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JEE Main 2020 Sep 03 First Shift Question Paper
JEE Main 2020 Sep 03 First Shift Question Paper
PHYSICS 2 3 3 2
(a) (b) (c) (d)
1. In a radioactive material, fraction of active material 3 2 2 3
remaining after time t is 9/16. The fraction that was 6. Model a torch battery of length l to be made up of a
remaining after t/2 is thin cylindrical bar of radius ‘a’ and a concentric thin
4 3 3 7 cylindrical shell of radius ‘b’ filled in between with an
(a) (b) (c) (d)
5 5 4 8 electrolyte of resistivity r (see figure). If the battery is
2. An elliptical loop having resistance R, of semi major connected to a resistance of value R, the maximum
axis a and semi minor axis b is placed in a magnetic Joule heating in R will take place for
field as shown in the figure. If the loop is rotated about ρ b
the x-axis with angular frequency w, the average power (a) R =
2πl a
loss in the loop due to Joule heating is ρ b
π 2 a 2 b2 B 2 ω 2 (b) R = ln l
(a) z 2πl a
2R B
ρ b
(b) zero (c) R = ln
b x πl a
x a
(c) πabBω a
2ρ b b
R y (d) R = ln
y πl a
π 2 a 2 b2 B 2 ω 2 7. Magnitude of magnetic field (in SI units) at the centre
(d)
R of a hexagonal shape coil of side 10 cm, 50 turns and
3. Consider a gas of triatomic molecules. The molecules µ I
are assumed to be triangular and made of massless carrying current I (Ampere) in units of 0 is
π
rigid rods whose vertices are occupied by atoms. The (a) 250 3 (b) 50 3
internal energy of a mole of the gas at temperature T is
(c) 500 3 (d) 5 3
5 3
(a) RT (b) RT
2 2 8. A balloon filled with helium (32°C and 1.7 atm.)
9 bursts. Immediately afterwards the expansion of helium
(c) RT (d) 3RT
2 can be considered as
2 (a) irreversible isothermal
4. Two isolated conducting spheres S1 and S2 of radius R
1 3 (b) irreversible adiabatic
and R have 12 mC and –3 mC charges, respectively (c) reversible adiabatic
3
and are at a large distance from each other. They are now (d) reversible isothermal.
connected by a conducting wire. A long time after this 9. A 750 Hz, 20 V (rms) source is connected to a
is done, the charges on S1 and S2 are respectively resistance of 100 W, an inductance of 0.1803 H and a
(a) 4.5 mC on both (b) 4.5 mC and –4.5 mC capacitance of 10 mF all in series. The time in which the
(c) 3 mC and 6 mC (d) 6 mC and 3 mC resistance (heat capacity 2 J/°C) will get heated by 10°C.
5. Moment of inertia of a cylinder of mass M, length L (assume no loss of heat to the surroundings) is close to
and radius R about an axis passing through its centre (a) 418 s (b) 245 s (c) 365 s (d) 348 s
and perpendicular to the axis of the cylinder is
10. The magnetic field of a plane electromagnetic
R2 L2
I = M + . If such a cylinder is to be made for wave is B = 3 × 10–8 sin[200p (y + ct)] i T, where
4 12
a given mass of a material, the ration L/R for it to have c = 3 × 108 m s–1 is the speed of light. The corresponding
minimum possible I is electric field is
2
25. A bakelite beaker has volume capacity of 500 cc at 30°C. (3) The reaction is accompanied by racemization.
When it is partially filled with Vm volume (at 30°C) of (4) The reaction is favoured by non-polar solvents.
mercury, it is found that the unfilled volume of the Which observations are correct?
beaker remains constant as the temperature is varied. (a) (1) and (2) (b) (1) and (3)
If g(beaker) = 6 × 10–6 °C–1 and g(mercury) = 1.5 × 10–4 °C–1, (c) (1), (2) and (3) (d) (2) and (4)
where g is the coefficient of volume expansion, then
30. Which one of the following compounds possesses the
Vm (in cc) is close to ______ .
most acidic hydrogen?
