 , where m and
𝜌𝑝 are the total mass of the sample and the density of the particles, respectively. Since the volume of one
particle is vp the number of particles in the sample N is given by:
▪ The total surface area is the surface area per particle times the number of particles,
2
Mixture of particles
❑ To apply Eqs. (1) and (2) to mixtures of particles having various sizes and densities, the mixture is
sorted into fractions, each of constant density and approximately constant size.
▪ Each fraction can then be weighed, or the individual particles in it can be counted or measured by
anyone of a number of methods.
▪ Particle size analysis can be done in two different ways: differential analysis and
cumulative analysis.
Differential analysis:
▪ Information from such a particle-size analysis is
tabulated to show the mass or number fraction in each
size increment as a function of the average particle size
(or size range) in the increment.
Mixture of particles
Cumulative analysis
▪ Obtained by adding, consecutively, the individual increments, starting with that containing the smallest
particles, and tabulating or plotting the cumulative sums against the maximum particle diameter in the
increment.
❑ Dividing the total volume of the sample by the number of particles in the mixture (see below) gives
the average volume of a particle.
▪ The diameter of such a particle is the volume mean diameter 𝑫𝑽 , which is found from the relation:
▪ For samples consisting of uniform particles these average diameters are, of course, all the same.
❑ For mixtures containing particles of various sizes, however, the several average diameters may differ
widely from one another.
Number of particles in mixture
❑ To calculate, from the differential analysis, the number of particles in a mixture, Eq. (1) is used to
compute the number of particles in each fraction, and Nw, the total population in one mass unit
of sample, is obtained by summation over all the fractions.
▪ For a given particle shape, the volume of any particle is proportional to its "diameter" cubed, or
▪ where a is the volume shape factor. From Eq. (1), then, assuming that a is independent of size,
▪ The specific surface area, the various average diameters, and the number of particles are readily
calculated from the particle-size analyses through the use of simple computer programs.
❑ Many measuring instruments for very fine particles are programmed to report these quantities
directly.
Particle size Measurement Methods
❑ A number of particle measurement methods and their measurement size ranges are given in Table
below. The correct method must be selected for the application of interest.
❑ Instrumental Particle size analyzers: Electronic particle counter, Laser diffraction analyzers,
Xray or photo sediment meters, dynamic light scattering techniques.
(1) Screen analysis (Sieving)
❑ Screen is an open container usually cylindrical with uniformly spaced
openings at the base.
❑ It is normally made of wire cloth, the wire diameter and interspacing
between wires is carefully controlled.
Screening and its terminology
❑ Screening is a method of separating particles on the basis of their size.
Aperture Size of screen
The higher the Mesh size, the smaller the particles must be to
pass through.
For example, 6/8 refers to the particles passing through the 6-mesh and remaining on
an 8-mesh screen.
Tayler Standard Screen Series
❑ Size of the upper screen must be larger by a factor √2 and that of lower screen must be
smaller by a factor √2.
Sample data sheet for sieve analysis
Example 1
▪ A mixture contains three sizes of particles: 25% by volume of 25 mm size,40% of
50 mm and 35% of 75 mm. The sphericity is 0.68. Calculate the volume surface
mean diameter (𝑫̅𝒔).
Example 2:
▪ A spherical solid powder was screen analyzed, the analysis
results are shown in the table below:
a. Calculate the mass fraction of the particulate material.
b. Calculate volume-surface mean diameter (𝑫̅𝒔)
c. Calculate the specific surface area (Aw) of the mixture if
the particle density was 2,500 kg/m³.
d. Calculate the total number of particles if the particle
shape factor was 2.5.
Example 3
The size analysis of a powdered material on a mass basis is represented by a straight line from 0 per
cent mass at 1 µm particle size to 100 per cent mass at 101 µm particle size as shown in Figure shown
below. Calculate the surface mean diameter of the particles constituting the system
Example 4
▪ Wheat flour is made by grinding the dry wheat grains. Particle size is an important characteristic in many of the
wheat products. For example, in making wafers, if the flour is too fine; light and tender products are formed. On the
other hand, incomplete sheets of unsatisfactory wafers are formed if the flour is too coarse.
▪ Therefore, it is important to test the grinding performance of flour by sieve analysis in wafer producing factories.
▪ Determine:
a. The volume surface mean diameter,
b. Mass mean diameter, and
c. Volume mean diameter of wheat flour by differential analysis using the data given in the following table.
Example 5
The size analysis of a powdered material measured by sieve analysis on a mass basis is represented by
the table below. Calculate the volume mean diameter of the particles constituting the system. [Show
detailed calculations]
Mass fraction Particle size
(𝝁𝒎)
0 1
0.1 11
0.2 21
0.3 31
0.4 41
0.5 51
0.6 61
0.7 71
0.8 81
0.9 91
1 101
(2) Sedimentation Methods
❑ These methods rely on the principle that particles settle at
different rates in a fluid medium based on their size and
density.
▪ The sedimentation techniques utilize the dependence of the
terminal velocities of particles on their size either in a gravitational
field or in a centrifugal field.
❑ According to Stokes’ law, it is possible to calculate the mean particle diameter d from the
sedimentation rate v :
(3) Particle Counting
▪ Originally images of particles would be counted and measured by hand, now this process is
often automated by computer. Individual particle images are captured from dispersed samples
and analyzed to determine their particle size, particle shape and other physical properties.
▪ The external force (𝑭𝒆 ) - Expressed as a product of the mass (m) and the acceleration (𝒂𝒆 ) of the
particle from this force:
Equation for One-dimensional Motion of Particle through Fluid
▪ Buoyant Force:
▪ This force acts in the upward direction, opposing the force of gravity.
