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SAFETY DATA SHEET

Page 1 of 3

Product Name: FoamSMARTTM Standard PU Chemical Part A (Polyol Blend)


SDS No: 139 Revision No : 3 Issued by: Sha
Issue Date: 12 Nov 2018

Section 1 – Company Details


Company Name : FoamSMARTTM Products
Address : Blk 3017A, #01-12, Tel : +65 6748 4292
Ubi Road 1 Fax : +65 6749 0844
Singapore 408709 Email: sales@accise-asia.com

Section 2 – Composition

A liquid mixture of polyether/ polyester polyols, amine catalysts, water and surfactant

Section 3 – Hazardous identification

Hazards identification: Irritant. Dangerous for ozone layer

Risk Phrases: R22 Harmful if swallowed.


R36/38 Irritating to eyes and skin.

Safety Phrases: S7 Keep container tightly closed


S18 Handle and open container with care
S26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice
Section 4 – First Aid Measures

Inhalation: Remove casualty from exposure ensuring one’s own safety whilst doing so. If
unconscious, check for breathing and apply artificial respiration if necessary. If conscious,
ensure the casualty sits or lies down. Consult a doctor.
Skin: Remove any contaminated clothing and launder before re-use. Wash affected area with
soap and plenty of water.
Eye: Immediately wash with plenty of clear water or an eyewash solution for at least 15
minutes. Obtain medical attention.
Ingestion: If swallowed, do not induce vomiting, keep at rest, and seek prompt medical attention

Section 5 – Fire Fighting Measures


Extinguishing Media: Dry powder, foam, and CO2

Protective Equipment: Self-contained breathing apparatus and full protective clothing must be worn in fire
conditions

Other Information: Noxious fumes may be emitted as products of combustion.


Section 6 – Accidental Release Measures

Personal Precautions: Remove all possible sources of ignition in the surrounding area.

Environmental Precautions: Do not discharge into drains or river. Contain the spillage using bunding.

Clean-up Methods: Ensure suitable personal protection during removal of spillage. Ventilate
area. Eliminate sources of ignition. Absorb spillage onto sand, earth or any
suitable absorbent material, and transfer to a container for disposal. Wash
the spillage area and clean with water and detergent. Do not allow entering
drains, sewer or water sources.

Other Information: Observe all relevant local regulations.


SAFETY DATA SHEET
Page 2 of 3

Product Name: FoamSMARTTM Standard PU Chemical Part A (Polyol Blend)


SDS No: 139 Revision No : 3 Issued by: Sha
Issue Date: 12 Nov 2018

Section 7 – Handling and Storage


Handling: When opening, the temperature of the container should be below 24C. Care should
be taken to release any internal pressure slowly. Take precautionary measures
against static discharges. Atmospheric concentrations should be minimized and
kept as low as reasonably practicable.
Storage: Keep away from direct sunlight. This material is hygroscopic, avoid ingress of
moisture by keeping containers properly sealed when not in use. Keep at
temperatures below 24C to assist prolong shelf life.

Section 8 – Exposure Control / Personal Protection

Exposure Controls: Not Established


Respiratory Type: Respiratory protection not required.
Eye Protection: Non-fogging chemical safety goggles or safety glasses with side shields.
Glove Type: Wear suitable impervious protective gloves such as PVC or Nitrile gloves.
Skin Protection: Wear suitable impervious protective clothing.

Section 9 – Physical And Chemical Characteristics

Physical: Yellow Liquid


Odour: Characteristic
Density(25C): 1.10 +0.05 g/cm3
Water Content: 1.40+ 0.05% wt
Colour: Yellow
Water Solubility: Soluble in water
Viscosity (25C): 250 + 50 cps

Section 10 – Stability and Reactivity

Stability: Relatively Stable


Products to Avoid: Strong acids, Strong bases and oxidizing agents
Hazardous Reactions: None
Hazardous Decomposition: NA
Section 11 – Toxicological Information

Inhalation: Slight/mild irritant.


