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MALAYSIAN MS IEC 60086-4:2010

STANDARD

PRIMARY BATTERIES - PART 4: SAFETY OF


LITHIUM BATTERIES
(IEC 60086-4:2007, IDT)

ICS: 29.220.10
Descriptors: primary cells, batteries, safety of lithium batteries

© Copyright 2010
DEPARTMENT OF STANDARDS MALAYSIA
DEVELOPMENT OF MALAYSIAN STANDARDS

The Department of Standards Malaysia (STANDARDS MALAYSIA) is the national


standards and accreditation body of Malaysia.

The main function of STANDARDS MALAYSIA is to foster and promote standards,


standardisation and accreditation as a means of advancing the national economy,
promoting industrial efficiency and development, benefiting the health and safety of
the public, protecting the consumers, facilitating domestic and international trade and
furthering international cooperation in relation to standards and standardisation.

Malaysian Standards (MS) are developed through consensus by committees which


comprise balanced representation of producers, users, consumers and others with
relevant interests, as may be appropriate to the subject at hand. To the greatest
extent possible, Malaysian Standards are aligned to or are adoption of international
standards. Approval of a standard as a Malaysian Standard is governed by the
Standards of Malaysia Act 1996 [Act 549]. Malaysian Standards are reviewed
periodically. The use of Malaysian Standards is voluntary except in so far as they are
made mandatory by regulatory authorities by means of regulations, local by-laws or
any other similar ways.

STANDARDS MALAYSIA has appointed SIRIM Berhad as the agent to develop,


distribute and sell the Malaysian Standards.

For further information on Malaysian Standards, please contact:

Department of Standards Malaysia OR SIRIM Berhad


Ministry of Science, Technology and Innovation (Company No. 367474 - V)
Level 1 & 2, Block 2300, Century Square 1, Persiaran Dato’ Menteri
Jalan Usahawan Section 2
63000 Cyberjaya 40000 Shah Alam
Selangor Darul Ehsan Selangor Darul Ehsan
MALAYSIA MALAYSIA

Tel: 60 3 8318 0002 Tel: 60 3 5544 6000


Fax: 60 3 8319 3131 Fax: 60 3 5510 8095
http://www.standardsmalaysia.gov.my http://www.sirim.my

E-mail: central@standardsmalaysia.gov.my E-mail: msonline@sirim.my


–i– MS IEC 60086-4:2010

CONTENTS

Page

Committee representation......................................................................................................... iv

National foreword...................................................................................................................... v

Foreword .................................................................................................................................. vi

Introduction……...................................................................................................................... viii

1 Scope ............................................................................................................................... 7
2 Normative references ....................................................................................................... 7
3 Terms and definitions ....................................................................................................... 7
4 Requirements for safety ................................................................................................... 9
4.1 Design ..................................................................................................................... 9
4.2 Quality plan ........................................................................................................... 10
5 Sampling ........................................................................................................................ 10
5.1 General ................................................................................................................. 10
5.2 Test samples ......................................................................................................... 10
6 Testing and requirements ............................................................................................... 11
6.1 General ................................................................................................................. 11
6.1.1 Test application matrix............................................................................... 11
6.1.2 Safety notice ............................................................................................. 11
6.1.3 Ambient temperature ................................................................................. 11
6.1.4 Parameter measurement tolerances .......................................................... 11
6.1.5 Predischarge ............................................................................................. 12
6.1.6 Additional cells .......................................................................................... 12
6.2 Evaluation of test criteria ....................................................................................... 12
6.2.1 Short-circuit ............................................................................................... 12
6.2.2 Excessive temperature rise........................................................................ 12
6.2.3 Leakage .................................................................................................... 12
6.2.4 Mass loss .................................................................................................. 12
6.2.5 Venting ...................................................................................................... 12
6.2.6 Fire ........................................................................................................... 13
6.2.7 Rupture ..................................................................................................... 13
6.2.8 Explosion .................................................................................................. 13
6.3 Tests and requirements – Overview....................................................................... 14
6.4 Tests for intended use ........................................................................................... 14
6.4.1 Test A: Altitude .......................................................................................... 14
6.4.2 Test B: Thermal cycling ............................................................................. 15
6.4.3 Test C: Vibration ....................................................................................... 15
6.4.4 Test D: Shock ............................................................................................ 16
6.5 Tests for reasonably foreseeable misuse ............................................................... 16
6.5.1 Test E: External short-circuit ..................................................................... 16

© STANDARDS MALAYSIA 2010 - All rights reserved


MS IEC 60086-4:2010 – ii –

CONTENTS (continued)

Page

6.5.2 Test F: Impact ........................................................................................... 17


6.5.3 Test G: Crush ............................................................................................ 17
6.5.4 Test H: Forced discharge .......................................................................... 18
6.5.5 Test I: Abnormal charging .......................................................................... 18
6.5.6 Test J: Free fall ......................................................................................... 19
6.5.7 Test K: Thermal abuse .............................................................................. 19
6.5.8 Test L: Incorrect installation ...................................................................... 20
6.5.9 Test M: Overdischarge .............................................................................. 20
6.6 Information to be given in the relevant specification .............................................. 21

6.7 Evaluation and report ............................................................................................ 22


