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LAKSHYA NEET 2.0 (2024)

Chemical Kinetics DPP-08

1. The activation energy of a reaction can be 7. For a reaction is equal to

determined from the slope of which of the
following graphs?
1 T 1
(1) In k vs (2) vs
T lnk T
lnk
(3) lnkvsT (4) vs T
T d[x]
, is equal to
dt
2. What is the activation energy for a reaction if its
rate doubles when the temperature is raised from (1) k1(a – x) – k2(a – x)
20ºC to 35ºC? (2) k2(a – x) – k1(a – x)
(R = 8.314 J mol–1 K–1) (3) k1(a – x) + k2(a – x)
(1) 34.7 kJ mol-1 (2) 15.1 kJ mol-1 (4) –k1(a – x) – k2(a – x)
(3) 342 kJ mol-1 (4) 269 kJmm-1
8. The mechanism of the reaction:
3. In a zero-order reaction, for every 10ºC rise of
A + 2B + C → D is
temperature, the rate is doubled. If the temperature
is increased from 10ºC to 100ºC, the rate of the (step 1) (fast) equilibrium A + B ⇌ X
reaction will become (step 2) (slow) X + C → Y
(1) 256 times (2) 512 times (step 3) (fast) Y + B → D
(3) 64 times (4) 128 times Which rate law is correct?
(1) r = k[C]
4. The rate constants k1 and k2 for two different (2) r = k[A] [B]2 [C]
reactions are 1016  e–2000/T and 1015  e–1000/T,
(3) r = k[A] [B] [C]
respectively. The temperature at which k1 = k2 is
(4) r = k[D]
1000
(1) 2000 K (2) K
2.303
9. A hypothetical reaction, A2 + B2 → 2AB follows
2000
(3) 1000 K (4) K the mechanism as given below:
2.303
A2 ⇌ A + A ….(fast)
5. For a reaction, temperature coefficient = 2, if the A + B2 → AB + B ….(slow)
temperature is increased from 25oC to 35oC, then A + B → AB …..(fast)
calculate the activation energy (in kJ) of the The order of the overall reaction is
reaction. (1) 2 (2) 1
(1) 52.8 kJ (2) 70 kJ (3) 1½ (4) zero
(3) 100 kJ (4) 0 kJ
10. The chemical reaction, 2O3 →3O2 proceeds as
6. The activation energies of the forward and
O3 ⇌ O2 + [O] (fast)
backward reactions in the case of a chemical
reaction are 30.5 and 45.4 kJ/mol respectively. The [O] + O3 → 2O2 (slow)
reaction is The rate law expression will be
(1) exothermic (1) Rate = k[O][O3]
(2) endothermic (2) Rate = k[O3]2[O2]–1
(3) neither exothermic nor endothermic (3) Rate = k[O3]2
(4) independent of temperature (4) Rate = k[O2][O]
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (1) 6. (1)
2. (1) 7. (3)
3. (2) 8. (3)
4. (2) 9. (3)
5. (1) 10. (2)

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