w(omega), Tc, Pc, Vc y Zc son sacados de la Tabla B1 Propiedades de especies Puras

((d))
Tc ≔ 417.2 K Pc ≔ 77.10 bar ω ≔ 0.069
cm 3 ⋅ kPa
T ≔ ((90 + 273.15)) K T = 363.15 K P ≔ 33.08 bar R ≔ 8314 ⋅ ――――
mol ⋅ K

T P
Tr ≔ ― Pr ≔ ― Tr = 0.87 Pr = 0.429
Tc Pc

De la tabla 3.1 de RW

σ≔1 ε≔0 Ω ≔ 0.08664 Ψ ≔ 0.42748

α ⎛⎝Tr⎞⎠ ≔ Tr -0.5 α ⎛⎝Tr⎞⎠ = 1.072

Ψ ⋅ α ⎛⎝Tr⎞⎠ Ω ⋅ Pr
q ⎛⎝Tr⎞⎠ ≔ ――― β ⎛⎝Tr , Pr⎞⎠ ≔ ――
Ω ⋅ Tr Tr

q ⎛⎝Tr⎞⎠ = 6.076 β ⎛⎝Tr , Pr⎞⎠ = 0.043

Calculo de Z para Liquido

Valores de prueba

Z ≔ 0.01
Restricciones

⎛ 1 + β ⎛⎝Tr , Pr⎞⎠ - Z ⎞
Z ＝ β ⎛⎝Tr , Pr⎞⎠ + ⎛⎝Z + ε ⋅ β ⎛⎝Tr , Pr⎞⎠⎞⎠ ⋅ ⎛⎝Z + σ ⋅ β ⎛⎝Tr , Pr⎞⎠⎞⎠ ⎜――――――⎟
⎝ ⎛⎝q ⎛⎝Tr⎞⎠ ⋅ β ⎛⎝Tr , Pr⎞⎠⎞⎠ ⎠
Solver

Z1 ≔ find ((Z)) Z1 = 0.077

Z1 ⋅ R ⋅ T cm 3
V1 ≔ ――― V1 = 70.316 ――
P mol
 Calculo de Z para Vapor
Valores de prueba

Z ≔ 0.9
Restricciones

Z - β ⎛⎝Tr , Pr⎞⎠
Z ＝ 1 + β ⎛⎝Tr , Pr⎞⎠ - q ⎛⎝Tr⎞⎠ ⋅ β ⎛⎝Tr , Pr⎞⎠ ⋅ ――――――
Z ⋅ ⎛⎝Z + β ⎛⎝Tr , Pr⎞⎠⎞⎠
Solver

Z2 ≔ find ((Z)) Z2 = 0.724

Z2 ⋅ R ⋅ T cm 3
V2 ≔ ――― V2 = 661.182 ――
P mol