Skin: Slight/mild irritant.
Eyes: Direct eye contact may cause sensitization and irritation.
Ingestion: Highly unlikely under normal industrial use. The effects of ingestion include irritation of
mouth and stomach.
SAFETY DATA SHEET
Page 3 of 3

Product Name: FoamSMARTTM Standard PU Chemical Part A (Polyol Blend)


SDS No: 139 Revision No : 3 Issued by: Sha
Issue Date: 12 Nov 2018

Section 12 – Ecological Information

Ecotoxicity: Not Established


Mobility: NA
Persistence/Degradability: NA
Bioaccumulation: NA

Section 13 – Disposal Considerations

Disposal Operation: Disposal should be accordance with local, state or national legislation. The
generation of waste should be avoided or minimised wherever possible. If this is not
possible, destruction is to be in approved facility under controlled conditions.

Section 14 – Transportation Information

This item is not classifies as non-hazardous and non-dangerous goods for transportation.
This item is not ICAO regulated
This item is not IATA regulated

Section 15 – Regulatory Information

None known

Other Information:
Section 16 – Other This safety data sheet is prepared in accordance with Commission Regulation (EU)
Information
No 453/2010.

The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. This company shall not be held liable damage resulting from handling or from contact with
the above product. We therefore provide no warranty, either explicit or otherwise regarding the suitability of
our products for any applications. It is the responsibility of the user to ensure that any proprietary rights and
existing laws and legislation are observed
SAFETY DATA SHEET
Page 1 of 3

Product Name: FoamSMARTTM Standard PU Chemical Part B (MDI)


SDS No: 140 Revision No: 3 Issued by: Sha
Issue Date: 12 Nov 2018

Section 1 – Company Details


Company Name: FoamSMARTTM Products Tel: +65 6748 4292
Address: Blk 3017A, #01-12, Fax: +65 6749 0844
Ubi Road 1 Email: sales@accise-asia.com
Singapore 408709

Section 2 – Composition

INGREDIENTS CAS No % CHIP Classification

2, 4’ - Diphenylmethane diisocyanate 5873-54-1 10 R20; R36/37/38; R42/43

4, 4’ - Diphenylmethane diisocyanate 101-68-8 60 R20; R36/37/38; R42/43


Diphenylmethane diisocyanate, isomers 9016-87-9 30 R20; R36/37/38; R42/43
& homologues

Section 3 – Hazardous Identification

Hazards identification:Irritant
Risk Phrases: R20 Harmful by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R42/43 May cause sensitization by inhalation and skin contact.
Safety Phrases: S18 Handle and open container with care
S23 Do not breathe fumes
S28 After contact with skin, wash immediately with plenty of water and soap
S30 Never add water to this product
S32 In case of contact with eyes, rinse immediately with water and seek
medical advice
S38 In case of insufficient ventilation, wear suitable respiratory equipment
S45 In case of accident or if you feel unwell, seek medical advice immediately

Section 4 – First Aid Measures

Inhalation: Remove to fresh air. If not breathing, give mouth-to-mouth resuscitation. If breathing
difficult, give oxygen. Call a physician. Effects may be delayed.
Skin: Wash immediately with water followed by soap and water. If symptoms persist, obtain
medical attention. Contaminated clothing should be laundered before reuse.
Eye: Irrigate immediately with plenty of clear water or an eyewash solution for at least 15
minutes. Apply sterile castor oil or simple eye ointment. Obtain medical attention.
Ingestion: If swallowed immediately call physician who will decide on need and method of emptying
the stomach.

Section 5 – Fire Fighting Measures


Extinguishing Media: Water fog, CO2, dry chemical, and foam.
Protective Equipment: Fire fighters must wear a full-face, positive pressure, self-contained
breathing apparatus and protective clothing.
Other Information: Products of combustion are CO, CO2, nitrogen oxide and ammonia. Do not
breathe smoke when burning
SAFETY DATA SHEET
Page 2 of 3

Product Name: FoamSMARTTM Standard PU Chemical Part B (MDI)


SDS No: 140 Revision No: 3 Issued by: Sha
Issue Date: 12 Nov 2018

Section 6 – Accidental Release Measures


Personal Precautions: Remove all possible sources of ignition in the surrounding area.
Environmental Precautions: Do not discharge into drains or river. Contain the spillage using bunding.
Clean-up Methods: Neutralize small spillage with a decontaminant (mixture of water with 2% of
a detergent and 5-10% of either concentrated ammonia or sodium
carbonate). Absorb large spillage onto an inert, non-flammable absorbent
carrier. Shovel the resulting mixture in waste drums and remove for
contamination and disposal. Wash the spillage area clean with liquid
contaminant. People dealing with major spillage should wear full protective
clothing including respiratory protection.
Other Information: Observe all relevant local regulations.