CHEMISTRY
N≡C C≡N
(a) (b) H3C — C ≡ C — H
26. Henry’s constant (in kbar) for four gases a, b, g and d in H H
water at 298 K is given below : O O
O
a b g d (c) (d) MeO OMe
H
KH 50 2 2 × 10–5 0.5 H3C CH3
O OMe
3 –3
(density of water = 10 kg m at 298 K)
This table implies that 31. Thermal power plants can lead to
(a) a has the highest solubility in water at a given (a) acid rain (b) blue baby syndrome
pressure (c) ozone layer depletion (d) eutrophication.
(b) solubility of g at 308 K is lower than at 298 K 32. An acidic buffer is obtained on mixing
(c) the pressure of a 55.5 molal solution of g is 1 bar (a) 100 mL of 0.1 M CH3COOH and
(d) the pressure of a 55.5 molal solution of d is 250 bar. 100 mL of 0.1 M NaOH
27. Which of the following compounds produces an (b) 100 mL of 0.1 M HCl and
optically inactive compound on hydrogenation? 200 mL of 0.1 M NaCl
H CH3 H CH3 (c) 100 mL of 0.1 M CH3COOH and
(a) (b) 200 mL of 0.1 M NaOH
(d) 100 mL of 0.1 M HCl and
H CH3 H CH3 200 mL of 0.1 M CH3COONa
(c) (d)
33. If the boiling point of H2O is 373 K, the boiling point of
28. An organic compound [A], molecular formula H2S will be
C10H20O2 was hydrolyzed with dilute sulphuric acid to (a) less than 300 K (b) equal to 373 K
give a carboxylic acid [B] and an alcohol [C]. Oxidation (c) more than 373 K
of [C] with CrO3 — H2SO4 produced [B]. Which of the (d) greater than 300 K but less than 373 K.
following structures are not possible for [A]? 34. Tyndall effect is observed when
CH3
(a) the diameter of dispersed particles is much larger
(a) CH — CH — CH — OCOCH CH — CH CH than the wavelength of light used
3 2 2 2 3
37. The Kjeldahl method of nitrogen estimation fails for 46. The mole fraction of glucose (C6H12O6) in an aqueous
which of the following reaction products? binary solution is 0.1. The mass percentage of water in
NO2 CN it, to the nearest integer, is _______.
Sn/HCl LiAlH4 47. The photoelectric current from Na (work function,
(1) (2) w0 = 2.3 eV) is stopped by the output voltage of the cell
Pt(s) | H2(g, 1 bar) | HCl(aq., pH = 1) | AgCl(s) | Ag(s)
CH2CN The pH of aq. HCl required to stop the photoelectric
(i) SnCl2 + HCl current from K(w0 = 2.25 eV), all other conditions
(3) (ii) H2O remaining the same, is _______ × 10–2 (to the nearest
integer).
NH2 NaNO2
(4) RT °
HCl Given, 2.303 = 0.06 V; EAgCl = 0.22 V
F | Ag | Cl −
(a) (3) and (4) (b) (1) and (4) 48. An element with molar mass 2.7 × 10–2 kg mol–1 forms
(c) (1), (3) and (4) (d) (2) and (3) a cubic unit cell with edge length 405 pm. If its
38. The atomic number of the element unnilennium is density is 2.7 × 103 kg m–3, the radius of the elementis
(a) 109 (b) 102 (c) 108 (d) 119 approximately _______ × 10–12 m (to the nearest
integer).
39. It is true that
(a) a second order reaction is always a multistep 49. The total number of monohalogenated organic
reaction products in the following (including stereoisomers)
(b) a zero order reaction is a multistep reaction reaction is _______.
(c) a first order reaction is always a single step reaction (i) H2/Ni/D
A
(d) a zero order reaction is a single step reaction. (Simplest optically (ii) X2/D
active alkene)
40. Let CNaCl and CBaSO4 be the conductances (in S)
measured for saturated aqueous solutions of NaCl and 50. The volume strength of 8.9 M H2O2 solution
BaSO4, respectively, at a temperature T. calculated at 273 K and 1 atm is _______.
