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Student
Class: 2nd Year
Name:

Paper Type: Subject: Chemistry

Maximum
Paper Time: 40
Marks:

Q1. Choose the correct option. (10X1=10)

1. Among group VA elements, the most electronegative element is:

(A) Sb (B) N (C) P (D) As
2. Oxidation of NO in air produces:
(A) (B) (C) (D)
3. SO3 is not absorbed in water directly to form H2SO4 because:
(A) The reaction does not (B) The reaction is quite (C) The reaction is highly (D) SO3 is insoluble in water
go to completion slow exothermic
4. Which catalyst is used in contact process?
(A) (B) (C) (D)
o
5. At 18 C the specific gravity of H2SO4:
(A) 1.891 (B) 1.834 (C) 2.101 (D) 1.740
6. Among group V A elements, the most electronegative is:
(A) Sb (B) N (C) P (D) As
7. Ortho phosphoric acid has melting point:
o o o o
(A) 49 C (B) 45 C (C) 41 C (D) 50 C
8. The brown gas formed, When metal reduces HNO3 is:
(A) N2O5 (B) N2O3 (C) NO2 (D) NO
9. Aqua regia contains HNO3 and HCL in the ratio of:
(A) 1:1 (B) 1:2 (C) 1:3 (D) 3:1
10. The most electronegative element of group VA is:
(A) N (B) P (C) Sb (D) Bi

Q2. Write short answers of following questions. (10X2=20)

‫ـ‬
[i ] Why the elements of group VIA other than oxygen show more than oxidation states?

‫ـ‬
[ii ] What is laughing gas?

‫ـ‬
[iii ] Why is does aqua regia dissolve gold and platinum?

‫ـ‬
[iv] Describe "Ring test" for the confirmation of the presence of nitrate ions in solution.

‫ـ‬
[v] Give the methods of preparation of PCl3.

‫ـ‬
[vi ] Give example of two important oxyacids of nitrogen while giving their structure.

‫ـ‬
[vii ] Nitrogen oxide is oxidizing agent, prove it by two reactions.

‫ـ‬
[viii ] Give two reactions in which nitrous acid (HNO₂) behaves as oxidizing agent.

[ix] How does ‫ـ‬ ꜀ₒₙ꜀ HNO₃ react with: (a) Cu (b) H₂S
‫ـ‬
[x] Give the reactions of nitric acid with: (a) Arsenic (b) Antimony.

Q3. Write detailed answers of the following questions. (2X5=10)

1. Describe the properties and applications of tellurium, a Group VIA element with unique electrical and optical properties. Discuss

its role in the production of semiconductors, thermoelectric devices, and solar cells.

2. Explain the significance of sulphuric acid in the manufacturing of fertilizers. Discuss its role in the production of ammonium

sulphate and phosphate-based fertilizers.

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