Section 7 – Handling and Storage

Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use
adequate ventilation. Wash hands and face thoroughly after handling.
Storage: Do not store drums uncovered out of doors. Do not reseal containers unless it is
certain that no moisture contamination has occurred.
Section 8 – Exposure Control / Personal Protection
INGREDIENTS CAS No % CHIP Classification
2, 4’ - Diphenylmethane diisocyanate 5873-54-1 10 R20; R36/37/38; R42/43
4, 4’ - Diphenylmethane diisocyanate 101-68-8 60 R20; R36/37/38; R42/43
Diphenylmethane diisocyanate, isomers 9016-87-9 30 R20; R36/37/38; R42/43
& homologues

Respiratory Type Respiratory protection not required.


Eye Protection Non-fogging chemical safety goggles or safety glasses with side shields.
Glove Type Wear suitable impervious protective gloves such as PVC or Nitrile gloves.
Skin Protection Wear suitable impervious protective clothing.

Section 9 – Physical And Chemical Characteristics

Physical: Dark brown liquid


Odour: Characteristic
Density (25C): 1.24 g/cm3
Colour: Dark Brown
Water Solubility: Not soluble in water and reactive
Viscosity (25C): 200 – 300 cps

Section 10 – Stability and Reactivity

Stability: Stable
Products to Avoid: Water, alcohols and strong bases
Hazardous Reactions: Reaction with water/moisture produces CO2 gas. Exothermic reaction
with materials containing active hydrogen groups.

Hazardous Decomposition: Above 270C, it produces CO, HCN and Nitrogen oxide
SAFETY DATA SHEET
Page 3 of 3

Product Name: FoamSMARTTM Standard PU Chemical Part B (MDI)


SDS No: 140 Revision No: 3 Issued by: Sha
Issue Date: 12 Nov 2018

Section 11 – Toxicological Information

Inhalation: Inhalation of MDI mists or vapors may cause respiratory irritation, breathlessness, chest
discomfort and reduced pulmonary function.

Skin: Skin contact with MDI may result in irritation and a mild tanning action, depending on the
amount and length of contact.
Eyes: Direct eye contact with MDI products may produce severe watering, irritation and
inflammation of mucous membranes. Corneal opacity and discharge may result, if MDI is
not removed.
Ingestion: The effects of ingestion include irritation and burning of the mouth, esophagus, and stomach.

Section 12 – Ecological Information


Ecotoxicity: Not established
Mobility: Readily absorbed into soil. Soluble in water.
Persistence/ Degradability: Not readily biodegradable
Bioaccumulation: Does not bio accumulate significantly

Section 13 – Disposal Considerations

Disposal Operation: Disposal should be accordance with local, state or national legislation. The
generation of waste should be avoided or minimised wherever possible. If this is not
possible, destruction is to be in approved facility under controlled conditions.

Section 14 – Transport Information


Declaration for land shipment: ---

Declaration for sea shipment: ---

Declaration for shipment by air: ---

Other information: Not dangerous cargo. Irritating to skin and eyes. Keep dry. Avoid heat
above 50C and below 0C. Keep away from foodstuffs, acids and alkalis.

Section 15 – Regulatory Information

None known

Other Information:
Section 16 – Other This safety data sheet is prepared in accordance with Commission Regulation (EU)
Information
No 453/2010.

The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. This company shall not be held liable damage resulting from handling or from contact with
the above product. We therefore provide no warranty, either explicit or otherwise regarding the suitability of
our products for any applications. It is the responsibility of the user to ensure that any proprietary rights and
existing laws and legislation are observed

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