Which of the following is false? (R = 0.0821 L atm K–1 mol–1) (rounded off to the
(a) Ionic mobilities of ions from both salts increase nearest integer)
with T. MATHEMATICS
(b) CBaSO4 (T2) > CBaSO4 (T1) for T2 > T1
2 2 π π
(c) CNaCl (T2) > CNaCl (T1) for T2 > T1 51. If y + log e (cos x ) = y , x ∈ − , , then
2 2
(d) CNaCl >> CBaSO4 at a given T
(a) y′′(0) = 0 (b) |y′(0)| + |y′′(0)| = 1
41. The complex that can show optical activity is
(c) |y′′(0)| = 2 (d) |y′(0)| + |y′′(0)| = 3
(a) trans-[Cr(Cl2)(ox)2]3–
(b) trans-[Fe(NH3)2(CN)4]– 4 5 16
52. 2π − sin −1 + sin −1 + sin −1 is equal to
(c) cis-[Fe(NH3)2(CN)4]– 5 13 65
(d) cis-[CrCl2(ox)2]3– (ox = oxalate) π 3π 7π
5π
42. Aqua regia is used for dissolving noble metals (Au, Pt, (a) (b) (c) (d)
2 4 2 4
etc.). The gas evolved in this process is
(a) NO (b) N2O5 (c) N2 (d) N2O3 53. If the first term of an A.P. is 3 and the sum of its first 25
terms is equal to the sum of its next 15 terms, then the
43. In a molecule of pyrophosphoric acid, the number
of P — OH, P O and P — O — P bonds/moiety(ies) common difference of this A.P. is
respectively are 1 1 1 1
(a) (b) (c) (d)
(a) 2, 4 and 1 (b) 3, 3 and 3 6 5 4 7
(c) 4, 2 and 0 (d) 4, 2 and 1 54. A hyperbola having the transverse axis of length 2
44. The antifertility drug “Novestrol” can react with has the same foci as that of the ellipse 3x2 + 4y2 = 12,
(a) ZnCl2/HCl; FeCl3; Alcoholic HCN then this hyperbola does not pass through which of the
(b) Br2/water; ZnCl2/HCl; FeCl3 following points?
(c) Alcoholic HCN; NaOCl; ZnCl2/HCl 1 3
(d) Br2/water; ZnCl2/HCl; NaOCl (a) , 0 (b) − , 1
2 2
45. Of the species, NO, NO+, NO2+ and NO–, the one with 3 1
minimum bond strength is 1
(c) 1, − (d) ,
(a) NO+ (b) NO (c) NO2+ (d) NO– 2 2 2
5
2
1 + ex
(b) y + 1 = y log e + 2
2 (a) 264 (b) 128 (c) 256 (d) 248
6
1 1 1 m n
log + + + ... to ∞
2.5 3 2 3 1+ i 2 1+ i 3
71. The value of (0.16) 3 3 is equal to 74. If = = 1, (m, n ∈ N ) then the
_________ . 1 − i i − 1
greatest common divisor of the least values of m and n
x 1 4 is _________ .
72. Let A = , x ∈ R and A = [aij]. If a11 = 109, then
1 0
a22 is equal to _________ .
1 x2 x2 x2 x2
75. If lim 8 1 − cos − cos + cos cos = 2–k ,
x →0 x 2 4 2 4
73. The diameter of the circle, whose centre lies on the line
x + y = 2 in the first quadrant and which touches both then the value of k is _________ .
the lines x = 3 and y = 2, is _________ .
µ I 1 1
2
\ q1 = × 9 = 6 µC [\ q1 + q2 = 9mC] = (50 × 6) × 0 + a
4 π 0.1 × cos 30° 2 2
3
1 µ I
q2 = × 9 = 3 µC ⇒ B = 500 3 0
3 π
R2 L2 8. (b) : Irreversible adiabatic.
5. (c) : Moment of inertia, I = M + ...(i)
4 12 9. (d) : Here, f = 750 Hz ; Vrms = 20 V ; R = 100 W;
As the mass is constant, so volume is also constant. L = 0.1803 H ; C = 10 mF
7
28. (a, c) :
N O
But µ = ⇒ N = µ × 100
100 CH3 — CH2 — CH — O — C — CH2 — CH — CH2 — CH3
N = 1.58 × 100 = 158
CH3 CH3
22. (150) : Given : m = 0.15 kg ; h = 20 m ; x = 0.2 m ; dil. H2SO4 [O]
g = 10 m/s2
CH3 — CH2 — CH — OH + HOOC — CH2 — CH — CH2 — CH3
From work-energy theorem, F × x = mgh
⇒ F × 0.2 = 0.15 × 10 × 20 \ F = 150 N CH3 CH3
(C) (B)
23. (9) : Given : m = 80 kg, M = 200 kg, f = 5 rpm CrO3 — H2SO4 [O]
According to conservation of angular momentum,
CH3 — CH2 — C O
2 1 2 MR2
mR + MR 2πf = ⋅ 2πf ′ CH3
2 2
Molecular formula of option (c) does not match with
200 200
80 + × 5 = × f′ molecular formula given, i.e., C10H20O2. Hence option (c)
2 2 is also correct.