7 Information for safety...................................................................................................... 22
7.1 Safety precautions during design of equipment ..................................................... 22
7.1.1 Charge protection ...................................................................................... 22
7.1.2 Parallel connection .................................................................................... 22
7.2 Safety precautions during handling of batteries ..................................................... 22
7.3 Packaging ............................................................................................................. 24
7.4 Handling of battery cartons.................................................................................... 24
7.5 Transport .............................................................................................................. 25
7.5.1 General ..................................................................................................... 25
7.5.2 Air transport .............................................................................................. 25
7.5.3 Sea transport ............................................................................................. 25
7.5.4 Land transport ........................................................................................... 25
7.6 Display and storage............................................................................................... 25
7.7 Disposal ................................................................................................................ 25
8 Instructions for use ......................................................................................................... 26
9 Marking .......................................................................................................................... 26
9.1 General ................................................................................................................. 26
9.2 Small batteries ...................................................................................................... 27

Annex A (informative) Guidelines for the achievement of safety of lithium batteries ............. 28
Annex B (informative) Guidelines for designers of equipment using lithium batteries............ 29
Annex C (informative) Additional information on display and storage ................................... 31

Bibliography.......................................................................................................................... 32

Figure 1 – Mesh screen ........................................................................................................ 13


Figure 2 – Thermal cycling procedure ................................................................................... 15
Figure 3 – Axes for free fall................................................................................................... 19

© STANDARDS MALAYSIA 2010 - All rights reserved


– iii – MS IEC 60086-4:2010

CONTENTS (concluded)

Page

Figure 4 – Circuit diagram for incorrect installation ............................................................... 20


Figure 5 – Circuit diagram for overdischarge ......................................................................... 21
Figure 6 – Safety wiring for charge protection ....................................................................... 22
Figure 7 – Ingestion gauge ................................................................................................... 24

Table 1 – Number of test samples ......................................................................................... 10


Table 2 – Test application matrix .......................................................................................... 11
Table 3 – Maximum mass loss .............................................................................................. 12
Table 4 – Tests and requirements ......................................................................................... 14
Table 5 – Vibration profile (sinusoidal) .................................................................................. 16
Table 6 – Shock parameters ................................................................................................. 16
Table 7 – Resistive load for overdischarge............................................................................ 21
Table A.1 – Battery design guidelines ................................................................................... 28
Table B.1 – Equipment design guidelines.............................................................................. 29

© STANDARDS MALAYSIA 2010 - All rights reserved


MS IEC 60086-4:2010 – iv –

Committee representation

The Industry Standards Committee on Generation, Transmission and Distribution of Electrical Energy (ISC E) under
whose authority this Malaysian Standard was adopted, comprises representatives from the following organisations:

Association of Consulting Engineers Malaysia


Department of Standards Malaysia
Federation of Malaysian Manufacturers
Jabatan Kerja Raya Malaysia
Malaysian Association of Standards Users
Malaysian Cable Manufacturers Association
Malaysian Electrical Appliances and Distribution Association
Ministry of Domestic Trade, Co-operatives and Consumerism
Ministry of International Trade and Industry
Persatuan Kontraktor Elektrikal dan Mekanikal Melayu Malaysia
Persatuan Penjana Kuasa Bebas
PETRONAS Research and Scientific Services Sdn Bhd
Pusat Tenaga Malaysia
SIRIM Berhad (Secretariat)
SIRIM QAS International Sdn Bhd
Suruhanjaya Komunikasi dan Multimedia Malaysia
Suruhanjaya Tenaga
Tenaga Nasional Berhad
The Electrical and Electronics Association of Malaysia
The Institution of Engineers, Malaysia
Universiti Teknologi Malaysia

The Technical Committee on Low Voltage Transformer and Storage of Electrical Energy which recommended the
adoption of the IEC Standard consists of representatives from the following organisations:

Jabatan Kerja Raya Malaysia


SIRIM Berhad (Secretariat)
SIRIM QAS International Sdn Bhd
Suruhanjaya Tenaga
Tenaga Nasional Berhad
The Electrical and Electronics Association of Malaysia
The Institution of Engineers, Malaysia
TNB Remaco Repair & Maintenance Sdn Bhd
Universiti Malaya
Universiti Teknologi Malaysia

Co-opted members:

Federation of Malaysian Manufacturers


Malaysian Association of Standards Users
Ministry of Domestic Trade, Co-operatives and Consumerism

© STANDARDS MALAYSIA 2010 - All rights reserved


–v– MS IEC 60086-4:2010

NATIONAL FOREWORD

The adoption of the IEC Standard as a Malaysian Standard was recommended by the
Technical Committee on Low Voltage Transformer and Storage of Electrical Energy under the
authority of the Industry Standards Committee on Generation, Transmission and Distribution
of Electrical Energy.

This Malaysian Standard is identical with IEC 60086-4:2007, Primary batteries - Part 4: Safety
of lithium batteries, published by the International Electrotechnical Commission (IEC).
However, for the purposes of this Malaysian Standard, the following apply:

a) in the source text, "this International Standard" should read "this Malaysian Standard";

b) the comma which is used as a decimal sign (if any), to read as a point; and

c) reference to International Standards should be replaced by corresponding Malaysian


Standards as follows:

Referenced International Standards Corresponding Malaysian Standards

IEC 60086-1, Primary batteries - Part 1: MS IEC 60086-1, Primary batteries - Part 1:
General General

IEC 60086-2, Primary batteries - Part 2: MS IEC 60086-2, Primary batteries - Part 2:
Physical and electrical specifications Physical and electrical specifications

Compliance with a Malaysian Standard does not of itself confer immunity from legal
obligations.

NOTE. IDT on the front cover indicates an identical standard i.e. a standard where the technical content, structure,
and wording (or is an identical translation) of a Malaysian Standard is exactly the same as in an International
Standard or is identical in technical content and structure although it may contain the minimal editorial changes
specified in clause 4.2 of ISO/IEC Guide 21-1.

© STANDARDS MALAYSIA 2010 - All rights reserved

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