▪ It is exerted on an object immersed in a fluid and is caused by the pressure difference between
the top and bottom of the object due to the weight of the fluid displaced by the object.
▪ Based on Archimedes’ law, it is the product of the mass of the fluid displaced by the
particle and the acceleration from the external force.
❑ In simpler terms, the buoyant force is equal to the weight of the fluid displaced by the object.
Equation for One-dimensional Motion of Particle through Fluid
The drag force (FD)
▪ Drag force arises due to the interaction between the particles and the fluid as they move through it.
▪ It opposes the motion of the particles relative to the fluid and can significantly affect their path,
velocity, and distribution within the fluid.
Equation for One-dimensional Motion of Particle through Fluid
❑ In this equation, u is the velocity of the particle relative to the fluid and is directed outwardly along a
radius.
Terminal velocity
❑ Terminal velocity, is the constant velocity that an object in a fluid achieves when the drag force acting
on it (due to the resistance of the fluid) becomes equal in magnitude to the gravitational force acting
on it (due to its weight).
▪ If a spherical particle is allowed to settle in a fluid under gravity, its velocity will increase until the
accelerating force is exactly balanced by the resistance force. At this point the particle falls with its
terminal velocity.
▪ Terminal velocity occurs when the sum of the drag force (Fd) and Fb Fd
the buoyancy is equal to the downward force of gravity (FG) acting on the
object. Since the net force on the object is zero, the object has
zero acceleration.
d
𝑭𝒈 = 𝑭𝒃 + 𝑭𝒅
Or, it can be expressed as:
W=mg
Terminal velocity: For spherical particle
Terminal velocity: Centrifugal force
❑ In motion from a centrifugal force, the velocity depends on the radius. The acceleration is not
constant if the particle is in motion with respect to the fluid.
𝑢2 𝜌𝐴𝑝
2𝐹𝐷
around the particle is not distorted;
▪ It must be moving at its terminal velocity with
𝐶𝐷 =
respect to the fluid.
𝐷𝑝 𝑢𝜌
𝑅𝑒 =
𝜇
Navier–Stokes equation
Stokes Law
𝐅𝐃 = 𝟑𝛑𝛍𝐃𝐩 𝐮
❑ Stokes's law, mathematical equation that expresses the drag force resisting the fall of small spherical
particles through a fluid medium.
Drag coefficient (CD): Drag curve
Criterion for settling regime
❑ To identify the range in which the motion of the particle lies, the velocity term is eliminated
from the Reynolds number (𝑅𝑒 ) by substituting 𝑢𝑡 from Stokes’ law and Newton’s law.
𝑪𝑫 = ∅ 𝑵𝑹𝒆
▪ Reynolds number can be defined as:
Flow of fluid through a granular bed
❑ Some industries often encounter processes that require flow of fluids through beds composed of
stationary granular particles. For example: Absorption and filtration process
❑ The drop in pressure for flow through a bed of small particles provides
a convenient method for obtaining a measure of the external surface
area of a powder.
Flow of fluid through a granular bed
❑ A granular bed refers to a collection of solid particles that are packed together in a confined
space.
▪ The flow of fluid through a granular bed refers to the movement of a fluid
(liquid or gas) through a bed of solid particles, such as sand, gravel, or
catalyst particles.
▪ Understanding the behavior of fluid flow through granular beds is crucial
for optimizing processes, predicting pressure drops, and designing
efficient systems in industries like chemical engineering, environmental
engineering, and petroleum engineering.
Darcy's law
❑ Permeability is the property of porous material that permits the flow of water or any other liquid
through it by its interconnecting voids.
▪ It quantifies the ability of the porous medium (the granular bed in this case) to transmit fluids.
Darcy's law: Permeability coefficient
❑ The permeability coefficient in the context of fluid flow through a porous medium, such as a
granular bed, indicates the ease with which a fluid can flow through the medium.
▪ It is a measure of the medium's ability to transmit fluids and is a crucial parameter in
understanding and predicting fluid flow behavior in porous materials.
▪ Voidage, also known as porosity or fractional voidage, represents the fraction of the total volume of a material that
is not occupied by solid particles. It quantifies the amount of empty space or voids within the material.
❑ Specific surface represents the amount of surface area available for interaction with fluids or other substances in
relation to the volume of the material.
Specific surface and voidage
❑ Where: D is equivalent diameter for the channel, v is average velocity and it is given by:
▪ For highly turbulent flow the friction factor should approach a constant value. Also, it is assumed that all
packed beds should have the same relative roughness. Experimental data indicated that 3f = 1.75.
▪ Hence, the final equation for turbulent flow for 𝑁𝑅𝑒,𝑝 > 1000, which is called the Burke-Plummer
equation, becomes:
Example 3
1. A packed bed is composed of cylinders having a diameter D=0.02 m and a length h= D. The
bulk density of the overall packed bed is 962 kg/𝑚3 and the density of solid cylinders
is 1600 kg/𝑚3 :
A. Calculate the void fraction
B. Calculate the effective diameter of the particles.
C. Calculate the value a
(Hint: do the calculations for a unit volume)
Example 4
A packed bed is composed of cubes 0.020 m on a side and the bulk density of the packed bed
is 980 kg/𝑚3 . The density of the solid cubes is 1500 kg/𝑚3 .
A. Calculate 𝜀, effective diameter 𝐷𝑝 , and a.
B. Repeat for the same conditions but for cylinders having a diameter of D = 0.02 m
and a length h = 1.5D.
Factors affecting the flow of fluid through granular bed
❑ Several factors can affect the flow of fluid through a granular bed. Some of the key factors
include:
2. If the Reynolds number is given by 0.89, calculate the average velocity of the water moving trough
the channel of the bed.
3. Find the pressure drop if the length of the bed is given by 2m?
End of chapter 2