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Arjuna (JEE)
DPP-07
General Organic Chemistry
1. Lassaigne's test in qualitative analysis is 8. Which of the following methods is not used
used to detect: for estimation of nitro and azo compounds?
(A) Nitrogen (B) Sulphur (A) Duma’s method
(C) Chlorine (D) All of these
(B) Kjeldahl’s method
2. The compound formed in the positive test (C) None of these
for nitrogen with the Lassaigne solution of (D) Both (A) and (B)
an organic compound is:
(A) Fe4[Fe(CN)6]3 9. In Duma’s method for estimation of
(B) Na3[Fe(CN)6] nitrogen 0.3 of an organic compound gave
(C) Fe(CN)3 50 mL of nitrogen collected at 300 K
(D) Na4[Fe(CN)5COS] temperature and 715 mm pressure.
Calculate the % composition of nitrogen in
3. Presence of halogen in organic compounds the compound: (Aueous tension at 300 k =
can be detected by using: 15 mm)
(A) Leibig's test (B) Duma's test (A) 11.46% (B) 17.46%
(C) Kjeldahl's test (D) Beilstein test (C) 22.06% (D) 39.65%

4. In an organic compound, phosphorus is 10. A sample of 0.5 of an organic compound

estimated as: was treated according to Kjeldahl’s method.
(A) Mg2P2O7 (B) Mg3(PO4)2 The ammonia evolved was absorbed in 50
(C) H3PO4 (D) P2O5 ml of 0.5M H2SO4. The remaining acid
after neutralisation by ammonia consumed
5. During the fusion of an organic compound 80 ml of 0.5 M NaOH. The percentage of
with sodium metal, nitrogen of the nitrogen in the organic compound is:
compound is converted into:
(A) 14 (B) 28
(A) NaNO2 (B) NaNH2
(C) NaCN (D) NaNC (C) 42 (D) 56

6. Violet coloured complex obtained in the 11. On complete combustion, 0.246 g of an

detection of sulphur is: organic compound gave 0.198 g of carbon
(A) Na2[Fe(NO)(CN)5] dioxide and 0.101 g of water. Determine the
(B) Na3[Fe(ONS)(CN5)] percentage composition of carbon and
(C) Na4[Fe(CN)5NOS] hydrogen in the compound:
(D) Both (B) and (C) (A) 8.9% (H) 4.58% (C)
(B) 6.8% (C) 4.58% (H)
7. In carius method of estimation of halogen,
0.15 g of an organic compound gave 0.12 g (C) 4.58% (H) 21.95% (C)
of AgBr. Find out the % of bromine in the (D) 3.2% (H) 21.95% (C)
compound.
(A) 34.04% (B) 44.04% 12. Following is estimated by leibig method:
(C) 96.05% (D) 88% (A) C and H (B) Nitrogen
(C) Chlorine (D) Bromine
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ANSWERS KEY

1. (D)
2. (A)
3. (D)
4. (A)
5. (C)
6. (C)
7. (A)
8. (B)
9. (B)
10. (B)
11. (C)
12. (A)

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