Max. Marks: 100 Date: 04.01.

2024
CHEMISTRY : JEE TEST-10
Topic: P-Block + D & F Block + Co-ordination Compound + Purification + GOC +
Hydrocarbons + Organic Compounds Containing (Halogen + Oxygen + Nitrogen)
1. Chemical formula for iron (III) hexacyanidoferrate (II) is
(a) Fe[Fe(CN)6] (b) Fe3[Fe(CN)6] (c) Fe3[Fe(CN)6]4 (d) Fe4[Fe(CN)6]3
2. Which of the following is the strongest field ligand?
(a) CN– (b) NO –2 (c) NH3 (d) en

3. Which of the following complexes in the descending order of their absorbed light wavelengths
(I) [CoCl6 ]3 – (II) [Co(H2O)6]3+ (III) [Co(NH3)6]3+ (IV) [Co(CN)6]3–

(a) I > II > III > IV (b) IV > III > II > I (c) III > IV > I > II (d) I > II > IV > III
4. Aromatic aldehydes react with aromatic primary amines to give
(a) amides (b) Schiff’s base (c) Oximes (d) Cyanohydrins
5. On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic
compound formed is
(a) An alkanol (b) An alkaneodiol
(c) An alkyl cyanide (d) An alkyl isocyanide
PO
2 5  A  4[H]
6. Identify ‘B’ in the reaction Acetamide  B


(a) CH3NH2 (b) CH3CH2NH2 (c) CH3CN (d) CH3COONH4

7. M+2/M of 3d element which has positive reduction potential is
(a) Cu+2/Cu (b) Zn+2/Zn (c) Ni+2/Ni (d) Mn+2/Mn
8. Name the gas that can readilydecolourise acidified KMnO4 solution
(a) SO2 (b) NO2 (c) P2O5 (d) CO2
9. The correct statement(s) from among the following are:
(i) all the d and f-block elements are metals
(ii) all the d and f-block elements from coloured ions
(iii) all the d- and f-block elements from paramagnetic ions
(a) (i) only (b) (i) and (ii) (c) (ii) and (iii) (d) All of these
10. BCl3 on hydrolysis forms:
(a) HCl (b) H3BO3 (c) Both (a) and (b) (d) None of these

Space for Rough Work

11. Boron compounds behave as Lewis acids because of their
(a) Ionizing property (b) Acidic property
(c) Covalent nature (d) Electron deficient character
12. Which is not the property of diamond?
(a)  f H value of diamond is 1.90 kJ mol–1

(b) Being hardest, it is used as an abrasive for sharpening hard tools

(c) It is oxidized with a mixture of K2Cr2O7 and H2SO4 at 200°C
(d) It is insoluble in all solvents
13. Carbon and silicon belong to group IV. The maximum coordination number of carbon in commonly occurring
compounds is four whereas that of silicon is six. This is due to
(a) More electropositive nature of silicon
(b) Silicon being vulnerable to attack by nucleophilic reagents
(c) Availability of d-orbitals in silicon
(d) Large size of silicon
14. Assertion: PbI4 is a stable compound.
Reason: Pb2+ ions with concentrated solution of KI forms a soluble complex.
(a) If both assertion and reason are true and the reason is the correct explanation of the assertion
(b) If both assertion and reason are true but reason is not the correct explanation of the assertion
(c) If assertion is true but reason is false
(d) If assertion is false but reason is true
15. Which of the following is not correct?
(a) Liquid helium is used as cryogenic liquid
(b) XeO3 has four  - and four  -bonds
(c) The hybridization of Xe in XeF4 is sp 3d2
(d) Among noble gases, the occurrence of argon is highest in air
16. The solubility of iodine in water is greatly increased by
(a) Adding an acid (b) Boiling the solution
(c) Cooling the solution (d) Adding potassium iodide
17. In which pair of ions both the species contain S-S bond?
(a) S2O72 – , S2O32 – (b) S4 O62 – , S2 O32 – (c) S4O72 – , S2O82 – (d) S4O62 – , S2O72 –

Space for Rough Work

18. NO2 and N2O4 are two forms of nitrogen dioxide. One exists in gaseous state while other in liquid state. The
nature of NO 2 and N2O4 forms are:
(a) both are paramagnetic (b) both are diamagnetic
(c) NO2 is paramagnetic while N2O4 is diamagnetic (d) NO2 is diamagnetic while N2O4 is paramagnetic
19. Which of the following will act as reducing agent
(a) Orthophosphoric acid (b) Hypophosphorous acid
(c) Hypophosphoric acid (d) All
20. What is the correct increasing order of extent of deprotonation of the following acids in its aqueous solution?
(I) CH3CH2COOH (II) (CH3)2CHCOOH (III) CH3CCl2COOH (IV) Cl2CHCH2COOH
(a) II < I < III < IV (b) I < IV < III < II (c) IV < III < I < II (d) II < I < IV < III
21. In which of the following first resonating structure is more stable than the second?
  
(a) CH 2 – CH  O  CH 2  CH – O (b) CH 2 – O – CH3  CH 2  O – CH3
   
(c) CH 2  CH – NH 2  CH 2 – CH  NH 2 (d) O – CH  CH 2  O  CH – CH 2

22. Consider thiol anion (RS ) and alkoxy anion (RO–). Which of the following statements is correct?

(a) RS is less basic and less nucleophilic than RO

(b) RS is less basic but more nucleophilic than RO
(c) RS is more basic and more nucleophilic than RO
(d) RS is more basic but less nucleophilic than RO
23. Identify the product B

HNO3/H2SO4 Br2
A B
< 60° C FeBr3
NO2 NO2
Br
(a) (b)
Br Br

NO2 NO2

(c) (d)
Br
Br
Space for Rough Work
24. Predict the product of the following reaction process,
H2
lindlar's catalyst
CH3

CH3

CH3 H H
(a) (b)
CH3 H

H H H CH3
(c) (d)
25.

Set-I (Reagent) Set-II (Reaction)

(A) Na/Ether 1. Decarboxylation

(B) NaOH + CaO 2. Wurtz reaction

(C) Zn/CH3COOH 3. Reduction of alkyl halides

(D) H2/Ni 4. Sabatier-Senderen’s reaction

5. Kolbe’s electrolysis

(a) A – 1, B – 2, C – 3, D – 4 (b) A – 2, B – 1, C – 3, D – 4
(c) A – 2, B – 1, C – 4, D – 5 (d) A – 1, B – 2, C – 4, D – 3

*****

Space for Rough Work