IMPORTANT NUMERICALS

CHEMICAL KINETICS
Rate of Ren
dA)
&T t df
-
-

:
:

at

· rate of formation C

5 x 20
d
e
+ = 2 .

L St

·
rate of disappearance
of
②
B
dTB
IXROR
-

Et
= 3 X125X10-9 = 3 . 75X10-9 CLHse
Rate & Ro = KTM02] [t]
Order = Second
Order O
=

Molecularity = 2

K =

(Mot(1)""sect
(20 1- 1)"
-
O
=
sect

= MOL It Sect
---
 tgoi
&sliga
=

>
-

a-k

2 303 ↳
Flig 100-80
= .

t 2 303
lig
=
.

↳ k

tV2
69
.
= 0

K 93
: 0
. : O
tyz 69 . 3

0 . 01 min

2 603
logs
.

- >
-

0 01 .
K : molt sece

second .

A- B
=
-
R =
K [A]

R2 :
K 53A]
4

=
9K [A]2
- ti Ro-R
°
⑥

K
K =
+ X10] Ms1

Ro + 0 1 M -

Ra 0 .
064

t =
Ro-R
F - 0
.
064
: T
&x 10
-
3 Y
T1 1200
K K = 0 02 sect
.

T2 +
500 K K2 = 0 20 Sea
.

Ea =?

logk =trset
Es :. (tst
is

loglo :

Eis (d
 0653
T1 300K K
+
g
=

Tn 320
=
4
K 0 %93
:

S-
0
,

ty
t =
Homin T1 =
Jook

the : Comin T2 = 320K

 Rate KTAK [B]]
- ·
:

RO R .

dCA]
=dist
O +dTc]
-

q Tt a
 &
t
24
=

1
As la
:

T
I
& 603 1 6 Ho-2 nol(1
->
-

lg
.
.

--
mot
-

0 4 X100
600 Jos
.
 -

SO2C - SO2 + On
t 0 4 Ch O O Pressure of SOU, at Hire t

3
.
= 0

O-fl CCC 0 4- If 0 4-PtHO 4

at fire t
.
. .

Total at fire t
=
0 .
8 - Pt
pressure
-
↓ 100 sec
=

Pt = 0 .
4-(4 + D +K Psoych
: 0 . 8-0 7.

l
Pt = 0 4 + ka2 30] initial p s
·
sos lg e
.

lg
:

=°
-1

t final per O :L
CCF Pt-0 . 4
 &
tggy 2xtgoy -goy.
2303 eng t
i
= =

t 2
33 lug e
= .

Agos lg te
loo-go

Aggy
3 eng the
=
.

100-99
- -
2 Job
lg le

E
2 303
D -

lig loo
T t9 : 303
2
I
- X 2 lig
Ogls Fo T
2

22303 --

230)
2
2 .

30346 legle -
E
T

%2XAgos =
.