180 × 5 29. (c) : SN1 reactions are favoured by polar, protic solvents.
⇒ f′= = 9 rpm
100 O O
24. (101) : Given : r = 0.015 cm, r = 900 kg/m3
h = 15 cm, g = 10 m/s2, q = 0° 30. (d) : MeO H OMe
2T cos θ Most acidic hydrogen
Height to which liquid will rise, h = O OMe
r ρg Due to presence of three (— COOMe) groups, among the
hr ρg 15 × 10 × 0.015 × 10 −2 × 900 × 10
−2
given compounds, this compound possesses the most acidic
or T = =
2 cos θ 2 hydrogen.
\ T = 0.10125 N/m = 101.25 mN/m 31. (a) : Thermal power plants produces large amounts
of nitrogen oxide and sulphur dioxide, the pollutants that
25. (20) : Given : V = 500 cc, T = 30°C
cause acid rain.
Vbeaker = 6 × 10–6/°C V – Vm
32. (d) : Acidic buffer is the solution of a mixture of
gmercury = 1.5 × 10–4/°C a weak acid and a salt of this weak acid with a strong
V – Vm = V′ – V′m base. After mixing 100 mL of 0.1 M HCl and 200 mL of
Vm
Now, V′ = V(1 + gbDT) 0.1 M CH3COONa, the solution will contain mixture of
CH3COOH and CH3COONa that will work as an acidic
and V′m = Vm(1 + gmDT)
buffer.
\ V – Vm = V + Vgb DT – Vm – Vm gmDT
33. (a) : At room temperature, H2O is a liquid whereas H2S
γb 500 × 6 × 10 −6 5 × 6 is a gas. Due to strong intermolecular hydrogen bonding,
or Vm = V = = = 20 cc
γm 1.5 × 10 −4 1. 5 H2O has a high boiling point (373 K). The boiling point of
26. (b, d) : Higher the value of KH, lower is the solubility of H2S is 213 K.
the gas at a particular temperature. Hence, g has the highest 34. (d)
solubility in water. 35. (d) : Glycerol is separated from spent lye in soap industries
The value of KH increases with increase of temperature by distillation under reduced pressure.
implying solubility decreases with increase of temperature.
55.5 −5 1
36. (d) : [Ti(H2O)6]3+ ⇒ Ti3+ ⇒ 3d1 ⇒ t12g e0g
pγ = K H ⋅ x γ = 2 × 10−5 × 1000 = 2 × 10 × 2 CFSE = (–0.4 × 1 + 0.6 × 0)D0 = –0.4 × 20300 cm–1
55.5 +
18 8120
–5
= 10 kbar = 10 bar –2 = –8120 cm–1 = − kJ mol–1 = –97 kJ mol–1
83.7
55.5 NO2 NH2 CN CH2NH2
pd = 0.5 ×xd = 0.5 × = 0.25 kbar = 250 bar
1000 LiAlH4
55.5 + 37. (a) :
Sn/HCl
;
18
H3C H CH3 H3C H CH3
CH2 Pd CH2CN CH2CHO
27. (d) : H C C C H2
C C CH3
3 C H3C C (i) SnCl2 + HCl
H CH3 H H CH3 + NH4Cl
(Optically inactive) (ii) H2O
9
49. (8) : H H
* H2/Ni/D
CH3 — CH2 — C — CH CH2 CH3 — CH2 — C — CH2 — CH3
CH3 CH3
Simplest optical active alkene X2/D
‘A’
H H
* * *
CH3 — CH — C — CH2 — CH3 , CH2 — CH2 — C — CH2 — CH3
X CH3 X CH3
(Two chiral carbons) (4) (One chiral carbon) (2)
H X
CH3 — CH2 — C — CH2 — CH3 , CH3 — CH2 — C — CH2 — CH3
CH2X CH3
(1) (1)
Hence, total number of organic products including stereoisomers = 8
10